SK_20-100_MSDS11
MaterialSafetyDataSheet-ClearTech

MATERIAL SAFETY DATA SHEETCitric Acid, 50% SolutionSection 01 - Chemical And Product And Company InformationProduct Identifier ……………………... Citric Acid 50% SolutionProduct Use …………………………..... Membrane cleaning in water treatment, pipe cleaning, metal oxidedeposit removal in boilersSupplier Name……………………….….ClearTech Industries Inc.1500 Quebec AvenueSaskatoon, SK. CanadaS7K 1V7Prepared By................……………..…..ClearTech Industries Inc. Technical DepartmentPhone: (306)664-2522Preparation Date.........…………….…...September 5, 201224-Hour Emergency Phone…………...306-664-2522Section 02 - Composition / Information on IngredientsHazardous Ingredients....…………....Citric Acid48-52%CAS Number...................…….…….....Citric Acid77-92-9Synonym (s)...................……………...NoneSection 03 - Hazard Identification Inhalation...................………….…....Breathing of vapour or mist is possible, may cause irritation.Skin Contact / Absorption…….…...Can cause skin irritation with contact such as redness & burning.Eye Contact................………….…....Can cause eye irritation such as tearing, stinging, redness and swelling. Ingestion.....................……………….Ingesting small amounts not likely to cause harmful effects. Ingestinglarge amounts may however, be harmful.Exposure Limits……………………...Not availableSection 04 - First Aid Measures Inhalation....................………………..Remove victim to fresh air. Give artificial respiration only if breathing hasstopped. If breathing is difficult, give oxygen. Seek immediate medicalattention.Skin Contact / Absorption…………..Remove contaminated clothing. Wash affected area with soap and water.Seek medical attention if irritation occurs or persistsEye Contact..................……………....Flush immediately with water for at least20minutes.Forcibly holdeyelids apart to ensure complete irrigation of eye tissue. Seek immediatemedical attention Ingestion......................……………….Seek medical attention. Do not give anything by mouth if individual isdrowsy or unconscious, place individual on left side with head down.Consult with a physician or poison control center whether to inducevomitting. Do not leave individual unattended.Additional Information.....…………...Pre-existing disorders of skin and lungs may be aggravated withexposure to material.Section 05 - Fire FightingConditions of Flammability………....Not considered flammableMeans of Extinction........………….....Water; carbon dioxide, foam and powder extinguisher.Flash Point....…………………………..Not applicableAuto-ignition Temperature………….Not availableUpper Flammable Limit ……………..Not applicableLower Flammable Limit...……….…...Not applicableHazardous Combustible Products...May form carbon dioxide, carbon monoxide, various hydrocarbons. Special Fire Fighting Procedures.....Wear NIOSH-approved self-contained breathing apparatus andprotective clothing.Explosion Hazards…………………....Material is not considered flammable but residue may burn in presence ofa strong ignition source after water has evaporated.Section 06 - Accidental Release MeasuresLeak / Spill................….……………...Wear appropriate personal protective equipment. Ventilate area. Stop orreduce leak if safe to do so. Prevent material from entering sewers. Coverspill with soda ash and discard waste into plastic or plastic linedcontainers. Flush are with water to remove any residue.Deactivating Materials...……….…...Not availableSection 07 - Handling and StorageHandling Procedures.......…………e proper equipment for lifting and transporting all esensible industrial hygiene and housekeeping practices. Wash thoroughlyafter handling. Avoid all situations that could lead to harmful exposure. Storage Requirements......……...…..Store in a cool, dry area away from ignition source.Section 08 - Personal Protection and Exposure ControlsProtective EquipmentEyes.………………………….………...Chemical goggles, full-face shield, or a full-face respirator is to be worn atall times when product is handled. Contact lenses should not be worn;they may contribute to severe eye injury. Respiratory…………………………....Wear a NIOSH-approved respirator for acid vapour.Gloves……………………………….....Impervious gloves of chemically resistant material (rubber or PVC) shouldbe worn at all times. Wash contaminated clothing and dry thoroughlybefore reuse.Clothing………………………..……....Body suits, aprons, and/or coveralls of chemical resistant material shouldbe worn at all times.Wash contaminated clothing and dry thoroughlybefore reuse.Footwear…………………………….....Impervious boots of chemically resistant material should be worn.Engineering ControlsVentilation Requirements………......Mechanical ventilation (dilution or local exhaust), process or personnelenclosure and control of process conditions should be provided. Supplysufficient replacement air to make up for air removed by exhaust systems. Other…………………………………....Not availableSection 09 - Physical and Chemical PropertiesPhysical State.......……....…………....LiquidOdor and Appearance…..…………...Characteristic odor; colorless to pale yellow liquidOdor Threshold....……………............Not availableSpecific Gravity (Water=1)…………..1.24-1.26Vapor Pressure (mm Hg, 20C)….…..Not availableVapor Density (Air=1)..……………....Not availableEvaporation Rate........……..…….…..< 1(butyl acetate=1)Boiling Point...............………….….....>100o CFreeze/Melting Point....……………....-10--15o C pH............................……………….…..Not availableWater/Oil Distribution Coefficient....Not availableBulk Density..............…………….…...Not available% Volatiles by Volume………..……...Not availableSolubility in Water...………………pleteMolecular Formula......………….…....Not availableMolecular Weight........…………….....Not availableSection 10 - Stability and Reactivity Stability.................…………....…………….Stable under normal conditions. Incompatibility..............…………..………..Reactive metals (iron, zinc, aluminum), metallic nitrates, strongoxidizers and alkalies.Hazardous Products of Decomposition..Not available Polymerization...........…………….…….….Hazardous polymerization will not occur.Section 11 - Toxicological Information Irritancy.................……..………….….Not availableNot available Sensitization........…….......…………..Chronic/Acute Effects……...………..Product may cause burns with prolonged contact.Synergistic Materials...……....……...Not availableAnimal Toxicity Data......…..………..Not available Carcinogenicity......……......………...Not availableReproductive Toxicity..…...………...Not available Teratogenicity..........….....…………...Not available Mutagenicity...........…….....………….Not availableSection 12 - Ecological InformationFish Toxicity..................……………...Not available Biodegradability.............……….…....Not availableEnvironmental Effects……………….Not availableSection 13 - Disposal ConsiderationWaste Disposal...........…...…………...Dispose in accordance with all federal, provincial, and/or local regulationsincluding the Canadian Environmental Protection Act.Section 14 - Transportation InformationTDG ClassificationClass (8)Group (III)PIN Number.................……..………....UN 1760Other………………………………….....Secure containers (full and/or empty) with suitable hold down devisesduring shipment.Section 15 - Regulatory InformationWHMIS Classification.......…………....ENOTE: THE PRODUCT LISTED ON THIS MSDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF THE CANADIAN CONTROLLED PRODUCTS REGULATIONS.THIS MSDS CONTAINS ALL INFORMATION REQUIRED BY THOSE REGULATIONS.NSF Certification.................................Product is certified under NSF/ANSI Standard 60 for pH adjustment at amaximum dosage of: 250mg/L [NOTE: product is also NSF certified for use off-line as a membrane (filter media) cleaner].Section 16 - Other InformationNote: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and safety information contained herein as a guide and should take those precautions required in an individual operation to instruct employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to comply with all applicable laws and regulations.Attention: Receiver of the chemical goods / MSDS coordinatorAs part of our commitment to the Canadian Association of Chemical Distributors(CACD)Responsible Distribution® initiative, ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Material Safety Data Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health, and safety information to you at your request.If you have any questions or concerns please call our customer service or technical service department.。
过氧化二乙酰[含量≤27%,含B型稀释剂≥73%]安全技术说明书MSDS
![过氧化二乙酰[含量≤27%,含B型稀释剂≥73%]安全技术说明书MSDS](https://img.taocdn.com/s3/m/ea93d1e06c175f0e7dd1370a.png)
第一部分化学品及企业标识化学品中文名:过氧化二乙酰[含量≤27%,含B型稀释剂≥73%]化学品英文名:diacetyl peroxide (not more than 27%,and diluent type B not less than 73%)化学品别名:-CASNo.:110-22-5ECNo.:203-748-8分子式:C4H6O4第二部分危险性概述紧急情况概述液体。
遇热有火灾危险。
有严重损害眼睛的危险。
GHS危险性类别根据GB30000-2013化学品分类和标签规范系列标准(参阅第十六部分),该产品分类如下:有机过氧化物,D型;皮肤腐蚀/刺激,类别1;眼损伤/眼刺激,类别1。
标签要素象形图警示词:危险危险信息:加热可能起火,造成严重皮肤灼伤和眼损伤,造成严重眼损伤。
预防措施:远离热源、热表面、火花、明火以及其它点火源。
禁止吸烟。
只能在原包装中存放。
保持低温。
容器和接收设备接地和等势联接。
不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
作业后彻底清洗。
戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
事故响应:立即呼叫中毒急救中心/医生。
沾染的衣服清洗后方可重新使用。
如误吸入:将受人转移到空气新鲜处,保持呼吸舒适的体位。
如误吞咽:漱口。
不要诱导呕吐。
如皮肤(或头发)沾染:立即去除/脱掉所有沾染的衣服。
用水清洗皮肤或淋浴。
如进入眼睛:用水小心冲洗几分钟。
如戴隐形眼镜并可方便地取出,取出隐形眼镜。
继续冲洗。
安全储存:存放在通风良好的地方。
存放处须加锁。
防日晒。
分开存放。
废弃处置:按照地方/区域/国家/国际规章处置内装物/容器。
物理化学危险:遇热有火灾危险。
健康危害:吸入该物质可能会引起对健康有害的影响或呼吸道不适。
意外食入本品可能对个体健康有害。
皮肤直接接触造成严重皮肤灼伤。
通过割伤、擦伤或病变处进入血液,可能产生全身损伤的有害作用。
眼睛直接接触本品能造成严重化学灼伤。
如果未得到及时、适当的治疗,可能造成永久性失明。
正己烷 n-hexane--MSDS--英文版

Material Safety Data SheetHexaneMSDS Name: HexaneCatalog Numbers: S80032, S800321, S800322MF, BP2615-100, BPH302-4EMW,H291-20, H291-200, H291-4, H291-500, H291FB-115, H291FB-19, H291FB-200,H291FB-50, H291RB-115, H291RB-19, H291RB-200, H291RB-50, H291RS-115,H291RS-19, H291RS-200, H291RS-28, H291RS-50, H291S-4, H291SS-115,H291SS-200, H291SS-28, H291SS-50, H292-1, H292-20, H292-200, H292-20LC,H292-4, H292-500, H292200LC, H292FB-115, H292FB-19, H292FB-200, H292FB-50, H292J-4, H292J-500, H292POPB-50, H292RB-115, H292RB-19, H292RB-200,H292RB-50, H292RS-19, H292RS-200, H292RS-50, H292RS115, H292RS28,H292SK-4, H292SS-115, H292SS-1350, H292SS-200, H292SS-28, H292SS-50,H300-4, H302-1, H302-4, H302-4LC, H302J-1, H302J-4, H302ME, H302N1-19,H302N119LC, H302N2-19, H302POP-19, H302POP-50, H302RS-115, H302RS-19,H302RS-200, H302RS-28, H302RS-50, H302SK-1, H302SK-4, H302SS-115,H302SS-19, H302SS-200, H302SS-28, H302SS-50, H303-1, H303-4, H303-4LC,H303J-1, H303J-4, H303RS-115, H303RS-19, H303RS-200, H303RS-28, H303RS-50, H303SK-4, H303SS-115, H303SS-19, H303SS-200, H303SS-28, H303SS-50, H307-4, H307-4LC, H334-1, H334-4, N3-20, N3-200, N3S-4, NC9173152, NC9321642,NC9321646, NC9321654, NC9321658, NC9323196, NC9394242, NC9410668,O3386-20, S800322, S80032HPLC, S93257Synonyms: n-Hexane; Hexyl hydride; Dipropyl; normal-Hexane; Hex.Company Identification:Fisher Scientific1 Reagent LaneFair Lawn, NJ 07410For information, call: 201-796-7100Emergency Number: 201-796-7100For CHEMTREC assistance, call: 800-424-9300For International CHEMTREC assistance, call: 703-527-3887EMERGENCY OVERVIEWAppearance: clear colorless liquid.Danger! Extremely flammable liquid and vapor. Vapor may cause flash fire. Breathing vapors may cause drowsiness and dizziness. Causes eye, skin, and respiratory tract irritation. May be harmful if absorbed through the skin. Aspiration hazard if swallowed. Can enter lungs and cause damage. Possible risk of impaired fertility. Long-term exposure may cause damage to the nervous system of the extremities (the hands, arms, legs and feet). Dangerous for the environment. Target Organs: Central nervous system, respiratory system, eyes, skin, peripheral nervous system, testes.Potential Health EffectsEye: Causes mild eye irritation.Skin: Prolonged and/or repeated contact may cause defatting of the skin and dermatitis. Causes irritation with burning pain, itching, and redness. Absorbed through the skin. There have been no reports of skin sensitization in people occupationally exposed to n-hexane. Skin sensitization was not observed in a maximization test using 25 volunteers.Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal. May cause central nervous system depression.Inhalation: Causes respiratory tract irritation. Exposure produces central nervous system depression. Vapors may cause dizziness or suffocation. n-Hexane vapor concentrations can become so high that oxygen is displaced, especially in confined spaces.Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis. Prolonged or repeated exposure may cause adverse reproductive effects. Chronic exposure may cause visual disturbances. Laboratory experiments have resulted in mutagenic effects. Peripheral neuropathy symptoms include: muscular weakness, paresthesia, numbing of the hands, feet, legs and arms, unsteadiness, and difficulty in walking and standing. Repeated exposure may cause nervous system abnormalities with muscle weakness and damage, motor incoordination, and sensation disturbances. Chronic exposure produces peripheral neuropathy.Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid.Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.Ingestion: Potential for aspiration if swallowed. Get medical aid immediately. Do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. If vomiting occurs naturally, have victim leanforward.Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.Notes to Physician: Treat symptomatically and supportively. For ingestion, the stomach sould be intubated, aspirated, and lavaged with a slurry of activated charcoal--protect the airway from aspiration of gastric contents. Monitor arterial blood gases in cases of severe aspiration.General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. May accumulate static electrical charges, and may cause ignition of its own vapors. Extremely flammable liquid and vapor. Vapor may cause flash fire. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas. This liquid floats on water and may travel to a source of ignition and spread fire.Extinguishing Media: Use dry chemical, carbon dioxide, or appropriate foam. Solid streams of water may be ineffective and spread material. Water may be ineffective because it will not cool material below its flash point.Flash Point: -22 to -26.1 deAutoignition Temperature: 225 deg C ( 437.00 deg F)Explosion Limits, Lower:1.2 vol %Upper: 7.7 vol %NFPA Rating: (estimated) Health: 2; Flammability: 3; Instability: 0General Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Use only non-sparking tools and equipment.Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Take precautionary measures against staticdischarges. Keep away from heat, sparks and flame. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Avoid breathing vapor or mist.Storage: Keep away from heat and flame. Keep away from sources of ignition. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or localexplosion-proof ventilation to keep airborne levels to acceptable levels. Exposure LimitsOSHA Vacated PELs: Hexane (contains a mixture of isomers): 50 ppm TWA; 180 mg/m3 TWAPersonal Protective EquipmentEyes: Wear chemical splash goggles.Skin: Wear appropriate protective gloves to prevent skin exposure.Clothing: Wear appropriate protective clothing to prevent skin exposure.Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.Physical State: LiquidAppearance: clear colorlessOdor: gasoline-likepH: Not available.Vapor Pressure: 151 mm Hg @ 25 deg CVapor Density: 2.97(Air = 1)Evaporation Rate:Not available.Viscosity: 0.31 mPas 20 deg CBoiling Point: 62 - 69 deg C @ 760 mmHgFreezing/Melting Point:-95 deg CDecomposition Temperature:Not available.Solubility: Insoluble.Specific Gravity/Density:0.678Molecular Formula:C6H14Molecular Weight:86.18Chemical Stability: Stable under normal temperatures and pressures.Conditions to Avoid: Ignition sources, excess heat, electrical sparks, confined spaces.Incompatibilities with Other Materials: Strong oxidizing agents.Hazardous Decomposition Products: Carbon monoxide, carbon dioxide. Hazardous Polymerization: Will not occur.RTECS#:CAS# 110-54-3: MN9275000LD50/LC50:CAS# 110-54-3:Draize test, rabbit, eye: 10 mg Mild;Inhalation, mouse: LC50 = 150000 mg/m3/2H;Inhalation, rat: LC50 = 48000 ppm/4H;Inhalation, rat: LC50 = 627000 mg/m3/3M;Oral, rat: LD50 = 25 gm/kg;.Carcinogenicity:CAS# 110-54-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.Epidemiology: Occupational polyneuropathy has resulted from hexane exposures as low as 500 ppm, but the minimum levels of n-hexane that are neurotoxic in humans haven't been established. Nearly continuous exposure of animals at 250 ppm has caused neurotoxic effects.Teratogenicity: No evidence of teratogenicity or embryotoxicity in anmial studies with hexane. Fetotoxicity has been observed in the presence of maternal toxicity. Reproductive Effects: Severe testicular damage has been observed in rats exposed to hexane at concentrations which have produced other significant toxicity. Although subneurotoxic doses of its principle toxic metabolite, 2,5-hexanedione, can induce progressive testiculartoxicity in rats, there have been no reports of human sterility orother reproductive toxicity associated with n-hexane exposures.Mutagenicity: Positive results (chromosomal damage in the bone marrow cells) obtained for rats exposed by inhalation to n-hexane.Neurotoxicity: n-Hexane is a mild irritant and CNS depressant in acute exposure, but its principal effects are damage to the sensory and motor peripheral nerves, particularly in chronic exposure.Other Studies:Ecotoxicity: No data available. Estimated BCF values = 2.24 and 2.89. These values suggest that hexane will show low bioconcentration in aquatic organisms. Estimated Koc value = 4.11. This product will show slight soil mobility and is expected to rapidly volatilize from moist surface soils.Environmental: Terrestrial: Volatilization and adsorption are expected to be the most important fate processes. Aquatic: Photolysis or hydrolysis are not expected to be important. Atmospheric: Expected to exist entirely in the vapor phase in ambient air, expected half life 2.8 days. Expected to biodegrade but not bioconcentrate. Physical: No information available.Other: No information available.Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 110-54-3 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.CERCLA Hazardous Substances and corresponding RQsCAS# 110-54-3: 5000 lb final RQ; 2270 kg final RQSARA Section 302 Extremely Hazardous SubstancesNone of the chemicals in this product have a TPQ.SARA CodesCAS # 110-54-3: immediate, delayed, fire.Section 313This material contains Hexane (contains a mixture of (CAS# 110-54-3, 100%),which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFRClean Air Act:CAS# 110-54-3 is listed as a hazardous air pollutant (HAP).This material does not contain any Class 1 Ozone depletors.This material does not contain any Class 2 Ozone depletors.Clean Water Act:None of the chemicals in this product are listed as Hazardous Substances under the CWA.None of the chemicals in this product are listed as Priority Pollutants under the CWA.None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:None of the chemicals in this product are considered highly hazardous by OSHA. STATECAS# 110-54-3 can be found on the following state right to know lists: New Jersey, Pennsylvania, Minnesota, Massachusetts.California Prop 65California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:XN F NRisk Phrases:R 11 Highly flammable.R 38 Irritating to skin.R 48/20 Harmful : danger of serious damage to health by prolongedexposure through inhalation.R 62 Possible risk of impaired fertility.R 51/53 Toxic to aquatic organisms, may cause long-term adverseeffects in the aquatic environment.R 65 Harmful: may cause lung damage if swallowed.R 67 Vapours may cause drowsiness and dizziness.Safety Phrases:S 16 Keep away from sources of ignition - No smoking.S 29 Do not empty into drains.S 33 Take precautionary measures against static discharges.S 36/37 Wear suitable protective clothing and gloves.S 9 Keep container in a well-ventilated place.S 61 Avoid release to the environment. Refer to special instructions/safety data sheets.S 62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label.WGK (Water Danger/Protection)CAS# 110-54-3: 1Canada - DSL/NDSLCAS# 110-54-3 is listed on Canada's DSL List.Canada - WHMISThis product has a WHMIS classification of B2, D2B.This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.Canadian Ingredient Disclosure ListCAS# 110-54-3 is listed on the Canadian Ingredient Disclosure List.MSDS Creation Date: 6/03/1999Revision #14 Date: 10/25/2007The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.。
SK综合化学EPDM牌号性能表

自行车轮胎,胶管,汽车配件,电器配件,TPV各种工业产品,各种高性能产品充油松散型,可用于低硬度产品,可高填充 轮胎胎侧,发泡件,高硬度产品 汽车发泡件,绝热发泡件,发泡密封条 汽车发泡件,绝热发泡件,发泡密封条 汽车发泡件,绝热发泡件,发泡密封条,硫速较快 低门尼高ENB,因此加工性能优异,硫化速度快且可以二烯烃类吸纳高并用 高分子量,高ENB,挺性好,低压变 松散型,高分子量,高ENB,挺性好,低压变 松散型,高分子量,高ENB,挺性好,低压变
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SK综合化学EPDM牌号性能表
NO 牌号 门尼粘度ML(1+4) 乙烯 第三单 充油 含量 体含量 份数 100℃ 125℃ 150℃ Wt% Wt% OilPHR 35 46 30 63 84 84 98 87 53 54 61 45 41 29 84 109 90 61 81 67 64 57 53 69 58 58 62 68 70 60 72 55 60 60 60 2.3 4.1 4.5 4.1 4.7 4.5 5.5 5.7 4.5 4 9.4 8.5 8.5 9.0 50 75 100 内胎、鞋材、机械制品等 注射制品,高硬度制品,垫圈,线缆,电子配件 胶管、门窗密封件、各种挤出制品,线缆 胶管、密实密封条,垫圈,一般工业制品 胶管、密实密封条,垫圈,一般工业制品,硫速快 门窗密封条,汽车外饰件,防水板材等 密封性密封条,胶管,模压产品,防水板材,汽车配件等 低硬度模压注射件(洗衣机门封,线束保护套等),胶管,高回弹产品等 低硬度模压注射件(洗衣机门封,线束保护套等),胶管,高回弹产品等 应用 特性
牌号乙烯含量第三单体含量份数应用特性100125150wtwtoilphrs5373355723内胎鞋材机械制品等优异的耐老化性可以iir并用s501a46305341注射制品高硬度制品垫圈线缆电子配件低门尼因此具有优异的加工性和流动性适用于形状复杂的挤出及注射产品s512f636945胶管门窗密封件各种挤出制品线缆高乙烯高生胶强度良好的物理性能与加工性能松散型混炼时间短s552845841胶管密实密封条垫圈一般工业制品优异的基础加工性和物理性能良好的耐寒性能s5521845847胶管密实密封条垫圈一般工业制品硫速快优异的基础加工性和物理性能优秀的弹性良好的低温柔韧性s553986245门窗密封条汽车外饰件防水板材等高门尼粘度优异的基础加工性能和物理性能可高填充良好的耐寒性s5890f87646855密封性密封条胶管模压产品防水板材汽车配件等松散型高填充良好的物理性能与加工管高回弹产品等高乙烯高分子量可以与它牌号并用来调节硬度优异的加工性能与物理性能s6075wf54604575低硬度模压注射件洗衣机门封线束保护套等胶管高回弹产品等高乙烯高分子量可以与它牌号并用来调节硬度优异的加工性能与物理性能10s600wf614172100自行车轮胎胶管汽车配件电器配件tpv各种工业产品各种高性能产品充油松散型可用于低硬度产品可高填充11s505a45295594轮胎胎侧发泡件高硬度产品低门尼高enb因此加工性能优异硫化速度快且可以二烯烃类吸纳高并用12s5206f84616085汽车发泡件绝热发泡件发泡密封条高分子量高enb挺性好低压变13s5527f109816085汽车发泡件绝热发泡件发泡密封条松散型高分子量高enb挺性好低压变14s7486f90676090汽车发泡件绝热发泡件发泡密封条硫速较快松散型高分子量高enb挺性好低压变
偶氮二甲氧基异庚腈-危险化学品安全技术说明书MSDS

第1部分化学品及企业标识化学品中文名:偶氮二甲氧基异庚腈化学品英文名:2,2'-azobis[4-methoxy-2,4-dimethylvaleronitrile]CAS号:15545-97-8分子式:C16H28N4O2分子量:308.42产品推荐及限制用途:工业及科研用途。
第2部分危险性概述紧急情况概述:加热可能起火。
对水生生物有害并具有长期持续影响。
GHS危险性类别:自反应物质和混合物类别C型危害水生环境——长期危险类别3标签要素:象形图:警示词:危险危险性说明:H242加热可能起火H412对水生生物有害并具有长期持续影响防范说明:•预防措施:——P210远离热源/火花/明火/热表面。
禁止吸烟。
——P234只能在原容器中存放。
——P235保持低温。
——P240容器和装载设备接地/等势联接。
——P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
——P273避免释放到环境中。
•事故响应:——P370+P378火灾时:使用灭火器灭火。
•安全储存:——P403存放在通风良好的地方。
——P420远离其他材料存放。
•废弃处置:——P501按当地法规处置内装物/容器。
物理和化学危险:加热可能起火。
健康危害:无资料环境危害:对水生生物有害并具有长期持续影响。
第3部分成分/组成信息第4部分急救措施急救:吸入:如果吸入,请将患者移到新鲜空气处。
皮肤接触:脱去污染的衣着,用肥皂水和清水彻底冲洗皮肤。
如有不适感,就医。
眼睛接触:分开眼睑,用流动清水或生理盐水冲洗。
立即就医。
食入:漱口,禁止催吐。
立即就医。
对保护施救者的忠告:将患者转移到安全的场所。
咨询医生。
出示此化学品安全技术说明书给到现场的医生看。
对医生的特别提示:无资料第5部分消防措施灭火剂:用水雾、干粉、泡沫或二氧化碳灭火剂灭火。
避免使用直流水灭火,直流水可能导致可燃性液体的飞溅,使火势扩散。
特别危险性:无资料灭火注意事项及防护措施:消防人员须佩戴携气式呼吸器,穿全身消防服,在上风向灭火。
2-乙氧基乙基乙酸酯

2-乙氧基乙基乙酸酯
2-乙氧基乙基乙酸酯,化学式C7H14O3,是一种有机化合物。
它是由乙二醇
与乙酸酐反应生成的酯化合物。
乙氧基乙基乙酸酯在化学上也被称为Ethyl Cellosolve Acetate(ECA)。
它是一种常见的溶剂,具有良好的挥发性和较低的毒性。
2-乙氧基乙基乙酸酯具有许多应用领域。
它在涂料和油墨工业中被广泛使用,
作为快干型、低溶解度溶剂。
由于其挥发性较高,并且在涂布后迅速干燥,因此可以有效地提高产品的涂装效率和质量。
此外,它还常用于表面涂层和清漆的制备,可以提供均匀且光滑的涂层。
乙氧基乙基乙酸酯也被用作印刷油墨的稀释剂和增塑剂。
它能够帮助调节油墨的流动性和粘度,提供更好的印刷效果和抗粘性能。
此外,它还被广泛应用于染
料工业,可以用作染料的溶剂和添加剂,以提供更高的染色效果和颜色稳定性。
除了上述应用领域外,2-乙氧基乙基乙酸酯还在其他领域中发挥作用。
它被用
作表面活性剂和乳化剂的成分,可以在化妆品和个人护理产品中起到辅助混合和
乳化的作用。
此外,它还可以用于涂料的去污剂和清洗剂的制备,具有良好的溶解性和清洁效果。
总之,2-乙氧基乙基乙酸酯是一种重要的有机化合物,在涂料、油墨、染料和
清洁剂等领域都有广泛的应用。
它的特性包括挥发性好、毒性低,并且能够提供高质量的涂装和印刷效果。
作为一种多功能的溶剂,它在工业生产和日常生活中都
发挥着重要的作用。
物质安全数据表(MSDS)-可溶性粉淀粉

监测方法:无资料
工程控制:无资料
呼吸系统防护:口罩
眼睛防护:无资料
身体防护:无资料
手防护:无资料
其他防护:无资料
第九部分:理化特性
外观与性状:白色或淡黄色粉末,无味无臭
pH值:无资料
熔点(oC):无资料
沸点(oC):无资料
相对密度(水=1):1.5
相对蒸气密度(空气=1):无资料
第十部分:稳定性和反应活性
稳定性:无
禁配物:无资料
避免接触的条件:无资料
聚合危害:无资料
分解产物:无资料
第十一部分:毒理学资料
急性毒性:LD50:无资料
LC50:无资料
刺激性:无
其他:无资料
第十二部分:生态学资料
生态毒性:无
生物降解性:无
非生物降解性:无
生物富集或生物积累性:无
其他有害作用:无资料
第十三部分:废弃处置
饱和蒸气压(KPa):无资料
临界温度(oC):无资料
辛ቤተ መጻሕፍቲ ባይዱ/水分配系数:无资料
闪点(oC):无资料
引燃温度(oC):无资料
爆炸下限[%(V/V)]:无资料
爆炸上限[%(V/V)]:无资料
分子式:C12H22O11分子量:342.2948
溶解性:不溶于冷水、乙醇和乙醚。溶于或分散于沸水中。
主要用途:1%胶体溶液是透明的乳状液体。粘着力很小。供纸张上胶、纺织品上浆、化学指示剂和保护胶体用。
第一部分:化学品及企业标识
化学品中文名:可溶性淀粉
化学品英文名:soluble starch
分子式或其简写:C12H22O11
第二部分:成分/组成信息
■纯品□混合物
MSDS中文版 Port Cleaner 洗枪水 2013

产品名称: 化学名称: 商标名称: 化学族: CAS 号码:
INSTAPAK® PORT CLEANER 洗枪水 Diisobutyl DBE 二异丁基酯 DBE-IB Dibasic esters 二元酯 见成分说明
危险鉴别
健康危害风险: 皮肤接触可能因刺激引起不适或皮疹。眼睛接触可能因刺激引起不适或流泪。 自然危害风险:轻微可燃液体。 因暴露而加剧的药物状态:没有 外观: 有芳香气味的透明液体。
未列入
Carbon Dioxide 二氧化碳
Ceiling=5,000ppm
STEL=30,000 ppm
ACGIH-TLV: Diidobutyl DBE 二异丁基酯
未列入
Carbon Dioxide 二氧化碳
Ceiling=5,000ppm
STEL=30,000 ppm
HMIS 危险代码: 健康: 1
吸入:一次性暴露吸入引起动物体重和视力下降,之后出现角膜模糊及程度不同的体重减轻。
皮肤接触:轻度皮肤刺激,但对动物不是皮肤过敏源。
眼睛接触:轻度眼睛刺激,一次性施予 10 uL 造成暂时性的角膜轻微模糊。
摄取:一次性摄取引起动物身体虚弱和中致癌性:产品成分(>0.1%)没有被列为致癌因素。
闪点: >212℉(>100℃)[TCC]
可燃下限: 未建立 可燃上限: 未建立
灭火介质:水、CO₂、干化学品或化学(alcohol)泡沫。
灭火程序: 消防员应当穿上符合国家防火协会规定的保护装备,包括独立呼吸用具、头盔、
帽子、鞋子和手套。避免与材料的接触。在重复使用呼吸用具及全套防护前请对其进行清洁。 火灾和爆炸危险:罐装内容物有压力存在,切保储液罐保存温度低于 120℉(49℃)以免发生爆裂。
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______________________________________________________________________________ MATERIAL SAFETY DATA SHEETVersion 1.1Supercedes all previous versions15JAN2009_____________________________________________________________________________ 1.Product and Company InformationProduct Name StressKote Brittle Coating,SK 20°F/(-7°C) through SK 100°F/(38°C), inclusiveCompany StressKote Brittle Coatings, LLCAddress S14 W33511 Hwy18, Bldg CDelafield WI 53018 USTechnical Information262-510-9568 or 414-940-1193Fax262-968-3050Emergency414-940-1193 or 414-322-3884Product Use Coating for Mechanical Stress AnalysisOSHA Status HazardousCAS#MixtureShipping Requirements (USDoT 49CFR, IATA)Proper Shipping Name Dichloromethane SolutionHazard Class, Division 6.1Identification Number UN1593____________________________________________________________________________________________ position/Information on IngredientsDefinitions:Liquid StressKote A clear (non-turbid), reddish-orange liquid, comprising a solution of gum rosinderivatives in a mixture of dichloromethane and toluene, with or without dibutylphthalate.A total of seventeen (17) solutions, of diverse composition, are included in the productline. Each is formulated to maximize strain sensitivity at a specific target temperature at 5F° intervals within the range of 20 -100 °F. As examples, SK 35°F and SK 80°F areformulated to maximize strain sensitivity at the target temperatures of 35°F (2°C) and80°F (27°C), respectively. Each of the seventeen solutions has a specific compositionwhich falls within the following range of compositions. Hereinafter, “Liquid StressKote”shall refer to each and all of the seventeen solutions.Wt %Substance CAS#75-78dichloromethane (methylene chloride) 75-09-28-10toluene (toluol, methylbenzene)108-88-30-3dibutylphthalate (o-benzenedicarboxylic acid, dibutyl ester)84-74-212-15gum rosin derivatives [Non-hazardous per OSHA: 29CFR 1910.1200]VOC: 83-87 wt %Page 1 of 12Dried Brittle Coating In normal use, Liquid StressKote is applied to a test surface by spraying, brushing, rolling and/or pouring in a series of thin coats, allowing a few minutes between the coats topromote solvent evaporation. The multilayered coating is purged of occluded residualsolvent by heating in air for a period of 12-24 hrs. at a temperature typically 10-20 °Fabove the target temperature, or at a minimum of 60°F for the SK 20°F through SK 50°Fcoatings. This processed coating is optimally 3-6 mil (0.08-0.15 mm) thick, smooth,shinny, copper or bronze colored, and essentially dichloromethane/toluene free. It ishereinafter referred to as “Dried Brittle Coating.”___________________________________________________________________________________________ 3.Hazards IdentificationThe specific hazards associated with a StressKote Brittle Coating depends upon its physical state as either Liquid StressKote, or Dried Brittle Coating. The liquid, which contains the volatile organic compounds, dichloromethane and toluene, has potential health effects primarily attributable to these two solvents, and to a much lesser extent, the gum rosin derivatives and the low concentration of dibutylphthalate, if present. The Dried Brittle Coating, containing only the gum rosin derivatives or gum rosin derivatives and dibutylphthalate, is believed not to pose a health risk to the end user, unless airborne dust, which can be inhaled, is generated during a mechanical removal (e.g., scraping, grinding, or wire brushing) of the coating from a test surface. The hazards identified below apply to Liquid StressKote, unless otherwise noted.Emergency OverviewOSHA HazardsToxic. Target Organ Effect, Harmful by ingestion, Irritant, Possible carcinogen and teratogen. May cause harm to the unborn child.Target OrgansLiver, kidneys, pancreas, eyes, bloodHM IS ClassificationHealth Hazard2Flammability1(Self-extinguishing liquid. See section 5)Physical Hazards0NFPA RatingHealth Hazard2Fire1(Self-extinguishing liquid)Reactivity0Potential Health EffectsInhalation May be harmful if inhaled, causing respiratory tract irritation. Liquid StressKoteproduces vapors which have a sweet, chlorinated hydrocarbon and pungent,aromatic hydrocarbon odor. These vapors, which are more dense than air, maycause at levels around 1000 ppm, drowsiness, dizziness, headache, nausea andvomiting, and if allowed to accumulate in poorly ventilated areas toconcentrations as low as 10,000 ppm, can cause CNS depression, cardiacarrhythmia, unconsciousness and death. Dichloromethane is metabolized in thebody producing carbon monoxide which increases and sustainscarboxyhemoglobin levels in the blood, reducing the blood’s oxygen-carryingcapacity.Skin May be harmful if absorbed through skin. May cause skin irritation andPage 2 of 12discoloration, with prolonged contact causing redness, swelling and burns.Severe response may be experienced on covered skin (under clothing, gloves orjewelry), with attendant drying and flaking of the skin. May cause dermatitis.Dried Brittle Coating may also cause skin irritation and discoloration, withprolonged contact causing redness and dermatitis.Eyes May cause eye irritation, conjunctivitis, and reversible corneal injury. DriedBrittle Coating dusts may also cause eye irritation and conjunctivitis.Ingestion Low toxicity if small amounts are swallowed. Larger amounts will causeabdominal pain (gastrointestinal discomfort), nausea, diarrhea, and throughaspiration may engender pneumonitis. Ingestion of small amounts of DriedBrittle Coating dust has a low toxicity.Cancer None of the components of Liquid StressKote or hence, Dried Brittle Coating, isbelieved to pose a measurable carcinogenic risk to man when handled asrecommended.____________________________________________________________________________________________ 4.First Aid M easuresGeneral adviceCall the StressKote emergency numbers and consult a physician. Have a copy of this MSDS available for use by emergency response personnel.If inhaledIf any of the potential health effects attributed to inhalation are observed, move the person into fresh air immediately. If breathing is labored, give oxygen. If not breathing, perform CPR. Consult a physician.In case of skin contactIf any Liquid StressKote contacts the skin, immediately wipe the area with a clean cloth, then remove all residuals with soap and water. Consult a physician. Contaminated clothing must be removed immediately and washed or dry cleaned before reuse. If the clothing is heavily contaminated, it should be taken to a well- ventilated area to allow for the safe evaporation of the dichloromethane and toluene, then discarded appropriately. Dried Brittle Coating dust should be removed with soap and water.In case of eye contactIf any Liquid StressKote splashes into the eye(s), or, for example, is transferred to the eye from a contaminated finger, then immediately flush the eye(s) [remove contact lenses] with clean water for 15 minutes, lifting the eye lids as necessary to ensure a complete rinse. Consult a physician, preferably an ophthalmologist. Dried Brittle Coating dust in the eye should be removed by a clean water rinse in the same manner.If Liquid StressKote is swallowedNever give anything by mouth to an unconscious person. Do not induce vomiting, as vomiting will significantly increases the risk of aspiration causing pneumonitis. Rinse mouth with clean water. Consult a physician and transport the victim to an emergency care facility immediately.____________________________________________________________________________________________ 5.Firefighting M easuresFlammable properties Self-extinguishing LiquidFlash Point None Liquid StressKote does not exhibit a TCT flash point as defined byASTM D56. A green halo, characteristic of thermal decomposition ofPage 3 of 12dichloromethane is observed around the test flame even at temperaturesapproaching 0°F.Flammable limits No determination made.Autoignition temperature Literature values for the autoignition temperatures of dichloromethane,toluene and dibutylphthalate, are 556°C (1,033°F), 536°C (997°F), and404°C (759°F), respectively. A propane torch flame applied to thesurface of Liquid StressKote will produce red-orange, sooty flamesattributable primarily to burning toluene. However, upon removal of thetorch flame, the liquid immediately self-extinguishes. Dried BrittleCoating is a combustible solid.Hazardous combustion products Carbon dioxide, carbon monoxide, hydrogen chloride, phosgene,smoke, fumes, unburned dichloromethane and hydrocarbons, aldehydes.Suitable extinguishing media Water spray, alcohol-resistant foam, dry chemical or carbon dioxide.Personal protective equipment Wear full-face, self-contained breathing apparatus and protectiveclothing.____________________________________________________________________________________________ 6.Accidental Release MeasuresPersonal precautions Use personal protective equipment, as detailed in Sections 7and 8.Avoid breathing vapors, mist, gas, or dust. Ensure adequate ventilation.Remove all sources of ignition. Evacuate personnel to safe areas.Beware of vapor accumulations in low areas, e.g., workpits andbasements.Environmental precautions Prevent further leakage or spillage if safe to do so. Do not allowspillage to enter drains, sewers, and natural waterways.Methods for cleaning up Do not touch with unprotected hand or walk through spilled material.Contain spillage, then collect with clean absorbant towelling or sand,earth, diatomaceous earth, or vermiculite, and place the sorbed materialin a container which will allow the drying of the Liquid StressKote in awell-ventilated, unoccupied area. It is possible, the sorbed Dried BrittleCoating may be offered as ordinary industrial waste for disposal inaccordance with local regulations. However, the end user (wastegenerator) should ensure that any dibutylphthalate contained in the gumrosin derivatives matrix does not preclude the disposal of the driedmaterial as ordinary industrial waste.____________________________________________________________________________________________ 7. Handling and StorageDefinition:Respirator OSHA’s Occupational Safety and Health Standard for methylene chloride (MC, dichloromethane),29 CFR 1910.1052, section 1910.1052(g)(3) requires employers to (I) select, and provide toemployees, the appropriate atmosphere-supplying respirator specified in paragraph (d)(3)(i)(A) of29 CFR 1910.134; however, employers must not select or use half masks of any type because MCmay cause eye irritation or damage, and (ii), for emergency escape, provide employees with one ofPage 4 of 12the following respirator options: A self-contained breathing apparatus operated in the continuous-flow or pressure-demand mode; or a gas mask with an organic vapor canister. Hereinafter, the term“OSHA required respirator” shall mean a full-face respirator which complies with the requirementsset forth in these aforementioned OSHA standards.HandlingGeneral handling Avoid contact with eyes, skin and clothing. Avoid breathing vapor, mist, gas ordust. Do not swallow. Use only with adequate ventilation. Do not enter confinedspaces in which Liquid StressKote is being used or has recently been used,unless the space is adequately ventilated and an OSHA required respirator isworn. As the dichloromethane vapors evolved from Liquid StressKote are moredense (heavier) than air, lethal concentrations can develop in low, confined andunventilated spaces such as tanks, workpits, small rooms, and basements. Do notenter these confined spaces where Liquid StressKote vapors are suspected unlessan OSHA required regulator is worn and an observer is present for monitoringand assistance. Wash thoroughly after handling. Keep containers tightly closedwhen not in use. For the storage of Liquid StressKote, use the metal containersprovided in the original packaging or an equivalent container. When using theproduct, do not eat, drink or smoke. Take normal measures for preventative fireprotection , which includes keeping sources of ignition (e.g, open flames andincendive electrostatic discharges) away from the Liquid StressKote and itsvapors, and airborne dusts of Dried Brittle Coatings.Other precautions Liquid StressKote containers, even those that have been emptied, can containvapors. Do not cut, drill, grind, weld, or perform similar operations on or nearpartial or empty containers. Uncapped emptied containers awaiting properdisposal should be placed in well-ventilated areas free of ignition hazards. Storage Store tightly closed containers of the Liquid StressKote in a clean, dry, cool, well-ventilated place away from direct sunlight. Containers which have been opened must becarefully resealed and kept upright to prevent leakage.____________________________________________________________________________________________ 8.Exposure Controls/Personal ProtectionAbbreviations (initialisms and acronyms):CAS Chemical Abstracts Service, Registry NumberACGIH US American Conference of Governmental and Industrial HygienistsBEI Biological Exposure IndexSTEL Short-term Exposure LimitTLV TWA Threshold Limit Value Time-Weighted AverageNIOSH US Department of Health and Human Services - National Institute forOccupational Safety and HealthREL NIOSH Recommended Exposure LimitRTECS Registry of Toxic Effects of Chemical SubstancesOSHA US Department of Labor-Occupational Safety and Health AdministrationCEIL Ceiling LimitPEL Permissible Exposure Limit (PEL)MSHA US Department of Labor, Mine Safety and Health AdministrationIARC International Agency for Research on CancerNTP National Toxicology ProgramPage 5 of 12Definition:Regulated Area(s)“Regulated area” as defined in OSHA’s Occupational Safety and Health Standard formethylene chloride (MC, dichloromethane), 29CFR 1910.1052, section 1910.1052(b),means an area, demarcated by the employer, where an employee’s exposure to airborneconcentrations of MC exceeds or can reasonably be expected to exceed either the 8-hourTWA PEL or the STEL Currently, the 8-hour TWA PEL and STEL for methylenechloride are 25 and 125 ppm, respectively. Because toluene has a lower volatility andhigher action level vapor concentrations than methylene chloride, a regulated areaestablished for methylene chloride will serve as well for the toluene in Liquid StressKote.The Federal Register, Vol. 71, No. 39, p10343 (28FEB2006) provides additionalguidance to general industry employers on the establishment of Regulated Areas. Components with workplace control parametersPage 6 of 12Personal protective equipmentEmploy good industrial hygiene practices. Unless otherwise indicated, the followingrecommendations apply to both the Liquid StressKote and the Dried Brittle Coating in the form ofairborne dust.Engineering controls Establish a regulated area(s) with good ventilation (typically 10 air changes perhour) or other engineering controls to maintain airborne concentrations of vaporsor mists below the applicable exposure limits indicated in the table above, and tosafely expel any generated airborne dust. Exhaust systems should be designed tomove the air away from the source of vapor/mist generation and personnel. Allelectrical equipment should comply with the National Electric Code. Anemergency eye wash station and safety shower should be located near theregulated area where the Liquid StressKote and Dried Brittle Coating are used.Respiratory protection Wear an OSHA required respirator when using Liquid StressKote. Forprotection against airborne dust which may be generated during the mechanicalremoval of Dried Brittle Coating, a respirator specifically designed for particleentrapment is strongly recommended, and one of which is tested and approvedunder germane government standards (e.g., NIOSH).Hand protection Avoid skin contact. Use heavy duty gloves made of chemical resistant materialssuch as Viton®, or butyl rubber. Wash hands with plenty of mild soap or dishdetergent and water before eating, drinking, smoking, use of toilet facilities, orleaving work. DO NOT use gasoline, kerosene, solvents or harsh abrasives asskin cleaners.Eye protection Wear an OSHA required respirator, with its full-face protection, when usingLiquid StressKote. Safety glasses equipped with side shields are recommendedas minimum protection in industrial settings when handling or processingmaterials coated with Dried Brittle Coating.Body protection Use protective clothing chemically resistant to Liquid StressKote. Selection ofspecific items such as boots, apron, or a full body suit will depend upon theproduct’s use. If any of the Liquid StressKote contacts the skin, immediatelywipe the area with a clean cloth, then remove all residuals with soap and water.Consult a physician. Contaminated clothing must be removed immediately andwashed or dry cleaned before reuse. If the clothing is heavily contaminated, itshould be taken to a well-ventilated area to allow for the safe evaporation of thedichloromethane and toluene, then discarded appropriately.Ingestion Avoid ingestion of even very small amounts of either Liquid StressKote or theDried Brittle Coating. Do not consume or store food, beverages, or tobacco inthe regulated area or any contiguous work areas. Wash hands and face beforeeating, drinking or smoking.____________________________________________________________________________________________ 9. Physical and Chemical PropertiesAppearance Liquid StressKote is a clear (non-turbid), reddish-orange liquid, as supplied. The DriedBrittle Coating, as normally used for mechanical stress analysis, is optimally a 3-6 mil(0.08-0.15 mm) thick, smooth, shinny, copper or bronze colored film or coating.Page 7 of 12Odor Liquid StressKote produces vapors which have a sweet, chlorinated hydrocarbon andpungent, aromatic hydrocarbon odor. The intact Dried Brittle Coating is nearly odorless,but as a dust, has a pleasant gum rosin odor.pH No measurements made on either Liquid StressKote or Dried Brittle Coating.Melting point The Dried Brittle Coating has a melting range of 145-160 °C. A melting (freezing) point for the Liquid StressKote has not been measured.Boiling point42-44°C (108-111°F) at 760 torr (normal bp). Note: As dichloromethane and tolueneapparently do not form an azeotrope, 42-44°C more accurately marks the beginning of theboiling range for the Liquid StressKote, ending with the normal boiling point for puretoluene at 110.6°C (231°F).Flash point None The Liquid StressKote does not exhibit a TCT flash point as defined byASTM D56. A green halo, characteristic of thermal decomposition ofdichloromethane is observed around the test flame even at temperaturesapproaching 0°F.Ignition temperature400°C (750°F), estimated for the Dried Brittle Coating.Lower explosion limit No determination madeUpper explosion limit No determination madeVapor pressure41-43 kPa (310-320 torr, 0.41-0.42 atm) absolute at 20°C (68°F) and 79-81 kPa(590-610 torr, 0.78-0.80 atm) absolute at 37.8°C (100°F) for Liquid StressKote.Vapor density (air = 1)3 (Liquid StressKote vapor).Evaporation rate (acetone =1)2Water solubility Liquid Stresskote is miscible with water at concentrations less than 2% byweight (calculated), and the Dried Brittle Coating is insoluble.Density (20°C)Liquid StressKote: 1.25 ± 0.03 g/ml (H O 1.0 g/ml)2Dried Brittle Coating 1.07 ± 0.03 g/cm3____________________________________________________________________________________________ 10.Stability and Reactivity This section applies to both Liquid StressKote and Dried BrittleCoating, unless otherwise noted.Storage stability Stable under recommended storage conditions. Keep containers of LiquidStressKote tightly closed in a clean, dry, cool, well-ventilated place away fromdirect sunlight. Containers which have been opened must be carefully resealedand kept upright to prevent leakage.Conditions to avoid Heat, flames and sparks.Materials to avoid Liquid Stresskote can react with alkali metals (Na, K), strong oxidizing agents,strong bases, amines, powdered zinc, aluminum and magnesium. Watercontamination may cause corrosion of ferrous metals due to the formation ofhydrochloric acid. As gum rosin derivatives can serve as pyrotechnic fuels,Page 8 of 12contact of the Dried Brittle Coating (especially in a particulate form) with strongoxidizing agents should be avoided.Hazardous decomposition products Hazardous decomposition products formed under fireconditions: Carbon dioxide, carbon monoxide, hydrogenchloride, phosgene, smoke, fumes, unburned dichloromethaneand hydrocarbons, aldehydes.Hazardous reactions Liquid StressKote vapors in large, enclosed spaces may formexplosive mixtures with air. Liquid StressKote does notundergo exothermic polymerization.____________________________________________________________________________________________ 11.Toxicological InformationDichloromethane, toluene and dibutylphthalate, the three hazardous components of Liquid StressKote, each have a unique set of oral, inhalation, and dermal toxicities. For each of the toxicity categories, the compound which has the highest value reported in the literature is considered to establish the toxicity of the mixture. Additional toxicity data may be available upon request.Acute toxicityIngestion (Oral)LD50, rat1,500 mg/kg(dichloromethane)3Inhalation LC50, rat, 4hr12,500 mg/m(toluene)Dermal LD50, guinea pig2,096 mg/kg(dibutylphthalate)LD50, rabbit12,196 mg/kg(toluene)Irritation and corrosionSkin rabbit skin irritation, 24 hr.(dichloromethane)Eyes rabbit severe irritation, 24 hr(toluene)Sensitization No data availableChronic exposureCarcinogenicity, rat inhalation(dichloromethane)Tumorigenic:Carcinogenic by RTECS criteria. Endocrine: TumorsGenotoxicity in vivo, rat oral (dichloromethane)DNA damage (dichloromethane)Developmental toxicity, rat oral Effects on embryo or fetus: Fetotoxicity (toluene)Reproductive toxicity, rat inhalation Paternal effects: Spermatogenesis, includinggenetic material, sperm morphology, motility, andcount (toluene)Liquid StressKote contains a component that has been reported to be possibly carcinogenic based on its IARC, ACGIH, NTP, OSHA, or EPA classification.IARC:Group 2The agent is possibly carcinogenic to humans (dichloromethane)NTP:Reasonably anticipated to be a human carcinogen (dichloromethane)Page 9 of 12OSHA:19.101.052 (dichloromethane)None of the components of StressKote is believed to pose a measurable carcinogenic risk to man when handled as recommended.Signs and symptoms of exposureDichloromethane Dichloromethane is metabolized in the body producing carbon monoxide whichincreases and sustains carboxyhemoglobin levels in the blood, reducing theoxygen-carrying capacity of the blood. It acts as a simple asphyxiant bydisplacing air. Anaesthetic effects include difficulty in breathing, headache, anddizziness. Prolonged or repeated contact with skin may cause defatting,dermatitis. Contact with the eyes can cause redness, blurred vision,conjunctivitis, and tearing. Effects due to ingestion may include gastrointestinaldiscomfort, central nervous system depression, paresthesia, drowsiness,convulsions, pulmonary edema through aspiration. Effects may be delayed.Toluene Lung irritation, chest pain, pulmonary edema. Inhalation studies on toluene havedemonstrated the development of inflammation and ulcerous lesions of the penis,prepuce, and scrotum in animals.Dibutyl phthalate Exposure can cause nausea, dizziness, and headache.Potential health effects See Section 3____________________________________________________________________________________________ 12.Ecological InformationElimination information (persistence and degradability)Both Liquid StressKote and Dried Brittle Coating should not be considered biodegradable. The bioconcentration factor (BCF) for dichloromethane is 2- 40, and it has a very high potential for soil mobility. No other data are available.Ecotoxicity effectsToxicity to fish(dichloromethane)96 hr LC50fathead minnow193 mg/l96 hr NOEC sheepshead minnow130 mg/l(toluene)96 hr LC50bluegill74-340 mg/l96 hr LC50rainbow trout7.63 mg/l7 d NOEC fathead minnow 5.44 mg/l7 d LOEC fathead minnow8.04 mg/l(dibutylphthalate)96 hr LC50fathead minnow0.92 mg/l96 hr LC50rainbow trout 1.6 mg/l96 hr LC50sheepshead minnow$0.6 mg/l96 hr LC50bluegill sunfish0.48 mg/lToxicity to daphnia(dichloromethane)48 hr EC50water flea1,682 mg/l(toluene)24 hr EC50water flea8 mg/l(dibutylphthalate)48 hr EC50daphnid 3 mg/lPage 10 of 12__________________________________________________________________________________________ 13.Disposal ConsiderationsProduct DO NOT DUMP UNUSED LIQUID STRESSKOTE OR THE DRIED BRITTLE COATING INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. Observe allfederal, state, and local environmental regulations. Regulations may vary with location. Wastecharacterization and compliance with applicable laws are the sole responsibility of the wastegenerator. If you characterize unused Liquid StressKote as waste, then contact a licensedprofessional waste disposal service to dispose of the material. Liquid StressKote may be destroyedby admixing with a combustible solvent and burning the mixture in a chemical incineratorequipped with an afterburner and scrubber. It is possible the Dried Brittle Coating may be offeredas ordinary industrial waste for disposal in accordance with local regulations. However, you, theend- user (waste generator) should ensure the occluded dibutylphthalate in the gum rosin derivativematrix does not preclude the disposal of the dried material as ordinary industrial waste. StressKoteBrittle Coatings, LLC has no control over the management practices or procedures of partieshandling or using Liquid StressKote or Dried Brittle Coating.Contaminated packaging Dispose of as Dried Brittle Coating.____________________________________________________________________________________________ 14.Transport Information This section applies only to Liquid StressKote. StressKote BrittleCoatings, LLC should be contacted directly for guidance on theshipping of Dried Brittle Coating.Shipping descriptions may vary based upon mode of transport, quantities, package size, origin and/or destination. Consult your company’s Hazardous Materials/Dangerous Goods expert for information specific to your situation. US DoT UN Number: 1593Class: 6.1Packing group: IIIProper shipping name:Dichloromethane SolutionIM DG UN Number 1593Class: 6.1Packing group: IIIProper shipping name:Dichloromethane Solution EMS-No: F-A, S-AMarine pollutant: Yes, dibutylphthalateIATA UN Number: 1593Class: 6.1Packing group: IIIProper shipping name:Dichloromethane Solution____________________________________________________________________________________________ 15.Regulatory Information This section applies to Liquid StressKote and in some cases to DriedBrittle Coating.OSHA Hazards Toxic. Target Organ Effect (liver, kidneys, pancreas, eyes, blood), Harmful by ingestion, Irritant, Possible carcinogen and tetratogen. May cause harm to unborn child.TSCA Status Dichloromethane, toluene, and dibutylphthalate are TSCA Inventory items.CEPA DSL Status Dichloromethane, toluene, and dibutylphthalate are listed on the Canadian DomesticSubstances List (DSL) under the Canadian Environmental Protection Act (CEPA).SARA 302 Components No chemicals in Liquid StressKote are subject to the reporting requirements of theSuperfund Amendments and Reauthorization Act, Title III, Section 302.SARA 313 Components Dichloromethane, toluene, and dibutylphthalate are subject to SARA Section 313reporting requirements, with De Minimis Limits of 0.1, 1.0, and 1.0, respectively.Page 11 of 12。