2016年哈三中三模化学答案

2016年哈三中三模化学答案
2016年哈三中三模化学答案

7.A 8.B 9.A 10.B 11.D 12.C 13.B

26.(1)Fe(OH)2++H 2O Fe(OH)3+H + (2分)

K 3 =]

)([)H (·

]Fe(OH)[23+OH Fe c c c (2分) K 1>K 2(2分) Fe 3+所带正电荷,对OH -的吸引能力强,所以水解程度大(2分)

(2)阴极(1分) N 2O 4 + 2HNO 3-2e -= 2N 2O 5+2H + (2分)

(3)不含(1分) 4.67(或4.7)(2分)

27. (每空2分)(1) (2)2C(s) + O 2(g) = 2CO(g) ΔH = -222.0kJ/mol

(3)① < ② K =2.0 (mol/L)-2 0.080mol/(L·min) ③ < 4

28.(1)恒压滴液漏斗 (1分) 抑制AlCl 3水解 (2分)

(2)烧杯中不再有淡黄色沉淀生成(2分)

(3)分液漏斗下端尖嘴处紧靠烧杯内壁、打开上端玻璃塞(或使塞上的凹槽对准漏斗颈小孔)、拧开漏斗下面的活塞,使下层液体慢慢沿烧杯壁留下,及时关闭活塞,将乙苯从上口倒出。(4分)

(4)温度过低,则速率慢;温度过高,则平衡逆向移动、且副反应多、产率下降 (合理即可)(2分)

(5)促进平衡正向移动提高溴乙烷转化率、防止乙苯继续取代,提高一元取代产物产率 (合理即可)(2分)

(6)66% 或64.9%(2分)

36.

37. (1)l s 22s 22p 63s 23p 63d 104s 24p 1(或[Ar]3d 104s 24p 1)(1分)

(2)Br > As > Se (2分) (3)强(1分) 平面三角形 (1分)

(4) 硅烷的相对分子质量越大,分子间范德华力越强(或其他合理答案) (2分)

(5)sp3 (1分)

(6) H 2O 2为氧化剂,氨与Cu 2+形成配离子,两者相互促进使反应进行(2分)

Cu+ H 2O 2+4NH 3=Cu(NH 3) 4 2+ +2OH -(2分)

(7) 1:3(1分) (197+64×3)×1030/(a 3N A )

38.(1)加成反应(1分) C 4H 5OCl (2分)

(2)(2分)(3)(2分)(4)羟基、羧基(2分);浓硫酸/△(2分)

(5)(2分)

(6)15种(2分)

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