应用化学专业英语lesson22heattransfer
化工专业英语第三篇翻译

Heat Transfer 传热Heat, as a form of energy, cannot be created or destroyed. Heat can be transferred from one substance to another.热是能量的一种形式,不能创造也不能消灭。
热可以从一个物体传递到另一个物体。
Heat always tends to pass from warmer objects to cooler ones. When a warm substance comes in contact with a cold substance, the molecules of the warm substance collide (碰撞) whth the molecules of the cold substance, giving some of its energy to the cold molecules. This is only one way to transfer heat.热总是倾向于从较热的物体向较冷的物体传递。
当一个暖的物体与一个冷的物体接触时,暖物体的分子与冷物体的分子碰撞,把他们的部分能量传给冷物体的分子。
这仅仅是传递热的一种方式。
In a chemical plant, for example, in a refinery (炼油厂), transfer of heat is very important , the successful operation of most processes is dependent on correct application of the principles (原理) of heat transfer. Where we are handling (处理;加工;操纵) a hot material, we may insulate(隔离,绝缘) the system to hold the heat in; where the material is cold, we insulate to keep the heat out. Efficient equipment, designed to take full advantage of (充分利用) processing heat, is in use on almost all chemical plants.在化工厂,例如一个精炼厂,传热是非常重要的,大多数过程的成功运行取决于传热原理的正确运用。
lesson 22 heat transfer

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• In this type, the hot and cold fluid streams do not come into direct contact with each other. They are separated by a tube wall or flat plate.
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Heat transfer

Lesson 6第 6 课Heat Transfer热量传递Practically事实上、几乎all the operations that are carried out by the chemical engineer involve the production放出or absorption of energy in the form of heat'.1、事实上几乎所有由化学工程师所实施的操作都涉及到以热量形式的能量放出或吸收。
The laws governing the transfer of heat and the types of apparatus设备that for their main object目标the control of heat flow are therefore因此of great importance.2、因此,控制热量传递的相关定律和对于主要目标的热量流动的控制的设备种类就非常的重要When two objects at different temperatures are brought into thermal热的contact接触, heat flows from the object at the higher temperature to that at the lower temperature.3、当两个温度不同的物体相互接触时,热量会从高温物体流向低温物体。
The net flow净流动is -always in the direction方向of the temperature decrease减小2.4、净热流总是沿着温度降低的方向。
The mechanisms原理、机理by which the heat may flow are three: conduction, convection, and radiation.5、根据热量流动的机理不同将其分为三类:热传导、热对流和热辐射。
Unit Four Heat Transfer_石油化工专业英语

4. The rate at which heat flows depends on the amount of temperature difference as well as on the properties of the material through which it has to flow.
radiation n. 辐射 absorption n. 吸收 convert v. (可)转变为,(into)变换,兑换 alter v. 改变 immerse v. 沉浸 coaxial a. 同心的 encounter v. 遇到 concentrically ad. 同心地,同轴地 parallel a. 平行的,并行的,同一方向(目的) 的 cylindrical n.圆柱形的 constrain v. 约束,限制,抑制 zig-zag n. 之字形,Z字形
句中两个 “which” 都引导了定语从句, 介词前置。 译文:热量流动的速率取决于温度差的 大小以及要通过热量的物料的性质5. Βιβλιοθήκη isturbance n. 干扰,扰动
disturb v. 打扰,扰乱,妨害 disturb the peace 扰乱治安
6. by means of 依靠,凭借,通过
9. In radiation, thermal energy is transformed into radiant energy, similar in nature to light.
“in nature” 实际上,本质上 译文:辐射时,热能变为与光的性质相 类似的辐射能。
10. Very commonly in a chemical process, the temperature of a stream of fluid must be altered.
应用化学专业英语考试指南

化学化工基础部分题型和内容:一、词汇(英译汉)10个词语(10分)二、分子式(16*2分)包括常见非金属氧化物、酸、碱、盐、甲烷、乙烷等的英文表达三、英译汉(20分,4段)课文及课后作业四、化学方程式的英文表达(2个方程式、6分)反应类型:中和反应、氨的合成反应、取代反应五、根据课文内容回答问题(一个问题8分)1. characteristics for an ideal refrigerant. 一个理想的制冷剂的特点2. requirements a reaction must satisfy before it can be used in titrimetric analysis?必须满足要求的反应,才能在滴定分析方法3. reactions which can be used in titrimetric analysis.可在滴定分析中使用的反应专业部分:1.词汇(汉译英)10个词语(10分)2.英译汉(28分,4段)3.汉译英(10分,2句)插座socket 指示灯pilot lamp 甲醇methanol 共价键covalent bond稳态steady state反馈系统feedback system 配体ligand1.Figures 1 and 2 show that electrode potentials after 30 minutes immersion in salt solutionscontaining sodium nitrite at 1N and 0.1N levels of concentration, have all moved in the anodic direction as compared to the potentials just after immersion, while in the case of 10-3N concentration of sodium nitrite, this is so only in the case of salt solution containing 200ppm of sodium chloride.图1和图2表明,30分钟后,电极在盐含有亚硝酸钠在1N的和0.1N的解决方案,浸泡的浓度水平的潜力,都搬到了阳极方向,这一比例仅为浸泡后的潜力,而在10例- 3晚亚硝酸钠的浓度,这是所以只有在盐溶液中的氯化钠200ppm的情况下2.For each element an extended table, a reduced table and tables with notes and bibliographyare given. In the extended tables the different electrode-systems are arranged alphabetically according to the right-hand term of the electrode reaction.对于每个元素扩展表,减少表和注释和参考书目表给出。
应用化学专业英语翻译

1 Unit5元素周期表第1段随着我们对原子的描述越来越详尽,我们发现我们陷入了进退两难之境。
有超过100多中元素要处理,我们怎么能记的住所有的信息?有一种方法就是使用元素周期表。
这个周期表包含元素的所有信息。
它记录了元素中所含的质子数和电子数,它能让我们算出大多数元素的同位素的中子数。
它甚至有各个元素原子的电子怎么排列。
最神奇的是,周期表是在人们不知道原子中存在质子、中子和电子的情况下发明的。
第2段在道尔顿提出他的原子模型(原子是是一个不可分割的粒子,其质量决定了它的身份)不久,化学家门开始根据原子的质量将原子列表。
在制定像这些元素表时候,他们观察到在元素中的格局分布。
例如,人们可以清楚的看到在具体间隔的元素有着相似的性质。
在当时知道的大约60种元素中,第二个和第九个表现出相似的性质,第三个和第十个,第四个和第十一个等都具有相似的性质。
第3段在1869年,Dmitri Ivanovich Mendeleev ,一个俄罗斯的化学家,发表了他的元素周期表。
Mendeleev通过考虑原子重量和元素的某些特性的周期性准备了他的周期表。
这些元素的排列顺序先是按原子质量的增加,,一些情况中, Mendeleev把稍微重写的元素放在轻的那个前面.他这样做只是为了同一列中的元素能具有相似的性质.例如,他把碲(原子质量为128)防在碘(原子质量为127)前面因为碲性质上和硫磺和硒相似, 而碘和氯和溴相似.第4段 Mendeleev在他的周期表中留下了一些空白。
他非但没有将那些空白看成是缺憾,反而大胆的预测还存在着仍未被发现的元素。
更进一步,他甚至预测出那些一些缺失元素的性质出来。
在接下来的几年里,随着新元素的发现,里面的许多空格都被填满。
这些性质也和Mendeleev所预测的极为接近。
这巨大创新的预计值导致了Mendeleev的周期表为人们所接受。
第5段我们现在所知道的元素的性质主要取决于元素原子最外层能量能级的电子数。
化学及化工专业英语词汇(H)

化学及化工专业英语词汇(H)h acid h 酸h bomb 氢弹h cell h 电池h theorem h 定理habit 习惯性haem 血红素hafnium 铪hafnium carbide 碳化铪hair crack 毛细裂纹hair hygrometer 毛发湿度计halation 晕影halazone 哈拉宗half bleaching 半漂白half cell 半电池half cell potential 半电池电势half finished product 半制品half finished rubber 未硫化橡胶half life 半裹期half mirror 半透玫half step potential 半波电势half tone 中间色调half wave potential 半波电势halide 卤化物halite 岩盐hall effect 霍耳效应halochromism 加酸显色halochromy 加酸显色haloform 卤仿haloform reaction 卤仿反应halogen 卤素halogenation 卤化halogenide 卤化物halogeno salt 卤代盐halohydrin 卤代醇halometer 盐量计halometry 盐分测定法halt 停止时间hamiltonian function 哈密顿函数hamiltonian operator 哈密顿算符hammer crusher 锤式破碎机hammer mill 锤式破碎机hand filter press 手工压力过滤器hand furnace 人工炉hand mold brick 手工砖hand picked coal 手选碳hand printing 手工印花hank dyeing 纹纱染色hank printing 纹纱印花hansa yellow 汉萨黄hantzsch synthesis 汉栖合成haptoglobin 亲血色蛋白haptophore 附着簇hard acid 硬酸hard base 硬碱hard burned magnesia 硬烧镁氧hard charcoal 白炭hard coal 无烟煤hard coke 焦炭hard detergent 硬性洗涤剂hard glass 硬玻璃hard metal 硬质合金hard pitch 硬沥青hard porcelain 硬质瓷器hard rubber 硬橡胶hard soap 钠皂hard sphere collision theory 刚性球碰撞理论hard water 硬水hardened filter paper 硬滤纸hardened oil 硬化油hardened rosin 硬化松香hardener 硬化剂hardening 硬化hardening bath 硬化浴hardening solution 硬膜液hardening time 硬化时间hardness 硬度hardness gage 硬度计hardness of water 水的硬度hardness scale 硬度计hardness test 硬度试验hardness tester 硬度试验器hardwood 硬材harman 哈尔满hazardous material 危险物head 水头head temperature 纺丝口温度head to head configuration 头对头结构head to tail configuration 头尾结构head velocity 顶端速度healing 加硫hearth 炉床heat 热heat absorber 吸热器heat accumulator 蓄热器heat balance 热平衡heat capacity 热容heat conduction 热传导heat conductivity 导热系数heat consumption 耗热量heat content 热含量heat control 热控制heat convection 热对流heat cure 干热硫化heat curing 热固化heat distortion 热变形heat effect 热效应heat engine 热机heat equivalent 热当量heat exchange 热交换heat exchanger 热交换器heat function 热函heat hardening 加热硬化heat insulating material 绝热材料heat loss 热损失heat medium 传热介质heat of activation 活化热heat of coagulation 凝结热heat of combustion 燃烧热heat of condensation 冷凝热heat of crystallization 结晶热heat of dilution 稀释热heat of dissociation 离解热heat of dissolution 溶解热heat of evaporation 蒸发热heat of explosion 爆炸热heat of formation 生成热heat of fusion 熔化热heat of hydration 水化热heat of immersion 湿化热heat of ionization 电离热heat of neutralization 中和热heat of reaction 反应热heat of solidification 凝固热heat of sublimation 升华热heat of swelling 膨润热heat of transformation 转变热heat of transition 转变热heat of vaporization 蒸发热heat of wetting 湿化热heat pipe 热导管heat pump 热泵heat quantity 热量heat radiation 热辐射heat recovery 热量回收heat resistance 耐热性heat resistant alloy 耐热合金heat resistant polymer 耐热聚合物heat resistant resin 耐热尸heat resisting coating 耐热涂料heat resisting glass 耐热玻璃heat sensitive paint 示温漆heat source 热源heat test 耐热试验heat transfer 热传递heat transfer coefficient 传热系数heat treatment 热处理heater 加热器heating 加热heating area 加热面积heating curve 加热曲线heating element 发热体heating loss 加热减量heating method of microwave furnace 微波炉加热法heating surface 加热面heatronic molding 高频模塑heavy atom method 重原子法heavy chemicals 化工制品heavy ends 重质馏分heavy hydrogen 重氢heavy ion nuclear reaction 重离子核反应heavy liquid 重液heavy metal 重金属heavy naphtha 重石脑油heavy oil 重油heavy oxygen 重氧heavy water 重水hecogenin 海柯皂苷元hehner number 亥讷值hehner value 亥讷值height per transfer unit 每迁移单位高度helical condenser 旋管冷凝器helicin 水杨醛葡糖甙heliotropin 天芥菜精helium 氦helium cooling 氦冷却helleborein 嚏根草毒苷hematein 苏木因hematin 正铁血红素hematite 赤铁矿hematoporphyrin 血卟啉hematoxylin 苏木精heme 血红素heme synthetase 血红素合成酶hemerythrin 血赤藓素hemiacetal 半缩醛hemicellulose 半纤维素hemicolloid 半胶质hemihydrate 半水合物hemiketal 半酮缩醇hemimorphic crystal 异极晶体hemimorphy 异极象hemin 氯化血红素hemipic acid 半蒎酸hemitropy 半体双晶hemocyanin 血蓝蛋白hemoglobin 血红蛋白hemolysin 溶血素hemolysis 溶血酌hemoporphyrin 血紫质hemopyrrole 血吡咯hemp 大麻hempel gas apparatus 汉培尔气体分析器hempseed oil 大麻子油hendecane 十一烷henry's law 享利定律hentriacontane 三十一烷heparin 肝素heptachlor 七氯heptacosane 廿七烷heptadecane 十七烷heptadecanol 十七烷醇heptanal 庚醛heptane 庚烷heptanoic acid 庚酸heptanol 庚醇heptavalence 七价heptene 庚烯heptose 庚糖heptoxide 七氧化物heptyl alcohol 庚醇heptyl aldehyde 庚醛heptylene 庚烯heptylic acid 庚酸herbicide 除草剂heroin 海洛因hesperidin 橙皮苷hess's law 蒜斯定律heteroatom 杂原子heteroauxin 杂茁长素heteroazeotrope 多相非共沸混合物heterocycle 杂环heterocyclic compound 杂环化合物heterogeneity 不均匀性heterogeneous catalyst 非均相催化剂heterogeneous equilibrium 多相平衡heterogeneous polymerization 非均相聚合heterogeneous reaction 多相反应heterogeneous system 非均相体系heteroion 杂离子heterolysis 异种溶解heterolyte 极性分解质heteronuclear 杂核的heteropolar bond 极性结合heteropolar compound 异极化合物heteropolar crystal 异极结晶heteropolarity 异极性heteropoly acid 杂多酸heteropoly compound 杂多化合物heteropolymer 异质共聚物heterotope 异位素heterotopic faces 异序面heterotrophism 营养异常heterotrophy 营养异常hexachlorobenzene 六氯代苯hexachloroethane 六氯乙烷hexacyanoferrate 铁氰化物hexacyanoferric acid 氰亚铁酸hexadecane 十六烷hexadiene 己二烯hexagonal close packed structure 六角密积结构hexagonal system 六方晶系hexahydrobenzyl alcohol 六氢化苯甲醇hexahydrocresol 六氢化甲酚hexahydropyrazine 六氢吡嗪hexahydropyridine 六氢化吡啶hexahydrothymol 六氢化百里酚hexalin 环己醇hexametaphosphate 六偏磷酸盐hexamethylene 环己烷hexamethylenediamine 己撑二胺hexamethylenetetramine 六甲撑四胺hexanal 己醛hexane 己烷hexanediol 己二醇hexanitrodiphenylamine 六硝基二苯胺hexanoic acid 己酸hexanol 正己醇hexene 己烯hexenol 己烯醇hexogen 黑素金炸药hexokinase 己糖激酶hexonic acid 己糖酸hexosan 聚己糖hexose 己糖hexyl acetate 乙酸己酯hexyl alcohol 正己醇hexylaldehyde 己醛hexylene 己烯hexylic acid 己酸hexylresorcin 己基间苯二酚hide powder 皮粉hiding power 遮盖力high alumina refractory 高铝耐火物high boiler 高沸点化合物high boiling phenols 高沸点石炭酸high density lipoprotein 高密度脂蛋白high density polyethylene 高密度聚乙烯high early strength portland cement 高快固波特兰水泥high elasticity 高弹性high explosive 高级炸药high fermentation 上层发酵high fired porcelain 高温焙烧瓷器high flash solvent 高闪点溶剂high frequency 高频high frequency analyzer 高谐波分析器high frequency coating material 高谐波涂料high frequency concentration meter 高频浓度计high frequency furnace 高谐波炉high frequency heating 高频加热high frequency oscillator 高谐波振荡器high frequency polarography 高谐波极谱法high frequency titration 高频滴定high furnace 高炉high gloss 高度光泽high malecular compound 高分子化合物high performance material 高性能材料high polymer 高分子聚合物high polymer chemistry 高分子化学high polymer ion 高分子离子high pressure 高压high pressure chemical industry 高压化学工业high pressure chemistry 高压化学high pressure compressor 高压压缩机high pressure gas 高压气体high pressure gasifier 高压气体发生炉high pressure plant 高压装置high pressure washing 高压冲洗high purity material 高纯度材料high speed flow 高速流high speed steel 高速钢high temperature carbonization 高温干馏high temperature cracking 高温热分解high temperature tar 高温焦油high vacuum 高真空high vacuum insulation 高真空绝缘higher alcohol 高级醇higher calorific 高发热值higher fatty acid 高级脂肪酸higher homologue 高级同系物higher order reaction 高级反应higher oxide 高级氧化物hindrance 阻碍hippuric acid 马尿酸histamine 组胺histidase 组氨酸酶histidine 组氨酸histochemistry 组织化学histogram 柱式图解hofmann degradation 霍夫曼氏分解hofmann reaction 霍夫曼反应hofmann rearrangement 霍夫曼重排hold up 滞留量hollow article 空心制品hollow brick 空心砖hollow rayon 空心人造丝hollow space radiation 空心辐射holmium 钬holmium chloride 氯化钬holmium hydroxide 氢氧化钬holmium nitrate 硝酸钬holmium oxide 氧化钬holoenzyme 全酶holography 全息照相holohedral form 全面体holohedry 全面体holohyaline 全玻璃质的holomorphic function 全纯函数holosymmetry 全面对称homatropine 后马托品homeomorphism 异质同晶homeopolar compound 无极化合物homochemical compound 二原子化合物homochromic isomer 同色异构体homocycle 同素环homocyclic compound 同素环化合物homogeneity 均一性homogeneous catalysis 均相催化酌homogeneous equilibrium 均相平衡homogeneous ion exchange membrane 均一离子交换膜homogeneous precipitation 均匀沉淀homogeneous reaction 均匀反应homogeneous system 均匀系homogenization of glass 玻璃均化homogenizer 均化器homogentisase 尿黑酶homogentisic acid 尿黑酸homologation 同素化homologous series 同系列homologue 同系物homology 同系现象homolysis 均裂homolytic reaction 均裂反应homophthalic acid 高邻苯二酸homopolar bond 同极键homopolar colloid 同极胶体homopolar compound 同无极化合物homopolymer 均聚物homopolymerization 均聚合homosteroid 高甾类homotropine 升马托品homozeotrope 均匀非共沸混合物hondrometer 粒度计hop 酒花hop resin 酒花尸hopper 料箱漏斗hordenine 大麦芽碱horizontal axis 水平轴horizontal dispersion 水平分散horizontal section 水平断面horizontal tube evaporator 水平管蒸发器hormone 激素horn substitute 角质物horse power 马力hot air cure 热空气硫化hot air sterilizer 干热灭菌器hot air vulcanization 热空气硫化hot atom chemistry 热原子化学hot bath 热浴hot blast 热风hot cure 热硫化hot filter 保温漏斗hot funnel 保温漏斗hot melt adhesive 热熔性胶粘剂hot plate 热板hot press 热压hot setting adhesive 热固胶粘剂hot shortness 热脆性hot strength 热强度hot vulcanization 热硫化hot wire anemometer 热线风速计hot working 热加工household soap 家用皂humectant 湿润剂humic acid 腐殖酸humidification 湿润humidifier 增湿器humidity 湿度humidity drier 可控湿度干燥器humification 腐殖质化humin 腐黑物humulene 蛇麻烯humus 腐殖质hyaluronic acid 透檬酸hyaluronidase 玻璃酸酶hybridization 杂化hybridized orbital 杂化轨道hydantoic acid 海因酸hydantoin 海因hydnocarpus oil 大风子油hydracrylic acid 羟基丙酸hydrargillite 水铝矿hydrastine 白毛莨碱hydrate 水化物hydrated alumina 水合氧化铝hydrated cellulose 水合纤维素hydrated electron 水合电子hydration 水合酌hydration energy 水合能hydrator 水化器hydraulic cement 水硬水泥hydraulic classification 水力离析hydraulic classifier 水力分粒机hydraulic extruder 液压式压出机hydraulic index 水硬系数hydraulic lime 水硬石灰hydraulic module 水硬系数hydraulic modulus 水硬系数hydraulic press 水压机hydraulic radius 水力半径hydraulic separation 水力离析hydraulic test 水力试验hydraulicity 水凝性hydrazine 肼hydrazine sulfate 硫酸肼hydrazinium 肼hydrazo compound 肼基化合物hydrazobenzene 肼撑苯hydrazoic acid 叠氮酸hydrazone 腙hydride 氢化物hydrido complex 氢化络合物hydrizing 氢化酌hydroaromatic hydrocarbon 氢化芳族碳氢化合物hydrobromic acid 氢溴酸hydrocarbon 碳氢化合物hydrocarbons of acetylene series 炔系碳氢化合物hydrocellulose 水合纤维素hydrochloric acid 氢氯酸hydrochloride 盐酸盐hydrochlorination 氯氢化反应hydrocooling 用水冷却hydrocortisone 氢化可的松hydrocracking 加氢裂化法hydrocyclon 水力旋林离器hydrocyclone 水力旋流hydrodealkylation 加氢脱烃酌;加氢脱烷基化hydrodesulfurization 加氢脱硫法;加氢脱硫酌hydrodynamic diameter 铃动力直径hydrodynamics 铃力学hydroextractor 脱水器hydrofining 加氢精制hydrofinishing 氢化精制hydrofluoric acid 氢氟酸hydroforming 临氢重整hydroformylation 烯烃醛化hydrogel 水凝胶hydrogen 氢hydrogen acceptor 受氢体hydrogen arsenide 砷化氢hydrogen bond 氢键hydrogen bromide 溴化氢hydrogen carrier 氢载体hydrogen chloride 氯化氢hydrogen cooling 氢冷却hydrogen cyanide 氰化氢hydrogen donor 氢供体hydrogen electrode 氢电极hydrogen embrittlement 氢脆性hydrogen exponent 氢指数hydrogen halide 卤化氢hydrogen iodide 碘化氢hydrogen ion 氢离子hydrogen ion concentration 氢离子浓度hydrogen peroxide 过氧化氢hydrogen polysulfide 多硫化氢hydrogen salt 氢盐hydrogen storing alloy 氢贮藏合金hydrogen sulfide 硫化氢hydrogen value 氢值hydrogenated fat 氢化脂hydrogenated oil 氢化油hydrogenation 氢化hydrogenolysis 加氢裂化法hydrogenous 富氢的hydroiodic acid 氢碘酸hydrolase 水解酶hydrolysis 水解hydrolysis constant 水解常数hydrolyte 水解质hydrolytic acidity 水解酸性hydrolytic adsorption 水解吸附hydrolytic dissociation 水解离解hydrolytic enzyme 水解酵素hydrolyzate 水解产物hydromechanics 铃力学hydrometallurgy 湿法冶金hydrometer 比重计hydron blue 海昌蓝hydronium ion 水合氢离子hydroperoxide 氢过氧化物hydrophile lipophile balance 亲水亲油平衡hydrophilic 亲水的hydrophilic colloid 亲水胶体hydrophilic group 亲水基团hydrophilization 亲水化hydrophily 亲水性hydrophobic 疏水的hydrophobic bond 疏水键合hydrophobic colloid 疏水胶体hydrophobic group 疏水基hydrophobic hydration 疏水性水合hydrophobic interaction 疏水性相互酌hydrophobing 疏水酌hydrophobization 疏水化hydroquinone 氢醌hydroquinone dimethyl ether 对苯二酚二甲醚hydrosilicate 含水硅酸盐hydrosilylation 氢化硅烷化hydrosol 水溶胶hydrostatic head 静水压头hydrosulfide 氢硫化物hydrothermal crystal growth 热液晶体生长hydrothermal synthesis 热液合成法hydrotimeter 水硬度计hydrotimetry 水硬度测量术hydrotropy 助溶性hydrous 含水的hydroxamic acid 氧肟酸hydroxide 氢氧化物hydroxy acid 羟基烃酸hydroxy compound 羟基化合物hydroxy fatty acid 羟基脂肪酸hydroxyaldehyde 羟醛hydroxyalkanoic acid 羟基烃酸hydroxyamino acid 羟基氨基酸hydroxybenzoic acid 羟基苯酸hydroxycarboxylic acid 羟基烃酸hydroxyketone 羟基酮hydroxyl ion 羟离子hydroxyl value 羟值hydroxylamine 羟胺hydroxylamine hydrochloride 盐酸羟胺hydroxylation 羟基化hydroxyproline 羟基脯氨酸hydroxyquinoline 羟基喹啉hydroxysalt 羟盐hydroxysuccinic acid 苹果酸hydrozincite 水锌矿hygrograph 自记湿度计hygrometer 湿度计hygrometry 测湿法hygroscopic 吸湿的hygroscopic depression 吸湿性降低hygroscopic equilibrium 吸着水平衡hygroscopic moisture 湿存水hygroscopicity 吸湿性hygrostat 恒湿器hymecromone 羟甲香豆素hyoscyamine 天仙子胺hyperbolic function 双曲线函数hyperchrome 增色团hyperchromic effect 增色效应hyperchromicity 增色性hyperconjugation 超共轭hyperfine structure 超精细结构hyperfine structure of spectral line 光谱线超精细结构hypergol 自燃火箭燃料hyperoxide 过氧化物hypersensitization 超增感hypertonic solution 高渗溶液hypnotoxin 催眼毒素hypoboric acid 连二硼酸hypochlorite 次氯酸盐hypochlorite titration 次氯酸盐滴定hypochlorous acid 次氯酸hypochlorous acid anhydride 次氯酸酐hypochromic effect 浅色效应hypochromicity 减色性hypoiodite 次碘酸盐hypometamorphism 亚变质酌hyponitric acid 过氧化氮hyponitrous acid 连二次硝酸hypothesis 假说hypotonic solution 低渗压溶液hypsochromic effect 色光变浅效应hysteresis 滞后hysteresis loss 滞后损失hysterocrystallization 次生结晶酌。
应用化学专业英语课后答案和课文翻译

U n i t1T h e R o o t s o f C h e m i s t r yI. Comprehension.2. B3. D4. C5. BII. Make a sentence out of each item by rearranging the words in brackets.1.The purification of an organic compound is usually a matter ofconsiderable difficulty, and it is necessary to employ various methods for this purpose.2.Science is an ever-increasing body of accumulated and systematizedknowledge and is also an activity by which knowledge is generated.3.Life, after all, is only chemistry, in fact, a small example of chemistryobserved on a single mundane planet.4.People are made of molecules; some of the molecules in people are rathersimple whereas others are highly complex.5.Chemistry is ever present in our lives from birth to death because withoutchemistry there is neither life nor death.6.Mathematics appears to be almost as humankind and also permeates allaspects of human life, although many of us are not fully aware of this. III. Translation.1. a chemical process b natural science c the technique of distillation2.It is the atoms that make up iron, water, oxygen and the like/and so on/andso forth/and otherwise.3.Chemistry has a very long history, in fact, human activity in chemistrygoes back to prerecorded times/predating recorded times.4.According to/From the evaporation of water, people know/realized thatliquids can turn/be/change into gases under certainconditions/circumstance/environment.5.You must know the properties of the material before you use it.IV. Translation化学是三种基础自然科学之一,另外两种是物理和生物;自从宇宙大爆炸以来,化学过程持续进行,甚至地球上生命的出现可能也是化学过程的结果;人们也许认为生命是三步进化的最终结果,第一步非常快,其余两步相当慢;这三步是:I物理进化化学元素的产生,II化学进化分子和生物分子的形成;和III生物进化有机物的形成和发展;V. Solution:1The relative mass of 1H and 12C atoms can be calculated from their absolute masses in grams.If the mass of a 12C atom is exactly 12 amu,then the mass of a 1H atom to five significant figures must be amu.12 amu x = amu2First we calculate k and then use the first-order rate equation.The bone was tossed away more precisely, the animal whose bone was died about 6100 years ago, or about 4100 . We can thus be sure that a village was in existence at that place at that time.Unit 7 The Nomenclature of Inorganic SubstancesI. ComprehensionII. Give the systematic name for the followingammonium ion ; copperII ion ; strontium ion;CcopperI ion; ironII ion; zinc ion;hydrogen ion; leadII ion; aluminum;silver ion; magnesium ion; chromiumIII ion;Barium ; ManganeseII ion; ironIII ion;calcium ion; mercuryII ion;chromiumII ion; tinII ion.carbon monoxide; ditrogen trioxide;carbon dioxide; diphosphorus pentoxide;sulfur trioxide; dichlorine heptoxidearsenate ion; sulfite ion; hydride ion;arsenite ion; bromide ion; hydroxide ion;phosphate ion; chlorate ion; hypochlorite ion;phosphate ion; chloride ion; iodate ion;carbonate ion; chlorite ion; nitrate ion;chromate ion; cyanide ion; iodide ion;dichromate ion; fluoride ion; nitrate ion;oxide ion; hydrogen carbonate ion; nitrite ion;sulfide ion; hydrogen sulfate ion; perchlorate ion;sulfate ion; hydrogen sulfite ion; permanganate ion.name of the acid ion negative ion. Use the rule to give the name of theof the sentence.altered; illustrate expect cancel6. are pulled on ; referred discussedVI. Translation1. Matter can neither be created nor be destroyed/eliminated.2. It is necessary that a scientist must know how to use fingures to get an accutate answer to question.3. Any substance is made of atoms whether it is solid, liquid or gas.4. The experiment was successful. It’s results was the same as what we had expected.5. It will not be long before we finish the experiment.VII. Write equations for the following acid-base reactions. Use the information in inorganic textbook to predict whether the equilibrium will favor the reactants or the products. Partially SolvedSolutin to a: Cyanide is the conjugate base of HCN. It can accept a proton from formic acid:Reading from inorganic textbook, formic acid p K a= is a stronger acid than HCN p K a=, and cyanide is a stronger base than formate. The products weaker acid and base are favored.…………..VIII. Write equations for the net reactions which occur when the following materials are added to a sodium-ammonia solution.Answer: 1 2CH3GeH3+ 2eam-→ H2+ 2CH3GeH2-2 I2 + 2eam-→ 2I-3 C2H52S + 2eam- + NH3→ C2H5S- + C2H6+ NH2-Unit 10 Nomenclature of HydrocarbonsI. ComprehensionV. Each of the following names is incorrect. Draw the structure represented by the incorrect name or a consistent structure if the name is ambiguous, and give your drawing the correct name.…………Unit 11 Carboxylic Acids and Their DerivativesI. ComprehensionII. Fill in the blanks with the phrases given below.out or so; put together made of ;divided by different from the contrary; consist of up for as ; dependent on down intoIII. Put in proper prepositions or adverbs into the blanks.; asIV. Translation1. Similarly, solvent also may not be liquid matter but the others2. A graph plotting solubility against temperature is called a solubility curve.The curve plot drawn made / produced by solubility as one coordinate and temperature as another coordinate is called solubility curve.3. Air is mixture of gases , the most abundant of which is nitrogen in themolecules.form of N24. The direction of the reaction and the position of the equilibrium may also be affected by the temperature, pressure, and other conditions.5. Hydrogen has a great affinity for oxygen and easily combines with it to form water.V. Translation玻意尔Bohr模型提出不久后,人们就发现原子中的电子比Bohr提出的模型要复杂得多;实验证实电子既有粒子的性质质量也有光的特性波的特性;因为它的两重性,电子不能被看作是在确定范围内绕核旋转的一种简单粒子,而且如Bohr所说的,如果电子高速运动,我们就不能确切地知道它的位置;Unit 13 Ultraviolet and Visible Molecular SpectroscopyI. ComprehensionII. Fill in the blanksof; as; in; out; In; for; for ; of; in; then; to; for;sincefor ; into. III. Fill the blank in each sentence with an appropriate phrase in its proper form.1. account for part in of ….as compared with5. is attached to the contrary in the case of contrast with as against 9. owing to for.Unit 17 CrystallisationI. ComprehensionII. Fill in the blanks with the proper word given below.Stage; interna; symmetrical; basis; physical; Furthermore; composed; responsible; reasonable; overall.III. Choose the item from 1 ~ 6 that best matches the item ina ~ f to makea correct sentence.1~a; 2~b; 3~c; 4~d; 5~e; 6~fthe following into Chinese共沸物;类质同晶;过饱和;砷酸盐;晶核;异丙基;醇;钠;硫酸盐;间甲酚;糖膏;十水合物;结晶质的;同系物;衍生物;结晶;四硼酸盐;盐析;乙基乙酰苯胺;矿物油;Uint18 DistillationI. Comprehension4. AII. Fill in the blanks with the phrases given below.order to relation to 3. in the case of the end5. in a number of to messy way掌握以下词汇:flashdistillation闪蒸 ;exit stream出流 ;e quilibrium curve 平衡曲线; weir堰; redistillation 重蒸; apparatus 设备;overhead product塔顶产物; enthalpy焓; intersection 交点; auxiliary辅助装置; rectifying section精馏段 ;reflux回流; reboller 再沸器; stripping section 汽提提馏段;bottom product 塔底产物Unit 21 catalysisI. Comprehension4. BIV. Translate the following sentences into English1 We define activity as size measure of catalysis of catalyst2 catalytic reaction may be carried out in different phases, of which mechanisms are generally consistent3 Enzymes are the most efficient proteinsin the human body which accelerate the metabolism of the human body.V. Translate the following into Englishreaction equilibrium; repetitiveness; elementary reaction step; stability; catalytic cycle; activity; quantitative analysis; selectivity;metabolic reaction; chemical energy; reaction mechanism; polymer nylonor nylon;qualitative analysis; molecular-sieve; tubular reactor; inhibitor; stoichiometry.Unit 22 Cosmetics introductionI. Comprehension4. D5. 1True; 2True; 3 False.II. Fill in the blanks with the proper word given below.Focused on; considerations; particular; boosting; price; affect; commitment;different; proposed.III. Put in proper prepositions or adverbs into the blanks.1. for, of;2. to;3. for4. forto5. of ,about.V、Translate the following into English.对亚苯基二胺,降解,丙烯,头皮屑,洗剂, N-亚硝基二乙醇胺,致癌的, 未成熟or早熟,香波or洗发剂, 激素荷尔蒙, 防汗剂, 诱变性, 脱臭剂芳香剂, 推论必然结果, 甘油VI、Translate the following sentences into Englishsurfactant;environmental pollution;emulsifier;side-effect;dirt;detergent; perspiration;preservative.PART TWO THE FUNDATIONS OF CHEMISTRYUnit7Chemical Bonds化学键There are approximately 100 chemical elements.世界上大概有100种元素;There are millions of chemical compound, and about 600000 new compounds are prepared every year.现有数百万种化合物,而且每年有60万种新化合物被合成出来;To form these compounds, atoms of different elements must be held together in specific combinations.be held togetherin specific combinations 以特定的方式为了合成这些化合物,不同种类的原子必须以特定方式结合在一起;Chemical bonds are the forces that maintain these arrangements.That引导定语从句,修饰forces化学键是保持这种结合状态的力;Chemical bonding also plays a role in determining the state of matter.plays a role 起作用化学键同时在决定物质状态方面也起作用;At room temperature, water is a liquid, carbon dioxide is a gas, and table salt is a solid because of differences in chemical bonding.在室温下,水是液体,二氧化碳是气体,晶体盐是固体,是由于化学键的不同;As scientists developed an understanding of the nature of chemical bonding, they gained the ability to manipulate the structure of compounds.As引导原因状语从句to manipulate the structure of compounds不定式短语做宾补随着化学家对化学键认识的发展,他们获得了控制化合物结构的能力;Dynamite, birth control pills, synthetic fibers, and a thousand other products were fashioned in chemical laboratories and have dramatically changed the way we live.炸药、避孕药、合成纤维,和数以千计的其他产品在实验室中被合成出来,并且魔术般的改变了我们的生活;We are now entering an era that promises some would say forebodes even greater change.我们现在进入了一个可望或者说预言更大变化的时代;The DNA molecular——the chemical basis of heredity—— carries its genetic message in its bonds in DNA.分子DNA——遗传物质的基础——以它的键传递遗传信息;Whether an organism is fish, fowl, hippopotamus, or human is determined by the arrangement of bonds in DNA.Whether an organism is fish, fowl, hippopotamus, or human 做主语无论一个生物体是鱼、家禽、河马还是人,都是由于DNA的键的组合方式决定的;Scientists already have the ability to rearrange these bonds, and this ability has given them limited control over the structure of living matter.Them, limited control over the structure of living matter 双宾语科学家已经获得了重组这些键的能力,而这种能力给了他们有限的对生物体结构的控制;As techniques of genetic engineering improve, scientists may literally be able to custom-tailor genes.随着基因工程的发展,科学家们将最终设计出符合条件的基因;Let us begin our consideration of chemical bonding so that we, too, can understand the forces that control the structure of matter, living and nonliving.That引导定语从句修饰forces,living and nonliving,动名词,matter得同位语,修饰matter 让我们开始对化学键的论述,并由此理解控制物质,包括有生命体和无生命体,的结构的力;Ionic Bond 离子键Let us look at an atom of the element sodium Na.我们看一下钠原子;It has 11 electrons, of which two are in the first energy level, eight in the second, and one in the third.the first energy level第一能级the second energy level第二能级the third energy level第三能级It has 11 electrons, of which two are in the first energy level, eight are in the second energy level, and one is in the third energy level.它有11个电子,其中2个电子在第一能级,8个电子在第二能级,1个电子在第三能级;If the sodium atom could get rid of an electron, then the product, called a sodium ion, would have the same electron structure as an atom of the noble gas neon Ne.called a sodium ion分词短语做非限定,修饰productnoble gas如果钠原子能够失去1个电子,产物称为钠离子,就和惰性气体氖Ne具有相同的电子结构;Let us immediately emphasize that the sodium ion Na+ and neon atom Ne are not identical.让我们首先强调一下,钠离子Na+和氖原子Ne并不相同;The electron arrangement is the same, but the nuclei——and resulting charges—— are not.electron arrangement 电子排布resulting charges最终电荷电子排布是相同的,而核及最终电荷是不同的;As long as sodium keeps its 11 protons, it is still a form of sodium, but it is the sodium ion, not the sodium atom.只要钠带有11个质子,它就一直是钠,但它是钠离子而不是钠原子;Ions are charged particles, particles in which the number of electrons does not equal the number of protons.in which 引导非限定定语从句;离子是一种带电粒子,一种电子数不等于质子数的粒子;Positively charged ions are called cations pronounced “cat-ions”. The sodium ion is a cation.带正电荷的粒子称为阳离子音为阳-离子;钠离子是阳离子;If a chlorine atom Cl could gain an electron, it would have the same electron structure as the noble gas argon Ar.如果氯原子Cl能够得到一个电子,它将与惰性气体氩Ar具有相同的电子结构;The chlorine atom, having gained an electron, becomes negatively charged. It has 17 protons 17+ and 18 electrons 18-. It is written Cl- and it called a chloride ion.having gained an electron动名词形式做定语,修饰chlorine atom获得一个电子的氯原子带有负电荷;它具有17个质子17+和18个电子18-,写作Cl-,称为氯离子;Negatively charged ions are called anions pronounced “ann-ions”. The chloride ion is an anion.带负电荷的粒子称为阴离子音为阴-离子;钠离子是阴离子;A sodium forms a less reactive species, a sodium ion, by losing an electron.a less reactive species, a sodium ion同位语钠原子通过失去一个电子形成不活泼的钠离子;A chlorine atom becomes a less reactive chloride ion by gaining an electron.氯原子通过得到一个电子形成不活泼的氯原子;A chlorine atom cannot just pluck an electron from empty space, nor can a sodium atom kick out an electron unless something else is willing to take it on.empty space 空白空间、真空空间,意为“凭空”、“无根据”nor作连词,与助动词和情态动词连用,句中主语与动词倒置;He can’t see, nor could he hear until a month ago. 他现在看不见,一个月之前他还听不见;She isn’t rich, nor do I image that she ever will be. 她现在不富,我看她将来也富不了;kick out 逐出、解雇、开除;意为“失去”They kicked him out of the club for fighting.他因为斗殴而被开除出俱乐部;something else 别的东西take … on 接纳、承受氯原子不能凭空获得一个电子,而钠原子也不能凭空失去一个电子,除非别的东西愿接受电子;What happens when sodium come into contact with chlorine The obvious. A chlorine atom removes an electron from a sodium atom.come into contact 接触、相遇The obvious 显而易见的当钠与氯接触时发现了什么很明显,氯原子从钠原子处拿走了一个电子;The sodium ion and the chloride ion have electron arrangement s electron configurations like those of two noble gases neon and argon, respectively.electron arrangement电子排布electron configurations电子结构钠离子和氯离子的电子排布电子结构就象两个惰性气体氖和氩,相应的一样;Not only do the ions have stable octets of electrons, they also have opposite charges.它们具有稳定的电子八耦体结构,而且有相反的电荷;Everyone knows that opposites attract.每个人都知道异性相吸;While this rule of thumb may not always work when applied to people, it works quite well for cations and anions.rule of thumb单凭经验来做的方法,比较粗糙的方法,约略得衡量或估计虽然这种经验对人未必适用,但对阴阳离子是非常适用的;The attractive force between oppositely charged ions is called an ionic bond, and the combination of sodium ions and chloride ions is the compound sodium chloride or table salt.相反电荷之间的吸引力称为离子键,钠离子和氯离子结合为化合物氯化钠和食盐;Covalent Bonds共价键One might expect a hydrogen atom, with its one electron, to acquire another electron and assume the helium configuration.to acquire another electron and to assume the helium configuration不定式做宾补人们也许希望带有一个电子的氢原子,获得另一个电子并呈现氦的结构;Indeed, hydrogen atom do just that in the presence of atoms of a reactive metal such as lithium, that is, a metal that finds it easy to give up an electron.do代替上句, just that引导条件状语reactive metal活泼金属that is 插入语,也就是说a metal,reactive metal的同位语,that引导定语从句修饰a metal实际上,氢原子只有在活泼金属如锂的存在下确实发生了这样的反应,活泼金属就是很容易失去电子的金属;But what if there are no other kinds of atoms around但是,如果周围没有其他种类的原子呢What if there are only hydrogen atoms as in a sample of the pure element如果只有氢原子作为纯元素样品呢One hydrogen atoms can scarcely grab an electrons from another, for among hydrogen atoms all have equal attraction for electrons Even more important, perhaps, hydrogen atoms do not have a tendency to lose electrons at all, for the result would be a highly reactive bare proton—— the hydrogen nucleus.Even more important更重要的一个氢原子几乎不能从另一个氢原子处获取电子,因为氢原子具有相同的电子吸引力更重要的,可能是,氢原子没有失去电子的倾向,因为那样的结果是生成高度活泼的裸露质子——氢原子核;Still—— hydrogen wants a duet of electrons like helium’s.而且——氢原子希望象氦原子那样拥有2个电子;If one hydrogen cannot capture another’s electron, the two atoms can compromise by sharing their electrons.如果一个氢原子不能获取另一个氢原子的电子,这两个原子则通过共用电子的方式解决;It is as if the two hydrogen atoms, in approaching one another, get their electron clouds or orbitals so thoroughly enmeshed that they cannot easily pull them apart again.in approaching one another 做插入语as if与as though 用法相同,意为:宛如、仿佛、好像;as if 后面常用过去时表示现在,说明所作的比较“不是真的”;You look as if you’d seen a ghost.在非正式文体中,常用like代替as if; He sat there smiling like it was his birthday.就好像两个氢原子,当它们互相接近时,其电子云充分重叠,以至于难于再分开;Moat of the time the electrons are located between the two nuclei.大部分时间电子位于两个原子之间;The electron-dot formula usually used, H:H, is therefore a fairly good picture If we were to attribute human qualities to hydrogen atoms, we would suggest that they are a bit nearsighted. Each one look s around, see s two electrons, and decide s that these electrons are its very own and that therefore it has as arrangement like that of helium, one of the noble gases.electron-dot formula 电子式noble gase惰性气体经常用电子式H:H表示,这是一个很好的画面如果我们以人的品性归于氢原子,我们说它们有些目光短浅;每个氢原子看看周围,看到两个电子,就认为这些电子是自己的,它们就有了象惰性气体氦那样的电子排布;This combination of hydrogen atoms is called a hydrogen molecule.这种氢原子化合物叫氢分子;Molecules are discrete groups of atoms held together by shared pairs of electrons. The bond formed by a shared pair of electrons is called a covenlent bond.分子是通过共用电子对将两个分离的原子结合在一起;通过共用电子对形成的键称为共价键;A chlorine atom will pick up an extra electron from anything willing to give one up.氯原子可以从任何愿意失去一个电子的原子处得到一个电子;But, again, what if the only thing around is another chlorine atom但是,如果周围只有另一个氯原子又会怎样Chlorine atoms, too, can attain a more stable arrangement by sharing a pair of electrons.氯原子同样也是通过共用电子对达到稳定结构;Each chlorine atom in the chlorine molecule counts eight electrons around itself and concludes that it has an arrangement like that of the noble gas argon.that it has an arrangement like that of the noble gas argon.宾语从句氯分子中每个氯原子周围都有8个电子,并且可以断定它具有惰性气体氩一样的排布;The shared pair of electrons in the chlorine molecule also creates a covalent bond.氯分子中共用的一对电子同样形成共价键;For simplicity, the hydrogen molecule is often represented as H2 and the chlorine molecule as Cl2.the chlorine molecule as Cl2:the chlorine molecule is often represented as Cl2为了简化,氢分子常写成H2,氯分子常写成Cl2;The subscripts indicate two atoms per molecule.这个下标表示每个分子中有2个原子;In each case, the covalent bond between the atoms is understood. Sometimes the covalent bond is indicated by a dash, H-H and Cl-Cl.在每种情况下,原子之间的共价键都可以理解,有时共价键也用一个短线表示H-H和Cl-Cl;:Let us be sure we understand the meaning of numbers in formulas.让我们确信我们理解公式中数字的意义;Take a moment to establish in your mind the difference among the following: H,H2,2H,2 H2,H2O,2 H2O.花点时间来搞清楚下面数字的不同:H,H2,2H,2 H2,H2O,2 H2O;Is it clear to you that although H represents a single atom of hydrogen, H2implies two atoms of H bonded together, whereas 2H represents two separate, free, and independent atoms of H That引导实际主语你是否明白H代表分离的氢原子,H2代表两个H结合而成的氢分子,而2H代表分离的、自由的、孤立的氢原子吗On the other hand, the meaning of H2 in H2O is totally different from that of H2 as a molecule.另一方面, H2在H2O中的意思与作为一种分子的H2完全不同;In H2O it means that two atoms of H are individually attached to Onot to themselves to form a molecule of water.在 H2O中表示两个H分别吸引O而不是它们自己来形成一个水分子;Finally, 2 H2O simply refers to two individual molecules of water.最后,2 H2O代表两个独立的水分子;Covalent bonds are not limited to the sharing of one pairof electrons. Consider, for example, the nitrogen atom. Its electron-dot symbol is :N .....共价键不限于分享一对电子;例如,对于氮原子;它的电子式是:N ..... Now, after all we have learned about the octet rule we knowthat this electron arrangement is not complete.octet rule 八耦体规则现在,我们学习了八耦体规则;我们知道这个电子排布是不饱和的;It has only five electrons in its outermost energy level .outermost energy level 外层电子能级在它的外层电子能级上只有5个电子;It could shared a pair of electrons with another nitrogen atom and would then look like this :N ...:::N . 它可以与另一个氮原子共用一对电子而变成如下形式:N ...:::N .The situation has not improved a great deal.情况并没有发生太大变化;Each nitrogen atom in this arrangement has only sixelectrons surrouding it not eight.每个氮原子周围电子排布只有6个电子不是8个;Each nitrogen atom has two electrons hanging out therewithout partners, so, to solve the dilemma, each nitrogen atomshares two additional pairs of electrons, for a total of three pairs.hanging out把…伸出、挂出,上身伸出窗外,闲荡每个氮原子都有两个未成对电子,所以,为了解决这一矛盾,每个氮原子共用另外两对电子,共3对电子In drawing the nitrogen molecule N2, we have placed all the electrons being shared by the two atoms in the space between the two atoms.being shared by the two atoms分词短语做定语写氮分子N2时,我们把两个原子的所有的共用电子都写在两个原子中间;Each nitrogen atom has now satisfied the octet rule.每个氮原子都满足了八耦体规则;A molecule in which three pairs of electrons a total of six individual electron are being shared is said to contain a triple bond.in which three pairs of electrons a total of six individual electron are being shared定语从句triple bond三键一个分子共享三对电子共6个单个电子被称为含有三键;Each nitrogen atom also has an unshared pair of electrons.每个氮原子还含有一对孤对电子;Note that we could have drawn the unshared pair of electrons above or below the atomic symbol.atomic symbol 元素符号注意我们可以把孤对电子写在元素符号的上方或下方;Such a drawing would represent the same molecule.这些写法代表相同的分子;Polar Covalent Bonds 极性共价键So far we have seen that atoms combine in two different ways.So far迄今为止,就此范围或程度说来迄今为止,我们看到了两种不同的原子结合方式;Some that are quite different in electron structure from the opposite ends of the periodic table react by the complete transfer of one or more electrons from one atom to another ionic bond formation.from the opposite ends of the periodic table周期表相对的两端句子结构:some……react by……Transfer 名词那些原子结构截然不同周期表左右两端的原子,一个将一个或数个电子由一个原子完全传递到另一个原子的方式反应离子键形成;Atoms that are identical combine by sharing one or more pairs of electrons covalent bond formation.相同的原子通过共用一对或多对电子共价键形成而结合;Now let us look at some “in-betweeners”.现在让我们看一下“居于中间者”;Hydrogen and chlorine react to form a colorless, toxic gas called hydrogen chloride.hydrogen chloride 氯化氢氢与氯反应生成一种无色、有毒的气体氯化氢;This reaction can be represented schematically by这个反应可由下式表示:H + Cl → HCl 或H-ClBoth the hydrogen atom and the chlorine atom want an electron, so they compromise by sharing and form a covalent bond.氢原子和氯原子都想得到一个电子,所以它们通过共用电子对结合并形成共价键;Since the substances hydrogen and chlorine actually consist of diatomic molecules rather than single atoms, the reaction is more accurately represented by the scheme.diatomic molecules 二原子分子由于氢和氯实际上是二原子分子而不是单个原子,反应写成下式更准确This can be more simply written as简写为H2+ Cl2→ 2HClOne might reasonably ask why the hydrogen molecule and the chlorine molecule react at all.有人也许会问为什么氢分子和氯分子能够完全反应;Have we not just explained that they themselves were formed provide a more stable arrangement of electrons宾语我们不是已经解释了它们本身形成了相对稳定的电子排布了吗Yes, indeed, we say that. But there is stable and there is more stable.是的,我们说过这些,但这有稳定和更稳定;The chlorine molecule represents a more stable arrangement than separate chlorine atoms, but, given the opportunity, a chlorine atom would rather bond to hydrogen thanbond to another chlorine atom.would rather……than含有选择得意思,“宁可……而不……”would rather与than后面为平行结构氯分子代表着比单独的氯原子更稳定的排列,但是,若有机会,氯原子宁可与氢成键而不愿与另一个氯成键;In a molecule of hydrogen chloride, a chlorine atom shares a pair of electrons with a hydrogen atom.在氯化氢分子中,氯原子和氢原子共用一对电子;In this case, and in others we shall consider, sharing does not mean sharing equally.在这种情况下,以及我们能想到的其他情况,共用并不意味着完全分享;Some atoms within molecules attract electrons more strongly than do other atoms.分子中一些原子吸引电子的能力比其他原子强;The term electronegativity is used to describe the affinity of an element in a molecule for electrons.电负性是用来描述分子中原子的亲和力的;The higher the electronegativity, the more strongly the atoms of an element attract electrons to themselves.电负性越大,原子吸引电子的能力越强;The most electronegativity element is fluorine, which is located in the upper right corner of the periodic table.电负性最大的元素是氟,它处于元素周期表的右上角;The electronegativity of elements decreases as one moves away from fluorine in the periodic table.在周期表中,离氟越远,元素的电负性越弱;Thus electronegativity decreases as one moves down a group column or left across a period row.down a group column 由族列向下left across a period row 由周期行向左所以,由族列向下或由周期行向左,电负性减弱;I. Comprehension1. What is the main idea of the paragraph AA. There are so many kinds of chemical bonds.B. How does the ionic bond come into being.C. The noble gases are stable.D. Can sodium atoms and chlorine atoms react with each otherto form a stable arrangement of electrons.2. What is the author’s meaning by saying “even atoms havetheir own standards of beauty” BA. Atoms can detect whether an electron arrangement isbeautiful or not.B. There are standards or rules that can determine if an electron arrangement is favored or not.C. Atoms are more favored a beautiful electron arrangementthan an ugly one.D. We can beautify atoms by their standards.3. What’s “the standards of beauty” of atoms CA. An octet eight outer electrons.B. A duet two outer electrons.C. A and B.D. There is no such standards.4. Are the sodium ion Na+and the neon atom Ne identical EA. Yes, they have same electron numbers.B. Yes, they have same electron arrangement.C. No, sodium ion is still a form of sodium, not atom but cations.D. No, sodium ion is a charged particle, while the neon atomis a neutral one.E. C and D.5. It is impossible for Tom to judge such important affairBA. as a rule of thumb.B. by rule of thumb.C. though a rule of thumb.D. by experiment.6. What happens during Na + Cl Na+Cl- DA. the nuclei of each ions are changed.B. the inner energy level of electrons changed.C. A and B.D. The outermost energy level is altered.7. Is there any order or any pattern to the way that theelectron dot are draw CA. No, there is no any order.B. Yes, the p orbitals are filled firstly.C. Yes, the s orbital is filled firstly and the p orbitals.D. Yes, but the p orbitals is filled willfully.V. TranslationChlorine is more electronegative than hydrogen. In a hydrogen chloride molecule, the chlorine atom has a much greater attraction than the hydrogen atom for the shared electron pair. Because the shared electron are held more tightly by the chlorine atom, the chlorine end of the molecule is more negative than the hydrogen end. If you think of an orbital as a fuzzy-looking cloud, then the cloud is denser near the chlorine atom. When the electrons in a covalent bond are not equally shared, the bond is said to be polar. Thus the bonding in hydrogen chloride is described as polar covalent. Whereas the bonding in the hydrogen molecule or in the chlorine molecule in nonpolar covalent. The polar covalent bond is not an ionic bond. In an ionic bond, one atom completely losed an electron. In a polar covalent bond, the atom at the positive end of the bond hydrogen in HCl still gas some share in the bonding pair of electrons. To distinguish this arrangement from that in an ionic bond, the following notation is use.The line between the atoms represents the covalent bond, a pair of shared electrons. The δ+ and δ- signify which end is partially positive and which is partially negative the word partially is used to distinguish this charge from the full charge on an ion.。
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ro ln r 1 1 i Th Tc qx hh .Ai kcopper .2L hc .Ao
Principle of Heat Exchanger
• First Law of Thermodynamic: “Energy is conserved.” 0 0 0 dE ˆ ˆ .hin m .hout q w s e generated m dt out in
Heat Exchangers prevent car engine overheating and increase efficiency Heat exchangers are used in Industry for heat transfer
Heat exchangers are used in AC and furnaces
T2 T1 T2 ln T 1
Log Mean Temperature evaluation h c ?p ?p ? h .C ? c .C m .T3 T6 m .T7 T10 T2 T1 TLn U T2 A.TLn A.TLn ln T 1
If this motion is associated with heat transfer mechanism only, then it is called Natural Convection
Forced Convection
If this motion is associated by mechanical means such as pumps, gravity or fans, the movement of the fluid is enforced. And in this case, we then speak of Forced convection.
Energy moves from hot fluid to a surface by convection, through the wall by conduction, and then by convection from the surface to the cold fluid.
Region III: Solid – Cold Liquid Convection
How is the heat transfer?
• Heat can transfer between the surface of a solid conductor and the surrounding medium whenever temperature gradient exists. Conduction Convection Natural convection Forced Convection
1 CON CURRENT FLOW 2
COUNTER CURRENT FLOW
U = The Overall Heat Transfer Coefficient [W/m.K]
Region I : Hot Liquid – Solid Convection Region II : Conduction Across Copper Wall Region III : Solid – Cold Liquid Convection
Region II : Conduction Across Copper Wall FOURIER’S LAW
dT dqx k . dr
• Velocity distribution and boundary layer When fluid flow through a circular tube of uniform crosssuction and fully developed, The velocity distribution depend on the type of the flow. In laminar flow the volumetric flowrate is a function of the radius.
1 1 d (T ) U .T .dA. m .C h m .C c c p h p
T2
T1
Th Tc A2 d (T ) U . . dA T qc A1 qh
T2
T1
1 d (T ) 1 U . m .C h m .C c T c p h p
Natural and forced Convection
Natural convection occurs whenever heat flows between a solid and fluid, or between fluid layers. As a result of heat exchange Change in density of effective fluid layers taken place, which causes upward flow of heated fluid.
Lesson 22 Heat Transfer
• • • •
• • • • •
How is the heat transfer? Mechanism of Convection Applications . Mean fluid Velocity and Boundary and their effect on the rate of heat transfer. Fundamental equation of heat transfer Logarithmic-mean temperature difference. Heat transfer Coefficients. Heat flux and Nusselt correlation Simulation program for Heat Exchanger
1
+
ro ro . ln r r 1 i U o hhot .ri kcopper .ri hcold
r
i
r
o
Calculating U using Log Mean Temperature
Hot Stream : Cold Stream:
Boundary layer
r
• Accordingly the temperature gradient is larger at the wall and through the viscous sub-layer, and small in the turbulent core.
Tube wall
Heat Exchangers
• A device whose primary purpose is the transfer of energy between two fluids is named a Heat Exchanger.
Applications of Heat Exchangers
dqx hc .Tow Tc .dA
Th Ti,wall
NEWTON’S LAW OF CCOLING
Region I : Hot LiquidSolid Convection NEWTON’S LAW OF CCOLING Q hot