附录Ⅵ 物质的标准摩尔生成焓、标准摩尔生成吉
附录Ⅵ 物质的标准摩尔生成焓、标准摩尔生成吉布斯函数、标准摩尔熵和摩尔热容(100kPa)>
(1)单质和无机物
物质Δf H m (298.15
K)
Δf G m (298.15
K)
S m (298.1
5K)
C p,m (298.15K
) kJ·mol-1kJ·mol-1J·K-1mol-1J·K-1·mol-1
Ag(s)0042.71225.48 Ag2CO3(s)-506.14-437.09167.36
Ag2O(s)-30.56-10.82121.7165.57 Al(s)0028.31524.35 Al(g)313.80273.2164.553
Al2O3-α-1669.8-2213.160.98679.0 Al2(SO4)3(s)-3434.98-3728.53239.3259.4 Br2(g)111.88482.396175.021
Br2(g)30.71 3.109245.45535.99 Br2(l)00152.335.6 C(g)718.384672.942158.101
C(金刚石) 1.896 2.866 2.439 6.07 C(石墨)00 5.6948.66 CO(g)-110.525-137.285198.01629.142 CO2(g)-393.511-394.38213.7637.120 Ca(s)0041.6326.27 CaC2(s)-62.8-67.870.262.34 CaCO3(方解
石)
-1206.87-1128.7092.881.83
CaCl2(s)-795.0-750.2113.872.63 CaO(s)-635.6-604.239.748.53 Ca(OH)2(s)-986.5-896.8976.184.5 CaSO4(硬石
膏)
-1432.68-1320.24106.797.65
Cl-(aq)-167.456-131.16855.10
Cl2(g)00222.94833.9 Cu(s)0033.3224.47 CuO(s)-155.2-127.143.5144.4 Cu2O-α-166.69-146.33100.869.8 F2(g)00203.531.46 Fe-α0027.1525.23
FeCO3(s)-747.68-673.8492.882.13 FeO(s)-266.52-244.354.051.1 Fe2O3(s)-822.1-741.090.0104.6 Fe3O4(s)-117.1-1014.1146.4143.42 H(g)217.94203.122114.72420.80 H2(g)00130.69528.83 D2(g)00144.88429.20 HBr(g)-36.24-53.22198.6029.12 HBr(aq)-120.92-102.8080.71
HCl(g)-92.311-95.265186.78629.12 HCl(aq)-167.44-131.1755.10
H2CO3(aq)-698.7-623.37191.2
Hl(g)-25.94-1.32206.4229.12 H2O(g)-241.825-228.577188.82333.571 H2O(l)-285.838-237.14269.94075.296 H2O(s)-291.850(-234.03)(39.4)
H2O2(l)-187.61-118.04102.2682.29 H2S(g)-20.146-33.040205.7533.97 H2SO4(l)-811.35(-866.4)156.85137.57 H2SO4(aq)-811.32
HSO4(aq)-885.75-752.99126.86
l2(g)00116.755.97 I2(g)62.24219.34260.6036.87 N2(g)00191.59829.12 NH3(g)-46.19-16.603192.6135.65 NO(g)89.86090.37210.30929.861 NO2(g)33.8551.86240.5737.90 N2O(g)81.55103.62220.1038.70 N2O4(g)9.66098.39304.4279.0 N2O5(g) 2.51110.5342.4108.0 O(g)247.521230.095161.06321.93 O2(g)00205.13829.37 O3(g)142.3163.45237.738.15 OH-(aq)-229.940-157.297-10.539
S(单斜)0.290.09632.5523.64
S(斜方)0031.922.60
(g)124.9476.08227.7632.55
S(g)222.80182.27167.825
SO2(g)-296.90-300.37248.6439.79 SO3(g)-395.18-370.40256.3450.70 SO42- (aq)-907.51-741.9017.2
(2)有机化合物
物质Δf H m (298.15K)Δf G m (298.15K)
S m (298.15K
)
C
p
,
m
(
2
9
8
.
1
5
K
) kJ·mol-1kJ·mol-1J·K-1mol-1
J
·
K
-
1
·
m
o
l
-
1烃类
CH4(g), 甲烷-74.84750.827186.303
5
.
7
1
5 C2H2(g), 乙炔226.748209.200200.9284
.
9
2
8 C2H4(g), 乙烯52.28368.157219.564
3
.
5
6 C2H6(g), 乙烷-84.667-32.821229.605
2
.
6
5
0 C3H6(g), 丙烯20.41462.783267.056
3
.
8
9 C3H6(g), 丙烷-103.847-23.391270.027
3
.
5
1 C4H6(g), 1,3-丁二烯110.16150.74278.857
9
.
5
4 C4H8(g), 1-丁烯-0.1371.60305.718
5
.
6
5 C4H8(g), 顺-2-丁烯-6.9965.96300.947
8
.
9
1 C4H8(g), 反-2-丁烯-11.1763.07296.598
7
.
2 C4H8(g), 2-甲基两烯-16.9058.17293.708
9
.
1
2 C4H10(g), 正丁烷-126.15-17.02310.239
7
.
4
5 C4H10(g), 异丁烷-134.52-20.79294.759
6
.
8
2 C6H6(g), 苯82.927129.723269.318
1
.
6
7 C6H6(l), 苯49.028124.597172.351
3
5
.
7
7 C6H12(g), 环己烷-123.1431.92298.511
6
.
2
7 C6H14(g), 正己烷-167.19-0.09388.851
4
3
.
9 C6H14(l), 正己烷-198.82-4.08295.891
9
4
.
3 C6H5CH3(g),甲苯49.999122.388319.861
3
.
7
6 C6H5CH3(l),甲苯11.995114.299219.581
5
7
.
1
1 C6H4(CH2)(g) 邻二甲苯18.995122.207352.861
3
3
.
2
6 C6H4(CH3)2(l), 邻二甲苯-24.439110.495246.481
8
7
.
9 C6H4 (CH3)2(g), 间二甲苯17.238118.977357.801
2
7
.
5
7 C6H(CH3)2(l), 间二甲苯-25.418107.817252.171
8
3
.
3 C6H4(CH3)2(g), 对二甲苯17.949121.266352.531
2
6
.
8
6 C6H4(CH3)2(l), 对二甲苯-24.426110.244247.361
8
.
7
含氧化合物
HCOH(g), 甲醛-115.90-110.0220.23
5
.
3
6 HCOOH(g), 甲酸-362.63-335.69251.15
4
.
4 HCOOH(l), 甲酸-409.20-345.9128.959
9
.
4 CH3OH(g), 甲醇-201.17-161.83237.84
9
.
4 CH3OH(l), 甲醇-238.57-166.15126.88
1
.
6 CH2COH(g), 乙醛-166.36-133.67265.86
2
.
8 CH3COOH(l), 乙酸-487.0-392.4159.81
2
3
.
4 CH3COOH(g), 乙酸-436.4-381.5293.47
2
.
4 C2H5OH(l), 乙醇-277.63-174.36160.71
1
1
.
4
C2HOH(g), 乙醇-235.31-168.54282.17
1
.
1 CH3COCH3(l),丙酮-248.283-155.33200.01
2
4
.
7
3 CH3COCH3(g),丙酮-216.69-152.2296.007
5
.
3 C2H5OC2H5(l),乙醚-273.2-116.47253.1
CH3COOC2H5(l), 乙酸乙酯-463.2-315.3259
C6H5COOH(s), 苯甲酸-384.55-245.5170.71
5
5
.
2
卤代烃
CH3Cl(g), 氯甲烷-82.0-58.6234.294
.
7
9 CH2Cl2(g), 二氯甲烷-88-59270.625
1
.
3
8 CHCl3(l), 氯仿-131.8-71.4202.91
1
6
.
3 CHCl3(g), 氯仿-100-67296.486
5
.
8
CCl4(l), 四氯化碳-139.3-68.5214.431
3
1
.
7
5 CCl4(g), 甲氯化碳-106.7-64.0309.418
5
.
5
1 C6H5Cl(l), 氯苯116.3-198.2197.51
4
5
.
6
含氮化合物
NH(CH3)2(g), 二甲胺-27.659.1273.26
9
.
3
7 C5H5N(l), 吡啶78.87159.9179.1
C6H5NH2(l), 苯胺35.31153.35191.61
9
9
.
6 C6H5NO2,(l)硝基苯15.90146.36244.3
本附录数据主要取自Handbook of Chemistry and Physics, 70 th Ed., 1990; Editor John A.Dean,Lange's Handbook of Chemistry, 1967。