Determination of thermal hydraulic data of GHARR-1 under reactivity insertion
ACI 209R-1992 混凝土结构蠕变、干缩和温度效应预测

J
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Chapter 4-Response of structures in which time change of stresses due to creep, shrinkage and temperature is negligible, pg. 209R-16
CHAPTER l-GENERAL l.l-Scope
Chapter 3-Factors affeating the structural response assumptions and methods of analysis, pg. 209R-12
5.9-Other cases 5.10-Example
Acknowledgements, pg. 209R-25 References, pg. 209R-25 Notation, pg. 209R-29 Tables, pg. 209R-32
4.1-Introduction 4.2-Deflections of reinforced concrete beam and slab 4.3-Deflection of composite precast reinforced beams in shored and unshored constructions 4.4-Loss of prestress and camber in noncomposite prestressed beams 4.5-Loss of prestress and camber of composite precast and prestressed-beams unshored and shored constructions 4.6-Example 4.7-Deflection of reinforced concrete flat plates and two-way slabs 4.8-Time-dependent shear deflection of reinforced concrete beams 4.9-Comparison of measured and computed deflections, cambers and prestress losses using procedures in this chapter
间隙腐蚀

间隙腐蚀间隙腐蚀是发生于间隙及有停滞溶液之遮蔽表面处的局部电化学腐蚀。
若要产生间隙腐蚀,必须有一个间隙其宽度足够让液体进入,但却也可使液体停滞不流出。
因此,间隙腐蚀通常发生于开口处有百万分之几公尺或更小宽度的间隙。
粒间腐蚀粒间腐蚀是发生在合金晶界及晶界附近的局部腐蚀现象。
在正常情况下,若金属均匀腐蚀时,晶界的反应只会稍快于基质的反应。
但在某些情况下,晶界区域会变得很容易起反应而导致粒间腐蚀,如此会使合金的强度下降,甚至导致晶界分裂。
应力腐蚀金属的应力腐蚀破裂(SCC)是指由拉伸应力及腐蚀环境结合效应所导致的破裂。
在SCC期间,金属表面通常只受到很轻微的侵蚀,但局部裂缝却很快沿着金属横断面传播。
产生SCC所需的应力可以是残留应力或施加应力。
裂缝会开始于金属表面上的蚀孔或其他不连续处。
在裂缝开始成长时,其尖端会开始向前,此时作用在金属上的拉伸应力会在裂缝尖端处形成高应力,当裂缝尖端向前传播时,在裂缝尖端处也会产生电化学腐蚀而使阳极金属溶解。
裂缝会沿着垂直于拉伸应力的方向成长,直到金属破坏为止。
若应力或腐蚀其中任一停止,则裂缝将停止成长。
冲蚀腐蚀冲蚀腐蚀可被定义为由于腐蚀性流体与金属表面相对运动而导致金属腐蚀速率加速的现象。
当腐蚀性流体的相对运动速率相当快时,机械磨擦效应将会相当严重。
冲蚀腐蚀的特征为金属表面具有与腐蚀性流体流动方向相同的凹槽、蚀孔与圆孔等。
涡穴损伤此类型的冲蚀腐蚀是由接近金属表面之液体中的气泡及充气孔穴破灭所造成的。
涡穴损伤通常发生在具有高速液体流动及压力改变的金属表面。
移擦腐蚀移擦腐蚀发生在材料承受振动及滑动负荷的界面处,它会形成具有腐蚀生成物的凹槽或蚀孔。
当金属发生移擦腐蚀时,磨擦表面间的金属碎片会被氧化且某些氧化膜会因磨擦动作而剥落,因此摩擦表面间会累积可当研磨剂用的氧化物颗粒。
选择性腐蚀选择性腐蚀是指固体合金内某一特定金属被优先去除的腐蚀过程。
此类型腐蚀最常见的例子是黄铜内之脱锌作用。
准噶尔盆地呼探1_井高温高压超深井试油测试技术

文章编号:1000 − 7393(2023)04 − 0447 − 08 DOI: 10.13639/j.odpt.202202006准噶尔盆地呼探1井高温高压超深井试油测试技术陈超峰1 刘新宇1 李雪彬1 陈雪茹2 相志鹏3 丁乙41. 中国石油新疆油田分公司勘探事业部;2. 中国石油集团西部钻探工程有限公司试油公司;3. 中国石油新疆油田分公司工程技术研究院;4. 西南石油大学引用格式:陈超峰,刘新宇,李雪彬,陈雪茹,相志鹏,丁乙. 准噶尔盆地呼探1井高温高压超深井试油测试技术[J ]. 石油钻采工艺,2023,45(4):447-454.摘要:呼探1井属于高温高压超深井,针对试油过程中所面临复杂的地质条件、恶劣的井况条件、极端的工况条件等问题,开展了施工风险评估,结果显示,试油施工主要面临入井管柱埋卡风险、井筒安全风险和井控安全风险。
通过优选光油管射孔测试一体化管柱进行施工,避免了入井管柱埋卡的风险;通过井筒安全校核、出砂预测和套压控制计算,设置套管最高限压,现场控制生产压差,消除了井筒安全风险;通过地面测试流程优化、实时跟踪分析、制定应急措施方法,有效控制了井控安全风险。
呼探1井试油作业安全平稳运行,并试获高产工业油气流,日产气61×104 m 3、日产油106 m 3,录取地层压力高达146.07 MPa 。
研究成果为高温高压超深井试油测试提供了技术借鉴。
关键词:呼探1井;高温高压;超深井;测试技术;地层压力;井筒安全中图分类号:TE273 文献标识码: AHigh-temperature, high-pressure & ultra-deep well testing technology used inWell Hutan 1 in tha Junggar BasinCHEN Chaofeng 1, LIU Xinyu 1, LI Xuebin 1, CHEN Xueru 2, XIANG Zhipeng 3, DING Yi 41. Exploration Division , PetroChina Xinjiang Oilfield Company , Karamay 834000, Xinjiang , China ;2. Oil Test Company , CNPC Xibu Drilling Engineering Co., Ltd., Karamay 834000, Xinjiang , China ;3. Research Institute of Engineering Technology , PetroChina Xinjiang Oilfield Company , Karamay 8340003, Xinjiang , China ;4. Southwest Petroleum University , Chengdu 610500, Sichuan , ChinaCitation: CHEN Chaofeng, LIU Xinyu, LI Xuebin, CHEN Xueru, XIANG Zhipeng, DING Yi. High-temperature, high-pressure & ultra-deep well testing technology used in Well Hutan 1 in tha Junggar Basin [J ]. Oil Drilling & Production Technology, 2023,45(4): 447-454.Abstract: Well Hutan 1 is an ultra-deep well with high pressure and high temperature. To address the challenges posed by complex geological conditions, adverse well conditions, and extreme operational conditions during the well testing process, a risk assessment of the construction was conducted. The well testing operation primarily faces three potential risks: pipe sticking in the well,well safety and well control risk. Innovative measures were taken to mitigate these risks. An integrated pipe string, optimized for perforation and testing, was used to avoid the risk of pipe sticking in the well. On the base of well safety check, sand production prediction and casing pressure control calculation, the maximum casing pressure limit was set, and the production pressure difference基金项目: 国家自然科学基金“极端条件下气井管柱耦联振动力学行为与控制基础理论研究”(编号:51974271)。
HTRI空冷器教程

H T R I7教程01界面熟悉1.双击快捷图标,打开程序界面:HTRI启动界面2.创建一个“新的空冷器”3.设置自己熟悉的一套单位制,比如MKH公制,也可以通过<Edit…>来自定义。
4.接下来就是将界面中的“红框”也就是缺少的参数按你将要设计的工况填写完整,包括如下几部分的数据,4.1 “Process”工艺条件:包括热流体侧和空气侧;4.2 “Geometry”机械结构:包括管子、管束、风机等;5.当输入数据足够所有的红框消失,那么初步的输入就完成了,可以点击"绿灯"图标运行。
02?工艺参数输入1.点击左边目录栏的“Process”标签,右边显示的就是供工艺参数输入的界面:??2.我们从上到下依次来看需要输入的参数:*为必要输入参数2.1 Fluid name –?流体名称,这里没有红框,不是必须输入的,就是自己定义下流体描述比如“Propylene”“Oil”“Wet Air”等,要注意的是程序对中文字符不支持,那么大家多写写英文就是了~本帖隐藏的内容2.2 Phase/Airside flow rate units –?流体相态/空气侧的流量单位*2.3 Flow rate –?流量不必多解释,热侧为质量流量。
2.4 Altitude of unit(above sea level) –?海拔高度*2.5 Temperature –?流体的温度,单位°C (SI,MKH), °F(US),这里要注意的是想输入0度,那么请填 0.001,不然0或0.0的输入都将被程序认为是没有输入(这个原则在HTRI程序的其他地方也适用)。
2.6 Weight fraction vapor –?重量气相分率,那么全气相就是1,全液相就是0咯。
2.7 Pressure reference –?压力参照点,就是接下来你输入的操作压力值指的是进口压力还是出口压力。
海洋钻井平台压井管汇注乙二醇参数优化

2021年1月第37卷第1期石油工业技术监督Technology Supervision in Petroleum IndustryJan.2021Vol.37No.1海洋钻井平台压井管汇注乙二醇参数优化霍宏博1,2,张启龙2,李金泽2,张磊2,王文21.油气藏地质及开发工程国家重点实验室西南石油大学(四川成都610500)2.中海石油(中国)有限公司天津分公司(天津300459)摘要通过数值模拟,钻井管汇在放喷时具备天然气水合物形成条件,有可能堵塞节流阀,导致严重的事故。
实验研究证明天然气水合物形成的概率会随着注入乙二醇体积分数而变化,以此为依据,绘制乙二醇的注入参数图版,保持在压井过程中管汇中的乙二醇体积分数预防水合物形成。
对乙二醇体积分数对天然气水合物抑制效果进行实验研究,得到天然气井通过节流管汇进行放喷时的乙二醇推荐注入量,以及不同工况的注入参数、注入时机,避免管汇内达到天然气水合物的生产条件,保障井控安全。
关键词火成岩;井壁稳定;破岩机理Optimization of Glycol Injection Parameters of Kill Manifold on Offshore Drilling PlatformHuo Hongbo1,2,Zhang Qilong2,Li Jinze2,Zhang Lei2,Wang Wen21.Oil and Gas Reservoir Geology and Exploitation,Chengdu University of Technology(Chengdu,Sichuan610500,China)2.Tianjin Branch,CNOOC(China)Co.,Ltd.(Tianjin300459,China)Abstract Numerical simulation shows that the drilling manifold has the formation conditions of natural gas hydrate during blowout, which may block the throttle valve,resulting in loss of well control means and serious accidents.The experimental study shows that the probability of gas hydrate formation will change with the injected glycol concentration.Based on this,the injection parameter chart of ethylene glycol is drawn to keep the glycol concentration in the manifold during well killing to prevent hydrate formation.The experi⁃mental study on the inhibition effect of ethylene glycol concentration on natural gas hydrate was carried out.The recommended injec⁃tion amount of ethylene glycol,injection parameters and injection timing under different working conditions are obtained when the natu⁃ral gas well is blowout through the choke manifold,so as to avoid reaching the production conditions of natural gas hydrate formation in the manifold and ensure the safety of well control.Key words igneous rock;wellbore instability;rock breaking mechanism霍宏博,张启龙,李金泽,等.海洋钻井平台压井管汇注乙二醇参数优化[J].石油工业技术监督,2021,37(1):27-30.Huo Hongbo,Zhang Qilong,Li Jinze,et al.Optimization of glycol injection parameters of kill manifold on offshore drilling platform [J].Technology Supervision in Petroleum Industry,2021,37(1):27-30.0引言天然气水合物在低温、高压状态下生成,也叫可燃冰,它在陆地冻土区与深海区被视为一种新型清洁能源[1-3],近期中国的成功开发已引起世界石油行业重视,但天然气水合物堵塞节流压井管汇将对钻井安全产生严重的负面影响[4-8]。
电导池

Effects of sulfonated polyether-etherketone (SPEEK)and composite membranes on the proton exchange membrane fuel cell (PEMFC)performanceErce S x engu ¨l a ,Hu ¨lya Erdener a ,R.Gu ¨ltekin Akay a ,Hayrettin Yu ¨cel a ,Nurcan Bac¸b ,_Inc _I Erog ˘lu a ,*a Chemical Engineering Department,Middle East Technical University,06531Ankara,TurkeybChemical Engineering Department,Yeditepe University,34755Istanbul,Turkeya r t i c l e i n f oArticle history:Received 8March 2008Received in revised form 20August 2008Accepted 22August 2008Available online 5November 2008Keywords:PEM fuel cells SPEEKComposite membrane Zeolite betaMembrane electrode assembly (MEA)a b s t r a c tSulfonated polyether-etherketone (SPEEK)has a potential for proton exchange fuel cell applications.However,its conductivity and thermohydrolytic stability should be improved.In this study the proton conductivity was improved by addition of an aluminosilicate,zeolite beta.Moreover,thermohydrolytic stability was improved by blending poly-ether-sulfone (PES).Sulfonated polymers were characterized by posite membranes prepared were characterized by Electrochemical Impedance Spectroscopy (EIS)for their proton conductivity.Degree of sulfonation (DS)values calculated from H-NMR results,and both proton conductivity and thermohydrolytic stability was found to strongly depend on DS.Therefore,DS values were controlled time in the range of 55–75%by controlling the reaction time.Zeolite beta fillers at different SiO 2/Al 2O 3ratios (20,30,40,50)were synthesized and characterized by XRD,EDX,TGA,and SEM.The proton conductivity of plain SPEEK membrane (DS ¼68%)was 0.06S/cm at 60 C and the conductivity of the composite membrane containing of zeolite beta filled SPEEK was found to increase to 0.13S/cm.Among the zeolite Beta/SPEEK composite membranes the best conductivity results were achieved with zeolite beta having a SiO 2/Al 2O 3ratio of 50at 10wt%loading.Single fuel cell tests performed at different operating temperatures indicated that SPES/SPEEK membrane is more stable hydrodynamically and also performed better than pristine SPEEK membranes which swell excessively.Membrane electrode assemblies (MEAs)were prepared by gas diffusion layer (GDL)spraying method.The highest performance of 400mA/cm 2was obtained for SPEEK membrane (DS 56%)at 0.6V for a H 2–O 2/PEMFC working at 1atm and 70 C.At the same conditions Nafion Ò112gave 660mA/cm 2.It was observed that the operating temperature can be increased up to 90 C with polymer blends containing poly-ether-sulfone (PES).ª2008International Association for Hydrogen Energy.Published by Elsevier Ltd.All rightsreserved.1.IntroductionThe increased interest in the potential use of proton exchange membrane fuel cells (PEMFCs)is due to the factthat they can offer high efficiencies with almost zero emis-sion of pollutant gases.Moreover,the quick start-up times and high flexibility to load changes are other advantages.The PEMFC,which uses hydrogen and oxygen (or air)as reactant*Corresponding author .Tel.:þ903122102609;fax:þ903122102600.E-mail address:ieroglu@.tr (_Inc _I Erog˘lu).A v a i l a b l e a t w w w.s c i e n c e d i r e c t.c o mj o u r n a l h o m e p a g e :w w w.e l s e v i e r.c o m /l o c a t e /h e0360-3199/$–see front matter ª2008International Association for Hydrogen Energy.Published by Elsevier Ltd.All rights reserved.doi:10.1016/j.ijhydene.2008.08.066i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 34(2009)4645–4652gases,is particularly attractive due to high power outputs delivered at low operating temperatures(50–80 C)and pres-sures(1–3atm).The electrochemical reaction occurs in the membrane electrode assembly(MEA),which is considered to be the heart of PEMFC[1].When hydrogen gas is fed to the anode side of the cell,it separates into its protons and elec-trons.The protons are conducted through the membrane electrolyte whereas the free electrons produced at the anode move through an external circuit to the cathode.At the cathode side,oxygen gas combines with the electrons and protons.Thefinal products of such a cell are electric power, water,and heat.They are ideally suited for transportation and other appli-cations.PEM fuel cell stacks operating on hydrogen can be 40–50%electrically efficient and80%system efficient if the heat recovery is included.The research and development of PEM fuel cell stacks based on different materials,structures and fabricating methods are going on[2–4].05pThe key component of PEMFC is the membrane which enables proton transfer between anode and cathode.Current applications prefer NafionÒ(DuPont)which belongs to the perflourosulfonic acid(PFSA)family[5].However,there are two significant drawbacks associated with the use of Nafion membrane.First,the cost of NafionÒmembrane is still too high for commercial applications.Second,it is not possible to operate at high temperatures with NafionÒ.High temperature operation is useful for enhanced reaction kinetics and reduced catalyst poisoning by fuel impurities.Therefore,efforts are concentrated on developing alternate membranes that are capable of operating at higher temperatures.Phosphoric acid doped polybenzimidazole is one of the most successful elec-trolyte membranes[6].Other,the most popular candidates are polyaromatic hydrocarbon polymers,especially PEEK,due to its high thermal and mechanical stability,low price and improvable proton conductivity via post-sulfonation. Although,it is improvable,the conductivity of SPEEK membrane is still lower than that of NafionÒ.Its proton conductivity depends on the degree of sulfonation(DS). However,the mechanical properties tend to deteriorate as the DS increases.Highly sulfonated polymers will swell signifi-cantly at high temperature and humidity[7].2.Experimental2.1.Zeolite synthesis and characterizationZeolite beta crystals were synthesized hydrothermally according to the batch composition2.2Na2O:1.0Al2O3:x SiO2: 4.6(TEA)2O:440H2O at various SiO2/Al2O3ratios[8].In hydrothermal synthesis,an alkaline precursor solution was prepared by dissolving sodium aluminate(52.9wt%Al2O3, 45.3wt%Na2O,Riedel de Hae¨n)in deionized water prior to addition of the structure directing agent,tetraethyl ammo-nium hydroxide(TEAOH)solution(20or35wt%in water, Aldrich).The silica precursor solution,mainly composed of colloidal silica(SiO2),(Ludox40wt%suspension in water, Sigma–Aldrich),was added to the alumina precursor solution and gelation was observed.This gel was poured into Teflon-lined steel autoclaves were kept at constant temperature (150 C)under autogenously pressure for a reaction period of 5–15days.The autoclaves were then taken out of the oven, cooled,filtered,and the zeolite product was dried at80 C. Zeolite beta was calcined at550 C,and then converted into more proton conductive Hþform after acid treatment with 95–98wt%H2SO4(Merck).Synthesized zeolite beta samples were characterized by X-Ray Diffraction(XRD)to confirm beta structure,Thermogravimetric Analysis(TGA)for its thermal stability,Energy Dispersive X-Ray Analysis(EDX)to compare theoretical Si/Al ratio with that in synthesized form,and Scanning Electron Microscopy(SEM)for crystal morphology and average particle size.2.2.Polymer sulfonation2.2.1.Sulfonation of PEEK polymerPEEK polymer was obtained as pellets(Polyoxy-1,4-pheney-leneoxy-1,4-pheneyelene carbonyl-1,4-phenylene,Aldrich, Mw¼20,800).PEEK pellets were ground to reduce the disso-lution time of the polymer and dried at100 C in vacuum oven prior to post-sulfonation.In the post-sulfonation reaction,the polymer was dissolved in H2SO4to give a dark,viscous solu-tion then the degree of sulfonation(DS)was controlled by changing the reaction times at a constant temperature(50 C) [9].Reaction was stopped by pouring the polymer solution in icy-water and white polymer strings were obtained.The decanted polymer strings were washed with deionized water and dried in vacuum oven.2.2.2.Sulfonation of PES polymerPES polymer cannot be easily sulfonated as PEEK in H2SO4. Therefore chlorosulfonic acid(CSA)was used in the sulfona-tion reaction.The polymer wasfirst dissolved in H2SO4 (usually1/10w/v)then a predetermined amount of CSA was added drop wise into the solution.Reactions were carried out at around5 C by using ice-cold water around reaction vessel to prevent cross linking and decomposition of the polymer chains which may occur above20 C.At the end of the pre-determined reaction time solution was poured into cold ice-water and the precipitate wasfiltered and washed until excess acid is removed and dried at90 C.2.2.3.Determination of DS by H-NMRThe H-NMR spectra were obtained by using Bruker Biospin NMR spectrometer with a resonance frequency of300MHz. Samples were prepared by dissolving10–20mg polymer in DMSO-d6.The degree of sulfonation,DS,was determined by integration of distinct aromatic signals determined quantita-tively by using H-NMR spectroscopy.In H-NMR the presence of sulfonic acid group’s results in a0.25ppm down-field shift of the hydrogen H E compared to H C,H D in the hydroquinone ring[10].The nomenclature of the aromatic protons for the SPEEK repeat unit is given in Scheme1below.The presence of sulfonic acid groups in the structure causes a distinct signal for protons at E position.Estimates for the H E content which is equal to the sulfonic acid group content can be done according to the intensity of this signal[10].The H-NMR signal for sulfonic acid group is difficult since the proton is labile.The ratio of peak area of distinct H E signalsðA HEÞand integrated areas of the signalsi n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y34(2009)4645–4652 4646corresponding to all the other aromatic hydrogen’s ðA H AA 0BB 0CD Þare expressed as:n 12À2n¼A H EPA H AA 0BB 0CD ð0 n 1Þ(1)DS ¼n Â100%(2)2.3.Membrane castingThe SPEEK polymer was dissolved in n-n,dimethyl-acet-amide (DMAc,Merck)and stirred overnight with magneticstirrer.Then,zeolite H þ-beta was added to the solution at certain quantities.The solution was mixed under ultrasonic mixing overnight and then drop-casted onto petri dishes.The membranes were dried in vacuum oven at 60–120 C for 24h.For blend membranes,proportional amounts of sulfonated PEEK and PES polymers were dissolved in DMAc to give a 10wt%polymer solution.The solution was stirred by magnetic stirrer overnight prior to mixing in ultrasonic water bath to obtain a homogenous solution.After mixing,the homogenous solution was cast onto Petri dishes and dried from 60 C to 120 C in 24h.2.4.Proton conductivity analysisThe proton conductivity of the membranes was measured by AC Electrochemical Impedance (EIS)technique over a frequency range of 1–300kHz with an oscillating voltage using GAMRY PCL40Potentiostat system.All measurements were performed in longitudinal direction,under water vapor atmosphere at 100%relative humidity with a 4probe EIS as a function of temperature.The specimens were prepared as 1Â5cm membrane strips and sandwiched into a Teflon Òconductivity cell with Pt electrodes (Fig.1).The specimen and the electrodes were fixed by nuts and bolts.The conductivity,s ,of samples in longitu-dinal direction was calculated in Siemens per cm from the impedance data by using Eq.(3);s ¼L RWd(3)where;L is the distance between the electrodes,W is the width of the membrane,d is the thickness of the membraneand R is the low intersect of the high-frequency semi-circle on a complex impedance plane with the Re(Z )axis.Proton conductivity measurements were performed in a closed jar with water at the bottom in a temperature controlled bath with mechanical stirrer.The temperature and relative humidity (RH)of the vapor inside the jar were measured with a thermocouple and RH meter.Conductivities were measured several times at each temperature until they were constant.2.5.MEA preparationMEAs were prepared from the membranes cast,which resul-ted in good proton conductivities during electrochemical impedance spectroscopy analyses.Gas diffusion layer (GDL)Spraying technique was applied for the preparation of MEAs [10].In the first step,catalyst ink,which is comprised of 20wt%Pt on Vulcan XC-72catalyst (E-Tek),5wt%Nafion Òsolution (Ion Power Inc),distilled water,and 2-propanol,were prepared and mixed in ultrasonic bath for 2h.In order to clean and increase the proton conductivity of the membranes,they were conditioned by boiling in 0.5M H 2SO 4solution and distilled water at 80 C.In order to coat the GDLs with catalyst layer,the anode and cathode side GDLs were fixed on a paper frame.The catalyst ink was sprayed until the desired catalyst loading (0.4mgPt/cm 2for both anode and cathode sides)was achieved.The catalyst loading was controlled by just weighing the GDLs at different times.After the GDLs were loaded with catalyst,they were kept in oven at 80 C for 1h in order to completely remove the liquid components of catalyst ink.Then,they were weighed again.To complete the MEA,the GDLs were hot pressed to the membrane at 130 C [11].2.6.Performance testsPerformances of fabricated MEAs were measured via the PEMFC test station built at METU Fuel CellTechnologyScheme 1–Aromatic protons of PEEK andSPEEK.Fig.1–Proton conductivity cell.i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 34(2009)4645–46524647Laboratory.A single cell PEMFC (Electrochem FC05-01SP-REF)having 5cm 2active area was used in the experiments.The external load was applied by means of an electronic load (Dynaload ÒRBL488),which can be controlled either manually or by the computer.The current and voltage of the cell were monitored and logged throughout the operation of the cell by fuel cell testing software (FCPower Òv.2.1.102Fideris).The fabricated MEA was placed in the test cell and the bolts were tightened with a torque 1.7Nm on each bolt.The cell temper-ature was adjusted and the temperatures of the humidifiers and gas transfer lines were set 10 C above the cell tempera-ture.After the preset temperatures were achieved,hydrogen and oxygen are supplied to the cell at a rate of 0.1slpm.The cell was operated at 0.5V until it came to steady state.After steady state was achieved,starting from the OCV value,the current–voltage data was logged by changing the load.3.Results3.1.Zeolite beta characterizationThe XRD pattern of zeolite beta that was hydrothermally synthesized at SiO 2/Al 2O 3ratio of 20is given in Fig.2a.The characteristic peaks of zeolite beta were observed at 2q w 7.8 and 2q w 22.4 as stated in literature [12].The morphology of the zeolites was explored with SEM and the average particle size distribution was found to be around 1micron as shown in SEM Picture below (Fig.2b).Another important characteristicof zeolite beta is its high thermal stability.Thermogravimetric Analyses of zeolite beta crystals showed that the first weight loss was around 465 C as given in Fig.2c and it demonstrates the removal of the structure directing agent (SDA)from the zeolite structure.Thus,zeolite crystals were calcined at higher temperatures to remove SDA completely.The thermal decomposition temperature of zeolite beta particles was around 850 C,this means that the zeolite beta particles are stable up to this temperature.Hence,they are suitable for fuel cell applications.As a result of the EDX analysis it was found that the Si/Al ratio in the structure of the as synthesized zeolite Na-Beta is close to the value of Si/Al ratio in the batch solution (theo-retical)(Table 1).3.2.Sulfonated polymer characterizationsDegree of sulfonation (DS)values of the sulfonated polymers was determined by using H-NMR data as described intheFig.2–(a)XRD pattern of as synthesized zeolite beta (SiO 2/Al 2O 3[20)(b)SEM micrograph of as synthesized zeolite beta (c)TGA of as synthesized zeolite beta.i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 34(2009)4645–46524648experimental section.The signal around7.6ppm chemical shifts corresponds to the aromatic proton H E and its area relative to the other aromatic protons shows the extent of DS (data are not given).The degree of sulfonation is directly related to the reaction time,temperature and the amount of the sulfonation agent used.At higher temperatures the reaction kinetics is enhanced thus higher degrees of sulfonation are achieved. PEEK sulfonation proceeds very slow at room temperature and takes several days to reach a DS above50%.However at around50 C this time decreases to several hours as shown in Fig.3which is consistent with the literature[13].DS of PES was determined similarly as reported in the literature[14].Since sulfonation of PES is more difficult than that of PEEK because of the electrophilic sulfone linkage,DS was around20%.Therefore,conductivity of SPES samples was lower than SPEEK.Since swelling and thermohydrolytic stability strongly depends on DS,SPES membranes showed better stability and low swelling.These properties can becombined by blending these compatible polymers.3.3.Proton conductivity of composite membranesThe objective of introducing zeolite particles into the polymer matrix was to enhance the proton transfer through the membrane by retaining water within the membrane and to create water mediated pathways while contributing their own proton conductivity.The hydrophilic zeolite particles improved the water retention property of the SPEEK membranes.Above60 C,the composite membranes absor-bed too much water and swelling problem was observed above this temperature(Fig.4).Thus,the proton conductivity analyses of composite membranes were limited up to this temperature.The proton conductivities of plain and composite membranes were measured at room temperature before and after treatment with1M HCl.Acid treatment was performed after the casting process,and all the membranes were kept in 1M HCl for2h for complete protonation.Acid treated membranes always result in higher conductivities naturally since all the available ion exchange sites are saturated with protons(–SO3H).All membranes were washed and hydrated with deionized water prior to measurement.As shown in Fig.5,the membranes with higher DS were resulted in better proton conductivities.Proton transfer enhances by increasing the number of acid sites enhances the proton transfer.Moreover,the effect of acid treatment on proton conductivity was explored in Fig.5and improved proton conductivities were observed after the acid treatment of the membranes.Thus,the membranes were treated with 1M HCl and washed with distilled water prior to proton conductivity measurements.Another important observation that could be made in Fig.5is the effect of zeolite particles. The composite membranes containing zeolite Beta have shown improved proton conductivities,for instance,0.11S/ cm was achieved for the composite membranes with74%DS after acid treatment.This is a promising result,since it is comparable with the conductivity of Nafion112membrane (0.1S/cm).Fig.3–Degree of sulfonation with respect to time ofsulfonationreaction.Fig.4–Water uptake capacities of plain and compositeSPEEKmembranes.Fig.5–Proton conductivity of plain and compositemembranes(with10wt%zeolite loading)at roomtemperature and fully hydrated state.i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y34(2009)4645–46524649In order to overcome the swelling problems observed in the pure and composite SPEEK membranes,SPEEK polymer was blended with a more hydrophobic polymer,namely sulfonated poly-ether-sulfone (SPES).The PES polymer was post-sulfonated and blended with SPEEK polymer at pre-determined proportions before membrane casting.However,owing to the poor proton transfer mechanism of SPES poly-mer,lower conductivities were obtained for blend membranes compared to the pure and composite SPEEK membranes.The proton conductivity measurements of pure SPEEK,SPES and blend membranes are given in Fig.6.So a trade-off between mechanical strength and conductivity exists for these blends.3.4.Performance testsFirst of all,the effect of using different catalyst ink solutions on the membrane performance is explored.The MEAs could be either prepared by using Nafion Òsolution or the original SPEEK solution [15].The comparison of two MEAs prepared by both Nafion Òand SPEEK solutions are given in Fig.7.It is apparent that the utilization of Nafion Òsolution in the catalyst ink resulted inhigher performance.Thus,Nafion Òsolution is utilized in the preparation of all MEAs.Second,the effect of operating temperatures on the performances of MEAs prepared by using SPEEK membranes (DS 56%)was examined and the results are given in Fig.8.It was observed that SPEEK based MEAs were not stable at high temperatures and they have punctured above 90 C.The best operating temperature of SPEEK based MEAs was found to be 70 C as demonstrated in Fig.9.The thermal stability of the membranes could be improved by blending with SPES poly-mer.It was noticed that,after the incorporation of 10wt%SPES into SPEEK membrane,the cell operating temperature could be increased up to 90 C without any damage to the membrane.As shown in Fig.9,the highest power output could be obtained at 80 C for SPES–SPEEK blend membranes.In order to understand the effect of sulfonation level on membrane performance,MEAs were prepared by using two membranes with different DS and the test results are displayed in Fig.10.It was not surprising to observe higher performance results for the MEA prepared by using the membrane at higher DS,since the proton transfer facilitates more easily with increased sulfonic acid groupcontents.Fig.6–Proton conductivities of plain and blendmembranes.Fig.7–Comparison of Nafion Òsolution and SPEEK solution for SPEEK based MEAs (cell temperature 708C).Fig.8–Effect of operating temperature on the performance of SPEEK (DS 56%)basedMEAs.Fig.9–Effect of sulfonation level on the performance of SPEEK based MEAs (cell temperature 708C).i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 34(2009)4645–46524650Another important parameter affecting the MEA’s perfor-mance is membrane treatment.Since the proton transfer mechanism of both SPEEK and SPES membranes depend on the acidic character of the membranes,the acid treatment influences the membrane performance.The performance curves of both untreated and acid treated SPEEK based MEAs are given in Fig.11.The acid treated membrane showed almost threefold higher power density compared to the untreated membrane.The fuel cell performance of SPEEK membrane was compared with the performance of Nafion Òmembrane as given in Fig.12.The current density of plain SPEEK membrane (DS 56%)was 400mA/cm 2at 0.6V,whereas that of Nafion Ò112membrane was 660mA/cm 2under the same conditions.Although SPEEK membrane possesses lower fuel cell perfor-mance in comparison to the Nafion membrane,the result is promising when the relatively low cost of SPEEK membrane is considered.Moreover,the composite membrane SPEEK-Laponite exhibited better performance than the pure SPEEK membrane [9].Composite membranes prepared with inor-ganic additives such as silica,zeolite 4A and zeolite beta increase the proton conductivity and fuel cell performances of both Nafion Òand SPES-40polymer membrane [16].It should be emphasized that the same technique of MEA fabrication,cell assembling and operating conditions were used in the present work.The significant difference of the obtained performances can be caused by various factors.One of them is the difference in the thickness of the membranes [17].Proton transfer mechanisms are also quite different in Nafion Òand SPEEK membranes.Degree of hydration is the factor that influences the proton conductivity of a membrane.The hydration is dependent on the phase separation between the hydrophobic polymer backbone and hydrophilic side chains [18].Nafion Òand SPEEK polymers both exhibit phase separated domains consisting of an extremely hydrophobic backbone which gives morphological stability and extremely hydrophilic side chains [18].Higher performances could be obtained for the membranes with higher DS values and for composite membranes.4.ConclusionThe development of alternative membranes at relatively low cost for fuel cell applications requires target properties such as suitable thermal and chemical stability,mechanical strength,comparable proton conductivity and fuel cell performance with the commercial PEM fuel cell membranes.In this study,zeolite beta composite membranes and blend membranes were developed.The proton conductivity of SPEEK was improved by addition of an aluminosilicate,zeolite beta.Also thermohydrolytic stability was improved by blending poly-ether-sulfone (PES).The proton conductivity of plain SPEEK membrane (DS ¼68%)was 0.06S/cm at 60 C and the conductivity of the composite membrane consisting of zeolite beta fillers into SPEEK was further increased to 0.13S/cm.Among the zeolite beta/SPEEK composite membranes the best conductivity results were achieved with zeolite beta having a SiO 2/Al 2O 3ratio of 50at 10wt%loading.Single fuel cell tests performed at different operating temperatures indicated that SPES/SPEEK membrane ismoreFig.11–Effect of acid treatment on the performance of SPEEK (DS 56%)based MEAs (cell temperature 708C).Fig.12–The comparison of performances of Nafion Òand SPEEKmembranes.Fig.10–Effect of operating temperature on the performance of blend membranes.i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y 34(2009)4645–46524651stable hydrodynamically and also performed better than pristine SPEEK membranes which swell excessively. Membrane electrode assemblies(MEAs)were prepared by gas diffusion layer(GDL)spraying method.The highest perfor-mance,which is400mA/cm2,was obtained for SPEEK membrane(DS56%)at0.6V for a H2–O2/PEMFC working at 1atm and70 C.At the same conditions NafionÒ112gave 660mA/cm2.It was observed that the operating temperature can be increased up to90 C with polymer blends containing poly-ether-sulfone(PES).AcknowledgementsThis study was supported by Turkish Scientific and Research Counsel with Project104M364and Turkish State Planning Organization Grant BAP-08-11-DPT2005K120600.r e f e r e n c e s[1]Barbir F.PEM fuel cells theory and practice.ElsevierAcademic Press;2005.[2]Corbo P,Migliardini F,Veneri O.Performance investigation of2.4kW PEM fuel cell stack in vehicles.International Journalof Hydrogen Energy2007;32:4340–9.[3]Hu M,Sui S,Zhu X,Yu Q,Cao G,Hong X,et al.A10kW classPEM fuel cell stack based on the catalyst-coated membrane (CCM)method.International Journal of Hydrogen Energy2006;31:1010–8.[4]Yan X,Hou M,Sun L,Liang D,Shen Q,Xu H,et al.ACimpedance characteristics of a2kW PEM fuel cell stackunder different operating conditions and load changes.International Journal of Hydrogen Energy2007;32:4358–64.[5]Bıyıkog˘lu A.Review of proton exchange membrane fuel cellmodels.International Journal of Hydrogen Energy2005;30: 1181–212.[6]Li Q,He R,Jensen JO,Bjerrum NJ.PBI-based polymermembranes for high temperature fuel cells–preparation,characterization and fuel cell demonstration.Fuel Cells2004;4(3):147–59.[7]Xing DM,Li BY,Liu FQ,Fu YZ,Zhang HM.Characterization ofsulfonated poly(ether ether ketone)/polytetrafluoroethylene composite membrane for fuel cell applications.Fuel Cells2005;5(3):406–11.[8]Akata B,Yilmaz B,Jirapnogphan SS,Warzywoda J,Sacco Jr A.Characterization of zeolite beta grown in microgravity.Microporous and Mezoporous Materials2004;71:1–9.[9]Chang JH,Park JH,Park G-G,Kim C-S,Park O-O.Proton-conducting composite membranes derived from sulfonated hydrocarbon and inorganic materials.Journal of PowerSources2003;124:18–25.[10]Zaidi SMJ,Michailenko SD,Robertson GP,Guiver MD,Kaliaguine S.Proton conducting composite membranes from polyether ether ketone and heteropolyacids for fuel cellapplications.Journal of Membrane Science2000;173:17–34.[11]Bayrakc¸eken A,Erkan S,Tu¨rker L,Erog˘lu_I.Effects ofmembrane electrode assembly components on protonexchange membrane fuel cell performance.InternationalJournal of Hydrogen Energy2008;33(1):165–70.[12]Holmberg BA,Hwang S-J,Davis ME,Yan Y.Synthesis andproton conductivity of sulfonic acid functionalized zeolitebeta nanocrystals.Microporous and Mesoporous Materials 2005;80:347–56.[13]Huang RYM,Shao P,Burns CM,Feng X.Sulfonation ofpolyetherether–ketone(PEEK):kinetic study andcharacterization.Journal of Applied Polymer Science2001;82: 2651–60.[14]Guan R,Zou H,Lu D,Gong C,Liu Y.Polyethersulfonesulfonated by chlorosulfonic acid and its membranecharacteristics.European Polymer Journal2005;41:1554–60.[15]S x engu¨l E,Erkan S,Erog˘lu_I,Bac¸N.Effect of gas diffusion layercharacteristics and addition of pore forming agents on theperformance of polymer electrolyte membrane fuel cells.Chemical Engineering Communications,2008;196(1–2):161–70.[16]Bac N,Nadirler S,Ma C,Mukerjee S.Inorganic–organiccomposite membranes for fuel cell applications.In:Proceedings international hydrogen energy congress andexhibition IHEC2005Istanbul,Turkey;2005.[17]Grigoriev SA,Lyutikova EK,Martemianov S,Fateev VN.Onthe possibility of replacement of Pt by Pd in a hydrogenelectrode of PEM fuel cells.International Journal of Hydrogen Energy2007;32:4438–42.[18]Hogarth M,Glipa X.High temperature membranes for solidpolymer fuel cells.Johnson Matthey Technology Center;2001 [Crown Copyright].i n t e r n a t i o n a l j o u r n a l o f h y d r o g e n e n e r g y34(2009)4645–4652 4652。
SL26-92水利水电工程技术术语标准
中华人民共和国行业标准PSL 26-92水利水电工程技术术语标准Standard of Technical Terms on Hydroengineering1992-06-02发布1992-12-01实施中华人民共和国行业标准水利水电工程技术术语标准SL 26—92主编单位:武汉水利电力大学批准部门:中华人民共和国水利部能源部中华人民共和国水利部发布能源部关于颁发《水利水电工程技术术语标准》SL26—92的通知水科教[1992] 19号为促进水利水电科学技术的发展,统一水利水电工程技术术语,推动国内和国际技术交流,由水利水电规划设计总院委托武汉水利电力大学主编的t水利水电工程技术术语标准》,经审查现批准为水利行业标准,其名称与编号为:《水利水电工程技术术语标准》SL26—92,该标准从1992年12月1日起实施。
在实施中如有问题,请函告水利水电规划设计总院或武汉水利电力大学。
本标准由水利电力出版社出版发行。
1992年6月2日目次I 水利水电工程勘测SURVEY AND INVESTIGATIONFOR HYDROENGINEERING工程测量1 工程测量基础2 测量仪器3 工程测量4 摄影测量5 遥感技术6 地图编绘与制印工程地质7 地质基础,8 水文地质9 工程地质水文测验10 一般术语11 水文调查12 水文测站和站网13 水文观测14 近代水文测验技术15 水文资料整编岩土力学16 岩土的物理性质17 岩土的变形性质18 岩土的强度特性19 岩土的渗透性质20 岩土中应力及岩土体变形计算21 岩土体稳定分析及承载力22 岩土现场测试Ⅱ水利水电工程规划PLANNING OF HYDROENGINEERING水文计算及水文预报1 河流及流域特征2 水文分析计算3 水文预报水资源开发利用4 水资源开发利用5 地下水资源开发利用航道整治规划6 航道整治规划防洪规划7 防洪规划水能利用规划8 水能利用规划灌溉排水规划9 土壤一作物一大气系统10 灌溉用水量的分析和计算11 灌溉水源12 灌水技术13 灌溉系统14 治涝排渍15 圩垸区及感潮河段治理16 排水系统17 灌溉排水试验及管理水土保持规划18 水土保持规划河流泥沙及河道整治规划19 河流泥沙运动力学20 河道形态与河床演变2l 河道整治22 水库泥沙23 河流模拟环境影响与库区移民24 环境影响与库区移民经济评价25 经济评价Ⅲ水工建筑物HYDROSTRUCTURES水力学1 水静力学2 水运动学及水动力学3 层流与紊流4 水流阻力和能头损失5 管流6 明槽流(明渠流)7 堰流及孔口出流8 建筑物下游消能9 波浪10 渗流水工建筑物11 水工建筑物的类别及荷载12 坝13 水闸14 溢洪道15 水工隧洞16 涵洞与涵管17 取水建筑物18 河道整治建筑物19 渠系建筑物20 通航、过木、过鱼建筑物21 地基处理水电站22 水电站23 引水系统及尾水系统建筑物水泵站24 抽水装置25 泵站Ⅳ水力机械与电气设备HYDRAULIC MACHINERY ANDELECTRIC EQUIPMENT水力机械1 水轮发电机组2 水泵电动机机组3 水力机组调节系统4 水力机组辅助系统5 水力机组测试6 水力机组的安装和试运行水工金属结构及安装7 钢结构8 闸门,阀门9 钢管、拦污栅及清理设备10 启闭机及起重机11 钢桥12 升船机及船厢13 埋件、连接件14 金属结构安装电力工程一次部分15 电力系统16 电力系统运行17 电力系统计算18 主要电气设备19 主接线及配电装置20 过电压21 厂用电、近区供电与施工用电电力工程二次部分22 励磁系统23 自动化及远动化24 继电保护25 控制与信号26 直流系统、二次设备及器具27 通信V 水利水电工程施工CONSTRUCTION OF HYDRAULICENGINEEBING施工组织l 施工组织施工导流2 施工导流土石方工程3 土石方工程混凝土工程4 混凝土工程施工工程设施5 施工工程设施概算、预算、决算6 概算、预算、决算施工管理7 施工管理中文索引I 水利水电工程勘测Ⅱ水利水电工程规划Ⅲ水工建筑物Ⅳ水力机械与电气设备V 水利水电工程施工编制说明附加说明I 水利水电工程勘测SURVEY AND IHVESTIGATION FORHYDROENGINEEBING工程测量Engineering Survey1 工程测量基础Fundomentals of engineering survey1.1 坐标与高程Coordinate and elevation1.1.1 大地水准面geoid与平均海(水)面(无波浪、潮汐、水流和大气压变化引起的扰动)重合并延伸到大陆和岛屿内部所形成的一个封闭的水准面。
威德福完井工具
Premium housing connections as a standard feature optimises reliability
No elastomeric seals are used, avoiding fluid compatibility and explosive decompressionproblems
Features:
API Q1 and API14AQuality programmes ensure design and manufacturing integrity
Number of Pressure Seals / potential leak paths minimized
No Complexity added to the Safety Valve tofacilitate Lockout or Control Line Communication
坚固的、经过现场检验的自平衡机构使操作非常简便。
设计的附属工具采用钢丝进行操作,避免复杂的作业需求。
应用范围:
Optimax系列安全阀设计用于生产井或注入井中的液体或气体环境,它是完井管柱的一个组成部分,通过液压控制管线进行控制,控制管线加压使安全阀保持在打开状态,压力释放后安全阀关闭。如果发生井喷,这种工具在人为控制下能可靠关闭,可有效地保护人员、财产和环境的安全。万一安全阀发生故障,可以用锁定打开工具和控制管线连通工具将安全阀改装成可下入一个插入式钢丝安全阀,减少生产的停顿。
安全阀
Optimax
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Optimax系列油管可回收式地面控制井下安全阀(TRSCSSV)是威德福进入安全阀市场的入门产品。应用最新的技术和设计理念使这一产品结构最简单,操作达到最大的可靠性。Optimax系列W(E)-5型油管可回收式安全阀是一种杆式活塞、活瓣型安全阀,额定工作压力为5,000psi,下入深度有1,000英尺和2,000英尺两种,有自平衡式活瓣机构供选择。
镜质体成烃反应动力学模型的标定及其在热史恢复中的应用
© 1994-2009 China Academic Journal Electronic Publishing House. All rights reserved. http://www.cnki.net14卷4期 1996年12月 沉积学报ACTASEDIMENTOLOGICASINICA V.14N.4Dec.1996
镜质体成烃反应动力学模型的标定及其在热史恢复中的应用①
卢双舫 王子文 付晓泰 王振平(大庆石油学院,安达 151400)
提 要 镜质体反射率(Ro)与其生烃率有关,因此,由R
o
应可求取其生烃率;同时,在求取了
镜质体成烃反应动力学参数之后,若已知其受热史,则可计算出镜质体的生烃率;反过来,若已知镜质体的生烃率,应可反推其受热史。基于这一基本原理,本文在建立和标定镜质体成烃反应动力学模型的基础上推导了可将其应用于存在着抬升、剥蚀和古地温非线性变化等复杂地质条件下热史恢复的原理模型,结合海拉尔盆地海参7井的实测Ro值,有效地恢复了其古热史。关键词 化学动力学 古地温梯度 古热史恢复 镜质体反射率第一作者简介 卢双舫 男 32岁 博士 副教授 石油地球化学
1 热史研究的意义和现状热史研究是有机质生烃史研究的基础,研究古地温的方法概括起来,可以分为三类:一类是岩石化学的方法,这主要是一些非连续的地质温度计的方法,如同位素地温计、自生矿物及其组合温度计、包裹体地温计、裂变径迹地温计等。用这类方法来研究古地温,优点是直观,但它们的不足是只能指示形成温度或所经历的最高温度,而不能反应时间的效应和古地温的演变,从而不能被应用于生烃史的动态评价中。第二类方法是从大地构造背景来研究热史变化的方法,这类方法是由Mckenzie(1978)提出,后经Royden〔5〕和Hellinger,Sclater(1980)改进的方法。其主要特点是依据盆地所处的大地构造背景和盆地
的形成机制和发育模式,从能量守衡和物质平衡的原理出发模拟古地温及其变化。这一方法的优点是能够把握区域大地热流变化的总体趋势和预测无钻井地区地层的热史,其局限性是需要深部地层的资料。另外,由于有关参数(如边界条件)的选取比较粗糙,因此难以反映局部的热史变化,预测精度也较低。第三类方法是有机地球化学的方法,这类方法主要是基于一些能够反应时间和温度综合效应的成熟度指标(如镜质体反射率和生物标记化合物成熟度指标的变化来反映热史变化。由于镜质体反射率能反映的成熟度范围大、测
利用自然伽马测井估算塔里木盆地沉积层生热率
自然界的岩石 中 存 在 着 许 多 的 放 射 性 元 素,这 些元素自然衰变所产生的放射热是地壳表层甚至地 球内热的主要来 源。 地 壳 中 含 有 60 多 种 不 稳 定 的 核 素 ,只 有 同 时 具 备 三 个 条 件 才 能 显 著 影 响 地 温 :一 定 丰 度 、产 热 量 高 、半 衰 期 与 地 球 年 龄 相 当 。 地 壳 中 同时具备这 三 个 条 件 的 核 素 只 有 铀 (U)、钍 (Th)、 钾(K)三种元素。这三种放射性元素 为 地 球 提 供 大 量的热能,对 地 表 热 流 的 贡 献 甚 至 能 达 到 30% 到 40%(Buntebarth,1988;WangJiyang,2015)。 这 三 种元素在地壳中的 分 布 很 不 均 匀,甚 至 在 同 一 种 岩 石 中 的 含 量 变 化 都 很 大 ,研 究 其 赋 存 分 布 规 律 ,对 于 了解地壳物质对大 地 热 流 的 贡 献、盆 地 热 体 制 和 油 气探勘等 领 域 具 有 重 大 指 导 意 义 (Qiu Nansheng, 2004;Abbady,2006)。
引用本文:罗昕,朱传庆,张宝收,唐博 宁,陈 天 戈.2020.利 用 自 然 伽 马 测 井 估 算 塔 里 木 盆 地 沉 积 层 生 热 率.地 质 学 报,94(7):2078~ 2088,doi:10.19762/j.cnki.dizhixuebao.2020219. LuoXin,ZhuChuanqing,ZhangBaoshou,TangBoning,ChenTiange.2020.Heatproductionratecalculationusinggamma rayloggingofthesedimentaryformationintheTarimbasin,NorthwestChina.ActaGeologicaSinica,94(7):2078~2088.
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Nuclear Engineering and Design 241(2011)5203–5210Contents lists available at SciVerse ScienceDirectNuclear Engineering andDesignj o u r n a l h o m e p a g e :w w w.e l s e v i e r.c o m /l o c a t e /n u c e n g d esDetermination of thermal hydraulic data of GHARR-1under reactivity insertion transients using the PARET/ANL codeN.A.Adoo a ,∗,B.J.B.Nyarko a ,b ,E.H.K.Akaho a ,b ,E.Alhassan a ,V.Y.Agbodemegbe a ,C.Y.Bansah a ,R.Della aa School of Nuclear and Allied Sciences,University of Ghana,Legon,P.O.Box AE 1,Atomic,Accra,Ghana bNational Nuclear Research Institute,Ghana Atomic Energy Commission,P.O.Box LG 80,Accra,Ghanaa r t i c l e i n f o Article history:Received 7October 2010Received in revised form 13August 2011Accepted 12September 2011a b s t r a c tThe PARET/ANL code has been adapted by the IAEA for testing transient behaviour in research reactors since it provides a coupled thermal hydrodynamic and point kinetics capability for estimating thermal hydraulic margins.A two-channel power peaking profile of the Ghana Research Reactor-1(GHARR-1)has been developed for the PARET/ANL (Version 7.3;2007)using the Monte Carlo N-Particle code (MCNP)to determine the thermal hydraulic data for reactivity insertion transients in the range of 2.0×10−3 k/k to 5.5×10−3 k/k.Peak clad and coolant temperatures ranged from 59.18◦C to 112.36◦C and 42.95◦C to 79.42◦C respectively.Calculated safety margins (DNBR)satisfied the MNSR thermal hydraulic design criteria for which no boiling occurs in the reactor core.The generated thermal hydraulic data demon-strated a high inherent safety feature of GHARR-1for which the high negative reactivity feedback of the moderator limits power excursion and consequently the escalation of the clad temperature.©2011Elsevier B.V.All rights reserved.Contents 1.Introduction........................................................................................................................................52032.The PARET model ..................................................................................................................................52042.1.Margin of hydrodynamic crisis.............................................................................................................52043.Reactor description ................................................................................................................................52053.1.Reactor application(s)and power upgrading strategies...................................................................................52054.Model ..............................................................................................................................................52065.Results and discussion.............................................................................................................................52066.Conclusion .........................................................................................................................................5209References .........................................................................................................................................52091.IntroductionThe production of stable and sustained nuclear power is never guaranteed in the economy of neutrons.This condition is attributed to the effect of unstable fluid flow,boiling liquids or reactivity,mechanical vibrations,malfunctioning of control apparatus or a combination of any two of these situations.A necessary condition for stable reactor power is that the reactor distortion accompany-ing a temperature rise,decrease the reactivity,thus slowing any further rise in power.The assertion,that satisfying the above con-dition guarantees power stability is based on a false assumption that reactor distortion occurs simultaneously with temperature rise which caused it.This distortion lags behind the temperature∗Corresponding author.Tel.:+233244537602;fax:+23321400310.E-mail address:nanakwame10@ (N.A.Adoo).change by a time determined by the dynamics of the system.Therefore the change in reactivity also lags behind the tempera-ture change raising the possibility of unstable power oscillations Han and Thomas,1999.Reactivity and stability are affected by depletion of reactor fuels and the accumulation of “poisons”dur-ing operation (Woodruff,1982).This causes transient instability in reactor power and hence the need for the acquisition of a fair knowledge of the transients and their effects to the operation.In the analysis of reactivity accidents it is customary to consider tran-sients with and without scram event called,protected transients and unprotected or self-limited transients respectively.Unpro-tected reactivity transients have received attention because of their relevance in determining the reactivity insertion limits imposed by clad melting temperature (Woodruff,1984;Nasir et al.,1999;Mirza et al.,1998;Housiadas,2000).Recent research in nuclear reactor technology has placed a high priority on the development of efficient and accurate analytical tools to carefully predict the0029-5493/$–see front matter ©2011Elsevier B.V.All rights reserved.doi:10.1016/j.nucengdes.2011.09.0195204N.A.Adoo et al./Nuclear Engineering and Design241(2011)5203–5210 behaviour of thermal hydraulic transients.During transients,thesafety behaviour of a reactor is influenced by the design character-istics,operating conditions and event sequence.Some of the mostimportant parameters in transient analysis include:(a)peak clad and coolant temperatures(b)temperature and void coefficients of reactivity and(c)power distribution and power peaking factors(d)heatflux at the hot spot.This work considers a thermal hydraulic data build-up of unpro-tected reactivity transients for the Ghana Research Reactor-1(GHARR-1)with the use of the PARET/ANL code(Version7.3;2007).2.The PARET modelThe PARET(P rogram for the A nalysis of RE actor T ransients)code was originally developed by the US Atomic Energy Com-mission(Hainoun and Alhabit,2008)for analysis of the SPERTIII experiments for temperatures and pressures typical of powerreactors(Scott et al.,1967;Obenchain,1969).The code has nowbeen modified to include a selection offlow instability,departurefrom nucleate boiling(DNB),single and two phase heat transfercorrelations and a coolant properties library considered more appli-cable to low pressures,temperatures as well asflow rates whichare typical of research reactors.This now gives room for loss-of-flow(LOF)and reactivity insertion accident(s)(RIA)of researchreactors to be modeled.Essentially,the code provides a coupledthermal–hydraulic and point kinetics capability with continuousreactivity feedback,and an optional voiding model which estimatesthe voiding produced by subcooled boiling(Woodruff,1982,1983;Olson and Jonah,2007).The design model of the code for the reac-tor core can be represented by1–50channels–each with its ownhydraulic parameters,coolantflow rates,and power distribution(radial).Each coolant channel can be divided up into as many as21axial sections for which the heat transfer is analysed.The solutions of the one-dimensional hydrodynamic equationsused are for each of the channels at each time node and is based onthe momentum integrated model(MIM).The heat transfer couldtake place by natural or forced convection,nucleate,transition,orstablefilm boiling and coolant could range from subcooled liquidthrough two-phase regime up to and including superheated steam.It allows forflow reversal as well(Clancy et al.,1975;Woodruff andSmith,2000).The governing equations of this model are expressedas:∂¯ ∂t =−∂G∂z(1)∂G ∂t +∂∂zG2=−∂P∂z−f|G|G2D e−¯ g(2)∂E∂t+G∂E∂z=q(3)where G is the massflow rate,∂P/∂z the pressure gradient,t time,z the axial coordinate(positive upwards),D e the equivalent hydraulic diameter,f the friction factor,q heat source rate per unit volume, g the acceleration due to gravity and E average coolant enthalpy in the energy equation.The coolant may range between a subcooled liquid and a sat-urated two-phase mixture.The average coolant density in the mass conservation equation,the average coolant enthalpy E in the energy equation,and the effective densities and pertaining to the momentum equation and energy equation respectively,are defined as:¯ = l(1−˛)+ v˛Average density(4)1=(1− )2l(1−˛)+2v˛Momentum density(5) =[ l + v(1− )]∂˛∂Slipflow density(6)¯E=El(1− )+E v Average enthalpy(7) where subscripts l and v denote liquid water and water vapor respectively,˛vapour volume fraction(void fraction),and vapour weight fraction(mass quality).The two-phase friction factor and the void-to-quality relationship are determined using the Mar-tinelli method(Collier,1972).Reactor transient behaviour requires the solution of the usual point kinetic equations which represent axial or radial power dis-tributions in each region.This comprises the neutronics with six groups of delayed neutrons and nine groups of photo-neutrons and for which the solution is shown below employing a modified Runge Kutta method(Hetrick,1971;Hamidouche et al.,2004).dndt=( (t)−1)ˇeffn(t)+6i=1i C di(t)+9j=1j C pj(t)+S p(8)dC didt=dˇdin(t)− i C di(t)(9)dC pjdt=pˇpn(t)− j C pj(t)(10)ˇeff= d6i=1ˇdi+ p9j=1ˇpj(11) S p=S(12)where n is the neutron density(or power), reactivity load,ˇefftotal fraction of delayed and photo neutrons,ˇdi,ˇpj=i th and j th group of delayed and photo neutron precursors respectively, i, j,decay constants for the i th and j th precursors,C di,C pj=precursordensities of delayed neutrons and photo neutrons, di, pj= efficiency of delayed and photo neutrons,S p(Watts/s)=source term,S(neutrons/s)=neutron source strength, =energy released perfission, =number of neutrons emitted perfission, =prompt neutron generation time.2.1.Margin of hydrodynamic crisisThe heatflux in water-cooled nuclear reactor system is used to estimate the Departure from Nucleate Boiling Ratio(DNBR)of the system which is an important engineering design parameter for nuclear reactors.The DNBR signifies an operational safety limit and during normal operation,there may befluctuations in,for example, the power of the reactor,which can affect the temperature distri-bution along a coolant channel.This causes variations in the DNBR and may reduce the safety margins(Zafar,2006).Heat removal in the GHARR-1is dependent on the upper and lower orifice heights which were determined to ensure effective cooling of the core.The criteria of thermal-hydraulic design require that the burnout ratio or DNBR should be larger than the calculated burnout heatflux i.e.DNBR>2.5(SAR,1995).The DNBR for GHARR-1operating at the transient power level of99.44kW was estimated by the relation,DNBR=q dnbq norm(13)N.A.Adoo et al./Nuclear Engineering and Design241(2011)5203–52105205Fig.1.Axial cross section of GHARR-1.where qdnb [W/m2]is the heatflux at the departure from nucleateboiling and q norm is the heatflux corresponding to the prevailing power.In subcooled boiling,qdnb is a function of the coolant velocity,the degree of subcooling and pressure.For low velocityflow the Mirshak correlation was employed in this work to calculate the q dnb and is given as DNB(Garland,1997),q dnb=1.51×106(1+0.1197u)[1+9.14×10−3( T)]×[1+1.89×10−1«](14)u=1.2727˙mcool H2(15)T=(5.725+147.6H−2.674)T−0.35iP(0.59+0.0019T i)(16) where u[m/s]is thefluid velocity in the range,H is the height of the inlet orifice in millimeters(mm),T i is the inlet core coolant temperature(◦C),P is the power level of the reactor(kW),and«[MPa]is the pressure.3.Reactor descriptionGHARR-1is a commercial version of the Chinese-made minia-ture neutron source reactor(MNSR)of maximum power30kW at a thermal neutronflux of1.0×1012n/(cm2s).It has a small com-pact cubic-cylindrical core with dimensions of230mm×230mm in diameter and height shown in Figs.1and2.It is a pool type research reactor developed and manufactured by the Chinese Insti-tute of Atomic Energy of which the details have been summarized in Table1(Akaho et al.,2003).Thefission heat generated is transferred by natural convection (a phenomenon that cools the reactor)in an upward direction as shown in Fig.3and circulated within the reactor tank.Some heat is transferred by conduction through the tank wall to the pool water. Under normal operational conditions,theflow regime is single phase but nucleate boiling is expected under abnormal condition when power excursion occurs due to large reactivity insertions.3.1.Reactor application(s)and power upgrading strategiesGHARR-1is predominantly used for neutron activation anal-ysis(NAA).However there is on-going research to access the feasibility of extending its application to the production of short-lived radioisotopes for medical purposes.The reactor could also be exploited for non-destructive testing by neutrons,radioactive tracer production,radiation source to demonstrateradiography,Fig.2.Annular view of the GHARR-1.criticality experiment and control rod calibration(Akaho et al., 2003;Ahmed et al.,2006).The long term reactor operation depletes the core excess reac-tivity due to fuel burn up,Xe-poisoning and the negative feedback of coolant temperature.The GHARR-1core has a fuel burn up of1%and was designed with a lifetime core of10years if it is operated at its maximumflux for2.5h a day,five days a week (Anim-Sampong et al.,1999).To minimize neutron leakage and hence conserve the neutron economy,the core is heavily reflected on the side and underneath the fuel cage by a thick annulus and slab of beryllium alloy material(Akaho et al.,2003).Under normal operating conditions of the HEU fuel a drop in core excess reactivity within the range of2.5–2.8mk due to fuel depletion are observed (Anim-Sampong et al.,2007).Due to the aging lifetime of the core, regulated shims of beryllium have been added to the top aluminium tray to compensate for the loss of reactivity resulting from fuel burn up and accumulation offission products(Akaho et al.,2003).Studies have therefore been initiated towards the conversion of the present 90.2%enriched HEU core to a proposed12.6%Low Enriched Ura-nium(LEU)core(Anim-Sampong et al.,2007)after the end of life (EOC)of the present core.The heat removal mechanism in MNSR depends on natural con-vection which is associated with lowflow velocities and low heat transfer coefficients.To boost the heat removal from the reactor core,improving the cooling inside the reactor pool and reactor vessel were both considered by Hainoun and Alissa(2007).Table1GHARR-1core design parameters with HEU fuel loading.No.Parameter Values1Reactor type Pool-tank2Rated thermal power30kW th3Fuel element loading3444No.of dummy elements65Fuel composition U-Al dispersed in Al 6Fuel density 3.456g/cm37Dummy element material Al8U-235enrichment90.2%9Burn up∼1%10Loading of U-235in core998.12g11Coolant/moderator Deionised H2O12Coolant/moderator density995.1kg/m313Coolant inlet temperature30◦C14Coolant inlet pressure101.3kPa–1bar15Cooling mode Natural convection 16Reflector Beryllium17Control rod absorber Cadmium18Number of control element119Excess reactivity–cold,clean4mk20Total number of irradiation sites105206N.A.Adoo et al./Nuclear Engineering and Design 241(2011)5203–5210Fig.3.Schematic diagram of the coolant flow pattern.The two major concepts of power-upgrade strategies proposed were,enhancing the heat transfer coefficient between primary and secondary side of reactor vessel by pumping part of pool water through an annulus duct surrounding the vessel at reactor core level and cooling the circulated water with an external heat exchanger.The second option dealt with cooling the reactor water via a heat exchanger located outside the reactor pool.The reactor coolant in the upper part of reactor vessel was pumped out,transported to the external heat exchanger,cooled and re-pumped to the vessel.At this location the re-pumped cooled water mixed directly with the hot coolant and reduced thereafter the core inlet temperature with the consequence of restricting the increase of average core temperature.This concept as indicated by Hainoun and Alissa (2007)and shown in Fig.4can be technically realized using the already avail-able reactor water purification system which is used for controlling and ensuring the required quality of reactor water.However,some technical modifications are required before extending the use of this system for the new task.This will imply also additional safety and radiation protection measures for the case of external heat exchanger.The option of pool water cooling was found to extend the con-tinuous reactor operation time up to 10h whiles that of reactor water cooling was up to 15h,both at nominal reactor power and under the assumption of initial excess reactivity corresponding to the fresh reactor core.This was possible because the external heat exchanger in each case enhanced core cooling by eliminating the negative feedback of coolant temperature and providing an excess reactivity to compen-sate the exclusive limiting effect of the Xe poisoning.By analogy,coupling of these two scenarios as shown in Fig.5could yield better results by further prolonging the operation time of the MNSR.4.ModelSimulations for a 500,000neutron population for 500cycles were run using the MCNP-5code based on a modified input deckdesign for GHARR-1(Briesmeister,2000;Anim-Sampong,2001)for which a two-channel radial power peak profile is generated at steady state.The channels represent the hottest fuel pin and the remainder of the core respectively and each of these was sectioned into 21equally spaced nodes over the active core region to be used for transient simulations.The axial peaking profile was also com-puted using the same procedure corresponding to the MCNP input deck design for axial sectioning.The transients were initiated by external reactivity insertions which ranged from 2.0×10−3 k/k to 5.5×10−3 k/k and specified as a function of time employing a modified PARET input deck by (Olson and Jonah,2007)to suit the reactor design specifications some of which are shown in Table 2.5.Results and discussionThe reactivity insertion accident simulated in this work demon-strated the self-limiting power excursion feature of the GHARR-1upon the full insertion of cold clean excess reactivity.The MNSR control and protection system is designed with the fail-safe prin-ciple,nevertheless,should a shut-down failure occur,a limiting maximum available excess reactivity of about 4.0mk could beTable 2GHARR-1model parameters.ParameterValueFuel temperature coefficient (mk ◦C −1)˛fm =7.73×10−6to 2.9×10−7T fm +1.09T 2fmMeat radius,f mr2.13×10−3m Moderator density, mod 998.19g cm −3Moderator temperature coefficient (mk ◦C −1)˛m =2.6445×10−5to 3.4752×10−6T m Decay constant, (s −1)9.62×10−2Void coefficient (mk per %)−4.78Prompt neutron generation time, (s)8.1×10−5Effective delayed neutron fraction,ˇeff8.03×10−6N.A.Adoo et al./Nuclear Engineering and Design241(2011)5203–52105207Fig.4.Conceptual MNSR power upgrading strategies by cooling pool water and vessel water(Hainoun and Alissa,2007). inserted.This available excess reactivity is less than1/2ˇeff to avertthe possibility of prompt criticality in the reactor.The simulationscarried out ranged from500to1.50×103s in transient span afterwhich the results are presented with their respective powers andtemperatures in Figs.6–13.The analysis which was carried out atnominal power level of30kW and inlet coolant of20◦C,consid-ered reactivity feedback effect,bulk temperature as well as the peakcladding temperature output.Simulated transient events initiatedby positive reactivity insertions ranging between2.0mk and5.5mkhave also been analysed.To check the accuracy of the simulation,a2.0mk step reactivity insertion was considered for which thepeak power recorded was40.17kW as against34.4kW and34.8kWobtained by RELAP-5and TEMPFED respectively(Akaho,2002)andapproximately37kW by TPR2in PARR-2(Mirza,1997).Experimen-tal results for a2.0×10−3 k/k reactivity insertion shown in Fig.8resulted in a peak power level of37.91kW and a coolant tempera-ture difference, T of22.42◦C in518s.Results from PARET/ANL forthe temperature profile are as follows:42.95◦C for the bulk coolant,59.18◦C for the clad and88.32◦C for the meat.This is illustrated inFigs.6and7.A simulated3.6mk reactivity insertion produced a maximumpower of71.22kW in6.23min in Fig.9.For this reactivity,theFig.5.Conceptual core cooling and long-time operation design for MNSR.0.00E+005.00E-031.00E-021.50E-022.00E-022.50E-023.00E-023.50E-024.00E-024.50E-020.00E+00 2.00E+02 4.00E+02 6.00E+028.00E+02 1.00E+03 Power(MW)Time (s)Fig.6.Power plot for2.0mk reactivity insertion.0.00E+001.00E+012.00E+013.00E+014.00E+015.00E+016.00E+017.00E+018.00E+019.00E+011.00E+020.00E+00 2.00E+02 4.00E+02 6.00E+028.00E+02 1.00E+03Temperature(°C)Time (s)Tclad CTf c/l CTout C Fig.7.Temperature plot for2.0mk reactivity insertion.5101520253035400100200300400500600700 Power(kW)Time (s)Fig.8.Experimental power profile for2mk reactivity for GHARR-1.5208N.A.Adoo et al./Nuclear Engineering and Design 241(2011)5203–52100.00E+001.00E-022.00E-023.00E-024.00E-025.00E-026.00E-027.00E-028.00E-020.00E+00 2.00E+02 4.00E+02 6.00E+028.00E+02 1.00E+03 1.20E+03 1.40E+03 1.60E+03P o w e r (M W )Time (s)Fig.9.Power plot for 3.6mk reactivity insertion.0.00E+002.00E+014.00E+016.00E+018.00E+011.00E+021.20E+021.40E+021.60E+020.00E+001.00E+022.00E+023.00E+024.00E+025.00E+02T e m p e r a t u r e (°C )Time (s)Tclad C Tf c/l C Tout CFig.10.Temperatures for ramp insertion of 3.6mk.0.00E+001.00E-022.00E-023.00E-024.00E-025.00E-026.00E-027.00E-028.00E-029.00E-021.00E-010.00E+001.00E+022.00E+023.00E+024.00E+025.00E+026.00E+027.00E+02P o w e r (M W )Time (s)Fig.11.Power plot for 4.0mk reactivityinsertion.T e m p e r a t u r e (C )Time (s)Fig.12.Temperature plot for 4.0mk reactivity insertion.020406080100120050100150200250300350400450500P o w e r (k W )Time (s)Fig.13.Experimental power profile for 4mk reactivity for GHARR-1.temperature profile for the peaks as shown in Fig.10are 60.57◦C for the moderator temperature,83.66◦C for the cladding and 134.26◦C for the fuel meat.The maximum allowed coolant temperature was 70.09◦C and the change in thermal transients was 3.4–6.2s between the meat and clad and then the clad to the coolant respec-tively.The transient response for GHARR-1upon simulation with RELAP-5code for 3.6mk ramp insertion presented comparable results with a peak power of 76kW after 6min of insertion with a corresponding maximum fuel centre temperature of 91.4◦C (SAR,1995).A 4mk ramp RIA was simulated by the PARET code to study the GHARR-1system response for a fully withdrawn control rod –a case for an unprotected transient for maximum allowed core excess reactivity as shown if Figs.11and 12.This is one of the severe tran-sients for the MNSR since it considers a completely stuck control rod accident for which the passive safety mechanism of the reac-tor is paring previous work by Akaho and Maakuu (2002);for the same ramp core excess reactivity to this work,the peak power as predicted by TEMPFED was 100.8kW which agreed favourably with the experimental result of 100.2kW in Fig.13.In comparison to Pakistan Research Reactor-2(PARR-2)which shares very similar design parameters with GHARR-1,Research Reactor Simulator (TPR2)under the same initiation event,effec-tively demonstrates the passive safety feature of PARR-2with a maximum reactivity insertion of the cold clean core (Mirza,1997).This work however presents a peak power of 91.13kW in a response time of 5min 50s which is justan approximate peak obtained from the PARR-2transient over –power simulation for the same reac-tivity magnitude as shown in Fig.14.A study of Tables 3and 4which present the power and temperature data for the variousFig.14.Variation of transient reactor power of 2mk and 4mk reactivities in PARR-2using the TPR2code (Mirza,1997).N.A.Adoo et al./Nuclear Engineering and Design 241(2011)5203–52105209Table 3Peak power and transient response times.Power (kW)Time (s)Reactivity (mk)Exp RELAP-5PARET/ANL TEMPFED Exp RELAP-5PARET/ANL TEMPFED 2.037.9134.440.1734.85186405933553.6–75.571.22––240332–4.0100.22–91.13100.8294–3243535.5–163.04–––150–Exp,experimental.Table 4Peak temperature and transient response times.Temperature (◦C)Reactivity (mk)RELAP-5PARET/ANL TEMPFED T outT max T fc T clad T out T max T fc T clad T out 2.048.451.968.368.042.9558.3688.3259.1855.73.661.562.191.591.260.5770.09134.2683.66–4.0––––64.1072.12161.2686.9272.65.5––––79.4283.23212.63112.36–reactivities reveal differences in time trends with the two codes.For example in the case of the power excursion for the 3.6mk inser-tion,whiles RELAP5recorded a response time of 240s,PARET/ANL comes up with a 332s time which is attributed to the different dis-cretization schemes/numerical schemes employed by these codes in solving the hydrodynamic equations.Whiles it is well established that PARET/ANL uses a modified Runge Kutta scheme,it is not clear whether the implicit or semi-implicit numerical solution scheme is employed by RELAP5in this case.Besides RELAP5is not the best code to simulate atmospheric pressure conditions as may be the case in this system.The differences in the experimental and ana-lytical results may be due to uncertainties in the correlations used in the models.The maximum reactivity load limit for the PARET simulation in this work was 5.5mk as illustrated in Figs.15and 16.The peak power calculated by PARET was 163.04kW which produced a large power pulse within a relatively short period of 150s.The fluctuat-ing power and thermal transient is due to the reactivity feedback caused by heating in the moderator (negative temperature coeffi-cient of reactivity),hence the reactor power is forced to drop until a stable power level of 102.12kW.This power excursion lasts for a period of 110s.Similar effects are experienced in the bulk coolant temperature and clad for the thermal hydraulic profile.The calcu-lated DNBRs for the heat fluxes generated during the 2mk,4mk and 5.5mk RIAs were found to be 13.42,6.63and 4.15respectively.0.00E+002.00E-024.00E-026.00E-028.00E-021.00E-011.20E-011.40E-011.60E-011.80E-010.00E+001.00E+022.00E+023.00E+024.00E+025.00E+02P o w e r (M W )Time (s)Fig.15.Power plot for 5.5mk reactivity insertion.0.00E+002.00E+014.00E+016.00E+018.00E+011.00E+021.20E+021.40E+021.60E+021.80E+020.00E+001.00E+022.00E+023.00E+024.00E+025.00E+02T e m p e r a t u r e (C )Time (s)Fig.16.Temperature plot for 5.5mk reactivity insertion.6.ConclusionThe PARET/ANL code has successfully been used under the MNSR operating conditions to simulate reactivity transients ranging from 2.0×10−3 k/k to 5.5×10−3 k/k.The code solved neutron and thermal hydraulic dynamic models under nominal reactor power and the results gave a basis for good comparison with earlier works on similar reactivity magnitudes by “Akaho et al”and analysis in the SAR.The code has been used to find the thermal hydraulic margins ofGHARR-1and has demonstrated that the high negative reactivity feedback of moderator temperature limits power excursion in the reactor.The maximum clad temperatures did not reach the condi-tion of onset of subcooled boiling and the fuel meat temperature remained below 640◦C –the melting point of U-Al.From the results of the safety margins,it can thus be said that no boiling occurred within the core since the MNSR thermal hydraulic design criteria for DNBR >2.5and also all measured temperatures were below the saturation temperature of light water at 100◦C at 101.3kPa.ReferencesAhmed,Y.A.,Ewa,I.O.B.,Umar,I.M.,Bezboruah,T.,Johri,M.,Akaho,E.H.K.,2006.TheLow Power Miniature Neutron Source Reactors:Design,Safety and Applications,ICTP Miramare –Trieste IC/2006/020.Akaho,E.H.K.,Maakuu,B.T.,2002.Simulation of reactivity transients in a miniatureneutron source reactor core.Nuclear Engineering and Design 213,31–42.Akaho,E.H.K.,Anim-Sampong,S.,Dodoo-Amoo,D.N.A.,Maakuu,B.T.,Emi-Reynolds,G.,Osae,E.K.,Boadu,H.O.,Bamford,S.A.,2003.Ghana Research Reactor-1Final。