《物理化学下册》期末试卷六

学年第1学期物理化学下册课程期末考试卷

考试时间（120）分钟一二使用班级三四五化学工程与工艺六七八九考试类型……. 闭卷总分.三明学院系班姓名座号. 题序得分阅卷人复核人一、选择填空题：（每小题3分）１、（）在相同的温度及压力，把一定体积的水分散成许多小水滴，经这一变化过程以下性质保持不变的是

A、总表面能

B、比表面

C、液面下的附加压力

D、表面张力

２、25℃下0.003mol.kg-1CaCl2水溶液中CaCl2的离子平均活度系数为。

3、在利用反应AgNO3+KI=AgI+KNO3配制溶胶时，若KI过量，则胶粒（）A、带正电荷B、带负电荷C、不带电荷D、不能确定４、（）无限稀薄的KCl溶液中，Cl-离子的迁移数为0.505，该溶液中K+

离子迁移数为

A、0.505

B、0.495

C、67.5

D、64.3 5、（）在下列电解质溶液中，不能用外推法求得??m的是：

A、NaCl;

B、NaOH;

C、HCl;

D、HAC

6、某反应A?B?C，当A的起始浓度增加一倍时，反应的半衰期也增加一倍，则此反应为级反应。

7通7、（）298K时，电池反应H2(g)+1/2O2(g)==H2O(l) 所对应的电池标准电动势Eo1，反应2H2O(l) ==2H2(g)+ O2(g) 所对应的电池标准电动势Eo2，则Eo2和Eo1的关系为

A、Eo2 = -2Eo1

B、Eo2 = 2Eo1

C、Eo2 = -Eo1

D、Eo2 = Eo1

8、若溶液能够润湿固体，则接触角θ 90o。( 大于、等于或小于) 9、一个给定的电极，它在电池中作为正极还是作为负极，其电极电势是的。（相同、不同）

10、平行反应

，主、副反应的频率因子相同，主反应的活化能为120

kJ·mol-1，副反应的活化能为80 kJ·mol-1，400K时cB∶cD = ，1000K时cB∶cD= 。二、简答题（共3题，每题4分，合12分）1．乙苯脱氢制苯乙烯反应为气相反应：C6H5C2H5(g)→C6H5C2H3(g)+H2(g) 生产中往往向系统中添加惰性组分H2O(g)，这是为什么？

2．用As2O3与略过量的H2S制成的硫化砷As2S3溶胶，试写出其胶团的结构式。

3．已知平行反应什么措施？

和，且Ea1>Ea2，为提高B的产量，应采取

计算题：

三、(12%)对反应A→P，当A反应掉3/4所需时间为A反应掉1/2所需时间的3倍，该反应是几级反应？若当A反应掉3/4所需时间为A反应掉1/2所需时间的5倍，该反应又是几级反应？请用计算式说明。，

四、(12%)下列电池在298K时的电动势E=0.165V Pt∣H2 (1.0 kPa) ∣HBr(0.1mol·kg-1)∣AgBr(s)∣Ag(s)

电池反应（1个电子得失）的ΔrHm=50kJ·mol-1，已知AgBr(s)的Ksp=1.0×10-12，Фo(Ag+/Ag)= 0.799V。

（1）写出电极反应和电池反应。（2）计算电池的Eo值。

（3）计算可逆电池产生1mol电子的电量时的热效应。

五、(10%) 292K时，丁酸水溶液的表面张力可表示为σ=σo?a ln(1+bc)，其中σo为纯水的

表面张力，a、b 为常数。(1) 导出Γ与c的关系式；(2) 若已知

a = 13.1×10?3N?m?1，

b = 19.6×10?3mol?1.m3 ，试计算浓度为0.2 mol?dm?3时的单位界面吸附量Γ。

六、(12%)400℃时，实验测定反应

1 NO2(g)?NO(g)?O2(g)

2二级反应，即γ=k〔NO2〕2。速率系数与温度的关系为

lnk1288K???20.26 ?13?1Tmol?dm?s(1)试求出此反应的活化能E及指前因子；（2）计算400℃时反应的速率系数；

（3）若在400℃时，将压力为26.67kPa的NO2(g)通入一恒容反应器，使之发生上述反应，试计算反应器中压力达到32.00kPa所需的时间。

七、(12%) 乙烯在汞蒸气存在下的氢化反应是：C2H4+H2→C2H6此反应的一个可能的机理是：

H*和

C2H5

Hg+Hk12Hg+2H*H*+Ck22H4C2H5C32H5+Hk2C2H6+H*H*+H*k4H2

可按稳态法处理。试证d[C2H6]dt=k[Hg]1/2[H2]1/2[C2H4]

速率方程是5

明：

六年级上册英语期末试卷及答案

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六年级上学期数学期末测试卷带答案

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六年级上册英语期末试卷及答案人教版

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【强烈推荐】六年级上学期期末试卷及答案

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PEP六年级英语上册期末试卷及答案

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六年级上册英语期末试卷_

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