化工原理英文教材传质分离过程Mass Transfer and Separation Processes
化工原理英文教材流体输送与计量泵设备Transportation and metering of fluids

If the suction pressure is actually less than the vapor pressure, cavitation will occur in the suction line, and no liquid can be drawn into the pump.
化工原理 Principles of Chemical Industry
Transportation and metering of fluids
The engineer is concerned with practical problems in transporting fluids from one place to another and in measuring their rates of flow.
Such devices increase the mechanical energy of the fluid.
The energy may be used to increase the velocity, the pressure, or the elevation of the fluid.
W
pb
gZb
ub2 2
pa
gZa
ua2 2
(8-1)
The equation(8-1) can be divided by g, gives
H
pb
g
Zb
ub2 2g
pa
g
Za
ua2 2g
(8-1a)
The quantity H is called developed (total) head, in which each term has the dimension of length.
传质过程 英语

传质过程英语Mass Transfer ProcessMass transfer is a process by which a substance moves from one location to another. The substance can be in solid, liquid or gas phase. The process is important in several areas of chemical engineering, including separation, purification, and reaction engineering. The following are the key aspects of mass transfer process.1. Mechanisms of mass transferThe mass transfer process can occur due to diffusion, convection, or a combination of both. Diffusion occurs when molecules move from high concentration to low concentration. It is driven by the concentration gradient and is a slow process. Convection, on the other hand, involves the movement of substances due to fluid flow, such as mixing or stirring. It is faster than diffusion but requires energy input.2. Mass transfer coefficientsMass transfer coefficients are parameters that indicate the rate of mass transfer under specific conditions. They are dependent on the properties of both the substance being transferred and the medium through which it moves. The coefficients can be determined experimentally or through theoretical equations. A high mass transfer coefficient indicates a fast transfer rate.3. Types of mass transferThere are three types of mass transfer: gas-phase mass transfer, liquid-phase mass transfer, and solid-phase mass transfer. In gas-phase mass transfer, the substance movesbetween gas phases, such as from the air to water. In liquid-phase mass transfer, the substance moves between different liquid phases, such as from water to oil. In solid-phase mass transfer, the substance moves through a solid, such as a catalyst.4. Applications of mass transferMass transfer is used in several areas of chemical engineering, such as separation and purification processes. Distillation, extraction, and adsorption are some examples of separation processes that utilize mass transfer. In reaction engineering, mass transfer plays a critical role in controlling the rate of reactant delivery to the reaction site.In conclusion, mass transfer is an essential process in chemical engineering. Understanding its mechanisms, coefficients, and types is crucial for designing effective separation, purification, and reaction systems.。
天大化工原理-英文版课件-Chapter 1-11Definitions and Principles

4. Course objectives
• Understand the basic principles of and equipment of the unit operations. • Include designing or selection of devices. operatioroubleshooting of various unit operations.
• The international steam table calorie (calIT), used in heat power engineering, is defined by • 1 calIT=4.1868*×107 ergs = 4.1868* J (1.22)
25
• The standard gravity acceleration
gn 980.665cm / s
2
26
3. FPS Units
• The standard for mass is the avoirdupois pound (lb), • 1 lb = 0.45359237* kg (1.26) • The standard for length is the inch (in.), • 1 ft= 12× 2.54×10–2m= 0.3048* m (1.27) • The standard for time remains the second (s). • The thermodynamic temperature scale is called the Rankine scale,
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1.1 UNIT OPERATIONS
• • • • 1. Unit operations 2. Classification of unit operations 3. Course description 4. Course objectives
《化工原理》8传质过程导论2

统为单向扩散时(B为停滞组分), J A = J B
NA >NBຫໍສະໝຸດ 传质通量(总通量)等于扩散通量的条件是:等摩尔相互扩散
双组分气体混合物中,组分A的扩散系数是:
(A)系统的物质属性
(B)组分A的物质属性
(C)只取决于系统的状态 (D) 以上三者都不是
College of Power Engineering NNU WANG Yanhua
pB1
p pA2 p pA1 ln p pA2 p pA1
p A1
ln p
p pA1
ln
2 101.3
100.5kPa
101.3 2
D N ART(z2 z1) pBm P( pA1 pA2 )
7.7 107 8.314 293 (0.022 0.01) 100.5
101.3 (2 0) 1.12105 m2 / s
D2
D1
p1 p2
T2 T1
1.75
二、液体中的D 约10-5cm2/s
分子密集 D液<D气
计算:经验公式,p11式(8-23) 或表8-4
【例】: 在一直立的毛细玻璃管内装有乙醇,初始液面距离管 口10mm,如图所示。管内乙醇保持为293K(乙醇饱和蒸汽压为 1.9998kPa),大气压为101.3kPa。当有一空气始终平缓吹过管 口时,经100小时后,管内乙醇液面下降至距管口21.98mm处。
D RTZ
P pBm
( pA1
pA2 )
气相
NAL
D z
L
c csm
cAq
cA2
L
液相
与等摩尔相互扩散相比多了一个因子p/pBm——漂流因数。 漂流因数反映总体流动对传质速率的影响。 p/pBm>1 传质速率较大。 若pA p/pBm;反之pA p/pBm≈1
化工专业英语——单元操作

单元操作Unit operation单元操作是化学工业和其他过程工业中进行的物料粉碎、输送、加热、冷却、混合和分离等一系列使物料发生预期的物理变化的基本操作的总称。
对这些操作的研究,是化学工程的一个重要分支。
各种单元操作依据不同的物理化学原理,应用相应的设备,达到各自的工艺目的。
如蒸馏根据液体混合物中各组分挥发能力的差异,可以实现液体混合物中各组分分离或某组分提纯的目的。
对单元操作的研究,以物理化学、传递过程和化工热力学为理论基础,着重研究实现各单元操作的过程和设备,故单元操作又称为化工过程及设备。
单元操作的应用遍及化工、冶金、能源、食品、轻工、核能和环境保护等部门,对这些部门生产的大型化和现代化起着重要作用。
Unit operation is a general term for a series of material handling, transportation, heating, cooling, mixing and separation of materials in the chemical industry and other process industries. The study of these operations is an important branch of chemical engineering. Various unit operations according to different physical and chemical principles, the application of the corresponding equipment, to achieve the purpose of their respective processes. Such as distillation according to the difference of the volatile capacity of the liquid mixture, can achieve the purpose of separation of components in liquid mixture or a group of purification. Based on the theory of physical chemistry, transfer process and chemicalthermodynamics, the research on the operation of the unit has focused on the process and equipment of realizing the operation of each unit, so the unit operation is also called the chemical process and equipment. Application of unit operation in chemical industry, metallurgy, energy, food, light industry, nuclear energy and environmental protection departments, the production of these departments and the modernization of large-scale play an important role.单元操作沿革Unit operation evolution单元操作在化学工业的发展过程中,人们最初以具体产品为对象,分别进行各种产品的生产过程和设备的研究。
化工原理课程(全英文)教学课件 11

Developed Head ������ = ������������ ������, unit m
12
Station a @ suction connection Station b @ discharge connection
© 2015 Yanwei Wang
Power Requirement & Motor Efficiency
������������ = ������������ − ������������������ = ������������������
������������ = Net work done to unit mass of fluid
������������ = Work done by the pump per unit mass of fluid ������������������ = Total friction in the pump per unit mass of fluid ������ = Pump efficiency ������ = Mass flow rate Shaft power = ������ = ������������������
Date: April 9, 2015
Chapter 2 Transportation of Fluids
Pipe, Fittings, and Valves (pp. 82-88)
Fluid-Moving Machinery (流体输送机械)
− Pumps (pp. 88-93)
− Positive-Displacement Pumps (pp.93-95)
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© 2015 Yanwei Wang
化工原理09-传质概论

A:可溶气体A溶于液体 —— 氨
液相
B:溶
剂 (solvent)—— 水
化工原理下册——传质概论
浓度表示 A组分 B组分 备 注
质量分率 a
aA=WA/W 气相yAg=nAg/ng
aB=WB/W
WA+ WB=W( kg); aA + aB=1 nAg+ nBg= ng( kmol); nAl+ nBl= nl( kmol) yA+yB=1; xA+xB=1; AA可大于,小于,等于1 YA可大于,小于,等于1 XA可大于,小于,等于1 V:混合物体积(m3) 总摩尔浓度Cm = (nA+ nB) / V 理想气体适用 以混合 物为计 算基准
NB = 0 ; NB ‘ = -JA
NA = JA / xB = D/d (CA1-CA2)CM / CmB
三、相内传质速率方程式
相内传质的要点是相内传质速率方程式 的表示,传质系数的单位搞清楚
化工原理下册——传质概论
JA 、 NA 、 N 、 NA’ 、 NB’的意义 JA ——扩散通量:单位时间,单位面积
化工原理下册——传质概论
∴ A组分的传质通量 NA = JA + NAb = JA + xANb B组分的传质通量 NB = JB + NBb = JB + xBNb 由于 Cm 一定, JA = -JB 仍然存在, 则 NA + NB = JA + JB + xANb + xBNb = Nb 又 JB = -NBb NB = 0 NA=Nb ∴ NA = JA + xANb = JA + xANA
NH3
气相内部 界面 传质 传质
3.传质分离过程解析

3 .1 .2 气 -液相传质设备
(一) 填充塔packed column;
packed tower
1 . 填料塔filled tower packed
tower
2 . 湍球塔turbulent ball tower (二) 板式塔column of trays; plate column; plate tower; tray column ; 1 . 筛板塔sieve 2 . 泡罩塔bubble cap 3 . 浮阀塔float valve tower 4 . 浮舌塔Floating tongue (三) 喷射式传质装置
3 .1 传质过程的机理及传质设备
3 .1 .1 传质过程的机理 (一) 单相中物质的扩散 1 . 分子扩散molecular diffusion--费克( Fick Law ) 定律 2 . 对流扩散convective diffusion--- 对流传质机理 (二) 相间传质 1 . 气-液相传质机理 (1 ) 双膜理论two-film theory (2 ) 溶质渗透-表面更新理论the penetration theory&the surface renewal theory 2 . 气-液相传质速率方程
溶质渗透-表面更新理论
Based on this model, a mathematical model of mass transfer coefficient of partial liquid phase was established by using Higbie solute permeation & Renewal Theory and Kolmogorff isotropic turbulence theory, and the oxygen transfer process of gas liquid two phase was described by the classical double film theory model. 在此模型基础上利用Higbie 溶质渗透&更新理论和 Kolmogorff各向同性湍流理 论建立了局部液相体积传 质系数数学模型, 并应用经典的双膜理论模 型描述气液两相间的氧传 递过程。费克( Fick )定律
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•How to separate a solution of salt and water?
(Problem for producing fresh water from the sea.) (1)Supply heat and boil water off; (2)Supply refrigeration and freeze out pure ice; (3)Pump the water to a higher pressure and force it through a thin solid membrane that will let water through preferentially to salt (reverse osmosis)反渗透.
•Thinking (introspection): Many environmental pollution problems are caused by separation itself?
Why? How to solve this problem?
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3. Definition of Separation Processes
Product Streams (different in composition, at least 2 streams)
19
Example: Distillation Fractionating
column
Feed
Overhead product
Bottom product
20
•The separation is caused by the addition of a separating agent). •separating agent: matter or energy •Usually the separating agent will cause the formation of a second phase of matter. • •Separation methods(mass transfer between two immiscible phases):
5
3. Learning Approaches
Mainly Learning: 1)process principles; 2)structure of typical equipment; 3)design calculations; 4)selection of typical equipment; 5)operating methods; 6)enhancement of unit operations.
化工原理 Principles of Chemical Industry
1. About the Courses and time scheduling
Lecturing (theory): About the Experiments(Contents, methods, groups): Course Design: What is the text book? Unit Operations of Chemical Engineering, the sixth edition. It is most popular in Chem. Eng. in USA univ. Authors? Warren L. McCabe, Julian C. Smith and Peter Harriott.
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3. Learning Approaches
For each of the unit operations, mainly learning the follow 1)Material balances; 2)Energy/Enthalpy balances; 3)Equilibria; 4) Heat and Mass transfer rates; 5)Operation relationships.
O2
Capbvilelosblvosaleedoslrvoseyedlssel
Blood Flow(High conc.of CO2)
CO2 O2ຫໍສະໝຸດ Blood Flow(low
CO conc.of CO2) 2
O2
Capillabrylood blood vessel v essel
Blood Flow Blood Vessel
•1)Forming a second phase of matter;
•2)Utilizing differences in some property such as vapor pressure, solubility or diffusivity…
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7. TERMINOLOGY AND SYMBOLS
Industrial processes: A group of operations for separating the components of mixtures is based on the transfer of material from one homogeneous phase to another.
7
3. Learning Approaches
Preparing lessons or preview before class →Review Don't take the course just for the grade. Practice makes a master. If you don't practice, you won'
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Introduction
9
1. An Example of Mass Transfer: Respira
CO2
Breathe in: O2; Breathe out: CO2
COCOC2 OO2 2
2O2 O2 Capillary
Lung
CO2 O2 CaCpialplbaillorlyoadry
•All three approaches are the reverse procedure of mixing, or “unmixing” , or separation processes.
15
•Spontaneous processes: randomness ↑ •Separation processes: randomness ↓ •Definition of separation processes: those operations which transform a mixture of substances into two or more products which differ from each other in composition.将物质在
4
2. Grading Standard (Continued)
《Experiments of Chem Eng Principles》: Final Exam(Including last semester’):80% Participation(including attendance, Assignments) :20% ( Participation of last semester :20%) Design Experiment?(Encouraged, Cooperation permitt
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Other examples of mass transfer:
•A lump of sugar added to a cup of black coffee. •Water evaporates from ponds to increase the humidity of the passing air stream. •Perfume presents a pleasant fragrance which is imparted throughout the surrounding atmosphere.
•The second law of thermodynamics(第二热力学定律): All natural processes take place so as to increase the entropy(熵), or randomness of the universe. •Salt dissolves in water and forms a solution of uniform composition. (spontaneously, randomness ↑)
3
2. Course Policies & Grading Standard
Final Exam of《 Mass Transfer and Separation Processes》 Participation(including attendance, Assignments) and Mid
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Other examples of Separation Processes : Food processing: •pharmaceutical manufacture. •Desalination of seawater. •Water and air pollution , municipal refuse (solid wastes) present separation problems of immense social importance.
membrane separations 3) Separation processes with chemical reaction
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6. General Separation process
Feed stream (one or more)
Separating agent (matter or energy)