Pierre Belloir PE100燃气管道发展的趋势 标准宣贯会 苏州 2015年9月

苏州，2015年9月PE100, 燃气管道材料的发展趋势WHAT IS IT ABOUT ? 关于PE100+ GLOBALIZATION 全球化HIGH QUALITY 高质量CONSISTENCY 一致性DURABILITY 耐久性SUSTAINABILITY 可持续COLLABORATION 合作INNOVATION 创新PROMOTION 推广Founding Scope of PE100+ AssociationPE100+ 协会的宗旨•Welcome any polyethylene manufacturer whose materials comply with the enhanced requirements of the PE100+ Association•欢迎任何符合PE100+协会要求的PE原料供应商加入•Establish a quality label for PE100+ products•建立PE100+产品质量标签•Assure consistent quality at the highest level in the production and application of PE100 pipe materials•确保PE100管道材料生产和应用的高品质和一致性•Promote usage of PE piping systems in general•推广PE管道系统的应用•Focus towards end-users with more information support•关注终端用户，提供更多的信息支持PE100+ Association •Founded on 24th February, 1999 by Borealis, Elenac and Solvay•1999年2月24日，由Borealis, Elenac 和 Solvay发起成立•Consisting of ELEVEN member companies currently – Total，Borealis, Borouge, Ineos, IRPC, LyondellBasell, Prime Polymer, SABIC, SCG Chemicals,Sinopec and Tasnee•目前有11家会员，Total，Borealis, Borouge, Ineos, IRPC, LyondellBasell, Prime Polymer, SABIC, SCG Chemicals, Sinopec and Tasnee•Supported by Advisory Committee and working closely with other associations •由顾问委员会技术支持，与行业协会紧密合作11 家会员单位???20132001 2004 2006 2015WHERE ARE OUR TODAY MEMBERS ? 会员的分布Founding Scope of PE100+ Association •Welcome any polyethylene manufacturer whose materials complywith the enhanced requirements of the PE100+ Association•Establish a quality label for PE100+ products•建立PE100+产品质量标签•Assure consistent quality at the highest level in the production and application of PE100 pipe materials•Promote usage of PE piping systems in general•Focus towards end-users with more information supportProperty 性能Test Method测试方法EN/ISO StandardRequirement标准要求PE 100+RequirementPE 100+要求Creep Rupture Strength耐蠕变Internal pressure test at20°C and 12.0 MPaISO 116720℃/12.0MPa静液压> 100 h > 200 hStress Crack Resistance (SCG)耐慢速裂纹增长Pipe notch test at 80°C and9.2 barISO 13479管材切口实验> 500 h > 500 hResistance to Rapid Crack Propagation (RCP)快速裂纹扩展S4 test at 0°CISO 13477Pc> MOP/2,4 – 13/18Pc: critical pressureMOP: max. operat.pressure> 10 barTechnical Requirements技术要求All tests are performed on 110 mm SDR 11 pipes 所有测试所用样品规格为dn110/SDR11is the PE100+ Administrator是PE100+的管理者- Selecting the testing organizations (today 6)-选择测试机构（目前有6家）-Organising the regular rounds-组织定期的测试-Collecting pipe samples-收集管材样品-Dispatching them to testing selected testing labs-把样品分配到各个指定的测试实验室-Gathering results-收集测试结果-Informing the PE100+ Board about the conclusions-向PE100+委员会报告结论PE 100+ Manufacturer 生产商Every 10 months 每10个月15 pipes 15个管材样品AdministratorKIWAPositive ListPE100+ Association列入PE100+清单AdministratorKIWAResultsTGM, JanalabInternal Pressure Test静液压测试Exova, IIP, JanalabNotch Test管材切口实验Becetel, JanalabS4 Test快速裂纹扩展实验（S4）Each 5 pipes各5根管材PE100+ Quality Materials The following 32 products met the PE100+ requirements (Valid until December 2015) 截至2015年12月，符合PE100+性能要求的产品有32个TASNEEOur new website is up and runningsince mid 2013自2013年中期启用新的网站Life Time of Human Beings人类的寿命•Theoretically men can easily exceed a life time of 100 and reach close to 120 years •理论上人类轻而易举就能够活到100岁甚至120岁•But what are the determining factors for the life time of humans? •影响人类寿命的主要因素是什么呢？•Good health 健康状况 •Hormones 荷尔蒙Gene Pool一般因素 •Pollution 污染•Hygienic conditions 卫生条件 Environment环境 •Nutrition 营养状况•Smoking, alcohol, drugs 烟、酒、药物•Sports 运动Life Style 生活方式•Accidents 意外•War, violence 战争、暴力事件 •Natural disaster 自然死亡Unforeseen 不可预知因素Life Time of HDPE Pipes•How is that translated into pipes made from HDPE? •对于管道而言，又有哪些影响因素呢•Polymer morphology 聚合物结构形态 •Additivation 助剂Gene Pool 一般因素 •External temperature 外部温度 •UV irradiation 紫外线辐射•Installation conditions 安装条件Environment环境 •Aggressive media 腐蚀性介质•Pressure, excessive stress 压力，过载的应力 •Media temperatureLife Style生活方式 •External damage 外部损伤 •Violence 野蛮施工•Natural disaster 自然死亡Unforeseen 不可预知的因素Three different failure mechanisms can be observed: failure by slow crack growth可以观察到的3种不同破坏模式：慢速裂纹增长导致破坏20°C80°Cbrittle/ductile crack脆性/韧性破坏The Process of Slow Crack Growth慢速裂纹增长的过程银纹引发微纤伸长形成裂纹导致开裂连接链分子连接链分子连接链分子解缠破坏示意图Pictures from Crazing Region in PE during Slow Crack Growth(1) PE裂纹慢速增长区的图片(1) MichlerFailure Mechanisms破坏机理•Phase I ductile failure•第一阶段/韧性破坏»strain over and above the yield point of a resin 应变超过了材料的屈服点»high crystallinity and rigidity are required»需要有较高的结晶度和刚性•Phase II failure by slow crack growth•第二阶段慢速裂纹增长的破坏»distanglement of the tie molecules»连接链分子的解缠»high degree of branching of the long molecules is required»需要有大量的长支链Test Method for Slow Crack Growth – Notch Test in Accordance to ISO 13479 慢速裂纹增长性能的测试方法—ISO13479管堵沿管周均匀分布的4道切口切刀切口深度切口深度管壁厚度切口长度1×d n 切口剩余壁厚为管材壁厚的0.78-0.821Pipe Specimen Failing the Notch TestDetermination of environmental stress crack resistance –FNCT in accordance to ISO 16770 耐环境应力性能测试—全切口蠕变实验- FNCT -- ISO 16770Determination of environmental stress crack resistance –FNCT in accordance to ISO 16770 耐环境应力性能测试—全切口蠕变实验- FNCT -- ISO 16770FNCT test rigStress Distribution: Comparison Butt welded pipe/FNCT Sample应力分布的比较：管材对焊/FNCT 样条Tensile loadon an FNCT sampleTensile load on a butt welded specimen: qualitative tensile stress distribution acc. to FEM - Calculation (Becetel)Why is the Resistance to Slow Crack Growth Important? 为什么耐慢速裂纹增长性能如此重要TRENDS : toward PE100RC趋势：PE100-RC GLOBALIZATION 全球化HIGH QUALITY 高质量CONSISTENCY 一致性DURABILITY 耐久性SUSTAINABILITY 可持续COLLABORATION 合作INNOVATION 创新PROMOTION 推广Founding Scope of PE100+ Association •Welcome any polyethylene manufacturer whose materials complywith the enhanced requirements of the PE100+ Association•Establish a quality label for PE100+ products•Assure consistent quality at the highest level in the production and application of PE100 pipe materials•Promote usage of PE piping systems in general•推广应用聚乙烯管道系统•Focus towards end-users with more information supportThe global PE100+ Footprint PE100+足迹Participation in Conferences, Roadshows, annual meeting•As member of PPCA 中国塑料加工协会会员•PE100+ in conference opening•开幕致词•Together with PPI, TEPPFA and PVC4pipes •与PPI 、TEPPFA 和 PVC4pipes»PE100+ also sponsored 2 papers»提供2篇论文•Comparing PE100 and PE4710•比较PE100 和 PE4710的异同•Alternative SCG method•其他测试SCG的方法Plastic Pipes XVII Chicago第17届管道会议2020 VISION : BECOME MORE GLOBAL ACTION PLAN TO ATTRACT NEW MEMBERS 2020愿景：全球化计划，吸引更多会员CONTINUE PROMOTION IN ASIA, ME, AFRICAPROACTIVELY ATTRACT NEW MEMBERS继续在亚洲、中东、非洲的推广积极吸纳新会员Approach taken•19 potential candidates identified, mainly from Asia, based on PE100 materials having beensuccessfully tested according to ISO 9080•已有19家企业候选，主要来自亚洲，这些企业的PE100材料成功完成了ISO9080测试Addressing technical issues of the Pipe industry 关注管道行业的技术问题•Support development of new SCG methods •支持SCG新方法的开发•Develop a software with PPI•与PPI合作开发软件•Write a HDD Technical guideline with Dowley •与Dowley合作编写HDD技术指南•Microbial growth LEADER SPONSORCOLLABORATIONFounding Scope of PE100+ Association •Welcome any polyethylene manufacturer whose materials complywith the enhanced requirements of the PE100+ Association•Establish a quality label for PE100+ products•Assure consistent quality at the highest level in the production and application of PE100 pipe materials•Promote usage of PE piping systems in general•Focus towards end-users with more information support•关注终端用户，提供更多信息支持Projects for Sustainability 可持续发展项目LCA/EPD on large diameter pipes大口径管道LCA/EPD 寿命/环境影响分析Addressing the Pipe industry关注管道行业Technical Projects 技术项目 Welding of large diameter pipe大口径管材的焊接HDD Technical GuideHDD 技术指南COMPARISON DN400 PE100 vs DUCTILE IRON DN400 PE100和铸铁管的比较Butt-fusion Project 焊接项目Program now completed 已完成项目•Lifetime of butt-fusion welds made by the three procedures is predicted to be in excess of 100 years.•用这3种方法焊接的接头，预期寿命超过100年•Tests demonstrate that good performance welds were obtained by the three procedures, with no deterioration of performance over the thickness rangeof 30 mm to 70 mm.•用这3种方法能够实现很好的焊接，适用的壁厚范围30 mm -70 mm•The short term tests used are capable of characterising welds and detecting brittle welds of unacceptable quality.•短期测试可用于评价焊点的特征，并检测到不合格的脆性焊点Common Target of all Endeavours共同的目标•Spread the message of highest quality PE pipingsystems•推广发布高质量聚乙烯管道系统的资讯•Create trust in these systems•建立聚乙烯管道系统的品质信任PE100+ ASSOCIATION Contact Tel: : +33 6 49 38 99 71E-mail: Mf.bottin@plastiem.eu Internet : Mrs Marie-Francoise BOTTIN。