德国拜耳TPU-US-60A10物质安全资料表
TPU牌号应用指南
普通系列TPU(硬度60A-64D)：（适合品牌：德国拜耳系列，台湾优得系列）适用于注射、挤出和吹塑成型的常规产品即泛指一般用途的TPU制品.这类制品需要的是TPU基本的物性要求:高的机械强度,好的成型性.在挤出成型中，即便成型时间很长，该系列牌号也不会出现结晶现象.主要应用包括脚轮、鞋跟、手把、按钮、气动管和波纹管等耐磨制品.快速成型系列TPU(硬度60A-64D)：（适合品牌：宝瑄，邦泰）这些牌号在注射成型时，还以快速成型、易脱模和极佳的流动性著称，令薄壁长流程制品的注射成型轻而易举.主要应用于：手机套，软管，鞋材，电线电缆高透明系列TPU(硬度60A-85A)：（拜耳3690A,拜耳3695A）该系列牌号都具有抗水解稳定性和特殊的紫外线保护性能超群.它们可以用于壁厚高达6毫米的透明注射制品成型.这些牌号还可以用于软管、平挤薄膜和型材挤出成型.耐紫外线(黄变) 系列TPU(硬度70A-64D)：（拜耳85085，拜耳优得UNY85A）在TPU的使用中,黄变无疑是最令人头疼的事情,尤其是高透明或白色的制品.此系列中产品除具备良好的物性之外特别添加耐黄变之成分,其耐黄等级为4.5以上.确保在耐紫外线(黄变)要求高的产品中使用无后顾之忧.挤出(押出) 级系列TPU(硬度75A-64D)：（德国拜耳，宝瑄，邦泰）以表面光泽度分为光面及雾面两种,成型性良好,表面无麻点.应用于弹性肩带、各种线材、装饰材料、运动器材、服装辅料、密封材料等领域.耐水解及耐腐蚀系列TPU(硬度60A-64D)：（德国拜耳，拜耳优得）注射和挤出牌号，具有高机械强度，同时具有改良的抗水解性和良好的低温柔韧性，在油、脂和溶剂中的溶涨性极小. 该系列牌号常被应用于各种挤出制品及高应力要求的结构部件.改进了压缩变形率、弹性、耐热性、耐水解性、抗油脂性能、抗微生物性能等.这些注射牌号首先也是最多地应用于汽车、机械工程以及工厂设备中的一些功能部件.。
TPU 德国拜耳 DESMOPAN 150物性表
英制
410 - 446 ° F 68.0 - 104 ° F 122 ° F
测试方法
描述性属性 可用性：亚太、欧洲、印度、中东/非洲、南美洲和中美洲 效率。热扩散率（平方米/秒） 8E-08 特点 脱模剂 形式 微丸 过程 注塑成型
50％
@温度 70.0° C
50％
@温度 158° F
热性能
比热容 热导率
公制
1.70 J/g-° C 0.139 W / mK 的
英制
0.406 BTU/lb-° F。 0.965 BTU-in/hr-ft“ - ° F
测试方法
融化 融化
加工性能
熔融温度 模具温度 脱模温度
公制
210 - 230 ° C 20.0 - 40.0 ° C 50.0 ° C
密度
公制
1.03 克/立方厘米 1.24 克/立方厘米
英制
0.0372 磅/³ 0.0448 磅/³
测试方法
融化 ISO 1183
力学性能
硬度，A 邵氏 D 硬度， 磨损 压缩永久变形
公制
96 50 30 25％，
温度 23.0° C
英制
96 50 30 25％，
温度 73.4° F
测试方法
ISO 868 ISO 868 ISO 4649 ISO 815 ISO 815
宝瑞塑胶
拜耳材料科技 DESMOPAN®150 聚氨酯 类别： 聚合物，热塑性聚氨酯，TP 材质说明：注塑级、具有机械强度高的文章受到磨损、圆柱形颗粒、不透明到半透明 应用：压路机轮胎、耦合元件、鞋跟 预处理 最大。含水量 = 0.05％ 干燥温度 70-110°C 干燥时间 干式空气干燥机 1-2 小时 物理性质
德国拜耳热塑性弹性体TPU-U-75AP物质安全资料表
化学品安全技术说明书 （MSDS ）UTECHLLAN U-75AP10 112000021497/1.0发行日期：2007年06月25日(第01次修正) 第 1 /4 页••1. 化学品及企业标识化学品中文名称： 热塑聚氨酯化学品英文名称： thermoplastic polyurethane 商品中文名称 ：商品英文名称 ： UTECHLLAN U-75AP10 化学品俗名：产品应用：生产模制塑料产品制造商 / 供货商名称 ：拜耳（中国）有限公司 上海聚合物科研开发中心2. 成分／组成信息：纯品( * ) 混合物( )化学品名称：热塑聚氨酯（thermoplastic polyurethane）有害物成分：―― 含量：―― CAS No.：――3. 危险性概述：危险性类别：按GB13690-92《常用危险化学品的分类及标志》规定，本产品为非危险化学品。
根据EC指令67/548/EEC或1999/45/EC及其有效改编版和衍生的国家法规定义，该产品对健康和环境无害。
侵入途径：―― 健康危害：―― 环境危害：―― 燃爆危险：――4. 急救措施：皮肤接触：与热熔物接触立即用大量的水冷却。
既不能强制也不能使用溶剂除去粘在皮肤上的产品结皮。
为治疗可能引起的皮肤烫伤及对皮肤的彻底洁净，要立即就医。
室温下操作该产品参考以下信息：皮肤接触：用肥皂和大量的水彻底冲洗。
眼睛接触：―― 吸 入：―― 食 入：――5. 消防措施：危险特性：――有害燃烧产物：燃烧过程中释放一氧化碳、二氧化碳、氮氧化物和痕量的氰化氢。
灭火方法及灭火剂：水，泡沫，干粉。
灭火注意事项：着火和/或爆炸时，禁止吸入烟雾。
消防人员必须佩戴自供气式呼吸器。
禁止让污染的灭火流水进入土壤、地下水或地表水。
化学品安全技术说明书 （MSDS ）UTECHLLAN U-75AP10 112000021497/1.0发行日期：2007年06月25日(第01次修正) 第 2 /4 页••6. 泄漏应急处理：个人防护：戴防护设备（见第8部分）。
FDA规格拜耳TPU
No
No
No
No
Also available in black
Hydraulic Seals, auto and industrial components
Excellent moldability
Toplifts, seals, gaskets, sleeves, casters, gears, industrial No
Boots, animal tags, seals, pads, tubing, cable jacketing,
Yes
No
No
No
heat and UV stabilized
sheet, profiles, general industrial
Good hydrolytic stability/ excellent microbe resistance
Profile, sheet, general industrial
No
No
No
No
Excellent hydrolytic stability;
Hose, tubing, shoe inserts, connectors, belting, general industrial, medical devices
Yes
Yes
Yes
Yes
Excellent hydrolytic stability; heat and UV stabilized
Hose, tubing, shoe inserts, connectors, belting, general industrial
Yes
No
No
No
Excellent hydrolytic stability; heat and UV stabililzed
MSDS-PU聚氨酯
MSDS-PU聚氨酯
安全数据表概述
本文档提供了聚氨酯的安全数据表（MSDS）信息。
聚氨酯是一种用于制造各种产品的合成材料，如涂料、粘合剂和弹性体。
本文档旨在提供必要的安全信息以及聚氨酯的物理和化学性质。
物理和化学性质
- 外观：黄色液体
- 密度：1.2 g/cm³
- 沸点：200 ℃
- 燃点：>120 ℃
- 溶解性：不溶于水、溶于有机溶剂
健康及安全信息
- 避免吸入蒸气，气雾或烟。
- 避免与皮肤接触，可能引起皮肤刺激。
- 避免眼睛接触，可能引起眼睛刺激。
- 如意外吸入或误食，请立即寻求医疗帮助。
操作和贮存
- 储存于阴凉、干燥处。
- 避免阳光直射。
- 避免高温、火源。
- 充分通风的地方使用。
环境信息
本产品对环境可能造成影响。
避免将本产品排入下水道、河流或者海洋等水体中。
采取措施防止产生或可能出现的环境风险。
急救措施
如果产生眼睛或皮肤刺激，请立即用大量水清洗。
如果吸入过量，请将受害者移到空气清新的地方。
如情况恶化，请立即寻求医疗帮助。
结论
聚氨酯是一种广泛使用的化学品，需要特别注意安全问题。
使用前请详细阅读本文档所提供的MSDS信息，了解其物理和化学性质，并按照操作和贮存要求进行储存和使用，以确保人身安全以及
对环境的保护。
同时，在使用过程中如出现异常情况，请及时采取应急措施并立即寻求医疗帮助。
LORD E-105黑色物质安全数据表说明书
USA SAFETY DATA SHEET3000000034161. CHEMICAL PRODUCT AND COMPANY IDENTIFICATIONProduct name: LORD E-105 BLACK Product Use/Class:Epoxy ResinLORD Corporation 111 LORD DriveCary, NC 27511-7923 USATelephone: 814 868-3180Non-Transportation Emergency: 814 763-2345 Chemtrec 24 Hr Transportation Emergency No.800 424-9300 (Outside Continental U.S. 703 527-3887)EFFECTIVE DATE: 11/18/20202. HAZARDS IDENTIFICATIONGHS CLASSIFICATION:Flammable liquids Category 4Acute toxicity Inhalation - Dust and Mist Category 4 - 86.4% of the mixture consists of ingredient(s) of unknown toxicity.Acute toxicity Inhalation - Vapours Category 4 - 86.4% of the mixture consists of ingredient(s) of unknown toxicity. Skin corrosion/irritation Category 2Serious eye damage/eye irritation Category 2A Skin sensitization Category 1Germ cell mutagenicity Category 2 Carcinogenicity Category 2Reproductive toxicity Category 2Specific target organ systemic toxicity (repeated exposure) Category 2 TestesSpecific target organ systemic toxicity (repeated exposure) Category 1 Respiratory system Hazardous to the aquatic environment - acute hazard Category 2 Hazardous to the aquatic environment - chronic hazardCategory 2GHS LABEL ELEMENTS: Symbol(s)Signal WordD ANGERHazard StatementsCombustible liquid. Harmful if inhaled. Causes skin irritation.Causes serious eye irritation.May cause an allergic skin reaction. Suspected of causing genetic defects. Suspected of causing cancer.Suspected of damaging fertility or the unborn child.May cause damage to organs through prolonged or repeated exposure.(Testes)Causes damage to organs through prolonged or repeated exposure.(Respiratory system) Toxic to aquatic life.Toxic to aquatic life with long lasting effects.Precautionary StatementsPreventionKeep away from heat/sparks/open flames/hot surfaces. - No smoking.Obtain special instructions before use.Do not handle until all safety precautions have been read and understood.Wear protective gloves/protective clothing/eye protection/face protection.Use personal protective equipment as required.Do not breathe dust/fume/gas/mist/vapors/spray.Wash thoroughly after handling.Do not eat, drink or smoke when using this product.Use only outdoors or in a well-ventilated area.Contaminated work clothing should not be allowed out of the workplace.Avoid release to the environment.ResponseIn case of fire: refer to section 5 of SDS for extinguishing media.Call a POISON CENTER or doctor/physician if you feel unwell.Specific treatment (see supplemental first aid instructions on this label).IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.IF ON SKIN: Wash with plenty of soap and water.If skin irritation or rash occurs: Get medical advice/attention.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing.Take off contaminated clothing and wash before reuse.Collect spillage.StorageStore in a well-ventilated place. Keep cool.Store locked up.Disposal:Dispose of contents/container in accordance with waste/disposal laws and regulations of your country or particular locality.Other Hazards:This product contains component(s) which have the following warnings; however based on the GHS classification criteria of your country or locale, the product mixture may be outside the respective category(s).Acute: Vapor harmful; may affect the brain or nervous system causing dizziness, headache or nausea. Possibleirritation of the respiratory system can occur causing a variety of symptoms such as dryness of the throat, tightness of the chest, and shortness of breath. May cause central nervous system depression characterized by the followingprogressive steps: headache, dizziness, staggering gait, confusion, unconsciousness or coma. Significantoverexposure to n-butyl glycidyl ether by the inhalation route is unlikely under most ambient conditions due to its low volatility. However, vapors, aerosols, and mists may be formed during some applications such as heating orapplications of uncured material on large surface areas. Harmful if absorbed through skin. May be harmful ifswallowed. Ingestion is not an expected route of entry in industrial or commercial uses.Chronic: IARC has designated carbon black as Group 2B - inadequate evidence for carcinogenicity in humans, but sufficient evidence in experimental animals. In 2006 IARC reaffirmed its 1995 finding that there is "inadequateevidence" from human health studies to assess whether carbon black causes cancer in humans. Further,epidemiological evidence from well-conducted investigations has shown no causative link between carbon black exposure and the risk of malignant or non-malignant respiratory disease in humans.3. COMPOSITION/INFORMATION ON INGREDIENTSChemical Name CAS Number RangeEpoxy resin PROPRIETARY - 90%N-Butyl glycidyl ether2426-08-6 - 15%Carbon black1333-86-4 - 1%Any "PROPRIETARY" component(s) in the above table is considered trade secret, thus the specific chemical and its exact concentration is being withheld.4. FIRST AID MEASURESFIRST AID - EYE CONTACT: Flush eyes immediately with large amount of water for at least 15 minutes holding eyelids open while flushing. Get prompt medical attention.FIRST AID - SKIN CONTACT: Flush contaminated skin with large amounts of water while removing contaminated clothing. Wash affected skin areas with soap and water. Get medical attention if symptoms occur.FIRST AID - INHALATION: Move person to fresh air. Restore and support continued breathing. If breathing is difficult, give oxygen. Get immediate medical attention.FIRST AID - INGESTION: If swallowed, do not induce vomiting. Call a physician or poison control center immediately for further instructions. Never give anything by mouth if victim is rapidly losing consciousness, unconscious or convulsing.5. FIRE-FIGHTING MEASURESSUITABLE EXTINGUISHING MEDIA: Carbon Dioxide, Dry Chemical, Foam, Water FogUNSUITABLE EXTINGUISHING MEDIA: Not determined for this product.SPECIFIC HAZARDS POSSIBLY ARISING FROM THE CHEMICAL: Combustible liquid and vapor. During a fire, irritating and/or toxic gases and particulate may be generated by thermal decomposition or combustion. Keep containers tightly closed. Isolate from heat, electrical equipment, sparks, open flame, and other sources of ignition. Closed containers may rupture when exposed to extreme heat. Use water spray to keep fire exposed containers cool.SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS FOR FIRE-FIGHTERS: Wear full firefighting protective clothing, including self-contained breathing apparatus (SCBA). Water spray may be ineffective. If water is used, fog nozzles are preferable.6. ACCIDENTAL RELEASE MEASURESPERSONAL PRECAUTIONS, PROTECTIVE EQUIPMENT AND EMERGENCY PROCEDURES: Remove all sources of ignition (flame, hot surfaces, and electrical, static or frictional sparks). Avoid contact. Avoid breathing vapors. Use self-contained breathing equipment.ENVIRONMENTAL PRECAUTIONS: Do not contaminate bodies of water, waterways, or ditches, with chemical or used container.METHODS AND MATERIALS FOR CONTAINMENT AND CLEANUP: Keep non-essential personnel a safe distance away from the spill area. Notify appropriate authorities if necessary. Avoid contact. Contain and remove with inert absorbent material and non-sparking tools. Before attempting cleanup, refer to hazard caution information in other sections of the SDS form.7. HANDLING AND STORAGEHANDLING: Keep closure tight and container upright to prevent leakage. Avoid skin and eye contact. Wash thoroughly after handling. Avoid breathing of vapor or spray mists. Do not handle until all safety precautions have been read and understood. Empty containers should not be re-used. Use with adequate ventilation. Because empty containers may retain product residue and flammable vapors, keep away from heat, sparks and flame; do not cut, puncture or weld on or near the empty container. Do not smoke where this product is used or stored.STORAGE: Do not store or use near heat, sparks, or open flame. Store only in well-ventilated areas. Do not puncture, drag, or slide container. Keep container closed when not in use. Refer to OSHA 29CFR Part 1910.106 "Flammable and Combustible Liquids" for specific storage requirements.INCOMPATIBILITY: Strong acids, bases, and strong oxidizers.8. EXPOSURE CONTROLS/PERSONAL PROTECTIONCOMPONENT EXPOSURE LIMITChemical Name ACGIH TLV-TWA ACGIH TLV-STELOSHA PEL-TWAOSHA PEL-CEILINGSkinEpoxy resin N.E.N.E.N.E. N.E.N.A.N-Butyl glycidyl ether 3 ppm N.E.270 mg/m350 ppmN.E.SCarbon black 3 mg/m3N.E. 3.5 mg/m3 N.E.N.A.N.A. - Not Applicable, N.E. - Not Established, S - Skin DesignationEngineering controls: Sufficient ventilation in pattern and volume should be provided in order to maintain air contaminant levels below recommended exposure limits. Caution: Solvent vapors are heavier than air and collect in lower levels of the work area.PERSONAL PROTECTION MEASURES/EQUIPMENT:RESPIRATORY PROTECTION: Use a NIOSH approved chemical/mechanical filter respirator designed toremove a combination of particulates and organic vapor if occupational limits are exceeded. For emergencysituations, confined space use, or other conditions where exposure limits may be greatly exceeded, use an approved air-supplied respirator. For respirator use observe OSHA regulations (29CFR 1910.134) or use in accordance with applicable laws and regulations of your country or particular locality.SKIN PROTECTION: Use neoprene, nitrile, or rubber gloves to prevent skin contact.EYE PROTECTION: Use safety eyewear including safety glasses with side shields and chemical goggles where splashing may occur.OTHER PROTECTIVE EQUIPMENT: Use disposable or impervious clothing if work clothing contamination is likely. Remove and wash contaminated clothing before reuse.HYGIENIC PRACTICES: Wash hands before eating, smoking, or using toilet facility. Do not smoke in anychemical handling or storage area. Food or beverages should not be consumed anywhere this product is handled or stored. Wash thoroughly after handling.9. PHYSICAL AND CHEMICAL PROPERTIESTypical values, not to be used for specification purposes.ODOR: Odorless VAPOR PRESSURE: N.D.APPEARANCE: Black VAPOR DENSITY: Heavier than Air PHYSICAL STATE: Liquid LOWER EXPLOSIVE LIMIT: Not ApplicableFLASH POINT: 165 °F, 73 °CSetaflash Closed CupUPPER EXPLOSIVE LIMIT: Not Applicable BOILING RANGE: 169 °C EVAPORATION RATE: Not Applicable AUTOIGNITION TEMPERATURE:N.D.DENSITY: 1.12 g/cm3 (9.32 lb/gal) DECOMPOSITION TEMPERATURE:N.D. VISCOSITY, DYNAMIC: N.D.ODOR THRESHOLD: N.D.VISCOSITY, KINEMATIC: N.D.SOLUBILITY IN H2O: Insoluble VOLATILE BY WEIGHT: 0.00 %pH: N.A.VOLATILE BY VOLUME: 0.00 %FREEZE POINT: N.D. VOC CALCULATED: 0 lb/gal, 0 g/l COEFFICIENT OF WATER/OILDISTRIBUTION:N.D.LEGEND: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined10. STABILITY AND REACTIVITYHAZARDOUS POLYMERIZATION: Hazardous polymerization will not occur under normal conditions.STABILITY: Product is stable under normal storage conditions.CONDITIONS TO AVOID: High temperatures. Sources of ignition.INCOMPATIBILITY: Strong acids, bases, and strong oxidizers.HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide11. TOXICOLOGICAL INFORMATIONEXPOSURE PATH: Refer to section 2 of this SDS.SYMPTOMS:Refer to section 2 of this SDS.TOXICITY MEASURES:Chemical Name LD50/LC50Epoxy resin Oral LD50: Rat11,400 mg/kgN-Butyl glycidyl ether Oral LD50: Rat2,050 mg/kgDermal LD50: Rat> 2,150 mg/kgInhalation LC50: Rat2590 ppm/4 hCarbon black Oral LD50: Rat> 15,400 mg/kgDermal LD50: Rabbit> 3 g/kgGHS LC50 (vapour): Acute toxicity point estimate55 mg/l Germ cell mutagenicity: Category 2 - Suspected of causing genetic defects.Components contributing to classification: N-Butyl glycidyl ether.Carcinogenicity: Category 2 - Suspected of causing cancer.Components contributing to classification: N-Butyl glycidyl ether.Reproductive toxicity: Category 2 - Suspected of damaging fertility or the unborn child.Components contributing to classification: N-Butyl glycidyl ether.12. ECOLOGICAL INFORMATIONECOTOXICITY:Chemical Name EcotoxicityEpoxy resin Invertebrates: Daphnia magna1.7 mg/l48 hN-Butyl glycidyl ether N.D.Carbon black N.D.PERSISTENCE AND DEGRADABILITY:Not determined for this product.BIOACCUMULATIVE: Not determined for this product.MOBILITY IN SOIL: Not determined for this product.OTHER ADVERSE EFFECTS: Not determined for this product.13. DISPOSAL CONSIDERATIONSDISPOSAL METHOD: Disposal should be done in accordance with Federal (40CFR Part 261), state and local environmental control regulations. If waste is determined to be hazardous, use licensed hazardous waste transporter and disposal facility.14. TRANSPORT INFORMATIONUS DOT RoadProper Shipping Name: Environmentally hazardous substances, liquid, n.o.s.Hazard Class: 9SECONDARY HAZARD: NoneUN/NA Number: 3082Packing Group: IIIEmergency Response Guide Number: 171For US DOT non-bulk road shipments this material may be classified as NOT REGULATED. For the mostaccurate shipping information, refer to your transportation/compliance department regarding changes inpackage size, mode of shipment or other regulatory descriptors.IATA CargoPROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s.Hazard Class: 9HAZARD CLASS: NoneUN NUMBER: 3082PACKING GROUP: IIIEMS: 9LIMDGPROPER SHIPPING NAME: Environmentally hazardous substance, liquid, n.o.s.Hazard Class: 9HAZARD CLASS: NoneUN NUMBER: 3082PACKING GROUP: IIIEMS: F-AThe listed transportation classification applies to non-bulk shipments. It does not address regulatory variations due to changes in package size, mode of shipment or other regulatory descriptors. For the most accurate shipping information, refer to your transportation/compliance department.15. REGULATORY INFORMATIONU.S. FEDERAL REGULATIONS: AS FOLLOWS:SARA SECTION 313This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372.:NoneTOXIC SUBSTANCES CONTROL ACT:INVENTORY STATUSThe chemical substances in this product are on the TSCA Section 8 Inventory.EXPORT NOTIFICATIONThis product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the United States:None16. OTHER INFORMATIONUnder HazCom 2012 it is optional to continue using the HMIS rating system. It is important to ensure employees have been trained to recognize the different numeric ratings associated with the HazCom 2012 and HMIS schemes.HMIS RATINGS - HEALTH: 2 FLAMMABILITY: 2 PHYSICAL HAZARD: 1* - Indicates a chronic hazard; see Section 2Revision: Section 2, Section 11, Section 12Effective Date: 11/18/2020DISCLAIMERThe information contained herein is, to the best of our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no guarantee of results, and assume no liability for damages incurred byuse of this material. It is the responsibility of the user to comply with all applicable federal, state and local laws and regulations.。
食品级TPU
金 橙 塑 胶内部资料
(2)TPU 台湾优得
60D-64D
U-85A
23
U-90A
25
UT-95A
25
UT-90AU10 27
UT-60D
28
(3)TPU 台湾南亚
95A-60D
(4)TPU 南韩：
95-98A
60D
S185A
S195A
S398A
(5)TPU 台湾虹溢
85-95AI
AE
AT
(6)TPU 德国拜耳
65A-98A
64D
28
(9)TPU 德国巴斯夫
1185A
22
1190A
25
1195A
22
685A
690AU
B95A
26
C59D
C60AW
C70AW
C80A
C90A
28
C95A
Hale Waihona Puke 26C98AS60AW
S95A
25
德国拜耳 TPU 德国巴斯夫 TPU 台湾亿何 TPU 台湾优
得 TPU
金 橙 塑 胶内部资料
H-18,1kg 载 荷 1000 分循环
ISO
4649
Die "C"
ISO 34
23℃
ISO 178
---
ISO 974
---
DMA
Rate A
ISO 306
---
ISO 1183
测试数据
85 34.5 500 5.3 11.7 65 16
35
87.6 27.6 < -68 -42 91 1.20
机械 性能
朗盛产品资料
及纤维的极佳粘合剂, 并且改善动摩擦系 牌号的溶液可应用在粘合剂 , 密封
数。产品牌号包括一系列的粘度及交联
件, 凃覆和摩擦材料。
度。
食物接触：
可向朗盛德国 HSEQ 部门索取 FDA 和
BfR 认可的资料。
______________________________________________________________________________________________________
拜耳平 (Baypren®) 氯丁橡胶（CR）
产品规格和一般物理性能
品种
结晶度
通用型 巯基－改性牌号 拜耳平 110
拜耳平 111
很轻微 极轻微
性能： 只要胶料配制及加工正确,产品具有良好的耐 候性、耐臭氧、耐老化、耐热空气和耐化学 药品的性能；耐油类和耐石油性能也相当 好。产品也具有良好的机械性能、生理性能 及耐磨性。 若选择适当配方，可使拜耳平硫化胶的阻燃 性符合特殊需要。
产品规格和一般物理性能
品种
丙烯腈含量
（％）
羟基丁腈胶牌号 卡兰钠 X146 卡兰钠 X160 卡兰钠 X740 卡兰钠 X750
32.5 32.5 26.5 27
门尼粘度(1) ML (1+4) 100℃
45 ± 5 58 38 ± 4 47 ± 5
密度 （克/立方厘
米）
0.97 0.97 0.99 0.99
门尼粘度 (1) ML (1+4) 100℃
密度 （克/立方厘米）
外观
标准包装 (2)
备注
41 ± 5 49 ± 5
42 ± 5
1.23 1.23
拜耳平 112 拜耳平 210 拜耳平 211
德国拜耳TeXin-RXT50D医疗级TPU
德国拜耳TeXin-RXT50D医疗级TPUProduct Information TEXIN? RxT50DThermoplastic PolyurethaneAromatic Polyether-Based GradeDescription and ApplicationsTexin RxT50D resin is an aromatic polyether-based thermoplastic polyurethane. It can be processed by injection molding, extrusion or blow molding. Texin RxT50D offers outstanding abrasion resistance, impact strength, toughness and flexibility. It also exhibits excellent hydrolytic stability.Typical medical applications include anesthetic connectors, catheters, flexible tubing, film, seals and gaskets and extruded profiles.Medical ApplicationsBiocompatibility: Texin RxT50D resin meets the requirements of the FDA-modified ISO 10993, Part 1“Biological Evaluation of Medical Devices” tests with human tissue contact time of 30 days or less. Only products that meet these requirements may be considered candidates for applications requiring biocompatibility.Regrind must not be used in medical applications requiring biocompatibility.Manufacturer’s Responsibility: It is the responsibil-ity of the medical device, biological product or pharmaceutical manufacturer (“Manufacturer”) to determine the suitability of all component parts and raw materials, including Texin RxT50D resin, used in its final product in order to ensure safety and compli-ance with FDA requirements. This determination must include, as applicable, testing for suitability as an implant device and suitability as to contact with and/or storage of human tissueand liquids including, without limitation, medication, blood or other bodily fluids. Under no circumstances may Texin RxT50D resin be used in any cosmetic, reconstructive or reproductive implant applications. Nor may Texin RxT50D resin be used in any other bodily implant applications or any applications involving contact with or storage of human tissue, blood or other bodily fluids for greater than 30 days, based on FDA-modified ISO 10993, Part 1 “Biological Evaluation of Medical Devices” tests. Furthermore, for aromatic grades of Texin resins, such longer-term uses are not permissible because possible hydrolysis of solid polyurethane may produce aromatic amines, such as methylene dianiline (MDA).The suitability of a Bayer product in a given end-use environment is dependent upon various conditions including, without limitation, chemical compatibility, temperature, part design, sterilization method, re-sidual stresses and external loads. It is the responsi-bility of the Manufacturer to evaluate its final product under actual end-use requirements and to adequately advise and warn purchasers and users thereof.Single-use medical devices made from a Bayer product are not suitable for multiple uses. If the medical device is designed for multiple uses, it is the responsibility of the Manufacturer to determine the appropriate number of permissible uses by evaluating the device under actual sterilization and end-use conditions and to adequately advise and warn purchasers and users thereof.Sterilization: Parts molded or extruded from Texin RxT50D resin are sterilizable using ethylene oxide, radiation or dry heat. Parts made of Texin resins must not be sterilized using steam autoclaving or boiling water techniques. Furthermore, thesesteril-ization methods must not be used with aromatic grades of Texin resin because possible hydrolysis of solid polyurethane may produce aromatic amines, such as methylene dianiline (MDA).Page 1 of 3— Document contains important information and must be read in its entirety.The sterilization method and the number of steriliza-tion cycles a medical device made from TexinRxT50D resin can withstand will vary depending upon type/grade of product, part design, processing parameters, sterilization temperature and chemical environment. Therefore, the Manufacturer must evaluate each device to determine the sterilization method and the number of permissible sterilization cycles appropriate for actual end-use requirements and must adequately advise and warn purchasers and users thereof.Storage, Drying and Regrind UsageTexin thermoplastic polyurethane resins are hygro-scopic and will absorb ambient moisture. The resins should remain in their sealed containers and stored in a dry area. Storage temperatures should not exceed 86°F (30°C). Unused resin from opened containers, or reground material that is not to be used immedi-ately should also be stored in sealed containers under cool and dry conditions.Prior to processing, Texin RxT50D resin must be thoroughly dried for a minimum of 2 hours in a desiccant dehumidifying hopper dryer to a moisture content of less than 0.03%. Hopper inlet air tem-perature should be 200-220°F (93-104°C), the inlet air dew point should be 0°F (-20°C) or lower.Injection Molding, Extrusion and Blow Molding Conditions Typical starting conditions for injection molding, extrusion, and blow molding are noted below. It is recommended that initialprocessing is done at the lower end of the suggested temperature ranges and increased as necessary. Actual processing condi-tions will depend on machine size, mold design, material residence time, shot size, part geometry, etc.Typical Injection Molding ConditionsBarrel Temperatures:Rear…………………….........…385o-405oF (196o-207oC)Mid dle…………….........……… 390o-410oF (199o-210oC)Front……………….........…… 390o-410oF (199o-210oC)Nozzle…………………........ 395o-415oF (202o-213oC) Melt Temperature………….......…395o-415oF (202o-213oC) Mold Temperature………….......…… 60o-100oF (16o-38oC) Injection Press ure………..........………….6,000-15,000 psiHold Pressure………........….60-80% of Injection Pressure Back Pressure……….......……………………..800 psi max. Screw Speed……….........……………………….40-80 rpm Injection Speed……...........………………………. Moderate Cushion……………….......………………….…1/8 inch max Typical Temperature Profile forExtrusion and Blow MoldingRear (Feed)360o - 385oF (182o - 196oC) Middle (Transition)380o - 405oF (193o - 207oC) Front (Meter)380o - 405oF (193o - 207oC) Die380o - 415oF (193o - 213oC) Melt390o - 415oF (199o - 213oC)Regulatory Compliance InformationThe end uses of the product described in this bulletin must comply with applicable regulations, such as the FDA. If you have any questions on the regulatory status of these products, contact your Bayer Material Sc ience representative or Bayer’s Regulatory Affairs Manager in Pittsburgh, PA.Health and Safety InformationAppropriate literature has been assembled which provides information concerning the health and safety precautions that must be observed when handling Texin RxT50D resin. Before working with this product, you must read and become familiar with the available information on its hazards, proper use and handling. This cannot be overemphasized. Information is available in several forms, e.g., material safety data sheets and product labels. Consult your Bayer Material Science representative or contact Bayer’s Product Safety and Regulatory Affairs Department in Pittsburgh, PA.* These items are provided as general information only. They are approximate values and are not part of the product specifications.Page 2 of 3 —Document contains important information and must be read in its entirety.20483 9/08Bayer MaterialScience LLC100 Bayer Road ? Pittsburgh, PA 15205-9741 ? Phone: 1-800-662-2927 ? /doc/8216235472.html The manner in which you use and the purpose to which you put and utilize our products, technical assistance and information (whether verbal, written or by way of production evaluations), including any suggested formulations and recommendations are beyond our control. Therefore, it is imperative that you test our products, technical assistance and information to determine to your own satisfaction whether they are suitable for your intended uses and applications.This application-specific analysis must at least include testing to determine suitability from a technical as well as health, safety, and environmentalstandpoint. Such testing has not necessarily been done by us. Unless we otherwise agree in writing, all products are sold strictly pursuant to the terms of our standard conditions of sale. All information and technical assistance is given without warranty or guarantee and is subject to change without notice. It is expressly understood and agreed that you assume and hereby expressly release us from all liability, in tort, contract or otherwise, incurred in connection with the use of our products, technical assistance, and information. Any statement or recommendation not contained herein is unauthorized and shall not bind us.Nothing herein shall be construed as a recommendation to use any product in conflict with patents covering any material or its use. No license is implied or in fact granted under the claims of any patent.Sales Offices1000 Route 9 North, Suite 103, Woodbridge, NJ 07095-1200 ? 1-732-726-8988 ? Fax: 1-732-726-16722401 Walton Boulevard, Auburn Hills, MI 48326-1957 ? Phone: 1-248-475-7700 ? Fax: 1-248-475-7701Page 3 of 3 —Document contains important information and must be read in its entirety.Note: The information contained in this bulletin is current as of September 2008. Please contact Bayer MaterialScience to determine whether this publication has been revised.ASTM Units Texin RxT50DTypical Properties* Test Method U. S. SI U. S. SI for Natural Resin (Other) Conventional Metric Conventional Metric General Specific Gravity D 792 (ISO 1183) 1.15Shore Hardness D 2240 (ISO 868) D Scale 50D Melt Flow Index, typical value D 1238 (ISO 1193) 200°C/8.7kg g/10min 5Yellowness Index E 313 (DIN 6167)<10Taber Abrasion D 3489 (ISO 4649) H-18 wheel, 1000-g load, 1000 cycles mg Loss 75Mold Shrinkage at 100-mil Thickness: D 955 (ISO 2577) Flow Direction in/in (mm/mm) 0.008 Cross-Flow Direction in/in (mm/mm) 0.008Mechanical Tensile Strength D 412 (ISO 37) lb/in 2MPa 7,300 50.3Tensile Stress at 100 % Elongation D 412 (ISO 37) lb/in 2MPa 1,700 11.7Tensile Stress at 300 % Elongation D 412 (ISO 37) lb/in 2MPa2,100 14.5Ultimate Elongation D 412 (ISO 37) % 460Tear Strength, Die “C” D 624 (ISO 34) lbf/in kN/m 750 131.3Flexural Modulus D 790 (ISO 178) 73oF (23oC)lb/in 2MPa16,500113.8Compression Set (Post-cured**): D 395B (ISO 815) 22 hours at 158oF (70oC) %4022 hours at 73oF (23oC) % 15ThermalVicat Softening Temperature (Rate A) D 1525 (ISO 306)oFoC262128*These values are provided as general information only. They are approximate values and are not part of the product specifications.**Post-cured for 16 hours at 230oF (110oC).。
拜耳40613(1)
上海欧图服饰有限公司一：拜耳材料和其它材料相比好在什么地方、天气恶劣、水洗干洗、任性等。
□BAYER TPU（拜耳热塑性聚氨酯弹性体）是新兴的塑料品种，弹性耐拉伸，不变形。
□耐候性佳：特別是耐至負30℃，仍保有相當的彈性強度。
□环保性：无毒、无味，完全符合歐盟環保標準。
□耐化學性；適用於惡劣環境。
□耐磨性优异、耐臭氧性极好、硬度大、强度高、弹性好。
二：绳扣是什么材料，包括弹簧过检针、和其它做对比好在什么地方。
□有塑料PP, ABS, PA等。
□过检针弹簧，合乎欧美日的高标准安全检测规范。
□优势：采用环保材料；合乎人体工学的设计；精细的工艺外观。
三：金属配件材料，和其它对比好好在什么地方。
□锌合金压铸成形加上无镍电镀(合乎环保规范)，用于复杂曲面构造零件，呈现精致质感以增益商品价值。
□黄铜合金钣材冲压成形加上无镍电镀(合乎环保规范)，用于金属弹簧扣或裤钩等，具备古典金属轻盈质感可经久耐用。
□金属合金材料不仅物性稳定而且没有塑料件的老化问题，确保完全的功能。
附件是拜耳的悟性表，重要部分要我们翻译成中文。
□TPU（热塑性聚氨酯弹性体）是新兴的塑料品种，由于TPU具有良好的加工性、耐候性、环保性，被广泛应用于鞋材、管材、薄膜、滚轮、电缆电线等相关行业。
聚氨酯热塑性弹性体又称热塑性聚氨酯橡胶，简称TPU，是一种(AB)n型嵌段线性聚合物，A为高分子量(1000-6000)的聚酯或聚醚，B为含2-12直链碳原子的二醇，AB链段间化学结构是用二异氰酸酯，通常是MDI连接。
一般的结构式为见图。
热塑性聚氨酯橡胶靠分子间氢键交联或大分子链间轻度交联，随着温度的升高或降低，这两种交联结构具有可逆性。
在熔融状态或溶液状态分子间力减弱，而冷却或溶剂挥发之后又有强的分子间力连接在一起，恢复原有固体的性能。
聚氨酯热塑性弹性体有聚酯型和聚醚型两类，白色无规则球状或柱状颗粒，相对密度1〃10-1〃25，聚醚型相对密度比聚酯型小。
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化学品安全技术说明书 （MSDS ）UTECHLLAN US-60A10 112000022190/1.0-CN发行日期：2007年07月30日(第01次修正) 第 1 /4 页••1. 化学品及企业标识化学品中文名称： 热塑聚氨酯化学品英文名称： thermoplastic polyurethane 商品中文名称 ：商品英文名称 ： UTECHLLAN US-60A10 化学品俗名：产品应用：生产模制塑料产品制造商 / 供货商名称 ：拜耳（中国）有限公司 上海聚合物科研开发中心2. 成分／组成信息：纯品( ) 混合物( * )化学品名称：热塑聚氨酯（thermoplastic polyurethane）有害物成分：二苯甲酸二聚丙二醇酯（oxydipropyl dibenzoate） 浓度%：约28 CAS No.：27138-31-4EINECS No.：248-258-5 分类：N R51/53（根据定义原理分类） 由于此处列出的物质牢固键合于聚合物体系中，因此预计在正确操作时无有害影响。
3. 危险性概述：危险性类别：按GB13690-92《常用危险化学品的分类及标志》规定，本产品为非危险化学品。
根据EC指令2006/121/EC或1999/45/EC及其有效改编版和衍生的国家法规定义，该产品对健康和环境无害。
侵入途径：―― 健康危害：―― 环境危害：―― 燃爆危险：――4. 急救措施：皮肤接触：与热熔物接触立即用大量的水冷却。
既不能强制也不能使用溶剂除去粘在皮肤上的产品结皮。
为治疗可能引起的皮肤烫伤及对皮肤进行护理，要立即就医。
室温下操作该产品参考以下信息：皮肤接触：用肥皂和大量的水彻底冲洗污染部位。
眼睛接触：―― 吸 入：―― 食 入：――5. 消防措施：危险特性：――有害燃烧产物：燃烧过程中释放一氧化碳、二氧化碳、氮氧化物和痕量的氰化氢。
灭火方法及灭火剂：水，泡沫，干粉。
化学品安全技术说明书 （MSDS ）UTECHLLAN US-60A10 112000022190/1.0-CN发行日期：2007年07月30日(第01次修正) 第 2 /4 页••灭火注意事项：着火和/或爆炸时，禁止吸入烟雾。
消防人员必须佩戴自供气式呼吸器。
禁止让污染的灭火流水进入土壤、地下水或地表水。
6. 泄漏应急处理：个人防护：戴防护设备（见第8部分）。
颗粒－小心滑倒！确保充分的通风/排气。
令未经授权人员离开。
环境防护：禁止倒入地表水或生活污水系统。
消除方法：使用机械处理设备，避免形成粉尘。
清洗并装入合适的容器待处理。
其它处理措施见第13部分。
7. 操作处置与储存：操作注意事项：要充分通风，必要时如在开启新容器，干燥颗粒和加工处理本产品时，必须在工作区提供有效排气。
在推荐的操作条件下会产生少量的空气污染物。
应提供良好的通风和/或局部排气设备，（有害物浓度）不应超过第8部分引用的极限值，粉尘必须通过有效的排气通风除掉。
储存注意事项：保持容器干燥紧闭。
储存温度<40℃。
VCI储存级别：11（VCI＝德国化学工业协会）8. 接触控制／个体防护：最高容许浓度：根据GBZ2-2002《工作场所有害因素职业接触限值》，其它粉尘PC-TWA: 8mg/m 3; PC-STEL: 10mg/m 3。
监测方法：――工程控制：加工该产品时，尤其是在高温处理过程中要参考以下物质的有关法规，基于经验要在产生蒸气的区域保证有效新鲜空气的供给和提供足够的通风换气设施，以确保遵守以下所提供的极限值。
物质 CAS编号 依据 类型 数值 阈值 备注一般粉尘阈值 TRGS 900 10mg/m 32 吸入部分一般粉尘阈值 TRGS 900 3mg/m 32 以泡状气溶胶含量计算 一般粉尘阈值 TRGS 900 STEL CL类别II：物质有再吸收的影响 呼吸系统防护：产生粉尘时，使用符合DIN EN 143规定的带P1型颗粒过滤器的呼吸防护设备。
眼睛防护：戴眼罩/面罩。
身体防护：穿合适的防护服。
手防护：防护手套的合适材料；DIN EN 374-3 聚氯乙烯-PVC(≥0.5mm)。
污染和/或损坏的手套必须更换。
其他防护：禁止吸入粉尘/蒸气，涂护肤脂。
卫生措施：远离食物，饮料和烟草。
休息前和工作结束后洗手洗脸。
将工作服单独存放。
更换被污染的衣物。
9. 理化特性：外观与性状：因染色而不同，颗粒气味：几乎无味 PH值：不适用 熔点（℃）：―― 软化点：>120℃相对密度（水=1）：约1.2g/cm 3容积密度：500-700kg/m 3沸点（℃）： ―― 相对蒸气密度（空气=1）：―― 饱和蒸气压：不适用化学品安全技术说明书 （MSDS ）UTECHLLAN US-60A10 112000022190/1.0-CN发行日期：2007年07月30日(第01次修正) 第 3 /4 页••燃烧热（kJ/mol）:―― 临界温度（℃）：――临界压力（MPa）:―― 辛醇/水分配系数的对数值：――闪点（℃）：―― 引燃温度（℃）：>210℃自燃温度：不适用 爆炸极限%（V/V）：不适用溶解性：几乎不溶于水 主要用途：――其他理化性质：粘度，动力学的：不适用10. 稳定性及反应活性：稳定性：热分解：在230℃时开始分解。
禁配物：―― 避免接触的条件：――聚合危害：未观察到有害反应。
分解产物：闷烧或不完全燃烧会产生主要含一氧化碳、二氧化碳和氮氧化物的有毒气体混合物。
11. 毒理学资料：在推荐的处理条件下，会释放少量的异氰酸酯。
超过推荐的操作温度时，导致产生的异氰酸酯蒸气的量显著升高。
过度暴露有导致刺激性和/或致敏之风险，危害程度随浓度升高而增大（症状如呼吸困难，咳嗽，哮喘可能滞后出现）。
操作该产品尤其在高温下操作该产品，必须遵守以下列出的物质法规。
物质 CAS编号 风险性短语异氰酸酯（全部，如NCO） R42 吸入可致敏 其它信息：根据我们的经验和产品信息，该产品在正确操作时无有害影响。
急性毒性：―― 亚急性和慢性毒性：―― 刺激性：―― 致敏性：―― 致突变性：―― 致畸性：―― 致癌性：―― 其 他：――12. 生态学资料：禁止倒入水体，废水或土壤中。
其它生态学信息：本产品几乎不溶于水。
根据它的密度和水中的不溶性，预料该产品在正确使用时无生态问题。
本产品不易生物降解。
生态毒性：―― 生物降解性：――非生物降解性：―― 生物富集或生物积累性：――13. 废弃处置：废弃物性质：废弃物产生时，按照《国家危险废物名录》判断是否属于/属于何类危险废物。
并遵守《中华人民共和国固体废物环境污染防治法》的规定。
化学品安全技术说明书 （MSDS ）UTECHLLAN US-60A10 112000022190/1.0-CN发行日期：2007年07月30日(第01次修正) 第 4 /4 页••废弃处置方法：必需遵守适用的国际、国家和当地法规、法令和标准。
在欧盟领域内废弃，应根据欧洲废弃物分类（EWC）的适当法规。
本产品适合回收再利用。
经过适当处理后，可被再熔融，再加工成新的模制产品。
唯有依据材料本身的类型有选择的回收并仔细分选，才可以进行回收。
废弃注意事项：尽可能将容器倒空（例如经倾倒，刮擦或排干直至“滴干”），可根据化学工业现存的回收方案送往适当的收集点处理。
容器的回收应遵守国家和环境法规。
14. 运输信息：UN编号：―― 包装标志：―― 包装类别：―― 包装方法：――ADR/RID：―― ADNR：―― IATA：―― IMDG：――运输注意事项：非危险货物。
微有味，保持干燥。
与食物分开存放。
15. 法规信息：国内法规：――国际法规：根据EC 指令2006/121/EC 或1999/45/EC 及其有效改编版和衍生的国家法规，无需加贴危害标签。
国家法规水污染类别（德国） nw－不损害水体（根据水体有害物质指令附录1）16. 其它信息：第2和3部分所涉及的风险性短语内容：R 51/53：对水生物有毒，对水域环境有长期的负面影响参考文献：填表时间： 2007年07月30日 填表部门： 健康, 安全, 环保, 质量管理 联系电话： 0086-21-61468282－8632 数据审核单位： 拜耳材料科技亚太区修改说明：其它信息：上述资料乃基于现有知识及经验。
本安全资料说明书是用以描述产品的安全准则。
此等资料并非产品性质的担保。
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