锂基脂MSDS
锂基脂化学品技术说明书
化学品中文名称：极压锂基润滑脂 供应商应急电话： 传真： 电子邮件地址：
第2部分 危险性概述
紧急情况措施：
GHS危险性类别： 不易燃 标签要素： 防范措施： 无 事故响应： 火灾时：使用抗溶性泡沫、二氧化碳、干粉、砂土灭火。收集泄漏物。 皮肤接触：立即脱去污染的衣着，用大量流动肥皂水和清水冲洗至少15分钟。就医。 眼睛接触：提起眼睑，用流动清水或生理盐水冲洗，就医。 吸入：迅速脱离现场至空气新鲜处，保持呼吸道通畅，如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸，就 医。 食入：用水漱口，用清水或 1％硫代硫酸钠溶液洗胃。就医。 安全储存：密封防泄漏储存 物理和化学危害： 高热分解产生有毒性烟气 健康危害： 急性吸入，可出现乏力、头晕、头痛、恶心，严重者可引起油脂性肺 炎。慢接触者，暴露部位可发生油性痤疮和 接触性皮炎。可引起神经衰弱综合征，呼吸道和眼刺激症状及慢性油脂性肺炎。有资料报道，接触 石油润滑油类 的工人，有致癌的病例报告。 环境危害：无明显危害 废弃处置：本品及容器的处置应遵循国家法规规定 危险性说明:明火及高温下仍可燃烧
第7部分 操作处置与储存
操作注意事项：密闭操作，加强通风。操作人员必须经过专门培训，严格遵守操作规程；远离火种、热源，工作场 所严禁吸烟； 避免与氧化剂禁配物接触（详见第十部分）； 配备相应数量的消防器材及泄漏应急处理设备。倒空的容器可能残留有害物后需洗手。 储存注意事项： 密封防泄漏储存
第8部分 接触控制/个体防护
危险的分解产物：加热分解可能释放有害之碱、硫氧化物。
第11部分 毒理学信息
急性毒性：食入：毒性 (老鼠): LD50 > 5000 mg/kg 极低毒性。根据化学结构相似物料的试验数。皮肤接触：毒 性 (兔): LD50 > 5000 mg/kg极低毒性。根据化学结构相似物料的试验数据。 刺激性 (兔)眼睛：可能会引起中等 程度、短暂的眼睛不适。根据对成分的分析。亚急性和慢性毒性： 致突变性： 微生物致突变： DNA抑制： 致癌性：无资料 生殖毒性：
MSDS-锂基润滑脂(黄油)化学品安全技术说明书.doc
化学品安全技术说明书（MＳＤＳ）1：化学品名称及企业标识产品名称：锂基润滑脂(俗称黄油)用途：车用或普通设备用脂-------------------------------------------------------------------------------------------------------------------------2：组成/成分资料成分：精制矿物油、皂类增稠剂、适当的性能添加剂。
此产品不含任何等于或高于规定限值的有害成分。
请参阅第八节职业接触限度-------------------------------------------------------------------------------------------------------------------------3：危险标识此产品并不属于危险产品。
但必须按照良好的工业卫生条件和安全操作规程进行使用。
-------------------------------------------------------------------------------------------------------------------------4：急救措施眼：将眼睛张大，用大量水冲洗眼睛。
若眼睛仍有任何红肿、疼痛或不适，应尽快就医。
皮肤：皮肤若接触到油品，应尽快用清水和肥皂彻底加以清洗。
更换严重受污染的衣服，清洗下面弄脏的皮肤。
吸入气体：产品在规定温度下使用不会生烟。
如若吸入高温下产生的油烟造成鼻喉部刺激、或咳嗽，应尽快移至空气新鲜处。
如果仍有不适，应送医诊治。
吞服：若污染了口部，应用水彻底冲洗，如有不适，请立即就医。
-------------------------------------------------------------------------------------------------------------------------5：灭火措施适用灭火媒介：使用泡沫、干粉、或水沫，不要用水流。
长城锂基润滑脂MSDS
产品安全技术说明书1）有关化学品和公司方面的信息品名长城二硫化钼锂基润滑脂一般特征膏状半固体用途适用于载重汽车的各摩擦部位以及其他重负荷机械设备的润滑制造商中国石油化工股份有限公司润滑油分公司客服电话 800-810-98862）构成成分的名称及含有量化学物质名组成成分含量Wt%稠化剂混合物 6-15添加剂混合物＜14基础油混合物 75-903）危险及有害性根据动物实验，没有发现有力证据证明该产品致癌。
通常情况下本产品不会危害健康，过度接触可能会对眼睛、皮肤、呼吸等产生刺激。
4）应急措施的要领进入眼睛时用洁净流水清洗15分钟以上，接受医生的诊疗。
接触皮肤时把沾染的部位擦拭干净后用香皂清洗，必要时就医。
吸入时脱离接触区域，吸入新鲜的空气，必要时接受医生的诊断。
食入时不要强行呕吐，立即接受医生诊疗。
5）发生爆炸火灾时的应对方法灭火剂二氧化碳、干粉、泡沫、喷雾灭火器等灭火方法喷洒燃烧时发生的有害物质不完全燃烧时产生浓烟、一氧化碳、硫氧化物、醛及其他分解成分。
不可使用的灭火剂水6）发生漏油时的应对方法保护措施当发生泄漏时，在清除泄露的油剂时，采用防护器材来保护人体。
泄漏处理大量泄漏时用真空泵抽到容器中，少量可用粘土、沙子等吸附，装入密封容器中处理掉。
7）使用及储存方法存储管理禁止储存在敞口容器中。
在阴凉、干燥、通风好的地方保存，禁止与火苗、火花、高温物体的接触。
空容器处理空容器可能还残留部分产品，勿切割、焊接，勿暴露在高温、火焰中。
8）防止泄露及个人防护管理方法尽量存放在室内，使用后确认封口密封，防止油液泄露。
对呼吸道的防护高浓度区域请使用防毒口罩对眼睛防护请使用保护眼镜对手的防护请使用耐油性、耐化学性的防护手套对身体保护请使用非渗透性的安全服装及安全鞋卫生注意事项作业后用水清洗，擦拭护肤霜来保护皮肤9）物理化学特性外观黑色均匀软膏气味无异味工作锥入度，0.1mm 220-250滴点≥185℃10）安全性及反应性稳定性稳定（室温）保管要求远离强氧化剂、火源等有害分解物质周围环境温度下不会分解聚合反应不发生11）有关毒性方面的信息毒害信息急性经口毒性实验（一次最大限度实验）雌性、雄性小鼠LD50均大于5000mg/kgBW，为实际低毒。
锂基润滑脂安全技术说明书
密闭操作，注意通风。
工程控制：
空气中浓度超标时，建议佩戴自吸过滤式防毒面具（半面罩）。紧急事态抢救或撤离时，应该佩戴空气呼吸器。
呼吸系统防护：
如果工程控制设施不能保证空气污染物浓度在足以保护工人健康的一定水平以下,则最好佩戴经过认可的呼吸器。
眼睛防护：
若可能会接触，建议使用配有侧护罩的防护眼镜。
锂基润滑脂安全技术说明书
第一部分：化学品名称
化学品中文名称：
3号通用锂基润滑脂
化学品英文名称：
第二部分：成分/组成信息
主ቤተ መጻሕፍቲ ባይዱ组成
基础油硬脂酸碱抗氧化剂
第三部分：危险性概述
健康危害：
吞入后会造成腹泻、损坏消化器官和肺部损伤。
环境危害：
不易分解，对土壤及植物有害。
燃爆危险：
第3类易燃物。
第四部分：急救措施
废弃注意事项：
储存注意事项：
1.使用适当设计及保养的机械通风系统,如整体换气装置或局部排气装置。2.以局部排气装置及必要的制程隔离以控制雾滴及蒸气量。3.供给充分新鲜空气以补充排气系统抽出的空气。4.可能需要处理发散的废气以免污染环境。5.置于室内环境,保持油品密封，不可与易燃、易爆化学品摆在一起。
第八部分：接触控制/个体防护
手防护：
工作现场严禁吸烟。避免长期反复接触。
第九部分：理化特性
外观与性状：
浅绿色至深绿色不透明胶体（半固体）气味微。
闪点(℃)：
＞170℃
引燃温度(℃)：
溶解性：
不溶于水，可溶于多种有机溶剂。
第十部分：稳定性和反应活性
稳定性：
稳定
避免接触的条件：
阳光曝晒,油桶不密封,呈于露天环境中。
物料安全数据表锂基脂
物料安全数据表1：化学品名称及企业标识锂基润滑脂2：组成/成分资料成分：精制矿物油、皂类增稠剂、适当的性能添加剂。
此产品不含任何等于或高于规定限值的有害成分。
3：危险标识此产品并不属于危险产品。
但必须按照良好的工业卫生条件和安全操作规程进行使用。
4：急救措施眼：将眼睛张大，用大量水冲洗眼睛。
若眼睛仍有任何红肿、疼痛或不适，应尽快就医。
皮肤：皮肤若接触到油品，应尽快用清水和肥皂彻底加以清洗。
更换严重受污染的衣服，清洗下面弄脏的皮肤。
吸入气体：产品在规定温度下使用不会生烟。
如若吸入高温下产生的油烟造成鼻喉部刺激、或咳嗽，应尽快移至空气新鲜处。
如果仍有不适，应送医诊治。
吞服：若污染了口部，应用水彻底冲洗，如有不适，请立即就医。
5：灭火措施适用灭火媒介：使用泡沫、干粉、或水沫，不要用水流。
特殊接触危险：燃烧或遇热可能会发出有毒烟雾。
特别保护仪器：限定空间内的火灾，应该由受训过的人员穿戴好氧气面具进行处理。
可以用水冷却附近的遇热区域/物品/包装。
由于有沸溢之危险。
要避免直接喷射到储存容器里。
6：意外溢出后措施个人安全：产品溢出在地上，容易使人滑倒。
环境安全：避免流入去水道、污水渠或其他水道。
解除污染程序：集中刮去大部分油品，剩下部分用砂土或其他适当的惰性物质去除。
建议备有足量的适当吸收性物质，以处理可能发生的任何泄漏。
7：处理及储存处理：避免与眼睛接触。
如果有可能会溅出，应戴上适当的全面罩护目镜或化学护目镜。
避免经常或长期地与新油或旧油有皮肤接触。
任何时候都要保持良好的工作状况、良好的个人卫生和车间清洁。
接触后彻底清洗双手。
防火：浸过油品的擦布、纸、或用来吸收泄漏物的材料，都有燃火危险性，所以不能堆积在一起，用后应立即安全地处理掉。
储存：确保容器密闭，存放在遮盖物下。
远离热源和火源。
8：接触限度/个人安全保护对该油品没有专业的暴露限制。
确保良好的通风。
尽量避免吸入使用中产生的油气、油烟雾。
如果生成了油气、油烟雾，应该控制他们在工作场所空气中的浓度，尽可能使之降至最低。
锂基润滑脂安全技术说明书
锂基润滑脂安全技术说明书（复合锂基易燃烧）1、产品及企业标识品名锂基润滑脂一般特征膏装半固体用途适用载重汽车的各摩擦部位以及其他重负荷机械设备的润滑公司名称地址邮编电话传真2、构成成分的名称及含有量化学物质名组成成份含量Wt%稠化剂混合物6-15添加剂混合物〈14基础油混合物75-903、危险及有害性根据动物实验，没有发现有力证据证明该产品致癌。
通常情况下本产品不会危害健康，过度接触可能会对眼睛皮肤，呼吸等产生刺激。
4、应急措施的要领进入眼睛时用洁净流水清洗15分钟以上，接受医生的诊疗接触皮肤时把沾染的部位擦试干净后用香皂清洗，必要时就医吸入时脱离接触区域，吸入新鲜空气，必要时就医食入时不要强行呕吐，立即接受医生诊疗5、发生爆炸火灾时的应对方法灭火剂二氧人碳、干粉、泡沫、喷雾灭火器等灭火方法喷洒燃烧时发生的有害物质不完全燃烧时产生浓烟，一氧化碳、硫氧化物、醛及其他分解成分。
不可使用的灭火剂水6、发生漏油时的应对方法保护措施：当发生泄漏时，在清除泄露的油剂时，采用防护器材来保护人体。
泄漏处理：大量泄漏时用颠泵抽到容器中，少量可用粘土，沙子等吸附，装入密封容器中处理掉。
7、使用及储存方法存储管理：禁止储存在敞口容器中。
在阴凉、干燥、通风好的地方保存，禁止怀火苗、火花、高温物体摘触。
空容器处理：空容器可能还残留部份产品，勿切割，焊接，勿暴露在高温、火焰中。
8、防止泄露及个人防护管理方法：尽量存放在室内，使用后确认封口密封，防止油液泄露。
对呼吸道的防护高浓度区域请使用防毒口罩对眼睛防护请使用防护眼镜对手防护请使用耐油性、耐化学性的防护手套对身体保护请使用非渗透性的安全服装及安全鞋卫生注意事项作业后用水清洗，擦拭护肤霜9、物理化学特性外观红色均匀软膏（红、蓝、黄）气味无异味工作锥入度0.1mm 220-250滴点≥185℃10、安全性及反应性稳定性稳定（室温）保管要求远离强氧化剂、火源等有害分解物质周围环境温度下不会分解聚合反应不发生11、有关毒性方面信息毒害信息急性经口毒性实验（一次最大限度实验）雌性、雄性小鼠LD50均大于5000mg/kgBW,为实际低毒。
MSDS-锂基润滑脂(黄油)化学品安全技术说明书
化学品安全技术说明书（MＳＤＳ）1：化学品名称及企业标识产品名称：锂基润滑脂(俗称黄油)用途：车用或普通设备用脂-------------------------------------------------------------------------------------------------------------------------2：组成/成分资料成分：精制矿物油、皂类增稠剂、适当的性能添加剂。
此产品不含任何等于或高于规定限值的有害成分。
请参阅第八节职业接触限度-------------------------------------------------------------------------------------------------------------------------3：危险标识此产品并不属于危险产品。
但必须按照良好的工业卫生条件和安全操作规程进行使用。
-------------------------------------------------------------------------------------------------------------------------4：急救措施眼：将眼睛张大，用大量水冲洗眼睛。
若眼睛仍有任何红肿、疼痛或不适，应尽快就医。
皮肤：皮肤若接触到油品，应尽快用清水和肥皂彻底加以清洗。
更换严重受污染的衣服，清洗下面弄脏的皮肤。
吸入气体：产品在规定温度下使用不会生烟。
如若吸入高温下产生的油烟造成鼻喉部刺激、或咳嗽，应尽快移至空气新鲜处。
如果仍有不适，应送医诊治。
吞服：若污染了口部，应用水彻底冲洗，如有不适，请立即就医。
-------------------------------------------------------------------------------------------------------------------------5：灭火措施适用灭火媒介：使用泡沫、干粉、或水沫，不要用水流。
3号锂基脂MSDS
自燃温度: 未制定
部分 6 泄漏应急处理
通告程序 在发生溢出或泄漏意外的情况下，应根据所有适用法规向有关部门通报。
部分 5 消防措施
灭火介质 适当的灭火介质: 使用消防水雾、泡沫、干化学制剂( 干粉 )或者二氧化碳(CO2) 灭火。 不当的灭火介质: 直接使用水。
消防 消防说明: 疏散该地区。防止控制火灾或稀释的流出液流入河川、下水道或饮水源。 消防员应使用标准防护设备，在密闭空间需使用自给式呼吸器(SCBA)。用喷水的方 式使暴露于火灾的表面降温并保护工作人员。 危险的燃烧产物: 浓烟，乙醛，硫氧化物，未完全燃烧产物，碳的氧化物。
包括: 一般的使用状况下通风足够时通常不需要保护措施。 在空气传播浓度高的环境中，使用经认可的自给式呼吸器，在正压方式下工作。带 有逃生瓶的自给式呼吸器适用于氧气不足、气体/蒸气预警告特性指标差，或者空气 过滤器负荷过载的情况。 手防护: 所提供的任何特定手套的信息是根据公开文献资料和手套生产商的数据。 要根据使用条件选择手套的种类及使用时间，可根据使用条件向手套生产商咨询选 择手套的种类及使用时间，检查和替换破旧和损坏的手套。 可用于处理该材料的手套类型包括: 在正常使用条件下一般不需要防护。合成橡胶，使用腈类手套。 眼睛防护: 若可能会接触，建议使用配有侧护罩的防护眼镜。 皮肤和身体防护: 这里提供的任何专门的保护衣信息均基于公开的文献或者生产商 数据。 可考虑用于该产品的工作服类型包括: 一般状况下使用时不需特别保护皮肤。保持良好的个人卫生习惯,应采取预防措施避 免皮肤接触。 卫生措施: 保持良好的个人卫生习惯，如在处理该之产品后洗手，以及吃饭、喝水 和/或吸烟之前洗手。定期清洗工作服和防护设备以清除污染物。丢弃不能洗净的受 污染衣物和鞋子，养成良好的生活习惯。
昆仑极压锂基润滑脂安全技术说明书
安全技术说明书（MSDS ）昆仑极压锂基润滑脂版本号：A2 版 发布日期：2016 年 10 月 11 日产品名称：极压锂基润滑脂 000 号、00 号、0 号、1 号、2 号、3 号产品分类：润滑脂商品名称：昆仑极压锂基润滑脂000 号、00 号、0 号、1 号、2 号、3 号推荐用途：适用高负荷机械设备轴承和齿轮的润滑，冶金行业的冷、热轧机及高炉附属设备、炼钢起重设备，矿山等行业的机械设备及重载车辆摩擦部位的润滑。
服务电话：400-810-3000 800-810-3001网址：制造企业名称：中国石油天然气股份有限公司润滑油分公司企业地址：北京市朝阳区太阳宫金星园 8 号楼 A 座 17 层传真号码：0086-010-********企业应急电话：0086-010-********本产品为精炼润滑油基础油与添加剂混合物，组成含量均为重量百分数。
成分基础油脂肪酸锂盐添加剂需要披露的有害物质：磷酸酯铵盐含量数（WT%） ＞85 ＜13.5 ＜0.5＜1.0 CAS 号 61188-14-5根据化学品分类和危险性公示通则（GB 13690-2009）以及危险货物品名表（GB 12268-2005），本产品不属于危险品。
在正常使用的情况下，本产品不存在不可预计的危险。
物理/化学危险性类别：不归为危险物质。
健康危险性类别：无明显危害。
健康危害：高压射向皮肤可能会造成严重损伤，过度接触会造成眼部、皮肤或呼吸刺激。
环境危害：无明显危害。
食入时：饮足量温水，催吐，大量吞服者，应立即送医院诊治，在医师的指导下采取催吐或其它的救护措施。
眼睛接触：立即翻开上、下眼睑，用流动清水或生理盐水冲洗,若发生持续刺激，则需就医。
皮肤接触：脱去污染的衣着，用肥皂和大量流动清水洗净被污染的部分。
如果产品被注入皮下或者人体任何部位,无论伤口的外观或大小,必须立即送医院进行外科检查治疗。
危险特性：本产品遇明火、高热或与氧化剂接触可能引起燃烧。
星普锂基脂润滑MSDS英文版
Revision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________SAFETY DATA SHEET1.PRODUCT AND COMPANY IDENTIFICATIONProduct Name:Lithium grease semifluid,XingpuProduct Code:noneRecommended Use:Lubricating GreaseManufacturer or supplier's detailsSupplier:Shandong Honsing Chemical Co.,Ltd.Xinxing Industrial ZoneGuangrao CountyDongying257335China24Hour Emergency Telephone(+86)532-83889090Supplier General Contact(+86)546-2952012800-8609178E-Mail hxhgxuhui@FAX(+86)546-2952026Recommended use of the chemical and restrictions on useRecommended use:Automotive and industrial greaseEMERGENCY OVERVIEWAppearance Semi-solid at ambient temperature.Colour YellowOdour Slight petroleumHealth Hazards Not classified as dangerous for supply or conveyance.High-pressure injection under the skin may cause serious damage including localnecrosis.Safety Hazards Not classified as flammable but will burn.Environmental Hazards Not classified as dangerous for the environment.GHS ClassificationBased on available data this substance/mixture does not meet the classification criteria.GHS label elementsHazard pictograms:No Hazard Symbol requiredSignal word:No signal wordHazard statements:Revision Date:2Feb 2021SDS Number:SDHXSDS2103EN Issue Date:2Feb 2021Version:1.00____________________________________________________________________________________________________________________________________PHYSICAL HAZARDS:Not classified as a physical hazard under GHS criteria.HEALTH HAZARDS:Not classified as a health hazard under GHS criteria.ENVIRONMENTAL HAZARDS:Not classified as an environmental hazard under GHS criteria.Precautionary statements :Prevention:No precautionary phrases.Response:No precautionary phrases.Storage:No precautionary phrases.Disposal:No precautionary phrases.Other hazards which do not result in classificationProlonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/ed grease may contain harmfulimpurities.High-pressure injection under the skin may cause serious damage including local necrosis.Not classified as flammable but will burn.Physical and chemical hazards Not classifiedas flammable but will burn.Health Hazards Inhalation:Under normal conditions of use,this is not expected to bea primary route of exposure.Skin:Prolonged or repeated skin contactwithout proper cleaning can clog the pores of the skin resulting indisorders such as oil acne/folliculitis.Eyes:May cause slight irritationto eyes.Ingestion:Low toxicity if swallowed.Environmental Hazards Not classified as dangerous for the environment.Chemical nature :A lubricating grease containing highly-refined mineral oils and additives.Thehighly refined mineral oil contains <3%(w/w)DMSO extract,according to IP346.Hazardous componentsChemical NameCAS#Concentration,%Classification BENZENAMINE,N-PHENYL-,REACTIONPRODUCTS WITH 2,4,4-TRIMETHYLPENTENEAND 2-methylpropene 184378-08-30.1-1.0Acute Env Tox.3;H402Chronic Env Tox.3;H412For explanation of abbreviations see section 16.Revision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00FIRST AID:INHALATIONUnder normal conditions of intended use,this material is not expected to be an inhalation hazard.SKIN CONTACTWash contact areas with soap and water.If product is injected into or under the skin,or into any part of the body,regardless of the appearance of the wound or its size,the individual should be evaluated immediately by a physician as a surgical emergency.Even though initial symptoms from high pressure injection may be minimal or absent,early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.EYE CONTACTFlush thoroughly with water.If irritation occurs,get medical assistance.INGESTIONFirst aid is normally not required.Seek medical attention if discomfort occurs.IMPORTANT SYMPTOMS AND HEALTH EFFECTSLocal necrosis as evidenced by delayed onset of pain and tissue damage a few hours after injection.ADVICE TO PROTECT RESCUERPlease refer to Section8for personal protection information.NOTE TO PHYSICIANThe need to have special means for providing specific and immediate medical treatment available in the workplace is not expected.Suitable extinguishing media:Foam,water spray or fog.Dry chemical powder,carbon dioxide,sand or earthmay be used for small fires only.Unsuitable extinguishing media:Do not use water in a jet.Specific hazards during firefighting:Hazardous combustion products may include:A complex mixture of airbornesolid and liquid particulates and gases(smoke).Carbon monoxide may beevolved if incomplete combustion occurs.Unidentified organic and inorganiccompounds.Specific extinguishing methods:Use extinguishing measures that are appropriate to local circumstances andthe surrounding environment.Special protective equipment for firefighters:Revision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________Proper protective equipment including chemical resistant gloves are to beworn;chemical resistant suit is indicated if large contact with spilledproduct is expected.Self-Contained Breathing Apparatus must be worn whenapproaching a fire in a confined space.Select fire fighter's clothingapproved to relevant Standards(e.g.Europe:EN469).Personal precautions,protective equipment and emergency procedures:Avoid contact with skin and eyes.Environmental precautions:Use appropriate containment to avoid environmental contamination.Preventfrom spreading or entering drains,ditches or rivers by using sand,earth,or other appropriate barriers.Methods and materials for containment and cleaning up:Shovel into a suitable clearly marked container for disposal or reclamationin accordance with local regulations.Additional advice:For guidance on selection of personal protective equipment see Chapter8of this Safety Data Sheet.For guidance on disposal of spilled materialsee Chapter13of this Safety Data Sheet.HANDLINGHandling General Precautions:Use local exhaust ventilation if there is risk of inhalation of vapours,mists or e the information in this data sheet as input to arisk assessment of local circumstances to help determine appropriatecontrols for safe handling,storage and disposal of this material. Advice on safe handling:Avoid prolonged or repeated contact with skin.Avoid inhaling vapour and/ormists.When handling product in drums,safety footwear should be worn andproper handling equipment should be used.Properly dispose of anycontaminated rags or cleaning materials in order to prevent fires. Avoidance of contact:Strong oxidising agents.STORAGEOther data:Keep container tightly closed and in a cool,well-ventilated eproperly labeled and closable containers.Store at ambient temperature. Packaging material:Suitable material:For containers or container linings,use mild steelor high density polyethylene.Unsuitable material:PVC.Container Advice:Polyethylene containers should not be exposed to high temperatures becauseof possible risk of distortion.Components with workplace control parametersRevision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________Components CAS-No.Value type(Form ofexposure)Control parameters/Permissible concentrationBasisOil mist,mineral Not Assigned TWA(Mist)5mg/m3OSHA Z-1Oil mist,mineral Not Assigned TWA(Inhalable fraction)5mg/m3ACGIH Biological occupational exposure limitsNo biological limit allocated.Monitoring MethodsMonitoring of the concentration of substances in the breathing zone ofworkers or in the general workplace may be required to confirm compliancewith an OEL and adequacy of exposure controls.For some substancesbiological monitoring may also be appropriate.Validated exposuremeasurement methods should be applied by a competent person and samplesanalysed by an accredited laboratory.Examples of sources of recommendedexposure measurement methods are given below or contact the supplier.Further national methods may be available.National Institute ofOccupational Safety and Health(NIOSH),USA:Manual of Analytical Methods/niosh/Occupational Safety and Health Administration(OSHA),USA:Sampling and Analytical Methods /Healthand Safety Executive(HSE),UK:Methods for the Determination of HazardousSubstances /Institut für Arbeitsschutz DeutschenGesetzlichen Unfallversicherung(IFA),Germanyhttp://www.dguv.de/inhalt/index.jsp L'Institut National de Recherche etde Securité,(INRS),France http://www.inrs.fr/accueilEngineering measures:The level of protection and types of controls necessary will vary dependingupon potential exposure conditions.Select controls based on a riskassessment of local circumstances.Appropriate measures include:Adequate ventilation to control airborne concentrations.Where materialis heated,sprayed or mist formed,there is greater potential for airborneconcentrations to be generated.General Information:Define proceduresfor safe handling and maintenance of cate and train workersin the hazards and control measures relevant to normal activitiesassociated with this product.Ensure appropriate selection,testing andmaintenance of equipment used to control exposure, e.g.personalprotective equipment,local exhaust ventilation.Drain down system priorto equipment break-in or maintenance.Retain drain downs in sealed storagepending disposal or subsequent recycle.Always observe good personalhygiene measures,such as washing hands after handling the material andbefore eating,drinking,and/or smoking.Routinely wash work clothing andprotective equipment to remove contaminants.Discard contaminatedclothing and footwear that cannot be cleaned.Practice good housekeeping.Due to the product's semi-solid consistency,generation of mists and dustsis unlikely to occur.Personal protective equipmentProtective measuresRevision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________Personal protective equipment(PPE)should meet recommended nationalstandards.Check with PPE suppliers.Respiratory protection:No respiratory protection is ordinarily required under normal conditionsof use.In accordance with good industrial hygiene practices,precautions shouldbe taken to avoid breathing of material.If engineering controls do notmaintain airborne concentrations to a level which is adequate to protectworker health,select respiratory protection equipment suitable for thespecific conditions of use and meeting relevant legislation.Check withrespiratory protective equipment suppliers.Where air-filteringrespirators are suitable,select an appropriate combination of mask andfilter.Select a filter suitable for the combination of organic gases andvapours[Type A/Type P boiling point>65°C(149°F)].Hand protection Remarks:Where hand contact with the product may occur the use of gloves approvedto relevant standards(e.g.Europe:EN374,US:F739)made from thefollowing materials may provide suitable chemical protection.PVC,neoprene or nitrile rubber gloves Suitability and durability of a gloveis dependent on usage,e.g.frequency and duration of contact,chemicalresistance of glove material,dexterity.Always seek advice from glovesuppliers.Contaminated gloves should be replaced.Personal hygiene isa key element of effective hand care.Gloves must only be worn on cleanhands.After using gloves,hands should be washed and dried thoroughly.Application of a non-perfumed moisturizer is recommended.For continuouscontact we recommend gloves with breakthrough time of more than240minutes with preference for>480minutes where suitable gloves can beidentified.For short-term/splash protection we recommend the same butrecognize that suitable gloves offering this level of protection may notbe available and in this case a lower breakthrough time maybe acceptableso long as appropriate maintenance and replacement regimes are followed.Glove thickness is not a good predictor of glove resistance to a chemicalas it is dependent on the exact composition of the glove material.Glovethickness should be typically greater than0.35mm depending on the glovemake and model.Eye protection:If material is handled such that it could be splashed into eyes,protective eyewear isrecommended.Skin and body protection:Skin protection is not ordinarilyrequired beyond standard work clothes.It is good practice to wearchemical resistant gloves.Thermal hazards:Not applicableEnvironmental exposure controlsGeneral advice:Take appropriate measures to fulfill the requirements of relevantenvironmental protection legislation.Avoid contamination of theenvironment by following advice given in Chapter6.If necessary,preventundissolved material from being discharged to waste water.Waste watershould be treated in a municipal or industrial waste water treatment plantbefore discharge to surface water.Local guidelines on emission limitsfor volatile substances must be observed for the discharge of exhaust airRevision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________Note:Physical and chemical properties are provided for safety,health and environmental considerations only and may not fully represent product specifications.Contact the Supplier for additional information.Appearance:Semi-fluid at ambient temperature.Colour:yellowOdour:Slight hydrocarbonOdour Threshold:Data not availablepH:Not applicableDrop point:>=150°C/302°F Method:IP396Initial boiling point and boiling range:Data not availableFlash point:>=200°C/392°F Method:ASTM D92(COC)Evaporation rate:Data not availableFlammability(solid,gas):Data not availableUpper explosion limit:Typical10%(V)Lower explosion limit:Typical1%(V)Vapour pressure:<0.5Pa(20°C/68°F)estimated value(s)Relative vapour density:>1estimated value(s)Relative density:0.950(15°C/59°F)Density:950kg/m3(15°C/59°F)Method:Gardner MethodSolubility(ies)Water solubility:negligibleSolubility in other solvents:Data not availablePartition coefficient:N-octanol/water:log Pow:>6(based on information on similar products)Auto-ignition temperature:>320°C/608°FDecomposition temperature:Data not availableViscosity Viscosity,dynamic:Data not availableViscosity,kinematic:8mm2/s(100°C/212°F)Method:ISO310490mm2/s(40.0°C/104.0°F)Method:ISO3104Explosive properties:Not classifiedOxidizing properties:Data not availableConductivity:This material is not expected to be a static accumulator.NOTE:Most physical properties above are for the oil component in the material.Reactivity:The product does not pose any further reactivity hazards in additionto those listed in the following sub-paragraph.Chemical stability:Stable.Possibility of hazardous reactions:Reacts with strong oxidising agents.Conditions to avoid:Extremes of temperature and direct sunlight.Incompatible materials:Strong oxidising agents.Hazardous decomposition products:No decomposition if stored and applied as directed.Revision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00Basis for assessment:Information given is based on data on the components and thetoxicology of similar products.Unless indicated otherwise,thedata presented is representative of the product as a whole,rather than for individual component(s).Exposure routes:Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion.Acute toxicityProduct:Acute oral toxicity:LD50rat:>5,000mg/kgRemarks:Low toxicity:Based on available data,the classification criteria are not met.Acute inhalation toxicity:Remarks:Based on available data,the classification criteria are not met. Acute dermal toxicity:LD50Rabbit:>5,000mg/kgRemarks:Low toxicity:Based on available data,the classification criteria are not met.Skin corrosion/irritationProduct:Remarks:Slightly irritating to skin.,Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acne/folliculitis.,Based on available data,the classification criteria are not met.Serious eye damage/eye irritationProduct:Remarks:Slightly irritating to the eye.,Based on available data,the classification criteria are not met. Respiratory or skin sensitisationProduct:Remarks:Not a skin sensitiser.Based on available data,the classification criteria are not met.Germ cell mutagenicityProduct:Remarks:Non mutagenic,Based on available data,the classification criteria are not met.CarcinogenicityProduct:Remarks:Not a carcinogen.,Based on available data,the classification criteria are not met.Remarks:Product contains mineral oils of types shown to be non-carcinogenic in animal skinpainting studies., Highly refined mineral oils are not classified as carcinogenic by the International Agency for Research on Cancer(IARC).Material GHS/CLP Carcinogenicity ClassificationHighly refined mineral oil No carcinogenicity classification.Reproductive toxicityProduct:Remarks:Not a developmental toxicant.,Does not impair fertility.,Based on available data,the classification criteria are not met.Revision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________ STOT-single exposureProduct:Remarks:Based on available data,the classification criteria are not met.STOT-repeated exposureProduct:Remarks:Based on available data,the classification criteria are not met.Aspiration toxicityProduct:Not an aspiration hazard.Further informationProduct:Remarks:Used grease may contain harmful impurities that have accumulated during use.The concentration of such harmful impurities will depend on use and they may present risks to health and the environment on disposal., ALL used grease should be handled with caution and skin contact avoided as far as possible.Remarks:High pressure injection of product into the skin may lead to local necrosis if the product is not surgically removed.Remarks:Slightly irritating to respiratory system.Basis for assessment:Ecotoxicological data have not been determined specifically for this product.Information given is based on a knowledge of the components and the ecotoxicologyof similar products.Unless indicated otherwise,the data presented isrepresentative of the product as a whole,rather than for individualcomponent(s).(LL/EL/IL50expressed as the nominal amount of product required toprepare aqueous test extract).EcotoxicityProduct:Toxicity to fish(Acute toxicity):Remarks:LL/EL/IL50>100mg/l Practically non toxic:Based on availabledata,the classification criteria are not met.Toxicity to crustacean(Acute toxicity):Remarks:LL/EL/IL50>100mg/l Practically non toxic:Based on available data,the classification criteria are not met.Toxicity to algae/aquatic plants(Acute toxicity):Remarks:LL/EL/IL50>100mg/l Practically non toxic:Based on available data,the classification criteria are not met.Toxicity to fish(Chronic toxicity):Remarks:Data not availableToxicity to crustacean(Chronic toxicity):Remarks:Data not availableToxicity to microorganisms(Acute toxicity):Remarks:Data not availablePersistence and degradabilityProduct:Biodegradability:Remarks:Not readily biodegradable.,Major constituents are inherentlybiodegradable,but contains components that may persist in the environment. Bioaccumulative potentialProduct:Bioaccumulation:Remarks:Contains components with the potential to bioaccumulate.PartitionRevision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________coefficient:noctanol/water:log Pow:>6Remarks:(based on information on similarproducts)Mobility in soilProduct:Mobility:Remarks:Semi-solid under most environmental conditions.,If it enters soil,it willadsorb to soil particles and will not be mobile.Remarks:Floats on water.Other adverse effectsno data availableProduct:Additional ecological information:Does not have ozone depletion potential,photochemical ozone creationpotential or global warming potential.,Product is a mixture ofnon-volatile components,which will not be released to air in anysignificant quantities under normal conditions of use.Poorly solublemixture.,Causes physical fouling of aquatic organisms.Mineral oil doesnot cause chronic toxicity to aquatic organisms at concentrations lessthan1mg/l.Waste from residues:Recover or recycle if possible.It is the responsibility of the wastegenerator to determine the toxicity and physical properties of thematerial generated to determine the proper waste classification anddisposal methods in compliance with applicable regulations.Do notdispose into the environment,in drains or in water courses Waste productshould not be allowed to contaminate soil or ground water,or be disposedof into the environment.Waste,spills or used product is dangerous waste. Contaminated packaging:Dispose in accordance with prevailing regulations,preferably to arecognized collector or contractor.The competence of the collector orcontractor should be established beforehand.Disposal should be inaccordance with applicable regional,national,and local laws andregulations.Local legislation Remarks:Disposal should be in accordance with applicable regional,national,andlocal laws and regulations.Hazardous Waste.If potential for exposure exists refer to Section8forspecific personal protective equipment.China List of Dangerous Goods(GB12268-2012):Not Regulated for Land Transport International RegulationsADR Not regulated as a dangerous goodIATA-DGR Not regulated as a dangerous goodIMDG-Code Not regulated as a dangerous goodTransport in bulk according to Annex II of MARPOL73/78and the IBC CodeRevision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________ Not applicable for product as supplied.MARPOL Annex1rules apply for bulk shipments by sea.Special precautions for user Remarks:Special Precautions:Refer to Section7,Handling&Storage,for special precautions which a user needs to be aware of or needs to complywith in connection with transport.REGULATORY STATUS AND APPLICABLE LAWS AND REGULATIONSThis material is not considered hazardous according to The General Rule for Classification and Hazard Communication of Chemicals(GB13690-2009).The General Rules for preparation of precautionary label for Chemicals(GB15258-2009):Not RegulatedLaw of the People's Republic of China on Prevention and Control of Environmental Pollution by Solid Waste: See Disposal Considerations section.National regulatory informationRotterdam Convention(Prior Informed Consent):Not applicableStockholm Convention(Persistent Organic Pollutants):Not applicableLaw on the Prevention and Control of Occupational DiseasesThe categories of occupational disease:Not applicableOccupational Disease Classification list:Not applicableRegulations on Safety Management of Hazardous ChemicalsIdentification of Major Hazard Installations for Hazardous Chemicals(GB18218):Not applicable Hazardous Chemicals for Priority Management under SAWS:Not applicableRegulations on Labour Protection in Workplaces where Toxic Substances are Used Catalogue of Highly Toxic Chemicals:Not applicableRegulation of Environmental Management on the First Import of Chemicals and the Import and Export of Toxic Chemicals China Severely Restricted Toxic Chemicals for Import and Export:Not applicableOther international regulationsThe components of this product are reported in the following inventories:EINECS:All components listed or polymer exempt.TSCA:All components listed.IECSC:All components listed.N/D=Not determined,N/A=Not applicableFull text of H-StatementsH315:Causes skin irritation;Skin Corr/Irritation,Cat2H318:Causes serious eye damage;Serious Eye Damage/Irr,Cat1H401:Toxic to aquatic life;Acute Env Tox,Cat2H402:Harmful to aquatic life;Acute Env Tox,Cat3H411:Toxic to aquatic life with long lasting effects;Chronic Env Tox,Cat2Revision Date:2Feb2021SDS Number:SDHXSDS2103EN Issue Date:2Feb2021Version:1.00____________________________________________________________________________________________________________________________________ H412:Harmful to aquatic life with long lasting effects;Chronic Env Tox,Cat3AICS-Australian Inventory of Chemical Substances;ANTT-National Agency for Transport by Land of Brazil; ASTM-American Society for the Testing of Materials;bw-Body weight;CMR-Carcinogen,Mutagen or Reproductive Toxicant;DIN-Standard of the German Institute for Standardisation;DSL-Domestic Substances List(Canada);ECx-Concentration associated with x%response;ELx-Loading rate associated with x% response;EmS-Emergency Schedule;ENCS-Existing and New Chemical Substances(Japan);ErCx-Concentration associated with x%growth rate response;ERG-Emergency Response Guide;GHS-Globally Harmonized System;GLP-Good Laboratory Practice;IARC-International Agency for Research on Cancer; IATA-International Air Transport Association;IBC-International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk;IC50-Half maximal inhibitory concentration;ICAO-International Civil Aviation Organization;IECSC-Inventory of Existing Chemical Substances in China; IMDG-International Maritime Dangerous Goods;IMO-International Maritime Organization;ISHL-Industrial Safety and Health Law(Japan);ISO-International Organisation for Standardization;KECI-Korea Existing Chemicals Inventory;LC50-Lethal Concentration to50%of a test population;LD50-Lethal Dose to50% of a test population(Median Lethal Dose);MARPOL-International Convention for the Prevention of Pollution from Ships;n.o.s.-Not Otherwise Specified;Nch-Chilean Norm;NO(A)EC-No Observed(Adverse)Effect Concentration;NO(A)EL-No Observed(Adverse)Effect Level;NOELR-No Observable Effect Loading Rate; NOM-Official Mexican Norm;NTP-National Toxicology Program;NZIoC-New Zealand Inventory of Chemicals; OECD-Organization for Economic Co-operation and Development;OPPTS-Office of Chemical Safety and Pollution Prevention;PBT-Persistent,Bioaccumulative and Toxic substance;PICCS-Philippines Inventory of Chemicals and Chemical Substances;(Q)SAR-(Quantitative)Structure Activity Relationship;REACH-Regulation(EC)No1907/2006of the European Parliament and of the Council concerning the Registration, Evaluation,Authorisation and Restriction of Chemicals;SADT-Self-Accelerating Decomposition Temperature; SDS-Safety Data Sheet;TCSI-Taiwan Chemical Substance Inventory;TDG-Transportation of Dangerous Goods;TSCA-Toxic Substances Control Act(United States);UN-United Nations;UNRTDG-United Nations Recommendations on the Transport of Dangerous Goods;vPvB-Very Persistent and Very Bioaccumulative;WHMIS -Workplace Hazardous Materials Information SystemSources of key data used to compile the Safety Data Sheet:The content and format of this safety data sheet is in accordance with the GHS guidelines.,The quoted data are from,but not limited to,one or more sources of information(e.g.toxicological data from Shell Health Services,material suppliers’data,CONCAWE,EUIUCLID date base,EC1272regulation,etc).---------------------------------------------------------------------------------------------------------The information and recommendations contained herein are,to the best of Honsing Chemical's knowledge and belief, accurate and reliable as of the date issued.You can contact Honsing Chemical to insure that this document is the most current available from Honsing Chemical.The information and recommendations are offered for the user's consideration and examination.It is the user's responsibility to satisfy itself that the product is suitable for the intended use.If buyer repackages this product,it is the user's responsibility to insure proper health,safety and other necessary information is included with and/or on the container.Appropriate warnings and safe-handling procedures should be provided to handlers and users.Alteration of this document is strictly prohibited.Except to the extent required by law,re-publication or retransmission of this document,。
- 1、下载文档前请自行甄别文档内容的完整性，平台不提供额外的编辑、内容补充、找答案等附加服务。
- 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
- 3、如文档侵犯您的权益，请联系客服反馈,我们会尽快为您处理(人工客服工作时间：9:00-18:30)。
五、 燃爆特性与消防 危险特性 灭火剂 消防人员保护设备 六、 泄漏应急处理 应急处理 七、操作处置与储存 放入合适的、有明显标记的容器， 进行处理和回收。 燃烧可能形成液体、固体悬浮颗粒与燃气组成的复杂混合物，包 括一氧化碳以及不确定的有机和无机化合物。 泡沫、 干化学粉末、二氧化碳；沙或泥土仅宜用于小火。 合适的保护装置包括 在密封空间内接近起火点时 必需配戴的呼 吸装置。
第 1 页，共 3 页
操作注意事项
如有吸入油蒸汽、油雾或空气悬浮颗粒的危险，应采取局部通风 措施。避免接触眼睛、皮肤和呼吸系统。在圆筒中处理产品时， 穿上安全鞋，使用合适的处理设备，防止溢出。吸收漏油的织 物，纸张和其他材料均是火灾隐患，应及时、安全地处理，避免 堆积。除了针对健康、安全和环境危险控制所给予的具体建议以 外，还必须进行危险评估，以此帮助决定适合当地情况的控制措 施。 保存在凉爽、通风好的地方。使用正确的、贴有标签的、可封闭 的容器。避开阳光直晒、热源和强氧化剂。存储温度：最低 0 ℃，最高 50℃。建议使用的材料：容器或容器内层，使用低碳 钢或高密度聚乙烯。不适用的物质：容器或容器内层，避免使用 聚氯乙烯。额外信息：聚乙烯容器不应置于高温下，因为可能造 成变形。
十、 稳定性和反应性 稳定性 聚合危害 避免接触的条件 禁忌物 稳定的。 不聚合。 极端温度和阳光直晒。 强氧化剂。
第 2 页，共 3 页
Байду номын сангаас
十一、 毒理学资料 眼睛刺激或腐蚀 呼吸或皮肤过敏 十二、 生态学资料 对环境的危害 十三、 废弃处置 废弃处置方法
制表人：
对眼睛有中度刺激。 如果蒸汽被吸入，可对呼吸道产生轻微刺激。
产品安全技术说明书
执行日期：2014年7月9日
一、化学品标识 化学品中文名称 一般特征 制造商 客服电话 二、成分/组成信息 主要组成 三、 危险性概述 健康危害 燃爆危险 四、 急救措施 眼睛接触 吸入 食入 皮肤接触 用大量的水冲洗眼睛。若发生持续刺激，则需就医。 晕眩或反胃不太可能出现，如果发生了，将患者移至有新鲜空气 的地方，若症状持续则要求助医生。 用水漱口并就医。不要催吐。 脱去污染衣物，用水和肥皂清洗受影响的皮肤。 在正常使用条件下无特定的危险,过久或重复暴露可引起皮炎。 用过的润滑脂可能含有害的杂质。 非易燃品，但可燃烧。 基础油、添加剂、稠化剂。 1#锂基润滑脂 膏状半固体
储存注意事项
八、 接触控制/个体防护 呼吸系统防护 身体防护 手防护 眼睛防护 九、 理化特性 外观与性状 气味 闪点（ ℃） 燃烧上下极限 蒸汽密度(空气=1) 密度 用途 黄色。 矿物油特性。 大于 150℃（基于矿物油的） 典型： 1-10%v/v（基于矿物油的） 大于 1 近于 900kg/m3 车用及工业润滑脂。 不需要。 减少所有类型的皮肤接触。应该穿工作服和鞋底耐油的鞋子。 化学防护手套。 如可能发生溅泼 ，请戴安全眼镜或脸面罩。
该物质对环境有危害，应特别注意对地表水、土壤、大气和饮用 水的污染。
符合相关规定的可进行燃烧处理或重复利用， 避免环境污染。
审核： 批准执行人：
第 3 页，共 3 页