赛默飞世尔科技REACH解决方案
??
1.Reach???? (1)
2.Thermo Fisher??Reach?????????-??丙 (2)
3.Thermo Fisher ??Reach???????????丙 (3)
3.1?Anthracene ?PAHs????? (3)
3.24,4’-???????4,4'- Diaminodiphenylmethane ???? (4)
3.3?????????? (5)
3.4???呱佭???? (7)
3.5 ?⒈???????? (8)
3.6 C10-C13?????????? (9)
3.7?????????? (10)
1ˊREACH????
REACH????ゴ?????????????????Registration, Evaluation, Authorization and Restriction of Chemicals?????????2007?6?1???????????????????????????????????????催???????ゲ???
2008?10?28??REACH???????????????佪?15?催??????SVHC????
?1. REACH佪?15乍催?????
????CAS No. ????????
?Anthracene 120-12-7 ???????????咥‵???
?????????????
GCMS
4?4’-???????4,4'- Diaminodiphenylmethane 101-77-9 ????????????????
????????????
GCMS
????????Dibutyl phthalate 84-74-2
???????‵?????????
????Ё???????????
?
GCMS
????Cobalt dichloride 7646-79-9 ????????????????
???
ICP/AAS
IC
?????Diarsenic pentaoxide 1303-28-2 ????????????????
???????
ICP/AAS
?????Diarsenic trioxide 1327-53-3
???????????????г
??????????????ㄝ?
?Ё
ICP/AAS
????Sodium dichromate 7789-12-0 ??????????有?????
???????
UV-VIS
???呱佭
5-tert-butyl-2,4,6-trinitro-m-xylene (musk xylene) 81-15-2 佭?????佭?????????
?Ё
GCMS
???????2-Э?????Bis (2-ethyl(hexyl)phthalate) (DEHP) 117-81-7 ??Э???Э?????????
???????????????
GCMS
?⒈????????Hexabromocyclododecane(HBCDD)
and all major diastereoisomers identified(?–HBCDD,?-HBCDD,?-HBCDD) 3194-55-6 ????????????????
???
GCMS
C10-13 ??????
Alkanes, C10-13, chloro (Short Chain Chlorinated Paraffins) 85535-84-8
????????????????
???????????‵????
ㄝ
GCMS
??????Bis(tributyltin)oxide 56-35-9 ?????????????????
??ㄝ
GCMS
????Lead hydrogen arsenate 7784-40-9 ?????????????ICP/AAS
????????Benzyl butyl phthalate 85-68-7
?????????????Э??
‵?ㄦ???????????ㄝ?
???Э????????
GCMS
?Э????Triethyl arsenate 15606-95-8 ??????????????ICP/AAS 2. Thermo Fisher?Reach?????????ˉ??丙
ISQ?????
? ? ??7KHUPRILVKHU?????咥$QDO\WLFD ??????????????????????,64?,64????7KHUPRILVKHU????????催?????????????ぎ??????⑤???????????([WUDFWD%ULWH噡??⑤????????????????????????????????
,64?????
??([WUDFWD%ULWH噡??⑤???????????????????
??????ぎ???????????⑤???????????????????????
????????????????? DPX???? DPX V?????催???????????! X? VFDQV V ?
??????? DPX???????????????
????????7KHUPR 6FLHQWLILF 4XDQ/DE )RUPV?????????????????????????催?????
????Triplus????????????乊ぎ?SPME???????г??????????????????????∈?Ё???????
3. Thermo Fisher?Reach?????????ˉ??丙
3.1?Anthracene?PAHs?
??16??????佭??PAHs?Ё???
1 Naphthalene ?
2 Acenaphthylene ??
3 Acenaphthene ?
4 Fluorene ?
5 Phenanthrene ?
6 Anthracene ?
7 Fluoranthene ??
8 Pyrene ?
9 Benzo(a)anthracene ???a??
10 Chrysene ?
11 Benzo(b)fluoranthene ???b???
12 Benzo(k)fluoranthene ??(k)??
13 Benzo(a)pyrene ???a??
14 Indeno(1,2,3-cd)pyrene ???1,2,3-cd??
15 Dibenzo(a,h)anthracene ????a, n??
16 Benzo(g,hi)perylene ???ghi????????
??????
PVC???‵???????1g???10ml???????1?1??????30min??????????SPE?????????????????????????GCMS?????????????????????????????????????????
???ZEK01, EPA3550B,EPA3540C,EPA3546ㄝ??
?????
AS?1ul
GC?SSL, 270?; splitless time =1min
50? (1min), 25?/min, 140?, 10?/min, 240?, 5?/min,300?(5min)
TR-5ms (30m, 0.25mm, 0.25um)
Transfer line: 280?
Flow rate: 1ml/min
06 Ion source: 250?
Full Scan: 50ˉ350 m/z
SIM: ??178m/z?
D:\????偠\SGS-SVOC-DATA\data0231/07/2008 17:34:53
RT:21.30 - 22.01SM:15G
3.2 4,4’-???????
4,4’-????????23?????Ё???
?????
?????GB/T19942-2005??
????
AS?1ul
GC?SSL, 250?; splitless time =1min
50? (1min), 20?/min, 150??8min?, 20?/min, 230??13min?, 20?/min,280?(1min) TR-5ms (30m, 0.25mm, 0.25um)
Transfer line: 280?
Flow rate: 1ml/min
06 Ion source: 290?
Full Scan: 50ˉ300 m/z
SIM: 4,4’-???????(198m/z?
D:\????偠\...\std30ppm_08102814073228/10/2008 14:07:32
RT:18.22 - 23.78SM:
15G
?????PAHs??????EN14362, EPA3540C, EPA3546ㄝ??
????
AS?1ul
GC?SSL, 250?;????????: 150:1
120? (1min), 25?/min, 280??10min?
TR-5ms (30m, 0.25mm, 0.25um)
Transfer line: 280?
Flow rate: 1ml/min
06 Ion source: 250?
Full Scan: 40ˉ450 m/z
3.4???呱佭
??????EPA3540C, EPA3550B ㄝ??.??1.0g ??,???????30min, ?Ё??????????,??????10ml, ??????.
????
AS ?1ul
GC ?SSL, 280?; splitless time =1min
50? (1min), 25?/min, 280??0.5min ?
TR-5ms (30m, 0.25mm, 0.25um)
Transfer line: 280?
Flow rate: 1ml/min
06 Ion source: 200?
Time (min)R e l a t i v e A b u n d a n c e
SIM: 4,4’-???????(282m/z?
Muskxylene-1ppm430/08/2010 11:51:55
3.5?⒈????
???????EPA3540C?EPA3546ㄝ????0.5g????????????30?????????????130mL???????????????????????
????
AS?1ul
GC?SSL, 280?; splitless time =1min
50? (1min), 25?/min, 280??5min?
TR-5ms (10m, 0.25mm, 0.1um)
Transfer line: 280?
Flow rate: 1.5 ml/min
06 Ion source: 200?
F:\Wendy\...\HBCD-Fullscan-3-36ppm31/08/2010 11:36:57
3.6 C10-C13??????
???????EPA3540C?EPA3546ㄝ????0.5g????????????30?????????????130mL???????????????????????
????
AS?1ul
GC?SSL, 280?; splitless time =1min
50? (1min), 25?/min, 280??0.5min?
TR-5ms (30m, 0.25mm, 0.25um)
Transfer line: 280?
Flow rate: 1ml/min
06 Ion source: 200?
SIM: SCCP (89, 115amu)
F:\Wendy\SCCP\20100831\SCCP-100ppm31/08/2010 21:50:48
f:\wendy\sccp\20100831\sccp-5ppm-231/08/2010 19:03:06
RT:0.00 - 15.19SM:15G
3.7??????????????
?????????DIN EN ISO 17353-2005, GB/T 20385-2006, GB/T22932-2008ㄝ
??2g?????250mL???Ё???100mL??????⒊?????38-40???30??????????25mL??⒊??50mL????Ё???250μl??????⒊??????????NaOH?pH???4.5??100ul?????5mL??????????????20min????????2g?∈???????Ё??10min???????GCMS ???
??⒊??1????∈Ё⒊?0.5g??-L-????5g????2.2g???????
0.1mol/L?NaOH⒊??pH??5.5?
?????⒊??1?????⒊?82gЭ???500mL??????pH??4.5???????∈?????
?????5???Э????????⒊?
????
AS?1ul
GC?SSL, 240?; splitless time =1min
50? (1min), 20?/min, 280?, 120?/min, 300?
CPSil-8-MS (20m, 0.15mm, 0.15um)
Transfer line: 240?
Flow rate: 0.8ml/min
06 Ion source: 200?
Full Scan: 50ˉ500 m/z
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