GHS分类测试报告---MEA一乙醇胺21201302220

化学品分类检验记录单

样品名称：一乙醇胺

报验编号：21201302220 样品编号：201326400

检验项目：化学品分类&GHS

检验依据：联合国《关于危险货物运输的建议书》(UN)；国际海事组织《国际海运危险货物规则》(IMO)；国际航空运输协会《危险品规则》(IATA)；《危险化学

品名录》(2002年版)

记录见附页：

湖北出入境检验检疫局技术中心

货物运输条件鉴定书

Hubei Entry-Exit Inspection and Quarantine Bureau of P.R.C

Certification for Safe Transport of Dangerous Goods

样品编号(Sample Number)：201326400

申报品名Name of Goods

中文

Chinese

一乙醇胺英文

English

Ethanolamine

分子式

Molecular formula

C2H7NO

申请单位Applicant

湖北仙粼化工有限公司

Hubei Xianlin Chemical Industry Co., Ltd.

生产单位Manufacturer

湖北仙粼化工有限公司

Hubei Xianlin Chemical Industry Co., Ltd.

样品外观与性状Appearance and property

有氨臭味无色透明的粘稠液体

Colorless transparent viscous liquid with an odor resembling that of ammonia

主要危险性

Main Danger

8 次要危险性

Subsidiary Danger

无

正确运输名称Proper Shipping Name

乙醇胺Ethanolamine

CAS登记号

CAS Register Number

C2H7NO : 141-43-5

危险性类别

Class or Division

8

联合国编号

UN Number

UN 2491

包装类别

Packing Group

Ⅲ

检测鉴定依据Warranty of Test 联合国《关于危险货物运输的建议书》，《Recommendations on the Transport of Dangerous Goods》(UN)；国际海事组织《国际海运危险货物规则》，《International Maritime Dangerous Goods》(IMO)；国际航空运输协会《危险品规则》，《Dangerous Goods Regulation》(IATA)；《危险化学品名录》(2002年版)，《The List of Dangerous Chemicals》(2002 Edition)。

特别声明Special Statements 委托人自送样品。本鉴定书适用于货物的航空运输和海洋运输，原件有效期至2014年08月09日

The client submits the sample. Certification for Safe Transport of Dangerous Goods applies to cargo air transport and marine transport, the term of validity to Aug 09.2014

爆炸危险性鉴定Determination for Explosive Danger 该货物无爆炸危险性

NONE

易燃危险性鉴定Determination for Flammable Danger 该货物无易燃危险性

NONE

氧化危险性鉴定Determination for Oxidizing Danger 该货物无氧化危险性

NONE

毒害与感染危险性鉴定Determination for Toxic & Infectious Danger 该货物无毒害性，无感染危险性

NONE

放射性危险性鉴定Determination for Radioactive Danger 该货物无放射性危险性

NONE

腐蚀危险性鉴定Determination for Corrosive Danger

该货物有腐蚀危险性

The goods have Corrosive Danger

其它危险性鉴定Determination for Other Dangers 该货物无其它危险性

NONE

理化性质Physical & Chemical

Properties 样品主要成份为一乙醇胺(99.5%)(The sample main ingredient is Ethanolamine)；分子式(Molecular Formula)：C2H7NO；分子量(Molecular Weight)：61.08g/mol；密度(Density)：1.0153 g/ml(20°C)；熔点(Melting Point)：10.3°C；沸点(Boiling Point)：170°C；闪点(Flash point)：86°C(闭杯法Closed Cup)；折射率(Refractive index)n20/D：1.4539；自燃温度(Autoignition Temperature)：410°C；敏感性(Sensitive)：空气和湿气敏感(Air and Moisture Sensitive)；水溶性(Water Solubility)：与水混溶(Miscible with water)；稳定性(Stability)：常温常压下稳定，可燃液体，有腐蚀性，按照规定使用和储存不会发生反应，与强酸、氧化剂、酸性氯化物、酸酐、铁、铝、铜、黄铜、橡胶等不相容。(This material is stable under normal temperatures and pressures. Flammable and corrosive. No reaction if used and stored according to specifications. Incompatible with strong acids, oxidizing agents, acid chlorides, acid anhydrides, iron, aluminium, copper, brass, rubber etc.)；有氨臭味无色透明的粘稠液体。混溶于酒精、氯仿和丙酮，微溶于苯、醚和四氯化碳。有吸湿性。蒸气比空气重，刺激眼睛和粘膜。摄取或接触皮肤和眼睛会引起严重刺激。用于高级染料、油漆制造和有机合成原料、表面活性剂、防锈剂、清洁剂、防腐剂等。广泛用作酸性气体吸收剂及石油添加剂的中间体，也用于农药、医药、非离子型洗涤剂、乳化剂等。用于食品工业用加工助剂、制药工业中合成杀菌剂及止泻剂、纺织工业中的荧光增白剂、橡胶工业和油墨工业中的中和剂、气相色谱固定液和溶剂等。A colorless transparent viscous liquid with an odor resembling that of ammonia. Miscible with alcohol, chloroform and acetone. Very slightly soluble in benzene, ether and carbon tetrachloride. Hygroscopic. Vapor, which is heavier than air, irritates the eyes and mucous membranes. Ingestion of liquid or contact with eyes or skin causes severe irritation. Used in the manufacture of high-grade dyestuff, paint and synthetic organic materials. Used as surface active agent, anti rust agent, cleaning agent, preservative etc. Widely used in acid gas absorbent and intermediate of oil additives, also used for pesticide, medicine, nonionic detergent, emulsifier etc. Processing aid for the food industry, synthetic fungicides and antidiarrheal agents in the pharmaceutical industry, fluorescent whitening agent in the textile industry, the neutralizer in rubber and printing ink industry, GC stationary liquid and solvent etc.

鉴定货物在贮存、运输中的危险性分析Analysis of Dangerous Properties For Goods in storage and Transport 处理措施：不使用时保持容器密闭，避免与眼睛、皮肤和衣物相接触。防止吸入蒸汽和烟雾。避免摄取和吸入。使用前需要获得专门的

指导，仅按照指导使用。确保工作区有良好的通风或排气装置，

仅在通风良好之处使用。一般性的防火保护措施。切勿靠近火

源。严禁烟火。切勿靠近热源和火源。采取措施防止静电积聚。

空容器可能含有残留物，不要重新使用或损坏空容器。处理及

打开容器时，必须小心。根据工业卫生和安全使用规则来操作。

物质转移时容器应接地。使用防火花和防爆工具。不要把空容

器暴露在热、火花或明火中。禁止增压、切割、焊接、铜焊、

焊锡、钻、研磨或使空容器暴露于热、火花、明火中或接触着

火源。防范蒸汽达到可爆炸的浓度。严禁沾染到皮肤或进入眼

睛，避免直接或长期反复接触皮肤和眼睛。接触后用肥皂水冲

洗皮肤。不要摄取或吸入。远离食品、饮料和饲料。作业后、

休息以前和工作结束时彻底洗手。丢弃被污染的衣物。

储藏方法：正常条件下运输和处置稳定。不使用时保持容器密封。储存于阴凉、干燥、通风的远离不能共存物质的防火区域。在正常状

态下储存与使用不会发生危险化学反应。惰性气体下操作和储

存。避免阳光直射和水分或潮湿。远离热源、火焰、火花和极

端的温度储存。远离强酸、氧化剂、酸性氯化物、酸酐、铁、

铝、铜、黄铜、橡胶、易燃物质、有机材料、活泼非金属等。

应与食用化学品分开存放。打开了的容器必须仔细重新封口并

保持竖放位置以防止泄漏。储区应备有合适的材料收容泄漏物。

配备相应品种和数量的消防器材及泄漏应急处理设备。不要在

工作区域饮食。在进食、饮水前要用肥皂水洗手。

运输信息：运输时运输车辆应配备相应品种和数量的消防器材及泄漏应急处理设备。夏季最好早晚运输。运输时所用的槽(罐)车应有接地

链，槽内可设孔隔板以减少震荡产生静电。严禁与强酸、氧化

剂、酸性氯化物、酸酐、铁、铝、铜、黄铜、橡胶、易燃物或

可燃物、活泼非金属、食用化学品等混装混运。运输途中应防

曝晒、雨淋，防高温。中途停留时应远离火种、热源、高温区。

装运该物品的车辆排气管必须配备阻火装置，禁止使用易产生

火花的机械设备和工具装卸。公路运输时要按规定路线行驶，

勿在居住区和人口稠密区停留。

Handing: Keep containers closed when not in use. Avoid contact with skin, eyes and clothing. Avoid inhalation of vapor or mist. Avoid

ingestion and inhalation. Obtain special instructions before use, use

only as directed. Ensure good ventilation at the workplace, use only

in a well ventilated area. Normal measures for preventive fire

protection. Keep away from sources of ignition. No smoking. Keep

away from heat and sources of ignition. Take measures to prevent

the buildup of electrostatic charge. Empty containers may contain

product residue. Do not reuse and damage empty container. Handle

and open container with care. Handle in accordance with good

industrial hygiene and safety practice. Ground and bond containers

when transferring material. Use spark-proof tools and explosion

proof equipment. Do not expose empty containers to heat, sparks or

open flames. Do not pressurize, cut, weld, braze, solder, drill, grind,

or expose empty containers to heat, sparks, open flames or sources

of ignition. Prevent build up of vapors to explosive concentration.

Do not get on skin or in eyes. Avoid direct, prolonged or repeated

contact with skin and eyes. Wash skin with soap and water after

contact. Do not ingest or inhale. Keep away from foodstuffs

beverages and feed. Wash hands thoroughly before handling, breaks

and at the end of workday. Discard contaminated clothes. Storage: Stable under normal shipping and handling conditions. Keep container tightly sealed when not in use. Store in a cool, dry, well-ventilated

and fireproof storage place away from incompatible substances.

Under normal conditions of storage and use, hazardous or reactions

will not occur. Handle and store under inert gas. Avoid direct

sunlight and damp or water/moisture. Store away from heat, flames,

sparks and extremes of temperature. Keep away from strong acids,

oxidizing agents, acid chlorides, acid anhydrides, iron, aluminium,

copper, brass, rubber, flammable substances, organic materials,

active nonmetal etc. Stored away from food chemicals. Containers

which are opened must be carefully resealed and kept upright to

prevent leakage. Storage areas should be equipped with appropriate

materials containing leakage. Equipped with suitable variety and

quantity of firefighting equipment and emergency leakage treatment

equipment. Consumption of food and beverage should be avoided

in work areas. Wash hands with soap and water before eating and

drinking.

Transport: Transport vehicles shall be equipped with suitable variety and quantity of firefighting equipment and emergency leakage treatment

equipment. It is recommended to transport in the morning and

evening in summer months. The tank truck should be equipped with

a grounding chain. Install orifice plate in tank to reduce static

caused by shock. Do not transport with strong acids, oxidizing

agents, acid chlorides, acid anhydrides, iron, aluminium, copper,

brass, rubber, active metal powder, flammable or combustible

material, active nonmetal powers, food chemicals etc. Keep away

from sun, rain and high temperature during transport. Keep away

from ignition, heat sources and hot places during rest stops. The

exhaust pipe on the vehicle must be equipped with a fireproof

device. Do not load and unload with mechanical equipment and

tools which create sparks easily. Use major routes when

transporting by road. Do not travel though residential and

densely-populated areas.

急救措施First-aid Measures 一般建议：请教医生。出示此安全技术说明书给到现场的医生看。吸入或接触可能刺激或灼伤皮肤和眼睛。可能会引起咳嗽、头痛、呼

吸急促、咽喉痛、腹痛、灼烧感、发红、疼痛、灼伤等症状。

该物质对粘膜组织和上呼吸道、眼睛和皮肤破坏巨大。推荐

24~48h医学观察。救援者需要穿戴个人防护用品，比如橡胶手

套和气密性护目镜。避免任何皮肤接触。对症辅助治疗。根据

接触程度，建议定期体检。

眼睛接触：不要让受害者擦拭眼睛眼或者保持眼睛紧闭，使用大量水冲洗眼睛至少30分钟，其间提起眼睑并取出隐形眼镜。立即就医。皮肤接触：立即用大量水和肥皂彻底冲洗至少15分钟，脱去污染衣物。

如大面积皮肤受损或持续刺激请立即就医。处理丢弃衣物时防

止进一步的污染。衣物清洗后再使用。

如误吸入：立即将人员移至通风处。如果呼吸停止，速进行人工呼吸抢救。

禁止使用口对口人工呼吸抢救。使用氧气或合适的设备(袋子、

面罩)辅助进行人工呼吸。如果呼吸困难或呼吸不规则，需立即

供氧。如果呼吸困难，需立即供氧。让病人保暖，严重情况或

不能立即完全恢复立即就医。

如误摄取：禁止催吐。松开衣领，领带，皮带或腰带等有束缚的衣物。切勿给失去知觉者从嘴里喂食任何东西。如患者意识清醒，用水

漱口并饮用2-4满杯牛奶或温水。如感觉不适立即就医。建议进

行医学观察。

General advice: Consult a physician. Show this safety data sheet to the doctor in attendance. Inhalation or contact with material may irritate or

burn skin and eyes. May cause cough, headache, shortness of

breath, sore throat, abdominal pain, burning sensation, redness,

pain, burn and other symptoms. This material is extremely

destructive to tissue of the mucous membranes and upper

respiratory tract, eyes, and skin. Medical observation is

recommended for 24~48h, as onset may be delayed 2 to 4 hours or

longer. A rescuer should wear personal protective equipment, such

as rubber gloves and airtight goggles. Avoid any skin contact. Treat

symptomatically and supportively. Depending on the degree of

exposure, periodic medical examination is indicated.

Eye: Do NOT allow victim to rub or keep eyes closed. Extensive irrigation is required, flush eyes with plenty of water for at least 30 minutes

while holding eyelids open and remove contact lenses. Obtain

medical aid immediately.

Skin: Immediately flush skin with plenty of water and soap and rinse thoroughly for at least 15 minutes while removing contaminated

clothing and shoes. If a large area of the skin is damaged or if

irritation persists get medical attention immediately. Discard

contaminated clothing in a manner which limits further exposure.

Wash clothing and shoes before reuse.

Inhalation: Remove victim to fresh area immediately. If not breathing, give artificial respiration. Prohibit the use of mouth-to-mouth rescue

breathing. The use of oxygen or proper equipment (bags, auxiliary

artificial respiration mask).If breathing is difficult or irregular

breathing, requiring immediate oxygen. If breathing is difficult,

give oxygen. Keep patient warm. In severe cases, or if recovery is

not rapid or complete seek immediate medical attention. Ingestion: Do NOT induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. Never give anything by mouth to an unconscious

person. If patient is conscious and alert, rinse mouth with water and

drink 2-4cupfuls of milk or warm water. If patient feels unwell call

a physician immediately. Medical observation is recommended.

灭火方法Fire-extinguishing

Method 危害特性：可燃液体，蒸汽或烟雾可与空气混合形成一种具有爆炸性的混合物。暴露于热或火焰中极其危险，遇热、火花或火焰极易燃

烧。受热燃烧可能分解产生刺激性的碳氧化物、氮氧化物等有

毒气体或烟雾。如必要的话，戴自给式呼吸器和穿上全面保护

衣物去救火。非相关人员应该撤离至安全地方。不要让水进入

容器。周围一旦着火，如果安全，移去可移动容器，因容器受

热可能爆炸，须撤离现场，远距离救火。在上风向灭火，用水

雾冷却容器，容器受热可能爆炸。不要用高压水流冲散泄露液

体，避免吸入燃烧产物。蒸气比空气重，能扩散相当远距离回

燃。泄露入下水道可能引起火灾或爆炸事故。

灭火剂：用水雾、耐醇泡沫、砂土、干粉或二氧化碳灭火。从上风处灭火，根据周围环境选择合适的灭火方法。灭火时，一定要穿戴个人

防护用品。用大量水冷却容器直到火灭。水喷雾可用来冷却未

打开的容器。小火时，用干粉、二氧化碳。大型火灾时，使用

水、砂土、干粉、二氧化碳或干冰。消防或稀释水废液可能具

有腐蚀性和有毒而造成污染。

Hazards Profile: Flammable liquid. Vapors or fumes can combine with air to form an explosive mixture. Very dangerous when exposed to heat or

flame; will be easily ignited by heat, sparks or flames. Heating

combustion may decomposition produce irritating carbon oxide,

nitrogen oxides and other toxic gas or fumes. Wear self-contained

breathing apparatus and full protective suit for firefighting if

necessary. Uninvolved persons should evacuate to a safe place. Do

not get water inside containers. In case of fire in the surroundings:

Remove movable containers if safe to do so. Evacuate area. Fight

fire remotely due to containers may explode when heated.

Extinguish in the direction of the wind, use water spray keep the

container cool. Containers may explode when heated. Do NOT use

high-pressure water that may cause leakage of the liquid and

breathing of the combustion products. Vapor is heavier than air and

may travel a considerable distance to source of ignition and flash

back. Runoff to sewer may create fire or explosion hazard. Extinguishing media：Use water spray, alcohol-resistant foam, sand, dry chemical or carbon dioxide. Fire-extinguishing work is done from

the windward and the suitable fire-extinguishing method according

to the surrounding situation is used. When extinguishing fire, be

sure to wear personal protective equipment. Cool containers with

flooding quantities of water until well after fire is out. Use water

spray to cool unopened containers. For small fires, use dry

chemical, carbon dioxide or water spray. For large fires, use water,

sand, dry chemical, carbon dioxide or dry-ice. Runoff from fire

control or dilution water may be corrosive and/or toxic and cause

pollution.

防护措施Protection Measures 一般建议：根据工业卫生和安全使用规则来操作。应遵循一般的化学物品预防措施。立即除去所有的不洁的和被污染的衣物。避免与皮

肤、眼睛和衣服接触。休息以前和操作过此产品之后立即洗手。

安装封闭体系或局部排风系统。提供安全淋浴和洗眼设备。在

化学通风烟橱处理。

眼/面保护：用眼睛保护装备，整面部防护。面罩与安全眼鏡，请使用经官方标准检测与批准的设备防护眼部。操作时不可戴隐形眼镜。皮肤保护：戴手套取，手套在使用前必须受检查。请使用合适的方法脱除手套(不要接触手套外部表面)，避免任何皮肤部位接触此产品。

使用后请将被污染过的手套根据相关法律法规和有效的实验室

规章程序谨慎处理。请清洗并吹干双手。

身体保护：全套防化学试剂工作服，阻燃防静电化学防护服。防护设备的类型必须根据特定工作场所中的危险物的浓度和含量来选择。呼吸系统防护：如危险性评测显示需要使用空气净化的防毒面具，请使用全面罩式多功能防毒面具。如果防毒面具是保护的唯一方式，

则使用全面罩式送风防毒面具。呼吸器使用经过测试并通过政

府标准的呼吸器和零件。

其他防护：严加密闭，提供充分的局部排风。工作现场禁止吸烟、进食和饮水。接触本品后，必须在进食、抽烟、上厕所、休息以前和

工作结束时彻底清洗手、胳膊和脸。处理沾有本品的抹布要采

取合适的方法。沾有本品的抹布要洗净后再次使用。确保盥洗

室、浴洗室离工作站较近。工作完毕，淋浴更衣。保持良好的

卫生习惯。

General advice: Handle in accordance with good industrial hygiene and safety practice. The usual precautionary measures for handling chemicals

should be followed. Instantly remove any soiled and impregnated

garments. Wash hands before breaks and at the end of workday.

Avoid contact with skin, eyes and clothing. Wash hands before

breaks and immediately after handling the product. Install a closed

system or local exhaust. Provide safety shower and eye equipment.

In the chemical ventilation fume cupboard handle.

Eye/face protection: Use equipment for eye protection. Full face protection.

Face shield and safety glasses. Use equipment for eye protection

tested and approved under appropriate government standards. Do

not wear contact lenses during operating.

Skin protection: Handle with gloves. Gloves must be inspected prior to use.

Use proper glove removal technique (without touching glove's outer

surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws

and good laboratory practices. Wash and dry hands.

Body Protection: Complete suit protecting against chemicals, Flame retardant antistatic protective clothing. The type of protective equipment

must be selected according to the concentration and amount of the

dangerous substance at the specific workplace.

Respiratory protection: Where risk assessment shows air-purifying respirators are appropriate use a full-face respirator with multi-purpose

combination. If the respirator is the sole means of protection, use a

full-face supplied air respirator. Use respirators and components

tested and approved under appropriate government standards. Other protections: Be strictly airtight and provide full local exhaust. No smoking, feeding and drinking at work. Wash hands, forearms and

face thoroughly after handling chemical products, before eating,

smoking, using the lavatory, breaks and at the end of workday.

Appropriate techniques should be used to remove potentially

contaminated clothing. Wash contaminated clothing before reusing.

Ensure that eyewash stations and safety showers are close to the

workstation location. Take a shower and change clothes after work.

Maintain good health habits.

泄漏应急措施Accidental Release Measures 应急措施：使用个人防护设备。将人员撤离到安全区域，远离泄露处并处在上风处。移去所有火源。远离燃烧的源头。泄露区应该用安

全带等圈起来，控制非相关人员进入。避免与眼睛接触。戴呼

吸罩，保证充分的通风，避免吸入蒸汽、烟雾或气体。防范蒸

汽或烟雾积累达到可爆炸的浓度，蒸汽或烟雾能在低洼处积聚。

避免接触泄漏物。蒸气抑制泡沫可以用来减少蒸汽。在确保安

全的前提下，采取措施防止进一步的泄漏或溢出。

泄漏处理：围堵溢出，收集、处理泄漏物。用合适的惰性吸收剂(如：干砂土、硅藻土、酸性粘合剂、通用粘合剂、锯屑、旧布、土等)吸

收泄露物。用防电真空清洁器或湿的刷子将溢出物尽可能多地

收集泄漏处理物于有标签的合适容器中，根据当地规定处理。

勿使泄漏物与强酸、氧化剂、酸性氯化物、酸酐、铁、铝、铜、

黄铜、橡胶、易燃物质、有机材料、活泼非金属等接触。处理

完泄露后用水冲刷泄露区域。泄漏处理物禁止倒入下水道、沟

渠或水渠。该物质对水生生物有害，应特别注意对水体的污染，

防止排放到周围环境中。

废弃处置：如果可能，回收处理。请咨询当地管理部门。建议在可燃溶剂中溶解混合，在装有后燃和洗涤装置的化学焚烧炉中焚烧。废

弃处置时请遵守国家、地区和当地的所有法规。

少量泄漏：清扫铲起，收集于密闭容器中。或用砂土、蛭石或其它惰性材料吸收。用水将泄漏的地方拖洗干净。

大量泄漏：一旦大量泄漏，构筑围堤或挖坑收容。用防爆泵转移至槽车或专用收集器内，回收或运至废物处理场所处置。附着物或收集

物应该立即根据合适的法律法规废弃处置。

Emergency measure: Use personal protective equipment. Evacuate personnel to safe areas, Keep people away from and upwind of leak. Remove

all sources of ignition. Keep away from ignition sources. Entry to

noninvolved personnel should be controlled around the leakage area

by roping off, etc. Avoid contact with eye. Wear respiratory

protection, Ensure adequate ventilation, Avoid breathing vapors,

mist or gas. Beware of vapors or fumes accumulating to form

explosive concentrations. V apors or fumes can accumulate in low

areas. Avoid contact with the spilled material. A vapor suppressing

foam may be used to reduce vapors. Prevent further leakage or

spillage if safe to do so.

Leakage treatment: Contain spillage, pick up and arrange disposal. Absorb

spilled material in a suitable inert absorbent (e.g. dry sand,

diatomite, acid binders, universal binders, sawdust, rag, earth etc.).

Collect with an electrically protected vacuum cleaner or by

wet-brushing as much of the spilled material as possible, placed the

spilled material into a suitable closed disposal container for disposal

according to local regulations. Do not let the leakage contact with

strong acids, oxidizing agents, acid chlorides, acid anhydrides, iron,

aluminium, copper, brass, rubber, flammable substances, organic

materials, active nonmetal etc. Wash spill site with plenty of water

after material has been taken up. Keep spilled material out of

sewers, ditches and bodies of water. This material harmful to

aquatic life and the special attention should be paid to its water

pollution. Discharge into the environment must be avoided.

Disposal considerations: Recycle to process, if possible. Consult your local

regional authorities. You may be able to dissolve or mix material

with a combustible solvent and burn in a chemical incinerator

equipped with an afterburner and scrubber system. Observe all

federal, state and local regulations when disposing of the substance.

Small leak: Sweep up, collected the spilled material into a closed container.

Absorb with sand, vermiculite, or other inert absorbent material.

Mop up spill site with water after material has been swept up.

Large leak: In case of large amount of spillage, contain a spill by bunding. Use

explosion-proof pump and transfer the spilled to the tank or

exclusive collector. Collection of recycling or shipped to the

disposal of waste disposal sites. Adhered or collected material

should be promptly disposed of, in accordance with appropriate

laws and regulations.

检验员(Inspector)：审核人(Verifier)：

日期(Date)：日期(Date)：

湖北出入境检验检疫局技术中心

GHS 分类试验报告单

Hubei Entry-Exit Inspection and Quarantine Bureau of P.R.C

Report for GHS Classification Test

委托单位：湖北仙粼化工有限公司

Applicant: Hubei Xianlin Chemical Industry Co., Ltd.

检测结果(Test result)： 样品编号(Sample Number)：201326400 样品名称

Name of Goods 危险类别 Classification

警示标签 Precautionary label 参考法规 Reference regulations 一乙醇胺 Ethanolamine 易燃液体 类别4

Flammable liquids

Category 4

急性毒性-口服 类别4

Acute toxicity – oral

Category 4

急性毒性-皮肤 类别4

Acute toxicity – dermal

Category 4

皮肤腐蚀/刺激 类别1B

Skin corrosion/irritation

Category 1B

敏化-皮肤 类别1

Sensitisation, skin

Category 1

严重眼损伤、眼刺激 类

别1

Serious eye damage/eye

irritation Category 1

急性毒性-吸入 类别4

Acute toxicity- inhalation

Category 4

敏化–呼吸 类别1

Sensitisation respiratory

Category 1

生殖毒性 类别 2

Reproductive toxicity

Category 2

特定目标器官毒性-单次图形符号 Pictogram 全球化学品统一分类和标签制度 (GHS)

标记字符 Signal word 危险 Danger 危险说明与代码 Hazard statements 可燃液体(H227) Combustible liquid (H227) 吞咽有害(H302) Harmful if swallowed(H302) 接触皮肤有害(H312) Harmful in contact with skin(H312) 造成严重皮肤灼伤和眼损伤(H314) Cause severe skin burns and eye damage(H314) 可能导致皮肤过敏反应(H317) May cause an allergic skin reaction(H317) 造成严重眼损伤(H318) Causes serious eye damage (H318) 吸入有害(H332) Harmful if inhaled(H332) 吸入可能导致过敏或哮喘病症状或呼吸困难(H334)

样品名称Name of Goods

危险类别

Classification

警示标签

Precautionary label

参考法规

Reference

regulations 接触类别1

Specific target organ

toxicity, single exposure;

Category 1

特定目标器官毒性-重复

接触类别1

Specific target organ

toxicity, repeated

exposure; Category 1

危害水生环境-急性毒

性 类别3

Hazardous to the aquatic

environment -acute

toxicity Category 3

May cause allergy or asthma

symptoms or breathing

difficulties if inhaled(H334)

怀疑对生育能力或胎儿造成

伤害(H361)

Suspected of damaging

fertility or the unborn

child(H361)

对器官造成损害：肝脏、神

经系统(H370)

Cause damage to organs: liver,

nervous system (H370)

长期或重复接触会对器官造

成伤害：肝脏、呼吸系统、

消化道、神经系统、肾脏、

睾丸(H372)

Cause damage to organs

though prolonged or repeated

exposure: liver, respiratory

system, digestive tract,

nervous system, kidney, testis

(H372)

对水生生物有害(H402)

Harmful to aquatic life(H402)

检验员(Inspector)：审核人(Verifier)：日期(Date)：日期(Date)：

防范说明表（Precautionary statements）

危险类型(Hazard category) 信号词(Signal word) 危险说明(Hazard statement) 4 警告可燃液体(H227) (4 Warning Combustible liquid (H227)) 4 警告吞咽有害(H302) (4 Warning Harmful if swallowed (H302)) 4 警告接触皮肤有害(H312) (4 Warning Harmful in contact with skin (H312)) 1B 危险造成严重皮肤灼伤和眼损伤(H314) (1B Danger Cause severe skin burns and eye damage (H314)) 1 警告可能导致皮肤过敏反应(H317) (1 Warning May cause an allergic skin reaction (H317)) 1 危险造成严重眼损伤(H318) (1 Danger Causes serious eye damage (H318)) 4 警告吸入有害(H332) (4 Warning Harmful if inhaled (H332)) 1 危险吸入可能导致过敏或哮喘病症状或呼吸困难(H334) (1 Danger May cause allergy or asthma symptoms

or breathing difficulties if inhaled (H334)) 2 警告怀疑对生育能力或胎儿造成伤害(H361) (2 Warning Suspected of damaging fertility or the unborn child (H361)) 1 危险对器官造成损害：肝脏、神经系统(H370) (1 Danger Cause damage to organs: liver, nervous system (H370)) 1 危险长期或重复接触会对器官造成伤害：肝脏、呼吸系统、

消化道、神经系统、肾脏、睾丸(H372) (1 Danger Cause damage to organs though prolonged or repeated exposure: liver,

respiratory system, digestive tract, nervous system, kidney, testis (H372)) 3 对水生生物有害(H402) (3 Harmful to aquatic life (H402)

防范说明Precautionary statements

预防Prevention 反应Response 贮存Storage

处置Disposal

远离热源、火花、明火、热表面，禁止吸烟。

Keep away from

heat/sparks/open flames/hot Surface, No smoking.

佩戴防护手套、穿防护服、戴防护眼罩与防护面具。

Wear protective gloves/protective clothing/eye protection/face protection.

作业后应彻底进行清洗。火灾时：使用水雾、砂土、干粉、耐醇泡沫或二

氧化碳灭火器灭火。

In case of fire: Use water spray, sand, dry chemical

powder, alcohol-resistant foam or carbon dioxide

for extinction.

漱口。

Rinse mouth.

脱掉所沾染的衣服，清洗后方可重新使用。

Wash contaminated clothing before reuse.

具体治疗（见本标签）。

Specific treatment (see on this label).

存放在通风良

好的地方。保持

低温。

Store in a

well-ventilated

place. Keep

cool.

存放处须加锁。

Store locked up.

处置内装物

或容器按照

地方、区域、

国家或国际

规章。

Dispose of

contents

/container in

accordance

with local

Wash thoroughly after handling. 使用本产品不得进食、饮水或吸烟。

Do not eat, drink or smoke when using this product.

不要吸入粉尘、烟、气体、蒸汽、喷雾和烟雾。

Do not breathe dust/fume/gas

/vapors/spray/mists.

只在室外或通风良好之处使用。Use only outdoors or in a

well-ventilated area.

如通风不足，须戴呼吸防护装置。

In case of inadequate ventilation wear respiratory protection.

受沾染的工作服不得带出工作场地。

Contaminated work clothing should not be allowed out of the workplace.

在使用前获取特别指示。Obtain special instructions before use.

在读懂所有安全防范措施之前切勿搬动。

Do not handle until all safety precautions have been read and understood.

使用所需的个人防护设备。Use personal protective equipment as required.

避免释放到环境中。

Avoid release to the environment. 立即呼叫解毒中心或医生。

Immediately call a POISON CENTER or

doctor/physician.

如误吸入：将受害人转移到空气新鲜处，保持呼

吸舒适的休息姿势。

IF INHALED: Remove victim to fresh air and keep

at rest in a position comfortable for breathing.

如皮肤沾染(或头发)：立即脱去受污染的衣。用

大量肥皂和水清洗/沐浴。

IF ON SKIN (or hair): Remove/Take off

immediately all contaminated clothing. Rinse skin

with plenty of soap and water/shower.

如误吞咽：不得诱导呕吐。如感觉不适，立即呼

叫解毒中心或医生。

IF SWALLOWED: Do NOT induce vomiting. Call

a POISON CENTER or doctor/physician if you feel

unwell.

如进入眼睛：用水小心冲洗几分钟。如戴隐形眼

镜并可方便地取出，取出隐形眼镜。继续冲洗。

IF IN EYES: Rinse cautiously with water for

several times minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

如有呼吸系统症状：立即呼叫解毒中心或医生。

IF experiencing respiratory symptoms: Immediately

call a POISON CENTER or doctor/physician.

如发生皮肤刺激或皮疹：就医或就诊。

IF skin irritation or rash occurs：Get medical

advice/attention.

如接触到或有疑虑：呼叫解毒中心或医生。就医

或就诊。

IF exposed or concerned: Call a POISON CENTER

or doctor/physician. Get medical advice/attention.

如感觉不适，就医或就诊。

Get medical advice/attention if you feel unwell.

/regional

/national

/international

regulations.