Improved Calculation of Electroweak Radiative Corrections and the Value of V_ud

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高密度阳极铝电解槽电

高密度阳极铝电解槽电

第 54 卷第 2 期2023 年 2 月中南大学学报(自然科学版)Journal of Central South University (Science and Technology)V ol.54 No.2Feb. 2023高密度阳极铝电解槽电−热场耦合仿真研究魏兴国1,廖成志1,侯文渊1, 2,段鹏1,李贺松1(1. 中南大学 能源科学与工程学院,湖南 长沙,410083;2. 中北大学 能源与动力工程学院,山西 太原,030051)摘要:在铝电解槽中,阳极炭块内存在的气孔会降低炭块的导电和导热性能,并且增加炭渣,降低电流效率,导致炭耗和直流电耗升高。

通过浸渍工艺得到的高密度阳极可以有效地降低炭块的气孔率。

为了探究高密度阳极铝电解槽的电−热场变化和影响,基于ANSYS 软件建立高密度阳极铝电解槽的电−热场耦合计算模型。

研究结果表明:铝电解槽高密度阳极炭块的平均温度上升8.73 ℃,热应力增加,但形变量减小;侧部槽壳的平均温度下降28.59 ℃,热应力和形变量均降低,有利于保持槽膛内形稳定;热场变化主要与阳极炭块物性改变有关;槽电压降低49.16 mV ,主要与炭块物性改变和电解质电阻率降低有关;高密度阳极电流全导通时间缩短3.39 h ,可有效减弱换极产生的负面影响,阳极使用寿命可延长4 d ,炭耗降低10.3 kg/t ;铝电解槽反应能耗占比增加0.62%,电流效率提高1.69%,直流电耗降低270 kW·h/t 。

关键词:铝电解槽;高密度阳极;电−热场;耦合仿真中图分类号:TF821 文献标志码:A 文章编号:1672-7207(2023)02-0744-10Simulation study of electric-thermal field coupling in high-densityanode aluminum electrolyzerWEI Xingguo 1, LIAO Chengzhi 1, HOU Wenyuan 1, 2, DUAN Peng 1, LI Hesong 1(1. School of Energy Science and Engineering, Central South University, Changsha 410083, China;2. School of Energy and Power Engineering, North University of China, Taiyuan 030051, China)Abstract: In aluminum electrolytic cells, porosity in anode carbon blocks can reduce the electrical and thermal conductivity of the blocks and increase carbon slag, reduce current efficiency and lead to higher carbon consumption and DC power consumption. High-density anodes obtained by impregnation process can effectively reduce the porosity of carbon blocks. In order to investigate the electric-thermal field variation and the causes of influence in the high-density anode aluminum electrolyzer, a coupled electric-thermal field calculation model of收稿日期: 2022 −07 −11; 修回日期: 2022 −08 −20基金项目(Foundation item):国家高技术研究发展项目(2010AA065201);中南大学研究生自主探索创新项目(2021zzts0668)(Project(2010AA065201) supported by the National High-Tech Research and Development Program of China; Project (2021zzts0668) supported by the Independent Exploration and Innovation of Graduate Students in Central South University)通信作者:李贺松,博士,教授,博士生导师,从事铝电解研究;E-mail:****************.cnDOI: 10.11817/j.issn.1672-7207.2023.02.032引用格式: 魏兴国, 廖成志, 侯文渊, 等. 高密度阳极铝电解槽电−热场耦合仿真研究[J]. 中南大学学报(自然科学版), 2023, 54(2): 744−753.Citation: WEI Xingguo, LIAO Chengzhi, HOU Wenyuan, et al. Simulation study of electric-thermal field coupling in high-density anode aluminum electrolyzer[J]. Journal of Central South University(Science and Technology), 2023, 54(2): 744−753.第 2 期魏兴国,等:高密度阳极铝电解槽电−热场耦合仿真研究the high-density anode aluminum electrolyzer was established based on ANSYS software. The results show that the average temperature of the anode carbon block increases by 8.73 ℃ when the high-density anode is put on the tank, and the thermal stress increases but the deformation variable decreases. The average temperature of the side shell decreases by 28.59 ℃, and the thermal stress and deformation variable both decrease,which helps to protect the inner shape of the tank chamber stable. The change of the thermal field is mainly related to the change of the physical properties of the anode carbon block. The cell voltage decreases by 49.16 mV which is mainly related to the change of carbon block physical ploperties and the decrease of electrolyte resistivity, respectively. The reduction of 3.39 h in the full conduction time of high-density anode current can effectively reduce the negative effects of electrode change, and the anode service life can be extended by 4 d. The carbon consumption is reduced by 10.3 kg/t. The reaction energy consumption of aluminum electrolyzer is increased by 0.62%, the current efficiency is increased by 1.69%, and the DC power consumption is reduced by 270 kW·h/t.Key words: aluminum electrolyzer; high-density anode; electric-thermal field; coupling simulation作为铝电解槽的核心部件,阳极炭块在反应过程中被不断消耗,其品质直接影响着各项经济技术指标[1]。

电化学除钙 创新点

电化学除钙 创新点

电化学除钙创新点(中英文实用版)英文文档:Electrochemical Calcium Removal: Innovative PointsCalcium ions (Ca) can be effectively removed from water and other liquids using electrochemical methods.This innovative approach offers several advantages over traditional techniques, such as ease of operation, lower maintenance requirements, and higher efficiency.The key innovative points of electrochemical calcium removal include:1.Non-chemical purification: Unlike traditional water softening methods that involve adding chemicals like sodium chloride, electrochemical calcium removal does not require the addition of chemicals.This makes it a more environmentally friendly and healthier option.2.Reusable electrode materials: The electrodes used in electrochemical calcium removal systems can be made from sustainable and reusable materials, such as graphite or carbon paste.This reduces waste and lowers the overall cost of the purification process.3.Energy-efficient operation: Electrochemical calcium removal systems require minimal energy input, making them an eco-friendly and cost-effective choice.The energy efficiency of these systems is attributed to the use of direct current (DC) and the absence of chemical reactions.4.Simplified operation and maintenance: Electrochemical calcium removal systems are relatively easy to operate and maintain.The electrodes require periodic cleaning and replacement, but this can be easily done by the user or a professional technician.5.Wide applicability: Electrochemical calcium removal techniques can be used for various applications, including drinking water purification, industrial process water treatment, and the removal of calcium-containing impurities from beverages and other liquids.6.Customizable design: Electrochemical calcium removal systems can be designed to meet the specific needs of different applications.The size, shape, and material of the electrodes can be customized, allowing for optimal performance and efficiency.In conclusion, electrochemical calcium removal offers a innovative and effective solution for the removal of calcium ions from water and other liquids.Its non-chemical nature, reusable electrode materials, energy efficiency, simplicity, wide applicability, and customizable design make it a promising technique for purification and water treatment applications.中文文档:电化学除钙:创新点电化学方法可以有效地去除水和其他液体中的钙离子(Ca)。

2006年苏州大学论文被《SCI(E)》,《EI》,《ISTP》收录情况表

2006年苏州大学论文被《SCI(E)》,《EI》,《ISTP》收录情况表
2006 年苏州大学论文被《SCI(E)、 》《EI》《ISTP》收录情况表 、
序号 作者 Li, Shan-Liang; Zhu, Dao-Li 论文名称 Principal-agent analysis of supply chain incentive contract with asymmetric information 李善良 第一(通讯)作者 所在院系 政治与公共管 理学院 刊名 Jisuanji Jicheng Zhizao Xitong/Computer Integrated Manufacturing Systems, CIMS ICEMI 2005: CONFERENCE 2 Xu, DC; Zhou, XJ; Wen, WX; Wang, CF An injector beam automatic shutdown control system based on MCU PROCEEDINGS OF THE SEVENTH 徐大诚 应用技术学院 INTERNATIONAL CONFERENCE ON ELECTRONIC MEASUREMENT & INSTRUMENTS, VOL 2 Zhang, XN; Tang, LH; 3 Gonga, JH; Xu, XY; Zhang, Q Alternative albendazole polybutylcyanoacrylate nanoparticles preparation, pharmaceutical properties and tissue distribution in rats Involvement of nitric oxide in oxidative 4 Wang, JW; Zheng, LP; Wu, JY; Tan, RX burst, phenylalanine ammonia-lyase activation and Taxol production induced by low-energy ultrasound in Taxus yunnanensis cell suspension cultures Chen, Gang; Wu, 5 Jian-Hong; Chen, Xin-Rong; Liu, Quan Measurement of profile parameters of holographic photoresist grating mask made on top of chrome stack in spectroscopic way 吴建宏 信息光学工程 研究所 Zhongguo Jiguang/Chinese Journal of Lasers 王剑文 药学院 NITRIC OXIDE-BIOLOGY AND CHEMISTRY SCI\SCIE 张学农 药学院 LETTERS IN DRUG DESIGN & DISCOVERY SCIE ISTP EI 检索系统

英语翻译3

英语翻译3

姓名:朱丽娜学号:2012708022以Al2O3为载体的废钴钼催化剂用硫酸焙烧后浸取关键词:废催化剂硫酸焙烧钼钴铝摘要来自炼油厂经过预先氧化处理的以Al2O3为载体的废钴钼催化剂,我们尝试通过低温(200–450◦C)硫酸焙烧然后再温和的条件下浸取处理这种催化剂从而溶解其中的金属。

以直接的硫酸浸取相同样本,出现了铝和钼较低的回收率,而硫酸焙烧后浸取大大提高了这两种金属的回收率。

这种预氧化的废催化剂来自韩国的炼油厂,发现其含40%铝,9.92%钼,2.28%钴,2.5%碳和少量其他元素如铁,镍,和磷。

X射线衍射结果表明这种废催化剂的主要载体是结晶状态很差的γ- Al2O 3。

本文主要研究各种焙烧参数如废催化剂和算得比率、焙烧温度和烘烤时间等对金属的溶解率的影响。

观察到,金属的溶解率随焙烧温度升高到300摄氏而增加,进一步增加焙烧温度金属的溶解率逐渐降低。

在最佳焙烧条件下,与如下浸取条件下超过90%钴和钼,和93%铝可从废催化剂中溶解出来。

浸出条件为:硫酸= 2%(体积比),温度为95℃,时间为60分钟和纸浆密度为5%。

1概述为了严格遵循的排放法规,在石油冶炼过程中为了获得低硫、高辛烷值的清洁能源,使得使用各种催化剂成为必要。

加氢过程或加氢处理的催化剂(加氢脱硫,加氢脱氮,氢化处理等。

)组成超过的固定床催化剂总量的90 %被用于石油冶炼[ 1 , 2 ]。

被用于那些催化剂的活性金属是钼,助催化剂由其他金属如钴,镍组成,氧化铝是载体。

当那些催化剂的活性下降到低于一定的水平,他们通常被用来再生和重复利用。

然而,那些被再生和再利用的催化经过几个周期后将不再有效;此后他们被当做废物材料从炼油厂中丢弃[ 3 5 ]。

全球产生的废加氢催化剂估计约为150–170000吨/每年[ 6 ]。

环境法规,加之其含有的贵重金属(镍,钴,钒,钼等)吸引了科学界探索各种高效的处理方法。

最近的文献检索显示,已经有许多方法被探索出用于从废加氢处理催化剂中回收贵金属。

可使手机待机时间提效8倍的多孔硅阴极材料

可使手机待机时间提效8倍的多孔硅阴极材料

可使手机待机时间提效8倍的多孔硅阴极材料
张祖力
【期刊名称】《功能材料信息》
【年(卷),期】2008(000)0Z1
【摘要】据媒体报道,韩国汉阳大学一个研究小组近日宣布,他们成功开发出一种三维多孔硅阴极材料,能大幅度提升锂离子充电电池(以下称锂电池)的容量和效率,手机待机时间因此有望提高8倍。

【总页数】1页(P111-111)
【作者】张祖力
【作者单位】
【正文语种】中文
【中图分类】TN304
【相关文献】
1.多孔纳米硅碳复合材料可使电池储量提升两倍 [J],
2.阴极还原和酸处理对多孔硅稳定性和发光特性的改善 [J], 元美玲;唐鹿;吴真琦;汪庆年
3.多孔硅场发射阴极研究进展 [J], 罗文;胡文波
4.哪种手机电池待机时间长?:八种手机原装电池待机时间比较试验结果 [J], 无
5.韩开发出三维多孔硅阴极材料可大幅提高锂电池性能 [J],
因版权原因,仅展示原文概要,查看原文内容请购买。

研究发现水电解反应的高效催化剂-英语科普-

研究发现水电解反应的高效催化剂-英语科普-

研究发现水电解反应的高效催化剂更多英语科普-请点击这里获得Solar energy appears to be the only form of renewable that can be exploited at level that matches the world's growing needs. However, it is equally necessary to find efficient ways to store solar energy in order to ensure a consistent energy supply when sunlight is scarce. One of the most efficient ways to achieve this is to use solar energy to split water into hydrogen and oxygen, and get the energy back by consuming hydrogen in a fuel cell. But collecting solar energy on a large and sustainable scale means that such cells must be made from materials that are cheap, abundant, and have 10% solar‐to‐hydrogen conversion efficiency. Publishing in Nature Communications, an EPFL-led team of scientists has found a method to create a high-efficiency, scalable(可称量的)solar water splitting device using cheap materials.Although one of the best means of sourcing renewable energy, solar systems cannot consistently produce adequate energy since sunlight varies from time to time and place to place. A solution to this problem is a device that can store energy in the form of hydrogen for later use, offering a consistent output over time with very little pollution.One of the most sustainable methods of producing hydrogen is photoelectrochemical (PEC) water-splitting. Solar energy is used to break water molecules into hydrogen and oxygen through a process called "hydrogen evolution reaction." This reaction requires a catalyst, which is a chemical agent that increases its speed. In PEC water-splitting devices, a common catalyst used to split water is platinum, which is deposited on the surface of the solar panel's photocathode(光电阴极)-- the solar panel's electrode that converts light into electric current.A research team at EPFL has now found a way to make efficient solar-powered water splitting devices using abundant and cheap materials. The group of Xile Hu developed a molybdenum-sulfide catalyst for the hydrogen evolution reaction, and the group of Michael Grätzel developed copper(I) oxide as a photocathode. The researchers found that the molybdenum sulfide can be deposited on the copper(I) oxide photocathode for use in PEC water splitting through a simple deposition process that can be easily expanded onto a large scale.The technique shows comparable efficiency to other hydrogen evolution reaction catalysts like platinum, it preserves the optical transparency for the light-harvesting surface and it shows improvedstability under acidic conditions, which could translate into lower maintenance. But more importantly, both the catalyst and the photocathode are made with cheap, earth-abundant materials that could greatly reduce the cost of PEC water-splitting devices in the future. According to senior author Xile Hu, the work represents a state-of-the-art example for solar hydrogen production devices.本文章由邯郸信息库/收集整理。

Energy storage in electrochemical capacitors-- designing functional materials to improve performance

Energy storage in electrochemical capacitors:designing functional materials to improve performancePeter J.Hall,*a Mojtaba Mirzaeian,a S.Isobel Fletcher,a Fiona B.Sillars,a Anthony J.R.Rennie,a Gbolahan.O.Shitta-Bey,a Grant Wilson,a Andrew Cruden b and Rebecca Carter bReceived 24th March 2010,Accepted 21st June 2010DOI:10.1039/c0ee00004cElectrochemical capacitors,also known as supercapacitors,are becoming increasingly important components in energy storage,although their widespread use has not been attained due to a high cost/performance ratio.Fundamental research is contributing to lowered costs through the engineering of new materials.Currently the most viable materials used in electrochemical capacitors are biomass-derived and polymer-derived activated carbons,although other carbon materials are useful research tools.Metal oxides could result in a step change for electrochemical capacitor technology and is an exciting area of research.The selection of an appropriate electrolyte and electrode structure is fundamental in determining device performance.Although there are still many uncertainties in understanding the underlying mechanisms involved in electrochemical capacitors,genuine progress continues to be made.It is argued that a large,collaborative international research programme is necessary to fully develop the potential of electrochemical capacitors.1.IntroductionElectrochemical capacitors are devices that are capable of storing electrical charge but are distinguished from electrochemical cells as they can absorb and release charge much more quickly;they are an increasingly important class of energy storage devices.1,2Although frequently referred to as ‘‘supercapacitors’’or ‘‘ultra-capacitors’’these names convey little scientific information and are herein referred to as electrochemical capacitors (ECs).This is itself a generic name for two main subdivisions—Electrochemical Double Layer Capacitors (EDLCs)and pseudocapacitors,both of which will be described in Section 2.The term ‘‘super-capacitor’’does,however,convey one essential feature of thesedevices,namely their specific capacitance is six to nine orders of magnitude larger than conventional dielectric capacitors.This can be seen from a simple order of magnitude calculation.The specific capacitance,C (F g À1),of a capacitor is given by:2C ¼303rS D(1)where 30is the electric constant (8.854Â10À12F m À1),3r the relative dielectric constant of the interface (whether liquid or solid),S is the specific surface area of the electrodes (m 2g À1),and D (m )is the separation of the electrode plates.Firstly,consider a conventional dielectric capacitor.Assuming 3r z 103,S z 1m 2,and D z 10À6m then C z 8Â10À3F (in fact most capacitors used in electronic circuits are pF to m F).ECs are based around materials with S z 103m 2g À1and the formation of an electro-chemical double layer on the electrode surface during polar-isation for which D z 10À9m.Assuming 3r z 10then C z 80F g À1.Clearly,this is several orders of magnitude greater than conventional capacitors.aDepartment of Chemical &Process Engineering,University of Strathclyde,James Weir Building,75Montrose Street,Glasgow,G11XJ,Scotland,UK.E-mail:p.j.hall@ bDepartment of Electronic &Electrical Engineering,University of Strathclyde,Royal College Building,204George Street,Glasgow,G11XW,Scotland,UKPERSPECTIVE /ees |Energy &Environmental ScienceD o w n l o a d e d b y N a n k a i U n i v e r s i t y o n 28 A u g u s t 2010P u b l i s h e d o n 02 A u g u s t 2010 o n h t t p ://p u b s .r s c .o r g | d o i :10.1039/C 0E E 00004CThere are many ways of defining specific capacitance,such as normalisation to unit surface area,volume or mass of the device. However,since the focus of this perspective is materials,capac-itance is normalised to unit mass of active material,which simplifies comparisons between materials.Since the energy stored in a capacitor is given by:2E¼1CðD VÞ2(2)it becomes possible to store enough energy for many practical purposes.For example,a10m F capacitor operating at50V can store1.25Â10À3J whereas a3000F capacitor operating at2.7V can store approximately11Â103J.To give this number a prac-tical context,this is the equivalent kinetic energy of a1000kg vehicle moving at16km hÀ1(10mph).It is important to emphasise that since EC voltage decreases linearly with state of charge,not all of the stored energy can generally be used.The factors influencing energy density are summarised in eqn (1)but the factors determining power density are much more complex.The power density,P,is inversely proportional to the resistance of the device,R,as illustrated by:P¼14ðD VÞ2R(3)R is the equivalent series resistance(ESR)which is comprised of the electrode resistance,electrolyte resistance and resistance dueto the diffusion of ions in the electrode porosity.The rationale behind this perspective acknowledges the fact that ECs can store sufficient energy for a variety of applications and they outperform batteries in terms of power handling.Also, it is recognised that they are far from achieving their true commercial potential.In order to realise this potential,signifi-cant improvements are required to enhance the cost/performance ratio.Improvements in manufacturing and materials engineering are needed.This perspective commences with a comparison of different types of capacitor with electrochemical cells.This leads to an outline of the applications of EC devices.Since progress and wider adoption will rely on materials development,the perspec-tive provides an overview of the main classes of materials(elec-trodes and electrolytes)used in ECs.2.Batteries and electrochemical capacitors for electrical energy storageAlthough batteries and ECs are normally regarded as separate technologies,it is much more illuminating to regard them as different points on a continuum of electron transfer between electrolyte and electrode(Fig.1).At one end of the continuum are dielectric capacitors which store energy directly as electro-static charges on two opposing electrodes.Batteries are at the other end of the continuum where energy is stored through electrochemical reactions.ECs(patented by Becker in19573and commercialised by SOHIO in19782,4,5)differ from electrostatic capacitors by storing charge as an electrical double layer at the interface between electrode and electrolyte.Solvated ions in the electrolyteare Fig.1Representations of electrical energy storage in charged devices: (a)a traditional capacitor where charges are physically separated by a dielectric material,(b)an EDLC where charge separation occurs at the electrode/electrolyte interface,(c)a pseudocapacitor where charge transfer reactions occur at the electrode surface and(d)a generic battery where energy is stored as chemical potential by the change in oxidation state of the bulk electrodematerial.Pictured are members of the consortium from the University of Strathclyde(l–r):Dr A.Cruden,Prof.P.J.Hall,R.Carter,G.Wilson,Dr M.Mirzaeian,A.J.R.Rennie,G.O.Shitta-Bey and F.B.SillarsThe UK Energy Storage Consortium was launched in2006by theEngineering and Physical Sciences Research Council(EPSRC)aspart of the SUPERGEN initiative.The consortium aims to accel-erate the development of energy storage systems,and to providestrategies for their rapid implementation in the UK energy sector.The University of Strathclyde focuses on the development of elec-trode materials for electrochemical capacitors and lithium–oxygenbatteries and the application of these devices in thefield of trans-portation.More information can be found at www.energystor-.DownloadedbyNankaiUniversityon28August21Publishedon2August21onhttp://pubs.rsc.org|doi:1.139/CEE4Cattracted to the electrode surface by equal but opposite charges on the electrode effectively creating two capacitors in series connected by electrolyte.As a result of the high internal surface area of the electrodes and the nanometre scale thickness of the double layer,the capacitance and the energy density of an EDLC are several orders of magnitude higher than those of electrostatic capacitors,as described in Section 1.A further step in the continuum shows a transitional state with electrochemical processes involving Faradaic and non-Faradaic energy storage simultaneously.Conway 2refers to this as pseudocapacitance which is observed when fast,potential-dependent reactions result in Faradaic charge transfer across the double-layer.These reac-tions become thermodynamically favourable in certain ranges of potential and produce capacitive charge/discharge characteris-tics.This occurs due to the appearance of a derivative (d q /d V ),equivalent to a capacitance,realised by a change in the rate of charge acceptance with changes in potential.2Pseudocapacitive behaviour is identified using cyclic voltammetry.Materials exhibiting pure double-layer capacitance produce parallelogram-shaped voltammograms whereas irregular peaks are generated by pseudocapacitive materials.Reactions that result in Faradaic charge transfer are mainly of the redox type where changes in the oxidation state of the materials occur which is analogous to battery systems.However,reactions do not propagate into the bulk material,and occur only at the electrode/electrolyte interface.For example,ruthenium dioxide (RuO 2)can participate in redox reactions with a very high degree of reversibility and conse-quently charge/discharge lifetimes in excess of 106cycles are possible.5Intercalation of a guest species,such as Li +,into the electrode material can also produce a pseudocapacitive response.6For this reason,ECs utilising pseudocapacitance can be considered as a transition between EDLCs and intercalation batteries.It is important to note that although EDLCs and pseudocapacitors are differentiated on the basis of the predom-inant charge storage mechanism,all EC devices exhibit both mechanisms to some extent.The process shown in Fig.1c represents pseudocapacitance.This is similar to the redox reac-tions that occur in batteries,however,the charge/discharge behaviour is capacitative in nature.Completing the continuum are batteries which,as mentioned previously,store energy indirectly using Faradaic oxidation and reduction of electroactive reagents capable of generating charge,and bulk-phase transformations achieving high energy density and high voltage at the expense of slower transport and reduced cycle life.7Conway 2quantified the degree of electron transfer in different devices as:0.17–0.20e Àper atom of accessible surface in a double-layer capacitor,1–2.5e Àper atom of accessible surface of electroactive material in a pseudocapacitor and 1–3e Àper atom or molecule of bulk phase for a battery.Although it has been argued that capacitors and batteries effectively lie on a continuum of electron transfer,this should not mask essential differences in their characteristics and performance.For example,the reversibility of the chemical and capacitive energy storage systems is substantially different.In batteries,charge transfer across the electrode/electrolyte interface leads to changes in the molecular structure of the electrode by redox reactions and restricts cycle life to $103charge/discharge cycles.7Conversely,physical charge storage in EDLCs has no associated chemical and phase changes during cycling.This results in a highly reversible storage mechanism where cycle lifetimes greater than 106are frequently obtained which,in turn,leads to important differences in the energy and power handling of capacitors and batteries.This is usually summarised in a Ragone plot which compares energy density ((W h)kg À1)and power density (W kg À1).Fig.2shows a Ragone plot comparing the energy and power densities of Li-ion batteries with those of ECs at different discharge rates.Li/O 2technology is projected to produce energy densities of several times the values attained using current Li-ion technology.8,9ECs have the ability to produce much higher power densities in comparison with batteries and exhibit considerably fewer material stability problems.Based on such comparisons ECs and batteries should be regarded as comple-mentary technologies,each providing a unique solution to energy storage.3.Applications of electrochemical capacitorsIt is expected that ECs will be used for a variety of applications,most of which can be grouped into one or more of the following three categories:1.Power capture and supply2.Power quality applications3.Backup,safety and low maintenance applicationsECs are particularly appropriate in certain applications due to their high power capability,high efficiency and long life span.3.1Power capture and supplyFuture hybrid energy systems will couple the high energy density of batteries,fuel cells or internal combustion engines (ICEs)combined with the rapid charge/discharge and power capabilities of ECs.In such hybrids,batteries could provide an average power output,while ECs provide additional peak power when required.10In this way,batteries are not pushed to the limit of their power capabilities,resulting in longer battery lifetimes.ECs allow a more flexible approach in the design of energy systems,and as further performance improvements in areas suchasFig.2Specific power against specific energy for ECs and high-power Li-ion batteries.D o w n l o a d e d b y N a n k a i U n i v e r s i t y o n 28 A u g u s t 2010P u b l i s h e d o n 02 A u g u s t 2010 o n h t t p ://p u b s .r s c .o r g | d o i :10.1039/C 0E E 00004Cenergy density are made,this design flexibility for systems should increase.A passenger car driven in an urban or suburban setting will accelerate and decelerate frequently as the driver encounters traffic lights,turns and obstacles.The resultant drive cycle has power spikes due to the acceleration of the vehicle,and contains a significant amount of potentially recoverable energy from braking.An example of a real-life drive cycle showing the speed and power required by a small passenger car during a standard urban journey is given in Fig.3.10,11Note that the peak power required by the vehicle is 17kW,but the average power indicated by the dashed line is just 2.5kW.Furthermore,a peak power of 15kW is available from regenerative braking.The large disparity between peak and average power indicates that ECs could be very useful in passenger vehicles.ECs may therefore be used to improve the efficiency of vehi-cles,although the metric defining ‘efficiency’depends on the type of vehicle being discussed.If the ECs are used with an ICE or fuel cell,then fuel efficiency is the most important factor.If the ECs are used with batteries,then the efficiency would typically be measured in the yield:km (kW h)À1.In either case a greater efficiency should mean a greater range or a smaller size for the primary energy source (fuel tank or battery pack).Efficiency may also be measured in total emissions from the vehicle;although this is a considerably more complex calculation,it does indicate the direct environmental benefits.ECs may also be used to reduce maintenance and running costs for vehicles.For an ICE vehicle this will primarily mean reducing fuel consumption.For a battery-powered vehicle,it means extending the life of the batteries.In both cases the ECs can also extend the life of the friction brakes,as their ability to accept high power bursts means that the friction brakes will be used less frequently.In turn this creates a reduction in pollutants,in this case particulate matter from the brake pads.The benefits of ECs for passenger cars are also applicable to heavier hybrid vehicles such as urban buses,urban delivery vehicles and refuse collectors that have a high number of acceleration and deceler-ation cycles throughout their working day.12EC applications for trams,trains and trolleybuses allow for energy recovery in either a mobile form (onboard the vehicle)or in a static form (at a station or specific route stop).13EC energy recovery systems for these vehicles may also allow infrastructure costs to be reduced e.g.overhead lines and third lines may not be required along the full route.ECs have also found an application in starting diesel loco-motives.They are less susceptible to degradation than batteries at lower temperatures,in terms of both performance and life-span.In addition to the advantages previously mentioned,including increasing the lifespan of the batteries,and allowing for a smaller bank of batteries to be used,they also improve the fuel consumption of diesel engines,as the operator has the option to turn the engine off in the knowledge that it will start again.Industrial applications that require power recovery and/or high power bursts are also well suited to energy systems incorporating ECs.14Some load lifting equipments such as forklift trucks and seaport cargo cranes use hybrid power systems that include ECs to reduce the size of the primary energy source.In smaller products such as mobile phones,ECs can provide a pulse of energy to meet the needs of high current LED flash devices.Enhanced battery performance can be obtained using LEDs rather than current xenon technology.There is also interest in using ECs to provide higher quality audio from mobile phone speakers by providing better power management to the audio circuits.In cameras,ECs are utilised to extend the life of the battery by providing some of the peak power required to power intensive areas such as the optical zoom and flash.3.2Power quality applicationsUninterruptible power supplies (UPS)have protected the power quality in industrial and commercial applications for many years.In sectors such as pharmaceuticals,biotech,paper and semi-conductor production the cost implications of a poor quality power supply necessitate some form of voltage protection.Even if there is no damage to critical equipment,the loss of stock or manufacturing capacity can be prohibitive.The effects of loss of service in telecommunications or data storage centres also mean that power quality is viewed as a critical issue.UPS systems typically provide bridging power support until an auxiliary power supply can be brought on line or delicate equipment is shut down in a controlled manner.Dependent on the type of UPS system,it can also provide protection against voltage spikes and undesired harmonics in the power supply.If,as expected,there will be more decentralised generation coupled with a higher dependence on variable renewable energy generation,localised power quality management products will have a greater role to play.The role of ECs within UPS systems is seen as being favourable.15ECs are also currently used to stabilise dc bus voltages in vehicles,in order to protect the delicate electronics of engine control and other electronic equipment from sudden variations in voltage,and provide power to energy intensive auxiliary equipment.16Fig.3A typical urban driving cycle created at West Virginia Univer-sity.10,11The upper plot shows the speed of the vehicle and the lower plot shows the power required for a small passenger car.D o w n l o a d e d b y N a n k a i U n i v e r s i t y o n 28 A u g u s t 2010P u b l i s h e d o n 02 A u g u s t 2010 o n h t t p ://p u b s .r s c .o r g | d o i :10.1039/C 0E E 00004C3.3Backup,safety and low maintenance applicationsIn many consumer electronic devices,ptops,cameras,and mobile phones,smaller ECs provide backup energy storage when the primary energy source is being changed;this allows basic information such as date and time information to be stored.The widespread use of smaller ECs in this field has shown that they are a cost effective way to provide this service.A newer market is found in cordless hand tools that use ECs as the energy store.These tools are characterised by smaller amounts of energy stored in comparison to batteries,but with the benefit of longer lifetime,less temperature-dependent loss of performance,and a much shorter charging time (typically under 3minutes).Screwdrivers,pipe cutters and torches are commer-cially available but more energy intensive tools such as drills require the energy density provided by lithium ion batteries.Some fail-safe actuators use ECs to power the actuator to a predetermined ‘‘safe’’position in the event of a power ing energy stored in ECs rather than in springs allows the actuator motor to be reduced in capacity,as it no longer has to overcome the force of the spring.Rigorous performance testing of EDLCs concluded that these devices are reliable over hundreds of thousands of cycles.Their robust design and long cycle life result in the requirement for little maintenance,and they offer a significant weight reduction in comparison with batteries for some applications.For these reasons,EDLCs are used as an integrated power source in the emergency door and slide management system on the Airbus A380.†ECs are increasingly used in wind turbine blade pitching systems to provide emergency power backup and peak power to provide the energy to the blade pitching motors.17This not only increases the efficiency of the wind turbine,but is also critical in terms of safety as the blades can be pitched to reduce damage associated with high wind speeds.Lower maintenance compo-nents are a critical design consideration for offshore wind turbines due to the increased costs of repair/replacing components.Overall,ECs will continue to find growth markets as compo-nents in hybrid energy systems for energy capture and/or provision of peak power,power quality,and to a much lesser degree as a primary energy source in their own right.The pene-tration into these markets will be driven by improvements in the performance of ECs,which continues as research progresses.As with other products,the limits to market penetration will be governed by future performance/cost improvements of ECs in relation to other technologies,but the expected growth in elec-trical systems coupled with changes of electrical generation and supply should mean that ECs have growing markets in which to compete.4.MaterialsAlthough ECs are designed to outperform batteries in terms of power density,it may be necessary in some applications to sacrifice power density performance to increase energy density.Other applications,such as power quality management,place a greater emphasis on power density.For some applications self-discharge may be crucial whereas for others this may only be a relatively minor inconvenience.This suggests that one single EC design will not suffice and that the appropriate selection of materials is crucial.4.1Carbon electrode materialsFrom the considerable amount of literature available on carbon electrode materials,2,18–20four major requirements for EC elec-trode carbons can be identified as:high surface area,low elec-trical resistance,good polarisability and controllable pore size.The following subsections give a brief outline of the various carbon materials that meet these requirements.A substantial fraction of the research carried out on ECs has depended,and continues to do so,on an understanding of the properties of carbon.Carbon is an element almost uniquely suited to EDLC production due to the existence of several allo-tropic forms (fullerenes,graphite and nanotubes),various microtextures owing to the degree of graphitisation,a rich variety of dimensionality from 0to 3D and the ability to exist in different forms (powders,fibres,foams and composites).They are also easy to process,relatively low cost,chemically stable in different solutions (from strongly acidic to basic),possess very high surface areas and are stable over a wide range of tempera-tures.184.1.1Activated carbons.Activated carbons are generally produced from the pyrolysis of biomass precursors such as wood,coal,peat,coconut and other agricultural waste products.The specific surface area and porosity of carbons are then signifi-cantly increased by an activation process which removes disor-dered carbon from the structure in an oxidising atmosphere.A large variety of carbonaceous materials can be converted into activated carbon,although the properties of the final product and the ease with which it can be produced will be dependent on:the nature of the raw material used,the nature of the activating agent,and the conditions of the activation process.There are two methods for activation:physical and chemical.In the chemical activation process,carbonisation and activation are carried out by thermal decomposition of the precursor impregnated with a chemical activating agent,such as KOH,HNO 3or H 3PO 4.Physical activation involves gasification of the carbon produced from carbonisation with an oxidising gas at elevated tempera-tures.As capacitance is theoretically related to the surface area of the electrode (eqn (1)),activated carbons are commonly used for EDLC production with surface areas over 2000m 2g À1possible.Inter alia Shi,18Qu and Shi,19and Frackowiak and B e guin 20have carried out comprehensive studies on activated carbons to determine the correlation between porous structure and the performance in EDLCs.The specific capacitance was observed to vary over the range 94–413F g À1,however,it was found that the specific capacitance was not proportional to total surface area as predicted by eqn (1)(see Section 4.5).4.1.2Carbon nanotubes.Since the late 1990s there has been a large volume of research carried out on the applicability of†Maxwell Technologies Press Release,14April 2005,/news-events/release.asp?PRID ¼162.D o w n l o a d e d b y N a n k a i U n i v e r s i t y o n 28 A u g u s t 2010P u b l i s h e d o n 02 A u g u s t 2010 o n h t t p ://p u b s .r s c .o r g | d o i :10.1039/C 0E E 00004Ccarbon nanotubes (CNTs)as EDLC Ts have a narrow pore size distribution (PSD),highly accessible surface area,low resistivity,and high stability.21The basic structure of a CNT is a single seamless cylinder of crystalline graphite,with a well-defined central core,whose end can be capped by a fullerene-type structure.This type of CNT is known as a Single Walled Carbon Nanotube (SWCNT).The more common form of CNTs is as Multi-Wall Carbon Nano-tubes (MWCNTs),which consist of several graphene cylinders,arranged concentrically around a common Ts are composed of mesopores and exhibit surface areas $102m 2g À1(surface areas up to 475m 2g À1have been reported for activated MWCNTs).20Their accessible pore network combined with low resistivity and high stability has led to CNTs being extensively researched as materials for EC electrodes.Specific capacitances of between 15and 300F g À1have been reported using different configurations of CNTs.22Due to high production costs,it is not considered viable to use CNTs as the bulk active material in electrodes.Therefore,the most recent developments for the use of CNTs in the manufacture of EDLCs are as conductivity enhancers replacing carbon blacks.They have several advantages over carbon or acetylene blacks as they have an electrical conductivity exceeding 5Â105S m À1at room temperature for purified materials.21The high aspect ratio of CNTs compared to other carbon additives allows for lower weight doping levels to obtain comparable conductivity enhancement.One investigation by Chen et al.23noted that by changing acetylene black to CNTs in electrode manufacture resulted in a 90%reduction in ESR.To reduce inter-particle resistance in carbon aerogel electrodes,CNTs were grown directly onto microfibrous carbon paper,and then dipped into polyacrylonitrile and dimethylformamide aquagel.Subsequent carbonisation and activation produced binderless composite electrodes that exhibited a specific capac-itance of 524F g À1(four times that of the pristine carbon aer-ogel electrode).244.1.3Carbon nanofibres.Carbon nanofibres (CNFs)were first synthesised in the 1990s and differ from the better-known carbon fibres in that their diameters are much smaller and are more difficult to produce in a well-aligned manner.25CNFs in many ways represent an ideal material for application in EDLCs;they generally exhibit an open,mesoporous structure and good conductivity (only along the fibre axis).If they are produced from electrospun polymers,compared to CNTs,they are rela-tively cheap and easy to manufacture and are therefore an attractive alternative to CNTs.Binderless web structures can also be produced via Fs can also be produced by chemical vapour deposition,although this increases costs vis-a-vis CNTs.CNFs have diameters between 50and 500nm with an average pore size (d av )of 3–20nm,and activation can lead to the opening of smaller pores.Due to the morphology of activated CNFs most of the porosity is situated on the surface of the fibres leading to more easily accessible active sites.25–28Activated CNFs have been noted to possess BET surface areas of up to 1200m 2g À1with specific capacitances in the range of 60–175F g À1.26,27Newer multi-branched CNFs exhibited a specific capacitance of 300F g À1.28Presently,CNFs are not considered to be an ideal material for ECs due to their high cost and high ESR arising from poor inter-fibre conductivity.4.1.4Carbide-derived carbons.The unique nanoporous structure of carbide-derived carbon (CDC)together with the narrow pore size distribution and the possibility to fine-tune the pore size has lead to a large volume of research being carried out to study these materials as electrodes for electrochemical capacitors.Carbide derived carbons are manufactured by the chlorination of metallic carbides (e.g.TiC,B 4C,ZrC,Ti 3SiC 2,Ti 2AlC,and SiC)at elevated temperatures (800–1200 C;high enough to facilitate the reaction,but lower than that required for graphi-tisation).The resulting carbons exhibit a high specific surface area with a pore size that can be controlled by choice of starting material and chlorination temperature.29Unlike other materials research for ECs,the research into the use of CDCs has been concentrated on the development of microporous carbon materials for improving performance.All results below are for microporous carbon materials with average pore widths below 2nm.So far,the best CDC materials for ECs are derived from TiC.TiC-derived CDC at 800 C with BET surface area of over 1600m 2g À1and average micropore width of 0.7nm have shown specific capacitances of between 130and 190F g À1.30,31Recently a new method was developed,which improves the pore size distribution in CDCs,using the chlorination of carbide/oxide mixture,due to which the carbothermal reduction of TiO 2in chlorine atmosphere gives the possibility to oxidise in situ the desired part of carbon during its formation from the carbide.32This method produced microporous carbons with surface areas of up to 1600m 2g À1and specific capacitance of 120F g À1.This class of carbons are important from a research point of view but have limited commercial potential due to their high cost,as well as safety and environmental concerns associated with production.4.1.5Template-derived carbons.Template-derived carbons are produced by filling the porous structure of an inorganic matrix with a carbon precursor (e.g.sucrose,propylene,pitch,or polymer solutions)followed by carbonisation.The inorganic template is then completely removed by hydrofluoric acid.The use of a template allows for the production of porous carbons with well-defined pore characteristics such as surface area,pore volume and PSD.Activated carbons can exhibit very wide PSDs with pores randomly connected,leading to poor conductivity and ionic transport for use as electrodes.Template-derived carbons have an advantage over activated carbons as they produce high-surface area materials with regularly interconnected pores that allow for improved ionic transport and improved power density.The pore size of the template can be engineered to match pore width to electrolyte properties to improve performance.Xing et al.33have shown that template-derived carbons produced a 10%reduction in capacitance with increasing discharge rate compared with Maxsorb Òactivated carbon’s 80%reduction under the same conditions.Specific capacitances of 220F g À1D o w n l o a d e d b y N a n k a i U n i v e r s i t y o n 28 A u g u s t 2010P u b l i s h e d o n 02 A u g u s t 2010 o n h t t p ://p u b s .r s c .o r g | d o i :10.1039/C 0E E 00004C。

IMPROVED CORED ELECTRODE WIRES

专利名称:IMPROVED CORED ELECTRODE WIRES发明人:JAMES, Horace, Stuart, Bosisto,FRENCH, Ian, Edward申请号:EP89902620.7申请日:19890206公开号:EP0397789B1公开日:19940601专利内容由知识产权出版社提供摘要:the present invention provides an electrode rod input to the nucleus welding pulsed electric arc, in which the core contains 2.5 to 12% of calcium fluoride, 2 to 8% of calcium carbonate, 0.2 to 2% of silicon dioxide and 0.5 to 1.5% of an oxide mixed in fusio n.the present invention also describes a pointer input electrode for arc welding method in which a pulsed electric core contains 4 to 15% manganese and 2% to 8% of basic elementary silicon, the rest of the core being composed of mixed oxides was ion, the desired alloying elements and iron powder.in each of the cases described above.the wand may be used with the appropriate input parameters (pulse energy, pulse 8 to 250 days, and preferably 10 to 120 days; pulse frequency: 10 to 500 hz, and preferably 15 to 350 hz; a bottom current: 250, and preferably 10 100; a rate of advance of the rod 1 to 20 m \/ min, preferably 4 to 5 m \/ min.申请人:COMMW SCIENT IND RES ORG,WELDING IND LTD地址:AU,AU国籍:AU,AU代理机构:Lawrence, John Gordon更多信息请下载全文后查看。

研究发现铝粒子可提高薄膜太阳能电池转化效率

研究发现铝粒子可提高薄膜太阳能电池转化效率
佚名
【期刊名称】《纳米科技》
【年(卷),期】2011(000)001
【摘要】新加坡A*STAR研究院高性能计算机研究所的科研人员尤里·阿基莫夫和魏诚美(音译)发现,通过沉积铝粒子的方法可以提高薄膜太阳能电池的光电转化效率。

这种金属纳米粒子能防止光线的逃逸和反射,使更多的直射光直接进入太阳能电池。

【总页数】1页(P87-87)
【正文语种】中文
【中图分类】TM914.42
【相关文献】
1.铝粒子提高薄膜太阳能电池转化效率 [J],
2.铝粒子可提高薄膜太阳能电池转化效率 [J],
3.研究发现铝粒子可提高薄膜太阳能电池光电转化效率 [J],
4.铝粒子可提高薄膜太阳能电池转化效率能使太阳能电池变得更轻更薄更高效 [J],
5.金属纳米粒子可提高薄膜太阳能电池转化效率 [J],
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铝电解用惰性阳极钙钛矿陶瓷的物性探索

铝电解用惰性阳极钙钛矿陶瓷的物性探索
徐荣历;侯智;刘雪燕;尹娜
【期刊名称】《山东大学学报:理学版》
【年(卷),期】2004(39)4
【摘要】选择LaxFe1 xO3,LaxNi1 xO3,LaW0 .2 5 xFexNi0 .75O3和LaSrMn1 xWxO3等材料作为铝电解用惰性电极 ,对其电阻率及抗熔融冰晶石—氧化铝熔盐的腐蚀能力进行了研究 .结果表明 ,样品的电阻率能满足铝电解生产的要求 ,但耐腐蚀性尚需进一步提高 .
【总页数】3页(P77-79)
【关键词】惰性阳极;铝电解;熔融冰晶石-氧化铝;电阻率;抗腐蚀性
【作者】徐荣历;侯智;刘雪燕;尹娜
【作者单位】山东大学物理与微电子学院
【正文语种】中文
【中图分类】TB321;TB332
【相关文献】
1.烧结气氛对铝电解 Ni/(NiFe2O4-10NiO)金属陶瓷惰性阳极耐腐蚀性能的影响 [J], 田忠良;郭伟昌;赖延清;张凯;李劼
2.电流密度对铝电解NiFe2O4基金属陶瓷惰性阳极腐蚀的影响 [J], 田忠良;张腾;魏琛娟;赖延清;李劼
3.烧结气氛对铝电解Ni/(NiFe2O4-10NiO)金属陶瓷惰性阳极耐腐蚀性能的影
响 [J], 田忠良;郭伟昌;赖延清;张凯;李劼;
4.烧结气氛对铝电解Ni/(NiFe2O4-10NiO)金属陶瓷惰性阳极耐腐蚀性能的影响(英文)简 [J], 田忠良;郭伟昌;赖延清;张凯;李劼;
5.钙钛矿与层状钙钛矿结构微波介质陶瓷研究——评《陶瓷矿物原料与岩相分析》[J], 邓举青
因版权原因,仅展示原文概要,查看原文内容请购买。

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a r X i v :h e p -p h /0510099v 2 18 O c t 2005Improved Calculation of Electroweak Radiative Corrections andthe Value of V udWilliam J.Marciano1and Alberto Sirlin 21Brookhaven National Laboratory,Upton,NY 119732New York University,Department of Physics,4Washington Place,New York,NY 10003(Dated:September 2005)Abstract A new method for computing hadronic effects on electroweak radiative corrections to low-energy weak interaction semileptonic processes is described.It employs high order perturbative QCD re-sults originally derived for the Bjorken sum rule along with a large N QCD-motivated interpolating function that matches long and short-distance loop contributions.Applying this approach to the extraction of the CKM matrix element V ud from superallowed nuclear beta decays reduces the the-oretical loop uncertainty by about a factor of 2and gives V ud =0.97377(11)(15)(19).Implications for CKM unitarity are briefly discussed.Precision studies of low-energy semileptonic weak-charged and neutral current processes can be used to test the SU(3)c×SU(2)L×U(1)Y Standard Model at the quantum loop level and probe for potential“new physics”effects.Examples for which a fraction of a percent experimental sensitivity has already been achieved include:pion,neutron and nuclear beta decays[1],as well as atomic parity violation[2].In those cases,electroweak radiative corrections(RC)have been computed[3,4,5]and found to be significant(of order several percent).They must be included in any meaningful confrontation between theory and experiment.Of course,inherent to any low-energy semileptonic process are uncertainties due to strong interactions,since quarks are involved.To minimize such effects,one often focuses on weak vector current-induced reactions,where CVC(conserved vector current)protects those am-plitudes at tree level from strong interaction corrections in the limit of zero momentum transfer.However,even for those amplitudes,electroweak loop corrections can involve weak axial-vector effects not protected by CVC,which give rise to hadronic(strong interaction) uncertainties in their evaluation[3,4].In this paper,we focus on the best known and tested examples of that phenomenon,the electroweak radiative corrections to neutron and corre-spondingly superallowed nuclear beta decays along with their implications for the extraction of the CKM matrix element V ud.However,the method we describe is quite general and can be easily applied to other charged and neutral current semileptonic low-energy reactions.The extraction of V ud(in fact all CKM matrix elements)entails normalizing a semileptonic reaction rate with respect to the muon lifetime,or equivalently the Fermi constant derived from itGµ=1.16637(1)×10−5GeV−2(1) For high precision,electroweak radiative corrections to both processes must be included and hadronic as well as environmental effects(e.g.,nuclear structure)must be controlled. Toward that end,super-allowed(0+→0+)nuclear beta decay transitions are very special since they only involve the weak vector current at tree level.Small violations of CVC due to the up-down mass difference or non-zero momentum transfer are small∼O(10−5)and can generally be neglected(or incorporated).Such an analysis leads to the very accurate relationship[6,7]2984.48(5)sec|V ud|2=where ft is the product of a phase space statistical decay rate factor f(which depends on the Q value of a specific nuclear beta decay)and its measured half-life t.RC designates the total effect of all radiative corrections relative to muon decay as well as QED-induced nuclear structure isospin violating effects.It is nucleus dependent,ranging from about+3.1%to +3.6%for the nine best-measured super-allowed decays.So,measuring Q and t combined with computing RC determines V ud.A similar formula will be given later for neutron beta decay.In that case,the Q value=m n−m p is very precisely known,but in addition to the neutron lifetime,g A≡G A/G V must be accurately measured because both weak axial and vector currents contribute at tree level[1,6].Our main goal in this paper is to reduce the hadronic uncertainty in the radiative correc-tions to super-allowed nuclear beta decays and thereby improve the determination of V ud. The need for such an improvement is well illustrated by a survey of ft values and RC for super-allowed beta decays by Hardy and Towner[7],more recently updated by G.Savard et al.[8],which foundV ud=0.9736(2)(4)EW(3) where thefirst uncertainty stems primarily from nuclear structure corrections(including O(Z2α3)effects)and very small ft value errors while the second,dominant error is due to hadronic uncertainties in electroweak loop effects.Although,as we mention later,the first error may currently be an underestimate and the central value of V ud could shift due to future Q value updates,it is clear that the hadronic loop uncertainty,which comes from weak axial-current loop effects,currently limits the determination of V ud and must be improved if further progress is to be made.Here,we describe a new method for controlling hadronic uncertainties in the radiative corrections to neutron and super-allowed nuclear beta decays.It validates our previous results[4,6]increasing V ud by only a small+0.00007,but reduces the loop uncertainty by about a factor of2,(0.0004)EW→(0.0002)EW as we now demonstrate.The one-loop electroweak radiative corrections to the neutron(vector current contribu-tion)and super-allowed nuclear beta decays are given by[3,4,9]RC EW=αg(E m)+3lnm Zm A+A g+2C Born (4)Thefirst two terms result from loop corrections and bremsstrahlung involving electromag-netic and weak vector current interactions,withover phase space and 3ln m ZπE m8π∞ 0dQ 2m 2WQ 2 1−αs (Q 2)Q 4)(6)Integrating over the range m 2A ≤Q 2<∞and combining with smaller vertex correctionsand ZW box diagrams,that prescription gave a short-distance amplitude contributionαm A +A g ,A g ≃−0.34(7)In the numerical estimate,the low energy cutoffwas chosen to be m A =1.2GeV ,roughly the mass of the A 1resonance,and the error was estimated by allowing m A to vary up or down by a factor of 2.Such a heuristic,albeit crude procedure led to a ±0.0004uncertainty in V ud .For the long-distance γW box diagram contribution,nucleon electromagnetic and axial-vector dipole form factors were used to find for neutron decay [4,5]C Born (neutron)≃0.8g A (µn +µp )≃0.89(8)where g A ≃1.27and µn +µp =0.88is the nucleon isoscalar magnetic moment.In the case of superallowed nuclear decays,nuclear quenching modifies C Born (neutron)and nucleon-nucleon electromagnetic effects must be included [11].Overall,in the case of a neutron,axial-vector-induced one-loop RC to the decay rate amount to0.67(8)%.Roughly the same uncertainty±0.08%applies to superallowed nuclear decays.To reduce the hadronic uncertainty in RC,we have carried out a new analysis of the γW box diagram axial-vector-induced radiative corrections that incorporates the following F(Q2)improvements[12]:1)Short Distances(1.5GeV)2≤Q2<∞,a domain where QCD corrections remain perturbative.F(Q2)=1MS MS MSQ2+m2ρ+6.855Q2+m2ρ′(12)mρ=0.776GeV(13)m A=1.230GeV(14)mρ′=1.465GeV(15)3)Long Distances:0≤Q2≤(0.823GeV)2Integrating the long-distance amplitude up to Q2=(0.823GeV)2,where the integrand matches the interpolating function,and using an update of the nucleon electromagnetic and axial-current dipole form factors,wefindC Born(neutron)≃0.829(16)a reduction from our own previous result in eq.(8),where the integration was carried up to Q2=∞.Details of the above calculations will be given in a subsequent publication[12].Here,we briefly discuss the results of the above analysis and its implications.The QCD corrections to the asymptotic form of F(Q2)have been given in eq.(9)to O(α3s).The additional terms are identical(in the chiral limit)to QCD corrections to the Bjorken sum rule[13]for polarized electroproduction and can be read offfrom well-studied calculations[14,15]for that process.Their validity has been well tested experimentally[16].The interpolating function in eq.(12)is motivated by large N QCD which predicts it should correspond to an infinite sum of vector and axial-vector resonances[17].We impose three conditions that determine the residues:i)The integral of eqs.(5)and(12)should equal that of eqs.(5)and(9)in the asymptotic domain(1.5GeV)2≤Q2≤∞,which amounts to a matching requirement between domains1and2,ii)In the large Q2limit, the coefficient of the1/Q4term in the expansion of eq.(12)should vanish as required by chiral symmetry[18],iii)The interpolator should vanish at Q2=0as required by chiral perturbation theory.Three conditions limit us to three resonances.The Q2=(0.823GeV)2match between domains2and3was chosen to be the value at which eq.(12)equals the integrand of the long-distance contribution.Interestingly,that matching occurs near theρmass.A novel technical point in the formulation is that in the evaluation of the Feynman diagrams associated with the long-distance contributions the integral over the auxiliary variables is carried outfirst.This leads to integrands that depend on Q2and can therefore be matched with eq.(12).Using this approach,wefind that at the one-loop electroweak level the last three terms in eq.(4)are effectively replaced by2.82αloop uncertainty from hadronic effects.Employing our new analysis,wefind the improved relationship between V ud,the neutron lifetime and g A≡G V/G A4908.7(1.9)sec|V ud|2=Table1.Decomposition of the RC for the nine best-measured superallowed nuclear β-decays.Coulomb corrections in1−δC are taken directly from ref.[1,7]while1+δR has been somewhat modified due to our new results.The short-distance1+∆factor is based on the recent update in ref.[6]which includes higher order leading logs and some next-to-leading logs.10C 1.01298(5)(35)0.9983(3) 1.02389(38)14O 1.01274(8)(50)0.9976(3) 1.02385(38)26Al 1.01468(21)(20)0.9971(3) 1.02380(38)34Cl 1.01343(34)(15)0.9939(3) 1.02379(38)38K 1.01322(41)(15)0.9939(3) 1.02378(38)42Sc 1.01469(49)(20)0.9954(3) 1.02377(38)46V 1.01392(57)(7)0.9959(3) 1.02377(38)50Mn 1.01394(65)(7)0.9957(3) 1.02376(38)54Co 1.01398(73)(7)0.9947(3) 1.02376(38)Table2.Values of V ud implied by various precisely measured superallowed nuclear beta decays.The ft values are taken from Savard et al.[8].Uncertainties in V ud correspond to:1)nuclear structure and Z2α3uncertainties added in quadrature with the ft error[10,11],2)a common error assigned to nuclear coulomb distortion effects[11],and3)a common uncertainty from quantum loop effects.Only thefirst error is used to obtain the weighted average.10C3039.5(47) 1.03542(36)(30)(38)0.97381(77)(15)(19)1403043.3(19) 1.03441(52)(30)(38)0.97368(39)(15)(19)26Al3036.8(11) 1.03582(30)(30)(38)0.97406(23)(15)(19)34Cl3050.0(12) 1.03121(38)(30)(38)0.97412(26)(15)(19)38K3051.1(10) 1.03099(44)(30)(38)0.97404(26)(15)(19)42Sc3046.8(12) 1.03403(54)(30)(38)0.97330(32)(15)(19)46V3050.7(12) 1.03376(59)(30)(38)0.97280(34)(15)(19)50Mn3045.8(16) 1.03357(67)(30)(38)0.97367(41)(15)(19)54Co3048.4(11) 1.03257(75)(30)(38)0.97373(40)(15)(19)Weighted Average0.97377(11)(15)(19)We note that46V gives a somewhat low value for V ud.It differs from the average by2.7 sigma.That particular nucleus recently underwent a Q value revision[8]which lowered its V ud.It may be indicating problems with other Q values.If the other nuclear Q values follow the lead of46V,we could see a fairly significant reduction in the weighted average for V ud. Clearly,remeasurements of Q values and half-lives of the superallowed decays are highly warranted.Employing the value of V ud in eq.(19)and the K l3average[19]for V usV us=0.2257(9)(0.961/f+(0)),K l3average(20) with f+(0)=0.961(8)[20]leads to the unitarity test|V ud|2+|V us|2+|V ub|2=0.9992(5)Vud (4)Vus(8)f+(0)(21)Good agreement with unitarity is found,with the dominant uncertainty coming now from the theory error in the form factor f+(0).Eq.(21)provides an important test of the standard model at the quantum loop level and a constraint on new physics beyond the standard model at the±0.09%level.We note,however,that some other calculations[19,21]of f+(0)and studies of other strangeness changing decays[22]suggest a lower V us bined with further Q value revisions possibly leading to a smaller V ud,they could cause a significant reduction in eq.(21).A future violation of unitarity is still possible.However,for it to be significant,the theoretical uncertainty in f+(0)must be further reduced.ACKNOWLEDGMENTSThe work of W.J.M.was authored under Contract No.DE-AC02-98CH1086with the U.S.Department of Energy.The work of A.S.was supported by NSF Grant PHY-0245068. 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