Comparison of Deterministic and Stochastic Method in Operational
高二英语哲学思想初探单选题30题

高二英语哲学思想初探单选题30题1. Philosophy is the study of _______ and the nature of reality.A. wisdomB. knowledgeC. truthD. thought答案:C。
本题主要考查哲学中对研究对象的理解。
选项A“wisdom”意为智慧;选项B“knowledge”意为知识;选项C“truth”意为真理,哲学研究的是真理和现实的本质;选项D“thought”意为思想,相比之下,“truth”更符合哲学研究的核心。
2. In philosophy, a ________ is a statement that is considered to be true without needing to be proved.A. theoryB. principleC. axiomD. concept答案:C。
“axiom”在哲学中特指无需证明即被认为正确的陈述,选项A“theory”指理论;选项B“principle”指原则;选项D“concept”指概念,均不符合题意。
3. The branch of philosophy that deals with the nature of beauty and art is called _______.A. ethicsB. aestheticsC. epistemologyD. metaphysics答案:B。
本题考查哲学分支。
选项A“ethics”是伦理学;选项C“epistemology”是认识论;选项D“metaphysics”是形而上学,而“aesthetics”指美学,与美和艺术的本质相关。
4. One of the fundamental questions in philosophy is 'What is the meaning of ______?'A. lifeB. existenceC. beingD. reality答案:A。
高三英语哲学单选题30题及答案

高三英语哲学单选题30题及答案1.The concept of “dialectics” is often associated with which philosophical school?A.PlatonismB.AristotelianismC.HegelianismD.Stoicism答案:C。
“dialectics”( 辩证法)这个概念常与黑格尔哲学相关,黑格尔的哲学以辩证法著称。
Platonism( 柏拉图主义)主要强调理念论;Aristotelianism( 亚里士多德主义)涉及逻辑、伦理等多方面,但不是以辩证法闻名;Stoicism 斯多葛学派)强调顺应自然和道德生活等,与辩证法关系不大。
2.Which adjective best describes the philosophy of existentialism?A.DeterministicB.RationalC.SubjectiveD.Objective答案:C。
存在主义哲学强调个人的主观体验和选择,是主观的。
Deterministic(决定论的)与存在主义强调的自由选择相悖;Rational 理性的)不能准确代表存在主义的特点;Objective(客观的)也不符合存在主义注重个人主观感受的特点。
3.In philosophy, “metaphysics” is concerned with what kind ofquestions?A.EthicalB.LogicalC.OntologicalD.Epistemological答案:C。
“metaphysics”( 形而上学)主要关注本体论问题。
Ethical 伦理的)是关于道德方面的;Logical 逻辑的)涉及思维规律;Epistemological 认识论的)是关于知识的来源和可靠性等问题。
4.Which verb is often associated with the philosophy of pragmatism?A.ContemplateB.ActC.ReflectD.Theorize答案:B。
事物的比较The comparisons between FBI and CIA

The comparisons between FBI and CIACIA and FBI are familiar to us when we watch the detective movies. Some find it quiet confusing to distinct them especially when they turn up at the same time. Are there any differences between these two agencies?The answer is certainly YES!First come the similarities between the FBI and CIA.CIA, the abbreviation of the Central Intelligent Agency, along with the FBI, standing for Federal Bureau of Investigation, is vital to the American national security and information gathering. Both play an important role in collecting and acting upon information, which is linked to criminal activities or affect national safety. Besides, some qualifications are required. The people, hoping to be members of them, have to gain American citizenship with at least high school education.For all these similarities, there are still some clear differences between them.To start with, headquarters and founded date. The same country as they are, the CIA is located in Virginia on the sep18,1947, whereas FBI is situated in the Washington D.C. on the july26,1908. It is obvious that the FBI is earlier. Secondly, the staff number. The CIA owns approximately 20,000 while there are overwhelming People in FBI—over 35,000 in 2010. What’s more, different characteristics. The CIA is major in the intelligent scope, but FBI concentrated on law enforcement. Last but notleast, the requirement. To join the CIA you must be a US citizen above 18 years of age and a high school graduate. A college degree is required for being an overseas officer, intelligence analyst, and for other non-clerical positions. Knowledge of a foreign language is also helpfulTo join the FBI, you must be a US citizen with no criminal record, afour-year college degree and pass a background test. There may also be a physical fitness test and polygraph test. Selected applicants undergo 21 weeks of training at the FBI academy.The number of employees is classified but is estimated to be is about 20,000.Reference:1./what-is-the-difference-between-the-fbi-and-the-cia.html2./difference/CIA_vs_FBI。
The Comparison and Contrast of Confucianism and Taoism

V. Choose one of the following topics and have a detailed discussion on it in a well organized short research paper on the basis of the detailed instructions in the lectures, the ideas from the classroom discussions and the inspirations from your independent study. (40%)The subjects:The Cultural Value of Chinese mythology( such as the Creation Myth)The Significance of Bronze Vessels( such as the historical, economical, cultural,…value)A Comparison and Contrast of the Confucianism and TaoismThe requirements:You are expected to write a short research paper of at least 300 words.You should present your ideas in a well organized way and support your ideas with relevant details and adequate analysis.Hand in your master copy (printed copy) in Times New Roman (小四) on December 12th.The Comparison and Contrast of Confucianism and Taoism Confucianism and Taoism, the two big trends, have a profoundly influence on traditional ideology and culture. There are also great differences between them.Confucianism, Taoism claims "m oderation, harmonious", enthusiasm to life, heavy soil homesickness, focusing on people lightening ghosts, people-oriented thoughts, against tyranny (harsh laws severe punishment, etc.). the thoughts of Lao Zi is based on natural socialist and give priority to it, and the thoughts of Confucius is based on rule and give priority to it. Lao zi and Confucius both are the representative figures of intelligentsia, but in treating rites, Lao zi is a radical opponent and Confucius is a moderate conservative. In case, Confucius is positive to argue that "justify". Lao zi from opposite argues that "the way of the move". Lao zi claims no –action, which does not mean inactivity but taking no action that is against the original nature and wishes of the people; while Confucius support virtual rules and Confucius holds that a ruler should first of all have a good moral character himself and then try to educate the people and make them virtuous. The Dao of Lao zi refers to the metaphysical natural heavenly while Confucius’s way refers to ethics model. Lao zi advocates nature, Confucius advocates morality; Lao zi upholds "kindness", Confucius upholds "benevolence".As far as I am concerned, the most obvious differences between Confucianism and Taoism are their h olds towards education and virtues. Confucius is China’s first educator, and no doubt one of the world’s first educators. He had a clear aim: he expected them to be virtuous (humanity, rightness, propriety, wisdom, trustworthiness, loyalty, reciprocity, filial piety, brotherly love), to understand man and society, to have a good knowledge of the past and a clear vision of the future, and to devote them to the spreading and carrying out of the Way. On the contrary, Lao Zi is against them. In his view, knowledge and wisdom( which produce evil ideas and make people think ofand do bad things), humaneness and rightness, should all be thrown away, so as to keep people’s thinking simple and primitive. He advises people to be peaceful, quiet, submissive, tolerant, modest, contented, and humble, live a simple life, not to strive for wealth, fame or power, which will only give one worries and trouble.All in all, Confucius’ lobbying, lecture, the disciple in politics, the study of the Confucianism and so on, make Confucianism become the main state thought and the main stream of Chinese thought for about 2,000 years. (In my opinion)Taoism is more implicit learning than Confucianism. Lao Zi’s achievement and retirement, Zhuang Zi ’s refusing into government, the apprentices’ great success and the study of Taoism doctrine deeply contribute to and make a great difference in the later law,arts, traditional Chinese medical science, agriculture, etc.100121078 英师二班陈海曼。
以比为主题写一篇英语作文

以比为主题写一篇英语作文Comparison: The Catalyst of Progress.In the tapestry of life, comparison serves as an indispensable thread, weaving intricate patterns of knowledge, understanding, and growth. As humans, our innate ability to compare and contrast shapes our perceptions,fuels our aspirations, and drives our relentless pursuit of progress.The Cognitive Power of Comparison.Comparison is a cognitive tool that allows us to establish similarities and differences between objects, ideas, and experiences. By juxtaposing two or more entities, we can extract meaningful insights that would otherwise remain hidden. Through analytical comparisons, we can uncover patterns, identify causes and effects, and draw abstract conclusions. This process of comparison isessential for acquiring knowledge, solving problems, andmaking informed decisions.For instance, in scientific research, scientists compare experimental groups with control groups todetermine the efficacy of new treatments. By isolating and contrasting variables, they can isolate the specificfactors responsible for observed changes, leading to advancements in medicine, technology, and other disciplines.The Motivational Role of Comparison.Comparison also plays a pivotal role in motivation. By comparing our current state to a desired state, we create a gap that drives us forward. This gap can ignite ambition, foster a sense of purpose, and propel us towards self-improvement.For students, comparing their grades to their peers or previous performance can serve as a motivator to study harder and achieve higher academic goals. Similarly, in business, comparing market share or revenue figures to competitors can spur companies to innovate, improveefficiency, and outmaneuver the competition.The Social Impact of Comparison.While comparison can be a powerful force for personal growth, it can also have a significant impact on our social interactions. When we compare ourselves to others, we may experience feelings of superiority, inferiority, or envy. While healthy competition can be beneficial, excessive comparison can lead to negative outcomes such as self-doubt, social anxiety, and unhealthy self-perceptions.Social media platforms have amplified the impact of comparison, providing a constant stream of curated images and accomplishments that can create a distorted perceptionof reality. This can lead to feelings of inadequacy and a diminished sense of self-worth, especially among younger users.The Need for Responsible Comparison.Given the profound impact of comparison, it isessential to approach it with mindfulness and intention. Responsible comparison involves:Setting realistic benchmarks: Comparing yourself to unattainable standards can be demoralizing. Instead, choose benchmarks that are challenging but achievable.Focusing on personal growth: Comparison should be used as a tool for self-improvement rather than a metric forself-worth.Valuing diversity: Recognize that each individual is unique and has their own strengths and weaknesses.Seeking balance: Avoid excessive comparison that can lead to negative outcomes.Practicing self-acceptance: Remember that everyone has flaws and that true self-worth comes from内在。
行驶时间函数(路阻函数):BPR(美国道路局Bureau of Public Road)函数

BPR BPR
BPR
GEOG 111 & 211A
Transportation Planning
Key Ingredients
• Link performance functions (travel time vs traffic volume) • Turning delays (penalties) • Algorithm for assignment of traffic • Behavioral assumptions
GEOG 111 & 211A
Transportation Planning
Algorithms
• Uncongested vs Congested Networks (capacity) • Deterministic vs Stochastic (analyst’s ignorance and people’s heterogeneity) • With vs Without Traffic Control “feedback” (think of intersections’ control effects) • Treatment of time & equilibrium considerations • Combined with other steps
Path 1
Origin
Path 2
Destination
GEOG 111 & 211A
Transportation Planning
STOCH (Transcad)
• Based on choice probability for each path from an origin to a destination • In a path TRANSCAD considers only reasonable links = links that take a traveler away from origin and closer to destination • Link travel time not dependent on link volume • Probability based on LOGIT (reviewed in modal choice) • Traveler chooses the most convenient path
八年级英语议论文论证方法单选题40题
八年级英语议论文论证方法单选题40题1. In the essay, the author mentions a story about a famous scientist to support his idea. This is an example of _____.A.analogyB.exampleparisonD.metaphor答案:B。
本题主要考查论证方法的辨析。
选项A“analogy”是类比;选项B“example”是举例;选项C“comparison”是比较;选项D“metaphor”是隐喻。
文中提到一个关于著名科学家的故事来支持观点,这是举例论证。
2. The writer uses the experience of his own life to prove his point. This kind of method is called _____.A.personal storyB.example givingC.case studyD.reference答案:B。
选项A“personal story”个人故事范围较窄;选项B“example giving”举例;选项C“case study”案例分析;选项D“reference”参考。
作者用自己的生活经历来证明观点,这是举例论证。
3. The author cites several historical events to strengthen his argument. What is this method?A.citing factsB.giving examplesC.making comparisonsing analogies答案:B。
选项A“citing facts”引用事实,历史事件可以作为例子,所以是举例论证;选项B“giving examples”举例;选项C“making comparisons”比较;选项D“using analogies”使用类比。
行驶时间函数(路阻函数):BPR(美国道路局Bureau of Public Road)函数
GEOG 111 & 211A
Transportation Planning
Incremental Assignment
• Many steps in the procedure • In each step one fraction of OD matrix assigned using all-or-nothing assignment • At each step link travel times are based on the volume assigned in previous step • May become very inaccurate
perceiveandweightheminthesameway?alltrafficisassignedtoshortestpathbetweeneachodpair?nocongestioneffect?linkcostsarefixed?simplebutnotaccurategeog111211atransportationplanningallornothingassignment?alltrafficfromzoneitozonejusestheinitiallyminimaltraveltimepath?roadwayperformancenotenforcedduringassignment?maybecomeinaccuratebutsimplefastmethod?notforcongestednetworksorigindestinationpath1path2geog111211atransportationplanningstochtranscad?basedonchoiceprobabilityforeachpathfromanorigintoadestination?inapathtranscadconsidersonlyreasonablelinkslinksthattakeatravelerawayfromoriginandclosertodestination?linktraveltimenotdependentonlinkvolume?probabilitybasedonlogitreviewedinmodalchoice?travelerchoosesthemostconvenientpathgeog111211atransportationplanningincrementalassignment?manystepsintheprocedure?ineachsteponefractionofodmatrixassignedusingallornothingassignment?ateachsteplinktraveltimesarebasedonthevolumeassignedinpreviousstep?maybecomeveryinaccurategeog111211atransportationplanningcapacityrestraint?manysteps
八年级英语议论文论证方法单选题40题
八年级英语议论文论证方法单选题40题1. In the essay about animals, the author gives many examples of different species to prove his point. This is an example of which kind of argumentation?A. Analogical argumentationB. Inductive argumentationC. Deductive argumentationD. Comparative argumentation答案:B。
本题考查举例论证的类型。
选项A“类比论证”是通过比较相似的事物来论证;选项C“演绎论证”是从一般到特殊的推理;选项D“比较论证”是对事物进行对比。
而文中作者通过列举多个不同物种的例子来证明观点,属于归纳论证,即选项B。
2. The writer of the article on history uses several specific events to support the main idea. What kind of argumentation is this?A. Statistical argumentationB. Exemplary argumentationC. Hypothetical argumentationD. Causal argumentation答案:B。
本题考查举例论证的方式。
选项A“统计论证”是基于数据和统计信息;选项C“假设论证”是基于假设情况;选项D“因果论证”是强调原因和结果的关系。
文中作者使用几个具体的事件来支持主要观点,这是典型的举例论证,即选项B。
3. In a composition about sports, the author presents several famous athletes' stories to strengthen the argument. Which argumentation method is employed?A. Illustrative argumentationB. Analogical argumentationC. Reductive argumentationD. Abstract argumentation答案:A。
Cai_2001_Comparison-of--solid-pmicroextraction-for-the-determination-of-volatile-flavor-components
930 (2001) 1–7Journal of Chromatography A,/locate/chromaComparison of simultaneous distillation extraction and solid-phase microextraction for the determination of volatile flavor componentsa,b b a,b ,*Jibao Cai ,Baizhan Liu ,Qingde SuaDepartment of Chemistry ,University of Science and Technology of China ,Hefei ,230026,PR ChinabResearch Center of Tobacco Science ,University of Science and Technology of China ,Hefei ,230052,PR ChinaReceived 6April 2001;received in revised form 28June 2001;accepted 28June 2001AbstractTraditional simultaneous distillation extraction (SDE)and solid-phase microextraction (SPME)techniques were compared for their effectiveness in the extraction of volatile flavor compounds from various mustard paste samples.Each method was used to evaluate the responses of some analytes from real samples and calibration standards in order to provide sensitivity comparisons between the two techniques.Experimental results showed traditional SDE lacked the sensitivity needed to evaluate certain flavor volatiles,such as 1,2-propanediol.Dramatic improvements in the extraction ability of the SPME fibers over the traditional SDE method were noted.Different SPME fibers were investigated to determine the selectivity of the various fibers to the different flavor compounds present in the mustard paste samples.Parameters that might affect the SPME,such as the duration of absorption and desorption,temperature of extraction,and the polarity and structure of the fiber were investigated.Of the various fibers investigated,the PDMS–DVB fiber proved to be the most desirable for these analytes.©2001Elsevier Science B.V .All rights reserved.Keywords :Solid-phase microextraction;Simultaneous distillation extraction;Mustard paste;Volatile organic compounds;Flavor compounds1.Introductionformed.Several extraction and concentration meth-ods have been used;among them are liquid–liquid The determination of volatile components in a extraction [2],liquid–liquid extraction with ultra-mixture is a process widely used in many disciplines,sound [3],simultaneous stream distillation extraction such as environmental,food,forensic,fragrance,oil,[4],solid-phase extraction [5],and other techniques pharmaceutical and polymer analysis.The method of [6,7].The main reason for extraction is to obtain a choice for many of these analyses is simultaneous more concentrated samples,to eliminate interfering distillation extraction (SDE)[1]followed by GC or substances and to improve detection limits for spe-GC–MS analysis.Extraction and concentration are cific compounds.usually necessary before analysis by GC is per-Solid-phase microextraction (SPME)[13]is a relatively new technique that is able to address the need for concentrating the analytes in the headspace *Corresponding author.Tel.:186-551-360-6642;fax:186-[8].SPME uses a small (1-cm long)piece of fused 551-360-3388.E -mail address :qdsu@ (Q.Su).silica,on which a liquid phase,similar to a GC0021-9673/01/$–see front matter ©2001Elsevier Science B.V .All rights reserved.PII:S0021-9673(01)01187-6930 (2001) 1–72J.Cai et al./J.Chromatogr.Astationary phase,has been coated to absorb the waterbath maintained at30,50and708C,respective-desired analytes and concentrate them on thefiber.ly,to optimize temperature of extraction.The vial The selectivity of the extraction of target analytes in was submerged only as far as necessary to submerge the gaseous phase can be significantly altered the solid phase of the sample,to help keep the SPME through the use of different liquid phase on thefiberfiber cool,which is a desired condition for SPME.[9].This is because as the temperature of thefiber Mustard paste,which is usually served as a spice increases,the partition coefficient decreases[10]. for foodflavoring,has become increasingly popular.The SPME holder was secured and thefiber extend-The main ingredients of mustard paste are Brassica ed into the headspace,and thefiber was equilibrated nigra and Brassica alba seeds.The most predomi-for20,40and60min,respectively,to optimize the nant constituent of Brassica nigra is allyl isothio-time of extraction.Thefiber was then retracted, cyanate,which accounts for more than90%of the removed from the vial,and placed immediately into total volatile compounds.The most predominant the injector of the GC at2508C.Injection was constituent of Brassica alba is sinalbin disulfide.accomplished by extending thefiber in the heated Consequently,the analysis of the volatileflavor inlet for3,5and7min,to optimize the time of compounds in mustard paste can identify the mustard desorption,while the injector operated in the splitless varieties.mode for2min.The additional time of exposuretime in the injector port allowed thefiber to becleaned of any compounds that may not be desorbed 2.Materials and methods in the initial minute.Preliminary studies indicatedthat the above procedure allowed for reproducible, 2.1.Materials quantitative transfer of target analytes into the injec-tor port of the GC–MS.Mustard pastes(made in Japan)were purchasedfrom a local supermarket.The mustard paste is2.3.Sampling conditions of SDEcomposed of mustard,sorbitol,corn oil,salt,water,artificialflavor,xanthan gum,turmeric,and artificialSimultaneous distillation–solvent extraction was color(FD&C Yellow no.5,FD&C Blue no.1).Thecarried out in a microversion apparatus,as described components of the standard solutions were all pur-elsewhere[11].Dichloromethane(chromatography-chased from Sigma(St.Louis,MO,USA).Standardgrade reagent,Merck)and n-tetradecane were used solutions were used to optimize GC–MS and SPMEas solvent and internal standard,respectively.For conditions.All solutions were stored at48C.each extraction,10g of mustard paste and250mldistilled water were placed in a500-mlflask,30ml 2.2.Sampling conditions of SPMEdichloromethane was placed in a50-mlflask,streamdistillation was stopped after2h,while the solvent For the SPME determinations,a SPME holder andextraction was continued for a further15min.The threefibers(100-m m PDMS,65-m m PDMS–DVBextract was concentrated to 1.0ml at558C by and65-m m CW–DVB)were used(Supelco,Belle-Kuderna-Danish apparatus(NE-1,Japan).The in-fonte,PA,USA).Thefibers were conditioned underjection volume was2.0m l with a split ratio of20:1. helium at2908C for4–5h prior to use.BetweenA series of three consecutive extractions was per-uses,fibers were kept sealed from ambient air byformed on different aliquots of mustard pastes in inserting the tip of the SPME needle into a smallorder to evaluate the repeatability of SDE method. piece of septum to prevent accidental contamination.The sampling procedure involved placing2–3g ofsample into a20-ml vial and sealing with a screwtop 2.4.Condition of GC–MSseptum-containing cap.The SPME needle was theninserted through the septum and suspended in the Autosystem TurboMass GC–MS(Perkin-Elmer, headspace of the vial.The vial was placed in a USA)was used.A30m30.25mm Supelco-wax930 (2001) 1–73J.Cai et al./J.Chromatogr.Aquartz capillary column(Supelco,Bellefonte,PA, 3.Results and discussionUSA)with0.25-m mfilm thickness was used toresolve the volatiles with the following temperature parison of SDE and headspace SPME programming:initial oven temperature was608C,techniquekept for2min;then was raised to2408C at48C/min,and kept at2408C for15min.Helium was used as As shown in Table1,traditional SDE technique carrier gas with column head pressure at10kPa.could extract all the volatileflavor compounds of Programming split/splitless(PSS)injector tempera-mustard paste,except for1,pared ture was at2508C.In SPME analysis,the I.D.of the with SPME,SDE could also extract high-molecular-injection liner was1.5mm;the desorption time was mass and low volatility compounds such as oleic 5min in splitless mode;and the time of the splitless acid,9-hexadecenoic acid and palmitic acid in was2min.In the analysis of SDE extract,the I.D.of volatileflavor compounds of mustard paste.So the the injection liner was4.0mm;the split ratio was traditional SDE technique seemed more comprehen-20:1,and the amount of injection was2m l.The sive but less sensitive to trace rge temperature of the GC–MS transfer line was2508C.amounts of furfural and furfural alcohol were found The MS was operated at1708C in the electron in the SDE extracts,perhaps arising from pyrolysis impact mode(70eV),scanning from m/z33to350or hydrolysis during the SDE process.In fact,if in0.3s with an0.2-s interval time of the scan;the these compounds were mustard paste volatileflavor voltage of the photoelectric multiplier tube(PMT)components,they should easily be extracted by was230V.The mass spectral identifications of the SPME.However,they were found only in SDE volatiles were carried out by comparing to the extracts.Representative TIC chromatograms of vola-NIST98(National Institute of Standards and Tech-tileflavor compounds from mustard pastes are shown nology,Gaithersburg,MD,USA)mass spectral in Fig. pared with SDE,SPME showed library as well as to the Wiley6.0(Wiley,New York,enormous advantages:simplicity,rapid solvent-free NY,USA)mass spectral library.extraction,low cost,little interference,no apparentTable1GC–MS identification of mustard paste volatiles and peak area percentagesPeak t Compound name Peak area(%)Rno.(min)100-m m65-m m65-m m SDEPDMS CW–DVB PDMS–DVB1 5.081-Propene,3,3-thiobis0.0220.0130.0170.009 28.10Thiocyanic acid,methyl ester0.0160.0270.0210.011 313.56Allyl isothiocyanate98.5863.6293.2498.84 413.83Furfural ND ND ND0.081 514.20Diallyl disulfide0.0220.0080.0130.012 617.50Methyl allyl trisulfide0.0140.0120.0130.006 717.881,2-Propanediol 1.12835.77 3.125ND 819.87Furfural alcohol ND ND ND0.125 923.37Diallyl trisulfide0.0150.0140.0140.005 1026.93Butylated hydroxyl toluene0.0700.0130.0410.011 1128.475-Methyl-tetrahydrothiophen-2-one0.0510.3300.1950.014 1231.25Ethanol,1-methoxy-,benzoate0.0090.0410.0270.011 1334.722-Phenylethyl isothiocyanate0.0140.0210.0160.012 1449.67Palmitic acid ND ND ND0.508 1550.619-Hexadecenoic acid ND ND ND0.799 1650.90Oleic acid ND ND ND 1.522 ND,not determined.930 (2001) 1–7 4930 (2001) 1–75J.Cai et al./J.Chromatogr.ATable2Repeatability of SPME(n55)and SDE(n53)Peak Compound name RSD(%)no.100m m65m m65m m SDECW–DVB PDMS PDMS–DVB11-Propene,3,3-thiobis 6.23 3.71 6.74 2.032Thiocyanic acid,methyl ester 5.768.73 4.73 3.743Allyl isothiocyanate8.64 3.52 2..22 1.614Furfural––– 3.495Diallyl disulfide 5.66 5.758.08 2.536Methyl allyl trisulfide–8.779.24 3.6871,2-Propanediol 4.60 4.207.99–8Furfural alcohol––– 1.369Allyl trisulfide7.919.72 3.29 2.2710Butylated hydroxyl toluene 5.817.55 5.82 3.52115-Methyl-tetrahydrothiophen-2-one9.557.44 4.29 2.4512Ethanol,1-methoxy-,benzoate7.91 4.75 6.48 1.45132-Phenylethyl isothiocyanate 6.689.148.89 2.3714Palmitic acid––– 3.09159-Hexadecenoic acid––– 1.3416Oleic acid––– 2.15–,not determined.21less than0.3m g l for most of analytes.The aqueous layer at thefiber-gas interface increased relative standard deviation(RSD)is better than9%.with increasing temperature,so that more analytes This method was applied to a food sample(mustard were absorbed at higher temperature if equilibrium paste)using an external calibration.had not been reached.The decreasing absorptionwith increasing temperature at708C was presumably 3.2.1.Extraction temperature due to the distribution constant decreasing with The extraction temperature profile obtained using increasing temperature.The absorption process was a PDMS–DVBfiber is shown in Fig.2.Optimum exothermic,thus lowing the temperature increased extraction efficiency was achieved at508C.The the distribution constant at equilibrium.In practical lower absorption of most analytes at308C was due to applications when the extraction was stopped before the decreased rate of diffusion of the analytes.The reaching the equilibrium,not only thermodynamic rate of diffusion of the analytes through the static but also kinetic aspects became important.An ex-traction temperature of508C was selected for thisstudy using the threefibers,because this temperaturewas relatively easily maintained,and the improve-ment in sensitivity at higher temperature was notnecessary.3.2.2.Extraction timeThe extraction time profile obtained using PDMS–DVBfiber is shown in Fig.3.For the PDMS–DVBfiber,the equilibrium condition for the absorption ofthe most analytes was almost reached after40min.Factors that influenced the equilibration period wereinvestigated by Pawliszyn and co-workers[13–15].The equilibration rate was limited by(1)the masstransfer rate of the analytes through a thin static Fig.2.Extraction temperature profile for65-m m PDMS–DVBfiber.Extraction time,40min;desorption time,5min.aqueous layer at thefiber-gas interface,(2)the930 (2001) 1–76J.Cai et al./J.Chromatogr.A3.2.parison of differentfibersThree differentfibers were evaluated to determinewhichfiber most effectively extractedflavor volatilesfrom mustard paste samples.Thefibers that wereused to extract analytes from the headspace ofaliquots of the same sample for comparison of therelative extraction effectiveness were100-m mPDMS,65-m m CW–DVB and65-m m PDMS–DVB,respectively.The results of the experiments on thesethreefibers are summarized in Fig.5.These resultsshow that,of thefibers evaluated,the PDMS–DVBfiber proved to be the most effective in extractingflavor volatiles overall,followed by the PDMSfiber,then the CW–DVBfiber.Therefore,the65-m m Fig. 3.Extraction time profile for65-m m PDMS–DVBfiber.Extraction temperature,508C;desorption time,5min.PDMS–DVBfiber was used for all subsequentcomparison experiments.The PDMS–DVBfiber was distribution constant of thefiber coating and(3)the chosen as a representative to investigate the duration thickness and kinds of thefiber coating.Extraction of absorption and desorption,temperature of absorp-periods of40min were chosen for the threefibers tion,detection of limits,and the precision of SPME since it was approximately equivalent to the time in this investigation.required to run GC in this experiment.The PDMS–DVBfiber performed the most effec-tive extractions,for this analysis,because thefiber 3.2.3.Desorption time coating was composed of a mixed coating containing The desorption time profile obtained using the PDMS,a liquid phase that favored the absorption of PDMS–DVBfiber is shown in Fig.4.A desorption nonpolar analytes,as well as DVB,a porous solid period of5min was enough to desorb the analytes that favored the adsorption of the more polar ana-from the PDMS–DVBfiber(temperature of the GC lytes.There was little difference between the PDMS injection port,2508C).So a desorption period of5fiber and the PDMS–DVBfiber in extracting the min was used for the threefibers(temperature of the nonpolar analytes(butylated hydroxytoluene),but GC injection port,2508C).No carryover of any the more polar disulfide and trisulfide were extracted, volatileflavor component was observed.on average,three times better by the PDMS–DVBFig. 4.Desorption time profile for65-m m PDMS–DVBfiparison of100-m m PDMS,65-m m PDMS–DVB and Extraction temperature,508C;extraction time,40min.65-m m CW–DVBfibers.930 (2001) 1–77J.Cai et al./J.Chromatogr.Afiber as measured by peak area.The CW–DVBfiber,sitivity allowed fast,accurate determinations of which was more selective towards polar analytes,didflavor compounds and easy performance of analyses. show enhanced extraction effectiveness of the polar Consequently,SPME was suitable for simple,rapid, analytes,but was less effective with the nonpolar routine screening,while SDE was used for proper analytes.quantitative analysis.Profiling of different mustard paste samples were3.2.5.Repeatability performed.Differentfibers were investigated withA series offive consecutive extractions were the bestfiber found to be65-m m PDMS–DVB.The performed on different aliquots of mustard pastes in optimal parameters for SPME sampling were also order to evaluate the repeatability of the headspace investigated.SPME(HS-SPME)method.The precision of theHS-SPME method was good and the RSD valueswere between2.22and9.72%for all the11volatile Referencesflavor compounds in mustard paste(Table2).[1]A.Orav,T.Kailas,M.Liiv,Chromatography43(1996)215.3.3.Mustard pastes determined by SPME–GC–MS[2]D.Martinez,F.Borrul,M.Calull,J.Chromatogr.A827(1998)105.[3]T.Hankemeier,S.J.Kok,R.J.J.Vreuls,U.A.Th.Brinkman,J. In total,11volatile compounds in mustard pasteChromatogr.A841(1999)75.were identified,which accounts for99%of TIC peak[4]A.J.Nunez,J.M.H.Bemelman,J.Chromatogr.294(1984) area as shown in Table1.The four methods made up361.[5]T.Hankemeier,E.Hooijschuur,R.J.J.Vreuls,U.A.Th.Brink-one another and validated mutually.Since allylman,T.Visser,J.High Resolut.Chromatogr.21(1998)341. isothiocyanate was the main volatile constituents of[6]M.D.Burford,S.B.Hawthorne,ler,J.Chromatogr. the mustard pastes(Table1),the main ingredient ofA685(1994)79.the mustard pastes was Brassica nigra seeds.[7]B.Gawdzik,T.Matynia,Chromatography38(1994)643.[8]Z.Zhang,M.Yang,J.Pawliszyn,Anal.Chem.66(1994)844A.[9]X.Yang,T.Pepard,LC–GC13(1995)882.4.Conclusions[10]Z.Zhang,J.Pawliszyn,Anal.Chem.67(1995)34.[11]M.Godefroot,P.Sandra,M.Verzele,J.Chromatogr.203 Traditional SDE analysis of volatile compounds is(1981)325.a widely used technique.However,for many analy-[12]C.L.Arthur,L.Killam,K.Buchhliz,J.Pawliszyn,J.Berg,Anal.Chem.64(1992)1960.ses,the SDE method lacked the sensitivity and[13]C.L.Arthur,J.Pawliszyn,Anal.Chem.62(1990)2145. convenience needed to perform adequately.SPME[14]D.Louch,S.Motlagh,J.Pawliszyn,Anal.Chem.64(1992) had the ability to perform these analyses where SDE1187.fell parison of SDE and SPME showed[15]D.W.Potter,J.Pawliszyn,J.Chromatogr.625(1992)247. that SPME determinations offlavor compounds[16]D.C.Garcia,S.Magnaghi,M.Reinchenbacher,K.Danzer,J.High Resolut.Chromatogr.19(1996)257.were,on average,more sensitive under the con-ditions employed in this study.The increased sen-。
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P rocedia Engineering 91 ( 2014 )130 – 1351877-7058 © 2014 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license(/licenses/by-nc-nd/3.0/).Peer-review under responsibility of organizing committee of the XXIII R-S-P seminar, Theoretical Foundation of Civil Engineering (23RSP)doi: 10.1016/j.proeng.2014.12.034ScienceDirectAvailable online at XXIII R-S-P seminar, Theoretical Foundation of Civil Engineering (23RSP) (TFoCE 2014) Comparison of Deterministic and Stochastic Method in Operational Modal Analysis in Application for Civil Engineering StructuresJacek Grocel a *a Wroc áaw University of Technology, Wroc áaw 50-370, Wybrze Īe S. Wyspia Ĕskiego 27, PolandAbstractApplying Operational Modal Analysis (OMA) one can extract modal properties of structure (eigenfrequencies, eigenforms and modal damping) on the basis of vibration measurement only - without excitation measurement, what is very complicated in case of big structures. This great advantage of OMA makes this method more common for civil engineering application. The two main techniques are used in OMA, one uses data processing in time domain, the second in frequency domain. The paper presents the comparison of these two method in application OMA for engineering structures .© 2014 The Authors. Published by Elsevier Ltd. Peer-review under responsibility of organizing committee of the XXIII R-S-P seminar, Theoretical Foundation of Civil Engineering (23RSP). Keywords: modal analysis; time domain; frequency domain; engineering structures 1. IntroductionNowadays architectural designing, due to more and more slender structures, force the dynamic analysis of those structures. Civil engineers have to apply apart from theoretical analysis, also some kind of experimental techniques. The basic one and the most frequently used in automotive industry is Experimental (or Classical) Modal Analysis (EMA). Applying EMA one has to measure the excitation of the structure. This is almost impossible with large civil engineering and make EMA useless for this type of application. Instead of EMA, Operational Modal Analysis OMA could be employed. The biggest advantage of OMA is that there is no need of excitation measurement. Modal parameters (eigenfrequencies, eifgenforms, modal damping) could be estimated when the structure is excited by environmental (wind, water flow, etc.) or technology influences (traffic, pedestrian movement). The only one condition should be satisfied, the excitation may be treated as white noise. Using OMA applies two main types of algorithms: a time domain and frequency domain. Those two approaches are shortly presented and differences in results are discussed.* Corresponding author Tel.: +48 71 320 3779; fax: +48 71 320 3645.E-mail address:jacek.grosel@.pl© 2014 The Authors. Published by Elsevier Ltd. This is an open access article under the CC BY-NC-ND license(/licenses/by-nc-nd/3.0/).Peer-review under responsibility of organizing committee of the XXIII R-S-P seminar, Theoretical Foundation of Civil Engineering (23RSP)131J acek Grocel / P rocedia Engineering 91 ( 2014 )130 – 135 Nomenclature[ ]matrix { }vector [ ] T ,{ }Tmatrix, vector transposition ( ) *, [ ] *,{ }*complex conjugate of number, matrix , vector [ ] H ,{ }H matrix, vector Hermitian transformation2. Theoretical background2.1. AssumptionsOMA is derived from following assumptions:x system is linear,x properties of system do not change in time (time-invariant system),x system is excited by white noise,x measurements are done in such a way that give information for analysis (eg. position of measurement points allows to observe modes).Whereas, the first two assumptions are obvious, two last could be hard to satisfy. Assumption about white noise is still valid but as system could be excited by not “pure” white noise, the effect of OMA is identification of the structure itself, but identification of “combined-system”. Combined system consist of structure and excitation filter, forces acting on combined-system have the properties of white noise, but forces acting on the structure are filtered by excitation filter to the actual state. Filtered excitation is still stationary and broadband. In order to satisfy the last assumption, some information about the structure before measurement are needed. This leads to conclusion that, apart from basic structures, either some previous, pre-measurement analysis is needed or OMA should be applied in at least two steps.2.2. Frequency domain methodThe well-known equation of motion, written in matrix form is the starting point>@^`>@^`>@^`^`M ()C ()K ()f (),q t q t q t t (1)where: [M], [C], [K] – denote: inertia, damping and stiffness matrices, respectively, while ^`^`^`)(,)(,)(t q t q t qdenote acceleration, velocity and displacement vectors, respectively, also ^`)f(t is a vector of external excitation. For any structure (for which the assumptions are fulfilled) the relationship between input {f(t )} and output {y(t )} is described by equation, [1], [2]:>@>@>@*Tff G (j Ȧ)H(j Ȧ)G (j Ȧ)H(j Ȧ),yy ªº ¬¼ (2)where: [G ff (j Z )] [G yy (j Z )] are the power spectral density matrices of input and output signal, respectively. The subscript yy denotes output to signalize that number of measuring point could be different from number of degrees of freedom, j Z – frequency, [H(j Z )] – frequency response function (FRF) matrix could be written in form (used also in classical modal analysis:>@>@>@¦ ¸¸¹·¨¨©§ n i i i i i 1**Ȝj ȦR Ȝj ȦR j ȦH (3)132 J acek Grocel / P rocedia Engineering 91 ( 2014 ) 130 – 135>@^`^`T R ,i i i u D (4) where ^`i u is eigenvector corresponding to the i -th eigenfrequency, ^`i D is modal participation vector.After transformation, matrix [G] could be rewritten in form:>@>@>@>@>@¦ ¸¸¹·¨¨©§ m i i i i i i i i i yy 1****Ȝj ȦB j ȦB Ȝj ȦA Ȝj ȦA j ȦG O (5) Matrix G ff (j Ȧ) on the basis of white noise excitation is a constant matrix; it does not depend on frequency; G ff (j Ȧ) = G ff , using that residue matrix is equal to:>@>@>@>@H ff R G R A .2ıii i i (6)For structures with small damping>@>@>@>@^`^`>@^`^`^`^`T T T T A R G R G ,i i xx i i i xx i i i i i u q q u d u u | (7) where d i – constant. The PSD matrix gets final form^`^`^`^`T *H **G j Ȧ,j ȦȜj ȦȜi i i i i i yy i i i d u u d u u §·ªº¨¸ ¬¼¨¸ ©¹¦ (8)where summing is valid only for those modes, which contribute the most at the particular frequency (practically no more than two components are taking into account). The matrix could be decomposed with use of the SVD technique (Singular Value Decomposition ):>@>@>@HG j ȦS .yy i i i i ªº ))¬¼ (9)Matrix [S i ] is a diagonal matrix of singular values; subscript “i ” denotes decomposition for particular frequency. From this matrix eigenfrequencies could be obtained. [)i ] is the unit matrix containing vectors proportional to eigenvectors.2.3. Time-domain methodEquation of motion (1) could be rewritten in state subspace [1]:^`>@ ^`>@ ^` ^`>@ ^`>@ ^`A B C D ,xt x t u t y t x t u t(10)where ^` ^`{}.q t x t q t ½°° ®¾°°¯¿133J acek Grocel / P rocedia Engineering 91 ( 2014 )130 – 135 Vector ^`)(t x is a state vector, ^`)(t y – response vector, which is measured, dimensions of these vector differ. Excitation vector is denoted by ^`)(t u . [A], [B], [C], [D] – are the state, input, output and transmission matrix, respectively. Description in continuous time could be changed into discrete time points (it corresponds to modern techniques of measurements). Taking into account inevitable system noise ^`)(k w and measurement noise ^`)(k v one gets:^`>@ ^`>@ ^` ^`^`>@ ^`>@ ^` ^`1A B C D x k x k u k w k y k x k u k v k(11) In the case of white noise excitation, state vector could be estimated in form:^`>@ ^`>@ ^` ^`>@ ^` ^`ˆˆ1A E ˆC ,xk x k e k y k x k e k (12)where [E] is the Kalman gain matrix and {e(k)} is innovation vector. Matrices [A] and [C] could be estimated on the basis of response measurement only {y(t )}, and from decomposition of state matrix [A] modal parameter could be obtained from relation:>@>@>@>@/ << A 1 (13) where / is a diagonal matrix of eigenvalues of A, and <-1, < is the left and right eigenvector matrices of A.3. Example – OMA of Sky Tower buildingThe construction of “Sky Tower” building was finished in 2012, at that time it was the tallest building in Poland. “Sky Tower” consist of three main parts (Fig. 1):x 3-storey bedplate with shops and service workshops in it,x 19-storey sail with offices and apartments in it,x 30-storey tower with offices and apartments in it.Measurements were performed during the final stage of finishing works (plaster works, inside painting, etc.). Fifteen accelerations in horizontal directions were recorded. Three seismic accelerometers type 8430 Bruel&Kjaer were mounted at each level chosen for measurement. Three pieces of information allow to identify storey movement, as a stiff plate movement.Fig. 1. Sky Tower building in Wroclaw, geometrical model of tower, OMA model.134J acek Grocel / P rocedia Engineering 91 ( 2014 )130 – 135The accelerometers were placed at five storeys of tower part: level + 87.04 m (XX storey), level + 116.96 m (XXVIII storey), level + 139.40 m (XXXIV storey), level + 161.84 m (XL storey), level + 184.28 m (XLIV storey). The transducers were mounted in the central part of building formed by lifts’ walls and staircases’ walls.Only horizontal accelerations were measured, at each level, two in the direction of the shorter axis of ellipse and one in the direction of the longer axis of ellipse created by the storey contour. Schematic position of accelerometers is shown in Fig. 1, where dotted line denotes the contour of the tower, dashed line - lifts and staircases stem and continuous line denotes geometrical model for OMA, which is also shown in Fig. 1.The measurements were done in order to perform OMA – so long time-history, 60 minutes, was recorded. Recording time was relatively short in comparison to cable connecting of all measuring points. Connecting and disconnecting measurement system had lasted one day. The recorded files were analyzed with use of OMA software by SVS [3]. Seven eigenfrequencies and eigenshapes (modes) were found in bandwidth up to 2.56 Hz.It is worth to lay emphasis that OMA is not one step analysis, e.g. some modes were recognized as the same because of very close eigenfrequency and because of high value of MAC (over 0.9). The example of OMA for Sky Tower is spectacular because in the mentioned bandwidth only half of modes were found with use of frequency-domain algorithm. List of identified frequencies and fractions of critical damping is presented in Table 1.Table 1. List of identified modal parameters.Mode number Type of analysis Frequency[Hz]Damping ratio[%]Difference infrequencies [%]Difference indamping [%]MAC[-]1 time-domain 0.3105 0.534 — — —2a time-domain 0.3822 0.6501.86 112 0.9864 2b frequency-domain0.3893 1.3813a time-domain 0.6425 0.9820.23 48.5 0.9883 3b frequency-domain0.6440 0.6614 time-domain 1.175 1.605 — — —5a time-domain 1.540 1.8750.06 33.6 0.9964 5b frequency-domain1.539 1.4036a time-domain 1.613 1.3900.06 149 0.7490 6b frequency-domain1.614 0.5577 time-domain 2.053 1.640 — — —Fig. 2 From left to right: eigenshape no 1 (0.31 Hz), eigenshape no 2 (0.38 Hz), eigenshape no 3 (0.64 Hz).135J acek Grocel / P rocedia Engineering 91 ( 2014 )130 – 135Fig. 3 From left to right: eigenshape no 4 (1.18 Hz), eigenshape no 5 (1.54 Hz), eigenshape no 6 (1.61 Hz).The identified eigenshapes are consistent with eigenshapes obtained from simplified bar-structure analysis. Eigenmodes no 1 and 2 are the first bending mode, one in the direction of the weakest, the second in the direction of the strongest momentum of inertia. Eigenmodes no 3 and 6 are the first and second torsional mode, eigenshape no 4 is the second bending mode and no 5 is the first mixed mode.4. ConclusionsOMA with use of algorithm in time domain gives more reasonable results than with use of algorithm in frequency domain. The result of OMA described above was obtained with excluding one measuring signal (Signal 23 from level + 161.84 m, red arrow in Fig. 1), when all signals were analysed only one mode was identified with use of frequency-domain technique. Signal 23 was excluded after eigenshapes’ analysis, it was the signal which made eigenshapes less smooth. This signal was probably measured with higher noise than other signals, what leads to conclusion that frequency domain algorithms are more sensitive to noise.Frequency domain algorithms operate on signals which are transformed (into frequency domain), whereas the time domain algorithms on original (measured) signal, it could be the second reason of better efficiency of time domain algorithms.Based on the Sky Tower example, as well as on other analysis made by author, it could be stated that the lower frequency the greater advantages of time-domain techniques. That could be caused by properties of Fourier transform, in low frequencies having long time-history is crucial for proper resolution in frequencies. Recommendation of recording time bigger than 1000T (T – the period of the lowest eigenfrequency) is good for time domain algorithms, for frequency domain algorithms better recommendation is 2000 T .References[1] M. Batel, Operational Modal Analysis – Another Way of Doing Modal Testing, Sound and Vibration, August 2002, pp. 22-27.[2] R. Brincker, L. Zhang, P. Andersen, Modal Identification from Ambient Responses using Frequency Domain Decomposition, Proceedings of the 18th International Modal Analysis Conference (IMAC), San Antonio, Texas,2000, pp.625-630.[3] Operational Modal Analysis 5.2, Structural Vibration Solution A/S, on-line help。