2020年交大附中高三上摸底考化学试卷

2020年交大附中高三上摸底考化学试卷
2020年交大附中高三上摸底考化学试卷

第一学期

高三化学摸底试卷

相对原子质量:H-1 N-14 O-16 F-19 Na-23 S-32 Cl-35.5 K-39 Ca-40 Mn-55

Fe-56 Cu-64 Ag-108

一、选择题(本题共40分,每小题2分,每题只有一个正确选项)

1.“一带一路(OneBelt AndOneRoad)”构建人类命运共同体,符合国际社会的根本利益,彰显人类社会的共同理想和美好追求。下列贸易的商品中,其主要成分属于无机物的是

A. 中国丝绸

B. 埃及长绒棉

C. 乌克兰葵花籽油

D. 捷克水晶

2. 能够产生如右图实验现象的液体是

A. CS2

B. CCl4

C. H2O

D. 苯

3. 下列化学用语的表述正确的是

A. 乙烯的最简式C2H4

B. 四氯化碳的电子式

C. 二氧化硅的分子式SiO2

D. 离子结构示意图:可以表示16O2-,也可以表示18O2-

4. 设N A为阿伏加德罗常数的值。下列说法正确的是

A. 1.6g由氧气和臭氧组成的混合物中含有氧原子的数目为0.1N A

B. 0.1mol丙烯酸中含有双键的数目为0.1N A

C. 标准状况下,11.2L苯中含有分子的数目为0.5N A

D. 在过氧化钠与水的反应中,每生成0.1mol氧气,转移电子的数目为0.4N A

5. 下列各组物质的熔点均与所含化学键的键能有关的是

A. CaO与CO2

B. NaCl与HCl

C. SiC与SiO2

D. Cl2与I2

6. BeCl2熔点较低,易升华,溶于醇和醚,其化学性质与AlCl3相似。由此可推测BeCl2

A. 熔融不导电

B. 水溶液呈中性

C. 熔点比BeBr2高

D. 不与NaOH溶液反应

7. 下列变化过程中,体系温度下降的是

A. 硫酸溶于氢氧化钠溶液

B. 铝热反应

C. 液溴和苯在铁粉存在下制溴苯

D. 硝酸铵溶于水

8. 下列不能说明氯的非金属性强于溴的事实是

A. HClO4酸性强于HBrO4

B. 向溴化亚铁溶液中滴入少量氯水,溶液颜色变黄

C. BrCl+H2O→HBrO+HCl是非氧化还原反应

D. HBr的分解温度低于HCl

9. 除去下列物质中混有的少量杂质(括号内的物质),选用的试剂和方法都正确的是

被提纯的物质(杂质)选用的试剂选用的方法

A.乙烷(乙烯)酸性高锰酸钾溶液洗气

B.乙酸乙酯(乙酸)饱和碳酸钠溶液过滤

C.乙醇(水)新制的生石灰蒸馏

D.苯(己烯)溴水过滤

10. 有关右图电化学装置的叙述中,正确的是

A. 若X为碳棒,Y为饱和食盐水,K置于N,则铁极上析出氢气

B. 若X为铂棒,Y为CuCl2溶液,K置于N,则铁棒质量将增加

C. 若X为锌棒,Y为海水,K置于M,形成对铁的外加电流阴极保护

D. 若X为铜棒,Y为稀硫酸,K置于M,则正极反应为:Fe-2e→Fe2+

11. 100℃时向pH=6的蒸馏水中加入NaHSO4晶体,保持温度不变,测得溶液的pH=2,下列叙述错误的是

A. 此时水的离子积K w=1.0×10-12

B. 水电离出的[H+]=1.0×10-10mol/L

C. 水的电离度随温度升高而升高

D. [H3O+]<[SO42-]

12. 下列物质的制备方法正确的是

A. 实验室用1体积酒精和3体积浓度为3mol/L的硫酸制乙烯

B. 将溴乙烷与氢氧化钠溶液共热制取乙烯

C. 2mL10%的NaOH溶液中滴加2%的CuSO4溶液5滴得新制Cu(OH)2悬浊液

D. 用电解熔融氯化铝的方法制得单质铝

13. 陶瓷堪称是中国的国粹,对BN陶瓷叙述正确的是

A. BN化合物中各原子均满足八电子结构

B. B3+和N3-具有相同的核外电子排布

C. 若BN是空间网状结构,则其硬度可能与金刚石相似

D. B3+的离子半径大于H-的半径

14. 向等物质的量浓度NaOH和Na2CO3的混合溶液中加入稀硫酸,下列离子方程式与事实不相符的是

A. OH -+CO 32-+2H +→HCO 3-+H 2O

B. 2OH -+CO 32-+4H +→CO 2↑+3H 2O

C. 2OH -+CO 32-+3H +→HCO 3-+2H 2O

D. OH -+CO 32-+3H +→CO 2↑+2H 2O

15. 常温下用pH=3的某酸溶液与pH=11的氢氧化钠溶液等体积混合,关于所得溶液酸碱性的描述正确的是 A. 不可能显碱性 B. 不可能显中性

C. 不可能显酸性

D. 可能中性、碱性、酸性

16. 已知反应A(g)+B(g)

C(g)+D(g)的平衡常数K 值与温度的关系如下表所示。830℃时,向一个2L 的

密闭容器中充入0.20molA 和0.20molB ,10s 达平衡,测得D 的浓度为0.05mol/L 。下列说法错误的是 A. 该反应为吸热反应,升高温度,平衡朝正反应方向移动

B. 增大压强,正、逆反应速率均加快

C. 反应初始至平衡,A 的平均反应速率v(A)=0.05mol/(L?s)

D. 达平衡时,B 的转化率为50%

17. 实验是研究化学的基础,下图中所示的制备实验方法、装置或操作均正确的是

A. 可用装置甲制取氯气

B. 可用装置乙制取氨气

C. 可用装置丙制取并检验乙炔

D. 可用装置丁制得金属锰

18. 测得某pH=2的溶液中有关数据如下:

则该溶液中还可能大量存在的一种离子是

A. Fe 2+

B. Al 3+

C. Cl -

D. CO

32-

19. 25℃时,在10mL 浓度均为0.1mol/LNaOH 和NH 3?H 2O 混合溶液中,滴加0.1mol/L 的盐酸,下列有关溶液中粒子浓度关系正确的是 A. 未加盐酸时:c(OH -)>c(Na +)=c(NH 3?H 2O) B. 加入10mL 盐酸时:c(NH 4+)+c(H +)=c(OH -) C. 加入盐酸至溶液pH=7时:c(Cl -)=c(Na +)

D. 加入20mL 盐酸时:c(Cl -)=c(NH 4+)+c(Na +)

20. 称取(NH 4)2SO 4和NH 4HSO 4混合物样品7.24g ,加入含0.1molNaOH 的溶液,完全反应,生成NH 3 1792mL

(标准状况),则(NH4)2SO4和NH4HSO4的物质的量比为

A. 1:1

B. 1:2

C. 1.87:1

D. 3.65:1

二、不锈钢是由铁、铬(Cr)、镍(Ni)、碳、硅及众多不同元素组成的合金。

21. 写出碳原子最外层电子的轨道表示式_________,该化学用语不能表达出碳原子最外层电子的(填序号)___________。

a. 电子层

b. 电子亚层

c. 所有电子云的伸展方向

d. 自旋状态

22. 硅烷(SiH4)可用于制备高纯硅。已知硅烷的分解温度远低于甲烷,请从原子结构角度解释硅元素与碳元素非金属性强弱的原因_________________________________________________________。

23. 下面是工业上冶炼Cr时会涉及到的反应:

CrO42-+S+H2O→Cr(OH)3↓+S2O32-+__________

(1)请将方程式补充完整并配平。

(2)上述反应中,若转移了3mol电子,得到的还原产物是______mol。

(3)Cr(OH)3和Al(OH)3类似,也是两性氢氧化物,写出Cr(OH)3的电离方程式___________________。

24. 铁和镍(Ni)位于周期表的同一周期同一族,请写出铁和镍在周期表中的位置_________________。

25. 镍粉在CO中低温加热,生成无色挥发性液态Ni(CO)4,呈四面体构型。Ni(CO)4是_______晶体,Ni(CO)4易溶于下列(填序号)__________。

a. 水

b. 四氯化碳

c. 苯

d. 硫酸镍溶液

三、Na2S又称臭碱、硫化碱,是应用广泛的化工原料,也常用于吸收工业废气中的SO2。

26. 用离子方程式说明Na2S又称臭碱、硫化碱的原因____________________________。

27. 向AgCl悬浊液中滴加Na2S溶液,生成黑色沉淀,写出反应的离子方程式____________________。

结合你所学习过的其它离子反应分析,离子互换反应进行的方向是________________________。

向Na2S溶液中不断通入SO2,直至不再能吸收。其间看到溶液变浑浊,停止反应后溶液中含硫微粒为:S2O32-、HSO3-、H2SO3、HS-。

28. 反应过程中,溶液的pH逐渐_______(填“变大”、“变小”),生成的沉淀是___________。

29. 写出反应后溶液中电荷守恒的表示式______________________________。

四、工业产生的废气CO x、NO x、SO x对环境有害,若能合理的利用吸收,可以减少污染,变废为宝。

30. 光气(COCl2)是一种重要的化工原料,用于农药、医药、聚酯类材料的生产,工业上通过Cl2(g)+CO(g)

COCl 2(g)制备。图1为此反应的反应速率随温度变化的曲线,图2为某次模拟实验研究过程中容器内各物质的浓度随时间变化的曲线。回答下列问题:

℃0~6min 内,反应的平均速率v(Cl 2)=____________;

℃10min 改变的条件是________,该反应平衡常数变化的趋势是____________(填“增大”、“减小”或“不变”)。 31. 利用氨水可以将SO 2和NO 2吸收,原理如图3所示:NO 2被吸收的离子方程式为___________________。

32. CO 2在自然界循环时可与CaCO 3反应,CaCO 3难溶于水,可溶于盐酸,请用平衡移动原理解释CaCO 3可溶于盐酸的原因___________________。

五、有机物W 用作调香剂、高分子材料合成的中间体等,制备W 的一种合成路线如下。

已知:

请回答下列问题:

33. F 的化学名称是__________,℃的反应类型是__________________。

34. D 中含有的官能团是_______(写名称),D 聚合生成高分子化合物的结构简式为________。 35. 反应℃的化学方程式是_____________________________。 反应℃的化学方程式是_______________________________。

36. 芳香化合物N 是D 的同分异构体,要求N 能与银氨溶液反应,且能与金属钠反应,一共有4种氢原子,写出符合要求的一种同分异构体的结构简式为________________。

37. 参照有机物W 的上述合成路线,设计以M 为起始原料制备F 的合成路线(无机试剂任选)。

[示例:CH 3CH 2OH 170???→浓硫酸℃

CH 2=CH 224

Br /CCl

????→BrCH 2CH 2Br]

参考答案

一、选择题

二、21. ;c

22. C和Si最外层电子数相同,C原子电子层数少于Si,因此C原子半径小于Si

23. 4;6;7;4;3;2OH-

24. 第四周期第VIII族

25. 分子晶体;b、c

三、26. S2-+H 2O OH-+HS-、HS-+H2O OH-+H2S

27. AgCl+S2-→Ag2S+2Cl-;某些离子浓度减小的方向

28. 变小;S

29. c(Na+)+c(H+)=2c(S2O32-)+c(HSO3-)+c(HS-)+c(OH-)

四、30.℃0.15mol?L-1?min-1℃升高温度;减小

31. 2NO2+4HSO3-→N2+4SO42-+4H+

32. 在溶液中存在CaCO 3的溶解平衡:CaCO3Ca2++CO32-,加入HCl后,H+与CO32-结合生成H2O和CO2,导致CO32-减少,平衡右移,促进CaCO3的溶解。

五、33. 苯甲醇;水解反应或取代反应

34. 羟基、羧基;

35.

36.

37.

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