Detonating Cord化学安全资料表
制品安全データーシート(产品安全数据表日文版)
製品安全データーシート第一部分：化学物質名称化学物質中国語名称：二氯甲烷（ジクロロメタン）化学物質英語名称：dichioromethane中国語名称2：(洗浄剤)英語名称2：技術説明書番号：753CAS NO：75-09-2分子式：CH2CL2分子量：84、94第二部分：組成、成分情報有害物質成分ジクロロメタン(塩化メチレン)含有量≥99.0%CAS NO 1975-09-2第三部分：危険有害性の要約危険有害性情報：麻酔作用がある。
中枢神経と呼吸器の障害。
急性中毒：軽微な場合は目眩、頭痛、嘔吐、目と呼吸器の粘膜刺激などをいたす可能性がある。
眠気、化学性気管支炎をいたす場合もある。
重症な場合は意識不明、肺臓の腫れを致すおそれがある。
血液の中のヘモグロビン含有量が増える。
長期反復暴露による頭痛、無力、目眩、食欲減退、動作遅延、眠気。
皮膚に脱脂作用があり、乾燥、脱皮、アカギレ等を起こす因となる。
燃焼、爆発危険性：可燃、有毒、刺激性がある第四部分：救急処置皮膚接触：汚染された衣服を脱いで、多量の水と石鹸で皮膚を洗うこと。
目に入った場合：流動した清水または生理食塩水で注意深く洗うこと。
吸入した場合：空気の新鮮な場所に移動し、呼吸しやすい姿勢で休憩させること。
呼吸困難な場合、酸素吸入を行うこと。
呼吸停止な場合、即時人工呼吸を行うこと。
飲み込んだ場合：大量の温かい水を飲んで、吐き気をもよおすこと。
医師の診断、手当を受けること。
第五部分：消防措置危険特性：火または高熱の物質に接触すると、刺激性または有毒なフュームやガス(ホスゲン、塩化水素、塩素)を放出する。
湿気の多い空気に暴露すると、水解し微量の塩化水素を放出する。
照明のある場所に暴露すると、本品の水解を促進し、金属への腐食性を高めるおそれがある。
有害燃焼産物：二酸化炭素、塩化水素、ホスゲン消火方法：消防士は必ず有機ガス用防毒マスクと消防服を着用する。
風上から作業し、ミスト、蒸気、ガス等を吸入しない。
二乙烯三胺(DETA)物性安全数据表
DIETHYLENETRIAMINE (DETA)2/5/2008.Material Safety Data SheetValidation date ::Product name MSDS #00010093Product UseIntermediate.Huntsman Petrochemical CorporationP.O.Box 4980The Woodlands,TX 77387-4980TELEPHONE NUMBERS Transportation Emergency Company:(800)328-8501CHEMTREC:(800)424-9300Medical Emergency:(409)722-9673(24Hour)General MSDS Assistance:(281)719-6000Technical Information:(281)719-7780E-MAIL:MSDS@:Physical state Liquid.[Liquid.]:Odor:Amine-like.OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29CFR 1910.1200).GENERAL INFORMATION Read the entire MSDS for a more thorough evaluation of the hazards.:Emergency overviewWARNING !CAUSES EYE AND SKIN BURNS.CAUSES RESPIRATORY TRACT IRRITATION.MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED.ASPIRATION HAZARD IF SWALLOWED -CAN ENTER LUNGS AND CAUSE DAMAGE DO NOT ADD NITRITES -MAY FORM SUSPECTED CANCER CAUSING NITROSAMINES Corrosive to eyes and skin.Causes burns.Harmful in contact with skin and if swallowed.Irritating to respiratory system.May cause sensitization by inhalation and skin contact.Do not breathe vapor or mist.Do not ingest.Do not get in eyes or on skin or e only with adequate ventilation.Keep container tightly closed and sealed until ready for use.Wash thoroughly after handling.:Diethylenetriamine111-40-060-100NameCAS number %Get medical attention immediately.Wash out mouth with water.Move exposed person to fresh air.Do not induce vomiting unless directed to do so by medical personnel.Chemical burns must be treated promptly by a physician.Never give anything by mouth to an unconscious person.Get medical attention immediately.Immediately flush eyes with plenty of water,occasionally lifting the upper and lower eyelids.Check for and remove any contact lenses.Continue to rinse for at least 10minutes.Chemical burns must be treated promptly by a physician.Get medical attention immediately.Flush contaminated skin with plenty of water.Remove contaminated clothing and shoes.Wash contaminated clothing thoroughly with water before removing or wear gloves.Continue to rinse for at least 10minutes.Chemical burns must be treated promptly by a physician.In the event of any complaints or symptoms,avoid further exposure.Wash clothing before reuse.Clean shoes thoroughly before reuse.Get medical attention immediately.Move exposed person to fresh air.If it is suspected that fumes are still present,the rescuer should wear an appropriate mask or self-contained breathing apparatus.Keep person warm and at rest.If not breathing,ifbreathing is irregular or if respiratory arrest occurs,provide artificial respiration or oxygen by trained personnel.It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.If unconscious,place in recovery position and get medical attention immediately.Maintain an open airway.Loosen tight clothing such as a collar,tie,belt or waistband.In case of inhalation of decomposition products in a fire,symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48hours.Eye contactSkin contactInhalationIngestionNotes to physician:Symptomatic and supportive therapy as needed.Following severe exposure medical follow-up should be monitored for atleast 48hours.Decomposition products may include the following materials:carbon oxides nitrogen oxidesUse an extinguishing agent suitable for the surrounding fire.Products of combustionExtinguishing media Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.No action shall be taken involving any personal risk or without suitable training.In a fire or if heated,a pressure increase will occur and the container may burst.Special protectiveequipment for fire-fightersFire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)with a full face-piece operated in positive pressure mode.::Special exposure hazards:None known.Suitable :Not suitable:Flash point:Closed cup:98°C (208.4°F)No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas.Keep unnecessary and unprotected personnel from entering.Do not touch or walk through spilled material.Avoid breathing vapor or mist.Provide adequate ventilation.Wear appropriate respirator when ventilation is inadequate.Put on appropriate personal protective equipment (see section 8).Stop leak if without risk.Move containers from spill area.Approach release from upwind.Prevent entry into sewers,water courses,basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible,absorbent material e.g.sand,earth,vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13).Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilled product.Note:see section 1for emergency contact information and section 13for waste disposal.Environmental precautions:Avoid dispersal of spilled material and runoff and contact with soil,waterways,drains and rm the relevant authorities if the product has caused environmental pollution (sewers,waterways,soil or air).Personal precautions:Methods for cleaning up:Store in accordance with local regulations.Store in original container protected from direct sunlight in a dry,cool and well-ventilated area,away from incompatible materials (see section 10)and food and drink.Separate from acids.Keep container tightly closed and sealed until ready for use.Containers that have been opened must be carefullyresealed and kept upright to prevent leakage.Do not store in unlabeled e appropriate containment to avoid environmental contamination.Put on appropriate personal protective equipment (see section 8).Eating,drinking and smoking should be prohibited in areas where this material is handled,stored andprocessed.Workers should wash hands and face before eating,drinking and smoking.Persons with a history of skin sensitization problems or asthma,allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used.Do not get in eyes or on skin or clothing.Do not breathe vapor or mist.Do not e only with adequate ventilation.Wear appropriate respirator when ventilation is inadequate.Keep in the original container or an approved alternative made from a compatible material,kept tightly closed when not in use.Keep away from acids.Empty containers retain product residue and can be hazardous.Do not reuse container.HandlingStorage::DiethylenetriamineACGIH TLV (United States,1/2006).Skin TWA:4.2mg/m³8hour(s).TWA:1ppm 8hour(s).NIOSH REL (United States,12/2001).Skin TWA:4mg/m³10hour(s).TWA:1ppm 10hour(s).OSHA PEL 1989(United States,3/1989).TWA:4mg/m³8hour(s).TWA:1ppm 8hour(s).Product name Exposure limitsConsult local authorities for acceptable exposure limits.Preventive MeasuresConditions of use,adequacy of engineering or other control measures,and actual exposures will dictate the need for specific protective devices at your workplace.:Use a properly fitted,air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator.Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes,mists,gases or dusts.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Personal protection EyesSkinRespiratory:::Chemical-resistant,impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.Hands:respiratory equipment should be used in cases of insufficient ventilation or whereoperational procedures demand it.For guidance on engineering control measures refer to publications such as the ACGIH current edition of 'Industrial Ventilation,a manual of RecommendedPractice.'General information Appearance Physical state Color Odor Odor threshold ::::Liquid.[Liquid.]Colorless to light yellow.Amine-like.Not available.Important health,safety and environmental information pH Boiling point Melting point Flash pointOxidizing properties Vapor pressure Relative densityOctanol/water partition coefficient ViscosityVapor densityAuto-ignition temperature :395°C (743°F): 3.48[Air =1]:4cSt at 25°C -1.30.95<0.013kPa (<0.1mm Hg)Not available.Closed cup:98°C (208.4°F)<-20°C (<-4°F)199°C (390.2°F)12::::::::VOC content:Not available.The product is stable.Reactive or incompatible with the following materials:oxidizing materials,organic materials and metals.Not available.Stability and reactivityIncompatibility with various substancesHazardous polymerization ::Decomposition products may include the following materials:carbon oxides nitrogen oxidesHazardousdecomposition products:Toxicity dataAcute toxicityProduct/ingredient name Test Species Result Exposure Diethylenetriamine LD50Dermal Rabbit >1000mg/kg -LD50Oral Rat >1080mg/kg-Conclusion/Summary :Long term toxicity tests show no oncogenic potential.Ingestion :Harmful if swallowed.May cause burns to mouth,throat and stomach.Inhalation :Irritating to respiratory system.May cause sensitization by inhalation.Eyes :Corrosive to eyes.Causes burns.Skin:Corrosive to the skin.Causes burns.Harmful in contact with skin.May cause sensitization by skin contact.Potential acute health effects Potential chronic health effects Target organs :Carcinogenicity Mutagenicity TeratogenicityDevelopmental effects Fertility effects:::::No known significant effects or critical hazards.No known significant effects or critical hazards.No known significant effects or critical hazards.No known significant effects or critical hazards.No known significant effects or criticalhazards.None known.Environmental effects:Not readily biodegradable.This product shows a low bioaccumulation potential.Aquatic ecotoxicityProduct/ingredient name Test Diethylenetriamine-Acute EC5017mg/LDaphnia 48hours -Acute LC50332mg/LFish 96hours Result Species Exposure Product/ingredient name Aquatic half-life Photolysis Biodegradability Diethylenetriamine--Not readily Bioaccumulative potential Product/ingredient name LogP ow BCF Potential Diethylenetriamine -1.3-lowThe generation of waste should be avoided or minimized wherever possible.Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.Disposal of this product,solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regional local authority requirements.Avoid dispersal of spilled material and runoff and contact with soil,waterways,drains and sewers.Waste disposal:Transportation Emergency Number 1-800-424-9300(CHEMTREC).PG*:Packing groupCorrosive material Sensitizing materialU.S.Federal regulationsWHMIS (Canada)Class D-2A:Material causing other toxic effects (Very toxic).Class D-2B:Material causing other toxic effects (Toxic).Class E:Corrosive material ::::CanadaUnited StatesSARA 313United States inventory (TSCA 8b):All components are listed or exempted.This product does not contain nor is it manufactured with ozone depleting substances.CEPA (DSL):Canada inventory:All components are listed or exempted.California Prop 65:No ingredients listed.HCS Classification No ingredients listed.CERCLA:Hazardous substances.:No ingredients listed.information requiredby the CPR.Hazardous MaterialInformation System (U.S.A.)National Fire Protection Association (U.S.A.)CAUSES EYE AND SKIN BURNS.CAUSES RESPIRATORY TRACT IRRITATION.MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED.ASPIRATION HAZARD IF SWALLOWED -CAN ENTER LUNGS AND CAUSE DAMAGE DO NOT ADD NITRITES -MAY FORM SUSPECTED CANCER CAUSING NITROSAMINES Label requirements:Notice to readerDate of printingDate of issueDate of previous issue 2/5/2008.2/5/2008.No previous validation.:::::While the information and recommendations in this publication are to the best of our knowledge,information and belief accurate at the date of publication,NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY,EXPRESS OR OTHERWISE.IN ALL CASES,IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION.WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION,NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.Hazards,toxicity,and behavior of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes.Such hazards,toxicity and behavior should be determined by the user and made known to handlers,processors and end users.NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE,OR MAKE AVAILABLE,DATA SHEETS FOR HUNTSMAN PRODUCTS.DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM,OR BY ANY MEANS,WITHOUT PERMISSION IN WRITING FROM HUNTSMAN.ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN,MANAGER,PRODUCT SAFETY,AT THE ABOVE ADDRESS.13HealthInstabilityFlammability。
危险化学品信息表邻甲酚
其他储存安全要求
运输的安全要求
运输方式要求
□公路□铁路□管道□水路□其他
对运输工具的要求
对运输温度的要求
包装方法（包括外包装、内包装）
液态：小开口钢桶；玻璃瓶或塑料桶（罐）外普通木箱或半花格木箱；螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱；螺纹口玻璃瓶、塑料瓶或镀锡薄钢板桶（罐）外满底板花格箱、纤维板箱或胶合板箱。固态：塑料袋或二层牛皮纸袋外全开口或中开口钢桶；塑料袋或二层牛皮纸袋外普通木箱；螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶（罐）外普通木箱；螺纹口玻璃瓶、塑料瓶或镀锡薄钢板桶（罐）外满底板花格箱、纤维板箱或胶合板箱。
生态毒理学信息
数据
数据来源
备注
急性毒性（藻类、溞类、ห้องสมุดไป่ตู้类）
降解性
生物蓄积性（logkow或BCF）
其他生态毒理学性质
该物质对环境有危害，应特别注意对水体的污染。
主要用途
用途
用作分析试剂并用于有机合成。
限制的用途
应用的行业领域
危险特性
物理危险
本品可燃，高毒，具腐蚀性、强刺激性，可致人体灼伤。
健康危害
本品对皮肤、粘膜有强烈刺激和腐蚀作用。引起多脏器损害。
库温不超过30℃，相对湿度不超过70％。
禁配物
应与氧化剂、碱类、食用化学品分开存放，切忌混储。
安全操作要求
密闭操作，提供充分的局部排风。尽可能采取隔离操作。操作人员必须经过专门培训，严格遵守操作规程。建议操作人员佩戴头罩型电动送风过滤式防尘呼吸器，穿胶布防毒衣，戴橡胶手套。远离火种、热源，工作场所严禁吸烟。使用防爆型的通风系统和设备。避免产生粉尘。避免与氧化剂、碱类接触。搬运时要轻装轻卸，防止包装及容器损坏。配备相应品种和数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物。
雷达诺酸氯氯发射器核酸安全数据表第一页，9部分说明书
S afety D ata S heetSection 1: Product and Company Identification Product Name:Radnor Developer Nuclear Grade (Aerosol)Product Identifier: Nuclear Developer Product Use: NDT Developer Item Code(s): 64000206SDS Code: 031R Supplier:RadnorPhysical Address: 259 North Radnor - Chester Road - Suite 100Radnor, PA 19087-5283Emergency Phone: 866-734-3438Date of Preparation:March 21, 2019OSHA Regulatory Status: Regulated WHMIS Classification:A, B-5, D-2BSection 2: Hazard IdentificationClassification of the Substance or Mixture:Skin corrosion/irritationCategory 2 Serious eye damage/eye irritationCategory 2A Specific target organ toxicity (single exposure) Category 3 Specific target organ toxicity (repeated exposure) Category 2Flammable aerosols Category 1Gases under pressureCompressed GasMay be used to comply with OSHA’s Hazard Communication Standard, 29 CFR 1910.1200.U.S. Department of LaborOccupational Safety and Health Administration (Non-Mandatory Form). Format meets ANSI Z400.1-1998, OSHA 1910.1200 and WHMIS requirements.GHS Label Elements, Including Precautionary StatementsEmergency OverviewDANGERHazard StatementsCauses skin irritation.Causes serious eye irritation.May cause respiratory irritation. May cause drowsiness or dizziness.May cause damage to organs (Central Nervous System, Eyes, Respiratory System, and Skin ) through prolonged or repeated exposure.Extremely flammable aerosol.Contains gas under pressure; may explode if heated.Appearance: Opaque Physical State: Aerosol Odor:Light Vanilla Scent Precautionary Statements - PreventionWash face, hands and any exposed skin thoroughly after handling.Wear protective gloves/eye protection/face protection.Do not breathe dust/fume/gas/mist/vapors/sprayUse only outdoors or in a well-ventilated area.Keep away from heat/sparks/open flames/hot surfaces. — No smoking.Do not spray on an open flame or other ignition source.Pressurized container: Do not pierce or burn, even after use.Precautionary Statements - ResponseIF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.If EYE IRRITATION persists: Get medical advice/attention.IF ON SKIN: Wash with plenty of soap and water.If SKIN IRRITATION occurs: Get medical advice/attention.Take off contaminated clothing and wash before reuse.IF INHALED: Remove person to fresh air and keep comfortable for breathing.Call a POISON CENTER or doctor/physician if you feel unwell.Precautionary Statements - StorageStore locked up.Store in a well-ventilated place. Keep container tightly closed.Protect from sunlight. Do not expose to temperatures exceeding 50°C/122°F.Precautionary Statements - DisposalDispose of contents/container to an approved waste disposal plant.HAZARDS NOT OTHERWISE CLASSIFIED (HNOC): NoneOTHER INFORMATION• Toxic to aquatic life with long lasting effects• 0% of the mixture consists of ingredient(s) of unknown toxicitySection 3: Composition and Information on IngredientsChemical Name CAS-No Weight %* ISOPROPYL ALCOHOL 67-63-0 30-40 PROPANE/ISOBUTANE/N-BUTANE 68476-86-8 20-30ACETONE 67-64-1 20-30ZINC STEARATE 67762-34-9 1-10 SURFACE TREATED SILICA 68611-44-9 1-10 *The exact percentage (concentration) of composition has been withheld as a trade secret. Section 4: First Aid MeasuresFirst Aid Measures for Different Exposure RoutesGENERAL ADVICE: Avoid contact with eyes,skin, and clothing. Avoid breathing, vapors,mist,or gas.EYE CONTACT: In the case of contact with eyes, rinse immediately with plenty of water for 15 minutes and seek medical advice.SKIN CONTACT: Wash off immediately with soap and plenty of water. Get medical attention immediately if symptoms occur.INHALATION: Move to fresh air. If not breathing, give artificial respiration. If breathing has stopped, contact emergency medical services immediately.INGESTION: Do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an unconscious person. Risk of product entering the lungs on vomiting after ingestion.Most Important Symptoms/Effects, Acute and DelayedMAIN SYMPTOMS: Causes skin and eye irritation. May cause respiratory irritation. Inhalation causing Central Nervous System effects. Ingestion may cause lung damage.Indication of Immediate Medical Attention and Special Treatment Needed, if NecessaryNOTES TO PHYSICIAN: Treat symptomatically.Section 5: Fire Fighting MeasuresSUITABLE EXTINGUISHING MEDIA: Water fog. Dry chemical. Carbon dioxide (CO2). Cool containers / tanks with water spray.UNSUITABLE EXTINGUISHING MEDIA: Do not use a solid water stream as it may scatter and spread fire. SPECIFIC HAZARDS ARISING FROM THE CHEMICAL: Flammable or extremely flammable aerosol. Container may burst in fire.Explosion DataSENSITIVITY TO MECHANICAL IMPACT: None.SENSITIVITY TO STATIC DISCHARGE: Yes.PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIREFIGHTERS: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Use shielding to protect fire-fighters from bursting containers.Section 6: Accidental Release MeasuresPersonal Precautions, Protective Equipment and Emergency ProceduresPERSONAL PRECAUTIONS: Use with adequate ventilation to keep the exposure levels below the OELS. Environmental PrecautionsENVIRONMENTAL PRECAUTIONS: Report spills as required by local and federal regulations.Methods and Materials for Containment and Cleaning UpMETHODS FOR CONTAINMENT: Prevent further leakage or spillage if safe to do so.METHODS FOR CLEANING UP: Contain liquid and collect with an inert, non-combustible material.Section 7: Handling and StoragePrecautions for Safe HandlingADVICE ON SAFE HANDLING: Avoid contact with eyes. Avoid breathing vapors or mists. Contents under pressure. Do not puncture or incinerate cans. Do not stick pin or any other sharp object into opening on top of can. Avoid skin contact. Use with adequate ventilation. Keep container away from heat, flames, and all other sources of ignition. Keep can away from all sources of electricity such as electric motors and batteries. Do not spray on hot surfaces.Conditions for Safe Storage, Including Any IncompatibilitiesTECHNICAL MEASURES/STORAGE CONDITIONS: Keep containers tightly closed in a dry, cool and well-ventilated place.INCOMPATIBLE PRODUCTS: Store away from strong oxidizers and acids.AEROSOL LEVEL: 3Section 8: Exposure Controls / Personal ProtectionChemical Name ACGIH TLV OSHA PEL NIOSH IDLH ISOPROPYL ALCOHOL STEL: 400ppm TWA: 400 ppm IDLH: 2000 ppm 67-63-0 TWA: 200 ppm TWA: 980 mg/m3TWA: 400 ppm(vacated) TWA: 400 ppm TWA: 980 mg/m3(vacated) TWA: 980 mg/m3STEL: 500 ppm(vacated) STEL: 500 ppm STEL: 1225 mg/m3(vacated) STEL: 1225 mg/m3PROPANE/ISOBUTANE/ 74-98-6: TWA: 1000 ppm 74-98-6:TWA: 1000 ppm 74-98-6:IDLH: 2100 ppm N-BUTANE 106-97-8: STEL: 1000 ppm TWA: 1800 mg/m3TWA: 1000 ppm68476-86-8 75-28-5: STEL: 1000 ppm (vacated) TWA: 1000 ppm TWA: 1800 mg/m3(vacated) TWA: 1800 mg/m3106-97-8:TWA: 800 ppm106-97-8: (vacated) TWA: 800 ppm TWA: 1900 mg/m3(vacated) TWA: 1900 mg/m375-28-5:TWA: 800 ppmTWA: 1900 mg/m3 ACETONE STEL: 750 ppm TWA: 1000 ppm IDLH: 2500 ppm67-64-1 TWA: 500 ppm TWA: 2400 mg/m3TWA: 250 ppm(vacated) TWA: 750 ppm TWA: 590 mg/m3(vacated) TWA: 1800 mg/m3(vacated) STEL: 2400 mg/m3The acetone STEL does notapply to the cellulose acetatefiber industry. It is in effectfor all other sectors(vacated) STEL: 1000 ppmACGIH: (American Conference of Governmental Industrial Hygienists)OSHA: (Occupational Safety & Health Administration)NIOSH IDLH: Immediately Dangerous to Life or HealthOTHER EXPOSURE GUIDELINES: Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992).Exposure ControlsENGINEERING MEASURES: Ventilation systems. Use adequate ventilation to keep the exposure levels below the OELs. Individual Protection Measures, such as Personal Protective EquipmentEYE/FACE PROTECTION: Safety glasses with side-shields.SKIN AND BODY PROTECTION: Chemical resistant apron. Protective gloves.RESPIRATORY PROTECTION: If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. HYGIENE MEASURES: Handle in accordance with good industrial hygiene and safety practiceSection 9: Physical and Chemical PropertiesPHYSICAL STATE: AerosolAPPEARANCE: OpaqueODOR: Light Vanilla ScentODOR THRESHOLD: No information availableCOLOR: WhiteProperty Values Remarks • MethodspH: No information available Not applicable MELTING/FREEZING POINT: No information availableBOILING POINT/BOILING RANGE: No information availableFLASH POINT: -96.4°C / -141°F Based on propellant EVAPORATION RATE: No information availableFLAMMABILITY (SOLID, GAS): No information availableFLAMMABILITY LIMITS IN AIR:Upper Flammability Limit : No information availableLower Flammability Limit: No information availableVAPOR PRESSURE: No information availableVAPOR DENSITY: No information availableSPECIFIC GRAVITY: 0.757WATER SOLUBILITY: Practically insolublePARTITION COEFFICIENT: n-octanol/water No information availableAUTO-IGNITION TEMPERATURE: No information available Not applicable DECOMPOSITION TEMPERATURE: No information availableVISCOSITY: No information availableEXPLOSIVE PROPERTIES: No information availableOther informationVOC CONTENT (%): 64.83Section 10: Stability and ReactivityREACTIVITY: No data availableCHEMICAL STABILITY: Stable under recommended storage conditions.POSSIBILITY OF HAZARDOUS REACTIONS: None under normal processing.CONDITIONS TO AVOID: Extremes of temperature and direct sunlight.INCOMPATIBLE MATERIALS: Store away from strong oxidizers and acids.HAZARDOUS DECOMPOSITION PRODUCTS: Carbon oxides.Information on Likely Routes of ExposurePRODUCT INFORMATION: Product does not present an acute toxicity hazard based on known informationINHALATION: Exposure to high vapor concentrations may cause nervous systems effects such as headache, nausea, and dizziness.EYE CONTACT: Irritating to eyes.SKIN CONTACT: Irritating to skin. Prolonged skin contact may defat the skin and produce dermatitis.INGESTION: Not acutely toxic. Aspiration into the lungs during swallowing may cause serious lung damage which may be fatal.Component InformationChemical Name LD50 Oral LD50 Dermal LC50 Inhalation ISOPROPYL ALCOHOL= 1870 mg/kg ( Rat ) = 4059 mg/kg ( Rabbit ) = 72600 mg/m3 ( Rat ) 4 h 67-63-0ACETONE = 5800 mg/kg 20,000 mg/kg (Rabbit) = 50100 mg/m3 ( Rat ) 8 h67-64-1Information on Toxicological EffectsSYMPTOMS: Symptoms of overexposure may be headache, dizziness, tiredness, nausea, and vomiting. Causes eye and skin irritation. Prolonged or repeated exposure may cause dermatitis. May respiratory system irritation. May be fatal if swallowed and enters airways.Delayed and Immediate Effects as well as Chronic Effects from Short and Long-Term ExposureSKIN CORROSION/IRRITATION: Irritating to skin.EYE DAMAGE/IRRITATION: Irritating to eyes.SENSITIZATION: No information available.GERM CELL MUTAGENICITY: No information available.CARCINOGENICITY: There are no known carcinogenic chemicals in this product.REPRODUCTIVE TOXICITY: The ingredients are not reproductive hazards.SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (SINGLE EXPOSURE): May cause respiratory irritation. May cause drowsiness and dizziness.SPECIFIC TARGET ORGAN SYSTEMIC TOXICITY (REPEATED EXPOSURE): May cause damage to organs through prolonged or repeated exposure.CHRONIC TOXICITY: Intentional misuse by deliberately concentrating and inhaling contents may be harmful or fatal. Chronic hydrocarbon abuse has been associated with irregular heart rhythms and potential cardiac arrest. Prolonged skin contact may defat the skin and produce dermatitis.TARGET ORGAN EFFECTS: Central Nervous System, Eyes, Respiratory System, Skin.ASPIRATION HAZARD: No information available.Numerical Measures of Toxicity - Product InformationUNKNOWN ACUTE TOXICITY: 0% of the mixture consists of ingredient(s) of unknown toxicityThe following values are calculated based on chapter 3.1 of the GHS document .ATEmix (oral): 920 mg/kgATEmix (dermal): 2501 mg/kgATEmix (inhalation-dust/mist): 72.6 mg/lATEmix (inhalation-vapor): 106 mg/lEcotoxicityChemical Name Toxicity to algae Toxicity to fish Toxicity to Toxicity to daphnia andmicroorganisms other aquatic invertebrates ISOPROPYL ALCOHOL 1000 mg/L EC50 11130 mg/L LC50 - 13299 mg/L EC50 Daphnia 67-63-0 Desmodesmus subspicatus Pimephales promelas magna 48h96h 96h static1000 mg/L EC50 9640 mg/L LC50Desmodesmus subspicatus Pimephales promelas72h 96h flow-through1400000 μg/L LC50Lepomis macrochirus 96hPROPANE/ISOBUTANE/ - - - -N-BUTANE68476-86-8ACETONE - 4.74 - 6.33 mL/L LC50 - 10294 - 17704 mg/L EC50 67-64-1 Oncorhynchus mykiss 96h Daphnia magna 48h Static6210 - 8120 mg/L LC50 12600 - 12700 mg/L EC50Pimephales promelas Daphnia magna 48h96h static8300 mg/L LC50Lepomis macrochirus 96hPERSISTENCE AND DEGRADABILITY: No information available.BIOACCUMULATION: No information available.Chemical Name log PowISOPROPYL ALCOHOL 0.0567-63-0PROPANE/ISOBUTANE/N-BUTANE 2.868476-86-8ACETONE -0.2467-64-1OTHER ADVERSE EFFECTS: No information availableSection 13: Disposal ConsiderationsWaste TreatmentWASTE DISPOSAL METHODS: Dispose of in accordance with federal, state, and local regulations. CONTAMINATED PACKAGING: Do not re-use empty containersSection 14: Transportation InformationDOT Ground : CONSUMER COMMODITY ORM-DorLIMITED QUANTITYIATA: UN1950, AEROSOLS, FLAMMABLE, 2.1, LTD. QTY.IMDG: UN1950, AEROSOLS, 2.1, LTD. QTY.INTERNATIONAL INVENTORIESChemical Name TSCA DSL/NDSL EINECS/ ENCS IECSC KECL PICCS AICSELINCSISOPROPYL ALCOHOL X X X X X X X XPROPANE/ISOBUTANE/N-BUTANE X X X Not listed X X X XACETONE X X X X X X X X ZINC STEARATE X X X Not listed X X Not listed Not listed SURFACE TREATED X X X X X X X X SILICALegend:TSCA - United States Toxic Substances Control Act Section 8(b) InventoryDSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances ListEINECS/ELINCS - European Inventory of Existing Commercial Chemical Substances/EU List of NotifiedChemical SubstancesENCS - Japan Existing and New Chemical SubstancesCHINA - China Inventory of Existing Chemical SubstancesKECL - Korean Existing and Evaluated Chemical SubstancesPICCS - Philippines Inventory of Chemicals and Chemical SubstancesAICS - Australian Inventory of Chemical SubstancesU.S. FEDERAL REGULATIONSSARA 313Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product contains a chemical or chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372:Chemical Name CAS-No Weight %* SARA 313 - ThresholdValues % ISOPROPYL ALCOHOL 67-63-0 30-40 1.0 67-63-0ZINC STEARATE 67762-34-9 1-10 1.067762-34-9SARA 311/312 Hazard CategoriesACUTE HEALTH HAZARD: YesCHRONIC HEALTH HAZARD: YesFIRE HAZARD: YesSUDDEN RELEASE OF PRESSURE HAZARD: YesREACTIVE HAZARD: NoClean Water ActThis product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42):Chemical Name CWA CWA CWA CWAReportable Quantities Toxic Pollutants Priority Pollutants Hazardous Substances ZINC STEARATE X67762-34-9CERCLAThis material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302):Chemical Name Hazardous Substances Extremely Hazardous RQRQs Substances RQsACETONE 5000 lb RQ 5000 lb final RQ67-64-1 RQ 2270 kg final RQ U.S. State RegulationsCalifornia Proposition 65This product does not contain any known Proposition 65 chemicals:U.S. State Right-to-Know RegulationsChemical Name New Jersey Massachusetts Pennsylvania ISOPROPYL ALCOHOL X X X 67-63-0ACETONE X X X67-64-1ZINC STEARATE X X67762-34-9EPA PESTICIDE REGISTRATION NUMBER: Not applicableCanadaThis product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the SDS contains all the information required by the CPR.Section 16: Other InformationNFPA: Health Hazard | 2 | Flammability | 4 | Instability | 0 | Physical and Chemical Hazards | - | HMIS: Health Hazard | 2 | Flammability | 4 | Physical Hazard | 1 | Personal Protection | B |This SDS format meets ANSI Z400.1-1998, OSHA 1910.1200 and WHMIS requirements. Radnor provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Product use and conditions of use are beyond the control of Radnor. Warranty of materials is limited to test results of product performance as detailed in certificates of compliance. Interpretation of test results is the responsibility of end-user. No other warranties, expressed or implied, are made.。
水溶液臭味除妥氧化物灌洗用品安全数据表说明书
SAFETY DATA SHEET 1. IdentificationProduct identifier: Water Based Malodor Air Freshener & DeodorizerOther means of identificationSDS number: RE1000037011Recommended restrictionsProduct Use: Air FreshenerRestrictions on use:Not known.Manufacturer/Importer/Distributor InformationManufacturerCompany Name: CLAIRE MANUFACTURING COMPANYAddress: 1000 Integram DrPacific, MO 63069Telephone: 1-630-543-7600Fax:Emergency telephone number: 1-866-836-88552. Hazard(s) identificationHazard ClassificationPhysical HazardsFlammable aerosol Category 1Label ElementsHazard Symbol:Signal Word:DangerHazard Statement: Extremely flammable aerosol.PrecautionaryStatementssources. No smoking. Do not spray on an open flame or other ignitionsource. Do not pierce or burn, even after use.Storage: Protect from sunlight. Do not expose to temperatures exceeding50°C/122°F.Hazard(s) not otherwiseNone.classified (HNOC):3. Composition/information on ingredientsMixturesChemical Identity CAS number Content in percent (%)*2-Propanol67-63-0 1 - <5%Nitrogen7727-37-9 0 - <0.1%4. First-aid measuresIngestion:Rinse mouth thoroughly.Inhalation: Move to fresh air.Skin Contact:Remove contaminated clothing and wash the skin thoroughly with soap andwater after work.Eye contact:Rinse immediately with plenty of water.Most important symptoms/effects, acute and delayedSymptoms: No data available.Hazards: No data available.Indication of immediate medical attention and special treatment neededTreatment:No data available.5. Fire-fighting measuresGeneral Fire Hazards: Use water spray to keep fire-exposed containers cool. Fight fire from aprotected location. Move containers from fire area if you can do so withoutrisk.Suitable (and unsuitable) extinguishing mediaSuitable extinguishingmedia:Use fire-extinguishing media appropriate for surrounding materials.Unsuitable extinguishingmedia:Do not use water jet as an extinguisher, as this will spread the fire.Specific hazards arising from the chemical:Vapors may travel considerable distance to a source of ignition and flash back.Special protective equipment and precautions for firefighters Special fire fightingprocedures:No data available.Special protective equipment for fire-fighters: Firefighters must use standard protective equipment including flame retardant coat, helmet with face shield, gloves, rubber boots, and in enclosed spaces, SCBA.6. Accidental release measuresPersonal precautions,protective equipment and emergency procedures: Ventilate closed spaces before entering them. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Keep upwind.Methods and material for containment and cleaning up: Stop the flow of material, if this is without risk. Absorb with sand or other inert absorbent.Notification Procedures:ELIMINATE all ignition sources (no smoking, flares, sparks or flames inimmediate area). Stop leak if you can do so without risk.Environmental Precautions: Avoid release to the environment. Prevent further leakage or spillage if safeto do so. Do not contaminate water sources or sewer. Environmentalmanager must be informed of all major spillages.7. Handling and storagePrecautions for safe handling: Keep away from heat, hot surfaces, sparks, open flames and other ignitionsources. No smoking. Do not spray on an open flame or other ignitionsource. Do not pierce or burn, even after use. Do not handle until all safetyprecautions have been read and understood. Obtain special instructionsbefore use. Use personal protective equipment as required.Conditions for safe storage, including anyincompatibilities: Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Store locked up. Aerosol Level 18. Exposure controls/personal protectionOccupational Exposure LimitsChemical Identity Type Exposure Limit Values Source2-Propanol REL400 ppm980 mg/m3US. NIOSH: Pocket Guide to ChemicalHazards(2005)STEL400 ppm US. ACGIH Threshold Limit Values(2008)STEL500 ppm1,225 mg/m3US. OSHA Table Z-1-A (29 CFR 1910.1000)(1989)STEL500 ppm1,225 mg/m3US. Tennessee. OELs. Occupational ExposureLimits, Table Z1A(06 2008)TWA400 ppm980 mg/m3US. Tennessee. OELs. Occupational ExposureLimits, Table Z1A(06 2008)PEL400 ppm980 mg/m3US. OSHA Table Z-1 Limits for AirContaminants (29 CFR 1910.1000)(02 2006)TWA400 ppm980 mg/m3US. OSHA Table Z-1-A (29 CFR 1910.1000)(1989)STEL500 ppm1,225 mg/m3US. California Code of Regulations, Title 8,Section 5155. Airborne Contaminants(092006)AN ESL200 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)ST ESL2,000 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)STEL500 ppm1,225 mg/m3US. NIOSH: Pocket Guide to ChemicalHazards(2005)TWA200 ppm US. ACGIH Threshold Limit Values(2008)TWA PEL400 ppm980 mg/m3US. California Code of Regulations, Title 8,Section 5155. Airborne Contaminants(092006)AN ESL492 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)ST ESL4,920 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)1,2-Benzenedicarboxylic acid, 1,2-diethyl ester REL 5 mg/m3US. NIOSH: Pocket Guide to ChemicalHazards(2005)TWA 5 mg/m3US. ACGIH Threshold Limit Values(2008) TWA PEL 5 mg/m3US. California Code of Regulations, Title 8,Section 5155. Airborne Contaminants(092006)TWA 5 mg/m3US. OSHA Table Z-1-A (29 CFR 1910.1000)(1989)TWA 5 mg/m3US. Tennessee. OELs. Occupational ExposureLimits, Table Z1A(06 2008)ST ESL50 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL 5 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)Acetic acid, pentyl ester REL100 ppm525 mg/m3US. NIOSH: Pocket Guide to ChemicalHazards(2005)TWA50 ppm US. ACGIH Threshold Limit Values(2008)STEL100 ppm US. ACGIH Threshold Limit Values(2008)STEL100 ppm532 mg/m3US. California Code of Regulations, Title 8,Section 5155. Airborne Contaminants(092006)TWA PEL50 ppm266 mg/m3US. California Code of Regulations, Title 8,Section 5155. Airborne Contaminants(092006)TWA100 ppm525 mg/m3US. Tennessee. OELs. Occupational ExposureST ESL2,700 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)ST ESL500 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL50 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL270 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)PEL100 ppm525 mg/m3US. OSHA Table Z-1 Limits for AirContaminants (29 CFR 1910.1000)(02 2006)TWA100 ppm525 mg/m3US. OSHA Table Z-1-A (29 CFR 1910.1000)(1989)TWA20 ppm US. ACGIH Threshold Limit Values(2008) Bicyclo[3.1.1]hept-2-ene,2,6,6-trimethyl-ST ESL3,500 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)ST ESL630 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL63 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL350 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)TWA10 ppm US. ACGIH Threshold Limit Values(2008) Acetic acid, phenylmethylesterTWA PEL10 ppm61 mg/m3US. California Code of Regulations, Title 8,Section 5155. Airborne Contaminants(092006)ST ESL100 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL10 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)ST ESL610 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL61 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)STEL 2 ppm US. ACGIH Threshold Limit Values(03 2018) Benzene, 1,1'-oxybis- -Vapor.TWA 1 ppm US. ACGIH Threshold Limit Values(03 2018)PEL 1 ppm7 mg/m3US. OSHA Table Z-1 Limits for AirContaminants (29 CFR 1910.1000)(02 2006)TWA PEL 1 ppm7 mg/m3US. California Code of Regulations, Title 8,Section 5155. Airborne Contaminants(092006)REL 1 ppm7 mg/m3US. NIOSH: Pocket Guide to ChemicalHazards(2005)TWA 1 ppm7 mg/m3US. OSHA Table Z-1-A (29 CFR 1910.1000)(1989)Benzene, 1,1'-oxybis-ST ESL70 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL7 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)Benzene, 1,1'-oxybis- - TWA 1 ppm7 mg/m3US. Tennessee. OELs. Occupational ExposureBenzene, 1,1'-oxybis-ST ESL10 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL 1 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)TWA 5 ppm US. ACGIH Threshold Limit Values(01 2010) 2,6-Octadienal, 3,7-dimethyl-- Inhalable fraction andvapor.2,6-Octadienal, 3,7-dimethyl-ST ESL50 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)ST ESL310 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL31 µg/m3 US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)AN ESL 5 ppb US. Texas. Effects Screening Levels (TexasCommission on Environmental Quality)(112016)Biological Limit ValuesChemical Identity Exposure Limit Values Source40 mg/l (Urine)ACGIH BEL (03 2013)2-Propanol (acetone:Sampling time: End of shift atend of work week.)Appropriate EngineeringNo data available.ControlsIndividual protection measures, such as personal protective equipmentGeneral information:Use personal protective equipment as required. Personal protectionequipment should be chosen according to the CEN standards and indiscussion with the supplier of the personal protective equipment.Eye/face protection: Wear goggles/face shield.Skin ProtectionHand Protection:No data available.Other: No data available.Respiratory Protection:In case of inadequate ventilation use suitable respirator. Seek advice fromlocal supervisor.Hygiene measures:When using do not smoke. Observe good industrial hygiene practices. Donot handle until all safety precautions have been read and understood.Obtain special instructions before use.9. Physical and chemical propertiesAppearancePhysical state:liquidForm: Spray AerosolOdor: No data available.Odor threshold: No data available.pH: No data available.Melting point/freezing point: No data available.Initial boiling point and boiling range: Estimated 100 °CFlash Point: Estimated 12.2 °CEvaporation rate: No data available.Flammability (solid, gas): No data available.Upper/lower limit on flammability or explosive limitsFlammability limit - upper (%): No data available.Flammability limit - lower (%):No data available.Explosive limit - upper (%):No data available.Explosive limit - lower (%):No data available.Vapor pressure:7,584.233 - 8,963.1845 hPa (20 °C)Vapor density:No data available.Density: No data available.Relative density:No data available.Solubility(ies)Solubility in water:No data available.Solubility (other):No data available.Partition coefficient (n-octanol/water):No data available.Auto-ignition temperature:No data available.Decomposition temperature:No data available.Viscosity:No data available.10. Stability and reactivityReactivity: No data available.Chemical Stability: Material is stable under normal conditions. Possibility of hazardousNo data available.reactions:Conditions to avoid: Avoid heat or contamination.Incompatible Materials: No data available.Hazardous DecompositionNo data available.Products:11. Toxicological informationInformation on likely routes of exposureSkin Contact: No data available.Eye contact: No data available.Ingestion: No data available.Symptoms related to the physical, chemical and toxicological characteristics Inhalation: No data available.Skin Contact: No data available.Eye contact: No data available.Ingestion: No data available.Information on toxicological effectsAcute toxicity (list all possible routes of exposure)OralProduct: Not classified for acute toxicity based on available data.Specified substance(s):2-Propanol LD 50 (Rat):5.84 g/kgDermalProduct: Not classified for acute toxicity based on available data.Specified substance(s):2-Propanol LD 50:> 2,000 mg/kgInhalationProduct: Not classified for acute toxicity based on available data.Specified substance(s):2-Propanol LC 50:> 5 mg/lLC 50:> 20 mg/lRepeated dose toxicityProduct: No data available.Specified substance(s):2-Propanol NOAEL (Rat, Inhalation, >= 104 Weeks): 5,000 ppm(m) InhalationExperimental result, Key studySkin Corrosion/IrritationProduct: No data available.Specified substance(s):2-Propanol in vivo (Rabbit): Not Classified Experimental result, Key study Serious Eye Damage/Eye IrritationProduct: No data available.Specified substance(s):2-Propanol Rabbit, 1 d: Irritating.Respiratory or Skin SensitizationProduct: No data available.Specified substance(s):2-Propanol Skin sensitization:, in vivo (Guinea pig): Non sensitising CarcinogenicityProduct: No data available.IARC Monographs on the Evaluation of Carcinogenic Risks to Humans:No carcinogenic components identifiedUS. National Toxicology Program (NTP) Report on Carcinogens:No carcinogenic components identifiedUS. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050):No carcinogenic components identifiedGerm Cell MutagenicityIn vitroProduct: No data available.In vivoProduct: No data available.Reproductive toxicityProduct: No data available.Specific Target Organ Toxicity - Single ExposureProduct: No data available.Specific Target Organ Toxicity - Repeated ExposureProduct: No data available.Aspiration HazardProduct: No data available.Other effects: No data available.12. Ecological informationEcotoxicity:Acute hazards to the aquatic environment:FishProduct: No data available.Specified substance(s):2-Propanol LC 50 (Pimephales promelas, 96 h): 9,640 mg/l Experimental result, KeystudyAquatic InvertebratesProduct: No data available.Specified substance(s):2-Propanol LC 50 (Daphnia magna, 24 h): > 10,000 mg/l Experimental result, Key study Chronic hazards to the aquatic environment:FishProduct: No data available.Aquatic InvertebratesProduct: No data available.Toxicity to Aquatic PlantsProduct: No data available.Persistence and DegradabilityBiodegradationProduct: No data available.Specified substance(s):2-Propanol53 % (5 d) Detected in water. Experimental result, Key study BOD/COD RatioProduct: No data available.Bioaccumulative potentialBioconcentration Factor (BCF)Product: No data available.Partition Coefficient n-octanol / water (log Kow)Product: No data available.Mobility in soil: No data available.Known or predicted distribution to environmental compartments2-Propanol No data available.Nitrogen No data available.Other adverse effects: No data available.13. Disposal considerationsDisposal instructions: Discharge, treatment, or disposal may be subject to national, state, or locallaws.Contaminated Packaging: No data available.14. Transport informationDOTUN Number: UN 1950UN Proper Shipping Name: Aerosols, flammableTransport Hazard Class(es)Class: 2.1Label(s): –Packing Group: IIMarine Pollutant: NoEnvironmental Hazards: NoMarine Pollutant NoSpecial precautions for user: Not regulated.IMDGUN Number: UN 1950UN Proper Shipping Name: Aerosols, flammableTransport Hazard Class(es)Class: 2Label(s): –EmS No.:Packing Group: –Environmental Hazards: NoMarine Pollutant NoSpecial precautions for user: Not regulated.IATAUN Number: UN 1950Proper Shipping Name: Aerosols, flammableTransport Hazard Class(es):Class: 2.1Label(s): –Packing Group: –Environmental Hazards: NoMarine Pollutant NoSpecial precautions for user: Not regulated.15. Regulatory informationUS Federal RegulationsTSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) None present or none present in regulated quantities.CERCLA Hazardous Substance List (40 CFR 302.4):Chemical Identity Reportable quantity2-Propanol lbs. 100lbs. 10001,2-Benzenedicarboxylicacid, 1,2-diethyl esterAcetic acid, pentyl ester lbs. 5000lbs. 100Bicyclo[3.1.1]hept-2-ene,2,6,6-trimethyl-Superfund Amendments and Reauthorization Act of 1986 (SARA) Hazard categoriesFire HazardFlammable aerosolSARA 302 Extremely Hazardous SubstanceNone present or none present in regulated quantities.SARA 304 Emergency Release NotificationChemical Identity Reportable quantity2-Propanol lbs. 100lbs. 10001,2-Benzenedicarboxylicacid, 1,2-diethyl esterAcetic acid, pentyl ester lbs. 5000lbs. 100Bicyclo[3.1.1]hept-2-ene,2,6,6-trimethyl-SARA 311/312 Hazardous ChemicalChemical Identity Threshold Planning Quantity 2-Propanol10000lbs1,2-Benzenedicarboxylicacid, 1,2-diethyl ester10000lbsAcetic acid, pentyl ester10000lbsBicyclo[3.1.1]hept-2-ene,2,6,6-trimethyl-10000lbsAcetic acid, phenylmethylester10000lbsBenzene, 1,1'-oxybis-10000lbs2,6-Octadienal, 3,7-dimethyl-10000lbsNitrogen10000lbsSARA 313 (TRI Reporting)Chemical Identity Reportingthreshold forother usersReporting threshold formanufacturing andprocessing2-Propanol lbs lbs.Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130):Clean Water Act Section 311 Hazardous Substances (40 CFR 117.3)US State RegulationsUS. California Proposition 65This product contains chemical(s) known to the State of California to cause cancer and/or to cause birth defects or other reproductive harm.Methanone, diphenyl-Carcinogenic. 07 2012US. New Jersey Worker and Community Right-to-Know ActChemical Identity2-PropanolUS. Massachusetts RTK - Substance ListNo ingredient regulated by MA Right-to-Know Law present.US. Pennsylvania RTK - Hazardous SubstancesChemical Identity2-PropanolUS. Rhode Island RTKNo ingredient regulated by RI Right-to-Know Law present.International regulationsMontreal protocolNot applicableStockholm conventionNot applicableRotterdam conventionNot applicableKyoto protocolNot applicableInventory Status:Australia AICS: Not in compliance with the inventory.EINECS, ELINCS or NLP: Not in compliance with the inventory.Japan (ENCS) List: Not in compliance with the inventory.China Inv. Existing Chemical Substances: Not in compliance with the inventory.Korea Existing Chemicals Inv. (KECI): Not in compliance with the inventory.Canada NDSL Inventory: Not in compliance with the inventory.Philippines PICCS: Not in compliance with the inventory.New Zealand Inventory of Chemicals: Not in compliance with the inventory.Japan ISHL Listing: Not in compliance with the inventory.Japan Pharmacopoeia Listing: Not in compliance with the inventory.Mexico INSQ: Not in compliance with the inventory.Ontario Inventory: Not in compliance with the inventory.Taiwan Chemical Substance Inventory: Not in compliance with the inventory.Canada DSL Inventory List: On or in compliance with the inventory US TSCA Inventory: On or in compliance with the inventory 16.Other information, including date of preparation or last revisionIssue Date: 07/31/2019Revision Information:No data available.Version #: 1.0Further Information: No data available.Disclaimer: This information is provided without warranty. The information is believed tobe correct. This information should be used to make an independentdetermination of the methods to safeguard workers and the environment.。
材料安全数据清单(卡尔菲休试剂)
编号：页码：3/4
11、消防措施
危险特性：
灭火介质：
灭火方法：
注意事项：
12、泄露应急处理
应急人员：
化学工作者。
应急行动：
将所有人员撤离受影响的区域
消除方法：
对该区域加强通风。
注意事项：
13、废弃处理
废弃方法：
卡尔菲休废液要排入固定密封瓶中，按有害物质处理。不可敞口放置或任意排入下水道，以防污染环境。不要
１４％～２５％
碘
２．８％～５％
3、危险性概述（包括危害类别、侵入途径、健康危害、环境危害、燃爆信息等）：
试剂中含有极难闻恶臭气味和较大的毒性，有损于测试者的健康和环境
4、物理和化学特性
外观
PH值
熔点
沸点
燃点
临界压力
溶解性
其他
5、稳定性和反应性
稳定性
禁配物
避免接触条件
聚合危害
分解产物
存储条件：
在通风良好、干燥、安全且不受天气影响的地方密封存储。
存储注意事项：
存储区域内不应有燃性材料并远离频繁出入处和紧急出口。对于还未使用的试剂应保持密封完好。
9、接触控制/个人防护
接触控制：
当接触试剂建议带皮质的工作手套.
个人防护：
一般情况:不需要
10、急救措施（包括自救与互救）
人员若吸入试剂散发的恶臭气体，必须将其移到空气清新处，若已出现中毒现象，需送往医院急救。
附录B
（规范性附录）
材料安全数据清单
编号：页码：1/4
化学品名称
卡尔菲休试剂（不含吡啶）
化学品代码
管理部门
1、化学品标识及企业标识
名称
三甲基-戊二醇二异丁酸酯安全数据单-江苏德纳化学股份
2,2,4-三甲基-1,3-戊二醇二异丁酸酯SDS 安全数据单德纳化工滨海有限公司根据GHS第五修订版第一部分化学品及企业标识化学品中文名称2,2,4-三甲基-1,3-戊二醇二异丁酸酯化学品英文名称2,2,4 - trimethyl-1,3 - pentanediol diisobutyrate申请单位德纳化工滨海有限公司申请单位地址江苏省盐城市滨海经济开发区沿海工业园中山4路申请单位邮编224555申请单位传真号码+86-515-89192555申请单位应急电话+86-515-68897296生产单位德纳化工滨海有限公司生产单位地址江苏省盐城市滨海经济开发区沿海工业园中山4路生产单位邮编224555生产单位传真号码+86-515-89192555生产单位应急电话+86-515-68897296生效日期2015/01/05第二部分危险标识依据联合国《化学品分类与标签全球统一协调制度》（GHS）第五修订版，该产品无危险性。
第三部分成分/组成信息成分含量(%) CAS No. EC No.2,2,4-三甲基-1,3-戊二醇二异丁酸酯≥99.06846-50-0 229-934-9第四部分急救措施皮肤接触用肥皂和大量的水冲洗。
请教医生。
眼睛接触用大量水彻底冲洗至少15分钟并请教医生。
食入切勿给失去知觉者从嘴里喂食任何东西。
用水漱口。
请教医生。
吸入如果吸入，请将患者移到新鲜空气处。
如果停止了呼吸，给予人工呼吸。
就医。
第五部分消防措施有害燃烧产物碳氧化物灭火方法用水雾，耐醇泡沫，干粉或二氧化碳灭火。
灭火注意事项如必要的话，戴自给式呼吸器去救火。
第六部分泄漏应急处理个人防护措施使用个人防护设备。
防止吸入蒸汽、气雾或气体。
保证充分的通风。
将人员撤离到安全区域。
环境保护措施在确保安全的前提下，采取措施防止进一步的泄漏或溢出。
不要让产物进入下水道。
收容清除方法收集、处理泄漏物。
存放在合适的封闭的处理容器内。
第七部分操作与储存操作注意事项避免接触皮肤和眼睛。
列管物质一览表含管制浓度标准若毒化物未模板
列管物質一覽表( 含管制濃度標準) -若毒化物未達該濃度標準則無須視為列管毒化物質。
毒化物列管物質一覽表錫丹2-胺2-胺醋酸鹽2-胺鹽酸鹽1-胺丙烯二苯駢喃六氯啶乙八氯N-亞硝-正-甲硫三苯基錫三苯基-α-錫胺基硫註: 1、*: 僅限試驗、研究、教育用。
2、**: 多氯聯苯最低管制限量數量為十台( 含十台) 含毒性化學物質多氯聯苯之電容器或變壓器。
3、#: 石綿管制濃度標準為纖維狀、細絲狀或絨毛狀石綿含量達1%以上( 含1％) W/W者。
4、##: 光氣、異氰酸甲酯、氯以體積百分率( V/V) 表示。
5、管制濃度標準: 例1、「苯」表示含苯70 %以上( 含70 %) w/w者。
例2、「氰化鈉」表示含氰離子達1％以上( 含1 %) w/w者。
例3、「多氯聯苯」表示含多氯聯苯0.1％( 1000 ppm) 以上( 含0.1 %) w/w者。
6、最低管制限量: 鍍槽之鍍液及金屬表面處理槽之表面處理液, 不計入最低管制限量。
例1、含六價鉻達1 %以上( 含1 %) w/w三氧化鉻運作總量( 不含鍍槽之鍍液) 低於500公斤( 不含500公斤) 者, 運作量低於最低管制限量。
例2、含氰離子達1 %以上( 含1 %) w/w氰化鈉運作總量( 不含鍍槽之鍍液) 低於500公斤( 不含500公斤) 者, 運作量低於最低管制限量。
7、在攝氏二十五度以下恆溫製程處理中之二異氰酸甲苯及2,4-二異氰酸甲苯, 其五公噸以下數量均計為使用量。
8、毒性化學物質之運作, 其運作量低於( 不含本數) 最低管制限量並報經當地主管機關核可者, 不受本法第八條、第十一條、第十六條及第十七條規定之限制。
9、第四類毒性化學物質, 除依規定申報運作紀錄、釋放量紀錄、毒理相關資料( 包括物質安全資料表及毒性化學物質防災基本資料表) 及適用本法第二十三條、第二十九條、第三十三條、第三十四條規定外, 不受本法其它規定之限制。
10、毒性分類: 〝1〞表第一類毒性化學物質, 〝2〞表第二類毒性化學物質, 〝3〞表第三類毒性化學物質, 〝4〞表第四類毒性化學物質。
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DETONATING CORDDATE MARCH 2011 MSDS NO. C-1 PAGE 1 of 2 SECTION I Issued by the Safety and Compliance Dept.Austin Powder Company 25800 Science Park Drive Cleveland, Ohio 44122CHEMTREC (24HR Emergency Telephone), call1-800-424-9300- United States, Canada, Puerto Rico (U.S. Commonwealth) and the Virgin Islands (U.S. Territory).International callers, dial the U.S. access number followed by 1-703-527-3887 (Mexico access number 00). U.S. Maritime callers dial- 1-703-527-3887.For non-emergency assistance, call 216-464-2400TRADE NAME AND SYNONYMSLite Line, Scotch Cord, A-Cord, No. 40, No. 50No. 60, No.80 etc. Seismic Detonating Cord, Slide Line Series, Heavy Duty Series, Cordeau Detonant Fuse, Cord, Detonating, Flexible, Special 18, 25, 30,40 and 50.Detonating Cord C3SECTION II HAZARDOUS INGREDIENTSPETN, Pentaerythritol tetranitrate, C 5H 8N 4O 12, CAS No. 78-11-5SECTION III PHYSICAL DATABOILING POINT N/A VAPOR PRESSURE (mm Hg) Negligible at 200C SPECIFIC GRAVITY (H 2O = 1) 1.76 VAPOR DENSITY (Air = 1) N/A PERCENT VOLATILE BY VOL. (%) N/A EVAPORATION RATE: N/A SOLUBILITY IN WATER: NegligibleAPPEARANCE AND ODOR: Flexible cord with an explosive core of PETN protected within a textile casing covered by aseamless polyethylene jacket. PETN is a white crystalline solid. No odor.SECTION IV FIRE AND EXPLOSION DATAFLASH POINT:FLAMMABLE LIMITS: EXTINGUISHING MEDIA:SPECIAL FIREFIGHTING PROCEDURES:UNUSUAL FIRE AND EXPLOSION HAZARDS:N/A N/ASee belowDo not fight fire. Withdraw personnel immediately. Allow fire to burn itself out.May explode when subjected to fire or shock. Avoid toxic fumes from fire.SECTION V HEALTH HAZARD DATATHRESHOLD LIMIT VALUE: ACGIH: PETN-None OSHA : PETN-NoneEFFECTS OF OVEREXPOSURE: Ingestion of PETN may cause headache and nausea. PETN is a vasodilator and produces dilation of blood vessels.EMERGENCY AND FIRST AID PROCEDURES: FUMES: Remove to fresh air.IF INGESTED: Obtain medical attention immediately.DETONATING CORDDATE MARCH 2011 MSDS NO. C-1 PAGE 2 OF 2SECTION VI REACTIVITY DATA Issued by the Safety and Compliance Dept. STABILITY: Stable under normal conditions. May explode when subjected to fire or shock.INCOMPATIBILITY (MATERIALS TO AVOID): Avoid contact with strong acids or alkalies.HAZARDOUS DECOMPOSITION PRODUCTS: Gaseous nitrogen oxides and carbon oxides: Toxic decomposition products including carbon monoxide (CO) may migrate to off blast-site areas.HAZARDOUS POLYMERIZATON WILL NOT OCCUR.SECTION VII SPILL OR LEAK PROCEDURESSTEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Sweep up and dispose of all spilled material immediately. Do not permit smoking or open flames near spill site.WASTE DISPOSAL METHOD: Dispose of under direct supervision of a qualified person according to local, state and federal regulations. Call Austin Powder for recommendations and assistance. This material may become a hazardous waste under certain conditions and must be collected, labeled and disposed of per state and federal hazardous waste regulations. TRANSPORTATION EMERGENCIES involving spills, leaks, fires or exposures in the United States, Canada, Puerto Rico (U.S. Commonwealth) and the Virgin Islands (U.S. Territory): CALL CHEMTREC for emergencies only: 1-800-424-9300. International callers, dial the U.S. access number followed by 1-703-527-3887 (Mexico access number 00).U.S. Maritime callers dial- 1-703-527-3887. All calls are recorded.SECTION VIII SPECIAL PROTECTION INFORMATION:RESPIRATORY PROTECTION: VENTILATION: PROTECTIVE GLOVES:EYE PROTECTION:Not required under normal conditions.Not required under normal conditions.Not required except to prevent abrasive injuries. Not required under normal conditions.SECTION IX SPECIAL PRECAUTIONSCOMPLY WITH THE SAFETY LIBRARY PUBLICATION NO. 4 “WARNINGS AND INSTRUCTIONS" AS ADOPTED BY THE INSTITUTE OF MAKERS OF EXPLOSIVES.TRANSPORTATION, STORAGE AND USE MUST COMPLY WITH OSHA SAFETY AND HEALTH STANDARDS29CFR1910.109, APPLICABLE MSHA REGULATIONS, THE DOT AND HAZARDOUS MATERIALS REGULATIONS, BATF REQUIREMENTS AND STATE AND LOCAL TRANSPORTATION, STORAGE AND USE REGULATIONS AND ORDINANCES.DOT or IMDG proper shipping description: Cord, Detonating, Flexible, 1.1D, UN0065, PG IIMay be offered for transportation domestically and transported as Cord, Detonating (UN 0289), Division 1.4 compatibilitygroup D (1.4D) Explosives, if the explosive content does not exceed 100 grains per linear foot (21.3 grams per meter) and the gross weight of all packages of detonating cord does not exceed (45 KG) 99 pounds per vehicle. See 49 CFR 173.63The maximum recommended temperature for detonating cord is 1600F (710C). None of the components are listed in the 1987 IARC Monographs, Group 1, 2A or 2B as known, probable, or possible carcinogens, nor are they listed in the NTP annual report on carcinogens.。