毕业论文外文资料翻译
隧道盾构-毕设论文外文翻译(翻译-原文)
毕业设计（论文）外文文献翻译院系：土木工程与建筑系年级专业：土木工程姓名：学号：附件：盾构SHIELDS指导老师评语：指导教师签名：年月日S HIEL D S【Abstr act】A tunnel shield is a structural system, used during the face excavation process. The paper mainly discusses the form and the structure of the shield. Propulsion for the shield is provided by a series of hydraulic jacks installed in the tail of the shield and the shield is widespread used in the underground environment where can not be in long time stable. The main enemy of the shield is ground pressure. Non-uniform ground pressure caused by the steering may act on the skin tends to force the shield off line and grade. And working decks inside the shield enable the miners to excavate the face, drill and load holes.【Keywor ds】shield hydraulic jacks ground pressure steering working decksA tunnel shield is a structural system, normally constructed of steel, used during the face excavation process. The shield has an outside configuration which matches the tunnel. The shield provides protection for the men and equipment and also furnished initial ground support until structural supports can be installed within the tail section of the shield. The shield also provides a reaction base for the breast-board system used to control face movement. The shield may have either an open or closed bottom. In a closed-bottom shield, the shield structure and skin provide 360-degree ground contact and the weight of the shield rests upon the invert section of the shield skin. The open shield has no bottom section and requires some additional provision is a pair of side drifts driven in advance of shield excavation. Rails or skid tracks are installed within these side drifts to provide bearing support for the shield.Shield length generally varies from1/2 to 3/4 of the tunnel diameter. The front of the shield is generally hooded to so that the top of the shield protrudes forward further than the invert portion which provides additional protection for the men working at the face and also ease pressure on the breast-boards. The steel skin of the shield may varyfrom 1.3 to 10 cm in thickness, depending on the expected ground pressures. The type of steel used in the shield is the subject of many arguments within the tunneling fraternity. Some prefer mild steel in the A36 category because of its ductility and case of welding in the underground environment where precision work is difficult. Others prefer a high-strength steel such as T-1 because of its higher strength/w eight ratio. Shield weight may range from 5 to 500 tons. Most of the heaviest shields are found in the former Sovier Union because of their preference for cast-iron in both structural and skin elements.Propulsion for the shield is provided by a series of hydraulic jacks installed in the tail of the shield that thrust against the last steel set that has been installed. The total required thrust will vary with skin area and ground pressure. Several shields have been constructed with total thrust capabilities in excess of 10000 tons. Hydraulic systems are usually self-contained, air-motor powered, and mounted on the shield. Working pressures in the hydraulic system may range from 20-70 Mpa. To resist the thrust of the shield jacks, a horizontal structure member (collar brace) must be installed opposite each jack location and between the flanges of the steel set. In addition, some structural provision must be made for transferring this thrust load into the tunnel walls. Without this provision the thrust will extend through the collar braces to the tunnel portal.An Englishman, Marc Brunel, is credited with inventing the shield. Brunel supposedly got his idea by studying the action of the Teredo navalis, a highly destructive woodworm, when he was working at the Chatham dock yard. In 1818 Brunel obtained an English patent for his rectangular shield which was subsequently uses to construct the first tunnel under the River Thames in London. In 1869 the first circular shield was devised by Barlow and Great Head in London and is referred to as the Great Head-type shield. Later that same year, Beach in New York City produced similar shield. The first use of the circular shield came during 1869 when Barlow and Great Head employed their device in the construction of the 2.1 in diameter Tower Subway under the River Thames. Despite the name of the tunnel, it was used only for pedestrian traffic. Beach also put his circular shield to work in 1869 to construct a demonstration project for a proposed NewYork City subway system. The project consisted of a 2.4 m diameter tunnel, 90 m long, used to experiment with a subway car propelled by air pressure.Here are some tunnels which were built by shield principle.Soft-ground tunneling Some tunnels are driven wholly or mostly through soft material. In very soft ground, little or no blasting is necessary because the material is easily excavated.At first, forepoling was the only method for building tunnels through very soft ground. Forepoles are heavy planks about 1.5 m long and sharpened to a point. They were inserted over the top horizontal bar of the bracing at the face of the tunnel. The forepoles were driven into the ground of the face with an outward inclination. After all the roof poles were driven for about half of their length, a timber was laid across their exposed ends to counter any strain on the outer ends. The forepoles thus provided an extension of the tunnel support, and the face was extended under them. When the ends of the forepoles were reached, new timbering support was added, and the forepoles were driven into the ground for the next advance of the tunneling.The use of compressed air simplified working in soft ground. An airlock was built, though which men and equipment passed, and sufficient air pressure was maintained at the tunnel face to hold the ground firm during excavation until timbering or other support was erected.Another development was the use of hydraulically powered shields behind which cast-iron or steel plates were placed on the circumference of the tunnels. These plates provided sufficient support for the tunnel while the work proceeded, as well as full working space for men in the tunnel.Under water tunneling The most difficult tunneling is that undertaken at considerable depths below a river or other body of water. In such cases, water seeps through porous material or crevices, subjecting the work in progress to the pressure of the water above the tunneling path. When the tunnel is driven through stiff clay, the flow of water may be small enough to be removed by pumping. In more porous ground,compressed air must be used to exclude water. The amount of air pressure that is needed increases as the depth of the tunnel increases below the surface.A circular shield has proved to be most efficient in resisting the pressure of soft ground, so most shield-driven tunnels are circular. The shield once consisted of steel plates and angle supports, with a heavily braced diaphragm across its face. The diaphragm had a number of openings with doors so that workers could excavate material in front of the shield. In a further development, the shield was shoved forward into the silty material of a riverbed, thereby squeezing displaced material through the doors and into the tunnel, from which the muck was removed. The cylindrical shell of the shield may extend several feet in front of the diaphragm to provide a cutting edge. A rear section, called the tail, extends for several feet behind the body of the shield to protect workers. In large shields, an erector arm is used in the rear side of the shield to place the metal support segments along the circumference of the tunnel.The pressure against the forward motion of a shield may exceed 48.8 Mpa. Hydraulic jacks are used to overcome this pressure and advance the shield, producing a pressure of about 245 Mpa on the outside surface of the shield.Shields can be steered by varying the thrust of the jacks from left side to right side or from top to bottom, thus varying the tunnel direction left or right or up or down. The jacks shove against the tunnel lining for each forward shove. The cycle of operation is forward shove, line, muck, and then another forward shove. The shield used about 1955 on the third tube of the Lincoln Tunnel in New York City was 5.5 m long and 9.6 m in diameter. It was moved about 81.2 cm per shove, permitting the fabrication of a 81.2 cm support ring behind it.Cast-iron segments commonly are used in working behind such a shield. They are erected and bolted together in a short time to provide strength and water tightness. In the third tube of the Lincoln Tunnel each segment is 2 m long, 81.2 cm wide, and 35.5 cm thick, and weighs about 1.5 tons. These sections form a ring of 14 segments that are linked together by bolts. The bolts were tightened by hand and then by machine.Immediately after they were in place, the sections were sealed at the joints to ensure permanent water tightness.Shields are most commonly used in ground condition where adequate stand-up time does not exist. The advantage of the shield in this type of ground, in addition to the protection afforded men and equipment , is the time available to install steel ribs, liner plates, or precast concrete segments under the tail segment of the shield before ground pressure and movement become adverse factors.One of the principle problems associated with shield use is steering. Non-uniform ground pressure acting on the skin tends to force the shield off line and grade. This problem is particularly acute with closed bottom shield that do not ride on rails or skid tracks. Steering is accomplished by varying the hydraulic pressure in individual thrust jacks. If the shied is trying to dive, additional pressure on the invert jacks will resist this tendency. It is not unusual to find shield wandering several feet from the required. Although lasers are frequently used to provide continuous line and grade data to operator, once the shield wanders off its course, its sheer bulk resists efforts to bring it back. Heterogeneous ground conditions, such as clay with random boulders, also presents steering problems.One theoretical disadvantage of the shield is the annular space left between the support system and the ground surface. When the support system is installed within the tail section of the shield, the individual support members are separated from the ground surface by the thickness of the tail skin. When steel ribs are used, the annular space is filled with timber blocking as the forward motion of the shield exposes the individual ribs.A continuous support system presents a different problem. In this case, a filler material, such as pea gravel or grout, is pumped behind the support system to fill the void between it and the ground surface.The main enemy of the shield is ground pressure. As ground pressure begins to build, two things happen, more thrust is required for shield propulsion and stress increases in the structural members of the shield. Shields are designed and function undera preselected ground pressure. Designers will select this pressure as a percentage of the maximum ground pressure contemplated by the permanent tunnel design. In some cases, unfortunately, the shield just gets built without specific consideration of the ground pressures it might encounter. When ground pressure exceeds the design limit, the shield gets “stuck”.The friction component of the ground pressure on the skin becomes greater than the thrust capability of the jacks. Several methods, including pumping bentonite slurry into the skin, ground interface, pushing heavy equipment, and bumping with dynamite, have been applied to stuck shields with occasional success.Because ground pressure tends to increase with time, the cardinal rule of operation is “keeping moving”.This accounts for the fracture activity when a shield has suffered a temporary mechanical failure. As ground pressure continues to build on the nonmoving shield , the load finally exceeds its structural limit and bucking begins. An example of shield destruction occurred in California in 1968 when two shields being used to drive the Carly V.Porter Tunnel were caught by excessive ground pressure and deformed beyond repair. One of the Porter Tunnel shields was brought to a halt in reasonably good ground by water bearing ground fault that required full breast-boards. While the contractor was trying to bring the face under control, skin pressure began to increase. While the face condition finally stabilized, the contractor prepared to resume operations and discovered the shield was stuck. No combination of methods was able to move it, and the increasing ground pressure destroyed the shield.To offset the ground pressure effect, a standard provision in design is a cutting edge radius several inches greater than the main body radius. This allows a certain degree o f ground movement before pressure can come to bear on the shield skin. Another approach, considered in theory but not yet put into practice, is the “w atermelon seed”design. The theory calls for a continuous taper in the shield configuration; maximum radius at the cutting edge and the minimum radius at the trailing edge of the tail. With this configuration, any amount of forward movement would create a drop in skin pressure.Working decks, spaced 2.4 to 3.0 m vertically, are provided inside the shield. These working decks enable the miners to excavate the face, drill and load holes, if necessary, and adjust the breast-board system. The hydraulic jacks for the breast-board are mounted on the underside of the work decks. Blast doors are sometimes installed as an integral part of the work decks if a substantial amount of blasting is expected.Some form of mechanical equipment is provided on the rear end of the working decks to assist the miners in handing and placing the element of the support system. In large tunnels, these individual support elements can weigh several tons and mechanical assistance becomes essential. Sufficient vertical clearance must be provided between the invert and the first working deck to permit access to the face by the loading equipment.盾构【摘要】隧道盾构是一结构系统，通常用于洞室开挖。
电气系统可编程序控制器毕业论文中英文资料外文翻译文献
电气系统可编程序控制器中英文资料外文翻译文献英文原文Programmable controller designed for electro-pneumatic systems This project deals with the study of electro-pneumatic systems and theprogrammable controller that provides an effective and easy way to control thesequence of the pneumatic actuators movement and the states of pneumatic system.The project of a specific controller for pneumatic applications join the studyof automation design and the control processing of pneumatic systems with theelectronic design based on microcontrollers to implement the resources of thecontroller.1.IntroductionThe automation systems that use electro-pneumatic technology are formed mainlyby three kinds of elements: actuators or motors, sensors or buttons and controlelements like valves. Nowadays, most of the control elements used to execute thelogic of the system were substituted by the Programmable LogicController(PLC).Sensors and switches are plugged as inputs and the direct controlvalves for the actuators are plugged as outputs. An internal program executes allthe logic necessary to the sequence of the movements, simulates other componentslike counter, timer and control the status of the system.With the use of the PLC the project wins agility, because it is possible tocreate and simulate the system as many times as needed. Therefore, time can besaved, risk of mistakes reduced and complexity can be increased using the sameelements.A conventional PLC, that is possible to find on the market from many companies,offers many resources to control not only pneumatic systems, but all kinds of systemthat uses electrical components. The PLC can be very versatile and robust to beapplied in many kinds of application in the industry or even security system andautomation of buildings.Because of those characteristics, in some applications the PLC offers to much resources that are not even used to control the system, electro-pneumatic system is one of this kind of application. The use of PLC, especially for small size systems, can be very expensive for the automation project.An alternative in this case is to create a specific controller that can offer the exactly size and resources that the project needs[3,4].This can be made using microcontrollers as the base of this controller.The controller, based on microcontroller, can be very specific and adapted to only one kind of machine or it can work as a generic controller that can be programmed as a usual PLC and work with logic that can be changed. All these characteristics depend on what is needed and how much experience the designer has with developing an electronic circuit and firmware for microcontroller. But the main advantage of design the controller with the microcontroller is that the designer has the total knowledge of his controller, which makes it possible to control the size of the controller, change the complexity and the application of it. It means that the project gets more independence from other companies, but at the same time the responsibility of the control of the system stays at the designer hands2.Electro-pneumatic systemOn automation system one can find three basic components mentioned before ,plus a logic circuit that controls the system. An adequate technique is needed to project the logic circuit and integrate all the necessary components to execute the sequence of movements properly.For a simple direct sequence of movement an intuitive method can be used[1,5],but for indirect or more complex sequences the intuition can generate a very complicated circuit and signal mistakes. It is necessary to use another method that can save time of the project, make a clean circuit, can eliminate occasional signal overlapping and redundant circuits.The presented method is called step-by-step or algorithmic [1,5], it is valid for pneumatic and electro-pneumatic systems and it was used as a base in this work. The method consists of designing the systems based on standard circuits made for each change on the state of the actuators, these changes are called steps.Fig.1.Standard circuit for the pneumatic system.Fig.2.Standard circuit for the electro-pneumatic system.The first part is to design those kinds of standard circuits for each step, the next task is to link the standard circuits and the last part to connect the control element that receive signals from sensors, switches and the previous movement and give the air or electricity to the supply lines of each step. In Figs.1 and 2 the standard circuits are drawn for pneumatic and electro-pneumatic system [8].It is possible to see the relations with the previous and the next steps.3. The method applied inside the controllerThe result of the method presented before is a sequence of movements of the actuator that is well defined by steps. It means that each change on the position of the actuators is a new state of the system and the transition between statesis called step.The standard circuit described before helps the designer to define the states of the systems and to define the condition to each change between the states. In the end of the design, the system is defined by a sequence that never chances and states that have the inputs and the outputs well defined. The inputs are the condition for the transition and the outputs are the result of the transition.All the configuration of those steps stays inside of the microcontroller and is executed the same way it was designed. The sequences of strings are programmed inside the controller with 5 bytes; each string has the configuration of one step of the process. There are two bytes for the inputs, one byte for the outputs and two more for the other configurations and auxiliary functions of the step. After programming, this sequence of strings is saved inside of a non-volatile memory of the microcontroller, so they can be read and executed.The controller task is not to work in the same way as a conventional PLC, but the purpose of it is to be an example of a versatile controller that is design for an specific area. A conventional PLC process the control of the system using a cycle where it makes an image of the inputs, execute all the conditions defined by the configuration programmed inside, and then update the state of the outputs. This controller works in a different way, where it read the configuration of the step, wait the condition of inputs to be satisfied, then update the state or the outputs and after that jump to the next step and start the process again.It can generate some limitations, as the fact that this controller cannot execute, inside the program, movements that must be repeated for some time, but this problem can be solved with some external logic components. Another limitation is that the controller cannot be applied on systems that have no sequence. These limitations are a characteristic of the system that must be analyzed for each application.4. Characteristics of the controllerThe controller is based on the MICROCHIP microcontroller PIC16F877 [6,7] with 40 pins, and it has all the resources needed for this project. It ha enough pins for all the components, serial communication implemented in circuit, EEPROM memory to save all the configuration of the system and the sequence of steps. For the execution of the main program, it offers complete resources as timers and interruptions.The list of resources of the controller was created to explore all the capacity of the microcontroller to make it as complete as possible. During the step, the program chooses how to use the resources reading the configuration string of the step. This string has two bytes for digital inputs, one used as a mask and the other one used as a value expected. One byte is used to configure the outputs value. One bytes more is used for the internal timer, the analog input or time-out. The EEPROM memory inside is 256 bytes length that is enough to save the string of the steps, with this characteristic it is possible to save between 48 steps.The controller has also a display and some buttons that are used with an interactive menu to program the sequence of steps and other configurations.4.1.Interaction componentsFor the real application the controller must have some elements to interact with the final user and to offer a complete monitoring of the system resources that are available to the designer while creating the logic control of the pneumatic system:.Interactive mode of work; function available on the main program for didactic purposes, the user gives the signal to execute the step..LCD display, which shows the status of the system, values of inputs, outputs, timer and statistics of the sequence execution..Beep to give important alerts, stop, start and emergency..Leds to show power on and others to show the state of inputs and outputs.4.2. SecurityTo make the final application works property, a correct configuration to execute the steps in the right way is needed, but more then that it must offer solutions in case of bad functioning or problems in the execution of the sequence. The controller offers the possibility to configure two internal virtual circuits that work in parallel to the principal. These two circuits can be used as emergency or reset buttons and can return the system to a certain state at any time[2]. There are two inputs that work with interruption to get an immediate access to these functions. It is possible to configure the position, the buttons and the value of time-out of the system.er interfaceThe sequence of strings can be programmed using the interface elements of the controller. A computer interface can also be used to generate the user program easily. With a good documentation the final user can use the interface to configure the strings of bytes that define the steps of the sequence. But it is possible to create a program with visual resources that works as a translator to the user,it changes his work to the values that the controller understands.To implement the communication between the computer interface and the controller a simple protocol with check sum and number of bytes is the minimum requirements to guarantee the integrity of the data.4.4. FirmwareThe main loop works by reading the strings of the steps from the EEPROM memory that has all the information about the steps.In each step, the status of the system is saved on the memory and it is shown on the display too. Depending of the user configuration, it can use the interruption to work with the emergency circuit or time-out to keep the system safety.A block diagram of micro controller main program is presented.5.Example of electro-pneumatic systemThe system is not a representation of a specific machine, but it is made with some common movements and components found in a real one. The system is composed of four actuators. The actuators A,B and C are double acting and D-single acting. Actuator A advances and stays in specified position till the end of the cycle, it could work fixing an object to the next action for example(Fig.3), it is the first step. When A reaches the end position, actuator C starts his work together with B, making as many cycles as possible during the advancing of B. It depends on how fast actuator B is advancing; the speed is regulated by a flowing control valve. It was the second step. B and C are examples of actuators working together, while B pushes an object slowly, C repeats. its work for some time.Fig.3.Time diagram of A,B,C and D actuators.When B reaches the final position, C stops immediately its cycle and comes back to the initial position. The actuator D is a single acting one with spring return and works together with the back of C, it is the third step. D works making very fast forward and backward movement, just one time. Its backward movement is the fourth step. D could be a tool to make a hole on the object.When D reaches the initial position, A and B return too, it is the fifth step.Fig.4 shows the first part of the designing process where all the movements of each step should be defined[2]. (A+)means that the actuator A moves to the advanced position and (A . )to the initial position. The movements that happen at the same time are joined together in the same step. The system has five steps.Fig.4.Step sequence of A,B,C and D actuators.These two representations of the system(Figs.3 and 4) together are enough to describe correctly all the sequence. With them is possible to design the whole control circuit with the necessary logic components. But till this time, it is not a complete system, because it is missing some auxiliary elements that are not included in this draws because they work in parallel with the main sequence.These auxiliary elements give more function to the circuit and are very important to the final application; the most important of them is the parallel circuit linked with all the others steps. That circuit should be able to stop the sequence at any time and change the state of the actuators to a specific position. This kind of circuit can be used as a reset or emergency buttons.The next Figs.5 and 6 show the result of using the method without the controller. These pictures are the electric diagram of the control circuit of the example, including sensors, buttons and the coils of the electrical valves.Fig.5.Electric diagram of the example.Fig.6.Electric diagram of the example.The auxiliary elements are included, like the automatic/manual switcher that permit a continuous work and the two start buttons that make the operator of a machine use their two hands to start the process, reducing the risk of accidents.6. Changing the example to a user programIn the previous chapter, the electro-pneumatic circuits were presented, used to begin the study of the requires to control a system that work with steps andmust offer all the functional elements to be used in a real application. But, as explained above, using a PLC or this specific controller, the control becomes easier and the complexity can be increase also.It shows a resume of the elements that are necessary to control the presented example.With the time diagram, the step sequence and the elements of the system described in Figs.3 and 4 it is possible to create the configuration of the steps that can be sent to the controller.While using a conventional PLC, the user should pay attention to the logic of the circuit when drawing the electric diagram on the interface (Figs.5and 6), using the programmable controller, describe in this work, the user must know only the concept of the method and program only the configuration of each step.It means that, with a conventional PLC, the user must draw the relation between the lines and the draw makes it hard to differentiate the steps of the sequence. Normally, one needs to execute a simulation on the interface to find mistakes on the logic.The new programming allows that the configuration of the steps be separated, like described by the method. The sequence is defined by itself and the steps are described only by the inputs and outputs for each step.The structure of the configuration follows the order:1-byte: features of the step;2-byte: for the inputs;3-byte: value expected on the inputs;4-byte: value for the outputs;5-byte: value for the extra function.Fig.7.Actuators A and B, and sensors.Fig.8.Actuators C and D, and sensors.Table 5 shows how the user program is saved inside the controller, this is the program that describes the control of the example shown before.The sequence can be defined by 25 bytes. These bytes can be divided in five strings with 5 bytes each that define each step of the sequence (Figs.7 and 8).7. ConclusionThe controller developed for this work shows that it is possible to create a very useful programmable controller based on microcontroller. External memories or external timers were not used in case to explore the resources that the microcontroller offers inside. Outside the microcontroller, there are only components to implement the outputs, inputs, analog input, display for the interface and the serial communication.Using only the internal memory, it is possible to control a pneumatic system that has a sequence with 48 steps if all the resources for all steps are used, but it is possible to reach sixty steps in the case of a simpler system.The programming of the controller does not use PLC languages, but a configuration that is simple and intuitive. With electro-pneumatic system, the programming follows the same technique that was used before to design the system, but here the designer works directly with the states or steps of the system.With a very simple machine language the designer can define all the configuration of the step using four or five bytes. It depends only on his experience to use all the resources of the controller.The controller task is not to work in the same way as a commercial PLC but the purpose of it is to be an example of a versatile controller that is designed for a specific area. Because of that, it is not possible to say which one works better; the system made with microcontroller is an alternative that works in a simple way.References[1]E.Nelli Silva,Fluid-mechanics systems Manual, Escola PolitecnicaUSP,2002(in Portuguese).[2]J.Swider,Control and Automation of Technological Process and Mechatronic systems,Silesian University Publishing Company,Gli-wice,2002(redaction in Polish).[3]J.Swider, G.Wszolek, W.Carvalho. Example of the system prepared to be controlled by the controller based on microcontroller,in:12 International Scientific Conference—Achievements in Mechanical and MaterialsEngineering,Gliwice-Zakopane,Poland,2003,pp.965-970.[4]J.Swider,G.Wszolek,W.Carvalho, Controller based on microcontroller designed to execute the logic control of pneumatic systems, in:12International Scientific Conference— Achievements in Mechanical and Materials Engineering,Gliwice-Zakopane,Poland,2003,pp. 959–964.[5]J.Swider,G.Wszoek, The methodical collection of laboratory and project tasks of technological process control in Pneumatic and Electro-pneumatic Systems with Logical PLC Control, Silesian University Publishing Company,Gliwice,2003.[6]PIC 16f87xDatasheet.MICROCHIP,2001.[7]Application notes AN587 and AN546.MICROCHIP,1997.[8]Fundamental of electro-pneumatic—FESTODidactic,2000.中文翻译应用于电气系统的可编程序控制器摘要此项目主要是研究电气系统以及简单有效的控制气流发动机的程序和气流系统的状态。
(完整版)_毕业设计(论文) 外文文献翻译_
毕业设计（论文）外文文献翻译题目：金融银行信用风险管理与知识管理教学院：经济与管理学院专业名称：工商管理学号：学生姓名：谭勤辉指导教师：刘显铭2013 年05 月28 日Managing Credit Risks with Knowledge ManagementforFinancial BanksPan JinDepartment of EconomicsEconomics and Management School of Wuhan UniversityWuhan,Hubei ProvinceChinaAbstract-Nowadays,financial banks are operating in a knowledge society and there are more and more credit risks breaking out in banks.So,this paper first discusses the implications of knowledge and knowledge management, and then analyzes credit risks of financial banks with knowledge management. Finally, the paper studies ways for banks to manage credit risks with knowledge management. With the application of knowledge management in financial banks, customers will acquire better service and banks will acquire more rewards.Index Terms–knowledge management; credit risk; risk management; incentive mechanism; financial banksI.INTRODUCTIONNowadays,banks are operating in a“knowledge society”.So, what is knowledge? Davenport(1996)[1]thinks knowledge is professional intellect,such as know-what, know- be shared and communicated. The awareness of the importance of knowledge results in the critical issue of “knowledge management”.So, what is knowledge management? According to Malhothra(2001)[2], knowledge management(KM)caters to the critical issues of organizational adaptation, survival and competence in face of increasingly discontinuous environmental change. Essentially it embodies organizational processes that seek synergistic combination of data and information processing capacity of information technologies and the creative and innovative capacity of beings. Through the processes of creating,sustaining, applying, sharing and renewing knowledge, we can enhance organizational performance and create value.Many dissertations some special fields. Aybübe Aurum(2004)[3] analyzes knowledge management in software engineering and D.J.Harvey ＆R.Holdsworth(2005)[4]study knowledge management in the aerospace industry. Li Yang(2007)[5] studies knowledge management in information-based education and Jayasundara＆Chaminda Chiran(2008)[6] review the prevailing literature on knowledge management in banking industries. Liang ping and Wu Kebao(2010)[7]study the incentive mechanism of knowledge management inBanking.There are also many papers about risks analysis and risks management. Before the 1980s, the dominant mathematical theory of risks analysis was to describe a pair of random vectors.But,the simplificationassumptions and methods used by classical competing risks analysis caused controversy and criticism.Starting around the 1980s, an alternative formulation of risk analysis was developed,with the identifiability. The new formulation is univariate risk analysis.According to Crowder(2001)[8], David＆Moeschberger(1978)[9]and Hougaard(2000)[10],univariate survival risk analysis dominantly, which is based on the i.i.d assumptions(independent and identically distributed) or, at least, based on the independent failure assumption.Distribution-free regression modeling allows one to investigate the influences of multiple covariates on the failure, and it relaxes the assumption of identical failure distribution and to some extent, it also relaxes the single failure risk restriction. However, the independent failures as well as single failure events are still assumed in the univariate survival analysis. Of course,these deficiencies do not invalidate univariate analysis, and indeed, in many applications, those assumptions are realistically valid.Based on the above mentioned studies, Ma and Krings(2008a, 2008b)[11]discuss the relationship and difference of univariate and multivariate analysis in calculating risks.As for the papers on managing the risks in banks, Lawrence J.White(2008)[12]studies the risks of financial innovations and takes out some countermeasures to regulate financial innovations. Shao Baiquan(2010)[13]studies the ways to manage the risks in banks.From the above papers, we can see that few scholars Ⅰis introduction. SectionⅡanalyzes credit risks in banks with knowledge management. SectionⅢstudies ways for banks to manage credit risks with knowledgemanagement. SectionⅣconcludes.II.ANALYZING CREDIT RISKS IN BANKS WITHKNOWLEDGE MANAGEMENTA.Implication of Credit RiskCredit risk is the risk of loss due to a debtor’s non-payment of a loan or other line of credit, which may be the principal or interest or both.Because there are many types of loans and counterparties-from individuals to sovereign governments-and many different types of obligations-from auto loans to derivatives transactions-credit risk may take many forms.Credit risk is common in our daily life and we can not cover it completely,for example,the American subprime lending crisis is caused by credit risk,which is that the poor lenders do not pay principal and interest back to the banks and the banks do not pay the investors who buy the securities based on the loans.From the example,we can find that there are still credit risks,though banks banks includes tacit knowledge and explicit knowledge,which is scattered in different fields.For example, the information about the customers’income, asset and credit is controlled by different departments and different staffs and the information can’t be communicated with others. So it is necessary for banks to set up a whole system to communicate and share the information and knowledge to manage the risks.C.Setting up Incentive Mechanism and Encouraging Knowledge InnovationThe warning mechanism of credit risks depends on the incentive mechanism in banks,so, banks should take out incentive mechanism to urge staffs to learn more knowledge and work creatively to manage credit risks.We can show the incentive mechanism as Fig.1:Fig.1 The model of incentive mechanism with knowledge management From Fig.1,we can see there are both stimulative and punitive measures in the incentive model of knowledge management for financial banks.With the incentive mechanism of knowledge management in financial banks,the staffs will work managing credit risks with knowledge management.We can show them in Fig.2:Fig.2 The blocks of managing credit risksA.Distinguishing Credit RiskDistinguishing credit risks is the basis of risk management.If we can’t recognize the risks,we are unable to find appropriate solutions to manage risks.For example,the United States subprime crisis in 2007 was partly caused by that the financial institutions and regulators didn’t recognize the mortgage securitization risks timely.With knowledge management,we can make out some rules to distinguish credit risks,which are establishing one personal credit rating system for customers and setting up the data warehouse.We can use the system to analyze customers’credit index, customers’credit the changes of customers’property and income to recognize potential risks.B.Assessing and Calculating Credit RiskAfter distinguishing the credit risks,we should assess the riskexposure,risk factors and potential losses and risks, and we should make out the clear links.The knowledgeable staffs in banking should use statistical methods and model and the regulators should establish credit assessment system and then set up one national credit assessment system.With the system and the model of risk assessment,the managers can evaluate the existing and emerging risk factors,such as they prepare credit ratings for internal use.Other firms,including Standard ＆Poor’s,Moody’s and Fitch,are in the business of developing credit rating for use by investors or other third parties.TableⅠshows the credit ratings of Standard＆Poor’s.TABLE ISTANDARD＆POOR’S CREDITT RATINGSCredit ratings ImplicationsAAA Best credit quality,extremely reliableAA Very good credit quality,very reliableA More susceptible to economic conditionsBBB Lowest rating in investment gradeBB Caution is necessaryB Vulnerable to changes in economicCCC Currently vulnerable to nonpaymentCC Highly vulnerable to payment defaultC Close to bankruptD Payment default has actually occurredAfter assessing credit risks,we can use Standardized Approach andInternal Rating-Based Approach to calculate the risks.And in this article,we will analyze uncovered loan.To calculate credit risk of an uncovered loan,firstly,we will acquire the bo rrower’s Probability of Default(PD),Loss Given Default(LGD),Exposure at Default(EAD)and Remaining Maturity(M).Secondly,we calculate the simple risk(SR)of the uncovered loan,using the formula as following: SR=Min{BSR(PD)*[1+b(PD)*(M-3)]*LGD50,LGD*12.5} (1)Where BSR is the basic risk weight and b(PD)is the adjusting factor for remaining maturity(M).Finally,we can calculate the weighted risk(WR)of the uncovered loan,using the following formula:WR=SR*EAD (2)From(1)and(2),we can acquire the simple and weighted credit risk of an uncovered loan,and then we can take some measures to ’t repay the loans,banks can get the compensation from the insurance company.(3)Loans Securitization. Banks can change the loans into security portfolio,according to the different interest rate and term of the loans,and then banks can sell the security portfolio to the special organizations or trust companies.D.Managing Credit Risk and Feeding backA customer may acquire the customer’s credit information,credit the data the banks get.By assessing and calculating the risks of the customer,banks can expect the future behavior of the customers and provides different service for different customers. Banks can provide morevalue-added service to the customers who remedial after the risks broke out.In order to set up the warning and feeding back mechanism,banks should score credit of the customers comprehensively and then test the effectiveness and suitability of the measures,which banks use to mitigate risks.Finally, banks should update the data of the customers timely and keep the credit risk management system operating smoothly.IV.CONCLUSIONIn this paper,we first discuss the implications of knowledge and knowledge management.Then we analyze the credit risks of financial banks with knowledge management. Finally,we put forward ways for banks to manage credit risks with knowledge management.We think banks should set up data warehouse of customers’credit to assess and calculate the credit risks,and at the same time,banks should train knowledgeable staffs to construct a whole system to reduce risks and feed back.With knowledge management,banks can take out systemic measures to manage customers’credit risks and gain sustainable profits.ACKNOWLEDGMENTIt is financed by the of China(NO.06JC790032).REFERENCES[1]Davenport,T.H.et al,“Improving knowledge work processes,”Sloan Management Review,MIT,USA,1996,Vol.38,pp.53-65.[2]Malhothra,“Knowledge management for the new world of business,”New York BRINT Institute,2001, software engineering education,”Proceedings of the IEEE International Conference onAdvanced Learning Technologies,2004,pp..[4]D.J.Harvey＆R.Holdsworth,“Knowledge management in the aerospace industry,”Proceedings of the IEEE International Professional Communication Conference,2005,pp..[5]Li Yang,“Thinking about knowledge management applications in information-based education,”IEEE International Conference on Advanced Learning Technologies,2007,pp.27-33.[6]Jayasundara＆Chaminda Chiran,“Knowledge managemen t in banking industries:uses and opportunities,”Journal of the University Librarians Association of Sri Lanka,2008,Vol.12,pp.68-84.[7]Liang Ping,Wu Kebao,“Knowledge management in banking,”The Conference on Engineering and Business Management,2010, pp..[8]Crowder,M.J.Classical Competing Risks,British:Chapman&Hall, 2001,pp.200.[9]David,H.A.&M.L.Moeschberger,The Theory of Competing Risks, Scotland,Macmillan Publishing,1978,pp.103.金融银行信用风险管理与知识管理摘要：目前，金融银行经营在一个知识型社会中，而且越来越多的信用风险在在银行中爆发。
高速数字混合锁相环频率合成器毕业论文中英文资料对照外文翻译文献综述
中英译文翻译英文：High Speed Digital Hybrid PLL Frequency Synthesizer译文：高速数字混合锁相环频率合成器To get the high-speed, it is necessary to prepare the precise synchronization of the complicated design.In 2001, H. G. Ryu proposed a simplified structure of the DDFS (direct digital frequency synthesizer)-driven PLL for the high switching speed [2].However, there is a problem that the speed of the whole system is limited by PLL.Y. Fouzar proposed a PLL frequency synthesizer of dual loop configuration using frequency-to-voltage converter (FVC) [3].It has a fast switching speed by the PD (phase detector), FVC using output signal of VCO and the proposed coarse tuning controller.However, H/W complexity is increased for the high switching speed.Also, it shows the fast switching characteristic only when the FVC works well.Another method is pre-tuning one which is called DH-PLL in this study [4].It has very high speed switching property, but H/W complexity and power consumption are increased due to digital look-up table (DLT) which is usually implemented by the ROM including the transfer characteristic ofVCO(voltage controlled oscillator).For this reason, this paper proposes a timing synchronization circuit for the rapid frequency synthesis and a very simple DLT replacement digital logic block instead of the complex ROM type DLT for high speed switching and low power consumption. Also, the requisite condition is solved in the proposed method. The fast switching operation at every the frequency synthesis process is verified by the computer circuit simulation.II.DH-PLL synthesizerAs shown in Fig.1, the open-loop synthesizer is a direct frequency synthesis type that VCO 要得到高运行速度,事先做好复杂设计的精确同步是必要的。
毕业设计(论文)外文资料翻译
南京理工大学紫金学院毕业设计(论文)外文资料翻译系：机械工程系专业：机械工程及自动化姓名：徐华俊学号：100104348外文出处：WASTE FOOD DISPOSAL SYSTEM(3)(用外文写)附件：1.外文资料翻译译文；2.外文原文。
指导教师评语：该生翻译了一篇有关《废弃食物处理系统》的论文，论文内容跟课题的研究领域相关，在将来的课题设计中可以借鉴。
译文语句基本通顺，专业术语正确，标点符号运用无误。
说明该生具备一定的英语水平和翻译能力。
但文中仍有部分语句组织得不够完善，可以进一步修改。
签名：年月日注：请将该封面与附件装订成册。
附件1：外文资料翻译译文垃圾食物处理系统（3）打开功率继电器32的驱动，关闭与其相连的常闭开关118，从而消除了在此之前被施加到定时器单元40的控制终端146的触发信号，并且需要注意的是，功率继电器30的电源开关108供应了一个类似的功能，如本文所述的，启动系统10每天第一次激活功率继电器30的时候，这个功能中断了定时器单元40的控制终端146，即先前追踪的触发信号电路，如本文所述。
进一步，在与功率继电器32相连的开关被关闭的时候，它的驱动被触发的结果是非常明显的，断开常开继电器开关119，为高流量水阀22的电磁阀80建立了一个到地面的备用路径，也就是可以追踪到电源线200；通过导线202；电磁阀80；导线204；导线416和现在被断开的功率继电器32的闭合开关119到地面，如此一来就能明显并且很方便的注意到，与功率继电器30相连的开关109执行同样的功能，通过一个完全可追踪的功率继电器30，而不是功率继电器32，使功率继电器30处于启动状态，所以在任何时期，控制单元12的电动机46可在任意一个方向操作（这取决于功率继电器30或功率继电器32处于激活状态），电磁阀80也将保持通电，来保持高流量水阀22在该段时期内处于闭合状态，这样的话，水流将会在需要大幅率的时候流通，通过管道76和78流到控制单元12，这个控制单元12的机构52正积极粉碎积累废料，并且已经积累或正在采用，接着顺着水流冲到下水道或者通过类似单元12的出口58.你将会很方便的观察到电磁阀74保持通电，并且在控制单元12积极运作期间，低流量水阀20也保持闭合，并且应当在任何特定安装情况下，把阀22的流通能力考虑在内。
毕业设计(论文)外文资料翻译(学生用)
毕业设计外文资料翻译学院：信息科学与工程学院专业：软件工程姓名： XXXXX学号： XXXXXXXXX外文出处： Think In Java (用外文写)附件： 1.外文资料翻译译文；2.外文原文。
附件1：外文资料翻译译文网络编程历史上的网络编程都倾向于困难、复杂，而且极易出错。
程序员必须掌握与网络有关的大量细节，有时甚至要对硬件有深刻的认识。
一般地，我们需要理解连网协议中不同的“层”（Layer）。
而且对于每个连网库，一般都包含了数量众多的函数，分别涉及信息块的连接、打包和拆包；这些块的来回运输；以及握手等等。
这是一项令人痛苦的工作。
但是，连网本身的概念并不是很难。
我们想获得位于其他地方某台机器上的信息，并把它们移到这儿；或者相反。
这与读写文件非常相似，只是文件存在于远程机器上，而且远程机器有权决定如何处理我们请求或者发送的数据。
Java最出色的一个地方就是它的“无痛苦连网”概念。
有关连网的基层细节已被尽可能地提取出去，并隐藏在JVM以及Java的本机安装系统里进行控制。
我们使用的编程模型是一个文件的模型；事实上，网络连接（一个“套接字”）已被封装到系统对象里，所以可象对其他数据流那样采用同样的方法调用。
除此以外，在我们处理另一个连网问题——同时控制多个网络连接——的时候，Java内建的多线程机制也是十分方便的。
本章将用一系列易懂的例子解释Java的连网支持。
15.1 机器的标识当然，为了分辨来自别处的一台机器，以及为了保证自己连接的是希望的那台机器，必须有一种机制能独一无二地标识出网络内的每台机器。
早期网络只解决了如何在本地网络环境中为机器提供唯一的名字。
但Java面向的是整个因特网，这要求用一种机制对来自世界各地的机器进行标识。
为达到这个目的，我们采用了IP（互联网地址）的概念。
IP以两种形式存在着：(1) 大家最熟悉的DNS（域名服务）形式。
我自己的域名是。
所以假定我在自己的域内有一台名为Opus的计算机，它的域名就可以是。
Mechanical-Design机械设计毕业论文外文文献翻译及原文
毕业设计（论文）外文文献翻译文献、资料中文题目：机械设计文献、资料英文题目：Mechanical Design文献、资料来源：文献、资料发表（出版）日期：院（部）：专业：班级：姓名：学号：指导教师：翻译日期： 2017.02.14外文资料翻译译文机械设计摘要：机器是由机械装置和其它组件组成的。
它是一种用来转换或传递能量的装置，例如：发动机、涡轮机、车辆、起重机、印刷机、洗衣机、照相机和摄影机等。
许多原则和设计方法不但适用于机器的设计，也适用于非机器的设计。
术语中的“机械装置设计”的含义要比“机械设计”的含义更为广泛一些，机械装置设计包括机械设计。
在分析运动及设计结构时，要把产品外型以及以后的保养也要考虑在机械设计中。
在机械工程领域中，以及其它工程领域中，所有这些都需要机械设备，比如：开关、凸轮、阀门、船舶以及搅拌机等。
关键词：设计流程设计规则机械设计设计流程设计开始之前就要想到机器的实际性，现存的机器需要在耐用性、效率、重量、速度，或者成本上得到改善。
新的机器必需具有以前机器所能执行的功能。
在设计的初始阶段，应该允许设计人员充分发挥创造性，不要受到任何约束。
即使产生了许多不切实际的想法，也会在设计的早期，即在绘制图纸之前被改正掉。
只有这样，才不致于阻断创新的思路。
通常,还要提出几套设计方案，然后加以比较。
很有可能在这个计划最后决定中,使用了某些不在计划之内的一些设想。
一般的当外型特点和组件部分的尺寸特点分析得透彻时，就可以全面的设计和分析。
接着还要客观的分析机器性能的优越性，以及它的安全、重量、耐用性，并且竞争力的成本也要考虑在分析结果之内。
每一个至关重要的部分要优化它的比例和尺寸，同时也要保持与其它组成部分相协调。
也要选择原材料和处理原材料的方法。
通过力学原理来分析和实现这些重要的特性，如那些静态反应的能量和摩擦力的最佳利用，像动力惯性、加速动力和能量；包括弹性材料的强度、应力和刚度等材料的物理特性，以及流体润滑和驱动器的流体力学。
毕业设计论文化学系毕业论文外文文献翻译中英文
毕业设计论文化学系毕业论文外文文献翻译中英文英文文献及翻译A chemical compound that is contained in the hands of the problemsfor exampleCatalytic asymmetric carbon-carbon bond formation is one of the most active research areas in organic synthesis In this field the application of chiral ligands in enantioselective addition of diethylzinc to aldehydes has attracted much attention lots of ligands such as chiral amino alcohols amino thiols piperazines quaternary ammonium salts 12-diols oxazaborolidines and transition metal complex with chiral ligands have been empolyed in the asymmetric addition of diethylzinc to aldehydes In this dissertation we report some new chiral ligands and their application in enantioselective addition of diethylzinc to aldehydes1 Synthesis and application of chiral ligands containing sulfur atomSeveral a-hydroxy acids were prepared using the literature method with modifications from the corresponding amino acids valine leucine and phenylalanine Improved yields were obtained by slowly simultaneous addition of three fold excess of sodium nitrite and 1 tnolL H2SO4 In the preparation of a-hydroxy acid methyl esters from a-hydroxy acids following the procedure described by Vigneron a low yield 45 was obtained It was found that much better results yield 82 couldbe obtained by esterifying a-hydroxy acids with methanol-thionyl chlorideThe first attempt to convert S -2-hydroxy-3-methylbutanoic acid methyl ester to the corresponding R-11-diphenyl-2-mercapto-3-methyl-l-butanol is as the following S-2-Hydroxy-3-methylbutanoic acid methyl ester was treated with excess of phenylmagnesium bromide to give S -11-diphenyl-3-methyl-12-butanediol which was then mesylated to obtain S -11-diphenyl-3-methyl-2-methanesulfonyloxy -l-butanol Unfortunately conversion of S-11-diphenyl-3-methyl-2- methanesulfonyloxy -l-butanol to the corresponding thioester by reacting with potassium thioacetate under Sn2 reaction conditions can be achieved neither in DMF at 20-60 nor in refluxing toluene in the presence of 18-crown-6 as catalyst When S -1ll-diphenyl-3-methyl-2- methane sulfonyloxy -l-butanol was refluxed with thioacetic acid in pyridine an optical active epoxide R-22-diphenyl -3-isopropyloxirane was obtained Then we tried to convert S -11-diphenyl-3-methyl-l2-butanediol to the thioester by reacting with PPh3 DEAD and thioacetic acid the Mitsunobu reaction but we failed either probably due to the steric hindrance around the reaction centerThe actually successful synthesis is as described below a-hydroxy acid methyl esters was mesylated and treated with KSCOCH3 in DMF to give thioester this was than treated with phenyl magnesium bromide to gave the target compound B-mercaptoalcohols The enantiomeric excesses ofp-mercaptoalcohols can be determined by 1H NMR as their S -mandeloyl derivatives S -2-amino-3-phenylpropane-l-thiol hydrochloride was synthesized from L-Phenylalanine L-Phenylalanine was reduced to the amino alcohol S -2-amino-3-phenylpropanol Protection of the amino group using tert-butyl pyrocarbonate gave S -2-tert-butoxycarbonylamino-3-phenylpropane-l-ol which was then O-mesylated to give S -2-tert-butoxycarbonylamino-3-phenylpropyl methanesulfonate The mesylate was treated with potassium thioacetate in DMF to give l-acetylthio-2-tert-butoxycarbonylamino-3-phenylpropane The acetyl group was then removed by treating with ammonia in alcohol to gave S -2-tert-butoxycarbonylamino-3-phenyl-propane-l-thiol which was then deprotected with hydrochloric acid to give the desired S-2-amino-3-phenylpropane-1-thiol hydrochlorideThe enantioselective addition of diethylzinc to aldehydes promoted by these sulfur containing chiral ligands produce secondary alcohols in 65-79 Synthesis and application of chiral aminophenolsThree substituted prolinols were prepared from the naturally-occurring L-proline using reported method with modifications And the chiral aminophenols were obtained by heating these prolinols with excess of salicylaldehyde in benzene at refluxThe results of enantioselective adBelow us an illustration forexampleN-Heterocyclic carbenes and L-Azetidine-2-carboxylicacidN-Heterocyclic carbenesN-Heterocyclic carbenes have becomeuniversal ligands in organometallic and inorganic coordination chemistry They not only bind to any transition metal with low or high oxidation states but also to main group elements such as beryllium sulfur and iodine Because of their specific coordination chemistry N-heterocyclic carbenes both stabilize and activate metal centers in quite different key catalytic steps of organic syntheses for example C-H activation C-C C-H C-O and C-N bond formation There is now ample evidence that in the new generation of organometallic catalysts the established ligand class of organophosphanes will be supplemented and in part replaced byN-heterocyclic carbenes Over the past few years this chemistry has become the field of vivid scientific competition and yielded previously unexpected successes in key areas of homogeneous catalysis From the work in numerous academic laboratories and in industry a revolutionary turningpoint in oraganometallic catalysis is emergingIn this thesis Palladium Ⅱ acetate and NN"-bis- 26-diisopropylphenyl dihydro- imidazolium chloride 1 2 mol were used to catalyze the carbonylative coupling of aryl diazonium tetrafluoroborate salts and aryl boronic acids to form aryl ketones Optimal conditions include carbon monoxide 1 atm in 14-dioxane at 100℃ for 5 h Yields for unsymmetrical aryl ketones ranged from 76 to 90 for isolated materials with only minor amounts of biaryl coupling product observed 2-12 THF as solvent gave mixtures of products 14-Dioxane proved to be the superior solvent giving higher yieldsof ketone product together with less biphenyl formation At room temperature and at 0℃ with 1 atm CO biphenyl became the major product Electron-rich diazonium ion substrates gave a reduced yield with increased production of biaryl product Electron-deficient diazonium ions were even better forming ketones in higher yields with less biaryl by-product formed 2-Naphthyldiazonium salt also proved to be an effective substrate givingketones in the excellent range Base on above palladium NHC catalysts aryl diazonium tetrafluoroborates have been coupled with arylboron compounds carbon monoxide and ammonia to give aryl amides in high yields A saturated yV-heterocyclic carbene NHC ligand H2lPr 1 was used with palladium II acetate to give the active catalyst The optimal conditions with 2mol palladium-NHC catalyst were applied with various organoboron compounds and three aryl diazonium tetrafluoroborates to give numerous aryl amides in high yield using pressurized CO in a THF solution saturated with ammonia Factors that affect the distribution of the reaction products have been identified and a mechanism is proposed for this novel four-component coupling reactionNHC-metal complexes are commonly formed from an imidazolium salt using strong base Deprotonation occurs at C2 to give a stable carbene that adds to form a a-complex with the metal Crystals were obtained from the reaction of imidazolium chloride with sodium t- butoxide Nal and palladium II acetate giving a dimeric palladium II iodide NHC complex The structure adopts a flat 4-memberedring u2 -bridged arrangement as seen in a related dehydro NHC complex formed with base We were pleased to find that chloride treated with palladium II acetate without adding base or halide in THF also produced suitable crystals for X-ray anaysis In contrast to the diiodide the palladium-carbenes are now twisted out of plane adopting a non-planar 4-ring core The borylation of aryldiazonium tetrafluoroborates with bis pinacolatoborane was optimized using various NHC ligand complexes formed in situ without adding base NN"-Bis 26-diisopropylphenyl-45-dihydroimidazolium 1 used with palladium acetate in THF proved optimal giving borylated product in 79 isolated yield without forming of bi-aryl side product With K2CO3 and ligand 1 a significant amount of biaryl product 24 was again seen The characterization of the palladium chloride complex by X-ray chrastallography deL-Azetidine-2-carboxylic acidL-Azetidine-2-carboxylic acid also named S -Azetidine-2-carboxylic acid commonly named L-Aze was first isolated in 1955 by Fowden from Convallaria majalis and was the first known example of naturally occurring azetidine As a constrained amino acid S -Azetidine-2-carboxylic acid has found many applications in the modification of peptides conformations and in the area of asymmetric synthesis which include its use in the asymmetric reduction of ketones Michael additions cyclopropanations and Diels-Alder reactions In this dissertation five ways for synthesize S-Azetidine-2-carboxylic acid were studied After comparing all methods theway using L-Aspartic acid as original material for synthesize S-Azetidine-2-carboxylic acid was considered more feasible All mechanisms of the way"s reaction have also been studied At last the application and foreground of S -Azetidine-2-carboxylic acid were viewed The structures of the synthetic products were characterized by ThermalGravity-Differential Thermal Analysis TG-DTA Infrared Spectroscopy IR Mass Spectra MS and 1H Nuclear Magnetic Resonance 1H-NMR Results showed that the structures and performances of the products conformed to the anticipation the yield of each reaction was more than 70 These can conclude that the way using L-Aspartie acid as original material for synthesize S -Azetidine-2-carboxylic acid is practical and effective杂环化合物生成中包含手性等问题如催化形成不对称碳碳键在有机合成中是一个非常活跃的领域在这个领域中利用手性配体诱导的二乙基锌和醛的不对称加成引起化学家的广泛关注许多手性配体如手性氨基醇手性氨基硫醇手性哌嗪手性四季铵盐手性二醇手性恶唑硼烷和过渡金属与手性配体的配合物等被应用于二乙基锌对醛的不对称加成中在本论文中我们报道了一些新型的手性配体的合成及它们应用于二乙基锌对醛的不对称加成的结果1含硫手性配体的合成和应用首先从氨基酸缬氨酸亮氨酸苯丙氨酸出发按照文献合成α-羟基酸并发现用三倍量的亚硝酸钠和稀硫酸同时滴加进行反应能适当提高反应的产率而根据Vigneron等人报道的的方法用浓盐酸催化从α-羟基酸合成α-羟基酸甲酯时只能获得较低的产率改用甲醇-二氯亚砜的酯化方法时能提高该步骤的产率从 S -3-甲基-2-羟基丁酸甲酯合成 R -3-甲基-11-二苯基-2-巯基-1-丁醇经过了以下的尝试 S -3-甲基-2-羟基丁酸甲酯和过量的格氏试剂反应得到 S -3-甲基-11-二苯基-12-丁二醇进行甲磺酰化时位阻较小的羟基被磺酰化生成 S -3-甲基-11-二苯基-2- 甲磺酰氧基 -1-丁醇但无论将 S -3-甲基-11-二苯基-2- 甲磺酰氧基 -1-丁醇和硫代乙酸钾在DMF中反应 20～60℃还是在甲苯中加入18-冠-6作为催化剂加热回流都不能得到目标产物当其与硫代乙酸在吡啶中回流时得到的不是目标产物而是手性环氧化合物 R -3-异丙基-22-二苯基氧杂环丙烷从化合物 S -3-甲基-11-二苯基-12-丁二醇通过Mitsunobu反应合成硫代酯也未获得成功这可能是由于在反应中心处的位阻较大造成的几奥斯塑手村犯体的合成裁其在不对称奋成中肠左用摘要成功合成疏基醇的合成路是将a-轻基酸甲酷甲磺酞化得到相应的磺酞化产物并进行与硫代乙酸钾的亲核取代反应得到硫酷进行格氏反应后得到目标分子p一疏基醇用p一疏基醇与 R 义一一甲氧基苯乙酞氯生成的非对映体经H侧NM吸测试其甲氧基峰面积的积分求得其ee值 3一苯基一氨基丙硫醇盐酸盐从苯丙氨酸合成斗3一苯基一氨基丙醇由L一苯丙氨酸还原制备氨基保护后得到习一3一苯基一2一叔丁氧拨基氨基一1一丙醇甲磺酞化后得到习一3一苯基一2一叔丁氧拨基氨基一1一丙醇甲磺酸酷用硫代乙酸钾取代后得匀一3-苯基一2一叔丁氧拨基氨基一1一丙硫醇乙酸酷氨解得习一3一苯基一2一叔丁氧拨基氨基一1一丙硫醇用盐酸脱保护后得到目标产物扔3一苯基屯一氨基丙硫醇盐酸盐手性含硫配体诱导下的二乙基锌与醛的加成所得产物的产率为65一79值为O井92手性氨基酚的合成和应用首先从天然的L一脯氨酸从文献报道的步骤合成了三种脯氨醇这些手性氨基醇与水杨醛在苯中回流反应得到手性氨基酚手性氨基酚配体诱导下的二乙基锌与醛的加成所得产物的产率为45一98值为0一90手性二茂铁甲基氨基醇的合成和应用首先从天然氨基酸绿氨酸亮氨酸苯丙氨酸和脯氨酸合成相应的氨基醇这些氨基醇与二茂铁甲醛反应生成的NO一缩醛经硼氢化钠还原得到手性二茂铁甲基氨基醇手性二茂铁甲基氨基醇配体诱导下的二乙基锌与醛的加成所得产物的产率为66一97下面我们举例说明一下例如含氮杂环卡宾和L-氮杂环丁烷-2-羧酸含氮杂环卡宾含氮杂环卡宾已广泛应用于有机金属化学和无机配合物化学领域中它们不仅可以很好地与任何氧化态的过渡金属络合还可以与主族元素铍硫等形成配合物由于含氮杂环卡宾不但使金属中心稳定而且还可以活化此金属中心使其在有机合成中例如C-H键的活化C-CC-HC-O和C-N键形成反应中有着十分重要的催化效能现有的证据充分表明在新一代有机金属催化剂中含氮杂环卡宾不但对有机膦类配体有良好的互补作用而且在有些方面取代有机膦配体成为主角近年来含氮杂环卡宾及其配合物已成为非常活跃的研究领域在均相催化这一重要学科中取得了难以想象的成功所以含氮杂环卡宾在均相有机金属催化领域的研究工作很有必要深入地进行下去本文研究了乙酸钯和NN双 26-二异丙基苯基 -45-二氢咪唑氯化物1作为催化剂催化芳基四氟硼酸重氮盐与芳基硼酸的羰基化反应合成了一系列二芳基酮并对反应条件进行了优化使反应在常温常压下进行一个大气压的一氧化碳14-二氧杂环己烷作溶剂100℃反应5h 不同芳基酮的收率达7690仅有微量的联芳烃付产物 212 反应选择性良好当采用四氢呋喃或甲苯作溶剂时得到含较多副产物的混合物由此可以证明14-二氧杂环己烷是该反应最适宜的溶剂在室温或0℃与一个大气压的一氧化碳反应联芳烃变成主产物含供电子取代基的芳基重氮盐常常给出较低收率的二芳基酮而含吸电子取代基的芳基重氮盐却给出更高收率的二芳基酮及较少量的联芳烃付产物实验证明2-萘基重氮盐具有很好的反应活性和选择性总是得到优异的反应结果在此基础上由不同的芳基四氟硼酸重氮盐与芳基硼酸一氧化碳和氨气协同作用以上述含氮杂环卡宾作配体与乙酸钯生成的高活性含氮杂环卡宾钯催化剂催化较高收率地得到了芳基酰胺优化的反应条件是使用2mol的钯-H_2IPr 1五个大气压的一氧化碳以氨气饱和的四氢呋喃作溶剂由不同的有机硼化合物与三种芳基重氮盐的四组份偶联反应同时不仅对生成的多种产物进行了定 L-氮杂环丁烷-2-羧酸L-氮杂环丁烷-2-羧酸又称 S -氮杂环丁烷-2-羧酸简称为L-Aze1955年由Fowden从植物铃兰 Convallaria majalis 中分离得到成为第一个被证实的植物中天然存在的氮杂环丁烷结构作为一种非典型的氨基酸已经发现 S -氮杂环丁烷-2-羧酸可广泛用于对多肽结构的修饰以及诸如不对称的羰基还原Michael 加成环丙烷化和Diels-Alder反应等不对称合成中的多个领域本文通过对 S -氮杂环丁烷-2-羧酸合成路线的研究综述了五种可行的合成路线及方法通过比较选用以L-天冬氨酸为初始原料合成 S -氮杂环丁烷-2-羧酸的路线即通过酯化反应活泼氢保护格氏反应内酰胺化反应还原反应氨基保护氧化反应脱保护等反应来合成 S -氮杂环丁烷-2-羧酸分析了每步反应的机理并对 S -氮杂环丁烷-2-羧酸的应用及前景给予展望通过热分析红外质谱核磁等分析手段对合成的化合物的结构进行表征结果表明所得的产物符合目标产物所合成的化合物的结构性能指标与设计的目标要求一致每步反应的收率都在70％以上可以判定以L-天冬氨酸为初始原料合成 S -氮杂环丁烷的路线方案切实可行。