Molecular gas in spiral galaxies a new warm phase at large galactocentric distances

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关于太空的信息英文作文

关于太空的信息英文作文

关于太空的信息英文作文Space: A Tapestry of Limitless Wonders.Space, the vast and enigmatic expanse beyond ourplanet's atmosphere, has captivated human imagination for centuries. It holds countless mysteries and infinite possibilities, inviting us to explore its uncharted territories and unravel its profound secrets.A Symphony of Celestial Bodies.Space is a symphony of celestial bodies, each playing a distinct part in the intricate cosmic dance. The Sun, the glowing heart of our solar system, showers Earth with itslife-sustaining rays. Planets, spherical orbs of varying sizes and compositions, orbit the Sun, tracing graceful paths through the void.Earth, our home and the cradle of life, is a vibrantand dynamic planet. Its swirling oceans, verdant continents,and atmospheric envelope create an environment teeming with diversity and wonder. Mars, the Red Planet, holds tantalizing secrets of the past, with evidence of ancient rivers and a potentially habitable environment. Jupiter, the colossal gas giant, reigns supreme in our solar system, its swirling atmosphere and Great Red Spot an awe-inspiring sight. Saturn, adorned with its iconic rings, presents a breathtaking spectacle that has captivated astronomers and poets alike.Beyond our solar system lies a universe teeming with galaxies, each a teeming city of stars and celestial wonders. The Milky Way, our home galaxy, is a spiral tapestry of stars, nebulae, and star clusters. Andromeda, our nearest major galactic neighbor, mirrors our own, a celestial twin beckoning for exploration.Cosmic Phenomena.Space is not merely a backdrop for celestial bodies; it is also a realm of dynamic phenomena that shape the fabric of our understanding.Nebulae, vast clouds of gas and dust, serve as stellar nurseries where stars are born. Supernovae, the explosive deaths of massive stars, release unimaginable amounts of energy, enriching the interstellar medium with heavy elements. Black holes, enigmatic celestial bodies with gravitational pulls so strong that not even light can escape, defy our comprehension and hint at the existence of cosmic riddles yet to be solved.Space Exploration: A Leap into the Unknown.Driven by an insatiable thirst for knowledge and the allure of the unknown, humans have ventured into space, their intrepid footsteps marking milestones in our collective exploration.The first artificial satellite, Sputnik, launched in 1957, ushered in the Space Age. Since then, countless satellites, probes, and spacecraft have traversed the vastness of space, gathering data, conducting experiments, and expanding our understanding of the cosmos.Humans have also ventured beyond Earth's protective atmosphere, leaving their footprints on the lunar surface during the Apollo missions. The International Space Station, a testament to international cooperation, has become a continuous habitat for astronauts from around the world, conducting cutting-edge research and pushing the boundaries of human endurance.Space Assets and Technology.Space exploration has not only expanded our scientific knowledge but has also led to the development of transformative technologies that permeate our daily lives.Satellites enable global communication, navigation, and weather forecasting. Space-based imaging systems providevital data for agriculture, disaster relief, and environmental monitoring. Space technology has also revolutionized industries such as healthcare, manufacturing, and transportation.The advancements made in space exploration have not only satisfied our curiosity but have also brought tangible benefits to our planet and its inhabitants.Space Challenges and Future Perspectives.Despite the remarkable progress made in space exploration, significant challenges remain. Radiation exposure, microgravity, and the need for self-sufficiency pose risks to astronauts and long-term space missions. Ethical concerns surrounding the colonization of space and the potential impact on indigenous celestial environments also warrant thoughtful consideration.The future of space exploration is as vast and promising as the cosmos itself. The exploration of Mars, the search for life beyond Earth, and the development of new space technologies are just a few of the endeavors that lie ahead.A Tapestry of Wonder and Discovery.Space is a tapestry of wonder, discovery, and limitless possibilities. As we continue to explore this vast expanse, we not only expand our scientific knowledge but also deepen our appreciation for the fragility and interconnectedness of our own planet.The cosmos holds endless secrets and promises toinspire and awe generations to come. It is a testament to human ingenuity, our unwavering quest for knowledge, and our enduring fascination with the enigmatic realm that lies beyond our world.。

介绍星系的英语作文

介绍星系的英语作文

介绍星系的英语作文English:A galaxy is a massive system of stars, gas, dust, and dark matter bound together by gravity. There are billions of galaxies in the universe, each one containing billions to trillions of stars. The Milky Way, our own galaxy, is a spiral galaxy with a central bulge surrounded by arms of stars spiraling outwards. Galaxies come in various shapes and sizes, including elliptical, spiral, and irregular. They can also interact with each other, leading to beautiful and complex structures known as galaxy mergers. Galaxies are not randomly distributed in the universe but instead form clusters and superclusters. The study of galaxies and their evolution helps us understand the origins and dynamics of the universe on a larger scale.中文翻译:星系是由恒星、气体、尘埃和暗物质所组成的庞大系统,它们被引力绑在一起。

宇宙中有数十亿个星系,每一个星系都包含数十亿到数万亿颗恒星。

Recent development of in silico molecular modeling for gas and

Recent development of in silico molecular modeling for gas and

Available online at Recent development of in silico molecular modeling for gas and liquid separations in metal–organic frameworksJianwen JiangAs a new family of nanoporous materials,metal–organic frameworks(MOFs)are considered versatile materials for widespread applications.Majority of current studies in MOFs have been experimentally based,thus little fundamental guidance exists for the judicious screening and design of task-specific MOFs.With synergistic advances in mathematical methods,computational hardware and software,in silico molecular modeling has become an indispensable tool to unravel microscopic properties in MOFs that are otherwise experimentally inaccessible or difficult to obtain.In this article,the recent development of molecular modeling is critically highlighted for gas and liquid separations in MOFs.Bottom-up strategies have been proposed for gas separation in MOFs,particularly CO2capture.Meanwhile, interest for liquid separation in MOFs is growing and modeling is expected to provide in-depth mechanistic understanding. Despite considerable achievements,substantial challenges and new opportunities are foreseeable in more practical modeling endeavors for economically viable separationsin MOFs.AddressDepartment of Chemical and Biomolecular Engineering,National University of Singapore,117576,SingaporeCorresponding author:Jiang,Jianwen(chejj@.sg)Current Opinion in Chemical Engineering2012,1:138–144This review comes from a themed issue onNanotechnologyEdited by Hua Chun ZengAvailable online23rd December20112211-3398/$–see front matter#2011Elsevier Ltd.All rights reserved.DOI10.1016/j.coche.2011.11.002IntroductionDuring the past decade,metal–organic frameworks (MOFs)have emerged as a new family of nanoporous materials[1,2].In remarkable contrast to traditional inor-ganic zeolites,MOFs can be synthesized from various inorganic clusters and organic linkers,thus possess a wide range of surface area and pore size.More fascinatingly, the judicious selection of building blocks allows the pore volume and functionality to be tailored in a rational manner.With such salient features,MOFs are considered versatile materials for widespread potential applications [3,4]as illustrated in Figure1.Indeed,MOFs have been identified as a topical area in materials science and technology because of their implications for global and national economies[5].To date,thousands of MOFs have been synthesized in this vibrantfield and several(Cu-BTC,ZIF-8,MIL-53,etc.) are commercially available under the trade name Basoli-te TM[6].However,massive research efforts on MOFs have been primarily based on experiments.It is impractical to search for task-specific MOFs by trial-and-error from infinitely large number of possible candidates.Therefore, quantitative guidelines are desired for the high-throughput screening of enormous MOFs and the rational design of new MOFs towards practical applications.In this context, clear and deep microscopic understanding from a molecu-lar level is indispensable.With synergistic advances in mathematical methods,computational hardware and soft-ware,in silico molecular modeling has played an increas-ingly important role in unraveling microscopic properties in MOFs[7 ,8 ,9 ].Sophisticated modeling and simu-lation provide molecular insights that are experimentally intractable,if not impossible,thus elucidate underlying physics from bottom-up.Among many potential appli-cations of MOFs,separations are of central importance in chemical industry and have been actively investigated [10].In this article,the recent development of molecular modeling is critically highlighted for both gas and liquid separations in MOFs,and the foreseeable challenges and opportunities are discussed.Gas separationThe overwhelming majority of studies for gas separation in MOFs have been focused on CO2capture.This is because the combustion of fossil fuels produces a huge quantity of CO2emissions into the atmosphere.Carbon capture and sequestration is crucial to environmental protection and sustainable economy.As an essential pre-requisite,CO2has to be captured fromflue gas/ shifted syngas in post-/pre-combustion processes. Another important gas separation involving CO2is puri-fication of natural gas,in which impurities such as CO2 need to be separated to enhance calorie content.MOF adsorbentsMost synthesized MOFs are crystallites and tested as adsorbents for gas separation.Several reviews have sum-marized numerous experimental studies for CO2capture in MOF adsorbents[11–13].Nevertheless,nearly all these experiments examined the adsorption of pure gases (e.g.CO2,N2,CH4,and H2)due to the formidable difficulty associated with mixtures.By contrast,simu-lation can be readily used for single or multi-componentsystems.Thus,quantitative understanding of mixture adsorption in MOFs has been obtained,to a large extent,from simulation studies.Several bottom-up strategies as illustrated in Figure 2have been proposed to tune CO 2capture performance,for example,using specific MOFs with small pores,catenation,functionalization,ionic fra-meworks,exposed metals or metal doping.Yang and Zhong [14]simulated the adsorption of CO 2/CH 4/H 2mixture in two MOFs (IRMOF-1and Cu-BTC)and found pore size strongly affects separation efficiency.However,IRMOF-1and Cu-BTC do not possess iden-tical topology,leading to ambiguous interplay with the effect of pore size.In this regard,Babarao et al.[15]examined the separation of CO 2/CH 4mixture in isostruc-tural MOFs (Cu-BTC and PCN-60)and observed that the selectivity in Cu-BTC with small pores is nearly twice of that in PCN-60.This strategy of small pores is also reflected in framework catenation that can induce con-stricted pores and greater potential overlaps.For example,catenated IRMOF-13and PCN-6exhibit a larger selectivity for CO 2/CH 4mixture than non-cate-nated counterparts [15].An appealing strategy is to use ionic MOFs as demonstrated by Jiang and co-workers [16,17 ,18]for the separation of CO 2-containing mixtures.Simulation reveals that CO 2molecules are strongly adsorbed onto the ionic frameworks and nonframeworkions,and the predicted selectivity is significantly higher than in neutral MOFs and many other nanoporous materials.On the other hand,Yazaydin et al.[19]screened a diverse set of 14MOFs for low-pressure CO 2capture from flue gas combining simulation and experiment.The results show that M/DOBDC (M =Zn,Mg,Co or Ni)with high density of exposed metals strongly interact with CO 2.By physical and chemical doping,Xu et al.[20 ]estimated the separation of CO 2/CH 4mixtures in Li-modified MOF-5.Owing to the enhancement of electro-static potentials,adsorption selectivity was predicted to be much higher than in MOF-5.In a separate study,Lan et al.[21 ]simulated CO 2capture in covalent-organic frameworks doped by alkali,alkaline-earth and transition metals,and concluded that Li is the best surface modifier for CO 2capture.The strategies outlined in Figure 2have been compre-hensively discussed [24 ,25 ].Two of them (ionic fra-meworks and metal doping)appear to be more efficient to enhance CO 2capture.It should be noted that these strategies also can tune the separation of other mixtures,for example,the selectivity of alkane isomers was found to be enhanced by framework catenation [26].In a recent perspective,Krishna and van Baten [27 ]highlighted the potency of simulation in screening of best MOFs for CO 2capture and hydrocarbon separation,and they furtherRecent development of in silico molecular modeling Jiang 139Figure 1Purification Toxics RemovalDrug DeliveryFuel Cell SystemsStorageStorage and SeparationCarbon SequestrationSensingMOPWidespread potential applications of MOFs (/ees6/clathrates/index.shtml ).compared MOFs against traditional zeolites with regard to separation characteristics.As an alternative to simulation,analytical theories have been developed for gas separation in MOFs.Liu et al.[28,29]proposed a density functional theory (DFT)in 3D-nanoconfined space.The theory was applied to adsorption and separation in 3D-MOFs with complex pore networks,whereas most DFT studies are limited in simple confined geometries (e.g.slit and cylindrical pores).Good agree-ment was obtained between theoretical predictions,simu-lation and experimental data.Coudert et al.[30]developed the osmotic framework adsorbed solution theory (OFAST)in terms of a competition between host’s free energy and adsorption energy.This theory is based exclusively on pure-component adsorption and has the superior capability to describe flexible MOFs.For illustration,the authors used the OFAST to examine the effect of breathing on separation of CO 2/CH 4mixtures in MIL-53.The modeling studies discussed above for gas separation in MOF adsorbents are primarily focused on adsorption selectivity.However,several other factors (e.g.working capacity,regenerability,etc.)should be included in prac-tice as discussed by Bae and Snurr [31 ].Another crucial issue is how moisture in gas mixtures would affect sep-aration performance?From systematical simulation stu-dies in various neutral and ionic MOFs,Jiang and coworkers observed four different intriguing effects ofH 2O on CO 2capture [25 ].It is also instructive to examine structural change in flexible MOFs that might occur upon adsorption [32].The incorporation of flexi-bility to simulate structural change would need a robust force field.However,a general force field is currently unavailable for MOFs and first-principles modeling is expected to play a pivotal role [33 ].In addition,the chemical and thermal stability of MOFs are important for separation [34].A large number of MOFs are unstable in atmosphere or under moisture,which impedes their util-ization.Therefore,it is indispensable to develop molecu-lar guidelines for the design of stable MOFs.Nevertheless,unraveling what govern the stability of MOFs at a microscopic level is a challenge.MOF membranesCompared with adsorptive separation,membrane-based separation is considered to be energetically more effi-cient,lower capital cost and larger separation capability.However,the fabrication of MOF membranes is a for-midable task [35].Only in recent years,have there been active experimental endeavors to explore MOF mem-branes for gas separation [36 ].Since both equilibrium and dynamic properties are required,simulation for gas separation in MOF mem-branes is more time-consuming than in MOF adsorbents.Nevertheless,a handful of simulation studies have been reported.Keskin and Sholl [37 ]examined the separation140NanotechnologyFigure 2functionalizationmetal dopingionic frameworksexposed metalssmall porescatenationBottom-up strategies to tune CO 2capture performance.The representative MOFs are from [15,17 ,20 ,22,23].performance of diverse MOFs for CO2/CH4and CO2/H2 mixtures.They found that all the MOFs examined exhi-bit unfavorably low CO2selectivities and mixture effects play a crucial role in determining the performance.By combining simulation and IR microscopy,Bux et al.[38] simulated ethene/ethane separation in ZIF-8membrane. They found that ethane adsorbs more strongly than ethene,but ethene diffuses faster;and the interplay results in a membrane permeation selectivity for ethene. Krishna and van Baten[27 ]underlined the advantages of using simulation tools in the screening of MOF mem-branes for CO2capture.Along with considerable interest in MOF membranes, MOF-based composite membranes have received increasing attention for gas separation.In this emerging area,a handful of experiments have been conducted[39], but modeling studies are ing atomistic simulation and continuum model,Keskin and Sholl[40]attempted to select MOF/polymer membranes for high-perform-ance gas separation.A highly selective MOF was ident-ified and predicted to enhance the performance of Matrimid and other polymers for CO2/CH4separation. Chen et al.[41]proposed a composite with ionic liquid (IL)supported on IRMOF-1.The simulation reveals that ions in the composite act as favorable sites for CO2adsorption,and the selectivity for CO2/N2mixture is higher than in neat IL,IRMOF-1and many other supported IL membranes.It is worthwhile to note that defects and inter-crystalline interstices usually exist in synthesized MOF membranes. Nevertheless,most simulation studies use perfect and rigid models for MOF membranes.How to incorporate defects and interstices into practical modeling is challenging.On the other hand,theflexibility of MOF structures may have a larger influence in membrane separation than adsorbent separation[36 ],and should be implemented as well into modeling.Another essential issue is the mech-anical properties of MOFs[42].The high pressure exerted for membrane separation may distort MOF structures and deteriorate performance.It is thus crucial to quantitatively understand how pressure affects pore geometries and framework dimensionalities.For MOF-based composite membranes,microscopic insights into the interactions between MOF and other species(e.g.polymer or ionic liquid)are strikingly important and fundamental studies at a molecular level are desired.Liquid separationWhile gas separation in MOFs has been extensively investigated,endeavors for liquid separation are lagged behind[43 ].A recent trend has been to explore the use of MOF adsorbents and membranes for liquid separation. By combining chromatographic and breakthrough exper-iments,Alaerts et al.determined the adsorption and separation of ortho-substituted alkylaromatics(xylenes, ethylbenzene,ethyltoluenes and cymenes)in a column packed with MIL-53crystallites[44].Jin and coworkers tested the separation of water/organics mixtures in MIL-53membrane and observed a high selectivity for water removal from ethyl acetate solution[45].Simulation for liquid separation in MOFs is scarce owing to the significant amount of computational time required to sample liquid phase.Consequently,the microscopic understanding of liquid separation in MOFs is far from complete.To the best of our knowledge,only two simu-lation studies have been reported in this area,one for water desalination and the other for biofuel purification. Recent development of in silico molecular modeling Jiang141Figure3Selectivities of biofuel in Na-rho-ZMOF and Zn4O(bdc)(bpz)2by pervaporation[47 ].Specifically,Hu et al.[46]performed simulation on the desalination of NaCl aqueous solution through a ZIF-8 membrane by reverse osmosis.Because of the sieving effect of small apertures in ZIF-8,Na+and ClÀions could not transport through ZIF-8membrane and water desa-lination was observed.Theflux of water permeating the membrane was found to scale linearly with external pressure.In a separate study,Nalaparaju et al.[47 ] examined hydrophilic Na-rho-ZMOF and hydrophobic Zn4O(bdc)(bpz)2for biofuel purification.The selectiv-ities between water and ethanol in the two MOFs are largely determined by adsorption behavior.As indicated in Figure3,Na-rho-ZMOF is preferable to remove water, whereas Zn4O(bdc)(bpz)2is promising to enrich ethanol. The simulation provides molecular guidelines for the selection of appropriate MOFs towards efficient biofuel purification.Currently,modeling for liquid separation in MOFs is very limited.With increasing demands for clean water,liquid fuels and other liquid-based applications,more efforts are expected in order to provide deep molecular insights.A pre-requisite for liquid separation is that the MOFs used should be stable in water or other liquids[48],it is crucial to understand what factors govern the stability of MOFs, which would allow to produce stable MOFs for liquid separation.ConclusionAs a burgeoningfield,research activities in MOFs are rather hectic.In addition to enormous experimental stu-dies,we have witnessed the recent development of in silico molecular modeling for MOFs.Microscopic under-standing has been achieved for gas separation particularly CO2capture in MOFs,and bottom-up strategies have been proposed to enhance separation efficiency.How-ever,liquid separation in MOFs remains largely unex-plored at a molecular level and more endeavors are desired towards this end.It is obvious that current molecular modeling for separ-ations using MOFs is still in an infant stage.As discussed above,substantial challenges are foreseen for more prac-tical modeling and precise description.A number of issues should be considered in future modeling,such as the stability and mechanical properties of MOFs, structuralflexibility,material regenerability,and effect of moisture(in gas separation).These challenges provide new opportunities for modeling studies to unravel in-depth microscopic insights and thus provide quantitative guidelines on the rational screening and design of novel MOFs.Furthermore,for energy-efficient and cost-effec-tive separations,process requirements are essential to be integrated with material properties at a system level.In this context,molecular modeling,process optimization, as well as material synthesis,should be synergized holi-stically towards the development of best MOFs for economically viable separations and other practical appli-cations.AcknowledgementsThe author gratefully acknowledges the National University of Singapore, the Singapore National Research Foundation,and the Ministry of Education of Singapore for support.References and recommended readingPapers of particular interest,published within the period of review, have been highlighted as:of special interestof outstanding interest1.Yaghi OM,O’Keefe M,Ockwig NW,Chae HK,Eddaoudi M,Kim J:Reticular synthesis and design of new materials.Nature2003, 423:705-714.2.Long JR,Yaghi OM:The pervasive chemistry of metal–organicframeworks.Chem Soc Rev2009,38:1213-1214.3.MacGillivray LR(Ed):Metal–Organic Frameworks:Design andApplication.Hoboken,New Jersey:John Wiley&Sons,Inc.;2010.4.Farrusseng D(Ed):Metal–Organic Frameworks:Applications fromCatalysis to Gas Storage.Weinheim,Germany:Wiley-VCH;2011.5.Adams J,Pendlebury D:Global Research Report:MaterialsScience and Technology.Leeds,UK:Thomson Reuters;2011. 6.Czaja AU,Trukhan N,Muller U:Industrial applications of metal–organic frameworks.Chem Soc Rev2009,38:1284-1293.7.Keskin S,Liu J,Rankin RB,Johnson JK,Sholl DS:Progress,opportunities,and challenges for applying atomically detailed modeling to molecular adsorption and transport in metal–organic framework materials.Ind Eng Chem Res2009,48:2355-2371.This article reviews the applications of atomically detailed modeling for MOFs.Quantum mechanical calculations are used to examine structural and electronic properties,while molecular modeling calculations are used to study adsorption and diffusion in MOFs.8.DU¨ren T,Bae YS,Snurr RQ:Using molecular simulation tocharacterise metal–organic frameworks for adsorptionapplications.Chem Soc Rev2009,38:1203-1212.This review gives an overview of how molecular simulation can be used to characterize MOFs for gas adsorption,and how molecular insights can be combined to develop design principles for specific applications.9.Jiang JW,Babarao R,Hu ZQ:Molecular simulations for energy, environmental and pharmaceutical applications of nanoporous materials:from zeolites,metal–organic frameworks to protein crystals.Chem Soc Rev2011,40:3599-3612.This review summarizes the recent simulation studies for energy,envir-onmental and pharmaceutical applications of nanoporous materials ran-ging from zeolites,MOFs to protein crystals with increasing degree of complexity in building blocks.Major challenges in future simulation exploration are discussed.10.Li JR,Sculley J,Zhou HC:Metal–organic frameworks forseparations.Chem Rev2012,112,doi:10.1021/cr200190s,inpress.11.Keskin S,van Heest TM,Sholl DS:Can metal–organicframework materials play a useful role in large-scale carbon dioxide separations?ChemSusChem2010,3:879-891.12.Fe´rey G,Serre C,Devic T,Maurin G,Jobic H,Llewellyn PL,Weireld GD,Vimont A,Daturi M,Chang JS:Why hybrid porous solids capture greenhouse gases?Chem Soc Rev2011,40:550-562.13.Li JR,Ma YG,McCarthy MC,Sculley J,Yu JM,Jeong HK,Balbuena PB,Zhou HC:Carbon dioxide capture-related gasadsorption and separation in metal–organic frameworks.Coord Chem Rev2011,255:1791-1823.14.Yang QY,Zhong CL:Molecular simulation of CO2/CH4/H2mixture adsorption in metal–organic frameworks.J Phys Chem B2006,110:17776-17783.142Nanotechnology15.Babarao R,Jiang JW,Sandler SI:Adsorptive separation of CO2/CH4mixture in metal–exposed,catenated and charged metal–organic frameworks:insight from molecular simulation.Langmuir2009,25:5239-5247.16.Jiang JW:Charged soc metal–organic framework for high-efficacy H2adsorption and syngas purification:atomisticsimulation study.AIChE J2009,55:2422-2432.17. Babarao R,Jiang JW:Unprecedentedly high selective adsorption of gas mixtures in rho zeolite-like metal–organic framework:a molecular simulation study.J Am Chem Soc 2009,131:11417-11425.A simulation study is reported for the separation of CO2-containingmixtures in rho zeolite-like MOF(ZMOF)with anionic framework.Forthefirst time,this study characterizes nonframework Na+ions,examines gas separation in ionic ZMOF,and reveals that rho-ZMOF is a promisingcandidate for CO2capture.18.Babarao R,Eddaoudi M,Jiang JW:Highly porous ionic rhtmetal–organic framework for H2and CO2storage andngmuir2010,26:11196-11203.19.Yazaydin AO,Snurr RQ,Park TH,Koh K,Liu J,LeVan MD,Benin AI,Jakubczak P,Lanuza M,Galloway DB et al.:Screeningof MOFs for CO2capture fromflue gas using a combinedexperimental and modeling approach.J Am Chem Soc2009,131:18198-18199.20. Xu Q,Liu DH,Yang QY,Zhong CL,Mi JG:Li-modified metal–organic frameworks for CO2/CH4separation.J Mater Chem 2010,20:706-714.The separation of CO2/CH4mixtures is simulated in Li-modified MOF-5. The selectivity is found to be greatly improved owing to the enhancement of electrostatic potential by Li doping.21. Lan JH,Cao DP,Wang WC,Smit B:Doping of alkali,alkaline-earth,and transition metals in covalent-organic frameworks for enhancing CO2capture byfirst-principles calculations and molecular simulations.ACS Nano2010,4:4225-4237.This study examines the doping of a series of alkali(Li,Na,and K), alkaline-earth(Be,Mg,and Ca),and transition(Sc and Ti)metals in covalent-organic frameworks,and the effects of the doped metals on CO2capture.22.Dietzel PDC,Johnsen RE,Fjellvag H,Bordiga S,Groppo E,Chavan S,Blom R:Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organicframework Ni2(dhtp)from gas adsorption.IR spectroscopyand X-ray diffraction.Chem Commun2008,44:5125-5127.23.Babarao R,Dai S,Jiang DE:Functionalizing porous aromaticframeworks with polar organic groups for high-capacity and selective CO2separation:a molecular simulation study.Langmuir2011,27:3451-3460.24. Liu DH,Zhong CL:Understanding gas separation in metal–organic frameworks.J Mater Chem2010,20:10308-10318.This feature article summarizes the recent advances of computer model-ing on gas separation in MOFs and demonstrates how computer model-ing can help to understand the separation characteristics of MOFs.Several strategies are proposed to improve the separation efficiency of MOFs.25. Jiang JW:Metal–organic frameworks for CO2capture:what are learned from molecular simulations.In Coordination Polymers and Metal Organic Frameworks.Edited by OO L,Ramı´rez LD.Nova Science Publishers;2011.In this book chapter,recent simulation studies are summarized for CO2 capture in MOFs.A number of strategies are discussed towards improv-ing capture performance.In addition,the effects of moisture in various MOFs on CO2adsorption and separation are presented.26.Babarao R,Tong YH,Jiang JW:Molecular insight intoadsorption and diffusion of alkane isomer mixtures in metal–organic frameworks.J Phys Chem B2009,113:9129-9136.27. Krishna R,van Baten JM:In silico screening of metal–organic frameworks in separation applications.Phys Chem Chem Phys 2011,13:10510-10593.This perspective highlights the potency of molecular simulation in deter-mining the best MOF for a given separation task.A variety of metrics that quantify separation performance such as adsorption selectivity,working capacity,diffusion selectivity and membrane permeability are determined by simulation.28.Liu Y,Liu HL,Hu Y,Jiang JW:Development of a densityfunctional theory in three-dimensional nanoconfined space:H2storage in metal–organic frameworks.J Phys Chem B2009, 113:12326-12331.29.Liu Y,Liu HL,Hu Y,Jiang JW:Density functional theory foradsorption of gas mixtures in metal–organic frameworks.J Phys Chem B2010,114:2820-2827.30.Coudert FX,Mellot-Draznieks C,Fuchs AH,Boutin A:Predictionof breathing and gate-opening transitions upon binary mixture adsorption in metal–organic frameworks.J Am Chem Soc2009,131:11329-11331.31.Bae YS,Snurr RQ:Development and evaluation of porousmaterials for carbon dioxide separation and capture.AngewChem Int Ed2011,50:11586-11596.The question of how a large number of MOFs can be quickly evaluated for CO2separation is addressed.Five adsorbent evaluation criteria are described and used to assess over40MOFs for their potential in CO2 separation processes for natural gas purification,landfill gas separation, and CO2capture from power-plantflue gas.32.Horike S,Shimomura S,Kitagawa S:Soft porous crystals.NatChem2009,1:695-704.33.Tafipolsky M,Amirjalayer S,Schmid R:Atomistic theoreticalmodels for nanoporous hybrid materials.MicroporousMesoporous Mater2010,129:304-318.Available atomistic theoretical models are overviewed for the new class of functional porous hybrid materials such as MOFs and COFs.The current status of both periodic and non-periodic quantum mechanic,as well as molecular mechanic models are discussed.34.Kang IJ,Khan NA,Haque E,Jhung SH:Chemical and thermalstability of isotypic metal–organic frameworks.Chem Eur J2011,17:6437-6442.35.Shekhah O,Liu J,Fischer RA,Woll C:MOF thinfilms:existingand future applications.Chem Soc Rev2011,40:1081-1106. 36.Caro J:Are MOF membranes better in gas separation thanthose made of zeolites.Curr Opin Chem Eng2011,1:77-83. MOF membranes developed and tested for gas separation during the past5years have been reviewed.The structuralflexibility of MOFs prevents a sharp molecular sieving effect.Mixed-matrix membranes containing MOFs are predicted for the near future.37.Keskin S,Sholl DS:Efficient methods for screening of metalorganic framework membranes for gas separations usingatomically detailed ngmuir2009,25:11786-11795. An efficient approximate method is introduced to screen MOF mem-branes for gas separation with a connection between mixture adsorption and mixture self-diffusion properties.The method is applied to MOF membranes with chemical diversity for light gas separation.38.Bux H,Chmelik C,Krishna R,Caro J:Ethene/ethane separationby ZIF-8membrane:molecular correlation of permeation,adsorption,diffusion.J Membr Sci2011,369:284-289.39.Vinh-Thang H,Kaliaguine S:MOF-based mixed-matrix-membranes for industrial applications.In CoordinationPolymers and Metal Organic Frameworks.Edited by Ortiz OL,Ramı´rez LD.Nova Science Publishers;2011.40.Keskin S,Sholl DS:Selecting metal organic frameworks asenabling materials in mixed matrix membranes for highefficiency natural gas purification.Energy Environ Sci2010,3:343-351.41.Chen YF,Hu ZQ,Gupta KM,Jiang JW:Ionic liquid/metal–organicframework composite for CO2capture:a computationalinvestigation.J Phys Chem C2011,115:21736-21742.42.Tan JC,Cheetham AK:Mechanical properties of hybridinorganic-organic framework materials:establishingfundamental structure–property relationships.Chem Soc Rev 2011,40:1059-1080.43.Cychosz KA,Ahmad R,Matzger AJ:Liquid phase separation by crystalline microporous coordination polymers.Chem Sci2010,1:293-302.This perspective details the experimental studies reported on liquid-phase separation using microporous coordination polymers(MCPs).Guest mole-cules examined include those as small as water to large organic dyes.In many cases,MCPs outperform zeolites and activated carbons in both kinetics and efficiency.Recent development of in silico molecular modeling Jiang143。

宇宙英文作文故事

宇宙英文作文故事

宇宙英文作文故事Title: Exploring the Cosmos: A Journey into the Unknown。

In the vast expanse of the cosmos, where stars twinkle like distant dreams and galaxies spiral in infinite dance, lies the boundless frontier of human exploration. This isthe story of intrepid adventurers who dared to venture beyond the familiar confines of Earth, reaching out intothe depths of space in search of understanding, discovery, and wonder.Our tale begins with the pioneers of space exploration, whose vision and courage paved the way for humanity's first steps beyond our planet's atmosphere. In the 20th century, amidst the tensions of the Cold War, the United States and the Soviet Union engaged in a race to conquer the cosmos. The launch of Sputnik by the Soviets in 1957 marked the dawn of the space age, sparking a fervent competition to achieve milestones such as the first human in space and the first manned lunar landing.In 1969, the world held its breath as Neil Armstrong and Buzz Aldrin set foot upon the lunar surface, uttering immortal words that echoed across the void: "That's one small step for man, one giant leap for mankind." Their historic feat not only demonstrated the triumph of human ingenuity and determination but also opened the door to a new era of exploration.As the decades passed, humanity's reach extended ever deeper into the cosmos. Robotic probes ventured to the outer planets, capturing breathtaking images of Jupiter's swirling storms, Saturn's majestic rings, and the icy moons of Neptune and Uranus. Meanwhile, space telescopes like Hubble peered into the distant reaches of the universe, revealing galaxies billions of light-years away and shedding light on the mysteries of dark matter and dark energy.But the quest for understanding did not end with the confines of our own solar system. In the 21st century, ambitious missions set their sights on distant worldsbeyond, searching for signs of life amidst the stars. The Mars rovers trundled across the red desert sands, analyzing soil samples and probing for evidence of ancient water and organic molecules. Elsewhere, telescopes scanned the skies for exoplanets orbiting distant stars, tantalizing astronomers with the possibility of other Earth-like worlds teeming with life.Yet, as humanity's reach extended further into the cosmos, so too did our awareness of its vastness and complexity. We learned of the violent birth and death of stars, the relentless pull of black holes, and the delicate balance of forces that govern the fabric of spacetime itself. And amidst the grandeur of the cosmos, we found humility in our own insignificance, mere specks of dust adrift in the cosmic ocean.But for all our knowledge and understanding, the cosmos remains a realm of endless possibility and discovery. With each new mission, each new observation, we peel back another layer of the cosmic tapestry, revealing new wonders and new mysteries that beckon us ever onward. For as longas there are stars in the sky and worlds beyond our own, the human spirit of exploration will continue to soar, driven by an insatiable curiosity to know and understand the universe that surrounds us.。

宇宙英语小作文带翻译

宇宙英语小作文带翻译

宇宙英语小作文带翻译Title: The Wonders of the Universe。

The universe is a vast expanse of space filled with countless celestial bodies, each holding its own mysteries and wonders. From the twinkling stars to the massive galaxies, the universe never fails to captivate our imagination and curiosity.First and foremost, let us delve into the beauty of the stars. Stars are like beacons of light scattered across the dark canvas of space. They come in various sizes, colors, and temperatures, each telling its own unique story. Some stars burn brightly, emitting dazzling light that illuminates the surrounding cosmos, while others shine faintly, barely visible to the naked eye. However, regardless of their luminosity, stars play a crucial rolein shaping the universe as we know it. They are responsible for creating elements essential for life, such as carbon, oxygen, and iron, through processes like nuclear fusion.Moreover, galaxies stand as the building blocks of the universe. These vast systems, composed of stars, gas, dust, and dark matter, come in different shapes and sizes. Spiral galaxies, like our own Milky Way, showcase graceful arms swirling around a central bulge, while elliptical galaxies appear as smooth, featureless orbs. Furthermore, irregular galaxies defy conventional classification with their chaotic shapes and structures. Within these galaxies lie billions upon billions of stars, along with planets, nebulae, and other celestial objects, forming a mesmerizing tapestry of cosmic wonders.As we gaze deeper into the universe, we encounter phenomena that challenge our understanding of the laws of physics. Black holes, for instance, are regions of spacetime where gravity is so intense that nothing, not even light, can escape their grasp. These enigmatic objects are born from the remnants of massive stars that have reached the end of their life cycle. They serve as cosmic vacuum cleaners, devouring anything that strays too close to their event horizons. Despite their ominous reputation,black holes also play a vital role in shaping galaxies and influencing the distribution of matter in the universe.Furthermore, the universe is filled with cosmic spectacles that leave us in awe of its grandeur. Supernovae, the explosive deaths of massive stars, release unfathomable amounts of energy, briefly outshining entire galaxies. Nebulae, vast clouds of gas and dust, serve as stellar nurseries, where new stars are born amidst swirling cosmic debris. Additionally, pulsars, rapidly spinning neutron stars, emit beams of radiation that sweep across the cosmos like cosmic lighthouses.In conclusion, the universe is a realm of boundless wonder and discovery. From the twinkling stars to the majestic galaxies, from the enigmatic black holes to the dazzling supernovae, the universe never ceases to amaze us with its beauty and complexity. As we continue to explore and unravel its mysteries, we gain a deeper appreciationfor the intricate tapestry of existence that surrounds us.(翻译: 宇宙的奇迹。

宇宙银河系科普英文作文

宇宙银河系科普英文作文

宇宙银河系科普英文作文Title: Exploring the Wonders of the Milky Way Galaxy。

The Milky Way galaxy, our celestial home, is a vast and mysterious expanse that has captured the imaginations of humans for centuries. Stretching across approximately100,000 light-years, it is a swirling mass of stars, planets, nebulae, and other cosmic wonders. Let's embark on a journey to explore the fascinating features of our galaxy.First and foremost, the Milky Way is a barred spiral galaxy, characterized by a central bar-shaped structure surrounded by spiral arms. These arms are comprised of stars, gas, and dust, swirling in a majestic dance through space. Our solar system is situated within one of these spiral arms, known as the Orion Arm or Local Spur.At the heart of the Milky Way lies a supermassive black hole called Sagittarius A. This gravitational behemoth hasa mass equivalent to millions of suns and exerts a powerfulinfluence on the surrounding stars and matter. While it may seem ominous, Sagittarius A plays a crucial role in shaping the dynamics of our galaxy.Throughout the Milky Way, stellar nurseries known as nebulae dot the cosmic landscape. These clouds of gas and dust are where new stars are born, emerging from the swirling mists of creation. One of the most famous examples is the Orion Nebula, a stellar nursery located in the Orion Arm near our solar system.Among the myriad stars that populate the Milky Way, our own sun holds a special place. Classified as a yellow dwarf star, the sun is a relatively average-sized star in terms of mass and luminosity. Yet, it is the source of light and warmth that sustains life on Earth, making it indispensable to our existence.As we journey further into the Milky Way, we encounter a diverse array of star systems and exoplanets. Some of these worlds may harbor conditions conducive to life, sparking the imaginations of scientists and dreamers alike.While the search for extraterrestrial life remains ongoing, each discovery brings us closer to unraveling the mysteries of the cosmos.In addition to stars and planets, the Milky Way is home to various types of celestial phenomena, including supernovae, pulsars, and black holes. These cosmic events shape the evolution of galaxies and contribute to the rich tapestry of the universe. Studying them allows us to gain insight into the fundamental processes that govern the cosmos.One of the most awe-inspiring aspects of the Milky Way is its sheer scale and beauty. From the majestic spiral arms to the glittering star clusters, every corner of our galaxy is a testament to the wonders of the universe. Through telescopes and space probes, we continue to explore and uncover its secrets, expanding our understanding of the cosmos.In conclusion, the Milky Way galaxy is a captivating tapestry of stars, planets, and cosmic phenomena. From itscentral bulge to its spiral arms, it offers a glimpse into the vastness and complexity of the universe. As we continue to explore and study our celestial home, we deepen our appreciation for the beauty and grandeur of the cosmos.。

奇妙星星作文英语

奇妙星星作文英语

奇妙星星作文英语Title: The Wondrous Stars: Exploring the Marvels of the Universe。

In the vast expanse of the universe, amidst the silent darkness, twinkling jewels adorn the velvet canvas of the night sky—stars, the celestial beacons that havecaptivated humanity since time immemorial. Their enigmatic beauty and profound mysteries have inspired wonder, curiosity, and countless contemplations about the nature of existence. Let us embark on a journey through the wondrous realm of stars, exploring their significance, characteristics, and the awe-inspiring phenomena they embody.To begin with, stars are not merely distant luminous points in the sky; they are colossal spheres of glowing gas, primarily hydrogen and helium, held together by their own gravitational force. The process of nuclear fusionoccurring within their cores transforms these elements intoheavier ones, releasing immense amounts of energy in the form of light and heat. This fundamental process powers the radiant brilliance of stars, sustaining life and driving the dynamics of the cosmos.One of the most remarkable aspects of stars is their diverse range of sizes, luminosities, and colors. From the diminutive red dwarfs to the colossal blue giants, stars exhibit a staggering array of physical characteristics, each influencing its lifespan and behavior. The luminosity of a star, for instance, determines its brightness as seen from Earth, while its color—ranging from fiery red to dazzling blue—is indicative of its surface temperature and composition.Moreover, stars are not solitary entities adrift in the emptiness of space; they often congregate in vast stellar communities known as galaxies. Within these cosmic metropolises, stars form intricate patterns and configurations, from the swirling arms of spiral galaxies to the dense cores of elliptical galaxies. Our own Milky Way galaxy, home to billions of stars, serves as atestament to the mesmerizing complexity of galactic ecosystems.Yet, amidst this grandeur, stars also meet their inevitable fate. As they exhaust their nuclear fuel, stars undergo dramatic transformations, culminating in spectacular cosmic events such as supernovae or the serene brilliance of white dwarfs. These phenomena not only mark the end of a star's life but also contribute to the enrichment of the universe, dispersing elements crucial for the formation of new stars, planets, and ultimately, life itself.Beyond their scientific significance, stars hold profound cultural and symbolic meanings for civilizations throughout history. Across diverse cultures and traditions, stars have been revered as symbols of guidance, enlightenment, and transcendence. They have inspired myths, legends, and philosophical contemplations, inviting humanity to ponder its place within the vastness of the cosmos.In conclusion, the wondrous stars transcend mere astronomical objects; they are cosmic storytellers, illuminating the mysteries of the universe and igniting the imagination of humanity. From their humble beginnings in stellar nurseries to their glorious finales in the cosmic tapestry, stars embody the essence of cosmic evolution and the eternal dance of creation and destruction. As we gaze upon the shimmering canopy of the night sky, let us marvel at the majesty of the stars and embrace the profound journey they invite us to undertake—exploring the universe within and beyond.。

关于宇宙的英语作文初二

关于宇宙的英语作文初二

关于宇宙的英语作文初二英文回答:As a middle school student, I am fascinated by the universe and all its mysteries. The universe is a vast and mysterious place, filled with countless stars, planets, galaxies, and more. It is a place of wonder and awe, where we can learn about the origins of the universe and our place in it.One of the most intriguing aspects of the universe is black holes. Black holes are regions of space where gravity is so strong that nothing, not even light, can escape. They are like cosmic vacuum cleaners, sucking in everything that comes too close. Scientists are still trying to understand the nature of black holes and how they affect the surrounding space.Another fascinating phenomenon in the universe is supernovas. Supernovas are massive explosions that occurwhen a star reaches the end of its life cycle. These explosions release an incredible amount of energy and can be seen from millions of light-years away. Supernovas play a crucial role in the formation of new stars and planets.In addition to black holes and supernovas, the universe is also home to countless galaxies, each containingbillions of stars. The Milky Way, our own galaxy, is just one of billions in the universe. Galaxies come in all shapes and sizes, from spiral galaxies like our own to irregular and elliptical galaxies.Overall, the universe is a place of endless wonder and discovery. There is still so much we don't know about the universe, and every new discovery brings us closer to understanding its vastness and complexity.中文回答:作为一名初中生,我对宇宙及其所有的奥秘都充满了兴趣。

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1.
Introduction
The use of 12 CO, the most abundant molecule after H2 itself, to trace H2 gas is a widely used practice since the discovery of bright 12 CO J=1–0 emission in Orion (Wilson, Jefferts, & Penzias 1970). The most easily excited H2 transition, the quadrupole S(0): Ju − Jl = 2 to undetected by the conventional method. This phase will be warm, diffuse and devoid of CO, and may contribute significantly to the pressure and total mass of the disk.
–2– corresponds to ∆E20 /k ∼ 510 K, much too high to be significantly populated in the cool ISM (Tkin ∼ 10−50 K) revealed by the 12 CO J=1–0 transition (∆E10 /k ∼ 5.5 K). Furthermore the (10) large optical depths of the latter (τ10 ∼ 5 − 10) reduce its critical density of ncr ∼ 380 cm−3 (10) −1 (for Tkin = 50 K; Kamp & Zadelhoff 2001) to ∼ ncr (1 − e−τ10 )τ10 ∼ 40 − 80 cm−3 , similar to the lowest average densities observed in Giant Molecular Clouds (GMCs). Hence the 12 CO J=1–0 transition is expected to be excited even in the coldest and most diffuse regions of the molecular ISM. However its large optical depths (e.g. Martin, Sanders, & Hills 1984; Sage & Isbell 1991; Falgarone 1998), do not allow a straightforward use of its luminosity together with a [12 CO/H2 ] abundance ratio for H2 mass estimates. The widely used XCO = M(H2 )/LCO factor (where LCO is the velocity/area-integrated brightness temperature of 12 CO J=1–0) is based on the notion of an effectively optically thin medium, where the 12 CO line emission arises from an ensemble of small, radiatively de-coupled cells not overlapping in space or velocity. Then the high optical depths arise locally within the individual cells and the observed wide line profiles result from their macroscopic motions rather than their intrinsic, much narrower linewidths (e.g. Martin et al. 1984; Young & Scoville 1991 and references therein). This picture, along with the observed virialization of molecular clouds (see e.g. Larson 1981) over a wide range of scales (∼ 0.1 − 100 pc) allows a statistical derivation of XCO as an ensemble-average that is relatively insensitive to local molecular cloud conditions (e.g. Dickman, Snell, & Schloerb 1986; Young & Scoville 1991; Bryant & Scoville 1996) and, for scales 10 pc, is expected to yield the correct H2 mass to within a factor of two. The existence of such cells is supported by high angular and velocity resolution studies of galactic clouds (e.g. Falgarone et al. 1998; Tauber 1996) while the statistical robustness of XCO for a variety of conditions has been verified using both observational (e.g. Young & Scoville 1991 and references therein), and theoretical methods (e.g. Kutner & Leung 1985; Dickman, Snell & Schloerb 1986; Maloney & Black 1988; Wolfire, Hollenbach, & Tielens 1993; Sakamoto 1996; Bryant & Scoville 1996). However these studies also suggest a likely failure of this method in two particular environments, namely a) galactic and/or starburst nuclei where non-virial motions cause the luminous 12 CO emission to overestimate the H2 mass (e.g. Dahmen et al. 1998; Downes & Solomon 1998), b) metal-poor regions where it seriously underestimates the H2 mass (e.g. Maloney & Black 1988; Arimoto, Sofue, & Tsujimoto 1996; Israel 1988, 1997, 1999). The last case is the most serious one since then 12 CO emission is usually faint and thus precludes the observations of more optically thin isotopes like 13 CO, C18 O that could yield the H2 mass without using the XCO factor. In this paper we show that the decreasing metallicity with galactocentric radius in disks and a larger H2 formation rate open up the possibility of large amounts of H2 gas being
Molecular gas in spiral galaxies: a new warm phase at large galactocentric distances?
P. P. Papadopoulos
arXiv:astro-ph/0208535v1 29 Aug 2002
ESA Astrophysics Division, Research and Scientific Support Department, ESTEC, Postbus 299, 2200 AG Noordwijk, The Netherlands W.-F. Thi Department of Physics & Astronomy, University College London, London WC1E 6BT and S. Viti Department of Physics & Astronomy, University College London, London WC1E 6BT ABSTRACT There is now strong evidence suggesting that the 12 CO J=1–0 transition, widely used to trace H2 gas, significantly underestimates its mass in metal-poor regions. In spiral disks such regions are found in large galactocentric distances where we show that any unaccounted H2 gas phase is likely to be diffuse (n ∼ 5 − 20 cm−3 ) and warmer (Tkin ∼ 50 − 100 K) than the cool (Tkin ∼ 15 − 20 K) CO-luminous one. Moreover we find that a high value of the H2 formation rate on grains, suggested by recent observational work, can compensate for the reduction of the available grain surface in the metal-poor part of typical galactic disks and thus enhance this CO-poor H2 component which may be contributing significantly to the mass and pressure of spiral disks beyond their optical radius. Subject headings: dark matter: galaxies—interstellar matter: molecular gas— galaxies: individual: NGC 891, Galaxy—molecules: CO, H2
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