2016复旦大学化学系物理化学考研真题(完整版)凯程首发

2016复旦大学化学系物理化学考研真题(完整版)凯程首发

凯程考研集训营,为学生引路,为学员服务!

第 1 页 共 1 页 2016复旦化学系物理化学考研真题(完

整版)凯程首发

刚考完2016考研初试,凯程教育的电话瞬间变成了热线,同学们兴奋地汇报自己的答题情况,几乎所有内容都在凯程考研集训营系统训练过,所考专业课难度与往年相当,答题的时候非常顺手,相信凯程的学员们对此非常熟悉,预祝亲爱的同学们复试顺利。考研分笔试、面试,如果没有准备,或者准备不充分,很容易被挂掉。如果需要复试的帮助,同学们可以联系凯程老师辅导。

下面凯程老师把专业的真题全面展示给大家,供大家估分使用,以及2017年考研的同学使用,本试题凯程首发!

一、 简答题

1. 具体阐述洪特规则

2. 简述slater 行列式的意义

3. 统计热力学的基本假设是什么

4. 化学势的定义?其引出解决了热力学的哪些问题?

5. 当反应体系中不止一个产物时,怎样利用热力学和动力学因素加以选择和判断?

二、 计算和讨论题

1. (1)CO 和H2O 都可以与金属原子形成配位键,但是前者与金属间的键更强,为什么?(2)CO 可以与两金属原子形成桥连键,也可以与金属原子形成端位键,哪一种键的振动频率更大?为什么?

2. 具体列出了金刚石两原子间的距离和密度,(1)假设金刚石是密堆积,且为立方面心,计算出其密度,解释为何和实际密度不一样?(2)现已知道金刚石一个晶胞中含有8个C 原子,则(111)晶面间距是多少?

3. 学习指导15-5原题

4. 学习指导11-22原题

5. 学习指导12-62原题

6. 复旦期末卷子的一道证明题:

合成氨的反应机理:

N2+2(Fe)→2N(Fe) (1)速控(k1)

N(Fe)+3/2H2→NH3+(Fe) (2)对峙(正向k2,逆向k-2)

假定(Fe)和N(Fe)的浓度之和为常数,试证明:

file:///C:/Users/lenovo/AppData/Local/Temp/msohtmlclip1/01/clip_image002.png (word 下的公式没法黏贴到这里,想要word 文档的可以加我)

(式中K=k-2/k2,k 为常数)

7. 给出了乙烯水合反应的标准吉布斯反应自由能变与温度的关系式,(1)求标准反应焓变与温度的关系式(2)求再T=573K 时的平衡常数(3)求T=573K 时的标准反应熵变

Ps.这道题可以参考学习指导14-39,知识点是类似的

2016年考研英语一真题及答案

2016 年全国硕士研究生入学统一考试英语(一) 真题及答案(完整版) Text 1 France, which prides itself as the global innovator of fashion, has decided its fashion industry has lost an absolute right to define physical beauty for woman. Its lawmakers gave preliminary approval last week to a law that would make it a crime to employ ultra-thin models on runways. The parliament also agreed to ban websites that" incite excessive thinness" by promoting extreme dieting. Such measures have a couple of uplifting motives. They suggest beauty should not be defined by looks that end up with impinging on health. That's a start. And the ban on ultra-thin models seems to go beyond protecting models from starring themselves to health -as some have done. It tells the fashion industry that it move take responsibility for the signal it sends women, especially teenage girls, about the social tape -measure they must use to determine their individual worth. The bans, if fully enforced ,would suggest to woman (and many men )that they should not let others be orbiters of their beauty .And perhaps faintly, they hint that people should look to intangible qualities like character and intellect rather than dieting their way to sine zero or wasp-waist physiques . The French measures, however, rely too much on severe punishment to change a culture that still regards beauty as skin-deep-and bone-showing. Under the law, using a fashion model that does not meet a government-defined index of body mess could result in a $85,000 fine and six months in prison. The fashion industry knows it has an inherent problem in focusing on material adornment and idealized body types. In Denmark, the United States, and a few other countries, it is trying to set voluntary standard for models and fashion images there rely more on pear pressure for enforcement. In contrast to France's actions, Denmark's fashion industry agreed last month on rules and sanctions regarding age, health, and other characteristics of models .The newly revised Danish Fashion Ethical charter clearly states, we are aware of and take responsibility for the impact the fashion industry has on body ideals, especially on young people. The charter's main toll of enforcement is to deny access for designers and modeling agencies to Copenhagen. Fashion week, which is men by the Danish Fashion Institute .But in general it relies on a name-and -shame method of compliance. Relying on ethical persuasion rather than law to address the misuse of body ideals may be the best step. Even better would be to help elevate notions of beauty beyond the material standards of a particular industry. 21. According to the first paragraph, what would happen in France [A] Physical beauty would be redefined [B] New runways would be constructed

复旦大学物理化学考研复试内容复试面试问题复试备考经验

前天刚刚复试结束,现在已经成功上岸,所以想趁着自己还有记忆,来介绍一下自己的学习经验和复试经历,以供后面的学弟学妹参考,让大家少走弯路,早日实现梦想。文笔不好请大家见谅,理工生真的是有什么说什么的。 复试 我也做了很多准备,大多也是参照了网上学长学姐的经验贴。 1.我报的是物化,所以只把物化书本看了2遍,把重点习题做了一遍,做习题的原因是单看书太无聊了,而且不动脑感觉有些东西你总想不起来,思路不像刚考初试那样活跃。 2.买了一本复旦用的物化实验书,网上买的二手10来块钱。每个方向都重点看了2个实验,比如热力学看了饱和蒸汽压的测量、气液相图绘制,动力学方向看了旋光法测蔗糖转化的反应速率等等,我总共看了8个左右。 3.了解之前联系的老师的研究方向,我这个真的做了大量工作,把老师实验室近一年发表的所有文章看了,把里面涉及到的仪器的原理啥的都弄懂,查了这个课题的前沿、国内外发展情况,就连老师获奖的新闻我都翻遍了。 4.所有谱学。分子光谱(包括紫外,红外,微波,拉曼)全部原理、应用,都看了3遍。能谱(AES、XPS、UPS、LEED)全部原理、应用,3遍。衍射谱(我只看了XRD)原理、应用。波谱(核磁共振、顺磁共振ESR)原理、应用,3遍。 5.注意观察一下复旦老师发文章喜欢发的期刊,查一下所属机构,影响因子。 6.我初试报了表面化学与催化方向,我查了这个方向的研究进程、现代表面化学的研究内容、以后的研究方向、国内外发展情况,查了一下历史上有哪位是搞这个方向而获得诺贝尔化学奖的科学家。 7.毕业设计(多了解一些,特别是往届的,老师超爱问)

8.英语口语,自我介绍我准备了两个版本,2分钟版和4分钟版。而且还提前练了半个月雅思,每天练习对话2小时。准备了15个日常生活的话题,后来练了几天,发现无论讲啥话题我都可以噼里啪啦讲一大堆了,就差不多了。而且我每天晚上洗澡,都很喜欢自己给自己想话题,然后对着淋浴头说个20分钟哈哈哈哈。 这里提醒大家,在复习备考的时候不要只顾闷头苦学,还要多多分析自己的专业情况,比如分数线、报录比,复试通知、复试流程等各个重要时间点都要重视起来,这些信息推荐以后查询鸿知复旦考研网,都有总结好,非常节省搜集整理信息的时间,建议大家加入收藏夹,经常访问查阅。有问题也可以咨询老师和学姐,人都挺好的,他们做复旦比较久了,资料和专业课的班也是信得过的,我有的同学是经过他们的培训的。 我今年复试的情况: 其实每个人问的都不一样,我这个只能作为参考。首先英语自我介绍,介绍完了,老师就说,你们快提问吧,中英文都可以,果不其然,一个老师用英语提问了,问我最近读过的文献(因为我自我介绍说读过一些文献),我就劈哩啪啦说了一下,另外一个老师又用英文问这个文献出自哪个期刊。后面的问题都是围绕我的毕业设计,问的原理好深啊,有些我都答不出来,然后我就回答了其他相近的方面。还问了光谱的原理,活化能怎么求,家庭主妇做饭为什么要点火(我从自由能、活化能方面答都没对),后来老师自己说了是自由基支链反应。好吧。。。反正整个过程还是比较愉悦的,因为我是比较爱笑的那种人,无论回答得出回答不出我都是在全程微笑,所以也比较放得开和老师交流。我只能说有些问题我能回答我就多说一点,不能回答我就说不知道。 好了,就写这么多了。欢迎各位学弟学妹来报考复旦。复旦是个很干净的地方,初试复试都很公平公正,没有任何歧视。大家如果还不知道怎么准备复试的,最好还是报一个鸿知复旦考研网的辅导班吧,由研究生学长学姐一对一辅导,可以让复习备考更有针对性,告别

2014年复旦大学431金融学综合[专业硕士]考研真题(含部分答案)【圣才出品】

2014年复旦大学431金融学综合[专业硕士]考研真题(含部分答案) 一、名词解释(5分×5=25分) 1.IPO折价 答:略。 2.消极投资策略 答:略。 3.金融深化 答:金融深化是指为实现经济迅速增长而必须实现一系列的金融自由化的政策。核心是促进实际货币需求的增长,其内容包括:取消不恰当的利率限制;控制名义货币的增长率;放松汇率限制;财政改革;放松对金融业过多的限制,允许金融机构之间开展竞争;大力发展各类金融市场,增加金融工具等。理论贡献有:①强调了金融体制和政策在经济发展中的核心地位,第一次把金融和经济发展密切结合起来;②批判了传统的经济理论,主张发展中国家的货币和实物资本具有互补性;③剖析了外源性融资的危害,主张发展中国家应依靠内源性融资;④主张发展中国家应注意促进中小企业的改造和提高,而不能只重视大企业。 4.杠杠收购

5.熊猫债券 答:略。 二、选择题(5分×5=25分) 1.久期最长的是()。 A.8年期零息债券 B.8年期,息票率为8% C.10年期零息债券 D.10年期,息票率为8% 【答案】C 【解析】久期定理:①只有贴现债券的久期等于它们的到期时间;②直接债券的久期小于或等于它们的到期时间。 2.有关普通股、优先股的股东权益不正确的是()。 A.普通股有公司的经营权 B.优先股一般不享有经营权 C.普通股不可退股

【答案】D 【解析】优先股股东不能要求退股,却可以依照优先股股票上所附的赎回条款,由股份有限公司予以赎回。 3.偿债率()。 A.外债余额/国内总值 B.外债余额/国民总值 C.外债余额/出口外汇收入 D.外债还本付息额/出口外汇收入 【答案】D 【解析】偿债率是指当年还本付息额占当年出口收入的比重。 4.不是我国货币M2统计口径()。 A.企业活期 B.企业定期 C.居民储备存款 D.商业票据 【答案】D 【解析】我国对货币层次的划分是:

2016考研英语二真题:小作文解析

2016考研英语二真题:小作文解析 Suppose you won a translation contest and your friend Jack wrote an email to congratulate you, and ask advice on translation. Write him a reply to 1)thank him; 2)give your advice. You should write neatly on the ANWSER SHEET. Do not sign you own name at the end of the letter, use “Li Ming ” instead. Do not write the address .(10 point) 如大家所见,这是2016年英语二小作文题目。英语(二)考纲的写作部分,其实主 要考查学生的应用能力,考查范围包括私人和公务信函、备忘录、报告等,还应能写一般 描述性、叙述性和说明或议论性的文章;而要求考生根据所给情景写出一篇约100词(标 点符号不计算在内)的应用性短文。 作为写作B部分的小作文总分10分,大家要抓住得分点。小作文在评分时有如下评分 要点:1.信息点——覆盖全面;2.内容——组织连贯;3.语言——准确性;4.格式——符 合要求;5.语域——恰当。 不出所料,今年英语二的小作文再次考查了书信体,并且考查的信件可以说是杂糅型的。这在2011年英语二中出现了同样的考查方式: Suppose your cousin LI MING has just been admited to a university write him/her a letter to: (1)Congratulate him/her,and (2)give him/her suggestions on how to get prepared for university life You should write about 100 words on ANSWER SHEET 2. DO not sign your own name at the end of the letter,Use zhangwei. 同样的考查方式,足以说明一件事情——绝对要重视考研真题。跨考教育英语教研室 的老师总在强调真题的重要性,希望大家以后一定要强化这种认识。 下面我们来详细解读下今年的小作文,首先看一下题目要求: 称呼: Dear Jack注意称呼中,后面的逗号不可丢,也不能写成冒号。 正文 建议大家三步走策略——简洁、直接、明了:写作目的、写作是由、重申目的第一段:写作内容需涵盖两点:写信目的,表明感谢来自朋友的祝贺;可以采用这样 的表达方式:I’m writing to express my gratitude for your congratulation on my success in the translation contest. 第二段:写作内容应以建议为主体。在这个过程中可以把日常我们如何提高的方式写 进正文,如讲究学习方式、注重坚持、多多接触外文文化及语境。那本篇老师主要从前两 个方面进行论述,表达如下:As regard to my experience, I would like to offer you some proposals in this part. At the top of list is the persistence due to the fact that you could deserve the position after days or years of efforts that you have had in the field. What’s more, you are supposed to pay more attention to the way in which you finish your major, for it plays a significant role in the process. 第三段:再次强调重申写信目的,如Thanks again and I do hope that my suggestions can be in favor of your future study. 落款: Yours sincerely, 特别提醒sincerely后面逗号不能丢;签名: Li Ming特别注 意 Ming 后面一定不能出现句点。

2018年复旦大学化学系物理化学 [070304]考试科目、参考书目、复习指导

2018年复旦大学化学系物理化学 [070304]考试科目、参考书目、 复习经验 一、招生信息 所属学院:化学系 所属门类代码、名称:理学[07] 所属一级学科代码、名称:化学[0703] 二、研究方向 01 (全日制)表面化学与催化 02 (全日制)复相催化 03 (全日制)电极过程和高能化学电源 04 (全日制)量子化学与分子模拟 05 (全日制)化学反应动力学和激光化学 06 (全日制)结构化学 07 (全日制)光化学和反应动力学 08 (全日制)分子筛催化和功能材料 09 (全日制)固态材料化学 10 (全日制)工业催化 11 (全日制)新型化学电源 三、考试科目 01、02、03、06、07、08、09、10、11方向:①101思想政治理论 ②201英语一 ③721物理化学(含结构化学) ④837有机化学或838无机化学和分析化学 04、05方向组1:①101思想政治理论 ②201英语一 ③721物理化学(含结构化学) ④837有机化学或838无机化学和分析化学

或组2:①101思想政治理论 ②201英语一 ③720量子力学 ④836普通物理 四、复习指导 一、参考书的阅读方法 (1)目录法:先通读各本参考书的目录,对于知识体系有着初步了解,了解书的内在逻辑结构,然后再去深入研读书的内容。 (2)体系法:为自己所学的知识建立起框架,否则知识内容浩繁,容易遗忘,最好能够闭上眼睛的时候,眼前出现完整的知识体系。 (3)问题法:将自己所学的知识总结成问题写出来,每章的主标题和副标题都是很好的出题素材。尽可能把所有的知识要点都能够整理成问题。 二、学习笔记的整理方法 (1)第一遍学习教材的时候,做笔记主要是归纳主要内容,最好可以整理出知识框架记到笔记本上,同时记下重要知识点,如假设条件,公式,结论,缺陷等。记笔记的过程可以强迫自己对所学内容进行整理,并用自己的语言表达出来,有效地加深印象。第一遍学习记笔记的工作量较大可能影响复习进度,但是切记第一遍学习要夯实基础,不能一味地追求速度。第一遍要以稳、细为主,而记笔记能够帮助考生有效地达到以上两个要求。并且在后期逐步脱离教材以后,笔记是一个很方便携带的知识宝典,可以方便随时查阅相关的知识点。 (2)第一遍的学习笔记和书本知识比较相近,且以基本知识点为主。第二遍学习的时候可以结合第一遍的笔记查漏补缺,记下自己生疏的或者是任何觉得重要的知识点。再到后期做题的时候注意记下典型题目和错题。 (3)做笔记要注意分类和编排,便于查询。可以在不同的阶段使用大小合适的不同的笔记本。也可以使用统一的笔记本但是要注意各项内容不要混杂在以前,不利于以后的查阅。同时注意编好页码等序号。另外注意每隔一定时间对于在此期间自己所做的笔记进行相应的复印备份,以防原件丢失。统一的参考书书店可以买到,但是笔记是独一无二的,笔记是整个复习过程的心血所得,一定要好好保管。

2016年考研管理类联考英语二真题.pdf

2016年考研管理类联考英语二真题

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