ECH MSDS( 环氧氯丙烷)
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Epichlorhydrin CAS-No. Annex-1 EINECS-No. Symbol(s) R-phrase(s) Concentration : : : : : : 106-89-8 603-026-00-6 203-439-8 T R45, R10, R23/24/25, R34, R43 > 99,00 %
3. HAZARDS IDENTIFICATION
Appearance Colour Odour : : : liquid colourless Chloroform
The product is classified in accordance with Annex I to Directive 67/548/EEC. Flammable May cause cancer. Toxic by inhalation, in contact with skin and if swallowed.
The following actions are recommended :
-
来自百度文库
Consult a physician. Take victim immediately to hospital. If swallowed, rinse mouth with water (only if the person is conscious). Do NOT induce vomiting. Do not give anything to drink. Artificial respiration and/or oxygen may be necessary. Artificial respiration and/or oxygen may be necessary.
If victim is conscious:
If victim is unconscious but breathing:
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media powder Foam, AFFF Carbon dioxide (CO2) 5.2. Extinguishing media which must not be used for safety reasons Water spray jet 5.3. Special exposure hazards in a fire Flammable Heating can release hazardous gases. 5.4. Special protective equipment for fire-fighters Evacuate personnel to safe areas. Wear self-contained breathing apparatus and protective suit. Fire fighters must wear fire resistant personnel protective equipment. Clean contaminated surface thoroughly. 5.5. Other information Cool containers / tanks with water spray. Flood the product with water.
7. HANDLING AND STORAGE
7.1. Handling Use in closed system. Handle small quantities under a lab hood. Keep away from heat and sources of ignition. Prevent product vapours decomposition from contacting hot spots. Prevent product vapours decomposition from electric arc action (welding). Preferably transfer by pump or gravity. Use only equipment and materials which are compatible with the product. Keep away from incompatible products 7.2. Storage Store in original container. Keep in a cool, well-ventilated place. Keep away from heat and sources of ignition. Keep away from incompatible products Keep in a bunded area. Keep container tightly closed. 7.3. Specific use(s) For further information, please contact: Supplier 7.4. Packaging material Steel drum Stainless steel 7.5. Other information Keep away from heat, sparks and open flame. - No smoking.
Telephone Telefax
: :
1.4. Emergency and contact telephone numbers : Emergency telephone +44(0)208 762 8322 [CareChem 24] (Europe) number
2. COMPOSITION/INFORMATION ON INGREDIENTS
FDS / P 232 / 7/02/2007 / Ireland / Report version 1.2 / Issuing date
23.10.2006
1/11
-
Causes burns. May cause sensitization by skin contact. Hazardous decomposition products formed under fire conditions.
4. FIRST AID MEASURES
4.1. Inhalation In case of accident by inhalation: remove casualty to fresh air and keep at rest. Victim to lie down in the recovery position, cover and keep him warm. Oxygen or artificial respiration if needed. If symptoms persist, call a physician. 4.2. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine). Immediate medical attention is required. 4.3. Skin contact Remove and wash contaminated clothing before re-use. Wash off with soap and water. If symptoms persist, call a physician. 4.4. Ingestion
FDS / P 232 / 7/02/2007 / Ireland / Report version 1.2 / Issuing date
23.10.2006
2/11
-
Avoid propagating the fire when directing the extinguishing agent as a jet onto the surface of the burning liquid.
SAFETY DATA SHEET
According to Directive 2001/58/EC
EPICHLOROHYDRIN
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
1.1. Identification of the substance/preparation Product name : EPICHLOROHYDRIN Chemical Name : Epichlorhydrin Synonyms : 1-chloro-2,3-epoxypropane, 3-chloro-1,2epoxypropane Molecular formula : C3H5OCl Structural formula CH2=CH-CH2Cl Molecular Weight : 92,53 g/mol 1.2. Use of the Substance/Preparation Recommended use : 1.3. Company/Undertaking Identification Address : Chemical intermediate SOLVAY CHIMIE SA RUE DU PRINCE ALBERT, 44 B- 1050 BRUXELLES +3225096617 +3225096624
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions Prevent further leakage or spillage if safe to do so. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Wear self-contained breathing apparatus in confined spaces, in cases where the oxygen level is depleted, or in case of significant emissions. Keep away from open flames, hot surfaces and sources of ignition. Cover the spreading liquid with foam in order to slow down the evaporation. Keep away from Incompatible products. Ventilate the area. Refer to protective measures listed in sections 7 and 8. 6.2. Environmental precautions Should not be released into the environment. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods for cleaning up Dam up. Soak up with inert absorbent material. Prevent product from entering drains. Keep in properly labelled containers. Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".
3. HAZARDS IDENTIFICATION
Appearance Colour Odour : : : liquid colourless Chloroform
The product is classified in accordance with Annex I to Directive 67/548/EEC. Flammable May cause cancer. Toxic by inhalation, in contact with skin and if swallowed.
The following actions are recommended :
-
来自百度文库
Consult a physician. Take victim immediately to hospital. If swallowed, rinse mouth with water (only if the person is conscious). Do NOT induce vomiting. Do not give anything to drink. Artificial respiration and/or oxygen may be necessary. Artificial respiration and/or oxygen may be necessary.
If victim is conscious:
If victim is unconscious but breathing:
5. FIRE-FIGHTING MEASURES
5.1. Suitable extinguishing media powder Foam, AFFF Carbon dioxide (CO2) 5.2. Extinguishing media which must not be used for safety reasons Water spray jet 5.3. Special exposure hazards in a fire Flammable Heating can release hazardous gases. 5.4. Special protective equipment for fire-fighters Evacuate personnel to safe areas. Wear self-contained breathing apparatus and protective suit. Fire fighters must wear fire resistant personnel protective equipment. Clean contaminated surface thoroughly. 5.5. Other information Cool containers / tanks with water spray. Flood the product with water.
7. HANDLING AND STORAGE
7.1. Handling Use in closed system. Handle small quantities under a lab hood. Keep away from heat and sources of ignition. Prevent product vapours decomposition from contacting hot spots. Prevent product vapours decomposition from electric arc action (welding). Preferably transfer by pump or gravity. Use only equipment and materials which are compatible with the product. Keep away from incompatible products 7.2. Storage Store in original container. Keep in a cool, well-ventilated place. Keep away from heat and sources of ignition. Keep away from incompatible products Keep in a bunded area. Keep container tightly closed. 7.3. Specific use(s) For further information, please contact: Supplier 7.4. Packaging material Steel drum Stainless steel 7.5. Other information Keep away from heat, sparks and open flame. - No smoking.
Telephone Telefax
: :
1.4. Emergency and contact telephone numbers : Emergency telephone +44(0)208 762 8322 [CareChem 24] (Europe) number
2. COMPOSITION/INFORMATION ON INGREDIENTS
FDS / P 232 / 7/02/2007 / Ireland / Report version 1.2 / Issuing date
23.10.2006
1/11
-
Causes burns. May cause sensitization by skin contact. Hazardous decomposition products formed under fire conditions.
4. FIRST AID MEASURES
4.1. Inhalation In case of accident by inhalation: remove casualty to fresh air and keep at rest. Victim to lie down in the recovery position, cover and keep him warm. Oxygen or artificial respiration if needed. If symptoms persist, call a physician. 4.2. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine). Immediate medical attention is required. 4.3. Skin contact Remove and wash contaminated clothing before re-use. Wash off with soap and water. If symptoms persist, call a physician. 4.4. Ingestion
FDS / P 232 / 7/02/2007 / Ireland / Report version 1.2 / Issuing date
23.10.2006
2/11
-
Avoid propagating the fire when directing the extinguishing agent as a jet onto the surface of the burning liquid.
SAFETY DATA SHEET
According to Directive 2001/58/EC
EPICHLOROHYDRIN
1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING
1.1. Identification of the substance/preparation Product name : EPICHLOROHYDRIN Chemical Name : Epichlorhydrin Synonyms : 1-chloro-2,3-epoxypropane, 3-chloro-1,2epoxypropane Molecular formula : C3H5OCl Structural formula CH2=CH-CH2Cl Molecular Weight : 92,53 g/mol 1.2. Use of the Substance/Preparation Recommended use : 1.3. Company/Undertaking Identification Address : Chemical intermediate SOLVAY CHIMIE SA RUE DU PRINCE ALBERT, 44 B- 1050 BRUXELLES +3225096617 +3225096624
6. ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions Prevent further leakage or spillage if safe to do so. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing. Wear self-contained breathing apparatus in confined spaces, in cases where the oxygen level is depleted, or in case of significant emissions. Keep away from open flames, hot surfaces and sources of ignition. Cover the spreading liquid with foam in order to slow down the evaporation. Keep away from Incompatible products. Ventilate the area. Refer to protective measures listed in sections 7 and 8. 6.2. Environmental precautions Should not be released into the environment. If the product contaminates rivers and lakes or drains inform respective authorities. 6.3. Methods for cleaning up Dam up. Soak up with inert absorbent material. Prevent product from entering drains. Keep in properly labelled containers. Keep in suitable, closed containers for disposal. Treat recovered material as described in the section "Disposal considerations".