高分子材料专业英语第二版部分答案2(供参考)(精品文档)

高分子材料专业英语第二版部分答案2(供参考)(精品文档)
高分子材料专业英语第二版部分答案2(供参考)(精品文档)

unit1

1.Not all polymers are built up from bonding together a single kind of repeating unit. At the other extreme ,protein molecules are polyamides in which n amino acide repeat units are bonded together. Although we might still call n the degree of polymerization in this case, it is less usefull,since an amino acid unit might be any one of some 20-odd molecules that are found in proteins. In this case the molecular weight itself,rather than the degree of the polymerization ,is generally used to describe the molecule. When the actual content of individual amino acids is known,it is their sequence that is of special interest to biochemists and molecular biologists.并不是所有的聚合物都是由一个重复单元链接在一起而形成的。在另一个极端的情形中,蛋白质分子是由n个氨基酸重复单元链接在一起形成的聚酰胺。尽管在这个例子中,我们也许仍然把n称为聚合度,但是没有意义,因为一个氨基酸单元也许是在蛋白质中找到的20多个分子中的任意一个。在这种情况下,一般是分子量本身而不是聚合度被用来描述这个分子。当知道了特定的氨基酸分子的实际含量,它们的序列正是生物化学家和分子生物学家特别感兴趣的地方。

1,题目:Another striking ...答案:.that quantity low saturation bottom much absorb

2. 乙烯分子带有一个双键,为一种烯烃,它可以通过连锁聚合大量地制造聚乙烯,目前,聚乙烯已经广泛应用于许多技术领域和人们的日常生活中,成为一种不可缺少的材料。

Ethylene molecule with a double bond, as a kind of olefins, it can make chain polymerization polyethylene, at present, polyethylene has been widely used in many fields of technology and People's Daily life, become a kind of indispensable materials.

Unit3

1 The polymerization rate may be experimentally followed by measuring the changes in any of several properties of the system such as density,refractive index,viscosity, or light absorption. Density measurements are among the most accurate and sensitive of the techniques. The density increases by 20-25 percent on polymerization for many monomers. In actual practice the volume of the polymerizing system is measured by carrying out the reaction in a dilatometer. This is specially constructed vessel with a capillary tube which allows a highly accurate measurement of small volume changes. It is not uncommon to be able to detect a few hundredths of a percent polymerization by the dilatometer technique. 聚合速率在实验上可以通过测定体系的任一性质的变化而确定,如密度、折射率、黏度、或者吸光性能。密度的测量是这些技术中最准确最敏感的。对许多单体的聚合来说,密度增加了20%-25%。在实际操作中,聚合体系的体积是通过在膨胀计中进行反应测定的。它被专门设计构造了毛细导管,在里面可以对微小体积变化进行高精确度测量。通过膨胀计技术探测聚合过程中万分之几的变化是很常见的。

Unti4

2 合成聚合物在各个领域中起着与日俱增的重要作用,聚合物通常是由单体通过加成聚合与缩合聚合制成的。就世界上的消耗量而论,聚烯烃和乙烯基聚合物居领先地位,聚乙烯、聚丙烯等属聚烯烃,而聚氯乙烯、聚苯乙烯等则为乙烯基聚合物。聚合物可广泛地用作塑料、橡胶、纤维、涂料、粘合剂等The synthetic polymers play an increasingly important role on a range of domains, which are synthesized by monomers through addition polymerization or condensation polymerization. Polyolefin and vinyl polymer have taken the lead in terms of the world consumption. PE, PP, etc. belong to the polyolefin, while PS, PVC etc. belong to the vinyl polymer. Polymers can be widely applied in plastics, rubbers, fibers, coatings, glues and so on.

Unit7

Ring-opening polymerizations proceed only by ionic mechanisms, the polymerization of cyclic ethers mainly by cationic mechanisms, and the polymerization of lactones and lactones by either a cationic or anionic mechanism. Important initiators for cyclic ethers and lactone polymerization are those derived from aluminum alkyl and zinc alkyl/water systems. It should be pointed out that substitution near the reactive group of the monomer is essential for the individual mechanism that operates effectively in specific cases; for

example, epoxides polymerize readily with cationic and anionic initiators, while fluorocarbon epoxides polymerize exclusively by anionic mechanisms.开环聚合反应只能通过离子机理进行,环醚(的开环)聚合主要通过阳离子机理,而内酯和内酰胺的聚合物是通过阳离子或阴离子机理。对于环醚和内酯型聚合物很重要的引发剂是那些来自于烷基铝和烷基锌/水的体系。应该指出的是(对于)在活性基团附近有取代的单体,只能由单一机理,(这一机理)是在特定条件下的有效操作,例如环氧聚合能用阳离子和阴离子引发剂,然而碳氟环氧化物的聚合只能是阴离子机理。

Unti8

1 Polymers can be classified into two main groups, addition polymers and ___condensation__ polymers. This classification is based on whether or not the repeating unit of the polymer contains the same atoms __as____ the monomer. The repeating unit of an addition polymer is identical _with/to____ the monomer, while condensation polymers contain __different/less___ because of formation of __compound/byproduct___ during the polymerization process. The corresponding polymerization processed would then be called addition polymerization and condensation polymerization. As was mentioned earlier, this classification can result ___in__ confusion, since it has been shown in later years that many important types of polymers can be _prepared by both addition and condensation processes. For example, polyesters, polyamides and polyurethanes are usually considered to be _condensation____ polymers, but they can be prepared by addition as well as by condensation reaction. Similarly, polyethylene normally considered an _addition_ polymer, can also be prepared by _condensation_ reaction.

2. Answer the following questions in English

(1) What is chain polymerization?

Many olefinic and vinyl unsaturated compounds are able to form chain-like macromolecules through eliminat ion of double bond.

(2) Which kinds of monomers can carry out step-growth polymerization process?

There are two kinds of monomers could carry out step-growth polymerization process. One is polyfunctional monomers and the other is a single monomer containing both types of functional groups.

(3) What properties of polymers can be based on for measuring the molecular weight?

The molecular weight of polymer could be measured based on colligative properties, light scattering, viscosity, ultracentrifugation sedimentation.

3. Please write out at least 10 kinds of polymers both in English and in Chinese

4. Please write out at least 10 kinds of monomers both in English and in Chinese and the corresponging chemical structure

Cl

F

F F COOH

乙烯 氯乙烯 丙烯 1-丁烯 丙烯腈

1,4-丁二烯 四氟乙烯 苯乙烯 异丁烯 丙烯酸

ethylene vinylchloride propylene 1- butene acrylonitrile

1,4-butadiene tetrafluoroethylene styrene isobutene acrylic acid

5 In general ,head-to-tail addition is considered to be the predominant mode of propagation in all polymerizations 。However ,when the substitutes on the monomer are small (and do not offer appreciable steric hindrance to the approaching radical) or do not have a large resonance stabilizing effect ,as in the case of fluorine atoms ,sizable amounts of head-to-head propagation may occur. The effect of increasing polymerization temperature is to increase the amount of head-to-head placement 。Increased temperature leads to less selective (more random) propagation but the effect is not large. Thus ,the head-to-head content in poly (vinyl acetate) only increases from 1.30 to 1.98 percent when the polymerization temperature in increased from 30 to 90 ℃.

通常在所有聚合物的链增长中,头-尾加成是主要方式。然而,当单体中的取代基很小(对接近的自由基没有空间阻碍)或没有较大的共振稳定作用,如氟原子,则有相当量的头头增长发生。提高聚合温度的影响是提高头-头排列的量。温度的提高导致较少的选择(更多的无规)增长,但影响不大。因而,在聚乙酸乙烯酯中,当聚合温度由30C 提高到90C ,头-头含量仅由1.3%提高到1.98%。

2.Write out an abstract in English for the text in this unit

Polymers with different structures present various properties. Usually, polymers are divided into three categories, i.e. plastic, elastomer, fiber with different initial modulus range respectively. Polymers show quite

different behaviors due to the different interchain forces in elastomer and fiber. However, with the advent of new techniques and mechanisms to improve the structure of polymers, polymers may be classified and named according to the mechanism, and their properties will largely depend on the structure.

3.Put the following words into Chinese

entanglement 纠缠irregularity 无规sodium isopropylate异丙醇钠permeability渗透性crystallite 微晶stoichiomertric balance 当量平衡fractionation分馏法light scattering光散射matrix 基体diffraction衍射

4.Put the following words into English

形态morphology 酯化esterification 异氰酸酯isocyanate

杂质impurity 二元胺diamine 转化率change ratio 多分散性polydispersity 力学性能mechanical property 构象conformation 红外光谱法infrared spectroscopy

常见聚合物命名

(1)常见杂链和元素有机聚合物类型

Polyamide ----聚酰胺. Polyester----聚酯Poly‘urethane ------聚氨酯Polysiloxane -------聚硅氧烷Phenol-formaldehyde----酚醛.Urea-formaldehyde-----脲醛Polyureas------聚脲Polysulfide -----聚硫Polyacetal-------聚缩醛Polysulfone (polysulphone)------聚砜Polyether---------聚醚

高分子材料专业英语第二版部分答案2

unit1 1.Not all polymers are built up from bonding together a single kind of repeating unit. At the other extreme ,protein molecules are polyamides in which n amino acide repeat units are bonded together. Although we might still call n the degree of polymerization in this case, it is less usefull,since an amino acid unit might be any one of some 20-odd molecules that are found in proteins. In this case the molecular weight itself,rather than the degree of the polymerization ,is generally used to describe the molecule. When the actual content of individual amino acids is known,it is their sequence that is of special interest to biochemists and molecular biologists.并不是所有的聚合物都是由一个重复单元链接在一起而形成的。在另一个极端的情形中,蛋白质分子是由n个氨基酸重复单元链接在一起形成的聚酰胺。尽管在这个例子中,我们也许仍然把n称为聚合度,但是没有意义,因为一个氨基酸单元也许是在蛋白质中找到的20多个分子中的任意一个。在这种情况下,一般是分子量本身而不是聚合度被用来描述这个分子。当知道了特定的氨基酸分子的实际含量,它们的序列正是生物化学家和分子生物学家特别感兴趣的地方。 1,题目:Another striking ...答案:.that quantity low saturation bottom much absorb 2. 乙烯分子带有一个双键,为一种烯烃,它可以通过连锁聚合大量地制造聚乙烯,目前,聚乙烯已经广泛应用于许多技术领域和人们的日常生活中,成为一种不可缺少的材料。 Ethylene molecule with a double bond, as a kind of olefins, it can make chain polymerization polyethylene, at present, polyethylene has been widely used in many fields of technology and People's Daily life, become a kind of indispensable materials. Unit3 1 The polymerization rate may be experimentally followed by measuring the changes in any of several properties of the system such as density,refractive index,viscosity, or light absorption. Density measurements are among the most accurate and sensitive of the techniques. The density increases by 20-25 percent on polymerization for many monomers. In actual practice the volume of the polymerizing system is measured by carrying out the reaction in a dilatometer. This is specially constructed vessel with a capillary tube which allows a highly accurate measurement of small volume changes. It is not uncommon to be able to detect a few hundredths of a percent polymerization by the dilatometer technique. 聚合速率在实验上可以通过测定体系的任一性质的变化而确定,如密度、折射率、黏度、或者吸光性能。密度的测量是这些技术中最准确最敏感的。对许多单体的聚合来说,密度增加了20%-25%。在实际操作中,聚合体系的体积是通过在膨胀计中进行反应测定的。它被专门设计构造了毛细导管,在里面可以对微小体积变化进行高精确度测量。通过膨胀计技术探测聚合过程中万分之几的变化是很常见的。 Unti4 2 合成聚合物在各个领域中起着与日俱增的重要作用,聚合物通常是由单体通过加成聚合与缩合聚合制成的。就世界上的消耗量而论,聚烯烃和乙烯基聚合物居领先地位,聚乙烯、聚丙烯等属聚烯烃,而聚氯乙烯、聚苯乙烯等则为乙烯基聚合物。聚合物可广泛地用作塑料、橡胶、纤维、涂料、粘合剂等The synthetic polymers play an increasingly important role on a range of domains, which are synthesized by monomers through addition polymerization or condensation polymerization. Polyolefin and vinyl polymer have taken the lead in terms of the world consumption. PE, PP, etc. belong to the polyolefin, while PS, PVC etc. belong to the vinyl polymer. Polymers can be widely applied in plastics, rubbers, fibers, coatings, glues and so on. Unit7 Ring-opening polymerizations proceed only by ionic mechanisms, the polymerization of cyclic ethers mainly by cationic mechanisms, and the polymerization of lactones and lactones by either a cationic or anionic mechanism. Important initiators for cyclic ethers and lactone polymerization are those derived from aluminum alkyl and zinc alkyl/water systems. It should be pointed out that substitution near the reactive group of the monomer is essential for the individual mechanism that operates effectively in specific cases; for

数学专业英语

数学专业英语课后答案

2.1数学、方程与比例 词组翻译 1.数学分支branches of mathematics,算数arithmetics,几何学geometry,代数学algebra,三角学trigonometry,高等数学higher mathematics,初等数学elementary mathematics,高等代数higher algebra,数学分析mathematical analysis,函数论function theory,微分方程differential equation 2.命题proposition,公理axiom,公设postulate,定义definition,定理theorem,引理lemma,推论deduction 3.形form,数number,数字numeral,数值numerical value,图形figure,公式formula,符号notation(symbol),记法/记号sign,图表chart 4.概念conception,相等equality,成立/真true,不成立/不真untrue,等式equation,恒等式identity,条件等式equation of condition,项/术语term,集set,函数function,常数constant,方程equation,线性方程linear equation,二次方程quadratic equation 5.运算operation,加法addition,减法subtraction,乘法multiplication,除法division,证明proof,推理deduction,逻辑推理logical deduction 6.测量土地to measure land,推导定理to deduce theorems,指定的运算indicated operation,获得结论to obtain the conclusions,占据中心地位to occupy the centric place 汉译英 (1)数学来源于人类的社会实践,包括工农业的劳动,商业、军事和科学技术研究等活动。 Mathematics comes from man’s social practice, for example, industrial and agricultural production, commercial activities, military operations and scientific and technological researches. (2)如果没有运用数学,任何一个科学技术分支都不可能正常地发展。 No modern scientific and technological branches could be regularly developed without the application of mathematics. (3)符号在数学中起着非常重要的作用,它常用于表示概念和命题。 Notations are a special and powerful tool of mathematics and are used to express conceptions and propositions very often. (4)17 世纪之前,人们局限于初等数学,即几何、三角和代数,那时只考虑常数。Before 17th century, man confined himself to the elementary mathematics, i. e. , geometry, trigonometry and algebra, in which only the constants were considered. (5)方程与算数的等式不同在于它含有可以参加运算的未知量。 Equation is different from arithmetic identity in that it contains unknown quantity which can join operations. (6)方程又称为条件等式,因为其中的未知量通常只允许取某些特定的值。Equipment is called an equation of condition in that it is true only for certain values of unknown quantities in it. (7)方程很有用,可以用它来解决许多实际应用问题。

高分子材料工程专业英语第二版(曹同玉)课后单词电子教案

高分子材料工程专业英语第二版(曹同玉) 课后单词

专业英语 accordion 手风琴 activation 活化(作用) addition polymer 加成聚合物,加聚物 aggravate 加重,恶化 agitation 搅拌 agrochemical 农药,化肥 Alfin catalyst 醇(碱金属)烯催化剂align 排列成行 aliphatic 脂肪(族)的 alkali metal 碱金属 allyl 烯丙基 aluminum alkyl 烷基铝 amidation 酰胺化(作用) amino 氨基,氨基的amorphous 无定型的,非晶体的anionic 阴(负)离子的antioxidant 抗氧剂 antistatic agent 抗静电剂 aromatic 芳香(族)的arrangement (空间)排布,排列atactic 无规立构的 attraction 引力,吸引 backbone 主链,骨干 behavior 性能,行为 biological 生物(学)的 biomedical 生物医学的 bond dissociation energy 键断裂能boundary 界限,范围 brittle 脆的,易碎的 butadiene 丁二烯 butyllithium 丁基锂 calendering 压延成型 calendering 压延 carboxyl 羧基 carrier 载体 catalyst 催化剂,触媒categorization 分类(法) category 种类,类型 cation 正[阳]离子 cationic 阳(正)离子的centrifuge 离心 chain reaction 连锁反应 chain termination 链终止 char 炭 characterize 表征成为…的特征 chilled water 冷冻水 chlorine 氯(气) coating 涂覆 cocatalyst 助催化剂 coil 线团 coiling 线团状的 colligative 依数性 colloid 胶体 commence 开始,着手 common salt 食盐 complex 络合物 compliance 柔量 condensation polymer 缩合聚合物,缩聚物 conductive material 导电材料conformation 构象 consistency 稠度,粘稠度contaminant 污物 contour 外形,轮廓 controlled release 控制释放controversy 争论,争议 conversion 转化率 conversion 转化 copolymer 共聚物copolymerization 共聚(合)corrosion inhibitor 缓释剂countercurrent 逆流 crosslinking 交联 crystal 基体,结晶 crystalline 晶体,晶态,结晶的,晶态的 crystalline 结晶的 crystallinity 结晶性,结晶度crystallite 微晶 decomposition 分解 defect 缺陷 deformability 变形性,变形能力deformation 形变 deformation 变形 degree of polymerization 聚合度dehydrogenate 使脱氢 density 密度 depolymerization 解聚deposit 堆积物,沉积depropagation 降解 dewater 脱水 diacid 二(元)酸 diamine 二(元)胺 dibasic 二元的 dieforming 口模成型 diffraction 衍射 diffuse 扩散 dimension 尺寸 dimensional stability 尺寸稳定性dimer 二聚物(体) diol 二(元)醇diolefin 二烯烃 disintegrate 分解,分散,分离 dislocation 错位,位错 dispersant 分散剂 dissociate 离解 dissolution 溶解 dissolve 使…溶解 distort 使…变形,扭曲 double bond 双键 dough (生)面团,揉好的面 drug 药品,药物 elastic modulus 弹性模量 elastomer 弹性体 eliminate 消除,打开,除去 elongation 伸长率,延伸率 entanglement 缠结,纠缠 entropy 熵 equilibrium 平衡 esterification 酯化(作用) evacuate 撤出 extrusion 注射成型 extrusion 挤出 fiber 纤维 flame retardant 阻燃剂 flexible 柔软的 flocculating agent 絮凝剂 folded-chain lamella theory 折叠链片晶 理论 formulation 配方 fractionation 分级 fragment 碎屑,碎片 fringed-micelle theory 缨状微束理 论 functional group 官能团 functional polymer 功能聚合物 functionalized polymer 功能聚合物 gel 凝胶 glass transition temperature 玻璃化温度 glassy 玻璃(态)的 glassy 玻璃态的 glassy state 玻璃态 globule 小球,液滴,颗粒 growing chain 生长链,活性链 gyration 旋转,回旋 hardness 硬度 heat transfer 热传递 heterogeneous 不均匀的,非均匀的 hydocy acid 羧基酸 hydrogen 氢(气) hydrogen bonding 氢键 hydrostatic 流体静力学 hydroxyl 烃基 hypothetical 假定的,理想的,有前提的 ideal 理想的,概念的 imagine 想象,推测 imbed 嵌入,埋入,包埋 imperfect 不完全的 improve 增进,改善 impurity 杂质 indispensable 不了或缺的 infrared spectroscopy 红外光谱法 ingredient 成分 initiation (链)引发 initiator 引发剂 inorganic polymer 无机聚合物 interaction 相互作用 interchain 链间的 interlink 把…相互连接起来连接 intermittent 间歇式的 intermolecular (作用于)分子间的 intrinsic 固有的 ion 离子 ion exchange resin 离子交换树 脂 ionic 离子的 ionic polymerization 离子型聚合 irradiation 照射,辐射 irregularity 不规则性,不均匀的 isobutylene 异丁烯 isocyanate 异氰酸酯 isopropylate 异丙醇金属,异丙氧化金属 isotactic 等规立构的 isotropic 各项同性的 kinetic chain length 动力学链长 kinetics 动力学 latent 潜在的 light scattering 光散射 line 衬里,贴面 liquid crystal 液晶 macromelecule 大分子,高分子 matrix 基体,母体,基质,矩阵 mean-aquare end-to-end distance 均方末端距 mechanical property 力学性能, 机械性能 mechanism 机理 medium 介质中等的,中间的 minimise 最小化 minimum 最小值,最小的 mo(u)lding 模型 mobility 流动性 mobilize 运动,流动 model 模型 modify 改性 molecular weight 分子量 molecular weight distribution 分子量分布 molten 熔化的 monofunctional 单官能度的 monomer 单体 morphology 形态(学) moulding 模塑成型 neutral 中性的 nonelastic 非弹性的 nuclear magnetic resonance 核磁共振 nuclear track detector 核径迹探测 器 number average molecular weight 数均分子量 occluded 夹杂(带)的 olefinic 烯烃的 optimum 最佳的,最佳值[点,状态] orient 定向,取向 orientation 定向 oxonium 氧鎓羊 packing 堆砌 parameter 参数 parison 型柸 pattern 花纹,图样式样 peculiarity 特性 pendant group 侧基 performance 性能,特征 permeability 渗透性 pharmaceutical 药品,药物,药物的,医药 的 phenyl sodium 苯基钠 phenyllithium 苯基锂 phosgene 光气,碳酰氯 photosensitizer 光敏剂 plastics 塑料 platelet 片晶 polyamide 聚酰胺 polybutene 聚丁烯 polycondensation 缩(合)聚 (合) polydisperse 多分散的 polydispersity 多分散性 polyesterification 聚酯化(作 用) polyethylene 聚乙烯 polyfunctional 多官能度的 polymer 聚合物【体】,高聚物 polymeric 聚合(物)的 polypropylene 聚苯烯 polystyrene 聚苯乙烯 polyvinyl alcohol 聚乙烯醇 polyvinylchloride 聚氯乙烯 porosity 多孔性,孔隙率 positive 正的,阳(性)的 powdery 粉状的 processing 加工,成型 purity 纯度 pyrolysis 热解 radical 自由基 radical polymerization 自由基聚合 radius 半径 random coil 无规线团 random decomposition 无规降解 reactent 反应物,试剂 reactive 反应性的,活性的 reactivity 反应性,活性 reactivity ratio 竞聚率 real 真是的 release 解除,松开 repeating unit 重复单元 retract 收缩 rubber 橡胶 rubbery 橡胶态的 rupture 断裂 saturation 饱和 scalp 筛子,筛分 seal 密封 secondary shaping operation 二次成型 sedimentation 沉降(法) segment 链段 segment 链段 semicrystalline 半晶 settle 沉淀,澄清 shaping 成型 side reaction 副作用 simultaneously 同时,同步 single bond 单键 slastic parameter 弹性指数 slurry 淤浆 solar energy 太阳能 solubility 溶解度 solvent 溶剂 spacer group 隔离基团 sprinkle 喷洒 squeeze 挤压 srereoregularity 立构规整性【度】 stability 稳定性 stabilizer 稳定剂 statistical 统计的 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