毕业论文(设计)外文文献翻译及原文
毕业论文(设计)外文文献翻译及原文
金融体制、融资约束与投资——来自OECD的实证分析R．SemenovDepartment of Economics，University of Nijmegen，Nijmegen（荷兰内梅亨大学，经济学院）这篇论文考查了OECD的11个国家中现金流量对企业投资的影响.我们发现不同国家之间投资对企业内部可获取资金的敏感性具有显著差异,并且银企之间具有明显的紧密关系的国家的敏感性比银企之间具有公平关系的国家的低.同时，我们发现融资约束与整体金融发展指标不存在关系.我们的结论与资本市场信息和激励问题对企业投资具有重要作用这种观点一致，并且紧密的银企关系会减少这些问题从而增加企业获取外部融资的渠道。
一、引言各个国家的企业在显著不同的金融体制下运行。
金融发展水平的差别(例如，相对GDP的信用额度和相对GDP的相应股票市场的资本化程度），在所有者和管理者关系、企业和债权人的模式中，企业控制的市场活动水平可以很好地被记录.在完美资本市场,对于具有正的净现值投资机会的企业将一直获得资金。
然而，经济理论表明市场摩擦，诸如信息不对称和激励问题会使获得外部资本更加昂贵，并且具有盈利投资机会的企业不一定能够获取所需资本.这表明融资要素，例如内部产生资金数量、新债务和权益的可得性，共同决定了企业的投资决策.现今已经有大量考查外部资金可得性对投资决策的影响的实证资料（可参考，例如Fazzari（1998）、 Hoshi(1991)、 Chapman（1996）、Samuel(1998））.大多数研究结果表明金融变量例如现金流量有助于解释企业的投资水平。
这项研究结果解释表明企业投资受限于外部资金的可得性。
很多模型强调运行正常的金融中介和金融市场有助于改善信息不对称和交易成本，减缓不对称问题,从而促使储蓄资金投着长期和高回报的项目,并且提高资源的有效配置（参看Levine（1997)的评论文章）。
因而我们预期用于更加发达的金融体制的国家的企业将更容易获得外部融资.几位学者已经指出建立企业和金融中介机构可进一步缓解金融市场摩擦。
隧道盾构-毕设论文外文翻译(翻译-原文)
毕业设计（论文）外文文献翻译院系：土木工程与建筑系年级专业：土木工程姓名：学号：附件：盾构SHIELDS指导老师评语：指导教师签名：年月日S HIEL D S【Abstr act】A tunnel shield is a structural system, used during the face excavation process. The paper mainly discusses the form and the structure of the shield. Propulsion for the shield is provided by a series of hydraulic jacks installed in the tail of the shield and the shield is widespread used in the underground environment where can not be in long time stable. The main enemy of the shield is ground pressure. Non-uniform ground pressure caused by the steering may act on the skin tends to force the shield off line and grade. And working decks inside the shield enable the miners to excavate the face, drill and load holes.【Keywor ds】shield hydraulic jacks ground pressure steering working decksA tunnel shield is a structural system, normally constructed of steel, used during the face excavation process. The shield has an outside configuration which matches the tunnel. The shield provides protection for the men and equipment and also furnished initial ground support until structural supports can be installed within the tail section of the shield. The shield also provides a reaction base for the breast-board system used to control face movement. The shield may have either an open or closed bottom. In a closed-bottom shield, the shield structure and skin provide 360-degree ground contact and the weight of the shield rests upon the invert section of the shield skin. The open shield has no bottom section and requires some additional provision is a pair of side drifts driven in advance of shield excavation. Rails or skid tracks are installed within these side drifts to provide bearing support for the shield.Shield length generally varies from1/2 to 3/4 of the tunnel diameter. The front of the shield is generally hooded to so that the top of the shield protrudes forward further than the invert portion which provides additional protection for the men working at the face and also ease pressure on the breast-boards. The steel skin of the shield may varyfrom 1.3 to 10 cm in thickness, depending on the expected ground pressures. The type of steel used in the shield is the subject of many arguments within the tunneling fraternity. Some prefer mild steel in the A36 category because of its ductility and case of welding in the underground environment where precision work is difficult. Others prefer a high-strength steel such as T-1 because of its higher strength/w eight ratio. Shield weight may range from 5 to 500 tons. Most of the heaviest shields are found in the former Sovier Union because of their preference for cast-iron in both structural and skin elements.Propulsion for the shield is provided by a series of hydraulic jacks installed in the tail of the shield that thrust against the last steel set that has been installed. The total required thrust will vary with skin area and ground pressure. Several shields have been constructed with total thrust capabilities in excess of 10000 tons. Hydraulic systems are usually self-contained, air-motor powered, and mounted on the shield. Working pressures in the hydraulic system may range from 20-70 Mpa. To resist the thrust of the shield jacks, a horizontal structure member (collar brace) must be installed opposite each jack location and between the flanges of the steel set. In addition, some structural provision must be made for transferring this thrust load into the tunnel walls. Without this provision the thrust will extend through the collar braces to the tunnel portal.An Englishman, Marc Brunel, is credited with inventing the shield. Brunel supposedly got his idea by studying the action of the Teredo navalis, a highly destructive woodworm, when he was working at the Chatham dock yard. In 1818 Brunel obtained an English patent for his rectangular shield which was subsequently uses to construct the first tunnel under the River Thames in London. In 1869 the first circular shield was devised by Barlow and Great Head in London and is referred to as the Great Head-type shield. Later that same year, Beach in New York City produced similar shield. The first use of the circular shield came during 1869 when Barlow and Great Head employed their device in the construction of the 2.1 in diameter Tower Subway under the River Thames. Despite the name of the tunnel, it was used only for pedestrian traffic. Beach also put his circular shield to work in 1869 to construct a demonstration project for a proposed NewYork City subway system. The project consisted of a 2.4 m diameter tunnel, 90 m long, used to experiment with a subway car propelled by air pressure.Here are some tunnels which were built by shield principle.Soft-ground tunneling Some tunnels are driven wholly or mostly through soft material. In very soft ground, little or no blasting is necessary because the material is easily excavated.At first, forepoling was the only method for building tunnels through very soft ground. Forepoles are heavy planks about 1.5 m long and sharpened to a point. They were inserted over the top horizontal bar of the bracing at the face of the tunnel. The forepoles were driven into the ground of the face with an outward inclination. After all the roof poles were driven for about half of their length, a timber was laid across their exposed ends to counter any strain on the outer ends. The forepoles thus provided an extension of the tunnel support, and the face was extended under them. When the ends of the forepoles were reached, new timbering support was added, and the forepoles were driven into the ground for the next advance of the tunneling.The use of compressed air simplified working in soft ground. An airlock was built, though which men and equipment passed, and sufficient air pressure was maintained at the tunnel face to hold the ground firm during excavation until timbering or other support was erected.Another development was the use of hydraulically powered shields behind which cast-iron or steel plates were placed on the circumference of the tunnels. These plates provided sufficient support for the tunnel while the work proceeded, as well as full working space for men in the tunnel.Under water tunneling The most difficult tunneling is that undertaken at considerable depths below a river or other body of water. In such cases, water seeps through porous material or crevices, subjecting the work in progress to the pressure of the water above the tunneling path. When the tunnel is driven through stiff clay, the flow of water may be small enough to be removed by pumping. In more porous ground,compressed air must be used to exclude water. The amount of air pressure that is needed increases as the depth of the tunnel increases below the surface.A circular shield has proved to be most efficient in resisting the pressure of soft ground, so most shield-driven tunnels are circular. The shield once consisted of steel plates and angle supports, with a heavily braced diaphragm across its face. The diaphragm had a number of openings with doors so that workers could excavate material in front of the shield. In a further development, the shield was shoved forward into the silty material of a riverbed, thereby squeezing displaced material through the doors and into the tunnel, from which the muck was removed. The cylindrical shell of the shield may extend several feet in front of the diaphragm to provide a cutting edge. A rear section, called the tail, extends for several feet behind the body of the shield to protect workers. In large shields, an erector arm is used in the rear side of the shield to place the metal support segments along the circumference of the tunnel.The pressure against the forward motion of a shield may exceed 48.8 Mpa. Hydraulic jacks are used to overcome this pressure and advance the shield, producing a pressure of about 245 Mpa on the outside surface of the shield.Shields can be steered by varying the thrust of the jacks from left side to right side or from top to bottom, thus varying the tunnel direction left or right or up or down. The jacks shove against the tunnel lining for each forward shove. The cycle of operation is forward shove, line, muck, and then another forward shove. The shield used about 1955 on the third tube of the Lincoln Tunnel in New York City was 5.5 m long and 9.6 m in diameter. It was moved about 81.2 cm per shove, permitting the fabrication of a 81.2 cm support ring behind it.Cast-iron segments commonly are used in working behind such a shield. They are erected and bolted together in a short time to provide strength and water tightness. In the third tube of the Lincoln Tunnel each segment is 2 m long, 81.2 cm wide, and 35.5 cm thick, and weighs about 1.5 tons. These sections form a ring of 14 segments that are linked together by bolts. The bolts were tightened by hand and then by machine.Immediately after they were in place, the sections were sealed at the joints to ensure permanent water tightness.Shields are most commonly used in ground condition where adequate stand-up time does not exist. The advantage of the shield in this type of ground, in addition to the protection afforded men and equipment , is the time available to install steel ribs, liner plates, or precast concrete segments under the tail segment of the shield before ground pressure and movement become adverse factors.One of the principle problems associated with shield use is steering. Non-uniform ground pressure acting on the skin tends to force the shield off line and grade. This problem is particularly acute with closed bottom shield that do not ride on rails or skid tracks. Steering is accomplished by varying the hydraulic pressure in individual thrust jacks. If the shied is trying to dive, additional pressure on the invert jacks will resist this tendency. It is not unusual to find shield wandering several feet from the required. Although lasers are frequently used to provide continuous line and grade data to operator, once the shield wanders off its course, its sheer bulk resists efforts to bring it back. Heterogeneous ground conditions, such as clay with random boulders, also presents steering problems.One theoretical disadvantage of the shield is the annular space left between the support system and the ground surface. When the support system is installed within the tail section of the shield, the individual support members are separated from the ground surface by the thickness of the tail skin. When steel ribs are used, the annular space is filled with timber blocking as the forward motion of the shield exposes the individual ribs.A continuous support system presents a different problem. In this case, a filler material, such as pea gravel or grout, is pumped behind the support system to fill the void between it and the ground surface.The main enemy of the shield is ground pressure. As ground pressure begins to build, two things happen, more thrust is required for shield propulsion and stress increases in the structural members of the shield. Shields are designed and function undera preselected ground pressure. Designers will select this pressure as a percentage of the maximum ground pressure contemplated by the permanent tunnel design. In some cases, unfortunately, the shield just gets built without specific consideration of the ground pressures it might encounter. When ground pressure exceeds the design limit, the shield gets “stuck”.The friction component of the ground pressure on the skin becomes greater than the thrust capability of the jacks. Several methods, including pumping bentonite slurry into the skin, ground interface, pushing heavy equipment, and bumping with dynamite, have been applied to stuck shields with occasional success.Because ground pressure tends to increase with time, the cardinal rule of operation is “keeping moving”.This accounts for the fracture activity when a shield has suffered a temporary mechanical failure. As ground pressure continues to build on the nonmoving shield , the load finally exceeds its structural limit and bucking begins. An example of shield destruction occurred in California in 1968 when two shields being used to drive the Carly V.Porter Tunnel were caught by excessive ground pressure and deformed beyond repair. One of the Porter Tunnel shields was brought to a halt in reasonably good ground by water bearing ground fault that required full breast-boards. While the contractor was trying to bring the face under control, skin pressure began to increase. While the face condition finally stabilized, the contractor prepared to resume operations and discovered the shield was stuck. No combination of methods was able to move it, and the increasing ground pressure destroyed the shield.To offset the ground pressure effect, a standard provision in design is a cutting edge radius several inches greater than the main body radius. This allows a certain degree o f ground movement before pressure can come to bear on the shield skin. Another approach, considered in theory but not yet put into practice, is the “w atermelon seed”design. The theory calls for a continuous taper in the shield configuration; maximum radius at the cutting edge and the minimum radius at the trailing edge of the tail. With this configuration, any amount of forward movement would create a drop in skin pressure.Working decks, spaced 2.4 to 3.0 m vertically, are provided inside the shield. These working decks enable the miners to excavate the face, drill and load holes, if necessary, and adjust the breast-board system. The hydraulic jacks for the breast-board are mounted on the underside of the work decks. Blast doors are sometimes installed as an integral part of the work decks if a substantial amount of blasting is expected.Some form of mechanical equipment is provided on the rear end of the working decks to assist the miners in handing and placing the element of the support system. In large tunnels, these individual support elements can weigh several tons and mechanical assistance becomes essential. Sufficient vertical clearance must be provided between the invert and the first working deck to permit access to the face by the loading equipment.盾构【摘要】隧道盾构是一结构系统，通常用于洞室开挖。
毕业设计论文外文文献翻译
毕业设计(论文）外文文献翻译院系：财务与会计学院年级专业：201＊级财务管理姓名:学号：132148*＊*附件: 财务风险管理【Abstract】Although financial risk has increased significantly in recent years risk and risk management are not contemporary issues。
The result of increasingly global markets is that risk may originate with events thousands of miles away that have nothing to do with the domestic market。
Information is available instantaneously which means that change and subsequent market reactions occur very quickly。
The economic climate and markets can be affected very quickly by changes in exchange rates interest rates and commodity prices。
Counterparties can rapidly become problematic。
As a result it is important to ensure financial risks are identified and managed appropriately. Preparation is a key component of risk management。
【Key Words】Financial risk，Risk management，YieldsI. Financial risks arising1.1What Is Risk1.1.1The concept of riskRisk provides the basis for opportunity. The terms risk and exposure have subtle differences in their meaning. Risk refers to the probability of loss while exposure is the possibility of loss although they are often used interchangeably。
建筑学Modern-Architecture现代建筑大学毕业论文外文文献翻译及原文
建筑学Modern-Architecture现代建筑⼤学毕业论⽂外⽂⽂献翻译及原⽂毕业设计（论⽂）外⽂⽂献翻译⽂献、资料中⽂题⽬：现代建筑⽂献、资料英⽂题⽬：Modern Architecture⽂献、资料来源：⽂献、资料发表（出版）⽇期：院（部）：专业：班级：姓名：学号：指导教师：翻译⽇期： 2017.02.14建筑学毕业设计的外⽂⽂献及译⽂⽂献、资料题⽬：《Advanced Encryption Standard》⽂献、资料发表（出版）⽇期：2004.10.25外⽂⽂献：Modern ArchitectureModern architecture, not to be confused with 'contemporary architecture', is a term given to a number of building styles with similar characteristics, primarily the simplification of form and the elimination of ornament. While the style was conceived early in the 20th century and heavily promoted by a few architects, architectural educators and exhibits, very few Modern buildings were built in the first half of the century. For three decades after the Second World War, however, it became the dominant architectural style for institutional and corporate building.1. OriginsSome historians see the evolution of Modern architecture as a social matter, closely tied to the project of Modernity and hence to the Enlightenment, a result of social and political revolutions.Others see Modern architecture as primarily driven by technological and engineering developments, and it is true that the availability of new building materials such as iron, steel, concrete and glass drove the invention of new building techniques as part of the Industrial Revolution. In 1796, Shrewsbury mill owner Charles Bage first used his ‘fireproof’ design, which relied on cast iron and brick with flag stone floors. Such construction greatly strengthened the structure of mills, which enabled them to accommodate much bigger machines. Due to poor knowledge of iron's properties as a construction material, a number of early mills collapsed. It was not until the early 1830s that Eaton Hodgkinson introduced the section beam, leading to widespread use of iron construction, this kind of austere industrial architecture utterly transformed the landscape of northern Britain, leading to the description, "Dark satanic mills" of places like Manchester and parts of West Yorkshire. The Crystal Palace by Joseph Paxton at the Great Exhibition of 1851 was an early example of iron and glass construction; possibly the best example is the development of the tall steel skyscraper in Chicago around 1890 by William Le Baron Jenney and Louis Sullivan. Early structures to employ concrete as the chief means of architectural expression (rather than for purely utilitarian structure) include Frank Lloyd Wright's Unity Temple, built in 1906 near Chicago, and Rudolf Steiner's Second Goetheanum, built from1926 near Basel, Switzerland.Other historians regard Modernism as a matter of taste, a reaction against eclecticism and the lavish stylistic excesses of Victorian Era and Edwardian Art Nouveau.Whatever the cause, around 1900 a number of architects around the world began developing new architectural solutions to integrate traditional precedents (Gothic, for instance) with new technological possibilities. The work of Louis Sullivan and Frank Lloyd Wright in Chicago, Victor Horta in Brussels, Antoni Gaudi in Barcelona, Otto Wagner in Vienna and Charles Rennie Mackintosh in Glasgow, among many others, can be seen as a common struggle between old and new.2. Modernism as Dominant StyleBy the 1920s the most important figures in Modern architecture had established their reputations. The big three are commonly recognized as Le Corbusier in France, and Ludwig Mies van der Rohe and Walter Gropius in Germany. Mies van der Rohe and Gropius were both directors of the Bauhaus, one of a number of European schools and associations concerned with reconciling craft tradition and industrial technology.Frank Lloyd Wright's career parallels and influences the work of the European modernists, particularly via the Wasmuth Portfolio, but he refused to be categorized with them. Wright was a major influence on both Gropius and van der Rohe, however, as well as on the whole of organic architecture.In 1932 came the important MOMA exhibition, the International Exhibition of Modern Architecture, curated by Philip Johnson. Johnson and collaborator Henry-Russell Hitchcock drew together many distinct threads and trends, identified them as stylistically similar and having a common purpose, and consolidated them into the International Style.This was an important turning point. With World War II the important figures of the Bauhaus fled to the United States, to Chicago, to the Harvard Graduate School of Design, and to Black Mountain College. While Modern architectural design never became a dominant style in single-dwelling residential buildings, in institutional and commercial architecture Modernism became the pre-eminent, and in the schools (for leaders of the profession) the only acceptable, design solution from about 1932 to about 1984.Architects who worked in the international style wanted to break with architectural tradition and design simple, unornamented buildings. The most commonly used materials are glass for the facade, steel for exterior support, and concrete for the floors and interior supports; floor plans were functional and logical. The style became most evident in the design of skyscrapers. Perhaps its most famous manifestations include the United Nations headquarters (Le Corbusier, Oscar Niemeyer, Sir Howard Robertson), the Seagram Building (Ludwig Mies van der Rohe), and Lever House (Skidmore, Owings, and Merrill), all in New York. A prominent residential example is the Lovell House (Richard Neutra) in Los Angeles.Detractors of the international style claim that its stark, uncompromisingly rectangular geometry is dehumanising. Le Corbusier once described buildings as "machines for living", but people are not machines and it was suggested that they do not want to live in machines. Even Philip Johnson admitted he was "bored with the box." Since the early 1980s many architects have deliberately sought to move away from rectilinear designs, towards more eclectic styles. During the middle of the century, some architects began experimenting in organic forms that they felt were more human and accessible. Mid-century modernism, or organic modernism, was very popular, due to its democratic and playful nature. Alvar Aalto and Eero Saarinen were two of the most prolific architects and designers in this movement, which has influenced contemporary modernism.Although there is debate as to when and why the decline of the modern movement occurred, criticism of Modern architecture began in the 1960s on the grounds that it was universal, sterile, elitist and lacked meaning. Its approach had become ossified in a "style" that threatened to degenerate into a set of mannerisms. Siegfried Giedion in the 1961 introduction to his evolving text, Space, Time and Architecture (first written in 1941), could begin "At the moment a certain confusion exists in contemporary architecture, as in painting; a kind of pause, even a kind of exhaustion." At the Metropolitan Museum of Art, a 1961 symposium discussed the question "Modern Architecture: Death or Metamorphosis?" In New York, the coup d'état appeared to materialize in controversy around the Pan Am Building that loomed over Grand Central Station, taking advantage of the modernist real estate concept of "air rights",[1] In criticism by Ada Louise Huxtable and Douglas Haskell it was seen to "sever" the Park Avenue streetscape and "tarnish" the reputations of its consortium of architects: Walter Gropius, Pietro Belluschi and thebuilders Emery Roth & Sons. The rise of postmodernism was attributed to disenchantment with Modern architecture. By the 1980s, postmodern architecture appeared triumphant over modernism, including the temple of the Light of the World, a futuristic design for its time Guadalajara Jalisco La Luz del Mundo Sede International; however, postmodern aesthetics lacked traction and by the mid-1990s, a neo-modern (or hypermodern) architecture had once again established international pre-eminence. As part of this revival, much of the criticism of the modernists has been revisited, refuted, and re-evaluated; and a modernistic idiom once again dominates in institutional and commercial contemporary practice, but must now compete with the revival of traditional architectural design in commercial and institutional architecture; residential design continues to be dominated by a traditional aesthetic.中⽂译⽂：现代建筑现代建筑,不被混淆与'当代建筑' , 是⼀个词给了⼀些建筑风格有类似的特点, 主要的简化形式,消除装饰等. 虽然风格的设想早在20世纪,并⼤量造就了⼀些建筑师、建筑教育家和展品,很少有现代的建筑物,建于20世纪上半叶. 第⼆次⼤战后的三⼗年, 但最终却成为主导建筑风格的机构和公司建设.1起源⼀些历史学家认为进化的现代建筑作为⼀个社会问题, 息息相关的⼯程中的现代性,从⽽影响了启蒙运动,导致社会和政治⾰命.另⼀些⼈认为现代建筑主要是靠技术和⼯程学的发展, 那就是获得新的建筑材料,如钢铁, 混凝⼟和玻璃驱车发明新的建筑技术,它作为⼯业⾰命的⼀部分. 1796年, shrewsbury查尔斯bage⾸先⽤他的'⽕'的设计, 后者则依靠铸铁及砖与⽯材地板. 这些建设⼤⼤加强了结构,使它们能够容纳更⼤的机器. 由于作为建筑材料特性知识缺乏,⼀些早期建筑失败. 直到1830年初,伊顿Hodgkinson预计推出了型钢梁, 导致⼴泛使⽤钢架建设，⼯业结构完全改变了这种窘迫的⾯貌,英国北部领导的描述, "⿊暗魔⿁作坊"的地⽅如曼彻斯特和西约克郡. ⽔晶宫由约瑟夫paxton的重⼤展览, 1851年,是⼀个早期的例⼦,钢铁及玻璃施⼯; 可能是⼀个最好的例⼦,就是1890年由William乐男爵延长和路易沙利⽂在芝加哥附近发展的⾼层钢结构摩天楼. 早期结构采⽤混凝⼟作为⾏政⼿段的建筑表达(⽽⾮纯粹功利结构) ,包括建于1906年在芝加哥附近,劳埃德赖特的统⼀宫, 建于1926年瑞⼠巴塞尔附近的鲁道夫斯坦纳的第⼆哥特堂,.但⽆论原因为何, 约有1900多位建筑师,在世界各地开始制定新的建筑⽅法,将传统的先例(⽐如哥特式)与新的技术相结合的可能性.路易沙利⽂和赖特在芝加哥⼯作,维克多奥尔塔在布鲁塞尔,安东尼⾼迪在巴塞罗那, 奥托⽡格纳和查尔斯景mackintosh格拉斯哥在维也纳,其中之⼀可以看作是⼀个新与旧的共同⽃争.2现代主义风格由1920年代的最重要⼈物,在现代建筑⾥确⽴了⾃⼰的名声. 三个是公认的柯布西耶在法国, 密斯范德尔德罗和⽡尔特格罗⽪乌斯在德国. 密斯范德尔德罗和格罗⽪乌斯为董事的包豪斯, 其中欧洲有不少学校和有关团体学习调和⼯艺和传统⼯业技术.赖特的建筑⽣涯中,也影响了欧洲建筑的现代艺术,特别是通过⽡斯穆特组合但他拒绝被归类与他们. 赖特与格罗⽪乌斯和Van der德罗对整个有机体系有重⼤的影响.在1932年来到的重要moma展览,是现代建筑艺术的国际展览,艺术家菲利普约翰逊. 约翰逊和合作者亨利-罗素阁纠集许多鲜明的线索和趋势, 内容相似,有⼀个共同的⽬的,巩固了他们融⼊国际化风格这是⼀个重要的转折点. 在⼆战的时间包豪斯的代表⼈物逃到美国,芝加哥，到哈佛⼤学设计⿊⼭书院. 当现代建筑设计从未成为主导风格单⼀的住宅楼，在成为现代卓越的体制和商业建筑, 是学校(专业领导)的唯⼀可接受的, 设计解决⽅案,从约1932年⾄约1984年.那些从事国际风格的建筑师想要打破传统建筑和简单的没有装饰的建筑物。
园林设计阿拉伯伊斯兰园林设计毕业论文外文文献翻译及原文
毕业设计（论文）外文文献翻译文献、资料中文题目：阿拉伯伊斯兰园林设计文献、资料英文题目：文献、资料来源：文献、资料发表（出版）日期：院（部）：专业：班级：姓名：学号：指导教师：翻译日期： 2017.02.14外文资料翻译Shady Attia.The role of landscape design in improving the microclimate in traditional courtyard-buildings in hot arid climates[C].PLEA2006 - The 23rd Conference on Passive and Low Energy Architecture, Geneva, Switzerland,2006,6-8.英文原文（节选）AbstractArab Islamic landscape design forms a unique source of inspiration for landscapearchitecture in barren open spaces in the Middle East. Arab Islamic gardens adopted a systemmarked by perfect responsiveness to the environment. The design of urban landscapes and gardens in Arab Islamic culture was similarly guided by the dictation of aridity. The need to provide shade, to prevent dust and to conserve water meant that urban open spaces and gardens were sheltered and enclosed. Alhambra in Moorish Spain and the Al-Suhaymi House in Islamic Cairo are two useful historical references for vernacular Islamic landscape designs. This paper presents an overview of landscape design considerations for the composition of vegetation and water and initial observations of their influence in controlling and improving the microclimate in courtyard buildings as a way of passive cooling in the Middle East region. This paper is a part of a Master’s thesis in the field of passive landscape strategies at Wageningen University. The objective is to identify the comfort improvements potential of successfully-planned and integrated landscape design in traditional courtyard buildings. The layout and plant material of Alhambra, Generalife courts and Al-Suhaymi court in Islamic Cairo are examined and evaluated. This study demonstrates that in arid environments, the landscape planning, the composition of vegetation and water and choice of planting material all have important consequences in creating thermally-pleasant environments.1. INTRODUCTIONIn most Islamic designs, the role of landscape design is highly appreciated. In examining traditional courtyard gardens, it is clear that the role of urban landscape design was not only restricted to a purely ornamental or theological function. It was additionally used to control and improve the microclimate around and inside the building. This paper attempts to present the role of landscape in traditional Islamic garden courtyards by analysing the design characteristics of Al Suhaymi house courtyards in Cairo and the layout of three courtyard gardens in Alhambra and Generalife palaces in Granada, Spain. Some physical parametermeasurements regarding temperature and humidity were made, in addition to a shade study. In fact, shades in courtyard-buildings were insufficient in improving the microclimate during hot summers. Therefore, vegetation and water were used to compensate for the lack of improvement provided by the shade.2. AL SUHAYMI HOUSE:Bayt al Suhaymi is one of the most important examples of a Cairene traditional courtyard house representing the Islamic landscape design around the 16th and 17th centuries. This house stands in El Darb EL Asfar alley and is directly located off the famous Fatimid street called El Moez street. The house witnessed several building phases before reaching its final layout, which covers 2000 square meters and includes 115 spaces distributed on five levels. The house is marked by perfect responsiveness to the environment and contains architectural elements of the traditional Cairean house. The bent entrance, which assures privacy to the house, leads to an inner courtyard surrounded by rooms and is overlooked by a maqaad (a roofed balcony facing the cool northern breeze) and a takhtaboosh (a space annexed by the court for receiving male visitors during the summer).2.1 The House layoutBy analysing the Al Suhaimy house layout, we find that this house layout was based on creating a passive ventilation system in order to ameliorate the microclimate. The passive ventilation system was created by locating two inner courtyards with two different pressures within the house. The north courtyard (Fig. 1c), called the rear garden, was a large open space and was meant to have low surrounding walls in order to keep the space sunny and relatively hot. The rear garden was designed to occupy 28 percent of the total plot area of the house with a 2.6:1.3:0.5 ratio (l:w:h). On the other hand, the south courtyard (Fig. 1b), simply called the courtyard, was a rectangular courtyard covering only 200 square meters and was designed to occupy only 10 percent of the total house area with a 1.8:1:1.3 ratio (l:w:h).This passive ventilation design solution is confirmed by comparing the shade in the rear garden to the courtyard. During winter (21 December, 2:00 p.m.) I found that the amount of shade in the rear garden was more than 53% compared to 100% in the courtyard space. During summer (21 June, 2:00 pm), the amount of shade in the rear garden is more than 12% compared to 40% in the courtyard space . Moreover, measurements have proved that when temperatures rise in the rear garden of the Al Suhaymi house, the air flows against the north prevailing wind directions during most daily hours. The wind flows from the south entrance, passing the courtyard and then into the takhtaboosh, with wind speeds of 1.3 m/s, and finally reaching the rear garden . On the other hand, during the stillness of the previously mentionedwind movement, the prevailing wind flows from the rear garden when the sun drops down after noon through the takhtaboosh to the courtyard with wind speeds reaching 0.7 m/s.2.2 Landscape design in Al Suhaymi house:Based on the previous design theory, we find that the role of landscape architecture in this design was essential. By analysing the plan, we find that the landscape design aimed to emphasize the passive ventilation in the Al Suhaymi house. The Islamic landscape design considerations for the composition of vegetation and water included the following environmental-responsive design principals:Quadripartite layoutReferences to the quadripartite design occurred more than once in the Koran; therefore, Islamic gardens adopted the geometrical and often symmetrical layout. Planning the layout was based on creating two axes perpendicularly crossing each other in the middle. The quadripartite layout was also considered as an environmental landscape design principle because the axes were planned as narrow water canals or walkways while the left rectangles were planted or used as water ponds. The quadripartite layout assured a combination between plant materials, water and pavement in courtyards, all of which improved the microclimate in the buildings.In the Al Suhaymi house, the courtyard had a quadripartite layout with slightly raised narrow walkways leading to the focal fountain at the centre of the courtyard. The walkways created four relatively large planted rectangular shapes , while the rear garden had two different planned layouts. The left part of the garden followed a quadripartite layout, while the right part of the garden had circular planning with a well in the centre. The quadripartite design helped the designer to manipulate the site and create a variety for the water, vegetation and pavement composition.Use of waterThe Al Suhaymi house had a focal fountain in the courtyard and some other fountains in the halls. The focal fountain was located at the centre of the courtyard. Next, a water wheel in the north-east corner of the house supported the fountains and house dweller with water. Using the fountain inside the courtyards helped to create a cold air reservoir, in addition to humidifying Cairo’s dry air. Using the fountains in the halls also helped in soothing the internal climate of the halls, reflecting the importance of having elements from the natural environment, such as water inside the house.Vegetation and shadeThe courtyard and rear garden were both planted, but to serve the passive ventilationconcept and create a relatively hot open area, the rear garden was mainly paved and planted with some flowers, medicinal herbs and palms. On the other hand, the courtyard was mainly planted with ground covers, evergreen trees and fruitful trees to provide maximum shade for the ground within the inner courtyard walls . Moreover, greenery inside the courtyard and rear garden absorbed dust and dirt in the atmosphere in addition to reducing the amount of glare. This study measured the differences in temperature between the planted courtyard and the house roof and it was found that the temperature was between 4oC to 7oC lower in the planted courtyard. Furthermore, by comparing the relative humidity in the house inner courtyard with El Darb EL Asfar alley, the humidity in the house inner courtyard ranged between 11 to 19 percent lower than in the alley.Walls and pavilionsIn the Koran, paradise is described as an enclosed garden, surrounded by “walls” and accessible through “gates”. In Al Suhaymi House, the courtyard was surrounded with thick high walls to achieve protection from the hot, dusty, and noisy environment, and to provide a refreshing shade and cool air, all of which are essential for human comfort. Moreover, the rear garden was surrounded by low walls in order to minimize shade and to create a hot open space. The surrounding walls of Al Suhaymi gardens are considered as part of an environmental landscape design element of the Islamic garden.译文摘要阿拉伯伊斯兰园林设计的独特灵感源于中东地区的贫瘠而又开放的景观空间。
外文翻译--燃气报警器
外文翻译--燃气报警器福州大学至诚学院本科生毕业设计（论文）外文翻译题目：基于单片机可燃气体检测报警器的设计姓名：蔡佳阳学号： 211014128系别：信息工程系专业：电子信息工程年级： 2010级指导教师：（签名）年月日附录：外文文献及译文外文原文1 ：Combustible gas alarmCombustible gas alarmto prevent gas leakage as a powerful weapon, it has, however, does not seem to have attracted the attention it deserves. This security and household fire extinguishers can be placed on a par, or even more than the fire extinguisher into the family of the little things that most families do not see it as one thing, do not even know there can be such a fundamental solution to gas poisoning and gas explosion, "the protection of God" exists. Shanghai as an example, last year, due to poisoning and cooking gas water heater overflow out, piece of rubber hose off the aging caused by gas leakage and poisoning caused by a total of 86 deaths, accounting for all the gas data of accidents were 84%. However, according to an authoritative department to another survey released shows that in Shanghai, about three million gas users, the installation of domesticgas leakage alarm of less than 10%.In their daily lives, whether it is gas poisoning or gas explosion, because of gas leak into the sky. Home life, no one is inseparable from the use of gas, no matter what you do more preventive measures, but a hundred secret inevitably very careful, not to mention of any fire safety measures are not taken on even more dangerous family. Therefore it is necessary to prepare a Combustible gas at home at any time for the owner guardian of the gas appliances, a gas alert to this invisible killer slipped quietly out to help the owner of the elimination offamily problems in the bud, the domestic security of the good housekeeper, so that family members with the use of gas, the use of hearts at ease. For example, there are many families of fire gas explosion, do not know in the room full of gas leaking out, the blind use of electricalswitches and tragedy in an instantif there is an alarm, a tragedy like this ,can be greatly avoided.Combustible gas alarm into the family, will become a good home security to help, this is an indisputable fact Product Description:Detection of gas: natural gas, liquefied petroleum gas, city gas (H2)Size: 115mm * 71mm * 43.3mm(1) add automatic sensor drift compensation, the real and omitted to prevent the false positives.(2) The failure prompted the police to enable the user to replace and repair, to prevent the non-reported.(3) MCU control the entire process, working temperature -40 degrees to 80 degrees. Operating voltage: 220V AC or 110V AC, 12VDC-20VDC Additional features: linkage exhaust fan, the manipulator, the solenoid valveNetworking: wired networking functions: (NO, NC) Wireless networking: 315MHZ/433MHZ (2262 OR 1527)译文：燃气报警器燃气报警器作为预防燃气泄漏的有力武器，它的出现却似乎并没有引起人们应有的注意。
毕业论文文献外文翻译----危机管理：预防,诊断和干预文献翻译-中英文文献对照翻译
第1页 共19页中文3572字毕业论文（设计）外文翻译标题：危机管理-预防，诊断和干预一、外文原文标题：标题：Crisis management: prevention, diagnosis and Crisis management: prevention, diagnosis andintervention 原文：原文：The Thepremise of this paper is that crises can be managed much more effectively if the company prepares for them. Therefore, the paper shall review some recent crises, theway they were dealt with, and what can be learned from them. Later, we shall deal with the anatomy of a crisis by looking at some symptoms, and lastly discuss the stages of a crisis andrecommend methods for prevention and intervention. Crisis acknowledgmentAlthough many business leaders will acknowledge thatcrises are a given for virtually every business firm, many of these firms do not take productive steps to address crisis situations. As one survey of Chief Executive officers of Fortune 500 companies discovered, 85 percent said that a crisisin business is inevitable, but only 50 percent of these had taken any productive action in preparing a crisis plan(Augustine, 1995). Companies generally go to great lengths to plan their financial growth and success. But when it comes to crisis management, they often fail to think and prepare for those eventualities that may lead to a company’s total failure.Safety violations, plants in need of repairs, union contracts, management succession, and choosing a brand name, etc. can become crises for which many companies fail to be prepared untilit is too late.The tendency, in general, is to look at the company as a perpetual entity that requires plans for growth. Ignoring the probabilities of disaster is not going to eliminate or delay their occurrences. Strategic planning without inclusion ofcrisis management is like sustaining life without guaranteeinglife. One reason so many companies fail to take steps to proactively plan for crisis events, is that they fail to acknowledge the possibility of a disaster occurring. Like an ostrich with its head in the sand, they simply choose to ignorethe situation, with the hope that by not talking about it, it will not come to pass. Hal Walker, a management consultant, points out “that decisions will be more rational and better received, and the crisis will be of shorter duration, forcompanies who prepare a proactive crisis plan” (Maynard, 1993) .It is said that “there are two kinds of crises: those that thatyou manage, and those that manage you” (Augustine, 1995). Proactive planning helps managers to control and resolve a crisis. Ignoring the possibility of a crisis, on the other hand,could lead to the crisis taking a life of its own. In 1979, theThree-Mile Island nuclear power plant experienced a crisis whenwarning signals indicated nuclear reactors were at risk of a meltdown. The system was equipped with a hundred or more different alarms and they all went off. But for those who shouldhave taken the necessary steps to resolve the situation, therewere no planned instructions as to what should be done first. Hence, the crisis was not acknowledged in the beginning and itbecame a chronic event.In June 1997, Nike faced a crisis for which they had no existi existing frame of reference. A new design on the company’s ng frame of reference. A new design on the company’s Summer Hoop line of basketball shoes - with the word air writtenin flaming letters - had sparked a protest by Muslims, who complained the logo resembled the Arabic word for Allah, or God.The council of American-Islamic Relations threatened aa globalNike boycott. Nike apologized, recalled 38,000 pairs of shoes,and discontinued the line (Brindley, 1997). To create the brand,Nike had spent a considerable amount of time and money, but hadnever put together a general framework or policy to deal with such controversies. To their dismay, and financial loss, Nike officials had no choice but to react to the crisis. This incident has definitely signaled to the company that spending a little more time would have prevented the crisis. Nonetheless,it has taught the company a lesson in strategic crisis management planning.In a business organization, symptoms or signals can alert the strategic planners or executives of an eminent crisis. Slipping market share, losing strategic synergy anddiminishing productivity per man hour, as well as trends, issues and developments in the socio-economic, political and competitive environments, can signal crises, the effects of which can be very detrimental. After all, business failures and bankruptcies are not intended. They do not usually happen overnight. They occur more because of the lack of attention to symptoms than any other factor.Stages of a crisisMost crises do not occur suddenly. The signals can usuallybe picked up and the symptoms checked as they emerge. A company determined to address these issues realizes that the real challenge is not just to recognize crises, but to recognize themin a timely fashion (Darling et al., 1996). A crisis can consistof four different and distinct stages (Fink, 1986). The phasesare: prodromal crisis stage, acute crisis stage, chronic crisisstage and crisis resolution stage.Modern organizations are often called “organic” due tothe fact that they are not immune from the elements of their surrounding environments. Very much like a living organism, organizations can be affected by environmental factors both positively and negatively. But today’s successfulorganizations are characterized by the ability to adapt by recognizing important environmental factors, analyzing them, evaluating the impacts and reacting to them. The art of strategic planning (as it relates to crisis management)involves all of the above activities. The right strategy, in general, provides for preventive measures, and treatment or resolution efforts both proactively and reactively. It wouldbe quite appropriate to examine the first three stages of acrisis before taking up the treatment, resolution or intervention stage.Prodromal crisis stageIn the field of medicine, a prodrome is a symptom of the onset of a disease. It gives a warning signal. In business organizations, the warning lights are always blinking. No matter how successful the organization, a number of issues andtrends may concern the business if proper and timely attentionis paid to them. For example, in 1995, Baring Bank, a UK financial institution which had been in existence since 1763,ample opportunitysuddenly and unexpectedly failed. There wasfor the bank to catch the signals that something bad was on thehorizon, but the company’s efforts to detect that were thwarted by an internal structure that allowed a single employee both to conduct and to oversee his own investment trades, and the breakdown of management oversight and internalcontrol systems (Mitroff et al., 1996). Likewise, looking in retrospect, McDonald’s fast food chain was given the prodromalsymptoms before the elderly lady sued them for the spilling ofa very hot cup of coffee on her lap - an event that resulted in a substantial financial loss and tarnished image of thecompany. Numerous consumers had complained about thetemperature of the coffee. The warning light was on, but the company did not pay attention. It would have been much simplerto pick up the signal, or to check the symptom, than facing the consequences.In another case, Jack in the Box, a fast food chain, had several customers suffer intestinal distress after eating at their restaurants. The prodromal symptom was there, but the company took evasive action. Their initial approach was to lookaround for someone to blame. The lack of attention, the evasiveness and the carelessness angered all the constituent groups, including their customers. The unfortunate deaths thatptoms,occurred as a result of the company’s ignoring thesymand the financial losses that followed, caused the company to realize that it would have been easier to manage the crisis directly in the prodromal stage rather than trying to shift theblame.Acute crisis stageA prodromal stage may be oblique and hard to detect. The examples given above, are obvious prodromal, but no action wasWebster’s New Collegiate Dictionary, an acute stage occursacutewhen a symptom “demands urgent attention.” Whether the acutesymptom emerges suddenly or is a transformation of a prodromalstage, an immediate action is required. Diverting funds and other resources to this emerging situation may cause disequilibrium and disturbance in the whole system. It is onlythose organizations that have already prepared a framework forthese crises that can sustain their normal operations. For example, the US public roads and bridges have for a long time reflected a prodromal stage of crisis awareness by showing cracks and occasionally a collapse. It is perhaps in light of the obsessive decision to balance the Federal budget that reacting to the problem has been delayed and ignored. This situation has entered an acute stage and at the time of this writing, it was reported that a bridge in Maryland had just collapsed.The reason why prodromes are so important to catch is thatit is much easier to manage a crisis in this stage. In the caseof most crises, it is much easier and more reliable to take careof the problem before it becomes acute, before it erupts and causes possible complications (Darling et al., 1996). In andamage. However, the losses are incurred. Intel, the largest producer of computer chips in the USA, had to pay an expensiveprice for initially refusing to recall computer chips that proved unreliable o n on certain calculations. The f irmfirm attempted to play the issue down and later learned its lesson. At an acutestage, when accusations were made that the Pentium Chips were not as fast as they claimed, Intel quickly admitted the problem,apologized for it, and set about fixing it (Mitroff et al., 1996). Chronic crisis stageDuring this stage, the symptoms are quite evident and always present. I t isIt is a period of “make or break.” Being the third stage, chronic problems may prompt the company’s management to once and for all do something about the situation. It may be the beginning of recovery for some firms, and a deathknell for others. For example, the Chrysler Corporation was only marginallysuccessful throughout the 1970s. It was not, however, until the company was nearly bankrupt that amanagement shake-out occurred. The drawback at the chronic stage is that, like in a human patient, the company may get used to “quick fixes” and “band “band--aid”approaches. After all, the ailment, the problem and the crisis have become an integral partoverwhelmed by prodromal and acute problems that no time or attention is paid to the chronic problems, or the managers perceive the situation to be tolerable, thus putting the crisison a back burner.Crisis resolutionCrises could be detected at various stages of their development. Since the existing symptoms may be related todifferent problems or crises, there is a great possibility thatthey may be misinterpreted. Therefore, the people in charge maybelieve they have resolved the problem. However, in practicethe symptom is often neglected. In such situations, the symptomwill offer another chance for resolution when it becomes acute,thereby demanding urgent care. Studies indicate that today anincreasing number of companies are issue-oriented and searchfor symptoms. Nevertheless, the lack of experience in resolvinga situation and/or inappropriate handling of a crisis can leadto a chronic stage. Of course, there is this last opportunityto resolve the crisis at the chronic stage. No attempt to resolve the crisis, or improper resolution, can lead to grim consequences that will ultimately plague the organization or even destroy it.It must be noted that an unsolved crisis may not destroy the company. But, its weakening effects can ripple through the organization and create a host of other complications.Preventive effortsThe heart of the resolution of a crisis is in the preventiveefforts the company has initiated. This step, similar to a humanbody, is actually the least expensive, but quite often the mostoverlooked. Preventive measures deal with sensing potential problems (Gonzales-Herrero and Pratt, 1995). Major internalfunctions of a company such as finance, production, procurement, operations, marketing and human resources are sensitive to thesocio-economic, political-legal, competitive, technological, demographic, global and ethical factors of the external environment. What is imminently more sensible and much more manageable, is to identify the processes necessary forassessing and dealing with future crises as they arise (Jacksonand Schantz, 1993). At the core of this process are appropriate information systems, planning procedures, anddecision-making techniques. A soundly-based information system will scan the environment, gather appropriate data, interpret this data into opportunities and challenges, and provide a concretefoundation for strategies that could function as much to avoid crises as to intervene and resolve them.Preventive efforts, as stated before, require preparations before any crisis symptoms set in. Generally strategic forecasting, contingency planning, issues analysis, and scenario analysis help to provide a framework that could be used in avoiding and encountering crises.出处：出处：Toby TobyJ. Kash and John R. Darling . Crisis management: prevention, diagnosis 179-186二、翻译文章标题：危机管理：预防，诊断和干预译文：本文的前提是，如果该公司做好准备得话，危机可以更有效地进行管理。
毕业设计论文化学系毕业论文外文文献翻译中英文
毕业设计论文化学系毕业论文外文文献翻译中英文英文文献及翻译A chemical compound that is contained in the hands of the problemsfor exampleCatalytic asymmetric carbon-carbon bond formation is one of the most active research areas in organic synthesis In this field the application of chiral ligands in enantioselective addition of diethylzinc to aldehydes has attracted much attention lots of ligands such as chiral amino alcohols amino thiols piperazines quaternary ammonium salts 12-diols oxazaborolidines and transition metal complex with chiral ligands have been empolyed in the asymmetric addition of diethylzinc to aldehydes In this dissertation we report some new chiral ligands and their application in enantioselective addition of diethylzinc to aldehydes1 Synthesis and application of chiral ligands containing sulfur atomSeveral a-hydroxy acids were prepared using the literature method with modifications from the corresponding amino acids valine leucine and phenylalanine Improved yields were obtained by slowly simultaneous addition of three fold excess of sodium nitrite and 1 tnolL H2SO4 In the preparation of a-hydroxy acid methyl esters from a-hydroxy acids following the procedure described by Vigneron a low yield 45 was obtained It was found that much better results yield 82 couldbe obtained by esterifying a-hydroxy acids with methanol-thionyl chlorideThe first attempt to convert S -2-hydroxy-3-methylbutanoic acid methyl ester to the corresponding R-11-diphenyl-2-mercapto-3-methyl-l-butanol is as the following S-2-Hydroxy-3-methylbutanoic acid methyl ester was treated with excess of phenylmagnesium bromide to give S -11-diphenyl-3-methyl-12-butanediol which was then mesylated to obtain S -11-diphenyl-3-methyl-2-methanesulfonyloxy -l-butanol Unfortunately conversion of S-11-diphenyl-3-methyl-2- methanesulfonyloxy -l-butanol to the corresponding thioester by reacting with potassium thioacetate under Sn2 reaction conditions can be achieved neither in DMF at 20-60 nor in refluxing toluene in the presence of 18-crown-6 as catalyst When S -1ll-diphenyl-3-methyl-2- methane sulfonyloxy -l-butanol was refluxed with thioacetic acid in pyridine an optical active epoxide R-22-diphenyl -3-isopropyloxirane was obtained Then we tried to convert S -11-diphenyl-3-methyl-l2-butanediol to the thioester by reacting with PPh3 DEAD and thioacetic acid the Mitsunobu reaction but we failed either probably due to the steric hindrance around the reaction centerThe actually successful synthesis is as described below a-hydroxy acid methyl esters was mesylated and treated with KSCOCH3 in DMF to give thioester this was than treated with phenyl magnesium bromide to gave the target compound B-mercaptoalcohols The enantiomeric excesses ofp-mercaptoalcohols can be determined by 1H NMR as their S -mandeloyl derivatives S -2-amino-3-phenylpropane-l-thiol hydrochloride was synthesized from L-Phenylalanine L-Phenylalanine was reduced to the amino alcohol S -2-amino-3-phenylpropanol Protection of the amino group using tert-butyl pyrocarbonate gave S -2-tert-butoxycarbonylamino-3-phenylpropane-l-ol which was then O-mesylated to give S -2-tert-butoxycarbonylamino-3-phenylpropyl methanesulfonate The mesylate was treated with potassium thioacetate in DMF to give l-acetylthio-2-tert-butoxycarbonylamino-3-phenylpropane The acetyl group was then removed by treating with ammonia in alcohol to gave S -2-tert-butoxycarbonylamino-3-phenyl-propane-l-thiol which was then deprotected with hydrochloric acid to give the desired S-2-amino-3-phenylpropane-1-thiol hydrochlorideThe enantioselective addition of diethylzinc to aldehydes promoted by these sulfur containing chiral ligands produce secondary alcohols in 65-79 Synthesis and application of chiral aminophenolsThree substituted prolinols were prepared from the naturally-occurring L-proline using reported method with modifications And the chiral aminophenols were obtained by heating these prolinols with excess of salicylaldehyde in benzene at refluxThe results of enantioselective adBelow us an illustration forexampleN-Heterocyclic carbenes and L-Azetidine-2-carboxylicacidN-Heterocyclic carbenesN-Heterocyclic carbenes have becomeuniversal ligands in organometallic and inorganic coordination chemistry They not only bind to any transition metal with low or high oxidation states but also to main group elements such as beryllium sulfur and iodine Because of their specific coordination chemistry N-heterocyclic carbenes both stabilize and activate metal centers in quite different key catalytic steps of organic syntheses for example C-H activation C-C C-H C-O and C-N bond formation There is now ample evidence that in the new generation of organometallic catalysts the established ligand class of organophosphanes will be supplemented and in part replaced byN-heterocyclic carbenes Over the past few years this chemistry has become the field of vivid scientific competition and yielded previously unexpected successes in key areas of homogeneous catalysis From the work in numerous academic laboratories and in industry a revolutionary turningpoint in oraganometallic catalysis is emergingIn this thesis Palladium Ⅱ acetate and NN"-bis- 26-diisopropylphenyl dihydro- imidazolium chloride 1 2 mol were used to catalyze the carbonylative coupling of aryl diazonium tetrafluoroborate salts and aryl boronic acids to form aryl ketones Optimal conditions include carbon monoxide 1 atm in 14-dioxane at 100℃ for 5 h Yields for unsymmetrical aryl ketones ranged from 76 to 90 for isolated materials with only minor amounts of biaryl coupling product observed 2-12 THF as solvent gave mixtures of products 14-Dioxane proved to be the superior solvent giving higher yieldsof ketone product together with less biphenyl formation At room temperature and at 0℃ with 1 atm CO biphenyl became the major product Electron-rich diazonium ion substrates gave a reduced yield with increased production of biaryl product Electron-deficient diazonium ions were even better forming ketones in higher yields with less biaryl by-product formed 2-Naphthyldiazonium salt also proved to be an effective substrate givingketones in the excellent range Base on above palladium NHC catalysts aryl diazonium tetrafluoroborates have been coupled with arylboron compounds carbon monoxide and ammonia to give aryl amides in high yields A saturated yV-heterocyclic carbene NHC ligand H2lPr 1 was used with palladium II acetate to give the active catalyst The optimal conditions with 2mol palladium-NHC catalyst were applied with various organoboron compounds and three aryl diazonium tetrafluoroborates to give numerous aryl amides in high yield using pressurized CO in a THF solution saturated with ammonia Factors that affect the distribution of the reaction products have been identified and a mechanism is proposed for this novel four-component coupling reactionNHC-metal complexes are commonly formed from an imidazolium salt using strong base Deprotonation occurs at C2 to give a stable carbene that adds to form a a-complex with the metal Crystals were obtained from the reaction of imidazolium chloride with sodium t- butoxide Nal and palladium II acetate giving a dimeric palladium II iodide NHC complex The structure adopts a flat 4-memberedring u2 -bridged arrangement as seen in a related dehydro NHC complex formed with base We were pleased to find that chloride treated with palladium II acetate without adding base or halide in THF also produced suitable crystals for X-ray anaysis In contrast to the diiodide the palladium-carbenes are now twisted out of plane adopting a non-planar 4-ring core The borylation of aryldiazonium tetrafluoroborates with bis pinacolatoborane was optimized using various NHC ligand complexes formed in situ without adding base NN"-Bis 26-diisopropylphenyl-45-dihydroimidazolium 1 used with palladium acetate in THF proved optimal giving borylated product in 79 isolated yield without forming of bi-aryl side product With K2CO3 and ligand 1 a significant amount of biaryl product 24 was again seen The characterization of the palladium chloride complex by X-ray chrastallography deL-Azetidine-2-carboxylic acidL-Azetidine-2-carboxylic acid also named S -Azetidine-2-carboxylic acid commonly named L-Aze was first isolated in 1955 by Fowden from Convallaria majalis and was the first known example of naturally occurring azetidine As a constrained amino acid S -Azetidine-2-carboxylic acid has found many applications in the modification of peptides conformations and in the area of asymmetric synthesis which include its use in the asymmetric reduction of ketones Michael additions cyclopropanations and Diels-Alder reactions In this dissertation five ways for synthesize S-Azetidine-2-carboxylic acid were studied After comparing all methods theway using L-Aspartic acid as original material for synthesize S-Azetidine-2-carboxylic acid was considered more feasible All mechanisms of the way"s reaction have also been studied At last the application and foreground of S -Azetidine-2-carboxylic acid were viewed The structures of the synthetic products were characterized by ThermalGravity-Differential Thermal Analysis TG-DTA Infrared Spectroscopy IR Mass Spectra MS and 1H Nuclear Magnetic Resonance 1H-NMR Results showed that the structures and performances of the products conformed to the anticipation the yield of each reaction was more than 70 These can conclude that the way using L-Aspartie acid as original material for synthesize S -Azetidine-2-carboxylic acid is practical and effective杂环化合物生成中包含手性等问题如催化形成不对称碳碳键在有机合成中是一个非常活跃的领域在这个领域中利用手性配体诱导的二乙基锌和醛的不对称加成引起化学家的广泛关注许多手性配体如手性氨基醇手性氨基硫醇手性哌嗪手性四季铵盐手性二醇手性恶唑硼烷和过渡金属与手性配体的配合物等被应用于二乙基锌对醛的不对称加成中在本论文中我们报道了一些新型的手性配体的合成及它们应用于二乙基锌对醛的不对称加成的结果1含硫手性配体的合成和应用首先从氨基酸缬氨酸亮氨酸苯丙氨酸出发按照文献合成α-羟基酸并发现用三倍量的亚硝酸钠和稀硫酸同时滴加进行反应能适当提高反应的产率而根据Vigneron等人报道的的方法用浓盐酸催化从α-羟基酸合成α-羟基酸甲酯时只能获得较低的产率改用甲醇-二氯亚砜的酯化方法时能提高该步骤的产率从 S -3-甲基-2-羟基丁酸甲酯合成 R -3-甲基-11-二苯基-2-巯基-1-丁醇经过了以下的尝试 S -3-甲基-2-羟基丁酸甲酯和过量的格氏试剂反应得到 S -3-甲基-11-二苯基-12-丁二醇进行甲磺酰化时位阻较小的羟基被磺酰化生成 S -3-甲基-11-二苯基-2- 甲磺酰氧基 -1-丁醇但无论将 S -3-甲基-11-二苯基-2- 甲磺酰氧基 -1-丁醇和硫代乙酸钾在DMF中反应 20～60℃还是在甲苯中加入18-冠-6作为催化剂加热回流都不能得到目标产物当其与硫代乙酸在吡啶中回流时得到的不是目标产物而是手性环氧化合物 R -3-异丙基-22-二苯基氧杂环丙烷从化合物 S -3-甲基-11-二苯基-12-丁二醇通过Mitsunobu反应合成硫代酯也未获得成功这可能是由于在反应中心处的位阻较大造成的几奥斯塑手村犯体的合成裁其在不对称奋成中肠左用摘要成功合成疏基醇的合成路是将a-轻基酸甲酷甲磺酞化得到相应的磺酞化产物并进行与硫代乙酸钾的亲核取代反应得到硫酷进行格氏反应后得到目标分子p一疏基醇用p一疏基醇与 R 义一一甲氧基苯乙酞氯生成的非对映体经H侧NM吸测试其甲氧基峰面积的积分求得其ee值 3一苯基一氨基丙硫醇盐酸盐从苯丙氨酸合成斗3一苯基一氨基丙醇由L一苯丙氨酸还原制备氨基保护后得到习一3一苯基一2一叔丁氧拨基氨基一1一丙醇甲磺酞化后得到习一3一苯基一2一叔丁氧拨基氨基一1一丙醇甲磺酸酷用硫代乙酸钾取代后得匀一3-苯基一2一叔丁氧拨基氨基一1一丙硫醇乙酸酷氨解得习一3一苯基一2一叔丁氧拨基氨基一1一丙硫醇用盐酸脱保护后得到目标产物扔3一苯基屯一氨基丙硫醇盐酸盐手性含硫配体诱导下的二乙基锌与醛的加成所得产物的产率为65一79值为O井92手性氨基酚的合成和应用首先从天然的L一脯氨酸从文献报道的步骤合成了三种脯氨醇这些手性氨基醇与水杨醛在苯中回流反应得到手性氨基酚手性氨基酚配体诱导下的二乙基锌与醛的加成所得产物的产率为45一98值为0一90手性二茂铁甲基氨基醇的合成和应用首先从天然氨基酸绿氨酸亮氨酸苯丙氨酸和脯氨酸合成相应的氨基醇这些氨基醇与二茂铁甲醛反应生成的NO一缩醛经硼氢化钠还原得到手性二茂铁甲基氨基醇手性二茂铁甲基氨基醇配体诱导下的二乙基锌与醛的加成所得产物的产率为66一97下面我们举例说明一下例如含氮杂环卡宾和L-氮杂环丁烷-2-羧酸含氮杂环卡宾含氮杂环卡宾已广泛应用于有机金属化学和无机配合物化学领域中它们不仅可以很好地与任何氧化态的过渡金属络合还可以与主族元素铍硫等形成配合物由于含氮杂环卡宾不但使金属中心稳定而且还可以活化此金属中心使其在有机合成中例如C-H键的活化C-CC-HC-O和C-N键形成反应中有着十分重要的催化效能现有的证据充分表明在新一代有机金属催化剂中含氮杂环卡宾不但对有机膦类配体有良好的互补作用而且在有些方面取代有机膦配体成为主角近年来含氮杂环卡宾及其配合物已成为非常活跃的研究领域在均相催化这一重要学科中取得了难以想象的成功所以含氮杂环卡宾在均相有机金属催化领域的研究工作很有必要深入地进行下去本文研究了乙酸钯和NN双 26-二异丙基苯基 -45-二氢咪唑氯化物1作为催化剂催化芳基四氟硼酸重氮盐与芳基硼酸的羰基化反应合成了一系列二芳基酮并对反应条件进行了优化使反应在常温常压下进行一个大气压的一氧化碳14-二氧杂环己烷作溶剂100℃反应5h 不同芳基酮的收率达7690仅有微量的联芳烃付产物 212 反应选择性良好当采用四氢呋喃或甲苯作溶剂时得到含较多副产物的混合物由此可以证明14-二氧杂环己烷是该反应最适宜的溶剂在室温或0℃与一个大气压的一氧化碳反应联芳烃变成主产物含供电子取代基的芳基重氮盐常常给出较低收率的二芳基酮而含吸电子取代基的芳基重氮盐却给出更高收率的二芳基酮及较少量的联芳烃付产物实验证明2-萘基重氮盐具有很好的反应活性和选择性总是得到优异的反应结果在此基础上由不同的芳基四氟硼酸重氮盐与芳基硼酸一氧化碳和氨气协同作用以上述含氮杂环卡宾作配体与乙酸钯生成的高活性含氮杂环卡宾钯催化剂催化较高收率地得到了芳基酰胺优化的反应条件是使用2mol的钯-H_2IPr 1五个大气压的一氧化碳以氨气饱和的四氢呋喃作溶剂由不同的有机硼化合物与三种芳基重氮盐的四组份偶联反应同时不仅对生成的多种产物进行了定 L-氮杂环丁烷-2-羧酸L-氮杂环丁烷-2-羧酸又称 S -氮杂环丁烷-2-羧酸简称为L-Aze1955年由Fowden从植物铃兰 Convallaria majalis 中分离得到成为第一个被证实的植物中天然存在的氮杂环丁烷结构作为一种非典型的氨基酸已经发现 S -氮杂环丁烷-2-羧酸可广泛用于对多肽结构的修饰以及诸如不对称的羰基还原Michael 加成环丙烷化和Diels-Alder反应等不对称合成中的多个领域本文通过对 S -氮杂环丁烷-2-羧酸合成路线的研究综述了五种可行的合成路线及方法通过比较选用以L-天冬氨酸为初始原料合成 S -氮杂环丁烷-2-羧酸的路线即通过酯化反应活泼氢保护格氏反应内酰胺化反应还原反应氨基保护氧化反应脱保护等反应来合成 S -氮杂环丁烷-2-羧酸分析了每步反应的机理并对 S -氮杂环丁烷-2-羧酸的应用及前景给予展望通过热分析红外质谱核磁等分析手段对合成的化合物的结构进行表征结果表明所得的产物符合目标产物所合成的化合物的结构性能指标与设计的目标要求一致每步反应的收率都在70％以上可以判定以L-天冬氨酸为初始原料合成 S -氮杂环丁烷的路线方案切实可行。
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矿产资源开发利用方案编写内容要求及审查大纲
矿产资源开发利用方案编写内容要求及《矿产资源开发利用方案》审查大纲一、概述
㈠矿区位置、隶属关系和企业性质。
如为改扩建矿山, 应说明矿山现状、
特点及存在的主要问题。
㈡编制依据
(1简述项目前期工作进展情况及与有关方面对项目的意向性协议情况。
(2 列出开发利用方案编制所依据的主要基础性资料的名称。
如经储量管理部门认定的矿区地质勘探报告、选矿试验报告、加工利用试验报告、工程地质初评资料、矿区水文资料和供水资料等。
对改、扩建矿山应有生产实际资料, 如矿山总平面现状图、矿床开拓系统图、采场现状图和主要采选设备清单等。
二、矿产品需求现状和预测
㈠该矿产在国内需求情况和市场供应情况
1、矿产品现状及加工利用趋向。
2、国内近、远期的需求量及主要销向预测。
㈡产品价格分析
1、国内矿产品价格现状。
2、矿产品价格稳定性及变化趋势。
三、矿产资源概况
㈠矿区总体概况
1、矿区总体规划情况。
2、矿区矿产资源概况。
3、该设计与矿区总体开发的关系。
㈡该设计项目的资源概况
1、矿床地质及构造特征。
2、矿床开采技术条件及水文地质条件。