煤制油工艺技术

煤制油工艺技术

张豫东2009071981

题目分析：煤制油的工艺，煤制油技术，可搜文献，搜期刊

检索过程：输入煤制油工艺或煤制油技术，关键词：coal to oil.通过文献的参考文献和类似文献查取。通过知网的外文文献查找英文。

1.“煤制油”势在必行

中国科技投资 , China Venture Capital, 2006年06期

【作者】高建业；李智；

【摘要】我国石油能源供需紧张,开发煤液化燃料产品,势在必行。我国国民经济持续快速增长,石油能源供需火爆,价格节节攀升,带动石油市场供需矛盾日益尖锐,逐年加深。石油资源紧张,需大于供,因此,寻找多元化石油能源替代产品,开发煤炭液化产品及清洁燃料利用

技术,使关系到国家石油能源安全的战略问题,是解决我国石油能源短缺的必然选择和有效途径。我国石油能源进口依存度上升据有关资料,目前我国石油剩余可采储量约24亿吨,

而2004年我国原油产量为1.745亿吨,按目前开采水平仅能满足十五年左右的开采需要(新探明的可采储量除外)。我国经济迅速发展对石油的消耗逐年增加,据国家统计局资料显示,2003年我国石油消耗量为2.5 。

2.对中国煤制油热的冷静思考

【作者】钱伯章；朱建芳；炼油技术与工程. 2006(07)

【摘要】分析了国内外煤制油技术的发展走势和煤制油项目的进展态势,对中国煤制油热的现象进行了冷静思考,对如何发展煤制油项目提出了看法。

3.替代能源考量的选择——煤制油

【作者】任相坤；中国石油和化工. 2008(15)

【摘要】煤制油产业的主要特征是煤的洁净利用。我国煤炭资源十分丰富,石油资源相对短缺,充分利用国内相对丰富的煤炭资源,大力发展煤制油产业,是我国技术经济发展过程中必须采取的一项措施。

4.煤制油:技术成熟可行资源环保掣肘——三位专家辨析煤制油技

术的特点、发展现状和趋势

作者】姚斌；王旸；曹军生；化学工程与装备. 2008(09)

【摘要】 <正>专业人士介绍:胡志海:中国石化石油化工科学研究院第十七研究室副主任、教授级高工申海平:中国石化石油化工科学研究院第六研究室副主任、教授级高工夏国富:中国石化石油化工科学研究院第十五研究室副主任、教授级高工

5. 煤制油路径选择

伍宏业.. 煤炭经济研究. 2005(11)

【摘要】所谓“煤制油”,本质上是煤炭液化技术。煤炭液化是把固体煤炭通过化学加工过程,使其转化成为液体燃料、化工原料和产品的先进洁净煤技术。即通过化学反应,将煤所含的碳氢化合物转换成其他碳氢化合物,如柴油、汽油等。根据不同的加工路线,煤炭液化可分为直接液化和间接液化两大类。直接液化技术是指在高温高压条件下,通过加氢使煤中复杂的有机化学结构直接转化成为液体燃料的技术,又称加氢液化。其典型的工艺过程主要包括煤的破碎与干燥、煤浆制备、加氢液化、固液分离、气体净化、液体产品分馏和精制,以及液化残渣气化制取氢气等部分。直接液化的操作条件苛刻,对煤炭种类的依赖性强。特点是对煤种要求虽较为严格,但热效率高,液体产品收

6. 煤制油"中国特色"的能源战略技术

【作者】罗威；新财经. 2005(10)

【摘要】 <正>放着现有的能源优势不利用,却因石油问题在政治、军事、外交上处处被动就不应该了最近,随着世界石油价格不断高企, 各界对石油问题高度敏感和关注。为了突围石油困局,中国舆论纷纷热炒“煤制油”项目,有报道指出,目前中国已经出现了“煤变油”的“千亿大跃进”。同时,有专家认为,“煤制油”与其发展机遇相比,更像是一个陷阱,因为它投资大、不可预计的风险高,前景并不乐观。“煤制油”项目目前在中国究竟处于什么状况,企业的投资价值如何,又在中国能源战略中处于什么样的位置呢?

7.煤制油工艺技术分析与评价

李大尚《煤化工》 2003年01期

【摘要】：分析了煤直接液化和间接液化两大类工艺路线的技术特点、对煤质的要求、产品分布等;并在技术难度、技术风险及经济指标等方面进行了比较与评价,供设计及科研人员参考

8.煤制油——煤化工业的绿色技术

王淑英《洁净煤技术》 2005年03期

【摘要】：煤制油通常有直接液化和间接液化,论述了煤的液化合成液体燃料的开发趋势和工业化状况。发展和应用洁净煤技术,是解决中国燃油短缺、保护环境的根本选择。

9.煤基合成油技术概述及战略研究

丁莉;赵文甲;靳灿才智;2009年19期

【摘要】：本文由日益严重的能源危机,引出国内外共同关注的煤转油,介绍了煤制油的生产技术。分别从企业和国家的角度,分析了我国煤制油产业的现状及发展趋势,并总结了我国对于煤制油行业应持有的态度。

10. 我国煤制油发展现状趋势及建议

金琳《天然气经济》 2006年05期

【摘要】：自2003年油价持续走高以来,煤制油作为接替资源受到普遍关注。文章分析了我国煤制油的发展现状,包括间接液化法和直接液化法两种煤制油装置的建设情况,以及我国煤制油的规划动向;认为我国在发展煤制油的过程中,应重点考虑煤炭液化制油技术是否成熟、水资源是否有保障两个问题;建议在我国煤制油工业的发展中,一是应抓好工业化示范,待成功后再进一步推广,二是国家应制定统一的煤制油发展规划,以引导行业健康发展。

11.煤制油的工艺经济分析

俞石波《现代化工》 1999年06期

【摘要】：壳牌公司的ＳＭＤＳ技术为煤制油工艺开辟了一条新的途径，本文对该技术的不同规模装置进行了经济评价

12. 煤制油技术在我国的发展现状

【作者】郝剑虹；高海洋；张富兴；. 煤炭科学技术. 2006(01)

【摘要】文中简要介绍了煤直接液化燃油和煤间接液化燃油的工艺特点及国内外煤制油的研究情况,论述了发展煤制油事业对我国能源安全战略的重要意义。煤制油在我国目前还没有进行大规模推广,文中指出了在汽车上应用煤制油所面临的问题,提出了解决问题的合理化建议。

13. 我国煤制油发展现状和前景及面临问题

【作者】洪二艳；. 煤炭经济研究. 2009(08)

【摘要】我国是当今世界上能源结构以煤炭为基础的少数国家之一,从我国油品缺口与能源储量来看,煤液化合成油是实现我国油品基本自给、保障我国经济可持续发展的最为切实可行的途径。介绍了煤液化的两种方法及国内已经成功示范的装置,以及诸如二氧化碳排放,水资源短缺等问题。更多还原

14. 中国煤制油化工产业发展前景分析

【作者】林长平；中国石油和化工. 2010(04)

【摘要】 <正>前言能源是一个国家经济发展的重要支撑,石油是目前和今后一个时期国家的重要资源,随着国家经济的发展,对石油资源的需求不断加大。这种情形下,实行石油替代是解决石油资源短缺的有效途径,根据我国煤炭较为丰富的资源禀赋,发展煤制油化工产业,对于缓解石油供需矛盾,实现煤炭清洁利用具有重要意义,煤制油化工产业具有广阔的发展前景。

15. 煤制油(CTO)技术及国内的发展状况

【作者】付长亮；张晓广东化工. 2008(01)

【摘要】煤制油技术主要有煤炭直接液化和煤炭间接液化两类。文章简要介绍了此两类方法的发展过程、工艺流程、工艺特点以及国内建设煤制油项目的基本情况。我国是煤炭大国,煤炭是我国的主要能源,在目前石油价格节节攀升的情况下,发展煤制油技术,对煤炭的洁净利用和保持国家能源的可持续发展,有着极为重要的意义。

16. 煤制油技术发展综述

作者】李志光；中国高新技术企业. 2008(23

【摘要】介绍了煤直接制油和煤间接制油技术的的工艺路线、工艺原理及特点。

17.煤间接液化制油技术进入新时代

黄慕礼,《瞭望》 2006年10期

【摘要】：正上海兖矿能源科技研发有限公司自2002年起开展煤间接液化制油技术的研究与开发工作．目标是在最短的时间内开发出具有我国自主知识产权的煤间接制油技术,建设具有我国自主知识产权、综合经济技术指标达到国际一流水平的煤制油工业装置．为我国的能源安全和能源多样化做出贡献。研究工作得到了国家“863”计划的支持。目前已开发成功具有自主知识。

18.实现我国煤化工、煤制油产业健康发展的若干思考

【作者】曹湘洪；

【摘要】针对我国目前出现的盲目发展煤化工、煤制油的状况提出了实现我国煤化工、煤制油产业科学发展的建议。一是发展煤化工、煤制油必须坚持"适度、有序"原则;二是综合考虑社会投入,发展煤基车用替代燃料应定位在煤制油上,不宜发展"醇醚燃料";三是发展煤化工、煤制油要高度关注国际原油和石化产品市场,认真分析产品的市场竞争力;四是发展煤化工、煤制油要积极推动煤炭生产企业与石油化工企业的以资本为纽带的强强联合。

19.煤化工工艺技术评述与展望Ⅳ.煤间接液化技术

相宏伟唐宏青李永旺《燃料化学学报》 2001年04期

【摘要】：评述了国内外煤间接液化合成液体燃料开发趋势和工业化状况,从催化剂研制、F T合成反应器开发、合成油工艺路线、工艺软件开发、工艺集成优化和技术经济分析等方面进行了讨论,指出发展洁净高效煤基合成液体燃料工业过程是解决我国燃油短缺的根本途径,并对我国煤制油工业化开发工作和示范厂建立提出一些建议和展望。

20.煤直接和间接液化生产燃料油技术

张哲民门卓武《炼油技术与工程》 2003年07期

【摘要】：介绍了煤直接和间接液化生产燃料油技术的发展历程及现状,并比较了煤直接和间接液化的优缺点。煤直接液化投资较低,产物主要由环状烃组成;煤间接液化投资较高,产物主要由链状烃组成;两种方法生产的燃料油性质互补,通过调合可以得到满足《世界燃油规范》Ⅱ类以上标准的柴油产品。

外文文献：

1.Supported liquid membrane extraction to treat coal gasification

wastewater containing high concentrations phenol

姚杰何志茹雒安国赵琪贾丽邵泽辉李彪铭

《Journal of Harbin Institute of Technology》 2012年01期

【摘要】：The hollow fiber supported liquid membrane extraction was introduced to treat coal gasification wastewater to recover phenolic compounds,with tributyl phosphate (TBP) as carrier,kerosene as the membrane solvent,sodium hydroxide solution as the stripping agent and PVDF as the membrane material. Factors having strong impact on the extraction efficiency were studied in detail,including the mass transfer mode,twophase flow rate,stripping phase concentration. As extraction system with 20% TBP-kerosene,parallel flow mass transfer,stripping phase concentration 0.1 mol/L,the optimal operating conditions could be obtained. Under the optimum operating conditions,the time required to reach equilibrium for the extraction is 50 min, and extraction efficiency of phenol is 86. 2% and the phenol concentration of effluent is 98.64

mg/L.

2.Influence of liquid water on coalbed methane adsorption:An experimental research on coal reservoirs in the south of Qinshui Basin 《Chinese Science Bulletin》 2005年S1期

【摘要】：正Using Isothermal Adsorption/Desorption System Model IS-100 and Electrohydraulic Servo Rock System Model MTS815 as the main apparatuses and collecting samples from the major coal reservoirs in the south of Qinshui Basin, a hot point region of coalbed methane exploration, the paper carries out systematical comparisons of the isothermal adsorption experimental data for injection water coal samples, equilibrium moisture samples and dry coal samples, probes and establishes an experimental method of injection water coal sample preparation and isothermal experiment to simulate real reservoir conditions, and then summaries the experimental regulations and discusses the mechanism of liquid water influencing coal methane adsorption. Results of the experiment indicate that: The Langmuir volume of injection water coal samples is notably larger than that of equilibrium moisture samples, as well as larger

than or equivalent to that of dry coal samples; the Langmuir pressure of injection water coal samples is the highest, the next is equilibrium moisture samples, while the dry samples is the lowest, of which the experimental results of injection water samples to simulate real reservoir conditions are more close to the fact. Under the conditions of in-position reservoirs, liquid water in coals has evident influence on methane adsorption ability of coal matrix, which can increase the adsorbability of coal and make the adsorption regulation fit to Langmuir model better. Its major reason is the increase of wetting coal matrix adsorbability. The above experimental results overthrow the conventional cognition that liquid water has no influence on coalbed methane adsorption, which may lead to an improvement of the coalbed methane isothermal adsorption experimental method and of the reliability of coalbed methane resource evaluation and prediction.

3．Eco no mic evaluatio ns o f d irect, ind irec t and hyb rid co al liq uefac tio n

作者：J o ng-S o o Ba e , In Hw a n g , Ye on g-J in Kw eo n , Yo u ng-Ch a n Ch o i , S e P a rk , Ha k-Jo o Kim ,He o n J un g , Ch oo n Ha n

期刊：Ko r e a n J ou rn a l of Ch em ic a l En g in e er in g 2011,29 ,第7 期

摘要：Ab str ac tT h e va r io us g eo p o lit ic a l p ro b le ms ass oc ia t e d w ith o il h a v e r e k in d le d int e re st in c o a l, w it h m a n y c o un tr ie s w or k in g o n pr o jec ts f or its liq u e f ac t io n. Th is s t ud y es t ab lis h e d t he f e as ib ilit y of c o a l liq u e f ac t io n t h ro u gh a t ec h n ic a l a n d ec o no m ic e x am in a t io n o f d ir ec t c o a l liq u e f ac t io n (D CL), in d ir ec t c o a l liq u e f ac t io n(I CL) an d h yb r id c o a l liq u e f ac t io n (HCL) p r oc e ss es. An ec o n om ic ef f ic ie nc y a n a lys is w a s pr e p ar e d inv o lv in g c o sts of in it ia l in v e s t m en t, a nn u a l op er a t in g a nd r aw c o a l p urc h as e a ...n d r e v en u es f ro m th e s a le o f m a jo r pr od uc ts a s k e y va r ia b les. F or th e r aw m at e r ia ls, p r od uc t s an d in v es t me n ts, a n a lys es of n e t pr es e nt v a lu e (NP V), in t er na l r at e o f r et ur n (I RR)an d se ns it iv it y w e r e c ar r ie d ou t.Th e p roc ess es’ I RRs w er e f o un d t o b e 22.26%(D CL),18.43% (I CL) a nd20.90% (HCL).N P Vs w er e $4.720m (D CL), $3.811 m (I CL) a n d $4.254m (HCL), a nd p a y bac k p er io ds w er e D CL 3.3 y e ars, I CL 4.2 y ea rs, an d HCL 3.6 y e ars. As a re su lt of t h e s e ns it iv it y a n a lys is, f ac to rs gr e at ly aff ec t in g t h e ea rn in g p ot e n t ia l o f c oa l liq u e f ac t io n inc lu de d p ro d uc t pr ic es, r aw c o a l pr ic es, an d c o nst ruc t io n c os ts, w h ic h s how e d s im ila r ef f ec ts in e ac h pr oc ess.

4．R es earc h o n the Mec hanis m o f Quic k Co al Liq uefac tio n at

High Temp eratures

作者：H. Lu o ,K. Lin g , W. Zh an g , Y. Wan g , J. Sh e n

期刊：En er g y S ou rc e s, P ar t A: Rec ov e ry, Ut iliz a t io n, an d En v iro nm e n ta l Ef f ec ts 2011 , 33卷, 8 期, 735-744 (页码)

摘要：Ab str ac tI n t h is a rt ic le, th e m ec h a n is m o f q u ic k c o a l liq u ef ac t io n a t h ig h t e mp e r at ur es is in v es t ig at e d t h e or et ic a lly an d e xp e r im en t a lly. Ba s ed o n t h e b on d e ne rg y of s om e m od e l c om po u nd s in th e c o a l m o lec u la r, it is p o in t e d o ut th a t t h e br id g e b o nd s of c oa l m o lec u la r st ruc tu r e d ur in g q u ic k c oa l liq u e f ac t ion at h ig h t em p er a tu re s c a n b e br o ke n.Ta k in g Ya n z ho u b it u m in o us c o a l as t h e r es ea rc h o b jec t, p yr o ly t ic b e h av io r of c o a l mo le c u la r a n d t he m ec ha n ism o f h y dr og e n-d on or of q u ic k c o a l liq u e f ac t io n a ...t h ig h t e m p er at ur es a r e s tu d ie d. Th e r eac t io n mec h a n is m of q u ic k c o a l liq u e f ac t io n a t h ig h t em p er a tu r es ha s b e e n pr op os e d.

5．R eac tio n Engineering o f Direc t Co al Liq uefac tio n

作者：Ke n K. Rob in so n

期刊：En er g ies2009

摘要：D ir ec t c o a l liq u e fac t io n h as b e en st u d ie d a nd p r ac t ic e d s in c e t h e 1930s.

I t w as u se d in G er m a ny d ur in g Wo r ld Wa r II t o p ro d uc e sy n th e t ic f u e ls w h e n t h er e w as n o o il a llo w e d in t o t h e c ou n tr y. S inc e t h en, it h as b e en s tu d ie d in t h e Un it e d St a t es a nd m a ny d iff er e nt t ec hn o lo g ies h a v e be e n in v es t ig at e d. S in c e t h e US is r ic h in c o a l r es ou rc e s, t h is is o n e w a y to b e e n erg y in d e p e n d en t. Most of t h e d e v e lo pm e nt ac t iv it y oc c u rr e d in t he 1980s an d n u m er ou s t ec h n o lo g ies w er e st u d ie d, t h e m ost no t a b le o f t h e ...s e b e in g H-Co a l, Ex xo n Do n or S o lv e nt, So lv e n t Re f in ed Co a l, a n d Tw o S ta g e Liq u e f ac t io n. T he k e y e le m e n ts o f t h es e t ec hn o lo g ies, p ar t ic u la r ly t h e r e ac t ion/r e ac to r sc h e m e, ar e d isc uss e d in t h is r e v iew.

6．Bimetallic d isp ers ed s ulfid e c atalys ts fro m o rgano metallic c lus ters fo r co al liq uefac tio n

作者：Chu ns h an S on g , D e rr ic k S. P a rf it t , Ha r o ld H. Sc h o b ert

期刊：Cat a ly s is Let t ers 1993 , 21卷, 第1期

摘要：Ab str ac t S e v er a l h e te ro m et a llic c o m p le x es c o ns ist in g of Mo, Co an d

s u lfu r in a s in g le mo le c u le w er e s y nt h es iz e d a nd t es t ed a s p r ec u rso rs of d is p ers e d c a t a lys ts fo r liq u e f ac t io n of a s u bb it u m in ous c o a l. T h e s tr uc t ur e of t h e pr ec urs ors, in p a rt ic u la r t he t y p e of lig a n ds t o t h e m e t a l s pec ie s, s ig n if ic a nt ly a ff ec ts th e ac t iv it y of th e b im et a llic Mo Co s u lf id e c at a lys ts g e n er a t ed in s it u. Am o n g t he M-M′ t y p e pr ec urs ors t es t e d, Mo-Co t h ioc ub a n e, Mo2Co2S4(Cp)2(CO)2(Cp =c yc lo p en t a d ie n e),p ro d uc ed...th e b es t c at a ly st.

7．Effects of Main Parameters on Rheological Properties of Oil-Coal Slurry

WANG Yong-gang[1]HAO Li-fang[1]XIONG Chu-an[2]SUN Xiu-ying[

JOURNAL OF CHINA UNIVERSITY OF MINING & TECHNOLOGY(ENGLISH EDITION) 2006, 16(3)

摘要：Oil-coal slurry prepared in coal direct liquefaction is a dispersed solid-liquid suspension system. In this paper, some factors such as solvent properties, solid concentrations and temperatures, which affect viscosity change of oil-coal slurry, were studied. The viscosity of coal slurry was measured using rotary viscometer, and the rheological properties have been investigated. The viscosity and rheological curves were plotted and regressed, respectively. The results show that the coal slurry behaves a pseudoplastic and thixotropic property. The rheological type of coal slurry was ascertained and its rheological equations were educed. The oil-coal slurry changes to non-Newtonian fluid from Newtonian fluid with the increasing of solid concentration.

8. Rheological studies of coal-oil mixtures

作者：M. R. Ghassemzadeh , S. Carmi

Rheologica Acta 2005 , 20 卷 , 第2 期

摘要：Summary Samples of stable coal-oil mixtures were prepared with coal concentrations ranging from 30–50% by weight. Extensive rheological data were obtained using capillary and cone-plate viscometers for samples of coal-oil mixtures and fuel-oil which served as a reference fluid. Viscosity measurements show coal-oil mixtures to be shear-thinning suspensions, i.e., the viscosity decreases moderately with increasing shear rates. In the concentration range of 30–40% coal, the coal-oil mixture s ...

9. Neutron activation analysis of wear products in a Diesel engine fueled with coal-oil slurries

作者：S. T. Mulvaney , H. P. Marshall , H. G. Knight , T. F. Parkinson Journal of Radioanalytical Chemistry 2006 , 72 卷 , 第1 期

英文摘要：Abstract The technique described is a stable tracer method and has the advantage of eliminating the use of radioactive engine components during the wear tests. The results obtained clearly show that the use of these slurries comprising pulverized coal and fuel oil is not acceptable due to excessive wear rates

10. Rheological study of black coal-oil suspensions

作者： A. K. Ghosh , S. N. Bhattacharya

期刊：Rheologica Acta 2005, 23 卷,第2 期

来源数据库：Springer Journal

关键词：Black coal ; oil ; suspension ; ageing ; power-law model

英文摘要：Abstract The rheological study of coal-oil suspensions is very important because of their application in many industries as alternative fuels to petroleum oil. In this work, the flow behaviour of black coal-oil suspension was studied for a range of coal volume fractions from

0.0378 to 0.427. Shear stresses were measured for shear rates up to 200 s?1 using a Weissenberg Rheogoniometer. All the suspensions behaved like non-Newtonian liquids and exhibited significant increases in apparent vis ...