附录Ⅵ物质和标准摩尔生成焓标准摩尔生成吉

附录Ⅵ 物质的标准摩尔生成焓、标准摩尔生成吉布斯函数、标准摩尔熵和摩尔热容(100kPa)>

(1)单质和无机物

物质Δf H m (298.15

K)

Δf G m (298.15

K)

S m (298.1

5K)

C p,m (298.15K

) kJ·mol-1kJ·mol-1J·K-1mol-1J·K-1·mol-1

Ag(s)0042.71225.48 Ag2CO3(s)-506.14-437.09167.36

Ag2O(s)-30.56-10.82121.7165.57 Al(s)0028.31524.35 Al(g)313.80273.2164.553

Al2O3-α-1669.8-2213.160.98679.0 Al2(SO4)3(s)-3434.98-3728.53239.3259.4 Br2(g)111.88482.396175.021

Br2(g)30.71 3.109245.45535.99 Br2(l)00152.335.6 C(g)718.384672.942158.101

C(金刚石) 1.896 2.866 2.439 6.07 C(石墨)00 5.6948.66 CO(g)-110.525-137.285198.01629.142 CO2(g)-393.511-394.38213.7637.120 Ca(s)0041.6326.27 CaC2(s)-62.8-67.870.262.34 CaCO3(方解

石)

-1206.87-1128.7092.881.83

CaCl2(s)-795.0-750.2113.872.63 CaO(s)-635.6-604.239.748.53 Ca(OH)2(s)-986.5-896.8976.184.5 CaSO4(硬石

膏)

-1432.68-1320.24106.797.65

Cl-(aq)-167.456-131.16855.10

Cl2(g)00222.94833.9 Cu(s)0033.3224.47 CuO(s)-155.2-127.143.5144.4 Cu2O-α-166.69-146.33100.869.8 F2(g)00203.531.46 Fe-α0027.1525.23

FeCO3(s)-747.68-673.8492.882.13 FeO(s)-266.52-244.354.051.1 Fe2O3(s)-822.1-741.090.0104.6 Fe3O4(s)-117.1-1014.1146.4143.42 H(g)217.94203.122114.72420.80 H2(g)00130.69528.83 D2(g)00144.88429.20 HBr(g)-36.24-53.22198.6029.12 HBr(aq)-120.92-102.8080.71

HCl(g)-92.311-95.265186.78629.12 HCl(aq)-167.44-131.1755.10

H2CO3(aq)-698.7-623.37191.2

Hl(g)-25.94-1.32206.4229.12 H2O(g)-241.825-228.577188.82333.571 H2O(l)-285.838-237.14269.94075.296 H2O(s)-291.850(-234.03）(39.4）

H2O2(l)-187.61-118.04102.2682.29 H2S(g)-20.146-33.040205.7533.97 H2SO4(l)-811.35(-866.4）156.85137.57 H2SO4(aq)-811.32

HSO4(aq)-885.75-752.99126.86

l2(g)00116.755.97 I2(g)62.24219.34260.6036.87 N2(g)00191.59829.12 NH3(g)-46.19-16.603192.6135.65 NO(g)89.86090.37210.30929.861 NO2(g)33.8551.86240.5737.90 N2O(g)81.55103.62220.1038.70 N2O4(g)9.66098.39304.4279.0 N2O5(g) 2.51110.5342.4108.0 O(g)247.521230.095161.06321.93 O2(g)00205.13829.37 O3(g)142.3163.45237.738.15 OH-(aq)-229.940-157.297-10.539

S(单斜)0.290.09632.5523.64

S(斜方)0031.922.60

(g)124.9476.08227.7632.55

S(g)222.80182.27167.825

SO2(g)-296.90-300.37248.6439.79 SO3(g)-395.18-370.40256.3450.70 SO42- (aq)-907.51-741.9017.2

(2)有机化合物

物质Δf H m (298.15K)Δf G m (298.15K)

S m (298.15K

)

C

p

,

m

(

2

9

8

.

1

5

K

) kJ·mol-1kJ·mol-1J·K-1mol-1

J

·

K

-

1

·

m

o

l

-

1烃类

CH4(g), 甲烷-74.84750.827186.303

5

.

7

1

5 C2H2(g), 乙炔226.748209.200200.9284

.

9

2

8 C2H4(g), 乙烯52.28368.157219.564

3

.

5

6 C2H6乙烷-84.667-32.821229.605

2

.

6

5

0 C3H6(g), 丙烯20.41462.783267.056

3

.

8

9 C3H6(g), 丙烷-103.847-23.391270.027

3

.

5

1 C4H6(g), 1,3-丁二烯110.16150.74278.857

9

.

5

4 C4H8(g), 1-丁烯-0.1371.60305.718

5

.

6

5 C4H8(g), 顺-2-丁烯-6.9965.96300.947

8

.

9

1 C4H8(g), 反-2-丁烯-11.1763.07296.598

7

.

2 C4H8(g), 2-甲基两烯-16.9058.17293.708

9

.

1

2 C4H10(g), 正丁烷-126.15-17.02310.239

7

.

4

5 C4H10(g), 异丁烷-134.52-20.79294.759

6

.

8

2 C6H6(g), 苯82.927129.723269.318

1

.

6

7 C6H6(l), 苯49.028124.597172.351

3

5

.

7

7 C6H12(g), 环己烷-123.1431.92298.511

6

.

2

7 C6H14(g), 正己烷-167.19-0.09388.851

4

3

.

9 C6H14(l), 正己烷-198.82-4.08295.891

9

4

.

3 C6H5CH3(g),甲苯49.999122.388319.861

3

.

7

6 C6H5CH3(l),甲苯11.995114.299219.581

5

7

.

1

1 C6H4(CH2）邻二甲苯18.995122.207352.861

3

3

.

2

6 C6H4（CH3）2(l), 邻二甲苯-24.439110.495246.481

8

7

.

9 C6H4（CH3）2间二甲苯17.238118.977357.801

2

7

.

5

7 C6H（CH3）2（l), 间二甲苯-25.418107.817252.171

8

3

.

3 C6H4（CH3）2对二甲苯17.949121.266352.531

2

6

.

8

6 C6H4（CH3）2(l), 对二甲苯-24.426110.244247.361

8

.

7

含氧化合物

HCOH(g), 甲醛-115.90-110.0220.23

5

.

3

6 HCOOH(g), 甲酸-362.63-335.69251.15

4

.

4 HCOOH(l), 甲酸-409.20-345.9128.959

9

.

4 CH3OH(g), 甲醇-201.17-161.83237.84

9

.

4 CH3OH(l), 甲醇-238.57-166.15126.88

1

.

6 CH2COH(g), 乙醛-166.36-133.67265.86

2

.

8 CH3COOH(l), 乙酸-487.0-392.4159.81

2

3

.

4 CH3COOH(g), 乙酸-436.4-381.5293.47

2

.

4 C2H5OH(l), 乙醇-277.63-174.36160.71

1

1

.

4

C2HOH(g), 乙醇-235.31-168.54282.17

1

.

1 CH3COCH3（l),丙酮-248.283-155.33200.01

2

4

.

7

3 CH3COCH3(g),丙酮-216.69-152.2296.007

5

.

3 C2H5OC2H5(l),乙醚-273.2-116.47253.1

CH3COOC2H5(l), 乙酸乙酯-463.2-315.3259

C6H5COOH（s), 苯甲酸-384.55-245.5170.71

5

5

.

2

卤代烃

CH3Cl(g), 氯甲烷-82.0-58.6234.294

.

7

9 CH2Cl2(g), 二氯甲烷-88-59270.625

1

.

3

8 CHCl3（l), 氯仿-131.8-71.4202.91

1

6

.

3 CHCl3(g), 氯仿-100-67296.486

5

.

8

CCl4(l), 四氯化碳-139.3-68.5214.431

3

1

.

7

5 CCl4(g), 甲氯化碳-106.7-64.0309.418

5

.

5

1 C6H5Cl(l), 氯苯116.3-198.2197.51

4

5

.

6

含氮化合物

NH（CH3）2(g), 二甲胺-27.659.1273.26

9

.

3

7 C5H5N(l), 吡啶78.87159.9179.1

C6H5NH2(l), 苯胺35.31153.35191.61

9

9

.

6 C6H5NO2，(l)硝基苯15.90146.36244.3

本附录数据主要取自Handbook of Chemistry and Physics, 70 th Ed., 1990; Editor John A.Dean,Lange's Handbook of Chemistry, 1967。