色谱术语中英对照
常用色谱术语(中英文对照)

常用色谱术语(中英文对照)色谱图 chromatogram色谱峰chromatographicpeak峰底peak base峰高h,peak height峰宽W,peak width半高峰宽Wh/2,peak width athalf height 峰面积A,peak area拖尾峰tailing area前伸峰leading area假峰ghost peak畸峰distorted peak反峰negative peak拐点inflection point原点origin斑点spot区带zone复班multiple spot区带脱尾zone tailing基线base line基线漂移baseline drift基线噪声N,base line noise统计矩moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法liquidchromatography,LC液液色谱法liquid liquidchromatography,LLC液固色谱法liquid solidchromatography,LSC正相液相色谱法normal phaseliquid chromatography反相液相色谱法reversed phaseliquid chromatography,RPLC 柱液相色谱法liquid columnchromatography高效液相色谱法high performanceliquid chromatography,HPLC尺寸排除色谱法size exclusionchromatography,SEC凝胶过滤色谱法gel filtrationchromatography凝胶渗透色谱法gel permeationchromatography,GPC亲和色谱法affinitychromatography离子交换色谱法ion exchangechromatography,IEC离子色谱法ionchromatography离子抑制色谱法ion suppressionchromatography离子对色谱法ion pairchromatography疏水作用色谱法hydrophobicinteraction chromatography制备液相色谱法preparativeliquid chromatography平面色谱法 planarchromatography纸色谱法 paperchromatography薄层色谱法 thin layerchromatography,TLC高效薄层色谱法 highperformance thin layerchromatography,HPTLC浸渍薄层色谱法 impregnatedthin layer chromatography凝胶薄层色谱法 gel thin layerchromatography离子交换薄层色谱法 ion exchangethin layer chromatography 制备薄层色谱法 preparativethin layer chromatography薄层棒色谱法 thin layer rodchromatography液相色谱仪 liquidchromatograph制备液相色谱仪preparativeliquid chromatograph 凝胶渗透色谱仪 gel permeationchromatograph涂布器 spreader点样器 sampleapplicator色谱柱 chromatographiccolumn棒状色谱柱 monolith columnmonolith column 微粒柱 microparticlecolumn填充毛细管柱 packedcapillary column空心柱 open tubularcolumn微径柱 microborecolumn混合柱 mixed column组合柱 coupled column预柱 precolumn保护柱 guard column预饱和柱 presaturationcolumn浓缩柱 concentratingcolumn抑制柱 suppressioncolumn薄层板 thin layerplate浓缩区薄层板 concentratingthin layer plate荧光薄层板 fluorescencethin layer plate反相薄层板reversed phasethin layer plate梯度薄层板 gradient thinlayer plate烧结板 sintered plate展开室 developmentchamber往复泵 reciprocatingpump注射泵 syringe pump气动泵 pneumatic pump蠕动泵 peristalticpump检测器 detector微分检测器 differentialdetector积分检测器 integraldetector总体性能检测器 bulk propertydetector溶质性能检测器 solute propertydetector(示差)折光率检测器 [differential] refractive indexdetector 荧光检测器 fluorescencedetector紫外可见光检测器 ultravioletvisible detector电化学检测器 electrochemicaldetector蒸发(激光)光散射检测器 [laser] light scattering detector光密度计 densitometer薄层扫描仪 thin layer scanner柱后反应器 post-columnreactor体积标记器 volume marker记录器 recorder积分仪 integrator馏分收集器 fractioncollector工作站 work station固定相 stationaryphase固定液 stationaryliquid载体 support柱填充剂 column packing化学键合相填充剂 chemicallybonded phase packing薄壳型填充剂 pellicularpacking多孔型填充剂 porous packing吸附剂 adsorbent离子交换剂 ion exchanger基体 matrix载板 support plate粘合剂 binder流动相 mobile phase洗脱(淋洗)剂 eluant,eluent展开剂 developer等水容剂 isohydricsolvent改性剂 modifier显色剂 color[developing] agent死时间 t0,dead time保留时间 tR,retentiontime调整保留时间 t''R,adjustedretention time死体积 V0,dead volume保留体积 vR,retentionvolume调整保留体积 v''R,adjustedretention volume柱外体积 Vext,extra-columnvolune粒间体积 V0,interstitialvolume(多孔填充剂的)孔体积 VP,pore volume of porous packing 液相总体积 Vtol,total liquidvolume洗脱体积 ve,elutionvolume流体力学体积 vh,hydrodynamicvolume相对保留值 ri.s,relativeretention value分离因子α,separation factor流动相迁移距离 dm,mobile phase migration distance流动相前沿 mobile phasefront溶质迁移距离 ds,solute migration distance比移值 Rf,Rf value高比移值 hRf,high Rf value相对比移值 Ri.s,relative Rfvalue保留常数值 Rm,Rm value板效能 plateefficiency折合板高 hr,reduced plate height分离度 R,resolution液相载荷量 liquid phaseloading离子交换容量 ion exchangecapacity负载容量 loadingcapacity渗透极限 permeabilitylimit排除极限 Vh,max,exclusion limit拖尾因子 T,tailing factor柱外效应 extra-columneffect管壁效应 wall effect间隔臂效应 spacer armeffect边缘效应 edge effect斑点定位法 localization ofspot放射自显影法 autoradiography原位定量 in situquantitation生物自显影法 bioautography归一法 normalizationmethod内标法 internalstandard method外标法 external standardmethod叠加法 addition method普适校准(曲线、函数)calibration function or curve[function] 谱带扩展(加宽) band broadening(分离作用的)校准函数或校准曲线 universalCalibration function or curve [of separation]加宽校正 broadeningcorrection加宽校正因子 broadeningcorrection factor溶剂强度参数ε0,solvent strength parameter洗脱序列 eluotropicseries洗脱(淋洗) elution等度洗脱 gradientelution梯度洗脱 gradientelution(再)循环洗脱 recycling elution线性溶剂强度洗脱 linear solventstrength gradient 程序溶剂 programmedsolvent程序压力 programmedpressure程序流速 programmed flow展开 development上行展开 ascendingdevelopment下行展开 descendingdevelopment双向展开 two dimensionaldevelopment环形展开 circulardevelopment离心展开 centrifugaldevelopment向心展开 centripetaldevelopment径向展开 radialdevelopment多次展开 multipledevelopment分步展开 stepwisedevelopment连续展开 continuousdevelopment梯度展开 gradientdevelopment匀浆填充 slurry packing停流进样 stop-flowinjection阀进样 valve injection柱上富集 on-columnenrichment流出液 eluate柱上检测 on-columndetection 柱寿命 column life柱流失 column bleeding显谱 visualization活化 activation反冲 back flushing脱气 degassing沟流 channeling过载 overloading(文章来源:网络)。
色谱字典-色谱词汇

色谱字典(术语大全)中文英文色谱图chromatogram色谱峰chromatographic peak峰底peak base峰高h,peak height峰宽W,peak width半高峰宽Wh/2,peak width at half height峰面积A,peak area拖尾峰tailing area前伸峰leading area假峰ghost peak畸峰distorted peak反峰negative peak拐点inflection point原点origin斑点spot区带zone复班multiple spot区带脱尾zone tailing基线base line基线漂移baseline drift基线噪声N,baseline noise统计矩moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法liquid chromatography,LC液液色谱法liquid liquid chromatography,LLC液固色谱法liquid solid chromatography,LSC正相液相色谱法normal phase liquid chromatography反相液相色谱法reversed phase liquid chromatography,RPLC柱液相色谱法liquid column chromatography高效液相色谱法high performance liquid chromatography,HPLC尺寸排除色谱法size exclusion chromatography,SEC凝胶过滤色谱法gel filtration chromatography凝胶渗透色谱法gel permeation chromatography,GPC亲和色谱法affinity chromatography离子交换色谱法ion exchange chromatography,IEC离子色谱法ion chromatography离子抑制色谱法ion suppression chromatography 离子对色谱法ion pair chromatography疏水作用色谱法hydrophobic interaction chromatography制备液相色谱法preparative liquid chromatography 平面色谱法planar chromatography纸色谱法paper chromatography薄层色谱法thin layer chromatography,TLC高效薄层色谱法high performance thin layer chromatography,HPTLC浸渍薄层色谱法impregnated thin layer chromatography凝胶薄层色谱法gel thin layer chromatography离子交换薄层色谱法ion exchange thin layer chromatography制备薄层色谱法preparative thin layer chromatography薄层棒色谱法thin layer rod chromatography液相色谱仪liquid chromatograph制备液相色谱仪preparative liquid chromatograph 凝胶渗透色谱仪gel permeation chromatograph涂布器spreader点样器sample applicator色谱柱chromatographic column棒状色谱柱monolith column monolith column微粒柱microparticle column填充毛细管柱packed capillary column空心柱open tubular column微径柱microbore column混合柱mixed column组合柱coupled column预柱precolumn保护柱guard column预饱和柱presaturation column浓缩柱concentrating column抑制柱suppression column薄层板thin layer plate浓缩区薄层板concentrating thin layer plate荧光薄层板fluorescence thin layer plate反相薄层板reversed phase thin layer plate梯度薄层板gradient thin layer plate烧结板sintered plate展开室development chamber往复泵reciprocating pump注射泵syringe pump气动泵pneumatic pump蠕动泵peristaltic pump检测器detector微分检测器differential detector积分检测器integral detector总体性能检测器bulk property detector溶质性能检测器solute property detector(示差)折光率检测器[differential] refractive index detector荧光检测器fluorescence detector紫外可见光检测器ultraviolet visible detector电化学检测器electrochemical detector蒸发(激光)光散射检测器[laser] light scattering detector光密度计densitometer薄层扫描仪thin layer scanner柱后反应器post-column reactor体积标记器volume marker记录器recorder积分仪integrator馏分收集器fraction collector工作站work station固定相stationary phase固定液stationary liquid载体support柱填充剂column packing化学键合相填充剂chemically bonded phase packing薄壳型填充剂pellicular packing多孔型填充剂porous packing吸附剂adsorbent离子交换剂ion exchanger基体matrix载板support plate粘合剂binder流动相mobile phase洗脱(淋洗)剂eluant,eluent展开剂developer等水容剂isohydric solvent改性剂modifier显色剂color [developing] agent死时间t0,dead time保留时间tR,retention time调整保留时间t'R,adjusted retention time死体积V0,dead volume保留体积vR,retention volume调整保留体积v'R,adjusted retention volume柱外体积Vext,extra-column volune粒间体积V0,interstitial volume(多孔填充剂的)孔体积VP,pore volume of porouspacking液相总体积Vtol,total liquid volume洗脱体积ve,elution volume流体力学体积vh,hydrodynamic volume相对保留值ri.s,relative retention value分离因子α,separation factor流动相迁移距离dm,mobil以上为美瑞泰克公司中国办事处从网上搜集并加以整理的,目的只有一个,就是能让每一个应用色谱分析的朋友能够更方便。
色谱术语中英文对照

色谱字典(术语大全)中文英文色谱图c h r o m a t o g r a m色谱峰c h r o m a t o g r a p h i c p e a k峰底p e a k b a s e峰高h,p e a k h e i g h t峰宽W,p e a k w i d t h半高峰宽W h/2,p e a k w i d t h a t h a l f h e i g h t峰面积A,p e a k a r e a拖尾峰t a i l i n g a r e a前伸峰l e a d i n g a r e a假峰g h o s t p e a k畸峰d i s t o r t e d p e a k反峰n e g a t i v e p e a k拐点i n f l e c t i o n p o i n t原点o r i g i n斑点s p o t区带z o n e复班m u l t i p l e s p o t区带脱尾z o n e t a i l i n g基线b a s e l i n e基线漂移b a s e l i n e d r i f t基线噪声N,b a s e l i n e n o i s e统计矩m o m e n t一阶原点矩γ1,f i r s t o r i g i n m o m e n t二阶中心矩μ2,s e c o n d c e n t r a l m o m e n t三阶中心矩μ3,t h i r d c e n t r a l m o m e n t液相色谱法l i q u i d c h r o m a t o g r a p h y,L C液液色谱法l i q u i d l i q u i d c h r o m a t o g r a p h y,L L C 液固色谱法l i q u i d s o l i d c h r o m a t o g r a p h y,L S C 正相液相色谱法n o r m a l p h a s e l i q u i dc h r o m a t o g r a p h y反相液相色谱法r e v e r s e d p h a s e l i q u i dc h r o m a t o g r a p h y,R P L C柱液相色谱法l i q u i d c o l u m n c h r o m a t o g r a p h y高效液相色谱法h i g h p e r f o r m a n c e l i q u i dc h r o m a t o g r a p h y,H P L C尺寸排除色谱法s i z e e x c l u s i o n c h r o m a t o g r a p h y,S E C凝胶过滤色谱法g e l f i l t r a t i o n c h r o m a t o g r a p h y凝胶渗透色谱法g e l p e r m e a t i o n c h r o m a t o g r a p h y,G P C亲和色谱法a f f i n i t y c h r o m a t o g r a p h y离子交换色谱法i o n e x c h a n g e c h r o m a t o g r a p h y,I E C 离子色谱法i o n c h r o m a t o g r a p h y离子抑制色谱法i o n s u p p r e s s i o n c h r o m a t o g r a p h y离子对色谱法i o n p a i r c h r o m a t o g r a p h y疏水作用色谱法h y d r o p h o b i c i n t e r a c t i o nc h r o m a t o g r a p h y制备液相色谱法p r e p a r a t i v e l i q u i d c h r o m a t o g r a p h y 平面色谱法p l a n a r c h r o m a t o g r a p h y纸色谱法p a p e r c h r o m a t o g r a p h y薄层色谱法t h i n l a y e r c h r o m a t o g r a p h y,T L C高效薄层色谱法h i g h p e r f o r m a n c e t h i n l a y e rc h r o m a t o g r a p h y,H P T L C浸渍薄层色谱法i m p r e g n a t e d t h i n l a y e rc h r o m a t o g r a p h y凝胶薄层色谱法g e l t h i n l a y e r c h r o m a t o g r a p h y离子交换薄层色谱法i o n e x c h a n g e t h i n l a y e rc h r o m a t o g r a p h y制备薄层色谱法p r e p a r a t i v e t h i n l a y e rc h r o m a t o g r a p h y薄层棒色谱法t h i n l a y e r r o d c h r o m a t o g r a p h y液相色谱仪l i q u i d c h r o m a t o g r a p h制备液相色谱仪p r e p a r a t i v e l i q u i d c h r o m a t o g r a p h 凝胶渗透色谱仪g e l p e r m e a t i o n c h r o m a t o g r a p h涂布器s p r e a d e r点样器s a m p l e a p p l i c a t o r色谱柱c h r o m a t o g r a p h i c c o l u m n棒状色谱柱m o n o l i t h c o l u m n m o n o l i t h c o l u m n微粒柱m i c r o p a r t i c l e c o l u m n填充毛细管柱p a c k e d c a p i l l a r y c o l u m n空心柱o p e n t u b u l a r c o l u m n微径柱m i c r o b o r e c o l u m n混合柱m i x e d c o l u m n组合柱c o u p l e d c o l u m n预柱p r e c o l u m n保护柱g u a r d c o l u m n预饱和柱p r e s a t u r a t i o n c o l u m n浓缩柱c o n c e n t r a t i n g c o l u m n抑制柱s u p p r e s s i o n c o l u m n薄层板t h i n l a y e r p l a t e浓缩区薄层板c o n c e n t r a t i n g t h i n l a y e r p l a t e荧光薄层板f l u o r e s c e n c e t h i n l a y e r p l a t e反相薄层板r e v e r s e d p h a s e t h i n l a y e r p l a t e梯度薄层板g r a d i e n t t h i n l a y e r p l a t e烧结板s i n t e r e d p l a t e展开室d e v e l o p m e n t c h a m b e r往复泵r e c i p r o c a t i n g p u m p注射泵s y r i n g e p u m p气动泵p n e u m a t i c p u m p蠕动泵p e r i s t a l t i c p u m p检测器d e t e c t o r微分检测器d i f f e r e n t i a l d e t e c t o r积分检测器i n t e g r a l d e t e c t o r总体性能检测器b u l k p r o p e r t y d e t e c t o r溶质性能检测器s o l u t e p r o p e r t y d e t e c t o r(示差)折光率检测器[d i f f e r e n t i a l]r e f r a c t i v e i n d e xd e t e c t o r荧光检测器f l u o r e s c e n c e d e t e c t o r紫外可见光检测器u l t r a v i o l e t v i s i b l e d e t e c t o r电化学检测器e l e c t r o c h e m i c a l d e t e c t o r蒸发(激光)光散射检测器[l a s e r]l i g h t s c a t t e r i n g d e t e c t o r光密度计d e n s i t o m e t e r薄层扫描仪t h i n l a y e r s c a n n e r柱后反应器p o s t-c o l u m n r e a c t o r体积标记器v o l u m e m a r k e r记录器r e c o r d e r积分仪i n t e g r a t o r馏分收集器f r a c t i o n c o l l e c t o r工作站w o r k s t a t i o n固定相s t a t i o n a r y p h a s e固定液s t a t i o n a r y l i q u i d载体s u p p o r t柱填充剂c o l u m n p a c k i n g化学键合相填充剂c h e m i c a l l y b o n d e d p h a s ep a c k i n g薄壳型填充剂p e l l i c u l a r p a c k i n g多孔型填充剂p o r o u s p a c k i n g吸附剂a d s o r b e n t离子交换剂i o n e x c h a n g e r基体m a t r i x载板s u p p o r t p l a t e粘合剂b i n d e r流动相m o b i l e p h a s e洗脱(淋洗)剂e l u a n t,e l u e n t展开剂d e v e l o p e r等水容剂i s o h y d r i c s o l v e n t改性剂m o d i f i e r显色剂c o l o r[d e v e l o p i n g]a g e n t死时间t0,d e a d t i m e保留时间t R,r e t e n t i o n t i m e调整保留时间t'R,a d j u s t e d r e t e n t i o n t i m e死体积V0,d e a d v o l u m e保留体积v R,r e t e n t i o n v o l u m e调整保留体积v'R,a d j u s t e d r e t e n t i o n v o l u m e柱外体积V e x t,e x t r a-c o l u m n v o l u n e粒间体积V0,i n t e r s t i t i a l v o l u m e(多孔填充剂的)孔体积V P,p o r e v o l u m e o f p o r o u s p a c k i n g液相总体积V t o l,t o t a l l i q u i d v o l u m e洗脱体积v e,e l u t i o n v o l u m e流体力学体积v h,h y d r o d y n a m i c v o l u m e相对保留值r i.s,r e l a t i v e r e t e n t i o n v a l u e分离因子α,s e p a r a t i o n f a c t o r流动相迁移距离d m,m o b i l e p h a s e m i g r a t i o nd i s t a n c e流动相前沿m o b i l e p h a s e f r o n t溶质迁移距离d s,s o l u t e m i g r a t i o n d i s t a n c e比移值R f,R f v a l u e高比移值h R f,h i g h R f v a l u e相对比移值R i.s,r e l a t i v e R f v a l u e保留常数值R m,R m v a l u e板效能p l a t e e f f i c i e n c y折合板高h r,r e d u c e d p l a t e h e i g h t分离度R,r e s o l u t i o n液相载荷量l i q u i d p h a s e l o a d i n g离子交换容量i o n e x c h a n g e c a p a c i t y负载容量l o a d i n g c a p a c i t y渗透极限p e r m e a b i l i t y l i m i t排除极限V h,m a x,e x c l u s i o n l i m i t拖尾因子T,t a i l i n g f a c t o r柱外效应e x t r a-c o l u m n e f f e c t管壁效应w a l l e f f e c t间隔臂效应s p a c e r a r m e f f e c t边缘效应e d g e e f f e c t斑点定位法l o c a l i z a t i o n o f s p o t放射自显影法a u t o r a d i o g r a p h y原位定量i n s i t u q u a n t i t a t i o n生物自显影法b i o a u t o g r a p h y归一法n o r m a l i z a t i o n m e t h o d内标法i n t e r n a l s t a n d a r d m e t h o d外标法e x t e r n a l s t a n d a r d m e t h o d叠加法a d d i t i o n m e t h o d普适校准(曲线、函数)c a l i b r a t i o n f u n c t i o n o r c u r v e[f u n c t i o n]谱带扩展(加宽)b a n d b r o a d e n i n g(分离作用的)校准函数或校准曲线u n i v e r s a l c a l i b r a t i o n f u n c t i o n o r c u r v e[o f s e p a r a t i o n]加宽校正b r o a d e n i n g c o r r e c t i o n加宽校正因子b r o a d e n i n g c o r r e c t i o n f a c t o r溶剂强度参数ε0,s o l v e n t s t r e n g t h p a r a m e t e r洗脱序列e l u o t r o p i c s e r i e s洗脱(淋洗)e l u t i o n等度洗脱g r a d i e n t e l u t i o n梯度洗脱g r a d i e n t e l u t i o n(再)循环洗脱r e c y c l i n g e l u t i o n线性溶剂强度洗脱l i n e a r s o l v e n t s t r e n g t h g r a d i e n t程序溶剂p r o g r a m m e d s o l v e n t程序压力p r o g r a m m e d p r e s s u r e程序流速p r o g r a m m e d f l o w展开d e v e l o p m e n t上行展开a s c e n d i n g d e v e l o p m e n t下行展开d e s c e n d i n g d e v e l o p m e n t双向展开t w o d i m e n s i o n a l d e v e l o p m e n t环形展开c i r c u l a r d e v e l o p m e n t离心展开c e n t r i f u g a l d e v e l o p m e n t向心展开c e n t r i p e t a l d e v e l o p m e n t 径向展开r a d i a l d e v e l o p m e n t多次展开m u l t i p l e d e v e l o p m e n t分步展开s t e p w i s e d e v e l o p m e n t连续展开c o n t i n u o u s d e v e l o p m e n t 梯度展开g r a d i e n t d e v e l o p m e n t匀浆填充s l u r r y p a c k i n g停流进样s t o p-f l o w i n j e c t i o n阀进样v a l v e i n j e c t i o n柱上富集o n-c o l u m n e n r i c h m e n t流出液e l u a t e柱上检测o n-c o l u m n d e t e c t i o n柱寿命c o l u m n l i f e柱流失c o l u m n b l e e d i n g显谱v i s u a l i z a t i o n活化a c t i v a t i o n反冲b a c k f l u s h i n g脱气d e g a s s i n g沟流c h a n n e l i n g过载o v e r l o a d i n g。
色谱专业英语

色谱专业英语阴离子交换色谱法anion exchange chromatography, AEC阴离子交换树脂anion exchange resin荧光薄层板fluorescent thin layer plate荧光检测器fluorescence detector荧光色谱法fluorescence chromatography迎头色谱法frontal chromatography迎头色谱法frontal method硬(质)凝胶hard gel涌浪效应surge effect有机改进剂organic modifier有机相生物传感器Organic biosensor有效峰数effective peak number EPN有效理论塔板数number of effective theoretical plates有效塔板高度effective plate height有效淌度effective mobility釉化处理glazing淤浆填充法slurry packing method予柱guard column予柱pre-column圆筒模型cylindrical model圆型纸色谱法circular paper chromatography圆形色谱法circular chromatography圆柱状超微薄层色谱法ultra micro TLC on a cylindrical suppor…圆锥模型conical model载气carrier gas载气净化器carry gas cleanser载气流速flow rate载气平均流速average flow rate载体support载体的钝化deactivation of support载体的活性部位active site of support载体涂层开口管柱support coated open tubular column,SCOT再生剂regenerant在线电堆集on-line electrical stacking在柱电导率检测on-column electrical conductivity detection噪声noise噪信比noise –signal ratio皂膜流量计soap film gas meter增强紫外-可见吸收检测技术UV-visible absorption enhanced det…窄粒度分布narrow particle size distribution粘度检测器viscosity detector展开development展开槽developing tank展开槽饱和Chamber saturation展开剂developer折射率检测器refractive index detector, RID真空脱气装置vacuum degasser阵列毛细管电泳capillary array electrophoresis蒸发光散射检测器evaporative light-scattering detector, ELSD整体性质检测器integral property detector正相高效液相色谱法normal phase high performance liquid chro…正相离子对色谱法normal phase ion-pair chromatography正相毛细管电色谱positive capillary electrokinetic chromatog…直接化学离子化direct chemical ionization GC-MS直接激光在柱吸收检测on-column direct laser detection指数式流动exponential flow纸色谱法paper chromatography置换色谱法displacement chromatography制备色谱preparative chromatography制备色谱仪preparative chromatograph制备柱preparation column智能色谱chromatography with artificial intelligence质量流量mass flow rate质量色谱mass chromatography质量型检测器mass detector质量型检测器mass flow rate sensitive detector中空纤维抑制器hollow fiber suppressor中压液相色谱middle-pressure liquid chromatography重建色谱图reconstructive chromatogram重均分子量weight mean molecular weight轴向扩散longitudinal diffusion轴向吸收池absorption pool of axial direction轴向压缩柱axial compression column柱端电导率检测out-let end detection of electrical conductiv…柱负载能力column loadability柱后衍生化post-column derivatization柱老化column ageing柱老化condition (aging) of column柱流出物(column) effluent柱流失column bleeding柱内径column internal diameter柱前衍生化pro-column derivatization柱切换技术column switching technique柱清洗column cleaning柱容量column capacity柱入口压力column inlet pressure柱色谱法column chromatography柱上检测on-line detection柱渗透性column permeability柱寿命column life柱头进样column head sampling柱外效应extra-column effect柱温箱column oven柱效column efficiency柱压column pressure柱再生column regeneration柱中衍生化on-column derivatization注射泵syringe pump转化定量法trans-quantitative method紫外-可见光检测器ultraviolet visible detector, UV-Vis 紫外吸收检测器ultraviolet absorption detector自动进样器automatic sampler自由溶液毛细管电泳free solution capillary electrophoresis 总分离效能指标over-all resolution efficiency总交换容量total exchange capacity总渗透体积total osmotic volume纵向扩散longitudinal diffusion组合式仪器系统building block instrument最佳流速optimum flow rate最佳实际流速optimum practical flow rate最小检测量minimum detectable quantity最小检测浓度minimum detectable concentration萃取色谱法extraction chromatography氩电离检测器argon ionization detector螯合离子交换剂chelating ion exchanger螯合离子色谱法chelating ion chromatography螯合树脂chelating resin脱氧核糖核酸电化学传感器DNA sensor外标法external standard method外梯度outside gradient网状结构reticular structure往复泵reciprocating pump往复式隔膜泵reciprocating diaphragm pump微分型检测器differential detector微孔树脂micro-reticular resin微库仑检测器micro coulometric detector微量进样针micro-syringe微量色谱法micro-chromatography微膜抑制器micro-membrane suppressor微乳液电动色谱microemulsion electrokinetic chromatography微生物传感器Microbial sensor微生物显影bioautography微填充柱micro-packed column微吸附检测器micro adsorption detector微型柱micro-column尾吹气make-up gas味觉传感器taste sensor涡流扩散eddy diffusion无放射源电子俘获检测器non-radioactive electron capture dete…无机离子交换剂inorganic ion exchanger无胶筛分毛细管电泳non-gel capillary electrophoresis无孔单分散填料non-porous monodisperse packing无脉动色谱泵pulse-free chromatographic pump物理钝化法physical deactivation吸附等温线adsorption isotherm吸附剂adsorbing material吸附剂活性adsorbent activity吸附平衡常数adsorption equilibrium constant吸附溶剂强度参数adsorption solvent strength parameter吸附色谱法adsorption chromatography吸附型PLOT柱adsorption type porous-layer open tubular colum…吸附柱adsorption column吸光度比值法absorbance ratio method洗脱强度eluting power下行展开法descending development method显色器color-developing sprayer限制扩散理论theory of restricted diffusion线速度linear velocity线性梯度linear gradient相比率phase ratio相对保留值relative retention value相对比移值relative Rf value相对挥发度relative volatility相对灵敏度relative sensitivity相对碳(重量)响应因子relative carbon response factor相对响应值relative response相对校正因子relative correction factor相交束激光诱导的热透镜测量heat lens detection of intersect …相似相溶原则rule of similarity响应时间response time响应值response小角激光散射光度计low-angle laser light scattering photomet…小内径毛细管柱Microbore column校正保留体积corrected retention volume校正曲线法calibration curve method校正因子correction factor芯片电泳microchip electrophoresis旋转薄层法rotating thin layer chromatography旋转小室逆流色谱rotational little-chamber counter-current c…选择性检测器selective detector循环色谱法recycling chromatography压电晶体piezoelectric crystal压电免疫传感器Piezoelectric Immunosensor压电转换器piezoelectric transducer压力保护pressure protect压力上限pressure high limit压力梯度校正因子pressure gradient correction factor压力下限pressure low limit盐析色谱法salting-out chromatography盐析纸色谱法salting-out paper chromatography衍生化法derivatization method衍生化试剂derivatization reagent阳离子交换剂cation exchanger阳离子交换色谱法cation exchange chromatography, CEC氧化铝色谱法alumina chromatography样品环sample loop样品预处理sample pretreatment液-液分配色谱法liquid-liquid partition chromatography液-液色谱法liquid-liquid chromatography液滴逆流色谱drop counter-current chromatography液固色谱liquid-solid chromatography液晶固定相liquid crystal stationary phase液态离子交换剂liquid ion exchanger液相传质阻力resistance of liquid mass transfer液相色谱-傅里叶变换红外光谱联用liquid chromatography-FTIR 液相色谱-质谱分析法liquid chromatography-mass spectrometry 液相色谱-质谱仪liquid chromatography-mass spectrometer液相色谱法liquid chromatography液相载荷量liquid phase loading一滴液相色谱法one drop liquid chromatography抑制器suppressor抑制型电导检测suppressed conductance detection抑制型离子色谱法suppressed ion chromatography, SIC 抑制柱suppressed column溢流区flooded zonevvv溶解度参数solubility parameter溶液性能检测器solution property detector溶胀swelling溶质性质检测器solute property detector容量因子capacity factor绒毛促性腺传感器Human chorionic gonadotropin sensor 乳胶附聚型离子交换剂latex-agglomerated ion exchanger 软(质)凝胶soft gel弱碱性阴离子交换剂weak-base anion exchanger弱酸性阳离子交换剂weakly acidic cation exchanger塞式流plug flow塞式流动plug flow色谱法chromatography色谱峰chromatographic peak色谱峰区域宽度peak width色谱富集过样samt injection of chromatography色谱工作站chromatographic working station色谱图chromatogram色谱仪chromatograph色谱纸chromatographic paper色谱柱chromatographic column色谱柱column色谱柱切换技术switching column technique筛分介质sieving medium上行展开法ascending development method蛇笼(状)树脂snake cage resin射频放电检测器radiofrequency discharge detector渗透极限分子量permeation limit molecular weight生物耗氧传感器Biological oxygen-consumption sensor 生物利用度bioavailability生物膜电极Biomembrane electrode生物亲和型传感器Biological affinity sensor生物色谱biological chromatography生物特异性柱biospecific column生物自显影法bioautography升温速率temperature rate湿法柱填充wet column packing十八烷基键合硅胶octadecyl silane石墨化碳黑graphitized carbon black实心载体solid support示差折光检测器differential refraction detector试剂显色法reagent color-developing method手动进样器manual injector手性氨基酸衍生物GC固定相chiral amino acid derivatives stat…手性拆分试剂chiral selectors手性固定相chiral stationary phase手性固定相拆分法chiral solid phase separation手性环糊精衍生物GC固定相chiral cyclodextrin der GC手性金属络合物GC固定相chirametal stationary phase in GC手性流动相chiral mobile phase手性流动相拆分法chiral mobile phase separation手性气相色谱法chiral gas chromatography手性色谱chiral chromatography手性试剂chiral reagent手性衍生化法chiral derivation method疏溶剂理论solvophobic theory疏溶剂色谱法solvophobic chromatography疏溶剂作用理论solvophobic interaction principle疏水作用色谱hydrophobic interaction chromatography 树脂交换容量exchange capacity of resin数均分子量number mean molecular weight双保留机理dual reservation mechanism双电层electrical double layer双活塞往复泵two-piston reciprocating pump双束差分检测器detector of dual-beam difference双向展开法two-dimensional development method双柱定性法double-column qualitative method双柱离子色谱法dual column ion chromatography双柱色谱法dual column chromatography水凝胶hydragel水系凝胶色谱柱aqua-system gel column瞬间离子基体效应moment ion matrix effect死区域dead zone死体积dead volume塑料泵plastic pump酸洗法acid wash酸性染料比色法acid dye colorimetry塔板理论方程plate theory equation碳分子筛carbon molecular sieve唐南排斥Donnan exclusion特殊选择固定液selective stationary phase梯度洗脱gradient elution梯度洗脱装置gradient elution device梯度液相色谱gradient liquid chromatography体积排斥理论size exclusion theory体积排斥色谱size exclusion chromatography体积色谱法volumetric chromatography填充毛细管柱packed capillary column填充柱packed column填料packing material停流进样stop-flow injection通用型检测器common detector涂壁毛细管柱wall coated open tubular column,WCOT 涂布器spreader涂层毛细管coated capillary 涂渍coat涂渍效率coating efficiency 拖尾峰tailing peak拖尾因子tailing factor。
色谱专用术语英语翻译

不知各位是否用的着色谱图 chromatogram 色谱峰 chromatographic peak峰底peak base峰高 h,peak height峰宽 W,peak width半高峰宽 Wh/2,peak width at half height峰面积 A,peak area拖尾峰 tailing area前伸峰 leading area假峰ghost peak畸峰 distorted peak反峰 negative peak拐点 inflection point原点 origin斑点 spot区带 zone复班 multiple spot区带脱尾 zone tailing基线 base line基线漂移 baseline drift基线噪声 N,baseline noise统计矩 moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法 liquid chromatography,LC液液色谱法 liquid liquid chromatography,LLC液固色谱法 liquid solid chromatography,LSC正相液相色谱法 normal phase liquidchromatography反相液相色谱法 reversed phase liquidchromatography,RPLC柱液相色谱法 liquid column chromatography高效液相色谱法 high performance liquidchromatography,HPLC尺寸排除色谱法 size exclusion chromatography,SEC凝胶过滤色谱法gel filtration chromatography凝胶渗透色谱法 gel permeation chromatography,GPC亲和色谱法 affinity chromatography离子交换色谱法 ion exchange chromatography,IEC离子色谱法 ion chromatography离子抑制色谱法 ion suppression chromatography离子对色谱法 ion pair chromatography疏水作用色谱法 hydrophobic interactionchromatography制备液相色谱法 preparative liquid chromatography平面色谱法 planar chromatography纸色谱法 paper chromatography薄层色谱法 thin layer chromatography,TLC高效薄层色谱法high performance thin layerchromatography,HPTLC浸渍薄层色谱法 impregnated thin layerchromatography凝胶薄层色谱法 gel thin layer chromatography离子交换薄层色谱法 ion exchange thin layerchromatography制备薄层色谱法 preparative thin layerchromatography薄层棒色谱法 thin layer rod chromatography液相色谱仪liquid chromatograph制备液相色谱仪 preparative liquid chromatograph凝胶渗透色谱仪 gel permeation chromatograph涂布器 spreader点样器 sample applicator色谱柱 chromatographic column棒状色谱柱monolith column monolith column微粒柱 microparticle column填充毛细管柱 packed capillary column空心柱open tubular column微径柱 microbore column混合柱mixed column组合柱 coupled column预柱 precolumn保护柱 guard column预饱和柱 presaturation column浓缩柱 concentrating column抑制柱 suppression column薄层板 thin layer plate浓缩区薄层板 concentratingthin layer plate荧光薄层板 fluorescence thin layer plate反相薄层板 reversed phase thin layer plate梯度薄层板 gradient thin layer plate烧结板 sintered plate展开室 development chamber 往复泵 reciprocating pump注射泵 syringe pump气动泵 pneumatic pump蠕动泵peristaltic pump检测器 detector微分检测器differential detector积分检测器 integral detector总体性能检测器 bulk property detector溶质性能检测器solute property detector(示差)折光率检测器[differential] refractive indexdetector荧光检测器fluorescence detector紫外可见光检测器 ultraviolet visible detector电化学检测器 electrochemical detector蒸发(激光)光散射检测器 [laser] light scatteringdetector光密度计 densitometer薄层扫描仪thin layer scanner柱后反应器 post-column reactor体积标记器 volume marker记录器 recorder积分仪integrator馏分收集器 fraction collector工作站 work station固定相 stationary phase固定液 stationary liquid载体 support柱填充剂 column packing化学键合相填充剂 chemically bonded phasepacking薄壳型填充剂pellicular packing多孔型填充剂 porous packing吸附剂 adsorbent离子交换剂 ion exchanger基体 matrix载板 support plate粘合剂 binder流动相 mobile phase洗脱(淋洗)剂 eluant,eluent展开剂 developer等水容剂isohydric solvent改性剂 modifier显色剂 color [developing] agent死时间 t0,dead time保留时间 tR,retention time调整保留时间 t'R,adjusted retention time死体积 V0,dead volume保留体积 vR,retention volume调整保留体积 v'R,adjusted retention volume柱外体积 Vext,extra-column volune粒间体积 V0,interstitial volume(多孔填充剂的)孔体积 VP,pore volume of porouspacking液相总体积 Vtol,total liquid volume洗脱体积 ve,elution volume流体力学体积 vh,hydrodynamic volume相对保留值 ri.s,relative retention value分离因子α,separation factor流动相迁移距离 dm,mobile phase migrationdistance流动相前沿 mobile phase front溶质迁移距离 ds,solute migration distance比移值 Rf,Rf value高比移值hRf,high Rf value相对比移值 Ri.s,relative Rf value保留常数值 Rm,Rm value板效能 plateefficiency折合板高 hr,reduced plate height分离度R,resolution液相载荷量 liquid phase loading离子交换容量 ion exchange capacity负载容量 loading capacity渗透极限 permeability limit排除极限 Vh,max,exclusion limit拖尾因子 T,tailing factor柱外效应 extra-column effect管壁效应 wall effect间隔臂效应 spacer arm effect边缘效应 edge effect斑点定位法 localization of spot放射自显影法 autoradiography 原位定量 in situ quantitation生物自显影法bioautography归一法 normalization method内标法internal standard method外标法 external standard method叠加法 addition method普适校准(曲线、函数) calibration function or curve 谱带扩展(加宽) band broadening(分离作用的)校准函数或校准曲线 universalcalibration function or curve [of separation]加宽校正 broadening correction加宽校正因子 broadening correction factor溶剂强度参数ε0,solvent strength parameter洗脱序列 eluotropic series洗脱(淋洗) elution等度洗脱 gradient elution 梯度洗脱 gradient elution(再)循环洗脱 recycling elution线性溶剂强度洗脱 linear solvent strength gradient程序溶剂 programmed solvent程序压力programmed pressure程序流速 programmed flow展开development上行展开 ascending development下行展开descending development双向展开 two dimensional development环形展开 circular development离心展开centrifugal development向心展开 centripetal development径向展开 radial development多次展开multiple development分步展开 stepwise development 连续展开 continuous development梯度展开 gradient development匀浆填充 slurry packing停流进样 stop-flow injection阀进样 valve injection柱上富集 on-column enrichment流出液 eluate柱上检测 on-column detection柱寿命 column life柱流失 column bleeding 显谱 visualization活化 activation反冲 back flushing脱气 degassing沟流 channeling过载overloading。
色谱术语大全

universal calibration function or curve [of separation]
色谱柱
chromatographic column
加宽校正
broadening correction
棒状色谱柱
monolith column monolith column
柱外效应
extra-column effect
平面色谱法
planar chromatography
管壁效应
wall effect
纸色谱法
paper chromatography
间隔臂效应
spacer arm effect
薄层色谱法
thin layer chromatography,TLC
边缘效应
edge effect
eluate
柱流失
column bleeding
柱上检测
on-column detection
荧光检测器
fluorescence detector
柱寿命
column life
紫外可见光检测器
ultraviolet visible detector
(示差)折光率检测器
[differential] refractive index detector
烧结板
sintered plate
向心展开
centripetal development
展开室
development chamber
径向展开
radial development
往复泵
reciprocating pump
多次展开
色谱常用英文词义

色谱常用英文词义色谱图 chromatogram色谱峰 chromatographic peak峰底 peak base峰高 h,peak height峰宽 W,peak width半高峰宽 Wh/2,peak width at half height峰面积 A,peak area拖尾峰 tailing area前伸峰 leading area假峰 ghost peak畸峰 distorted peak反峰 negative peak拐点 inflection point原点 origin斑点 spot区带 zone复班 multiple spot区带脱尾 zone tailing基线 base line基线漂移 baseline drift基线噪声 N,baseline noise统计矩 moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法 liquid chromatography,LC液液色谱法 liquid liquid chromatography,LLC液固色谱法 liquid solid chromatography,LSC正相液相色谱法 normal phase liquid chromatography反相液相色谱法 reversed phase liquid chromatography,RPLC柱液相色谱法 liquid column chromatography高效液相色谱法 high performance liquid chromatography,HPLC尺寸排除色谱法 size exclusion chromatography,SEC凝胶过滤色谱法 gel filtration chromatography凝胶渗透色谱法 gel permeation chromatography,GPC亲和色谱法 affinity chromatography离子交换色谱法 ion exchange chromatography,IEC离子色谱法 ion chromatography离子抑制色谱法 ion suppression chromatography 离子对色谱法 ion pair chromatography疏水作用色谱法 hydrophobic interaction chromatography制备液相色谱法 preparative liquid chromatography 平面色谱法 planar chromatography纸色谱法 paper chromatography薄层色谱法 thin layer chromatography,TLC高效薄层色谱法 high performance thin layer chromatography,HPTLC浸渍薄层色谱法 impregnated thin layer chromatography凝胶薄层色谱法 gel thin layer chromatography离子交换薄层色谱法 ion exchange thin layer chromatography制备薄层色谱法 preparative thin layer chromatography薄层棒色谱法 thin layer rod chromatography液相色谱仪 liquid chromatograph制备液相色谱仪 preparative liquid chromatograph 凝胶渗透色谱仪 gel permeation chromatograph涂布器 spreader点样器 sample applicator色谱柱 chromatographic column棒状色谱柱 monolith column monolith column微粒柱 microparticle column填充毛细管柱 packed capillary column空心柱 open tubular column微径柱 microbore column混合柱 mixed column组合柱 coupled column预柱 precolumn保护柱 guard column预饱和柱 presaturation column浓缩柱 concentrating column抑制柱 suppression column薄层板 thin layer plate浓缩区薄层板 concentrating thin layer plate荧光薄层板 fluorescence thin layer plate反相薄层板 reversed phase thin layer plate梯度薄层板 gradient thin layer plate烧结板 sintered plate展开室 development chamber往复泵 reciprocating pump注射泵 syringe pump气动泵 pneumatic pump蠕动泵 peristaltic pump检测器 detector微分检测器 differential detector积分检测器 integral detector总体性能检测器 bulk property detector溶质性能检测器 solute property detector(示差)折光率检测器 [differential] refractive index detector荧光检测器 fluorescence detector紫外可见光检测器 ultraviolet visible detector电化学检测器 electrochemical detector蒸发(激光)光散射检测器 [laser] light scattering detector光密度计 densitometer薄层扫描仪 thin layer scanner柱后反应器 post-column reactor体积标记器 volume marker记录器 recorder积分仪 integrator馏分收集器 fraction collector工作站 work station固定相 stationary phase固定液 stationary liquid载体 support柱填充剂 column packing化学键合相填充剂 chemically bonded phase packing薄壳型填充剂 pellicular packing多孔型填充剂 porous packing吸附剂 adsorbent离子交换剂 ion exchanger基体 matrix载板 support plate粘合剂 binder流动相 mobile phase洗脱(淋洗)剂 eluant,eluent展开剂 developer等水容剂 isohydric solvent改性剂 modifier显色剂 color [developing] agent死时间 t0,dead time保留时间 tR,retention time调整保留时间 t''R,adjusted retention time死体积 V0,dead volume保留体积 vR,retention volume调整保留体积 v''R,adjusted retention volume柱外体积 Vext,extra-column volune粒间体积 V0,interstitial volume(多孔填充剂的)孔体积 VP,pore volume of porous packing液相总体积 Vtol,total liquid volume洗脱体积 ve,elution volume流体力学体积 vh,hydrodynamic volume相对保留值 ri.s,relative retention value分离因子α,separation factor流动相迁移距离 dm,mobile phase migration distance流动相前沿 mobile phase front溶质迁移距离 ds,solute migration distance比移值 Rf,Rf value高比移值 hRf,high Rf value相对比移值 Ri.s,relative Rf value保留常数值 Rm,Rm value板效能 plate efficiency折合板高 hr,reduced plate height分离度 R,resolution液相载荷量 liquid phase loading离子交换容量 ion exchange capacity负载容量 loading capacity渗透极限 permeability limit排除极限 Vh,max,exclusion limit拖尾因子 T,tailing factor柱外效应 extra-column effect管壁效应 wall effect间隔臂效应 spacer arm effect边缘效应 edge effect斑点定位法 localization of spot放射自显影法 autoradiography原位定量 in situ quantitation生物自显影法 bioautography归一法 normalization method内标法 internal standard method外标法 external standard method叠加法 addition method普适校准(曲线、函数) calibration function or curve[function]谱带扩展(加宽) band broadening(分离作用的)校准函数或校准曲线 universal calibration function or curve [of separation]加宽校正 broadening correction加宽校正因子 broadening correction factor溶剂强度参数ε0,solvent strength parameter洗脱序列 eluotropic series洗脱(淋洗) elution等度洗脱 gradient elution梯度洗脱 gradient elution(再)循环洗脱 recycling elution线性溶剂强度洗脱 linear solvent strength gradient 程序溶剂 programmed solvent程序压力 programmed pressure程序流速 programmed flow展开 development上行展开 ascending development下行展开 descending development双向展开 two dimensional development环形展开 circular development离心展开 centrifugal development向心展开 centripetal development径向展开 radial development多次展开 multiple development分步展开 stepwise development连续展开 continuous development梯度展开 gradient development匀浆填充 slurry packing停流进样 stop-flow injection阀进样 valve injection柱上富集 on-column enrichment流出液 eluate柱上检测 on-column detection柱寿命 column life柱流失 column bleeding显谱 visualization活化 activation反冲 back flushing脱气 degassing沟流 channeling过载 overloading。
色谱基本理论

(二) 塔扳理论存在的不足:
1.塔板理论是模拟在一些假设条件下 而提出的,假设同实际情况有差距, 所以他描述的色谱分配过程定量关系 合有不准确的地方。
2.对于塔板高度H这个抽象的物理量 究竟由哪些参变量决定的?H又将怎 样影响色谱峰扩张等一些实质性的较 深入的问题,塔板理论却不能回答。
3.为什么流动相线速度(U)不同,柱效率 (n)不同;而有时当U值由很小一下变得 很大时,则柱效能(n)指标并未变化许 多,但峰宽各异,这些现象塔板理论也 无能为力.
讨论: K’=0 则 tR = tM 组分无保留行为 K’=1 则 tR = 2tM K’→∞ tR很大 组分峰出不来
所以K’=1-5 最好 如何控制K’? 主要选择合适的固定液 色谱测K’容易(只测tR tM )所以常用K’
四 分配系数K与分配比K’的关系于
K =K’β β = VG/ VL= K/ K’
2,压力校正
jF皂
P0 PW P0
TC Tr
PW ---室温下的的水饱 和蒸汽压 P0---柱出口处压力 Pi ---柱入口处压力
j
3(Pi 2(Pi
/ /
P0 )2 P0 )3
1 1
3,温度校正
FC
jF皂
P0 PW P0
TC Tr
Vg
273.16VN TC M L
Vg
273.16 TC
假设色谱柱由5块塔板组成: (0号板,1号,2号,…4号板) 令N=5(N表示进入柱中载气的脉冲次数 令组分进样量为:W=1 组分在柱内的分配过程是以气液色谱分
配为例,组分在气液两相中进行分配
○表示进入气相的组分分子 □表示进入液相的组分分子 此时若组分容量因子K,=1,即p=q 组分中有p量溶于液相 组分中有q量溶于液相
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1、气相色谱法(GC)—gas chromatography用气体做为流动相的色法。
2、气液色谱法(GLC)—gas liquid chromatography 将固定液涂在载体上作为固定相的气相色谱法。
3、气固色谱法(GSC)—gas solid chromatography 用固体(一般指吸附剂)作固定相的气相色谱法。
4、程序升温气相色谱法—programmed temperature gas chromatography 色谱柱按照预定的程序连续地或分阶段地进升温的气相色谱法。
5、反应气相色谱法—reaction gas chromatography 试样以过色谱前、后的反应区进行化学反应的气相色谱法。
6、裂解气相色谱法—pyrolysis gas chromatography 试样经过高温、激光、电弧等途径,裂解为较小分子后进入色谱柱的气相色谱法。
7、顶空报相色谱法—haed (应为head -编者注)space gas chromatography d在密闭的容器中与液体(或)固体)试样处于势力学平衡(应为热力学平衡 -编者注)状态的气相组分,是间接测定试样中挥发性组分的一种方法。
8、毛细管气相色谱法—capillary gas chromatography 使用具有高分离效能的毛细管柱的气相色谱法。
9、多维气相色谱法—multidimensional gas chromatography 将两个或多个色谱柱组合,通过切换,可进行正吹、反吹或切割等的气相色谱法。
10、制备气相色谱法—preparative gas chromatography 用能处理较大量试样的色谱系统,进行分离、切割和收集组分,以提纯化全物的气相色谱法。
11、色谱柱:chromatographic column内有固定相用以分离混合组分的柱管。
12、填充柱:packed cklumn (应为column-编者注)填充了固定相的色谱柱。
13、微填充柱:micro-packed column填充了微粒固定相的内径一般为0.5-1mm的色谱柱。
14、毛细管柱:capillary column 内径一般为0.1—0.5mm的色谱柱。
15、空心柱:open tubular column 内壁上有固定相的开口毛细管柱。
16、涂壁空心柱(WCOT):wall –coated open tubular column 内壁上直接涂渍固定液的空心柱。
17、多孔层空心柱(PLOT):porus –layer open tubular column 内壁上有多层孔的固定相的空心柱。
18、涂载体空心柱(SCOT):support –coated open tubular column 内壁上沉积载体后涂渍固定液的空心柱。
19、填充毛细管柱:packed capillary column 将载体或吸附剂疏松地装入玻璃管中,然后拉制成内径一般为0.25—0.5mm的毛细管柱。
20、分流器:splitter 按一定比例将气流分成两部分的部件。
21、进样器:sample injector 能定量和瞬间地将度样注入色谱系统的器件。
通常指进样阀或注射器。
22、汽化室:vaporizer 使试样瞬间汽化并预热载气的部件。
23、检测器:detector 能检测色谱柱流出组分及其量的变化的器件。
24、浓度敏感型检测器:concnetration sensitive detector 响应值取决于组分浓度的检测器。
25、质量敏感型检测器:mass(flow rate)sensotive detector. 响应值取决于组分质量流量的检测器。
26、积分型检测器:integral detector 响应值取决于组分累积量的检测器。
27、微分型检测器:differential detector 响应值取决于组分瞬时量的检测器。
28、热导检测器(TCD):thermal conductivity detector. 当载气和色谱柱流出物通过热敏元件时,由于两者的热导系数有同,使阻值发生差异而产生电信号的器件。
29、火焰离子化检测器(FID):flame ionization detector. 有机物在氢火焰中燃烧时生成的离子,在电场作用下产生电信号的器件。
30、碱焰离子化检测器(AFID):alkali fiame ionization detector. 在火焰离子化检测器的喷嘴附近放置碱金属化合物,能增加含氮或含磷化合物所生成的离子,从而使电信号增强的检测器。
31、光离子化检测器(PID):photoionization detector. 利用高能量的紫外线,使电离电位低于紫外线能量的组分离子化,在电场作用下产生电信号的器件。
32、火焰光度检测器(FPD):flame photometric detector. 将含硫或含磷的化合物在富氢火焰中产生的特征波长的光能转化为电信号的检测器。
33、电子俘获检测器(ECD):electron capture detector. 载气分子在3H或Ni63等辐射源产生的β粒子的作用下离子化,在电场中形成稳定的基流,当含有电负性的基团的组分通过电场时,俘获电子使基流减小而产生电信号的器件。
34、微波等离子体(发射光谱)检测器:microwave plasma(emission spectrometric) detector 用微波等离子体激发化合物,使所含元素产生特征发射光谱,经分光系统,能同时检测多种元素的器件。
35、记录器:recorder 记录由检测系统所产生的随时间变化的电信号的仪器。
36、积分仪:integrator 按时间累积检测系统所产生电信号的仪器。
37、固定相:stationary phase 色谱柱内不移动的、起分离作用的物质。
38、吸附剂:adsorbent 具有吸附活性并用于色谱分离的固体物质。
39、固定液:stationary liquid 固定相的组成部分,指涂渍于载体表面上起分离作用的物质,在操作温度下是不易挥发的液体。
40、载体:support 负载固定液的惰性固体。
41、化学键合相:chemically bonded phase 用化学反应在载体表面键合上特定基团的固定相。
42、高分子多孔小球:porous polymer beads 苯乙烯和二乙烯基苯的共聚物或其它共聚的多孔小球,可以单独或涂渍固定液后作为固定相。
43、流动相:mobile phase 在色谱柱中用以携带试样和洗脱组分的气体。
44、载气:carrer gas 用作流动相的气体。
色谱图 chromatogram色谱峰 chromatographic peak峰底 peak base峰高 h,peak height峰宽 W,peak width半高峰宽 Wh/2,peak width at half height峰面积 A,peak area拖尾峰 tailing area前伸峰 leading area假峰 ghost peak畸峰 distorted peak反峰 negative peak拐点 inflection point原点 origin斑点 spot区带 zone复班 multiple spot区带脱尾 zone tailing基线 base line基线漂移 baseline drift基线噪声 N,baseline noise统计矩 moment一阶原点矩γ1,first origin moment二阶中心矩μ2,second central moment三阶中心矩μ3,third central moment液相色谱法 liquid chromatography,LC液液色谱法 liquid liquid chromatography,LLC液固色谱法 liquid solid chromatography,LSC正相液相色谱法 normal phase liquid chromatography反相液相色谱法 reversed phase liquid chromatography,RPLC柱液相色谱法 liquid column chromatography高效液相色谱法 high performance liquid chromatography,HPLC尺寸排除色谱法 size exclusion chromatography,SEC凝胶过滤色谱法 gel filtration chromatography凝胶渗透色谱法 gel permeation chromatography,GPC亲和色谱法 affinity chromatography离子交换色谱法 ion exchange chromatography,IEC 离子色谱法 ion chromatography离子抑制色谱法 ion suppression chromatography离子对色谱法 ion pair chromatography疏水作用色谱法 hydrophobic interaction chromatography制备液相色谱法 preparative liquid chromatography 平面色谱法 planar chromatography纸色谱法 paper chromatography薄层色谱法 thin layer chromatography,TLC高效薄层色谱法 high performance thin layer chromatography,HPTLC浸渍薄层色谱法 impregnated thin layer chromatography凝胶薄层色谱法 gel thin layer chromatography离子交换薄层色谱法 ion exchange thin layer chromatography制备薄层色谱法 preparative thin layer chromatography薄层棒色谱法 thin layer rod chromatography液相色谱仪 liquid chromatograph制备液相色谱仪 preparative liquid chromatograph 凝胶渗透色谱仪 gel permeation chromatograph涂布器 spreader点样器 sample applicator色谱柱 chromatographic column棒状色谱柱 monolith column monolith column微粒柱 microparticle column填充毛细管柱 packed capillary column空心柱 open tubular column微径柱 microbore column混合柱 mixed column组合柱 coupled column预柱 precolumn保护柱 guard column预饱和柱 presaturation column浓缩柱 concentrating column抑制柱 suppression column薄层板 thin layer plate浓缩区薄层板 concentrating thin layer plate荧光薄层板 fluorescence thin layer plate反相薄层板 reversed phase thin layer plate梯度薄层板 gradient thin layer plate。