A New Energy Efficient Approach by Separating Data

合集下载

建设“无饿医院”

建设“无饿医院”

·专家论坛·建设“无饿医院”石汉平,陈伟,杨柳青,丛明华,王昆华,李勇,李薇,李增宁,杨勤兵,张晓伟,周福祥,叶文锋,张骁玮,王晓琳,王欣,朱乾坤,蔡丽雅,贾平平,邓丽,贺源,吉琳琳,于恺英,赵青川,秦环龙,韦军民,朱明炜,陈俊强,杨桦,王新颖,许红霞,李涛,刘明,崔久嵬,李苏宜,陈永兵,江波,饶本强,李素云,陈春霞,刘晓倩,赵文芝(中国抗癌协会肿瘤营养与支持治疗专业委员会,中华医学会肠外肠内营养学分会)基金项目:国家重点研发计划项目(2017YFC1309200)通讯作者:石汉平,电子邮箱:shihp@摘要:医院是营养不良发病率最高的地方之一,患者是营养不良发生率最高的人群。

高达20%~60%的患者入院时存在营养不良,30%~80%的患者住院期间发生显著的体重丢失,提示患者住院期间发生了医源性或院内营养不良(nosocomial malnutrition ,NM )或医院获得性营养不良(hospital acquired malnutrition ,HAM ),从而进一步加重了原有的疾病相关性营养不良(disease-related malnutrition ,DRM )。

无饿医院建设就是要确保患者住院期间吃到卫生、经济、营养丰富的膳食,减少饥饿及隐性饥饿,有效预防HAM ;确保患者得到合理的营养治疗,有效治疗DRM 。

无饿医院建设是一个系统工程,包括提高对营养不良危害性的认识、研发更加便利的营养不良诊断工具、强化入院二元诊断,提高营养不良诊断率、建立NST 及NSC 团队、畅通营养诊治收费体系、提供RUSF 及RUTF 、优化检查和治疗时间、建立无饿医院考评体系、持续质量改进等。

主要从四个方面推进“无饿医院”建设:①解决营养科学问题;②规范临床营养诊疗;③改善医疗与护理行政管理;④强化后勤保障。

医院行政管理、临床医护、后勤保障、患者及家属一体化参与“无饿医院”建设,在全社会开展无饿医院文化宣传,努力为患者提供一个无饿、舒适的就医环境。

2023 Warnings, Cautions, and Notices 制品安装和维护指南说明书

2023 Warnings, Cautions, and Notices 制品安装和维护指南说明书

467©2023Inspection•Unpack all components of the kit.•Check carefully for any shipping damage. If any damage is found it must bereported immediately and a claim made against the transportation company.•Visually inspect the components for shipping damage as soon as possibleafter delivery, before it is stored. Concealed damage must be reported within15 days.•If concealed damage is discovered, stop unpacking the shipment.•Do not remove damaged material from the receiving location. Take photosof the damage, if possible. The owner must provide reasonable evidence thatthe damage did not occur after delivery.•Notify the carriers terminal of damage immediately by phone and by mail.Request an immediate joint inspection of the damage by the carrier and theconsignee.Important:Do not attempt to repair any damaged parts until the parts areinspected by the carriers representative.Safety Instructions Before Operating the Unit•This appliance does not have a pilot. It is equipped with an ignition devicewhich automatically lights the burner. Do not try to light the burner by hand.•BEFORE OPERATING smell all around the appliance area for gas. Be sureto smell next to the floor because some gas is heavier than air and will settleon the floor.What to do if you Smell Gas•Do not try to light any appliance.•Do not touch any electric switch; do not use any phone in your building.•Immediately call your gas supplier from a neighbor’s phone. Follow the gassupplier’s instructions.•If you cannot reach your gas supplier, call the fire department.Temperature Control DevicesRoom thermostats and zone sensors are delicate temperature control devices.Thermostats will energize and de-energize the heating or cooling circuit tomaintain the temperature setting selected.Zone sensors will sense the room temperature to allow the unit controls toactivate the heating and cooling functions and maintain the temperatureselected.Many thermostats and zone sensors contain a room thermometer to indicate theapproximate room temperature, and a temperature scale at the adjustmentindicator to select the desired indoor air temperature. Most controls have aselector mode switch with Heat, Off, and Cool positions, and a fan switch with Onand Auto positions.When the selector switch is positioned at Off, the unit will not operate in either theheat or cool modes. If the selector switch is set at Heat, the unit will automaticallycycle on and off to maintain the desired temperature setting. The unit will alsooperate automatically when the selector switch is positioned at Cool.The fan selector switch can be used to operate the indoor fan continuously bypositioning it at On. When set at Auto, the fan will only operate when requiredduring the heating or cooling cycles.To verify the thermostat or zone sensor operates properly, it must be level andpositioned to avoid the influence of such external heat sources such as lamps,televisions, or other heat producing appliances.Owner ManualPackaged Rooftop Air ConditionersVoyager™ 3 Gas/ElectricFor Servicers and Owners UseModel Number:27.5 to 50 Ton Packaged Gas/ElectricSeptember 2023RT-SVU04K-EN9118©2023Trane and American Standard have a policy of continuous product and product data improvement and reserve the right to change design and specifications without notice. We are committed to using environmentally conscious print practices.Trane and American Standard create comfortable, energy efficient indoor environments for commercial and residential applications. For more information, please visit or .Air FiltersImportant:It is very important to keep the central duct system air filters clean.Inspect them at least once each month when the system is in constant operation. In new homes, check the filters every week for the first 4 weeks. See Table 1 for the required filter size(s).If filters are disposable, replace them with new filters of the same type and size. Do not attempt to clean disposable filters.Permanent type filters can be cleaned by washing them with a mild detergent and water. Confirm filters are thoroughly dry before reinstalling them in the unit (or duct system).Note: It may be necessary to replace permanent filters annually if washing fails to clean the filter, or if the filter shows signs of deterioration. Use the same type and size as was originally installed.Table 1.Recommended filter sizeModel Qty Filter Size (L x W x D)YC*330-4201616 x 20 x 2(a)(a)4-inch are optional. Replace with same size as originally supplied.YC*480-6001716 x 20 x 2(a)Heating SystemHeating Cycle OperationA normal heating cycle begins when the air temperature in the home drops below the selected setting. The control then energizes the heating electrical circuit that starts and controls the main burners. Shortly after the main burners ignite, the indoor fan starts and circulates warm air through your home, or building.When the air temperature rises to the selected setting, the control de-energizes the heating electrical circuit which, in turn, extinguishes the main burners. The indoor fan continues to circulate warm air until most of the heat is removed from the unit’s combustion chamber.Safety ControlsThe unit is equipped with automatic reset safety limit controls to prevent overheating. When one of these controls open, it shuts down the heatingelectrical circuit until it cools down sufficiently. Inadequate airflow (dirty air filters or a defective fan motor) may cause the unit to cycle on and off as the limit controls trip and automatically reset. If you suspect the unit is cycling on its limit controls, immediately contact a technician for instructions.Operating Instructions1.Set the temperature control to lowest setting.2.Turn off all electric power to the appliance.3.This appliance is equipped with an ignition device which automatically lights the burner. Do not try to light the burner by hand.Note: Depending on heater size, the gas valve control will be a knob, as shown in Figure 1, or a toggle switch.6.Wait 5 minutes to clear out any gas. If you then smell gas, STOP! Follow “What to do if you Smell Gas” in the safety information above in this manual. If you do not smell gas, go to the next step.7.Turn gas control knob counter-clockwise or flip the toggle switch to ON .8.Replace panel removed in Step 4.9.Turn on all electric power to the appliance.10.Set the temperature control to desired setting.Note: If the unit is equipped with modulating gas heat, the discharge air setpoint will also need to be set before the initial setup is complete.11.If the appliance does not operate, follow instructions in “To Turn Off Gas to the Appliance” below and call your service technician or gas supplier.To Turn Off Gas to the Appliance1.Set the temperature control to lowest setting.2.Turn off all electric power to the appliance if service is to be performed.3.Remove the access panel that has the following label:4.Turn the gas control knob clockwise or flip the toggle switch to the OFF position.Note: Some valves require the knob to be pushed in slightly before turning. Do not force.5.Replace panel removed in Step 3.REMOVE THIS PANELTO GAIN ACCESS TO THE GAS VALVERT-SVU04K-EN 30 Sep 2023Supersedes RT-SVU04J-EN (May 2020)。

能源环境用富氮共轭微孔聚合物材料研究进展

能源环境用富氮共轭微孔聚合物材料研究进展

㊀第40卷㊀第9期2021年9月中国材料进展MATERIALS CHINAVol.40㊀No.9Sep.2021收稿日期:2021-04-01㊀㊀修回日期:2021-06-09基金项目:国家自然科学基金资助项目(52073046,51873036,51673039,52103106);教育部长江学者奖励计划青年项目(Q2019152);上海市曙光人才计划项目(19S-G28);上海市自然科学基金项目(19D3859);中央高校基本科研业务资助项目(2232019A3-01,2232020D-08)第一作者:滕砺宽,男,1998年生,硕士研究生刘永盛,男,1998年生,硕士研究生通讯作者:吕㊀伟,女,1989年生,讲师,硕士生导师,Email:wlyu@廖耀祖,男,1982年生,研究员,博士生导师,Email:yzliao@DOI :10.7502/j.issn.1674-3962.202104005能源环境用富氮共轭微孔聚合物材料研究进展滕砺宽1,刘永盛1,吕㊀伟1,吴子豹2,廖耀祖1(1.东华大学材料科学与工程学院纤维材料改性国家重点实验室,上海201620)(2.南通斐腾新材料科技有限公司,南通226334)摘㊀要:共轭微孔聚合物(conjugated microporous polymers,CMPs)是一类由刚性芳香结构单元组成㊁自具微孔结构㊁具有三维网络骨架的有机多孔材料,具有稳定的多孔性和半导体特征,在电化学和热能存储㊁氢能转化㊁CO 2捕获和存储㊁污染物吸附和分离纯化等能源环境领域有着重要应用㊂其中,富氮共轭微孔聚合物因富含极性氮原子,具有强吸附位点和富电子结构,拥有独特的氧化还原电化学活性和一定的润湿性,显现出独特的应用优势㊂系统概述了富氮共轭微孔聚合物的制备及其在能源环境领域的应用研究进展,分析了各种制备方法的优缺点以及在应用方面存在的主要问题,并指出了富氮共轭微孔聚合物材料未来的发展方向 开发绿色㊁廉价的合成新方法以及相关高性能膜或块体材料的制备新路径等㊂关键词:有机多孔材料;富氮共轭微孔聚合物;制备方法;能源存储与转化;污染物吸附分离中图分类号:TQ317㊀㊀文献标识码:A㊀㊀文章编号:1674-3962(2021)09-0645-14Research Progress in Preparation of Nitrogen-RichConjugated Microporous Polymers for Energyand Environmental ApplicationsTENG Likuan 1,LIU Yongsheng 1,LYU Wei 1,WU Zibao 2,LIAO Yaozu 1(1.State Key Laboratory for Modification of Fibers and Polymer Materials,College of Material Science andEngineering,Donghua University,Shanghai 201620,China)(2.Nantong Feiteng New Matrials Technology Co.,Ltd.,Nantong 226334,China)Abstract :Conjugated microporous polymers (CMPs)are a class of porous polymers with three-dimensional network skeletonand microporous structure,which consist of rigid aromatic structural units.Owing to their characteristics of stable porosity and semiconductor,they have shown significant potentials in the applications of energy and environmental areas such as electro-chemical and thermal energy storage,hydrogen energy conversion,the capture and storage of CO 2and the adsorption,separa-tion and purification of pollutants.Among these CMPs,nitrogen-rich conjugated microporous polymers (NCMPs)possess extra adsorption active sites and electrons and therefore show the unique redox electrochemical activity and wettability because of their plentiful polar N atoms,endowing NCMPs with excellent performance in energy and environmental applications.In this review,the research progress in preparation of NCMPs for energy and environmental applications is summarized.The meritsand demerits of these preparation methods are analyzed.The main problems existing in the preparation methods and their applications are summarized.The future development direc-tions including developing new,green and cost-efficient syn-thetic method and new routes of high-performance membraneand bulk materials of NCMPs are finally proposed.Key words :organic porous materials;nitrogen-rich conjugated microporous polymers;preparation method;en-ergy storage and conversion;adsorption and separation of pollutants1㊀前㊀言多孔材料如沸石㊁金属有机框架㊁共价有机骨架㊁博看网 . All Rights Reserved.中国材料进展第40卷有机多孔聚合物等已广泛应用于能源存储与转化和污染物分离与吸附等能源环境领域㊂其中,有机多孔聚合物(porous organic polymers,POPs)由轻质元素组成,具有化学和热稳定性良好㊁比表面积高㊁孔隙率高㊁骨架密度低㊁分子可设计和易于功能化等优点㊂随着能源短缺和环境污染问题日益严重,设计合成性能优异的有机多孔聚合物材料成为当下的研究热点[1]㊂共轭微孔聚合物(conjugated microporous polymers, CMPs)作为一种新型有机多孔聚合物材料,是一类由π-π键连接的刚性芳香结构单元组成,自具微孔结构的三维骨架材料[2]㊂CMPs首次被报道于2007年,Cooper 课题组[3]通过Sonogashira偶联反应将芳香炔烃和芳香卤化物连接起来,进而制得共轭微孔聚乙炔撑芳基(PAEs)网络结构,其比表面积高达834m2㊃g-1㊂随后,一系列不同网络结构和性能的CMPs被陆续合成出来㊂其中,芳香环和共价键为CMPs骨架提供刚性和方向性,可防止微孔结构坍塌,赋予聚合物优异的热稳定性和化学稳定性;而共轭结构可为CMPs提供半导体特性[4],以上特性使得CMPs在电㊁热能源存储㊁氢能转化㊁CO2捕获和存储㊁环境污染物吸附和分离纯化等能源环境领域具有巨大的应用潜力[5]㊂通过向聚合物本体引入极性官能团或者杂原子可使CMPs进一步功能化㊂如引入氮原子,不仅能为CMPs提供额外的吸附活性位点㊁金属键合位点,并且这些氮原子中心还可以提供额外电子,使CMPs具有独特的氧化还原性和一定的润湿性,使其在能源环境相关领域中显现出更为优异的性能㊂本文旨在对能源环境用富氮共轭微孔聚合物的制备方法和应用进行系统归纳,并对目前该研究领域存在的问题进行分析和展望㊂2㊀富氮共轭微孔聚合物的制备方法因绝大多数具有共轭结构的单体都可作为CMPs的构筑单元,因此CMPs在结构单元的选择性上具有高度灵活性,从而具有很强的分子设计性㊂通常,富氮CMPs 的制备方法主要分为含氮原子共轭结构单元的C C偶联反应(如Suzuki,Sonogashira,Yamamoto偶联反应)㊁直接以胺基为聚合反应位点的C N偶联反应(如席夫碱缩合反应㊁Buchwald-Hartwig偶联反应)以及其它种类的反应(如Chichibabin吡啶合成反应㊁氧化聚合反应㊁氰基环化反应)等㊂2.1㊀含氮共轭结构的C C偶联反应(Suzuki,Sono-gashira,Yamamoto偶联反应)㊀㊀Suzuki和Sonogashira偶联反应是在钯催化作用下,卤代芳烃分别与硼酸芳烃或端炔芳烃进行C C键合的偶联反应㊂合理设计富氮共轭单体拓扑结构是构筑高性能富氮CMPs的关键㊂Jiang等设计合成具有类似化学组成,但构型和刚性不同的两种富氮型单体:2,2 -二氨基-3,3 ,5,5 -四溴联苯(单体1)和2,4,7,9-四溴苯并[C]噌啉(单体2),采用Suzuki和Sonagashira偶联聚合得到二氨基CMPs(DA-CMPs)和偶氮基CMPs(Azo-CMPs)的系列富氮型CMPs(图1)㊂研究表明,单体1中侧链的胺基占据了部分孔道致使最终聚合物的比表面积降低,而由单体2聚合所得的刚性偶氮基CMPs具有较高的比表面积(1146m2㊃g-1)㊂此外,胺基和偶氮基的引入都有效地增加了孔道与CO2的亲和力,而增加单体的刚性可以提高聚合物的比表面积,两者协同作用后使聚合物的气体吸附能力提高[6]㊂图1㊀Suzuki和Sonagashira偶联反应制备二氨基和偶氮基富氮共轭微孔聚合物[6]Fig.1㊀Synthetic route for DA-CMPs and Azo-CMPs by Suzuki and Sona-gashira crosslinking method[6]㊀㊀Yamamoto偶联反应是在镍催化剂作用下,双卤代芳烃或多卤代芳烃通过C C键合的偶联反应㊂该偶联方法的优点在于仅需要单个卤素官能化的单体,反应路线简单㊂因芳基卤化物单体种类繁多,故可通过Yamamoto偶联设计合成系列富氮CMPs㊂2017年,作者课题组[7]采用Yamamoto反应对聚咔唑进行吡啶㊁双吡啶㊁氰基功能化处理(图2)㊂相对于单纯的聚咔唑,极性氮功能化聚咔唑对CO2的选择性吸附显著增强,吸附焓由22.3提升到31.8kJ㊃mol-1㊂646博看网 . All Rights Reserved.㊀第9期滕砺宽等:能源环境用富氮共轭微孔聚合物材料研究进展图2㊀聚咔唑网络(PCZN)的反应路线[7]Fig.2㊀Synthetic route for polycarbazole network (PCZN)[7]2.2㊀席夫碱(Schiff base )缩合反应由芳香胺和芳香醛碳氮偶联缩合形成亚胺或甲亚胺特性基团( RC N )的席夫碱反应是制备富氮CMPs 的一种常用手段(图3)[8],该类富氮CMPs 在CO 2选择性吸附应用方面受到了研究者的广泛关注[9,10]㊂因该反应不使用金属催化剂,故而具有绿色㊁低成本㊁无二次污染的优点㊂合理选择芳香胺和芳香醛单体,席夫碱反应可以促使聚合物在水热条件下凝胶化,进而使生成的聚合物作为高性能氮掺杂炭气凝胶的前驱体㊂作者课题组[11]采用价格低廉的工业副品红碱和均苯三甲醛为原料,通过多次试验筛选溶剂类型㊁调控单体浓度及反应温度,设计合成富氮有机多孔聚合物纳米球凝胶,通过简单的高温热处理,一步法成功地制备得到了具有极高比表面积(2356m 2㊃g -1)的新型氮掺杂炭气凝胶,其CO 2/N 2选择性系数高达47.8㊂图3㊀席夫碱反应制备富氮共轭微孔聚合物[8]Fig.3㊀Nitrogen-rich CMPs synthesized via Schiff base reaction [8]2.3㊀Buchwald -Hartwig 偶联反应在少量钯的催化作用下,由芳香卤化物和芳香胺进行C N 偶联的Buchawald-Hartwig(BH)反应是制备富含亚胺氮CMPs 的又一常用方法㊂作者课题组于2014年首次将BH 偶联反应拓展到富氮CMPs 的高效制备上[12]㊂所制备的富氮CMPs 具有类似于导电高分子聚苯胺的独特氧化还原电活性,兼具微孔结构和优异电活性的特点,在电化学能源存储领域显现出了独特的优势㊂通过优化芳香胺的共轭长度和刚性,BH 偶联反应制备的富氮CMP 比表面积最高可达600m 2㊃g -1(图4)[13]㊂2019年以来,利用不同阴离子尺寸的盐(如NaF,NaCl,NaBr 和NaI)和阳离子尺寸的盐(如LiNO 3,NaNO 3,KNO 3和Ba(NO 3)2),对合成溶剂的Hansen 溶度进行调控并使之与聚合物的溶度常数匹配,可以将该类型CMPs 的比表面积提高到1152m 2㊃g -1㊂该方法对制备具有均一微孔孔径分布㊁高比表面积的富氮CMPs 具有指导意义[14,15]㊂2.4㊀Chichibabin 吡啶合成反应Chichibabin 吡啶合成是一种利用醛和氨发生缩合,得到2,3,5-取代吡啶的反应㊂该反应简单㊁易操作㊁反应时间短㊁反应条件温和且不使用任何金属催化剂,是一种绿色制备吡啶基富氮CMPs 的合成路径㊂作者课题组[16]于2020年首次选用对苯二甲醛和均苯三甲醛分别与苯乙酮和三乙酰基苯在醋酸铵/醋酸的混合溶剂中120ħ下回流1h(图5),制得纳米球状吡啶基富氮CMPs,即PCMPs㊂PCMPs 特有的电子结构使其在光催化产氢领域具有潜在的应用价值㊂进一步地,通过调控单体的几何拓扑结构和氮含量,实现了对PCMPs 能带和光催化制氢性能的调节,最高可实现1198.9μmol㊃g -1㊃h-1的光催化产氢速率(紫外光照射)[17]㊂Chichibabin 吡啶合成反应为光催化产氢聚合物催化剂提供了一种绿色的制备新途径㊂746博看网 . All Rights Reserved.中国材料进展第40卷图4㊀Buchawald-Hartwig偶联反应合成氨基蒽醌型共轭微孔聚合物(PAQ)网络[13] Fig.4㊀Synthetic route for the formation of PAQ networks via Buchawald-Hartwig cross-coupling reaction[13]图5㊀纳米球状吡啶基富氮共轭微孔聚合物(PCMPs)合成路径[16] Fig.5㊀Synthetic route to PCMPs[16]2.5㊀氧化聚合反应氧化聚合反应是富氮CMPs制备的另一常见手段,通常选用含苯胺㊁吡咯或咔唑单元的单体,在化学氧化剂如FeCl3的作用下进行化学氧化聚合或电化学氧化聚合㊂作者课题组[18,19]于2017年以FeCl3为氧化剂,硝基甲烷/氯仿混合溶液为反应溶剂分别对星状咔唑㊁苯胺单体进行化学氧化聚合,制备得到氮含量(质量分数)分别为6.1%和11.84%的富氮CMPs(图6和图7),比表面积高达1200m2㊃g-1(PTCT)㊂其中,由于PTCT的刚性交联结构,咔唑基富氮CMPs热解制备氮掺杂炭材料的产率可高达75%~80%㊂得益于其较高的微孔孔隙率㊁比表面积以及氮含量,该氮掺杂炭材料具有优异的CO2存储(19.6%, 0ħ,0.1MPa)和电化学储能性能(558F㊃g-1,1A㊃g-1)㊂与化学氧化聚合相比,电化学氧化聚合虽然产量较低,但却能通过调节扫描速率和氧化电位精准制备厚度图6㊀聚咔唑网络及其衍生炭的合成路径[18] Fig.6㊀Synthetic route to polycarbazole networks and their derived car-bons[18]846博看网 . All Rights Reserved.㊀第9期滕砺宽等:能源环境用富氮共轭微孔聚合物材料研究进展图7㊀富氮共轭微孔聚合物(NCMP1,NCMP2,NCMP3)网络的合成路径[19]Fig.7㊀Synthetic route to nitrogen-rich CMPs (NCMP1,NCMP2,NC-MP3)networks [19]可控的富氮CMPs 薄膜㊂相较于不溶不熔㊁难以加工的粉末状富氮CMPs,薄膜状材料更具实际使用价值,便于高性能分离膜和膜器件的开发和应用㊂2013年,Ma 等[20]以四(4-咔唑基苯基)甲烷为单体,通过电化学氧化聚合法制备了相应的CMPs 薄膜材料,用作聚合物太阳能电池的阳极层;2015年,该课题组[21]以Zn(II)-5,10,15,20-四[(咔唑-9-基)苯基]卟啉为单体,通过电化学氧化聚合得到厚度为60nm 的Zn-卟啉基CMPs 薄膜,并将其用作超级电容器电极材料;2017年,他们又以1,2-双(4-(9 H-[3,6-三咔唑]-9 -基)苯基)二氮烯为单体,采用电化学氧化聚合制备了光刺激响应型的CMPs 薄膜材料[22]㊂江东林㊁Scherf 等也通过电化学氧化聚合法合成了系列咔唑基CMPs 薄膜[23,24]㊂电化学氧化聚合法具有简单易行的特点,并可以拓展材料的功能性,但是其适用的单体分子具有一定的局限性㊂2.6㊀氰基环化反应将氰基单体和ZnCl 2在离子热条件下熔融,当温度超过400ħ时即可发生腈基环化反应,可将氰基单体链接形成C 3N 3的三嗪环网络,是另一种制备富氮CMPs 的方法㊂该类CMPs 又称为共价三嗪框架(CTFs),具有一定的结晶性㊂Kuo 等[25]利用自制的1,3,6,8-四氰基芘进行环化反应制备了一种芘基CTFs(图8),该材料的比表面积最高可达1019m 2㊃g -1,具有出色的电化学性能和CO 2吸附能力,在电化学能源存储和气体吸附分离中具有很大的应用潜力㊂相对其他制备方法而言,该方法的反应条件较苛刻,不利于后期的规模化制备及功能拓展㊂图8㊀芘基共价三嗪框架的合成路径[25]Fig.8㊀Synthetic route to pyrene-CTFs [25]3㊀富氮CMPs 在能源环境领域的应用富氮CMPs 因具有较高的氮含量㊁丰富的微孔结构㊁高孔隙率㊁π-π共轭体系㊁优良的化学和热稳定性等优点,在电能㊁热能等能源储存[13,26-38]㊁光电催化产氢等能源转化[39-47]㊁CO 2存储㊁环境污染物吸附与分离[7,11,12,18,19,48-60]等领域表现出了良好的应用潜力㊂3.1㊀电化学能源存储通过合理的分子结构设计可制备出具有高比表面积的CMPs,而掺杂的氮原子可以带来额外的氧化还原电化学活性㊂因此,富氮CMPs 可同时具备双电层电容和赝电容特性,作为超级电容器电极材料用于电化学储能,具有很大优势㊂基于BH 偶联反应制备的富氮CMPs 即保留了CMPs 的微孔特性,亚胺基的引入同时赋予了CMPs 类似聚苯胺的电化学活性,而进一步通过引入其他官能团,可显著增加材料的电化学储能性质[13,26,27]㊂作者课题组[13]通过BH 偶联反应将2,6-二氨基蒽醌(DAQ)和不同芳基溴化物进行交联,合成氨基蒽醌型共轭聚合物网络,并加工成柔性电极(图9),所制备的PAQs 柔性电极具有高比电容和良好的循环稳定性㊂将PAQs 组装成不对称双电极超级电容器,在0~1.6V 的工作电位下,该电容器表现出168F㊃g-1的比电容,并且在60Wh㊃kg-1的能量密度下具有1300W㊃kg-1的功率密度㊂组装的不对称超级电容器经过2000次循环后仍可保留高达97%的库伦效率和95.5%的比电容㊂该工作在高性能电化学储能用CMPs 的网络分子设计上提出了新颖且有前途的方法㊂进一步地,为了探究不同氮结构对电化学储能性能的影响,作者课题组[26]选择了带有不同取代基的吡啶基构件作为单体,通过BH 反应合成了一种富氮共轭微孔聚三苯胺(PTPA)网络,制备的CMPs 孔隙率可调,且具备氧化还原活性㊂电化学表征结果表明,在1.0mol㊃L-1H 2SO 4中,在0.5A㊃g-1的电流密度下,使用2,5-二氨基946博看网 . All Rights Reserved.中国材料进展第40卷图9㊀PAQs电极在0.5mol㊃L-1H2SO4中不同电流密度下的电化学存储容量曲线(a),2A㊃g-1电流密度下PAQs电极的电化学存储稳定性(b),PAQs电极组装的超级电容器阵列(c)[13]Fig.9㊀Specific capacitance of PAQs electrodes obtained at different current densities conducted in0.5mol㊃L-1H2SO4(a),electrochemical storage stability of PAQs electrodes(2A㊃g-1)(b),photograph of PAQs electrodes asymmetric supercapacitor arrays(c)[13]吡啶二盐酸盐制得的PTPA-25共轭微孔聚合物显示出最高的比电容,达到335F㊃g-1,并且具有出色的循环稳定性㊂利用BH反应,Patra等[28]制备了一种苯胺/芘连接的共轭微孔聚合物(pyrene aniline-based CMP,PYBDA),也表现出了良好的电化学存储性能㊂三嗪环网络中含有大量氮原子,以三嗪基化合物为原料,也可得到具有高比表面积和比电容的富氮CMPs㊂Bhaumik等[29]通过1,3,5-三(4-氨基苯基)三嗪与2,6-二甲酰基-4-甲基苯酚的溶剂热席夫碱缩合反应制备了一种新型CMPs,表现出了极好的能量存储能力㊂Dutta 等[30]在高温下合成了富含氮原子的三嗪基聚酰亚胺框架(TPI-P/TPI-N),其中TPI-P-700氮含量高达6.3% (质量分数),比表面积可达1650m2㊃g-1,其组装的对称超级电容器在0.5A㊃g-1的电流密度下能量密度为10.5Wh㊃kg-1㊂Wei等[31]用合成的三嗪基CMPs与石墨烯气凝胶复合,制备出的N-GA/CMPs具有更高的含氮量,其组装的超级电容器能量密度可得到进一步提高㊂与三嗪环结构相似,三苯胺基衍生物也具有星形结构㊂Zhang等[32]通过Suzuki反应和FeCl3化学氧化聚合反应合成了三苯胺基CMPs,其充放电速率快且循环稳定性好,可用于锂离子电池的正极材料㊂此外,作者课题组[33]利用Chichibabin交叉偶联反应,不添加金属催化剂,利用芳香醛和酮为单体㊁乙酸铵为氮源合成了吡啶基CMPs,即PCMPs㊂以PCMPs为前驱体,碳化得到氮掺杂多孔炭微球材料(NCM),比表面积高达1232m2㊃g-1㊂此NCM作为超级电容器电极材料时,表现出高的比电容和高功率密度㊂随着研究的进行,柔性可穿戴电子器件逐渐走进了人们的视野,为了满足人们对可穿戴电子设备小型化㊁灵活性和兼容性不断增长的需求,供能器件的柔性和可穿戴性成为了新的挑战[61]㊂由于其柔性和可编织性,一维纤维状超级电容器(FSCs)得到了广泛的关注[62]㊂在前有研究的基础上,作者课题组[27]通过BH反应在溴功能化的碳纳米管纤维(CNF)上进行CMPs的原位交叉偶联聚合,首次制备了宏观尺度的纤维状CMPs,即CNF@CMPs,该材料在1mA㊃cm-2电流密度下表现出高面积比电容(671.9mF㊃cm-2)㊂以CNF@CMPs作为电极,PVA/H3PO4为凝胶电解质,制备得到了全固态对称扭曲纤维状CNF@PTPA对称超级电容器,其在0.28mA㊃cm-2电流密度下,具有高面积比电容(398mF㊃cm-2);在1.4V的最大工作电压下,表现出高能量密度(18.33μWh㊃cm-2)㊂该纤维状对称超级电容器具有出色的柔韧性和机械稳定性,在10000次弯曲循环后,可保留初始比电容的84.5%㊂该研究为高性能可穿戴超级电容器(HPWS)的制备提供了一个新思路(图10)㊂056博看网 . All Rights Reserved.㊀第9期滕砺宽等:能源环境用富氮共轭微孔聚合物材料研究进展图10㊀对称纤维状超级电容器(FSCs)的制备示意图(a),CNT@CMPs 的合成示意图(b),FSCs 编织表带点亮手表的照片(c)及FSCs 十字绣点亮发光二极管的照片(d)[27]Fig.10㊀Schematic illustration of the fabrication for symmetrical fiber-shaped supercapacitors (FSCs)(a),synthetic route of CNT@CMPs(b),photographs of a knitted watchband containing FSCs powering a digital watch (c),photographs of a cross-stitched logo con-taining FSCs powering LED bubbles (d)[27]3.2㊀相变储热近年来,为了解决能源危机这一全球性问题,以减少化石燃料的消耗为目标,除了电化学器件,热能存储材料也得到了广泛的关注[63]㊂其中相变材料(phase change materials,PCMs)是潜热储能系统中最有效的储能系统之一㊂相变储热材料的机理是通过在发生相变过程中的吸热和放热来实现存储和释放热能,因具有储热密度高且在充放热过程中温度可控的优点,受到研究者的广泛关注[64],目前相变材料已经充分应用在太阳能存储[65]和建筑节能[66]等领域中㊂然而,在相变过程中熔融的PCMs 泄露问题严重限制了其应用性,为了解决这一问题,使用多孔材料的封装技术来制备形状稳定的PCMs 是一种有效方法[67]㊂作者课题组在2017年首次采用富氮多孔聚合物(N-POP)封装1-十八烷醇(ODA ),解决了相变材料泄露问题(图11a)[34]㊂富氮卟啉基多孔聚合物能够吸收红外光并将其转化为热能,具有优异的光热性质㊂以之为PCMs 的封装材料在某种程度上可显著提高材料的热稳定性㊂2021年,作者课题组[35]采用Diels-Alder 反应制备得到最高比表面积为650m 2㊃g -1的卟啉-二茂铁基富氮CMPs(PFCMP)(图11b),封装ODA 后所得的复合材料ODA@PFCMP 具有153.8J㊃g-1的高熔融潜热(图11c),并且具有长达425s 的储热稳定时间㊂采用多孔炭对PCMs 进行封装不仅可以有效防止PCMs 泄漏,并且在某种程度上可提高热传导效应[36]㊂研究表明,对多孔炭材料进行氮原子掺杂可有效改变材料的结构性质,进而提高封装PCMs 的形状稳定性和热传导效应[37]㊂设计合成富氮CMPs 则是制备氮掺杂多孔炭的一种有效途径㊂2020年,作者课题组[38]通过BH 反应制得螺旋芴和苯胺连接的CMPs(SACMPs)㊂以之为前驱体,热解得到高比表面积的多孔空心炭球(HCSPs),并对ODA 相变材料进行了有效的包封(图11d 和11e)㊂所得到的HCSPs /ODA 具有180~190J㊃g-1的高熔融潜热,加热速率与纯ODA 相当,并且具有良好的形状稳定性和热循环稳定性(图11f),有望应用于太阳能光热转化工程中㊂156博看网 . All Rights Reserved.中国材料进展第40卷图11㊀富氮多孔聚合物封装1-十八烷醇储热示意图(a)[34];卟啉-二茂铁基富氮共轭微孔聚合物的合成路径(b)及其封装1-十八烷醇的复合材料的热红外照片(c)[35];多孔空心炭球/1-十八烷醇复合物的合成路径(d),多孔空心炭球的TEM 照片(e),复合物的热红外照片(f)[38]Fig.11㊀Scheme showing the heat storage of ODA encapsulated by N-POP (a)[34];synthetic route to PFCMP (b)and the thermal infrared photosof composite material of ODA encapsulated by PFCMP (c)[35];synthetic route to HCSPs /ODA composite (d),TEM image of HCSPs(e),thermal infrared photo of HCSPs /ODA composite (f)[38]3.3㊀光催化制氢氢气燃烧无污染㊁释放热量高,是一种可替代化石燃料的绿色清洁燃料㊂作为可再生能源,氢气可通过光催化分解水获得㊂光催化析氢材料的研究主要集中在氮化碳材料或无机半导体材料上,但这些材料通常仅在紫外光区域展现出光催化活性,对可见光利用率低㊁活性较差[68,69]㊂CMPs 具有半导体特性,且氮的掺杂可对其电子结构进行调控,因此可以合理设计得到在可见光下具有一定光催化产氢活性的富氮CMPs [70]㊂Cooper 等[39]合成了一系列无定形的CMPs,比表面积最高可达1700m 2㊃g -1,在可见光下,无需添加金属助催化剂就可以进行光催化产氢㊂通过调整聚合单体结构,可以有效调控CMPs 的带隙宽度,赋予其可见光吸收的能力,与其它光催化剂相比具有显著的优势㊂该课题组[40]在低温下合成了一种具有层状结构的CTFs,在可见光下分解水析氢的速率最高可达2647μmol㊃g -1㊃h -1㊂此后,他们又通过Suzuki 反应合成了结构多样的系列CTFs,研究发现催化剂中残留的钯可以提高光催化活性㊂其中,采用2,5溴-苄腈单体合成的CTFs 光催化析氢速率最高,高达2946μmol㊃g -1㊃h-1[41]㊂任世杰等[42]通过Suzuki 偶联反应分别合成了具有噻吩单元和芴单元的4种三嗪基共轭微孔聚合物(TCMPs)㊂研究表明,TCMPs 具有较大的比表面积和与光催化分解水相匹配的光学带隙㊂该研究表明,通过改变功能单元结构和连接体的长度可以有效改变聚合物的能带带隙,进而调节聚合物的产氢性能㊂Yu 等[43]发现联吡啶基团的加入可提高CMPs 对可见光的吸收,进而显著提高CMPs 的光催化活性㊂作者课题组[16]通过芳基醛和酮之间的Chichibabin 反应合成了PCMPs,反应过程中不添加任何金属催化剂,合成快速且成本低廉㊂PCMPs 的电子结构适合可见光驱动水分解产氢,为开发新型绿色低廉聚合物光催化剂的制备提供了新思路㊂Xiang 等[44]设计了含双吡啶基团的CMPs (COP-PB-N2),双吡啶结构能够降低氢吸附和活化的能垒(图12a 和12b)㊂研制的COP-PB-N2的表观量子产率可达1mg㊃mL -1,是迄今为止CMPs 可达到的最高值㊂Maji 等[45]选用三(4-氨基苯基)胺(TAPA)和不同取代基的对苯撑乙炔(OPE)基于席夫碱反应合成了两种新型具有氧化还原活性的富氮CMPs (TAPA-OPE-mix 和TAPA-OPE-gly)(图12c)㊂两种富氮CMPs 对电催化还原O 2和光催化制H 2都显示出良好的多相催化活性和循环稳定性㊂此外,两种富氮CMPs 的氧化还原活性可用于铂纳米粒子的原位生成和固定,并且这些Pt@CMPs 表现出显著增强的光催化活性(图12d 和12e)㊂2021年,作者课题组[46]首次利用吡啶基PCMPs 锚定非贵金属Ni 或Co 原子,构建了单原子光催化剂(图13)㊂所制备的Ni@PCMPs 和Co@PCMPs 光催化剂具有适合可见光催化析氢活性的电子结构㊂其中,30%Co@PCMPs 的光催化析氢活性最高,析氢速率为1.72mmol㊃g -1㊃h -1,是纯PCMPs 的2倍,并具有良好的稳定性㊂这一研究为能源环境相关的CMPs 负载非贵金属单原子光催化剂的设计合成及制备提供了一种新的思路㊂256博看网 . All Rights Reserved.。

中考英语人教版 中考题型专题 题型专题二 阅读理解 (3)

中考英语人教版 中考题型专题 题型专题二 阅读理解 (3)

D.
【技巧 4】标题归纳 (1)注意文中的核心及高频词汇; (2)根据文章的主题句提炼出标题。
(C)4.What would be the best title for the A.How Do We Protect Our Planet? B.What Are the Fuels' Differences? C.What Is the Best Fuel for Cars? D.How Do We Make Fuels for Cars?
标题归纳题:此 2 句定位第 4 题,由此 2 句可知,文章讨论的是哪 种原料最好。故选 C。
【文章大意】文章主要介绍了几种不同的“燃料”:汽油、电和其他 液体燃料的作用及其优缺点等。总结出环境友好型以及价格合适的燃料 是最适合使用的。
【解题技巧】 【技巧 1】细节理解
读懂题干,根据其中的关键信息,运用略读、扫读、跳读的方法, 在文章中寻找相关语句;与题干仔细核对,选出正确答案。 (A)1.Gasoline provides cars with ______. A.great power B.fresh air C.clean water D.enough space
The other choices are other liquid fuels.Many of these can be stored in the same places as gasoline,and used in the same cars.They can also be friendly to the environment.
For a fuel to be the best,people have to be able to afford it.Unluckily,almost every green technology is more expensive than that of using ernments and car producers are doing everything they can to cut down the costs.In the end,the best fuel will be both affordable for car users and green for our planet. ↓

高三英语非谓语动词完成高级单选题40题

高三英语非谓语动词完成高级单选题40题

高三英语非谓语动词完成高级单选题40题1.Protecting the environment by using new energy sources is of great importance. The underlined part is the main structure of the sentence, and the function of the gerund phrase “Protecting the environment by using new energy sources” is _____.A.subjectB.objectC.predicateD.adverbial答案:A。

本题中“Protecting the environment by using new energy sources”在句中作主语,动名词短语作主语。

选项B“object”宾语;选项C“predicate”谓语;选项D“adverbial”状语。

2.Developing artificial intelligence technology requires a lot of efforts. The function of the gerund phrase “Developing artificial intelligence technology” in this sentence is _____.A.subjectB.objectC.predicateD.adverbial答案:A。

“Developing artificial intelligence technology”在句中作主语,动名词短语作主语。

选项B 宾语是动作的对象;选项C 谓语是表示动作或状态的部分;选项D 状语用来修饰动词、形容词、副词等。

3.Understanding the importance of sustainable development is crucial for our future. The gerund phrase “Understanding the importance of sustainable development” acts as _____.A.subjectB.objectC.predicateD.adverbial答案:A。

高中英语真题-2014高考英语阅读理解抓分训练(72)及答案

高中英语真题-2014高考英语阅读理解抓分训练(72)及答案

高中英语真题:2014高考英语阅读理解抓分训练(72)及答案阅读理解There’s an energy crisis in America, and it has nothing to do wit h fossil fuels. Millions of us get up each morning already weary over the day holds. “I just can’t get started.” People say. But it’s not physical energy that most of us lack. Sure, we could all use extra sleep and a better diet. But in truth, people are healthier t oday than at any time in history. I can almost guarantee that if y ou long for more energy, the problem is not with your body. What you’re seeking is not physical energy. It’s emotional energ y. Yet, sad to say life sometimes seems designed to exhaust ou r supply. We work too hard. We have family obligations (义务). We encounter (遭遇) emergencies and personal crises. No wonder so many of us suffer from emotional fatigue (疲劳), a kind of utter exhaustion of the spirit.And yet we all know people who are filled with joy, despite the u npleasant circumstances of their lives. Even as a child I observ ed people who were poor or disabled or ill, but who nevertheles s faced life with optimism and vigor (活力). Consider Laura Hillenbrand, who despitean extremely weak body wrote the best-seller Seabiscuit. Hillenbrand barely had enough physical energ y to drag herself out of bed to write. But she was fueled by havi ng a story she wanted to share. It was emotional energy that he lped her succeed. Unlike physical energy, which is finite (有限的) and diminishes (减少) with age, emotional energy is unlimited and has nothing to d o with genes or upbringing. So how do you get it? You can’t sim ply tell yourself to be positive. You must take action. Here are si x practical strategies that work.1. Do something new.Very little that’s new occurs in our lives. The impact of this sam eness on our emotional energy is gradual, but huge: It’s like a ti re(轮胎) with a slow leak(漏). You don’t notice it at first, but eventually you’ll get a flat. It’s up to you to plug the leak—even though there are always a dozen reasons to stay stuck in your dull routines of life. That’s where Maura, 36, a waitress, fo und herself a year ago. Fortunately, Maura had a lifeline—a group of women friends who meetregularly to discuss their lives. Their lively discussions spurred Maura to make small but nevertheless life altering changes. She joined a gym in the next town. She changed her look with a short haircut and new black T-shirts. Eventually, Maura gathered the courage to quit her job a nd start her own business. Here’s a challenge: If it’s something you wouldn’t ordinarily do, do it. Trya dish you’ve never eaten. Listen to music you’d ordinarily tune out. You’ll discover these small things add to your emotional en ergy.2. Reclaim life’s meaning.So many of my patients tell me that their lives used to have me aning, but that somewhere along the line things went stale (厌倦的). The first step in solving this meaning shortage is to figure o ut what you really care about, and then do something about it.A case in point is Ivy, 57, a pioneer in investment banking. “I mi stakenly believed that all the money I made would mean somet hing.” she says. “But I feel lost, like a 22-year-old wondering what to do with her life.”Ivy’s solution? She start ed a program that shows Wall Streeters how to donate time and money to poor children. In the process, Ivy filled her life with m eaning.3. Put yourself in the fun zone.Most of us grown-ups are seriously fun-deprived(缺乏的). High-energy people have the same day-to-day work as the rest of us, but they manage to find something e njoyable in every situation. A real estate broker I know keeps h erself amused on the job by mentally redecorating the houses s he shows to clients(客户). “I love imagining what even the most run-down house could look like with a little tender loving care,” she says. “It’s a challenge—and the least desirable properties are usually the most fun.” We all define fun differently, of course, but I can guarantee this: If y ou put just a bit of it into your day, you energy will increase quic kly4. Bid farewell (告别)to guilt and regret.Everyone’s past is filled with regrets that still cause pain. But fro m an emotional energy point of view, they are dead weights tha t keep us from moving forward. While they can’t merely be wille d away, I do recommend you remind yourself that whatever hap pened in the past, nothing can change that. Holding on to the m emory only allows the damage to continue into the present.5. Make up your mind]Say you’ve been thinking about cutting your hair short. Will it lo ok stylish—or too extreme? You endlessly think it over. Having the decisionhanging over your head is a huge energy drain. Every time you can’t decide, you burden yourself with alternatives. Quit thinkin g that you have to make the right decision; instead, make a choi ce and don’t look back.6. Give to get.Emotional energy has a kind of magical quality: the more you gi ve, the more you get back. This is the difference between emoti onal and physical energy with the latter. You have to get it to be able to give it. With the former, however, you get it by giving it. Start by asking everyone you meet, “How are you?” as if you re ally want to know, and then listen to the reply. Be the one who h ears. Most of us also need to smile more often. If you don’t smil e at the person you love first thing in the morning, you’re suckin g energy out of your relationship. Finally, help another person—and make the help real, concrete. Give a massage to someone you love, or cook her dinner, then, expand the circle to work. Tr y asking yourself what you’d do if your goal were to be helpful r ather than efficient. After all, if it’s true that what goes around co mes around, why not make sure that what’s circulating around y ou is the good stuff?16. Laura Hillenbrand is an example quoted to show how _____ ___ in life.A. physical energy can contribute to one’s unsuccessB. emotional energy can contribute to one’s successC. physical energy can contribute to one’s successD. emotional energy can contribute to one’s unsuccess17. The author believes emotional energy is ________.A. inherited and genetically determinedB. related to inherite d and genesC. not inherited and genetically determinedD. related to inher ited and upbringing18. Even small changes people make in their lives ________ the ir emotional energy.A. cannot help controlB. cannot help increaseC. can help controlD. can help increase19. Ivy filled her life with meaning by launching a program to __ ______.A. help herselfB. teach herselfC. teach poor children D . help poor children20. The real-estate broker the author knows enjoyed ________.A. redecorating the housesB. mentally redecorating the housesC. the same day-to-day workD. defining fun differently参考答案 BCDDB(2012·四川眉山一诊)Cheating is nothing new.But today, educators and administrator s are finding that instances of academic dishonesty on the part of students have become more frequent and are less likely to b e punished than in the past .Cheating appears to have gained a cceptance among good and poor students alike.Why is student cheating on the rise? No one really knows .Som e blame the trend on a general loosening of moral values amon g today's youth.Others have attributed increased cheating to th e fact that today's youth are far more pragmatic(实用主义的) than their more idealistic predecessors(前辈).While in the late sixties and early seventies, students were filled with visions about changing the world, today's students fe el great pressure to conform(随大流) and succeed.In interviews with students at high schools and colleges around the country, both young men and women said that cheating had become easy.Some suggested they did it out of spite for teachers they did not respect; others looked at it as a game.Only if they were caught, some said, would they feel guilty.“People are competitive.” said a secondyear college student named Anna, from Chicago.There's an underlying fear .If you d on't do well, your life is going to be ruined .The pressure is not o nly from parents and friends but from yourself.To achieve.To su cceed.It's almost as though we have to outdo other people to ac hieve our own goals.Edward Wynne, editor of a magazine blames the rise in acade mic dishonesty on the schools.He claims that administrators an d teachers have been too hesitant to take action.Dwight Huber, chairman of the English department at Amarillo sees the matter differently, blaming the rise in cheating on the way students are evaluated.“I would cheat if I felt I was being cheated,” Mr.Hub er said.He feels that as long as teachers give shortanswer tests rather than essay questions and rate students by the number o f facts they can memorize rather than by how well they can com bine information, students will try to beat the_system. “The conc ept of cheating is based on the false assumption that the syste m is reasonable and there is something wrong with the individu al who's doing it,” he said, “That's too easy an answer.We've got to start looking at the system.”文章大意:本文对越来越多的学生作弊现象进行了剖析。

紫杉醇及其衍生物的半合成概述

紫杉醇及其衍生物的半合成概述

紫杉醇及其衍生物的半合成概述邓夏萌;曹辉;沈海伟;钟光祥;夏春年【摘要】紫杉醇是第一个被发现能促进微管蛋白聚合的天然产物,是近20年来最成功的抗癌药物之一.简单叙述了紫杉醇的发现和历史、来源和作用机理.目前紫杉醇的合成方法有紫杉醇的其他植物资源、紫杉烷植物细胞悬浮培养、生物合成、真菌培养、全合成与半合成等方法,目前真正用于实际工业化生产紫杉醇的方法是半合成方法,着重总结了半合成的研究进展.%Taxol is a natural product drug which promotes the polymerization of tubulin. The source, pharmacological mechanism and the synthesis of taxol were introduced in this paper. At present, the extraction of natural yew plants, suspension culture of taxane plants, biosynthesis, fungal fermentation, total synthesis and semi-synthesis are the main source of taxol. Semi-synthesis is the method for the industrial production of taxol, the research progress of semi-synthesis was mainly introduced.【期刊名称】《浙江化工》【年(卷),期】2018(049)005【总页数】8页(P1-8)【关键词】紫杉醇;半合成;作用机理【作者】邓夏萌;曹辉;沈海伟;钟光祥;夏春年【作者单位】浙江工业大学药学院, 浙江杭州 310014;宁波绿之健药业有限公司,浙江宁波 315505;浙江工业大学药学院, 浙江杭州 310014;浙江工业大学药学院, 浙江杭州 310014;浙江工业大学药学院, 浙江杭州 310014【正文语种】中文紫杉醇(Paclitaxel,TaxolR,图 1)的发现在天然产物的研究中是具有里程碑意义的重大事件。

高三英语阅读理解细节理解题单选题30题

高三英语阅读理解细节理解题单选题30题

高三英语阅读理解细节理解题单选题30题1. What is the main purpose of the new technology mentioned in the passage?A. To increase productivity.B. To save energy.C. To improve quality.D. To reduce costs.答案:B。

本题考查对文中新技术主要目的的理解。

原文提到新技术主要是为了节能,A 选项提高生产力未提及,C 选项提高质量并非主要目的,D 选项降低成本文中未明确说明。

2. How many experiments have been conducted on the new material?A. Five.B. Three.C. Two.D. Four.答案:A。

文中明确指出对新材料进行了五次实验,B 选项三次、C 选项两次、D 选项四次均与原文不符。

3. When was the first prototype of the device developed?A. Last year.B. Two years ago.C. Three years ago.D. Five years ago.答案:C。

原文提到该设备的第一个原型是在三年前开发的,A 选项去年、B 选项两年前、D 选项五年前均错误。

4. Which of the following is NOT a feature of the advanced system?A. High speed.B. Large capacity.C. Simple operation.D. Low cost.答案:D。

文中未提及该先进系统具有低成本这一特征,A 选项高速、B 选项大容量、C 选项操作简单均有提及。

5. What is the main challenge faced by the research team?A. Lack of funds.B. Technical difficulties.C. Shortage of staff.D. Intense competition.答案:B。

  1. 1、下载文档前请自行甄别文档内容的完整性,平台不提供额外的编辑、内容补充、找答案等附加服务。
  2. 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
  3. 3、如文档侵犯您的权益,请联系客服反馈,我们会尽快为您处理(人工客服工作时间:9:00-18:30)。

A New Energy Efficient Approach by Separating Data Collection and Data Report in Wireless Sensor NetworksYuning HeGraduate School of Systems and Information Engineering,University of Tsukuba,Tsukuba, Ibaraki305-8573,JapanY ongbing ZhangGraduate School of Systems and Information Engineering,University of Tsukuba,Tsukuba, Ibaraki305-8573,JapanYusheng JiNational Institute of Informatics,Chiyoda-ku, Tokyo101-8430,JapanXuemin(Sherman)Shen Department of Electrical and Computer Engineering,University of Waterloo,Ontario,CanadaABSTRACTA sensor network consists of a large number of distributed wireless sensors which are equipped with low power wireless transceivers. Network lifetime,scalability,and load balancing are important re-quirements for many data gathering sensor network applications. Network clustering is an effective approach for achieving these goals wherein sensors are grouped into multiple clusters.Multi-hop data transmission may provide efficient energy conservation further.A sensor in a cluster may work as a cluster head for data gathering,aggregation,and report to the base station(BS).These tasks can also be performed by distinct sensors in the same clus-ter.In this paper,we clarify some characteristics of multi-hop data transmission.Furthermore,we propose a new data gathering ap-proach for single-hop transmission wherein both the data gathering and the aggregation are performed by the same sensor in a cluster but the report to the BS may be done by a different sensor.The simulation results show that the proposed algorithm achieves better performance than other existing algorithms.Keywordssensor networks,energy efficiency,network lifetime,network clus-tering.1.INTRODUCTIONAdvantages in sensor technology,low-power electronics,and low-power radio frequency(RF)design have enabled the develop-ment of small,relatively inexpensive and low-power sensors,called microsensors,which can be connected via a wireless network[1, 2,3].These sensor nodes(or simply nodes)are usually deployed randomly and densely in hostile environment.They collaborate to observe the surroundings and send the information back to the net-Permission to make digital or hard copies of all or part of this work for personal or classroom use is granted without fee provided that copies are not made or distributed for profit or commercial advantage and that copies bear this notice and the full citation on thefirst page.To copy otherwise,to republish,to post on servers or to redistribute to lists,requires prior specific permission and/or a fee.IWCMC’06,July3–6,2006,Vancouver,British Columbia,Canada. Copyright2006ACM1-59593-306-9/06/0007...$5.00.work manager(or base station)when abnormal events occur.For example,sensor networks can play an essential role in emergency situation such asfires,building collapses or extreme weather phe-nomena.Since battery replacement is not an option for networks with thousands of physically embedded nodes,an efficient energy saving protocol is required to prolong the sensor network lifetime [4,5].Network lifetime can be defined as the time elapsed from the network operation starts until thefirst node(or the last node)in the network depletes its energy(dies).Energy consumption in a node can be due to either”useful”or”wasteful”operations.The useful energy consumption includes transmitting or receiving data messages,and processing query requests.On the other hand,the wasteful consumption can be due to overhearing,retransmitting be-cause of harsh environment,dealing with the redundant broadcast overhead messages,as well as idle listening to the media.In order to save the transmission power,clustering[6,7],and multi-hop tranmission techniques[1]can be used.Adjacent sensors may sense the same data and therefore the data gathering can re-duce the redundant data collection.Sensors close to each other in the network can be grouped into clusters and data obtained from sensors in the same cluster are aggregated and then reported to the base station(BS).Data report to the BS can be performed by single-hop or multi-hop transmission.The collected data is directly trans-mitted to the BS in the former approach while via multiple inter-mediate sensors in the latter.Even though the multi-hop transmis-sion may lead to more power saving,it is more difficult to imple-ment.To the best of our knowledge,there is no efficient multi-hop transmission method until now.In this paper,we explore some characteristics of multi-hop transmission and propose a more ef-ficient single-hop transmission approach than existing ones.The data gathering,aggregation,and the report to the basestation(BS) can all be performed by a single node and this node is called the cluster head.Many clustering algorithms in this type have been proposed for wireless sensor networks[8,9,10,11].Heinzelman et al.[8]proposed a two-phase mechanism,called LEACH,based on single-hop transmission.Each node becomes a cluster head ac-cording to a certain probability.Non-head nodes choose the closest cluster to join.Any node is required to be able to communicate with any other node directly.Younis and Fahmy[9]proposed a distributed energy-based clustering algorithm,called HEED,which has been extended from LEACH by using cluster range limits andcost information.It is assured in HEED that a node with more en-ergy has more opportunity to be chosen as a cluster head,as well as cluster heads are distributed well over the area.Other clustering-based algorithms such as VCA[10]and EECS[11]can also be found in the literature.Clustering algorithms require re-clustering after a period of time (called round)and there are mainly two tasks during each re-clusteringprocess.One task is to receive and aggregate the messages from the non-head nodes,and the other is to transmit the aggregated data di-rectly to the BS.In the above algorithms,the cluster head plays an important role and the two tasks are all performed by the cluster head.The main disadvantage of those algorithms is that the cluster head may be the”best”node to collect data in a cluster but maynot be the”best”node to send the collected data to the BS.There-fore,it may be preferable to assign the two tasks to distinct nodes in order to reduce the energy consumption.In this paper,we pro-pose a new energy efficient clustering algorithm wherein the data gathering and aggregation are performed by one node,called the collector,while the report to the BS may be performed by another node,called the forwarder.The node for data aggregation and for report to the BS are determined based on the energy consumption and the data transmission distance to the BS.The paper is organized as follows.In Section2,we introduce the network model used in the paper.Multi-hop data transmission from a sensor to the BS is discussed here.Details of our proposedalgorithm are described in Section3.We evaluate the performance of our approach by simulation in Section4.In Section5,we sum-marize the concluding remarks of the paper.2.PROBLEM OUTLINEData gathering is a typical application in wireless sensor net-works.Sensor nodes monitor the environment and periodically transmit the sensed data to the BS.The BS gathers the messages from the sensors to draw some conclusions about the conditions of the service area,and broadcasts control messages to sensors in the network.In this section,we introduce the sensor network model under consideration.2.1Network ModelThe network model is basically similar to those in LEACH[8] and HEED[9].The nodes are grouped into small clusters.The sensed data in a cluster are gathered at a pariticular node and then sent to the BS directly or via multiple intermediate nodes.Unlike existing algorithms,the data gathering and aggregation in the pro-posed algorithm are performed by the same node,called the clustercollector(or simply collector),while the report to the BS can beperformed by another node,called the cluster forwarder(or sim-ply forwarder).We assume that nodes are uniformly dispersed in the service area of the network,and are quasi-stationary in the sense that they do not change their locations once deployed.Furthermore,the nodes are location-unaware and have the same characteristics. We also assume that data aggregation technique is available,and data collected from sensors in a cluster is packed into one packet. Table1lists the parameters and their definitions used in this pa-per.We use a simple model for the radio hardware energy dissi-pation.The energy consumptions for sending and for receiving anl-bit message are denoted by E t(l)and E r(l),respectively,and they are assumed to be equal and determined by the hardware factors, that is,E t(l)=E r(l)=lY.The energy consumption required to amplify the radio signal in order to send an l-bit message to a loca-tion with distance d away is denoted by E a(l,d).It is well-known that the transmission power depends on the environment and thetransmission distance.In this paper,two parametersε1andε2are used to indicate the amplification factors for different transmission distance.When the transmission distance d is less than a given threshold d0,that is,if d<d0,ε1is used,otherwiseε2is used.Ad-ditionally,the energy consumption for data aggregation is denoted by E g.Furthermore,energy needed to transmit an l-bit message to a location with a distance d away is given by:E t(l,d)=E t(l)+E a(l,d)=l(Y+ε1d2)d<d0,l(Y+ε2d4)d≥d0.(1)The energy consumption for receiving an l-bit message is given as follows.E r(l)=lY.(2)Table1:Meanings of the parametersTerm Definition UnitE t Energy dissipation rate to send the signals J/bitE r Energy dissipation rate to receive the signals J/bitd0Threshold distance for E a mE a Energy dissipation rate at the transmit amplifier J/bit/m2J/bit/m4E g Energy dissipation rate for data aggregation J/bit/signal N Total number of sensor nodesv i The i th sensor node(1≤i≤N)E i Energy dissipation rate from v i to the BS J/bite i Residual energy of sensor v i JR c Cluster radius mR t Inter-cluster transmission radius m2.2Problem StatementA typical clustering algorithm consists of four components:net-work clustering,channel assignment,data collection,and data re-port.The network clustering component divides nodes in the net-work into clusters.The channel assignment component determines the channel used for data transmission in each cluster.The data collection component is used for gathering and aggregating data in a cluster.Finally,the data report component is used for sending the compressive data to the BS.Most of the existing algorithms fo-cus on thefirst component.Specifically,they consider the way to choose cluster heads as well as achieve the clusters well-balanced over the network.The differences among the clustering algorithms (such as LEACH[8],HEED[9],and VCA[10])are in the cluster forming period.After the formation of clusters,all the algorithms execute the same following components.In this paper,the cluster forming method is the same as the existing approaches,but a dif-ferent method for data reporting to the BS is developed to prolong the network lifetime.In most distributed clustering algorithms,a cluster head node does not only receive and aggregate data from member nodes,but also transmits the compressive data to the BS.Since the energy consumption is quite concentrated on the head node,it causes tra-ditional cluster algorithms unsatisfied in some conditions.For ex-ample,as shown in Figure1,four sensors have the same cluster radius.Both A and C have1J energy,while B and D have2J and 3J energy,respectively.Nodes A,C and D are within the commu-nication range of B.However,A,C and D can not communicateFigure 1:The traditional clustering algorithm.with each other directly.In this case,node B is the most suitable to be the head,because data fusion can be performed by B and only one piece of message needs to be delivered to the distant BS.How-ever,compared to node D,node B is not suitable for transmitting the compressive message,because D has more residual energy and is nearer to the BS.2.3Data Transmission to the Base Station(a)Single-hop method.(b)Multi-hop method.Figure 2:Single-hop and multi-hop data transmission.We can consider two distinct approaches to transmit the collected data from a cluster to the BS as shown in Figure 2.In the figure,the collectors and forwarders of clusters are denoted by the gray and the black nodes,respectively,while the other nodes are de-noted by the white nodes.One of the communication methods is single-hop transmission,that is,each cluster transmits the collected data directly to the BS.This approach is simple to implement but clusters far from the BS have to consume much energy.The other is multi-hop transmission,that is,a cluster can transmit the collected data to the BS via multiple intermediate forwarders.In this section,we investigate the multi-hop transmission in details.Younis et al.[9]considered a sensor network with N nodes.They divided the network into n square cells each with a cell side length of R c /√2,where R c denotes the transmission range of a cluster.They showed that each cell contains at least one node when N and n become infinite.In this paper,we consider the same assumptions as in [9].Furthermore,we assume that no collector is located in the coverage of another collector,even though the sevice areas of two collectors may overlap.In the following,we first introduce two Lemmas and then derive two theorems.L EMMA 1.If the inter-cluster transmission range satisfies the condition R t ≥2.8R c ,a cluster collector can find at least one other collector within the transmission radius R t .Proof.According to the assumptions in [12,9],if the the node density of the network area is large enough,there exists at least onenode in any square cell with side length of R c /√2.Let us consider a situation shown in Figure 3where there are two cluster collectors,A and B .Let a square cell tangent to the cluster area centered at A with a side length of R c /√2as shown in the figure.According to [12],there must exist a node in the square cell.Assume that node v belongs to the cluster centered at B and is located at the boundary of cluster B .Let us consider the case where node v is located at the right bottom of the cell,which is the farthest point in the cell from collector A .Then,the Euclidean distances among A ,B ,and v satisfy the following relation.A −B ≤ A −v + v −B=(1+1√2)2+(12√2)2×R c +R c ≈2.8R c.Figure 3:Minimum transmission range for inter-cluster com-munication.We see that the distance of 2.8R c indicates the farthest distance between the neighboring cluster collectors,A and B.Therefore,if R t ≥2.8R c ,there is no isolated cluster collector in the network.L EMMA 2.The network graph of the cluster collectors is con-nected if R t ≥2.8R c .Figure 4:Minimum transmission range for inter-cluster com-munication.Proof.If we can prove that any two collectors are connected when the transmission radius between two cluster collectors R t is just equal to 2.8R c ,then we can prove the lemma.Now,we choose two collecters arbitrarily,H 1and H 2.If H 1−H 2 ≤2.8R c ,H 1and H 2are connected directly,since R t =2.8R c .Let us consider the case when H 1−H 2 >2.8R c as shown in Figure 4.We can draw a square area with side length of R c /√2,which is not tangent to but very close to the area centered at H 1.Therefore,there must exist a node v in the square area and it does not belong to H 1or H 2.Assuming that node v belongs to the cluster centered at H 3,we have H 1−H 3 ≤2.8R c .Therefore,H 1is connected with H 3.Since no two collectors are within each other’s range,we have H 3as shown in Figure 4that indicates the farthest point from H 2.We see that H 2−H 3 ≈2.7R c ,when H 1−H 2 =2.8R c .Therefore,we can find a collector H 3for H 1that is connected to H 1and is nearer to H 2.By using the similary way,we can find another collector that is connected to H 3and is closer to H 2if H 2−H 3 >2.8R c .Since the distance between H 1and H 2is limited,we can finally find a collector that is connected with H 1,and directly connected to H 2.Therefore,H 1and H 2is connected.In order to realize the multi-hop transmission from a cluster to the BS,the network graph of the cluster forwarders should be con-nected.We define R tas the transmission radius between two for-warders.In the following theorem,we give the condition under which the forwarders in the network are connected.T HEOREM 1.The network graph of the cluster forwarders is connected if the transmission range between forwarders satisfiesthe condition R t ≥4.8R c .Proof.In Lemma 2we see that all the collectors are connected ifR t ≥2.8R c .Therefore,the forwarders are connected ifR t≥R t +2R c ≥2.8R c +2R c =4.8R c .Let m denote the shortest distance from the BS to the nearest point of the sensor service area.In the following,we derive the conditions under which sensors are able to reach to the BS.T HEOREM 2.When the maximum transmission power level of sensor nodes is stronger than max {4.8R c ,m +2.8R c },all the nodes can deliver the data to the BS using multi-hop communication.Figure 5:The maximum transmission range to the BS.Proof.In Figure 5,we see that there is at least one node in the semicircle area,or else a blank (R c /√2×R c /√2)size of cell ex-ists.The maximum distance from the BS to the nearest forwarder is given by:BS −f orwarder ≤m +√104R c +2R c≈m +2.8R c .(3)That is,if the transmission range is longer than m +2.8R c ,there is at least a forwarder w which can communicate with the BS.Moreover,according to Theorem 1,if R t ≥4.8R c,any forwarder can reach forwarder w .Therefore,the transmission range must be longer than both m +2.8R c and 4.8R c .3.PROPOSED APPROACHIn this section,we describe the proposed algorithm in details.Because of the specific characteristics of sensor network,it is hard to determine an efficient way to transmit the collected information via multi-hop transmission to the BS.We showed the necessary conditions for multi-hop,and we will make further research in fu-ture works.In this paper we only focus on the single-hop transmis-sion.The determination of the collector in a cluster is similar to the method to determine the cluster head in existing algorithms [9].However,the forwarder is chosen based on the residual energy of each node in a cluster and the distance from the node to the BS.It is assumed that the BS broadcasts a ”hello”message periodi-cally with a certain given power level.Then,each node computes the approximate distance to the BS based on the strength of signal received.For example,node i can determine the value of parameter E i shown in Table 1using the distance from node i to the BS.3.1Forwarder DeterminationThe forwarder of each cluster is selected according to the report cost of nodes.The node report cost is determined by the current re-maining energy and the distance to the BS.The remaining energy of node i in a cluster is denoted by e i .Furthermore,the energy re-quired for transmission from node i to the BS is denoted by E i .We consider the report cost that is proportional to the energy consump-tion from node i to the BS,E i ,and is inversely proportional to the current remaining energy of node i ,e i .That is,the report cost of node i in a cluster,denoted by c i ,is given by:c i =E i e i.(4)3.2Implementation of the Proposed AlgorithmThe mechanism for determining the cluster collector is similar to the method of determining the cluster head in HEED [9].In order to determine the cluster forwarder,each member of a cluster com-putes its report cost,adds the cost information to the cluster-joining broadcast packet,and then sends it to the collector.Therefore,no much overhead will be appended to the proposed algorithm com-pared with the existing algorithms.The collector selects a node with the minimum report cost as the forwarder.Note that the col-lector can also be the forwarder in its cluster if its report cost is the minimum.Then,the collector determines the TDMA slot as-signment for the cluster members.The collector gathers the data from the members except the forwarder,aggregates the collected data into one packet,and then transmits it to the forwarder.The forwarder aggregates the compressive data with its own data,and then transmits to the BS directly (see Figure 6).The proposed algorithm consists of four procedures:initializa-tion ,cluster construction ,TDMA slot allotment ,and data trans-mission .The pseudo-code of the proposed algorithm is shown inFigure6:Data aggregation and report to the BS in the pro-posed algorithm.Figure7.In the proposed algorithm,the variable v i.status indi-cates the status of node i,which may be a collector,a non-collector, or a forwarder(a forwarder is also a non-collector).The variable v i.cluster indicates the set of member nodes of a cluster cen-tered at collector v i.v i.collector and v i.forwarder denote the collector and the forwarder of the cluster which contains node v i.4.EXPERIMENTSIn this section,we evaluate the performance of the proposed approach through the simulations.We compare the proposed ap-proach with HEED.In our experiments,we consider a network topology where nodes are randomly distributed between(x=0, y=0)and(x=100,y=100)with the BS at location(x=50, y=200).We repeat the simulation100times.The parameters used in the simulation are given in Table2.We consider two scenarios in simulation,each of which has a dis-tinct ratio of data packet size to the broadcast packet size.In Sce-nario1,the data packet size is500bytes,and the broadcast packet size is25bytes.On the other hand,in Scenario2,the data packet size is150bytes,and the broadcast packet size is50bytes.Here, we define the network lifetime as the time elapsed from the net-work operation starts until thefirst node dies,since if a node dies, it causes a vacancy area which can not be covered by a sensor node.Table2:Parameters used in experiments.Parameter ValueNetwork grid from(0,0)to(100,100)Base station At(50,200)Threshold distance(d0)100mCluster radius25mE t,E r50nJ/bitε110pJ/bit/m4ε20.0013pJ/bit/signalE g5nJ/bit/signalRound5TDMA framesInitial energy0.5J/batteryWe consider the number of nodes is100,and we compare the proposed approach with HEED and LEACH respectively in the Scenario1.In Figure8,we can see that the our approach is su-perior to both HEED and LEACH on network lifetime.In the following experiments,we compare our approach with HEED to observe the impact on performance by various parame-ters.Figure9and Figure10show the network lifetime by chang-•Initialization1.Receive”hello”message from BSpute E i•Cluster construction1.Construct clusters using HEED algorithm2.If(v i.status=collector)3.Wait for the joining messages from members4.If(v i.status=non-collector)5.Join a cluster with E i information•TDMA allotment1.If(v i.status=collector)2.v i.forwarder←least cost(v i.cluster)3.Assign TDMA slots to all the members4.Else5.Receive TDMA information from v i.collector•Data transmission1.If(v i.status=collector)2.If(v i.forwarder=v i)3.Receive all the data from members4.Aggregate and transmit to the BS5.Else6.Receive all the data from members7.Aggregate and transmit to v i.forwarder8.If(v i.status=non-collecter)9.If(v i.status=forwarder)10.Receive data from v i.collector11.Aggregate and transmit to the BS12.Else13.Transmit to v i.collectorFigure7:Pseudo-code of the proposed algorithm.ing the number of nodes and cluster radius respectively.From the figures,we can see that many conditions,such as density of nodes, cluster radius have big impacts on network performance.Due to the complexities,it is hard to determine the optimal values for all the parameters.In Figure11,we consider the case that there are100nodes in the network area.We keep the x-coordinate of the BS as50,which is introduced in Table2,and vary the y-coordinate of the BS.We change the y-coordinate of the BS from150to300.We can see that network lifetime severely deteriorates when using single-hop trans-mission as the distance increases,which emphasizes the advantages of network clustering.5.CONCLUSIONSIn this paper,we proposed a new clustering approach for sen-sor networks wherein the data gathering and data aggregation are separated from the data report to the BS,and these tasks can be assigned to distinct nodes in a cluster.The proposed algorithm pro-20 40 60 80 100 120 0 20 40 6080 100 120 140 160 180 200N u m b e r o f a l i v e s e n s o r n o d e sRoundsHEED Proposed(a)HEED vs.Proposedapproach.20 40 60 80 100 120 0 20 4060 80 100120N u m b e r o f a l i v e s e n s o r n o d e sRoundsLEACH Proposed(b)LEACH vs.Proposed approach.Figure 8:Network lifetime in HEED and LEACH.0 20 40 60 80 100 120 50150250 350 450 550R o u n d s u n t i l t h e f i r s t n o d e d i e sNumber of nodesHEED Proposed(a)Scenario 1. 80 100 120 140 160 180 200 50150250 350 450 550R o u n d s u n t i l t h e f i r s t n o d e d i e sNumber of nodesHEED Proposed(b)Scenario 2.Figure 9:Network lifetime with various number of nodes.0 20 40 60 80 100 120 140 152535 45 55 65R o u n d s u n t i l t h e f i r s t n o d e d i e sCluster transmission rangeHEED Proposed(a)Scenario 1. 60 80 100 120 140 160 180 200 152535 45 55 65R o u n d s u n t i l t h e f i r s t n o d e d i e sCluster transmission rangeHEED Proposed(b)Scenario 2.Figure 10:Network lifetime with various cluster range.0 20 40 60 80 100 120 140 150175200 225 250 275 300R o u n d s u n t i l t h e f i r s t n o d e d i e sVertical coordinates of the BSHEED Proposed(a)Scenario 1. 0 50 100 150 200 250 150175200 225 250 275 300R o u n d s u n t i l t h e f i r s t n o d e d i e sVertical coordinates of the BSHEED Proposed(b)Scenario 2.Figure 11:Network lifetime with various position of the BS.vides much better performance than previous algorithms.Simula-tion results show that our proposed algorithm prolongs the network lifetime compared with the traditional approaches.In large scale sensor networks,multi-hop communication be-comes important for energy conservation.In this paper,we showed the necessary conditions for multi-hop data transmission.We are now working on designing multi-hop data transmission algorithms to achieve better performance.Since it is generally difficult to have the optimal solution,we are trying to develope heuristic algorithms for multi-hop data transmission.6.REFERENCES[1]I.Akyildiz,W.Su,Y .Sankarasubramaniam,and E.Cayirci,“A survey on sensor networks,”IEEE Commun.Mag.,pp.102–114,August 2002.[2]G.Pottie and W.Kaiser,“Wireless intergrated networksensors,”Communications of the ACM ,vol.43,pp.51–58,May 2000.[3]J.Agre and L.Clare,“An integrated architecture forcooperative sensing networks,”IEEE Computer ,vol.33,pp.106–108,May 2000.[4]J.Chang and L.Tassiulas,“Energy conserving routing inwireless ad-hoc networks,”in Proc.of IEEE INFOCOM ,March 2000.[5]C.Chiasserini,I.Chlamtac,P.Monti,and A.Nucci,“Energyefficient design of wireless ad hoc networks,”in Proc.of European Wireless ,February 2002.[6]T.Kwon and M.Gerla,“Clustering with power control,”COM ,November 1999.[7]V .Kawadia and P.Kumar,“Power control and clustering inad hoc networks,”in Proc.of IEEE INFOCOM ,April 2003.[8]W.Heinzelman,A.Chandrakasan,and H.Balakrishnan,“Anapplication-specific protocol architecture for wireless microsensor networks,”IEEE Trans.Wireless Commun.,vol.1,pp.660–669,October 2002.[9]O.Younis and S.Fahmy,“Distributed clustering in ad-hocsensor networks:A hybrid,energy-efficient approach,”in Proc.IEEE INFOCOM ,March 2004.[10]M.Qin and R.Zimmermann,“An energy-efficientvoting-based clustering algorithm for sensor networks,”in ACIS Int.Workshop Self-Assembling Wireless Networks(SAWN 2005),May 2005.[11]M.Ye,C.Li,G.Chen,and J.Wu,“EECS:An energyefficient clustering scheme in wireless sensor networks,”in IEEE Int.Workshop on Strategies for Energy Efficiency in Ad Hoc and Sensor Networks (IWSEEASN’05),April 2005.[12]D.Blough and P.Santi,“Investigating upper bounds onnetwork lifetime extension for cell-based energyconservation techniques in stationary ad hoc networks,”in Proc.8th Int.Conf.Mobile Computing and Networking (MobiCom 2002),pp.183–192,September 2002.。

相关文档
最新文档