Mixing of Primordial Gas in Lyman Break Galaxies
九年级英语地理常识单选题60题

九年级英语地理常识单选题60题1. Which country is known as the "Land of the Rising Sun"?A. ChinaB. JapanC. IndiaD. South Korea答案:B。
日本被称为“日出之国”,中国是“The People's Republic of China”,印度是“India”,韩国是“South Korea”,所以选B。
2. Where is the Amazon Rainforest located?A. North AmericaB. South AmericaC. AfricaD. Australia答案:B。
亚马逊雨林位于南美洲,北美洲没有如此大面积的雨林,非洲主要是热带草原和沙漠,澳大利亚以独特的生态环境为主,故选B。
3. Which country is famous for the Pyramids of Giza?A. EgyptB. IraqC. IranD. Israel答案:A。
吉萨金字塔位于埃及,伊拉克、伊朗和以色列没有著名的吉萨金字塔,所以选A。
4. In which continent is the Alps mountain range?A. AsiaB. EuropeC. AfricaD. North America答案:B。
阿尔卑斯山脉在欧洲,亚洲、非洲和北美洲没有阿尔卑斯山脉,故答案是B。
5. Which country is the largest in area in the world?A. ChinaB. RussiaC. United StatesD. Canada答案:B。
世界上面积最大的国家是俄罗斯,中国面积居世界第三,美国面积第四,加拿大面积第二,所以选B。
6. Which river is the longest in the world?A. The Yangtze RiverB. The Nile RiverC. The Amazon RiverD. The Yellow River答案:B。
pre-gastrulation developmental

pre-gastrulation developmentalWhat is Pre-gastrulation Developmental Phase?Pre-gastrulation developmental phase refers to the early stage in embryonic development before the formation of the gastrula. During this critical phase, various crucial events occur that lay the foundation for the subsequent formation of the three germ layers that give rise to the different tissues and organs in the developing embryo. In this article, we will explore the pre-gastrulation developmental phase in detail, discussing its key stages and the processes that take place during this time.1. Fertilization and Cleavage:The pre-gastrulation phase begins with fertilization, where a sperm fuses with an egg to form a zygote. Following fertilization, the zygote undergoes cleavage, a process of rapid cell divisions. These divisions result in the formation of blastomeres, smaller cells that make up the blastula.2. Blastula Formation:As cleavage continues, the blastomeres divide and rearrange, leading to the formation of a hollow ball-like structure called ablastula. The blastula consists of an outer layer of cells, known as the trophoblast, and an inner cell mass.3. Compaction and Morula Formation:During this stage, the blastomeres undergo a process called compaction, where they tightly adhere to each other, forming a compacted ball of cells called a morula. Compaction is crucial for the subsequent differentiation of embryonic cells.4. Blastocyst Formation:At this point, the morula undergoes further cell divisions and differentiation, resulting in the formation of a blastocyst. The blastocyst consists of two distinct cell populations: the inner cell mass (ICM) and the outer trophoblast layer. The ICM gives rise to the embryo, while the trophoblast layer contributes to the formation of extraembryonic structures such as the placenta.5. Implantation:The blastocyst moves towards the uterine lining and undergoes implantation, a process where it buries itself into the endometrium. This establishes a connection between the embryo and the maternal blood supply, allowing for nutrient and gas exchange.6. Formation of the Three Germ Layers:Following implantation, the pre-gastrulation phase progresses further as the blastocyst differentiates into the three germ layers: ectoderm, mesoderm, and endoderm. This process is known as gastrulation. The ectoderm gives rise to the nervous system, skin, and other ectodermal tissues. The mesoderm gives rise to the skeletal system, muscles, heart, and blood vessels. The endoderm gives rise to the gastrointestinal tract, respiratory system, and other endodermal tissues.7. Germ Layer Migration and Differentiation:During gastrulation, cells from each of the three germ layers undergo migration and differentiation to form specific tissues and organs. For example, ectodermal cells migrate to form the neural tube, which develops into the brain and spinal cord. Mesodermal cells differentiate to form muscles, bones, and internal organs. Endodermal cells give rise to the lining of the digestive and respiratory tracts.8. Organogenesis:As gastrulation progresses, the three germ layers continue todifferentiate and form the rudiments of various organs. This process, known as organogenesis, involves intricate cell interactions, proliferation, and remodeling to shape and develop organs such as the heart, lungs, liver, and kidneys.In conclusion, the pre-gastrulation developmental phase is a crucial period in embryonic development. It involves key events such as fertilization, cleavage, blastula, and blastocyst formation, implantation, gastrulation, and organogenesis. These processes play a fundamental role in establishing the basic body plan of the developing embryo, paving the way for its subsequent growth and differentiation into a complex multicellular organism.。
岩心荧光 含油级别

岩心荧光含油级别英文回答:Fluorescence in drill cuttings can provide valuable insights into the presence and properties of hydrocarbonsin subsurface formations. Fluorescence is the emission of light by a substance that has absorbed electromagnetic radiation. In the context of drill cuttings, fluorescence is typically caused by the presence of aromatic compounds, which are found in crude oil and natural gas.The level of fluorescence in drill cuttings can be used to assess the oil saturation of the formation from which the cuttings were obtained. Higher levels of fluorescence indicate higher oil saturation. However, it is important to note that other factors, such as the presence of other fluorescent compounds, can also affect the level of fluorescence.In general, the following qualitative scale can be usedto assess the oil saturation of drill cuttings based on their fluorescence:Non-fluorescent: No oil saturation.Weakly fluorescent: Low oil saturation.Moderately fluorescent: Moderate oil saturation.Strongly fluorescent: High oil saturation.It is important to note that this scale is only a general guideline and that the actual oil saturation of a formation may vary depending on a number of factors, such as the type of oil and the formation properties.In addition to assessing oil saturation, fluorescencein drill cuttings can also be used to identify the type of oil present. Different types of oil have different fluorescence characteristics, which can be used to differentiate between them. For example, crude oiltypically has a yellow-green fluorescence, while condensatehas a blue-white fluorescence.Fluorescence in drill cuttings is a valuable tool for formation evaluation. It can be used to assess the oil saturation of a formation, identify the type of oil present, and provide insights into the formation's properties.中文回答:岩心荧光是指岩心在受到光波激发后产生的光。
The

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1
The role of unsteadiness in direct initiation of gaseous detonations
By C H R I S A. E C K E T T, J A M E S J. Q U I R K† A N D J O S E P H E. S H E P H E R D‡
2
C. A. Eckett, J. J. Quirk and J. E. Shepherd
detonation transition (DDT). The main variable believed to control the success or failure of direct initiation is the magnitude of the initial energy release, provided the energy deposition is sufficiently fast and the igniter sufficiently small. Experiments suggest that for a given combustible gas mixture at given uniform premixed initial conditions, the energy release must be above a certain level, known as the critical energy, to successfully initiate a detonation. The same arguments apply for direct initia
chapter3(简)

Fig. 3.1 dry gas
1. gas in-place
From the real-gas law:
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zi nRT pi
n Vgi Pi zi RT
气体储量:
Vsc
G
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G piVgi zscTsc ziTpsc
Vgi 43.56 Ah (1 S wi ) (Mft3)
A-acre
1acre(英亩)=43.5Swi )
p i z sc Tsc p sc z i T
(Mft3)
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Vgi 43.56 Ah (1 S wi ) (Mft3)
RB
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G Vgi 7758Ah(1 Swi )
Mo
R3
The molecular weight of the stock-tank liquid:
Mo
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or
Mo
42.43 o 1.008 o
•Gas production from low-pressure separators and stock
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total initial gas in place :
GT
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鱼类生殖细胞移植的研究进展及应用前景

在鱼类胚胎发育早期,体细胞系和生殖细 胞系就发生了分离,形成了生殖细胞的祖细 胞,即PGCs。随后,PGCs迁移到达生殖原基, 增殖、分化为精原细胞或卵原细胞,接着开始 配子发生。在精巢中,精原细胞发育为精子需 要经过3个阶段:有丝分裂(精原细胞增殖)、减 数分裂(初级和次级精母细胞形成)、精子生成[36-37]。 在有丝分裂阶段,具有干细胞特性的未分化A型 精原细胞(Aund)通过有丝分裂产生分化的A型精 原细胞(Adiff),同时伴随着自我更新能力的大幅 降低,然后Adiff继续分裂产生B型精原细胞;通 常把Aund称为精原干细胞[36, 。 38-39] 卵巢中,卵原 细胞经过有丝分裂增殖后,快速进入到减数分 裂阶段,成为初级卵母细胞,经过初级、次级 生长及卵黄生成后,发育成为卵子。在卵原细 胞增殖过程中,部分卵原细胞保持干细胞特
水产学报, 2020, 44(2): 321−337
JOURNAL OF FISHERIES OF CHINA DOI: 10.11964/jfc.20190511781
·综述·
鱼类生殖细胞移植的研究进展及应用前景
叶 欢1, 危起伟1, 徐冬冬2, 岳华梅1, 竹内裕3, 阮 瑞1, 杜 浩1, 李创举1*
鱼类生殖细胞移植技术首先在斑马鱼daniorerio中建立10经过十多年的发展该技术取得了一系列突破性的进展包括先后建立了以胚胎仔鱼和成鱼为受体的生殖细胞移植模式41011供体生殖细胞的选择从pgcs拓展到精原和卵原干细胞46受体的选择与制备等1215
文章编号: 1000-0615(2020)02-0321-17
2 鱼类生殖细胞移植
鱼类生殖细胞移植主要包括供体细胞、受 体的选择与制备,以及二者的亲缘关系等关键 科学与技术问题。
Principles of Plasma Discharges and Materials Processing9

CHAPTER8MOLECULAR COLLISIONS8.1INTRODUCTIONBasic concepts of gas-phase collisions were introduced in Chapter3,where we described only those processes needed to model the simplest noble gas discharges: electron–atom ionization,excitation,and elastic scattering;and ion–atom elastic scattering and resonant charge transfer.In this chapter we introduce other collisional processes that are central to the description of chemically reactive discharges.These include the dissociation of molecules,the generation and destruction of negative ions,and gas-phase chemical reactions.Whereas the cross sections have been measured reasonably well for the noble gases,with measurements in reasonable agreement with theory,this is not the case for collisions in molecular gases.Hundreds of potentially significant collisional reactions must be examined in simple diatomic gas discharges such as oxygen.For feedstocks such as CF4/O2,SiH4/O2,etc.,the complexity can be overwhelming.Furthermore,even when the significant processes have been identified,most of the cross sections have been neither measured nor calculated. Hence,one must often rely on estimates based on semiempirical or semiclassical methods,or on measurements made on molecules analogous to those of interest. As might be expected,data are most readily available for simple diatomic and polyatomic gases.Principles of Plasma Discharges and Materials Processing,by M.A.Lieberman and A.J.Lichtenberg. ISBN0-471-72001-1Copyright#2005John Wiley&Sons,Inc.235236MOLECULAR COLLISIONS8.2MOLECULAR STRUCTUREThe energy levels for the electronic states of a single atom were described in Chapter3.The energy levels of molecules are more complicated for two reasons. First,molecules have additional vibrational and rotational degrees of freedom due to the motions of their nuclei,with corresponding quantized energies E v and E J. Second,the energy E e of each electronic state depends on the instantaneous con-figuration of the nuclei.For a diatomic molecule,E e depends on a single coordinate R,the spacing between the two nuclei.Since the nuclear motions are slow compared to the electronic motions,the electronic state can be determined for anyfixed spacing.We can therefore represent each quantized electronic level for a frozen set of nuclear positions as a graph of E e versus R,as shown in Figure8.1.For a mole-cule to be stable,the ground(minimum energy)electronic state must have a minimum at some value R1corresponding to the mean intermolecular separation (curve1).In this case,energy must be supplied in order to separate the atoms (R!1).An excited electronic state can either have a minimum( R2for curve2) or not(curve3).Note that R2and R1do not generally coincide.As for atoms, excited states may be short lived(unstable to electric dipole radiation)or may be metastable.Various electronic levels may tend to the same energy in the unbound (R!1)limit. Array FIGURE8.1.Potential energy curves for the electronic states of a diatomic molecule.For diatomic molecules,the electronic states are specifiedfirst by the component (in units of hÀ)L of the total orbital angular momentum along the internuclear axis, with the symbols S,P,D,and F corresponding to L¼0,+1,+2,and+3,in analogy with atomic nomenclature.All but the S states are doubly degenerate in L.For S states,þandÀsuperscripts are often used to denote whether the wave function is symmetric or antisymmetric with respect to reflection at any plane through the internuclear axis.The total electron spin angular momentum S (in units of hÀ)is also specified,with the multiplicity2Sþ1written as a prefixed superscript,as for atomic states.Finally,for homonuclear molecules(H2,N2,O2, etc.)the subscripts g or u are written to denote whether the wave function is sym-metric or antisymmetric with respect to interchange of the nuclei.In this notation, the ground states of H2and N2are both singlets,1Sþg,and that of O2is a triplet,3SÀg .For polyatomic molecules,the electronic energy levels depend on more thanone nuclear coordinate,so Figure8.1must be generalized.Furthermore,since there is generally no axis of symmetry,the states cannot be characterized by the quantum number L,and other naming conventions are used.Such states are often specified empirically through characterization of measured optical emission spectra.Typical spacings of low-lying electronic energy levels range from a few to tens of volts,as for atoms.Vibrational and Rotational MotionsUnfreezing the nuclear vibrational and rotational motions leads to additional quan-tized structure on smaller energy scales,as illustrated in Figure8.2.The simplest (harmonic oscillator)model for the vibration of diatomic molecules leads to equally spaced quantized,nondegenerate energy levelse E v¼hÀv vib vþ1 2(8:2:1)where v¼0,1,2,...is the vibrational quantum number and v vib is the linearized vibration frequency.Fitting a quadratic functione E v¼12k vib(RÀ R)2(8:2:2)near the minimum of a stable energy level curve such as those shown in Figure8.1, we can estimatev vib%k vibm Rmol1=2(8:2:3)where k vib is the“spring constant”and m Rmol is the reduced mass of the AB molecule.The spacing hÀv vib between vibrational energy levels for a low-lying8.2MOLECULAR STRUCTURE237stable electronic state is typically a few tenths of a volt.Hence for molecules in equi-librium at room temperature (0.026V),only the v ¼0level is significantly popula-ted.However,collisional processes can excite strongly nonequilibrium vibrational energy levels.We indicate by the short horizontal line segments in Figure 8.1a few of the vibrational energy levels for the stable electronic states.The length of each segment gives the range of classically allowed vibrational motions.Note that even the ground state (v ¼0)has a finite width D R 1as shown,because from(8.2.1),the v ¼0state has a nonzero vibrational energy 1h Àv vib .The actual separ-ation D R about Rfor the ground state has a Gaussian distribution,and tends toward a distribution peaked at the classical turning points for the vibrational motion as v !1.The vibrational motion becomes anharmonic and the level spa-cings tend to zero as the unbound vibrational energy is approached (E v !D E 1).FIGURE 8.2.Vibrational and rotational levels of two electronic states A and B of a molecule;the three double arrows indicate examples of transitions in the pure rotation spectrum,the rotation–vibration spectrum,and the electronic spectrum (after Herzberg,1971).238MOLECULAR COLLISIONSFor E v.D E1,the vibrational states form a continuum,corresponding to unbound classical motion of the nuclei(breakup of the molecule).For a polyatomic molecule there are many degrees of freedom for vibrational motion,leading to a very compli-cated structure for the vibrational levels.The simplest(dumbbell)model for the rotation of diatomic molecules leads to the nonuniform quantized energy levelse E J¼hÀ22I molJ(Jþ1)(8:2:4)where I mol¼m Rmol R2is the moment of inertia and J¼0,1,2,...is the rotational quantum number.The levels are degenerate,with2Jþ1states for the J th level. The spacing between rotational levels increases with J(see Figure8.2).The spacing between the lowest(J¼0to J¼1)levels typically corresponds to an energy of0.001–0.01V;hence,many low-lying levels are populated in thermal equilibrium at room temperature.Optical EmissionAn excited molecular state can decay to a lower energy state by emission of a photon or by breakup of the molecule.As shown in Figure8.2,the radiation can be emitted by a transition between electronic levels,between vibrational levels of the same electronic state,or between rotational levels of the same electronic and vibrational state;the radiation typically lies within the optical,infrared,or microwave frequency range,respectively.Electric dipole radiation is the strongest mechanism for photon emission,having typical transition times of t rad 10À9s,as obtained in (3.4.13).The selection rules for electric dipole radiation areDL¼0,+1(8:2:5a)D S¼0(8:2:5b) In addition,for transitions between S states the only allowed transitions areSþÀ!Sþand SÀÀ!SÀ(8:2:6) and for homonuclear molecules,the only allowed transitions aregÀ!u and uÀ!g(8:2:7) Hence homonuclear diatomic molecules do not have a pure vibrational or rotational spectrum.Radiative transitions between electronic levels having many different vibrational and rotational initial andfinal states give rise to a structure of emission and absorption bands within which a set of closely spaced frequencies appear.These give rise to characteristic molecular emission and absorption bands when observed8.2MOLECULAR STRUCTURE239using low-resolution optical spectrometers.As for atoms,metastable molecular states having no electric dipole transitions to lower levels also exist.These have life-times much exceeding10À6s;they can give rise to weak optical band structures due to magnetic dipole or electric quadrupole radiation.Electric dipole radiation between vibrational levels of the same electronic state is permitted for molecules having permanent dipole moments.In the harmonic oscillator approximation,the selection rule is D v¼+1;weaker transitions D v¼+2,+3,...are permitted for anharmonic vibrational motion.The preceding description of molecular structure applies to molecules having arbi-trary electronic charge.This includes neutral molecules AB,positive molecular ions ABþ,AB2þ,etc.and negative molecular ions ABÀ.The potential energy curves for the various electronic states,regardless of molecular charge,are commonly plotted on the same diagram.Figures8.3and8.4give these for some important electronic statesof HÀ2,H2,and Hþ2,and of OÀ2,O2,and Oþ2,respectively.Examples of both attractive(having a potential energy minimum)and repulsive(having no minimum)states can be seen.The vibrational levels are labeled with the quantum number v for the attrac-tive levels.The ground states of both Hþ2and Oþ2are attractive;hence these molecular ions are stable against autodissociation(ABþ!AþBþor AþþB).Similarly,the ground states of H2and O2are attractive and lie below those of Hþ2and Oþ2;hence they are stable against autodissociation and autoionization(AB!ABþþe).For some molecules,for example,diatomic argon,the ABþion is stable but the AB neutral is not stable.For all molecules,the AB ground state lies below the ABþground state and is stable against autoionization.Excited states can be attractive or repulsive.A few of the attractive states may be metastable;some examples are the 3P u state of H2and the1D g,1Sþgand3D u states of O2.Negative IonsRecall from Section7.2that many neutral atoms have a positive electron affinity E aff;that is,the reactionAþeÀ!AÀis exothermic with energy E aff(in volts).If E aff is negative,then AÀis unstable to autodetachment,AÀ!Aþe.A similar phenomenon is found for negative molecular ions.A stable ABÀion exists if its ground(lowest energy)state has a potential minimum that lies below the ground state of AB.This is generally true only for strongly electronegative gases having large electron affinities,such as O2 (E aff%1:463V for O atoms)and the halogens(E aff.3V for the atoms).For example,Figure8.4shows that the2P g ground state of OÀ2is stable,with E aff% 0:43V for O2.For weakly electronegative or for electropositive gases,the minimum of the ground state of ABÀgenerally lies above the ground state of AB,and ABÀis unstable to autodetachment.An example is hydrogen,which is weakly electronegative(E aff%0:754V for H atoms).Figure8.3shows that the2Sþu ground state of HÀ2is unstable,although the HÀion itself is stable.In an elec-tropositive gas such as N2(E aff.0),both NÀ2and NÀare unstable. 240MOLECULAR COLLISIONS8.3ELECTRON COLLISIONS WITH MOLECULESThe interaction time for the collision of a typical (1–10V)electron with a molecule is short,t c 2a 0=v e 10À16–10À15s,compared to the typical time for a molecule to vibrate,t vib 10À14–10À13s.Hence for electron collisional excitation of a mole-cule to an excited electronic state,the new vibrational (and rotational)state canbeFIGURE 8.3.Potential energy curves for H À2,H 2,and H þ2.(From Jeffery I.Steinfeld,Molecules and Radiation:An Introduction to Modern Molecular Spectroscopy ,2d ed.#MIT Press,1985.)8.3ELECTRON COLLISIONS WITH MOLECULES 241FIGURE 8.4.Potential energy curves for O À2,O 2,and O þ2.(From Jeffery I.Steinfeld,Molecules and Radiation:An Introduction to Modern Molecular Spectroscopy ,2d ed.#MIT Press,1985.)242MOLECULAR COLLISIONS8.3ELECTRON COLLISIONS WITH MOLECULES243 determined by freezing the nuclear motions during the collision.This is known as the Franck–Condon principle and is illustrated in Figure8.1by the vertical line a,showing the collisional excitation atfixed R to a high quantum number bound vibrational state and by the vertical line b,showing excitation atfixed R to a vibra-tionally unbound state,in which breakup of the molecule is energetically permitted. Since the typical transition time for electric dipole radiation(t rad 10À9–10À8s)is long compared to the dissociation( vibrational)time t diss,excitation to an excited state will generally lead to dissociation when it is energetically permitted.Finally, we note that the time between collisions t c)t rad in typical low-pressure processing discharges.Summarizing the ordering of timescales for electron–molecule collisions,we havet at t c(t vib t diss(t rad(t cDissociationElectron impact dissociation,eþABÀ!AþBþeof feedstock gases plays a central role in the chemistry of low-pressure reactive discharges.The variety of possible dissociation processes is illustrated in Figure8.5.In collisions a or a0,the v¼0ground state of AB is excited to a repulsive state of AB.The required threshold energy E thr is E a for collision a and E a0for Array FIGURE8.5.Illustrating the variety of dissociation processes for electron collisions with molecules.collision a0,and it leads to an energy after dissociation lying between E aÀE diss and E a0ÀE diss that is shared among the dissociation products(here,A and B). Typically,E aÀE diss few volts;consequently,hot neutral fragments are typically generated by dissociation processes.If these hot fragments hit the substrate surface, they can profoundly affect the process chemistry.In collision b,the ground state AB is excited to an attractive state of AB at an energy E b that exceeds the binding energy E diss of the AB molecule,resulting in dissociation of AB with frag-ment energy E bÀE diss.In collision b0,the excitation energy E b0¼E diss,and the fragments have low energies;hence this process creates fragments having energies ranging from essentially thermal energies up to E bÀE diss few volts.In collision c,the AB atom is excited to the bound excited state ABÃ(labeled5),which sub-sequently radiates to the unbound AB state(labeled3),which then dissociates.The threshold energy required is large,and the fragments are hot.Collision c can also lead to dissociation of an excited state by a radiationless transfer from state5to state4near the point where the two states cross:ABÃðboundÞÀ!ABÃðunboundÞÀ!AþBÃThe fragments can be both hot and in excited states.We discuss such radiationless electronic transitions in the next section.This phenomenon is known as predisso-ciation.Finally,a collision(not labeled in thefigure)to state4can lead to dis-sociation of ABÃ,again resulting in hot excited fragments.The process of electron impact excitation of a molecule is similar to that of an atom,and,consequently,the cross sections have a similar form.A simple classical estimate of the dissociation cross section for a level having excitation energy U1can be found by requiring that an incident electron having energy W transfer an energy W L lying between U1and U2to a valence electron.Here,U2is the energy of the next higher level.Then integrating the differential cross section d s[given in(3.4.20)and repeated here],d s¼pe24021Wd W LW2L(3:4:20)over W L,we obtains diss¼0W,U1pe24pe021W1U1À1WU1,W,U2pe24021W1U1À1U2W.U28>>>>>><>>>>>>:(8:3:1)244MOLECULAR COLLISIONSLetting U2ÀU1(U1and introducing voltage units W¼e E,U1¼e E1and U2¼e E2,we haves diss¼0E,E1s0EÀE11E1,E,E2s0E2ÀE1EE.E28>>>><>>>>:(8:3:2)wheres0¼pe4pe0E12(8:3:3)We see that the dissociation cross section rises linearly from the threshold energy E thr%E1to a maximum value s0(E2ÀE1)=E thr at E2and then falls off as1=E. Actually,E1and E2can depend on the nuclear separation R.In this case,(8.3.2) should be averaged over the range of R s corresponding to the ground-state vibrational energy,leading to a broadened dependence of the average cross section on energy E.The maximum cross section is typically of order10À15cm2. Typical rate constants for a single dissociation process with E thr&T e have an Arrhenius formK diss/K diss0expÀE thr T e(8:3:4)where K diss0 10À7cm3=s.However,in some cases E thr.T e.For excitation to an attractive state,an appropriate average over the fraction of the ground-state vibration that leads to dissociation must be taken.Dissociative IonizationIn addition to normal ionization,eþABÀ!ABþþ2eelectron–molecule collisions can lead to dissociative ionizationeþABÀ!AþBþþ2eThese processes,common for polyatomic molecules,are illustrated in Figure8.6.In collision a having threshold energy E iz,the molecular ion ABþis formed.Collisionsb andc occur at higher threshold energies E diz and result in dissociative ionization,8.3ELECTRON COLLISIONS WITH MOLECULES245leading to the formation of fast,positively charged ions and neutrals.These cross sections have a similar form to the Thompson ionization cross section for atoms.Dissociative RecombinationThe electron collision,e þAB þÀ!A þB Ãillustrated as d and d 0in Figure 8.6,destroys an electron–ion pair and leads to the production of fast excited neutral fragments.Since the electron is captured,it is not available to carry away a part of the reaction energy.Consequently,the collision cross section has a resonant character,falling to very low values for E ,E d and E .E d 0.However,a large number of excited states A Ãand B Ãhaving increasing principal quantum numbers n and energies can be among the reaction products.Consequently,the rate constants can be large,of order 10À7–10À6cm 3=s.Dissocia-tive recombination to the ground states of A and B cannot occur because the potential energy curve for AB þis always greater than the potential energycurveFIGURE 8.6.Illustration of dissociative ionization and dissociative recombination for electron collisions with molecules.246MOLECULAR COLLISIONSfor the repulsive state of AB.Two-body recombination for atomic ions or for mol-ecular ions that do not subsequently dissociate can only occur with emission of a photon:eþAþÀ!Aþh n:As shown in Section9.2,the rate constants are typically three tofive orders of magnitude lower than for dissociative recombination.Example of HydrogenThe example of H2illustrates some of the inelastic electron collision phenomena we have discussed.In order of increasing electron impact energy,at a threshold energy of 8:8V,there is excitation to the repulsive3Sþu state followed by dissociation into two fast H fragments carrying 2:2V/atom.At11.5V,the1Sþu bound state is excited,with subsequent electric dipole radiation in the ultraviolet region to the1Sþg ground state.At11.8V,there is excitation to the3Sþg bound state,followedby electric dipole radiation to the3Sþu repulsive state,followed by dissociation with 2:2V/atom.At12.6V,the1P u bound state is excited,with UV emission tothe ground state.At15.4V,the2Sþg ground state of Hþ2is excited,leading to the pro-duction of Hþ2ions.At28V,excitation of the repulsive2Sþu state of Hþ2leads to thedissociative ionization of H2,with 5V each for the H and Hþfragments.Dissociative Electron AttachmentThe processes,eþABÀ!AþBÀproduce negative ion fragments as well as neutrals.They are important in discharges containing atoms having positive electron affinities,not only because of the pro-duction of negative ions,but because the threshold energy for production of negative ion fragments is usually lower than for pure dissociation processes.A variety of pro-cesses are possible,as shown in Figure8.7.Since the impacting electron is captured and is not available to carry excess collision energy away,dissociative attachment is a resonant process that is important only within a narrow energy range.The maximum cross sections are generally much smaller than the hard-sphere cross section of the molecule.Attachment generally proceeds by collisional excitation from the ground AB state to a repulsive ABÀstate,which subsequently either auto-detaches or dissociates.The attachment cross section is determined by the balance between these processes.For most molecules,the dissociation energy E diss of AB is greater than the electron affinity E affB of B,leading to the potential energy curves shown in Figure8.7a.In this case,the cross section is large only for impact energies lying between a minimum value E thr,for collision a,and a maximum value E0thr for8.3ELECTRON COLLISIONS WITH MOLECULES247FIGURE 8.7.Illustration of a variety of electron attachment processes for electron collisions with molecules:(a )capture into a repulsive state;(b )capture into an attractive state;(c )capture of slow electrons into a repulsive state;(d )polar dissociation.248MOLECULAR COLLISIONScollision a 0.The fragments are hot,having energies lying between minimum and maximum values E min ¼E thr þE affB ÀE diss and E max ¼E 0thr þE af fB ÀE diss .Since the AB Àstate lies above the AB state for R ,R x ,autodetachment can occur as the mol-ecules begin to separate:AB À!AB þe.Hence the cross section for production of negative ions can be much smaller than that for excitation of the AB Àrepulsive state.As a crude estimate,for the same energy,the autodetachment rate is ffiffiffiffiffiffiffiffiffiffiffiffiffiM R =m p 100times the dissociation rate of the repulsive AB Àmolecule,where M R is the reduced mass.Hence only one out of 100excitations lead to dissociative attachment.Excitation to the AB Àbound state can also lead to dissociative attachment,as shown in Figure 8.7b .Here the cross section is significant only for E thr ,E ,E 0thr ,but the fragments can have low energies,with a minimum energy of zero and a maximum energy of E 0thr þE affB ÀE diss .Collision b,e þAB À!AB ÀÃdoes not lead to production of AB Àions because energy and momentum are not gen-erally conserved when two bodies collide elastically to form one body (see Problem3.12).Hence the excited AB ÀÃion separates,AB ÀÃÀ!e þABunless vibrational radiation or collision with a third body carries off the excess energy.These processes are both slow in low-pressure discharges (see Section 9.2).At high pressures (say,atmospheric),three-body attachment to form AB Àcan be very important.For a few molecules,such as some halogens,the electron affinity of the atom exceeds the dissociation energy of the neutral molecule,leading to the potential energy curves shown in Figure 8.7c .In this case the range of electron impact ener-gies E for excitation of the AB Àrepulsive state includes E ¼0.Consequently,there is no threshold energy,and very slow electrons can produce dissociative attachment,resulting in hot neutral and negative ion fragments.The range of R s over which auto-detachment can occur is small;hence the maximum cross sections for dissociative attachment can be as high as 10À16cm 2.A simple classical estimate of electron capture can be made using the differential scattering cross section for energy loss (3.4.20),in a manner similar to that done for dissociation.For electron capture to an energy level E 1that is unstable to autode-tachment,and with the additional constraint for capture that the incident electron energy lie within E 1and E 2¼E 1þD E ,where D E is a small energy difference characteristic of the dissociative attachment timescale,we obtain,in place of (8.3.2),s att¼0E ,E 1s 0E ÀE 1E 1E 1,E ,E 20E .E 28>><>>:(8:3:5)8.3ELECTRON COLLISIONS WITH MOLECULES 249wheres 0%p m M R 1=2e 4pe 0E 1 2(8:3:6)The factor of (m =M R )1=2roughly gives the fraction of excited states that do not auto-detach.We see that the dissociative attachment cross section rises linearly at E 1to a maximum value s 0D E =E 1and then falls abruptly to zero.As for dissociation,E 1can depend strongly on the nuclear separation R ,and (8.3.5)must be averaged over the range of E 1s corresponding to the ground state vibrational motion;e.g.,from E thr to E 0thr in Figure 8.7a .Because generally D E (E 0thr ÀE thr ,we can write (8.3.5)in the forms att %p m M R 1=2e 4pe 0 2(D E )22E 1d (E ÀE 1)(8:3:7)where d is the Dirac delta ing (8.3.7),the average over the vibrational motion can be performed,leading to a cross section that is strongly peaked lying between E thr and E 0thr .We leave the details of the calculation to a problem.Polar DissociationThe process,e þAB À!A þþB Àþeproduces negative ions without electron capture.As shown in Figure 8.7d ,the process proceeds by excitation of a polar state A þand B Àof AB Ãthat has a separ-ated atom limit of A þand B À.Hence at large R ,this state lies above the A þB ground state by the difference between the ionization potential of A and the electron affinity of B.The polar state is weakly bound at large R by the Coulomb attraction force,but is repulsive at small R .The maximum cross section and the dependence of the cross section on electron impact energy are similar to that of pure dissociation.The threshold energy E thr for polar dissociation is generally large.The measured cross section for negative ion production by electron impact in O 2is shown in Figure 8.8.The sharp peak at 6.5V is due to dissociative attachment.The variation of the cross section with energy is typical of a resonant capture process.The maximum cross section of 10À18cm 2is quite low because autode-tachment from the repulsive O À2state is strong,inhibiting dissociative attachment.The second gradual maximum near 35V is due to polar dissociation;the variation of the cross section with energy is typical of a nonresonant process.250MOLECULAR COLLISIONS。
分层接种对猪粪厌氧干发酵产气性能及微生物群落结构的影响

第37卷第1期农业工程学报V ol.37 No.1 2021年1月Transactions of the Chinese Society of Agricultural Engineering Jan. 2021 251分层接种对猪粪厌氧干发酵产气性能及微生物群落结构的影响李丹妮1,高文萱1,张克强1,孔德望2,王思淇1,杜连柱1※(1. 农业农村部环境保护科研监测所,天津300191;2.杭州能源环境工程有限公司,杭州310020)摘要:为避免厌氧干发酵酸抑制,提高产气效率,以猪粪和玉米秸秆为发酵原料,采用中温批式试验,在总固体(Total Solid, TS)为20%、接种比为25%的条件下研究分层接种和混合接种对猪粪干发酵厌氧消化性能的影响。
结果表明:2种接种方式下的发酵体系内挥发性脂肪酸(V olatile Fatty Acids,VFAs)均发生明显积累,其中,分层接种在第15天的TVFAs 质量浓度达到33.0 mg/g,之后明显降低,至发酵结束时VFAs消耗殆尽。
混合接种从第15天至发酵结束,TVFAs质量浓度维持在29.2~38.5 mg/g高水平范围内。
分层接种的累积挥发性固体甲烷产率为211.5 mL/g。
高通量测序结果显示,氢营养型产甲烷途径在2种接种方式下均占主导,但分层接种增加了发酵体系中微生物的丰富度和多样性,且群落结构更加稳定。
进一步分析表明,乙酸和pH值是影响厌氧干发酵中微生态结构的主要环境因子。
该研究结果为解除畜禽养殖废弃物酸抑制、提高产气效率提供理论依据与有益借鉴。
关键词:发酵;粪;微生物群落;分层接种;混合接种doi:10.11975/j.issn.1002-6819.2021.01.030中图分类号:X705 文献标志码:A 文章编号:1002-6819(2021)-01-0251-08李丹妮,高文萱,张克强,等. 分层接种对猪粪厌氧干发酵产气性能及微生物群落结构的影响[J]. 农业工程学报,2021,37(1):251-258. doi:10.11975/j.issn.1002-6819.2021.01.030 Li Danni, Gao Wenxuan, Zhang Keqiang, et al. Influences of layer inoculation on biogas production and microbial community in solid-state anaerobic fermentation of pig manure[J]. Transactions of the Chinese Society of Agricultural Engineering (Transactions of the CSAE), 2021, 37(1): 251-258. (in Chinese with English abstract) doi:10.11975/j.issn.1002-6819.2021.01.030 0 引 言近年来,中国的沼气产业发展迅速,已经成为最大的生物质能源产业之一[1],随着畜禽养殖向集约化、规模化发展方式转变,沼气发酵成为消纳养殖废弃物应用最广泛的有效措施之一[2]。
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a r X i v :a s t r o -p h /0611376v 1 13 N o v 2006ApJ Letters,in pressPreprint typeset using L A T E X style emulateapj v.10/09/06MIXING OF PRIMORDIAL GAS IN LYMAN BREAK GALAXIESLiubin Pan and John ScaloAstronomy Department,University of Texas at Austin,Austin,TXpanlb@;scalo@ApJ Letters,in pressABSTRACTMotivated by an interpretation of z ∼3objects by Jimenez and Haiman (2006),we examine processes that control the fraction of primordial (Z =0)gas,and so primordial stars,in high-SFR Lyman break galaxies.A primordial fraction different from 1or 0requires microscopic diffusion catalyzed by a velocity field with timescale comparable to the duration of star formation.The only process we found that satisfies this requirement for LBGs without fine-tuning is turbulence-enhanced mixing induced by exponential stretching and compressing of metal-rich ejecta.The time-dependence of the primordial fraction for this model is calculated.We show that conclusions for all the models discussed here are virtually independent of the IMF,including extremely top-heavy IMFs.Subject headings:ISM:evolution–galaxies:abundances–galaxies:evolution–galaxies:ISM–turbulence1.INTRODUCTIONGalaxies begin their lives with entirely primordial (Z =0)gas.As they age,metal production and mixing can only reduce the primordial gas fraction.We have ex-plored the expected time dependence of the primordial fraction for various types of mixing and chemical evolu-tion processes using a kinetic equation for the evolution of the abundance distribution.The present Letter ad-dresses the narrower question of whether any models for mixing and chemical evolution predict this transforma-tion occurs at an accessible redshift.Jimenez and Haiman (2006)(hereafter JH)showed that several UV properties of a variety of objects,mostly Lyman break galaxies (LBGs),at redshift z ∼3,can all be understood if these objects contain a substantial fraction,about 10to 50percent,of massive stars withessentially zero metallicity (Z ∼<10−5Z ⊙;we use Z and metallicity indiscriminantly here).These UV prop-erties cannot together be explained by a top-heavy IMF,and require Z =0stars;a top-heavy IMF is not re-quired.Massive stars have short lifetimes,so their metal abundances reflect that of the concomitant gas.Thus,if JH are correct,a substantial fraction of the interstel-lar medium of these galaxies,with star formation ages a few hundred million years,has not been polluted by any products of nucleosynthesis.1Motivated by JH and other suggestions for Z =0stars (Malhotra &Rhoads 2002;Shimasaku et al.2006),and the fact that during some early period in the lives of all galaxies a transformation from primordial to non-primordial must occur,leaving spectrophotometric sig-natures (JH;see Schaerer 2003),we examined the viabil-ity of a number of models for this transformation.A change in the primordial fraction requires micro-scopic diffusion enhanced by a complex velocity field,1The existence of Z =0gas requires an IMF deficient in stars with M ∼<1M ⊙.Otherwise the number of low-mass stars observable today would be large,contradicting observational limits on the star fraction with very small Z (see Oey 2003)by several orders of magnitude.We discuss the effects of different IMFs below,where we show that all our conclusions are independent of the IMF as long as it satisfies the requirement M ∼>1M ⊙.such as instabilities in swept-up supernova shells or aturbulent interstellar medium (ISM),along with disper-sal of nucleosythesis products over many kpc,involving a scale range of ∼105.Existing hydrodynamic simulations in a cosmological context (e.g.,Governato et al.2004;Scannapieco et al.2005)therefore cannot represent the transition of the primordial gas or mixing in general,since they adopt mixing rules that arbitrarily spread met-als among nearest neighbor cells or SPH particles.The only hydrodynamic simulations of true mixing of tracers in galaxies were concerned either with turbulent disper-sal of mean metallicity,not mixing (Klessen &Lin 2003),or mixing of initial spatially periodic inhomogeneities by numerical diffusivity in a turbulent galaxy with no con-tinuing source of metals (de Avillez &Mac Low 2002).Instead of simulations,the arguments given here are phenomenological,in order to clarify the essentials for each physical process.A detailed discussion is given elsewhere (Pan and Scalo 2006,hereafter PS)using a formal probability distribution evolution equation.Here we report that most processes we examined are either far too fast or slow to partially erase the primordial frac-tion (Sec.2),except for mixing by turbulence-enhanced diffusivity based on exponential stretching of blobs of nucleosynthesis products,discussed in Sec.3.22.ESTIMATES OF TIMESCALES FOR MIXINGPROCESSES2.1.Star Formation AgeThe existence of a primordial gas fraction P (t )that is not nearly unity or zero,i.e.,both P (t )and 1−P (t )are significantly larger than zero,a condition we refer to as a “significant”or “intermediate”primordial fraction,requires a mixing or depletion process whose character-istic timescale is comparable to the star formation (SF)age,the time since SF began.If the mixing timescale is much smaller,P (t )will be nearly zero;if it is much2A recent estimate of the effect of SN mixing (sec. 2.4below)on the primordial fraction at high redshift (Tumlinson 2006)ap-parently used a shell mass much larger than found in analytical and numerical calculations of supernova remnant evolution (see Thornton et al.1998;Hanayama &Tomisaka 2006).2Pan&Scalolarger,P(t)will remain near unity.SF ages for LBGs and likely-related objects at somewhat different redshifts have been estimated by Papovich et al.(2001),Shapley et al.(2001),Erb et al.(2006)and others,using galaxy evolution models that assume an exponentially decreas-ing SFR that began at some time in the past.Although there is much variation,median SF ages are3×108yr. These SF ages cannot be significantly different for a number of reasons.The lookback times of about11.5 Gyr for z=3imply a strict upper limit to the SF age of 2Gyr,and a more likely upper limit of1.5Gyr(corre-sponding to z∼8).The irregular morphologies of the LBGs(Giavalisco2002)suggest that LBGs are in the process of formation,accumulating large fragments of gas and stars through mergers(Conselice2006),and proba-bly undergoing one of theirfirst major bursts of SF;star-burst populations have durations,estimated from statis-tics(Kennicutt et al.1987;Nikolic et al.2004),model-ing of integrated light features(Marcillac et al.2006), and theoretical arguments(see Leitherer2001),that are similar to the estimates in LBGs.Finally,ages much greater than3×108yr would produce greater metallic-ity than observed(see Giavalisco2002).We assume star formation has been a continuous func-tion of time.If instead the SFR preceding or during the present episode consists of bursts of shorter duration, most of our arguments remain unchanged if the SF age is replaced by the accumulated duration of SF.2.2.Depletion of the Primordial Fraction by Sources The JH result of10-50%primordial at z∼3seems surprising,but actually galaxies should remain almost completely primordial for billions of years in the absence of microscopic diffusivity.SN metal production slowly depletes primordial gas by transferring it from a Z=0 delta function in the Z probability distribution(pdf)to another delta function at a much larger Z,the source metallicity Z s averaged over the IMF(∼0.1assuming the hot ejecta are well mixed).Intermediate values of Z cannot be reached without diffusivity.This suggests the simplest explanation for an inter-mediate primordial fraction in LBGs:50to90%of the primordial gas passed through stars that became SNe. The timescale for this process is the source timescale,τsrc=M gas/BR SN,where B is the star formation rate and R SN is the returned fraction from SNe aver-aged over the IMF.We take the total gas mass M gas as 5×1010M⊙,extrapolated from gas masses estimated in the z∼2UV-selected sample of Erb et al.(2006). From a number of studies,we adopt a median SFR of100 M⊙/yr for LBGs at z∼3assuming the IMF lower limit M l=0.1(Papovich et al.2001;Shapley et al.2001; Giavalisco2002;Erb et al.2006;Yan et al.2006).For this M l,we calculate R SN≈0.1for various IMFs using the ejected masses given in Woosley&Weaver(1995), Meynet&Maeder(2002)and Nomoto et al.(2006),find-ing little dependence on metallicity,including Z=0,and 20-30%variation between studies.Variations in the form of the IMF change the SFR by∼50%,with only a slight effect on R SN.The source timescale is thenτsrc=5 Gyr,within a factor of a few considering the uncertainty in the SFR and M gas,too large to affect the primordial fraction.We examined the IMF-dependence ofτsrc.There are two nonstandard IMFs that are especially relevant. 1. Intermediate primordial fractions require that the IMF lower limit M l∼>1M⊙to avoid too many Z=0stars observable today.Such a cutoffdoes not affect the source timescale:The empirical SFRs are based on integrated light from massive stars corrected for the rest of the IMF, and the resulting decrease of the SFR due to the cutoffis exactly compensated by the increase of the mass ejected by supernovae per unit mass of stars formed R SN.This IMF-independence ofτsrc holds for any cutoffsmaller than the lower mass limit for SNe,∼8M⊙.By the same argument,such a cutoffdoes not overproduce metallicity.2.A perennially popular IMF for Z=0star formation consists of only very massive stars(VMS)due to the Jeans mass resulting from H2cooling(Hutchins1976; see Bromm and Larson2004)although it has been ques-tioned on a number of grounds(Silk&Langer2006). Comparing Hαemission per unit SFR for a VMS IMF (50-500)M⊙of Z=0stars in Schaerer(2003)with the same quantity for a(0.1-100)M⊙IMF in Kennicutt (1998),both for a Salpeter IMF(for illustration only), the SFR for a VMS IMF is26times smaller.Assuming only stars in the range130-260M⊙explode as pair in-stability SNe(Woosley et al.2002),wefind R SN=0.27, soτsrc=50Gyr,an order of magnitude larger than the normal IMF case.These results strengthen our conclusion that the forma-tion of massive stars is far too slow to deplete primordial gas significantly in the available time.2.3.Filling the Gap by DiffusionWithout a process to spread metals into the“gap”be-tween the Z s peak and the primordial Z=0peak,P(t) would remain near unity for billions of years.The only physical process that canfill this gap is microscopic diffu-sivity.However an estimate of the rate at which diffusiv-ity from random sources could pollute primordial gas in LBGs,using diffusion lengths for the cold neutral,warm neutral,and warm ionized ISM similar to those in Oey (2003),shows that the fraction of the mass of a galaxy mixed in time t is only∼10−5(t/0.5Gyr)5/2,so diffu-sivity by itself cannot pollute more than a tiny fraction of the primordial gas over the estimated SF ages.To reduce the primordial fraction,a velocityfield is required to catalyze diffusivity.However a velocityfield cannot by itself affect the global metallicity distribution or primordial fraction,or mix at all:Displacement of fluid parcels of different Z by the velocityfield conserves their volumes and thus volume fractions(or mass frac-tions for compressibleflows),replacing one by another in space,having no effect on the Z distribution.This can be shown rigorously using a metallicity pdf equation (PS).A velocityfield can only enhance mixing by spa-tially ramifying the Zfield for diffusion to operate on small scales.Models that mix by sweeping of gas by SN or SB shells,cloud motions,differential rotation,or“tur-bulent diffusion”are unphysical without recognition that they are implicit models for microscopic diffusion.2.4.Several Catalyzing Velocity Fields Expanding SNRs and superbubbles(SBs)are the main agents of mixing in many sequential enrichment inho-mogeneous chemical evolution models(Reeves1972;seePrimordial Gas in LBGs3Tsujimoto et al.1999;Oey2000;Argast et al.2000; Saleh et al.2006).Shells can mix,but only if instabilities allow diffusion to mix swept-up gas with new products of nucleosynthesis.Assuming this oc-curs,each SNR sweeps up and mixes a mass M sw∼2×104M⊙for Z=0gas(Thornton et al.1998; Hanayama&Tomisaka2006).The time to sweep up primordial ISM isτsw=M gas/(νSN M sw),where the SN rateνSN=ǫB/ M∗ .For an IMF with mass range (0.1,100)M⊙and indices(-0.4,-1.7)below and above 1M⊙the number fractionǫof stars that become SNe is0.004and the average stellar mass M∗ =0.6,so νSN=0.7/yr andτsw=3×106yr.Equivalently,the ac-cumulated volumefilling factor NQ=t/τsw(Oey2000), so P=exp(−t/τsw)=exp(−NQ)and it is impossible to preserve primordial gas in LBGs for longer than∼1% of the observed SF ages∼3×108yr,unless the mixing efficiency is artificially tuned to1%,in which case the model predicts too large a present-day scatter in metal-licity compared to observations.Superbubbles have a smaller frequency,but sweep up more gas,producing an almost identical result.Spatial clustering and infalling Z=0gas also do not affect the conclusion.These points are discussed in details in a separate publication(PS). Using the same argument as forτsrc in sec2.2,an IMF cutoffat1M⊙does not affect the SN rate,giving the sameτsw.Unexpectedly,τsw for a VMS IMF is also nearly unchanged,because of the cancellation of the de-crease ofνSN(by a factor of100)and the increase of M sw by a factor of∼50due to the large explosion en-ergy of pair instability SNe(up to1053erg,see Woosley et al.2002).Therefore our conclusion that SN or SB sweep-up mixing is so fast that LBGs should have zero primordial gas is virtually independent of the IMF.The mixing would be100times faster using the mixed mass per event adopted by Tumlinson(2006).Unmixed pockets of metals in SBs could blast out of a galactic disk,later showering the disk with“droplets”of pure metals,diffusively mixing once they land in the disk(Tenorio-Tagle1996).Fine-tuning of the number of droplets,or equivalently the mixed mass,per SN,is required to give the desired timescale,but is unspecified by the model.Differential rotation could stretch the products of nu-cleosynthesis deposited in a∼100pc SN blob,into long thin annuli until the scale of diffusivity is reached.The shear rate in LBGs,or whether they differentially rotate, is unknown.We used the rate∼10km/sec/kpc in our Galaxy as an illustration and found that the timescale to reach the diffusive scale derived in sec.3below,is about 8Gyr,which is too slow.Another stretching process,turbulence,produces ex-ponential,rather than linear,stretching,with strain rates ten times larger than Galactic differential rotation.3.TURBULENCE-ENHANCED DIFFUSIVE MIXING Turbulence deforms large-scalefluid elements and the tracers they contain intofilaments and sheets,bring-ing tracers closer together until scales are reached on which diffusivity can homogenize faster than the strain timescale of thefluid.The process is described by the general equation for the evolution of the metallicityfield in an arbitrary velocityfield u(x,t),∂Z(x,t)ρ∇·(ρκ∇Z(x,t))+S(1)whereκis the diffusivity and S denotes the sources.In our model a straining event on the scale of the sources L s takes Z to a critical scale,L diff, small enough for diffusivity to operate,at con-stant mean strain rate in a single step,by expo-nential stretching of line elements(Batchelor1952; Voth et al.2002).This“short circuit”of the scalar cascade(Villermaux et al.2001)is supported by exper-iments(Villermaux2004;Voth et al.2002)and simula-tions(Girimaji&Pope1990;Goto&Kida2003),and is similar to the scalar turbulencefield theory of Shraiman and Siggia(2000).We assume that in supersonic tur-bulence compressions are analogous to stretching in the sense of bringing tracers to the critical scale L diff.The scale L diff below which the diffusivity term ex-ceeds the advection term in eq1is obtained by equating the two terms and replacing spatial derivatives by L−1diff and u by the velocity at scale of L diff.Assuming u l∼l scaling appropriate for exponential stretching,the result is L diff=[κ/(U/L s)]1/2,where U is the rms turbulent velocity on the scale of the sources.A residence-time average diffusivity,assuming the WNM contains more than20%of the ISM mass,isκ∼1020cm2s−1.Then the average diffusivity scale in the ISM is L diff∼0.06 (L100/U10)1/2pc where L100is L s/100pc,and U10is U in units of10km/s(Kulkarni&Heiles1987).We as-sume the same scale for z∼3LBGs,noting that L diff only enters the mixing time(below)logarithmically. The mixing time follows from the assumed exponen-tial stretching,in which scales change as dl/dt=−γl, whereγ=U/L s is the large scale strain rate.This gives a time to bring tracers from L s to L diff asτmix= (L s/U)ln(L s/L diff)=(L s/2U)ln(UL s/κ).The quan-tity UL s/κis the diffusivity analogue of the Reynolds number,called the Peclet number P e.Numerically P e∼3×107(U10L100/κ20),givingτmix=(L s/2U) ln(P e)∼75Myr.The result could be smaller if the velocity dispersion increases with the SFR,as for turbu-lence driven by SNe(e.g.,Dib&Burkert2005).The primordial fraction is the cumulative pdf of the gas metallicity Z0f(Z′,t)dZ′,where f(Z,t)is the dif-ferential pdf of metallicity,as the integration limit Z approaches zero.We can obtain the equation for P(t)heuristically,without details of the integral closure (Janicka et al.1979)we used to derive the full pdf equa-tion corresponding to the advection-diffusion equation eq 1(PS),a turbulent mixing closure that gives the same timescale for exponential variance decay as found in sim-ulations by de Avillez and Mac Low(2002,eq.17),and the same dependence of mixing time on initial size and SN rate(their Fig.7),if velocity dispersion U scales as the square root of the SN rate(Dib and Burkert2005). The primordial fraction decreases wheneverfluid ele-ments with primordial mass fraction P and gas that has been polluted by sources or previous mixing events,with mass fraction1−P,are stretched sufficiently to result in diffusive mixing.This interaction occurs with an averagefrequencyτ−1mix.P is also gradually depleted by cycling through massive stars that inject metals when they ex-4Pan &Scalo0 0.20.40.60.810.20.40.60.81P r i m o r d i a l F r a c t i o nSF duration (Gyr)JHτmix = 0.075infall rate = SFR 0.0250.075τmix = 0.15Gyrτsrc = 5Gyr2GyrFig. 1.—Primordial fraction as a function of SF duration for combinations of the mixing timescale τmix and the source timescale τsrc (see sec 2.2).The empirical value for τsrc is about 5Gyr within a factor of a few for an IMF with M l =0.1.τsrc is independent of M l if it is smaller than the mass limit for SNe.For a VMS IMF,τsrc is much larger but does not affect the result significantly,as discussed in the text.The range suggested for z ∼3LBGs (JH)is indicated by the arrow.Also shown is an infall model with infall rate equal to the SFR.plode,on a timescale τsrc (sec 2.2),which we assume is constant for the times of interest.The equation for the primordial fraction is thendP/dt =−P (1−P )/τmix −P/τsrc(2)whose solution is,using the fact that τmix ≪τsrc ,P =(1+(τmix /τsrc )exp (t/τmix ))−1(3)P decreases exponentially on timescale τmix ,but only after a delay time ∼τmix ln (τsrc /τmix ),which is ∼3×108yr for τmix =75Myr and τsrc =5Gyr assuming an IMF with M l ∼<8M ⊙.The delay time is the time for sources to provide enough non-primordial gas to make P depart from unity,but the dependence on τsrc is only logarithmic,and so is nearly independent of IMF,even for the extreme case of a VMS IMF (see sec 2.2).The behavior of P as a function of time for different τmix and τsrc is illustrated in Fig.1.The smallest mixingtimescale shown,0.025Gyr,corresponds to a larger ve-locity dispersion ∼30km/s,not unreasonable for galax-ies with large SFRs.Our major result is that P (t )de-clines on a timescale similar to SF ages inferred from empirical modeling,without adjustment of parameters.The effect of Z =0infall can be understood by adding to eq 2a term (1−P )/τin where τin =M gas /infall rate is the infall timescale.An example is shown in Fig.1.Infall allows intermediate values of P (t )for a longer time,but only for infall timescales close to τmix ,implying a huge infall rate.Therefore it is unlikely that infall modifies the primordial fraction predicted by turbulent mixing.Galactic winds with large rates (Erb et al.2006)have no effect if the winds sample the full pdf of metallicity.If the galaxies have undergone previous episodes of SF with an accumulated duration as large as ∼1Gyr,even the turbulent model cannot explain the intermediate pri-mordial fractions claimed by JH.4.DISCUSSIONMost mixing processes predict a primordial fraction that is either unity or zero at z ∼3because they mix on a timescale that is much larger or smaller than the empir-ical SF ages.P (t )should be zero in almost all galaxies if stellar explosions mix as efficiently as assumed in sequen-tial enrichment models (or much more efficiently,Tum-linson 2006).Our turbulence-enhanced diffusivity model naturally preserves primordial gas from rapid mixing for a few times the mixing time,which itself depends only weakly on parameters,in particular the assumed IMF or the averaged diffusivity,and gives an intermediate pri-mordial fraction in galaxies with SF ages ∼1−3×108yr.That this timescale happens to match the star formation ages of these galaxies is no coincidence if star formation is driven by turbulence (Mac Low &Klessen 2004)pow-ered by stellar explosions.Future systematic investiga-tions of the spectrophotometric signatures of primordial gas in galaxies could distinguish these possibilities.We thank J.Craig Wheeler and the referee for con-structive comments.This work was supported by NASA ATP grant 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