邻-硝基甲苯-英文MSDS
邻硝基氯苯安全技术说明书
编号:JM-EHS-MSDS-017邻硝基氯苯安全技术说明书(MSDS)1、物质的理化常数2.对环境的影响:一、健康危害侵入途径：吸入、食入、经皮吸收。
健康危害：对粘膜和皮肤有刺激作用。
吸收后，产生高铁血红蛋白血症。
急性中毒：病人可有头痛、头昏、乏力、皮肤粘膜有紫绀、手指麻木等症状。
重者可出现胸闷、呼吸困难、心悸，甚至发生心律紊乱、昏迷、抽搐、呼吸麻痹。
有时可引起溶血性贫血，肝损害。
慢性中毒：有头痛、乏力、失眠、记忆力减退等神经衰弱征候群；有慢性溶血时，可出现黄疸、贫血；还可引起中毒性肝炎。
二、毒理学资料及环境行为毒性：属高毒类。
急性毒性：LD50288mg/kg(大鼠经口)污染来源：硝基氯苯是制备偶氮染料和硫化染料的中间体，也是制造农药，橡胶的原料。
有机合成、油漆、涂料、染料及制药厂排放的废水、废气是环境中邻（间）硝基氯苯的主要来源。
贮运过程中的意外倾倒、泄漏，容器破裂等也会造成硝基苯污染事故。
邻硝基氯苯的稳定性不如硝基苯，在碱性条件下，可发生水解，虽然其沸点较高，但受热易分解，其分解产物有毒，且具有爆炸性。
具有强氧化性，与可燃性物质及还原性物质起强烈反应，受热分解成有毒气体。
能空气形成爆炸性混合物。
发生爆炸起火时，产生刺激性有毒气体氯气、盐酸雾、光气、氮氧化物等。
进入水体可改变水体颜色，并散发出特殊气味，可造成水生生物死亡。
通过吸入、摄入或皮肤吸收可使人员中毒。
危险特性：遇明火、高热可燃。
与强氧化剂可发生反应。
受高热分解，产生有毒的氮氧化物和氯化物气体。
有腐蚀性。
燃烧(分解)产物：一氧化碳、二氧化碳、氧化氮、氯化氢。
3.现场应急监测方法:便携式气相色谱法《突发性环境污染事故应急监测与处理处置技术》万本太主编4.实验室监测方法:气相色谱法(GB13194-91，水质)盐酸萘乙二胺比色法《空气中有害物质测定方法》(第二版)，杭士平主编5.环境标准:6.应急处理处置方法:一、泄漏应急处理隔离泄漏污染区，周围设警告标志，若发生破洒、泄漏在地面上，应配戴好面具和手套，仔细的将漏物收集在容器内封存。
MSDS危险化学品安全技术说明书——61676--2-硝基乙苯、邻硝基乙苯
化学品安全技术说明书第一部分化学品及企业标识化学品中文名：2-硝基乙苯；邻硝基乙苯化学品英文名：2-nitroethylbenzene；o-nitroethylbenzene企业名称：生产企业地址：邮编: 传真:企业应急电话：电子邮件地址：技术说明书编码:第二部分成分/组成信息√纯品混合物有害物成分浓度CAS No.2-硝基乙苯第三部分危险性概述危险性类别：第6.1类毒害品侵入途径：吸入、食入、经皮吸收健康危害：本品吸入或经皮肤吸收均可引起中毒。
接触者可在一周后出现血尿，无紫绀，但有轻度贫血。
停止接触容易恢复。
环境危害：对环境有害。
燃爆危险：可燃，其蒸气与空气混合，能形成爆炸性混合物。
第四部分急救措施皮肤接触：立即脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。
如有不适感，就医。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
如有不适感，就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
呼吸、心跳停止，立即进行心肺复苏术。
就医。
食入：饮足量温水，催吐。
如有不适感，就医。
第五部分消防措施危险特性：遇明火、高热可燃。
受高热分解产生有毒的腐蚀性烟气。
与强氧化剂接触可发生化学反应。
有害燃烧产物：一氧化碳、氮氧化物。
灭火方法：用泡沫、雾状水、干粉、二氧化碳、砂土灭火。
灭火注意事项及措施：消防人员必须佩戴空气呼吸器、穿全身防火防毒服，在上风向灭火。
尽可能将容器从火场移至空旷处。
喷水保持火场容器冷却，直至灭火结束。
处在火场中的容器若已变色或从安全泄压装置中产生声音，必须马上撤离。
第六部分泄漏应急处理应急行动：根据液体流动和蒸气扩散的影响区域划定警戒区，无关人员从侧风、上风向撤离至安全区。
消除所有点火源。
建议应急处理人员戴正压自给式呼吸器，穿一般作业工作服。
尽可能切断泄漏源。
防止泄漏物进入水体、下水道、地下室或密闭性空间。
小量泄漏：用干燥的砂土或其它不燃材料吸收或覆盖，收集于容器中。
大量泄漏：构筑围堤或挖坑收容。
邻硝基甲苯规格
邻硝基甲苯规格
《邻硝基甲苯规格》
一、邻硝基甲苯概述
邻硝基甲苯（ ortho-Nitrotoluene，简称o-NT）是一种化学稳定性较强的工业原料，采用六环吡啶的按平衡吡啶芳烃新技术得到的，具有芳香气味，无毒无害，是一种重要的有机合成中间体，主要用于制造磺胺类、烟碱类、多种酸性酯类、酰胺类和聚酰胺类等产品。
二、邻硝基甲苯特性
1、无色或淡黄色液体，具有芳香气味；
2、沸点：117.4℃；
3、密度：0.944~0.948g/cm3；
4、熔点：-20℃；
5、物理状态：液体；
6、稳定性：化学稳定性较强，易挥发，不溶于水；
7、商品性质：无毒、无害；
8、具有高度有机合成需求，是一种重要的有机合成中间体；
9、可用于制造磺胺类、烟碱类、多种酸性酯类、酰胺类和聚酰胺类等产品；
10、由于其有害物质含量低，可以用于食品工业、医药行业中；
11、具有优良的抗氧化性和光稳定性，可用于染料生产。
三、邻硝基甲苯规格
邻硝基甲苯规格通常是按其中无机离子含量，杂质含量，水分含
量，芳香烃总量，无毒挥发物含量等来确定的，具体如下：
1、无机离子含量≤1.0％；
2、杂质含量≤1.0％；
3、水分含量≤0.1％；
4、芳香烃总量≤0.1％；
5、无毒挥发物含量≤0.05％。
邻硝基甲苯结构式
邻硝基甲苯结构式邻硝基甲苯，也称为o-硝基甲苯，是一种有机化合物，化学式为C7H7NO2。
它是甲苯的同分异构体之一，其结构式如下所示：CH3|NO2|CH3邻硝基甲苯是一种无色结晶物质，具有特殊的化学性质和广泛的应用。
下面将从不同角度对其进行描述。
一、物理性质：邻硝基甲苯是一种固体，具有较高的熔点和沸点。
它在常温下不溶于水，但可以溶于有机溶剂如乙醇、苯等。
其熔点为78-80℃，沸点为238-239℃。
二、化学性质：1. 硝基基团的反应性：邻硝基甲苯中的硝基基团具有较高的反应活性。
它可以在适当条件下发生亲电取代反应、加成反应等。
例如，它可以和亲电试剂如卤代烷、醇类等发生取代反应，生成相应的取代产物。
2. 芳香性：邻硝基甲苯具有芳香环，表现出一定的芳香性。
它可以参与芳香性的反应，如芳香取代反应、芳香性亲电加成等。
3. 氧化性：邻硝基甲苯具有一定的氧化性，可以参与氧化反应。
例如，它可以在适当条件下被硝酸等氧化剂氧化，生成相应的氧化产物。
三、应用领域：邻硝基甲苯在化工领域有广泛的应用。
它可以作为有机合成的中间体，用于合成各种有机化合物。
例如，它可以作为染料、医药、农药等的原料进行进一步的合成。
同时，邻硝基甲苯也可以作为引发剂、聚合物添加剂等在聚合反应中发挥重要作用。
总结：邻硝基甲苯是一种有机化合物，具有一定的化学性质和应用价值。
它在有机合成和化工领域有广泛的应用，可以作为染料、医药、农药等的原料，同时也可以作为引发剂、聚合物添加剂等在聚合反应中发挥作用。
对于邻硝基甲苯的深入研究和应用开发，有助于推动有机化学和化工技术的发展，为人类社会的进步做出贡献。
2-硝基甲苯 邻硝基甲苯MSDS危险化学品安全技术说明书
分子量：
137.14
燃烧热(kJ/mol)：
119.6
临界压力(MPa)：
无资料
爆炸上限%(V/V)：
无资料
爆炸下限%(V/V)：
2.2
外观与性状：
微黄色液体。
主要用途：
用于各种染料合成。
其它理化性质：
无资料
第十部分：稳定性和反应活性
稳定性：
稳定
禁配物：
强氧化剂、强还原剂、强碱。
避免接触的条件：
储存注意事项：
储存于阴凉、通风的库房。远离火种、热源。保持容器密封。应与氧化剂、还原剂、碱类、食用化学品分开存放，切忌混储。配备相应品种和数量的消防器材。储区应备有泄漏应急处理设备和合适的收容材料。应严格执行极毒物品“五双”管理制度。
第八部分：接触控制/个体防护
工程控制：
严加密闭，提供充分的局部排风。提供安全淋浴和洗眼设备。
无资料
聚合危害：
不能出现
分解产物：
无资料
第十一部分：毒理学信息
急性毒性：
LD50：891mg／kg(大鼠经口)LC50：
第十二部分：生态学资料
第十三部分：废弃处置
第十四部分：运输信息
危险货物编号：
61058
UN 编号：
1664
IMDG 规则页码：
6211
包装标志：
14
包装类别：
O52
包装方法：
无资料
灭火方法：
消防人员须佩戴防毒面具、穿全身消防服，在上风向灭火。灭火剂：泡沫、干粉、二氧化碳。
第六部分：泄漏应急处理
应急处理：
迅速撤离泄漏污染区人员至安全区，并进行隔离，严格限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器，穿防毒服。不要直接接触泄漏物。尽可能切断泄漏源。防止流入下水道、排洪沟等限制性空间。小量泄漏：用砂土或其它不燃材料吸附或吸收。大量泄漏：构筑围堤或挖坑收容。用泵转移至槽车或
MSDS危险化学品安全技术说明书——61058--4-硝基甲苯
化学品安全技术说明书第一部分化学品及企业标识化学品中文名：4-硝基甲苯；对硝基甲苯化学品英文名：4-nitrotoluene；p-nitrotoluene企业名称：生产企业地址：邮编: 传真:企业应急电话：电子邮件地址：技术说明书编码:第二部分成分/组成信息√纯品混合物有害物成分浓度CAS No.4-硝基甲苯99-99-0第三部分危险性概述危险性类别：第6.1类毒害品侵入途径：吸入、食入、经皮吸收健康危害：对眼睛、呼吸道和皮肤有刺激作用。
吸收进入体内可引起高铁血红蛋白血症，出现紫绀。
严重中毒者可致死。
环境危害：对水生生物有毒作用。
燃爆危险：可燃，其粉体与空气混合，能形成爆炸性混合物。
第四部分急救措施皮肤接触：立即脱去污染的衣着，用肥皂水和清水彻底冲洗皮肤。
如有不适感，就医。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。
如有不适感，就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
呼吸、心跳停止，立即进行心肺复苏术。
就医。
食入：饮足量温水，催吐。
如有不适感，就医。
第五部分消防措施危险特性：易燃，遇明火、高热可燃。
受高热分解放出有毒的气体。
有害燃烧产物：一氧化碳、氮氧化物。
灭火方法：用泡沫、干粉、二氧化碳灭火。
灭火注意事项及措施：消防人员必须佩戴空气呼吸器、穿全身防火防毒服，在上风向灭火。
尽可能将容器从火场移至空旷处。
喷水保持火场容器冷却，直至灭火结束。
第六部分泄漏应急处理应急行动：隔离泄漏污染区，限制出入。
建议应急处理人员戴防尘口罩，穿防毒服。
穿上适当的防护服前严禁接触破裂的容器和泄漏物。
尽可能切断泄漏源。
用塑料布覆盖泄漏物，减少飞散。
勿使水进入包装容器内。
用洁净的铲子收集泄漏物，置于干净、干燥、盖子较松的容器中，将容器移离泄漏区。
第七部分操作处置与储存操作注意事项：密闭操作，提供充分的局部排风。
操作人员必须经过专门培训，严格遵守操作规程。
建议操作人员佩戴自吸过滤式防尘口罩，戴安全防护眼镜，穿透气型防毒服，戴橡胶耐油手套。
邻硝基甲苯标准
邻硝基甲苯标准邻硝基甲苯（o-nitrotoluene），分子式为C7H7NO2，是一种有机化合物，具有重要的工业用途和环境污染问题。
邻硝基甲苯主要用于制造染料、颜料、塑料添加剂、药物等，同时也可用于生产炸药和农药。
然而，邻硝基甲苯对人体和环境具有一定的毒性，其排放和污染问题引起了广泛关注。
一、邻硝基甲苯的性质邻硝基甲苯是一种无色或微黄色的油状液体，具有特殊的芳香气味。
其沸点为216°C，熔点为5°C，密度为1.14 g/cm³。
邻硝基甲苯不溶于水，易溶于有机溶剂如醇、醚等。
邻硝基甲苯具有较高的化学稳定性，但在高温、高压条件下，可发生分解、硝化等反应。
其分解产物包括甲苯、氮气、一氧化氮等。
在酸性条件下，邻硝基甲苯可发生硝化反应，生成邻硝基甲苯的二硝化物、三硝化物等。
二、邻硝基甲苯的工业应用邻硝基甲苯在工业上具有广泛的应用，主要用途包括：1. 染料和颜料生产：邻硝基甲苯是合成染料和颜料的重要原料，如偶氮染料、硫化染料等。
2. 塑料添加剂：邻硝基甲苯可用于生产塑料稳定剂，提高塑料的耐热性、耐光性等。
3. 药物生产：邻硝基甲苯可用于合成多种药物，如抗生素、解热镇痛药等。
4. 炸药和农药生产：邻硝基甲苯是生产TNT（三硝基甲苯）和其他炸药的重要原料。
此外，邻硝基甲苯还可用于生产某些农药。
三、邻硝基甲苯的环境污染问题邻硝基甲苯在生产、使用和处理过程中，可能对环境造成污染。
其主要环境污染问题包括：1. 土壤污染：邻硝基甲苯及其代谢产物可渗透土壤，导致土壤污染。
这会影响土壤的肥力和微生物活性，进而影响植物生长和生态系统的稳定。
2. 水体污染：邻硝基甲苯可通过废水排放、事故泄漏等方式进入水体，导致水体污染。
这会对水生生物造成毒性影响，破坏水生态系统。
3. 大气污染：邻硝基甲苯在生产、使用过程中，可能发生泄漏、排放，进入大气。
其挥发性较强，对人体呼吸系统造成危害。
四、邻硝基甲苯的毒性邻硝基甲苯具有一定的毒性，对人类和环境生物产生影响。
2-硝基甲苯
侵入途径：吸入、食入、经皮吸收。
健康危害：对眼睛、呼吸道和皮肤有刺激作用。吸收进入体内可引起高铁血红蛋白血症，出现紫绀。严重中毒者可致死。
急救措施
皮肤接触：立即脱去被污染的衣着，用肥皂水和清水彻底冲洗皮肤。就医。
眼睛接触：提起眼睑，用流动清水或生理盐水冲洗。就医。
吸入：迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。
PC-STEL(mg/m3)：25[皮]
前苏联MAC(mg/m3)：3
美国TVL-TWA
OSHA 5ppm [皮]；
ACGIH 2ppm，11mg/m3[皮]
美国TLV-STEL未制定标准
检测方法：
工程控制：严加密闭，提供充分的局部排风。提供安全淋浴和洗眼设备。
防
护
措
施
呼吸系统防护：空气中浓度超标时，建议佩戴自吸过滤式防毒面具（半面罩）。
眼睛防护：戴安全防护眼镜。
身体防护：穿透气型防毒服。
手防护：戴橡胶耐油手套。
其它：工作现场严禁吸烟、进食和饮水。及时换洗工作服。工作前后不饮酒，用温水洗澡。注意检测毒物。实行就业前和定期的体检。
理
化
性
质
熔点（℃）：-4.1
沸点（℃）：222.3
相对密度（水=1）1.16
相对密度（空气=1）4.72
饱和蒸气压（kPa）0.13(50℃)
2-硝基甲苯
标
识
中文名：2-硝基甲苯；邻硝基甲苯
英文名：2-nitrotoluene;o-nitrotoluene
分子式：C7H7NO2
相对分子质量：137.14
CAS号：88-72-2
结构式：
3-硝基甲苯-安全技术说明书MSDS
第1部分化学品及企业标识化学品中文名：3-硝基甲苯化学品英文名：3-nitrotolueneCAS号：99-08-1分子式：C7H7NO2分子量：137.14产品推荐及限制用途：工业及科研用途。
第2部分危险性概述紧急情况概述：吞咽会中毒。
皮肤接触会中毒。
吸入会中毒。
长期或反复接触可能对器官造成伤害。
GHS危险性类别：急性经口毒性类别3急性经皮肤毒性类别3急性吸入毒性类别3特异性靶器官毒性反复接触类别2标签要素：象形图：警示词：危险危险性说明：H301吞咽会中毒H311皮肤接触会中毒H331吸入会中毒H373长期或反复接触可能对器官造成伤害防范说明：•预防措施：——P264作业后彻底清洗。
——P270使用本产品时不要进食、饮水或吸烟。
——P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
——P261避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
——P271只能在室外或通风良好处使用。
——P260不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
•事故响应：——P301+P310如误吞咽：立即呼叫解毒中心/医生——P330漱口。
——P302+P352如皮肤沾染：用水充分清洗。
——P312如感觉不适，呼叫解毒中心/医生——P361+P364立即脱掉所有沾染的衣服，清洗后方可重新使用——P304+P340如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。
——P311呼叫解毒中心/医生——P314如感觉不适，须求医/就诊。
•安全储存：——P405存放处须加锁。
——P403+P233存放在通风良好的地方。
保持容器密闭。
•废弃处置：——P501按当地法规处置内装物/容器。
物理和化学危险：无资料健康危害：吞咽会中毒。
皮肤接触会中毒。
吸入会中毒。
长期或反复接触可能对器官造成伤害。
环境危害：无资料第3部分成分/组成信息第4部分急救措施急救：吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
如呼吸困难，给输氧。
呼吸、心跳停止，立即进行心肺复苏术。
邻-硝基甲苯-英文MSDS
MATERIAL SAFETY DATA SHEETM ANUFACTURERContact Information:ALL-IN-LINE CHEMICALS ENTERPRISE CO.,LTD.NO.16,Chung Zhen St.,Lu Chu County, Taoyuan Hsien, Taiwan,R.O.C.Telephone: 03-3543066 FAX: 03-35423871. IDENTIFICATIONProduct name: 2-NitrotolueneProduct use: For laboratory research purposes.Restrictions on use: Not for drug or household use.2. HAZARD(S) IDENTIFICATIONOSHA Haz Com: CFR 1910.1200: Acute Toxicity - Oral [Category 4]Acute Toxicity - Inhalation [Category 3]Toxic to Reproduction [Category 2]Specific Target Organ Toxicity (Single Exposure) [Category 1]Specific Target Organ Toxicity (Single Exposure) [Category 3]Specific Target Organ Toxicity (Repeated Exposure) [Category 1]Specific Target Organ Toxicity (Repeated Exposure) [Category 2]Aquatic Hazard (Acute) [Category 2]Aquatic Hazard (Long-Term) [Category 2]Signal word: Danger!Hazard Statement(s): Harmful if swallowedSuspected of damaging fertility or the unborn childToxic if inhaledToxic to aquatic lifeToxic to aquatic life with long lasting effectsCauses damage to: BloodMay cause drowsiness or dizziness.Causes damage to organs: Blood through prolonged or repeated exposure.May cause damage to organs: Liver through prolonged or repeated exposure.Pictogram(s) or Symbol(s):Precautionary Statement(s):[Prevention] Do not eat, drink or smoke when using this product. Wash hands and face thoroughly after handling. Do not breathe fume, mist, vapors or spray. Use only outdoors or in a well-ventilated area. Obtainspecial instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection and face protection. Avoid breathing fume, mist, vapors or spray.[Response] If swallowed: Immediately call a poison center or doctor. Rinse mouth. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor. If exposed: Call a poison center or doctor. Call a poison center or doctor if you feel unwell. Get medical advice or attention if you feel unwell.[Storage] Store in a well-ventilated place. Keep container tightly closed. Store locked up.SAFETY DATA SHEETTransportation Emergencies:2. HAZARD(S) IDENTIFICATION[Disposal] Dispose of contents and container in accordance with US EPA guidelines for the classification and determination of hazardous waste listed in 40 CFR 261.3. (See Section 13)3. COMPOSITION/INFORMATION ON INGREDIENTSSubstance/Mixture: SubstanceChemical Formula: C7H7NO24. FIRST-AID MEASURESInhalation: Immediately call a poison center or doctor. Effects of exposure (inhalation) to substance may be delayed.Inhalation of vapors or contact with substance will result in contamination and potential harmful effects. Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Keep victim warm and quiet. Treat symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.Skin contact: Immediately call a poison center or doctor. Effects of exposure (skin contact) to substance may be delayed. Remove and wash contaminated clothing before re-use. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Treat symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.Eye contact: If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper eyelids. If eye irritation persists get medical advice/attention. Move victim to fresh air. Check for and remove any contact lenses. Keep victim warm and quiet. Treat symptomatically and supportively. Effects of exposure to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.Ingestion: Harmful if swallowed. Effects of exposure (ingestion) to substance may be delayed. Call a physician or Poison Control Center immediately. Do not use mouth-to-mouth method if victim ingested the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Loosen tight clothing such as a collar, tie, belt or waistband. If a person vomits place them in the recovery position so that vomit will not reenter the mouth and throat. Rinse mouth. Keep victim warm and quiet. Treat symptomatically and supportively. Ensure that medical personnel areaware of the material(s) involved and take precautions to protect themselves.Symptoms/effects:Acute: Dizziness. Drowsiness.Delayed: No data availableImmediate medical attention: WARNING: It might be dangerous to the person providing aid to give mouth-to-mouth respiration, becausethe inhaled material is toxic. CAUTION: Victim may be a source of contamination. If breathing has stopped, perform artificial respiration. Use first aid treatment according to the nature of the injury. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.5. FIRE-FIGHTING MEASURESSuitable extinguishing media: Dry chemical, CO2 or water spray. Consult with local fire authorities before attempting large scale fire fighting operations.Specific hazards arising from the chemicalHazardous combustion products: These products include: Carbon oxides Nitrogen oxidesOther specific hazards: Closed containers may explode from heat of a fire.Special precautions for fire-fighters:Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not scatter the material. Containers may explode whenheated. Move containers from fire area if you can do it without risk.Special protective equipment for fire-fighters:Wear positive pressure self-contained breathing apparatus (SCBA). Structural fire fighters' protective clothing provides limited protection in fire situationsONLY; it may not be effective in spill situations. Wear chemical protective clothing which is specifically recommended by the manufacturer. It mayprovide little or no thermal protection.Molecular Weight: 137.14Components: 2-NitrotoluenePercent: >99.0%(GC)CAS Number: 88-72-26. ACCIDENTAL RELEASE MEASURESPersonal precautions: Avoid contact with skin, eyes, and clothing. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing (Section 8). Warn unnecessary personnel to move away. Stop leak if you can do it without risk. Ensure adequate ventilation.Isolate the hazard area and deny entry to unnecessary and unprotected personnel.Personal protective equipment: Splash goggles. Wear protective clothing (chemical resistant suit and chemical resistant boots). Vapor respirator. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Wear protective gloves (nitrile).Emergency procedures: Do not clean-up or dispose except under supervision of a specialist. In case of a spill and/or a leak, always shut off any sources of ignition, ventilate the area, and excercise caution. Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. Warn personnel to move away. Prevent entry into sewers, basements or confined areas; dike if needed.Methods and materials for containment and cleaning up:ELIMINATE all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if without risk. Absorb with an inert material and put the spilled material in an appropriate waste disposal container. Use clean non-sparking tools to collect absorbed material. Dike far ahead of spill; use drysand to contain the flow of material. Ventilate the area.Environmental precautions:Keep away from living quarters. Environmental hazard. Do not let product enter drains. Prevent further leakage or spillage if safe to do so. Water runoff can cause environmental damage. Prevent entry into sewers, basements or confined areas; dike if needed.7. HANDLING AND STORAGEPrecautions for safe handling: Do NOT breath gas, fumes, vapor, or spray. Manipulate under an adequate fume hood. Do not ingest.Avoid contact with skin and eyes. Avoid contact - obtain special instructions before use. Avoid prolongedor repeated exposure. Normal measures for preventive fire protection. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Keep container dry. Handle and open container with care. Wear suitable protective clothing, gloves and eye/face protection. When using do not eat, drink, or smoke. Keep away from sources of ignition. Conditions for safe storage: Store locked up. Keep containers tightly closed in a cool, well-ventilated place. Keep away from incompatibles. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Avoid prolonged storage periods.Storage incompatibilities: Store away from oxidizing agents8. EXPOSURE CONTROLS / PERSONAL PROTECTIONExposure limits:ACGIH TLV (TWA): 2 ppm (skin)OSHA PEL (TWA): 5 ppm (skin)Appropriate engineering controls:Handle only in a fully enclosed system and equipment. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Ventilation is normally required when handling or using this product. Eyewash fountains should be providedin areas where there is any possibility that workers could be exposed to the substance. Follow safe industrial engineering/laboratory practices when handling any chemical.Personal protective equipmentRespiratory protection: Vapor respirator. Be sure to use a MSHA/NIOSH approved respirator or equivalent.Hand protection: Wear protective gloves.Eye protection: Splash goggles.Skin and body protection: Wear protective clothing (chemical resistant suit and chemical resistant boots).9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state (20°C): LiquidForm: ClearColor: Pale yellow - YellowOdor: Weakly AromaticOdor threshold: No data availableMelting point/freezing point: No data availableBoiling point/range: 222°C (432°F)Decomposition temperature: No data availableRelative density: 1.17Kinematic viscosity: No data availablePartition coefficient: 2.3n-octanol/water (log Pow)Flash point: 106°C (223°F)Flammability (solid, gas): No data availablepH: No data availableVapor pressure: 0.02kPa/20°CVapor density: 4.73Dynamic Viscosity: No data availableEvaporation rate: No data available(Butyl Acetate = 1)Autoignition temperature: 305°C (581°F)Flammability or explosive limits:Lower: 2.2%Upper: .?%Solubility(ies):Water: Insoluble (0.044g/100mL, 20°C)Miscible: EtherSoluble: Alcohols, Benzene, Acetone, Chloroform, Petroleum ether, Petroleum benzine, Sulfur dioxide Slightly soluble: Ammonia10. STABILITY AND REACTIVITYReactivity: Not Available.Chemical Stability: Stable under recommended storage conditions. (See Section 7)Possibility of Hazardous Reactions: No hazardous reactivity has been reported.Conditions to avoid: Avoid excessive heat and light.Incompatible materials: Oxidizing agentsHazardous Decomposition Products: No data available11. TOXICOLOGICAL INFORMATIONRTECS Number: XT3150000Acute Toxicity:ihl-mus LC50:328 mg/m3ihl-rat LC50:790 mg/m3orl-mus LD50:970 mg/kgorl-rat LD50:891 mg/kgSkin corrosion/irritation:No data availableSerious eye damage/irritation:No data availableRespiratory or skin sensitization:No data availableGerm cell mutagenicity:dna-rat-orl 150 mg/kg dns-rat-lvr 500 ug/Ldns-rat-orl 200 mg/kgCarcinogenicity: orl-rat TDLo:10.1 g/kg/12W-CIARC: Group 3 (Not classifiable ascarcinogenic to humans).NTP: No data availableOSHA: No data availableReproductive toxicity:orl-mus TDLo:140 g/kg(13W male) orl-rat TDLo:32123 mg/kg(13W male)Routes of Exposure: Inhalation, Eye contact, Ingestion, Skin contact.Symptoms related to exposure:Overexposure may result in serious illness or death. Inhalation causes irritation of the lungs and respiratory system.Potential Health Effects:Inhalation causes irritation of the lungs and respiratory system.Target organ(s):Causes damage to: BloodMay cause drowsiness or dizziness.Causes damage to organs: Blood through prolonged or repeated exposure.May cause damage to organs: Liver through prolonged or repeated exposure.12. ECOLOGICAL INFORMATIONEcotoxicityFish: 48h LC50:88 ppm (Oryzias latipes)Crustacea: No data availableAlgae: No data availablePersistence and degradability: 0.5% (by BOD), 2.3% (by UV-VIS), 0.8% (by GC) Bioaccumulative potential (BCF): 12.5 - 29.9 (conc. 0.1 ppm), 6.6 - 29.7 (conc. 0.01 ppm) Mobillity in soil: No data availablePartition coefficient: 2.3 n-octanol/water (log P ow)n-octanol/water (log Pow)Soil adsorption (Koc): No data availableHenry's Law: 5.7constant (PaM3/mol)13. DISPOSAL CONSIDERATIONSDisposal of product: Recycle to process if possible. It is the generator's responsibility to comply with Federal, State and Local rules and regulations. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. This section is intended to provide assistance but does not replace these laws, nor does compliance in accordance with this section ensure regulatory compliance according to the law. US EPA guidelines for Identification and Listing of HazardousWaste are listed in 40 CFR Parts 261. The product should not be allowed to enter the environment, drains, water ways, or the soil.Disposal of container: Dispose of as unused product. Do not re-use empty containers.Other considerations: Observe all federal, state and local regulations when disposing of the substance.14. TRANSPORT INFORMATIONDOT (US)IATAIMDGEmS number: F-A, S-AReportable Quantitiy: 1000 Pounds (454 Kilograms)UN.NO.：1664Dangerous Goods Code: 6105815. REGULATORY INFORMATIONToxic Substance Control Act (TSCA 8b.):This product is ON the EPA Toxic Substances Control Act (TSCA) inventory.US Federal RegulationsCERCLA Hazardous substance and Reportable Quantity:SARA 313: Not ListedSARA 302: Not ListedState RegulationsState Right-to-KnowMassachusetts Not ListedPacking Group:IIUN number:UN1664Proper Shipping Name:Nitrotoluenes, liquidClass or Division:6.1 Toxic material.UN number:UN1664Packing Group:IIUN number:UN1664Proper Shipping Name:Nitrotoluenes, liquidProper Shipping Name:Nitrotoluenes, liquidClass or Division:6.1 Toxic material.Packing Group:IIClass or Division:6.1 Toxic material..15. REGULATORY INFORMATIONNew Jersey ListedPennsylvania Not ListedCalifornia Proposition 65: ListedOther InformationInternational InventoriesWHMIS hazard class: D1B: Materials causing immediate and serious toxic effects. (Toxic) D2A: Materials causing other toxic effects. (Very Toxic)D2B: Materials causing other toxic effects. (Toxic)Canada: DSL On DSLEC-No: 201-853-3Notice Through Official Gazettes Reference Number: (Japan)ENCS: (3)-43716. OTHER INFORMATIONRevision date: 11/20/2013HMIS Classification:2-NitrotolueneHealth: 3Health: 3Flammability: 1 Flammability: 1NFPA Rating:Instability: 0 Physical: 0。
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MATERIAL SAFETY DATA SHEETM ANUFACTURERContact Information:ALL-IN-LINE CHEMICALS ENTERPRISE CO.,LTD.NO.16,Chung Zhen St.,Lu Chu County, Taoyuan Hsien, Taiwan,R.O.C.Telephone: 03-3543066 FAX: 03-35423871. IDENTIFICATIONProduct name: 2-NitrotolueneProduct use: For laboratory research purposes.Restrictions on use: Not for drug or household use.2. HAZARD(S) IDENTIFICATIONOSHA Haz Com: CFR 1910.1200: Acute Toxicity - Oral [Category 4]Acute Toxicity - Inhalation [Category 3]Toxic to Reproduction [Category 2]Specific Target Organ Toxicity (Single Exposure) [Category 1]Specific Target Organ Toxicity (Single Exposure) [Category 3]Specific Target Organ Toxicity (Repeated Exposure) [Category 1]Specific Target Organ Toxicity (Repeated Exposure) [Category 2]Aquatic Hazard (Acute) [Category 2]Aquatic Hazard (Long-Term) [Category 2]Signal word: Danger!Hazard Statement(s): Harmful if swallowedSuspected of damaging fertility or the unborn childToxic if inhaledToxic to aquatic lifeToxic to aquatic life with long lasting effectsCauses damage to: BloodMay cause drowsiness or dizziness.Causes damage to organs: Blood through prolonged or repeated exposure.May cause damage to organs: Liver through prolonged or repeated exposure.Pictogram(s) or Symbol(s):Precautionary Statement(s):[Prevention] Do not eat, drink or smoke when using this product. Wash hands and face thoroughly after handling. Do not breathe fume, mist, vapors or spray. Use only outdoors or in a well-ventilated area. Obtainspecial instructions before use. Do not handle until all safety precautions have been read and understood. Wear protective gloves, protective clothing, eye protection and face protection. Avoid breathing fume, mist, vapors or spray.[Response] If swallowed: Immediately call a poison center or doctor. Rinse mouth. If inhaled: Remove person to fresh air and keep comfortable for breathing. Call a poison center or doctor. If exposed: Call a poison center or doctor. Call a poison center or doctor if you feel unwell. Get medical advice or attention if you feel unwell.[Storage] Store in a well-ventilated place. Keep container tightly closed. Store locked up.SAFETY DATA SHEETTransportation Emergencies:2. HAZARD(S) IDENTIFICATION[Disposal] Dispose of contents and container in accordance with US EPA guidelines for the classification and determination of hazardous waste listed in 40 CFR 261.3. (See Section 13)3. COMPOSITION/INFORMATION ON INGREDIENTSSubstance/Mixture: SubstanceChemical Formula: C7H7NO24. FIRST-AID MEASURESInhalation: Immediately call a poison center or doctor. Effects of exposure (inhalation) to substance may be delayed.Inhalation of vapors or contact with substance will result in contamination and potential harmful effects. Move victim to fresh air. Give artificial respiration if victim is not breathing. Administer oxygen if breathing is difficult. Keep victim warm and quiet. Treat symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.Skin contact: Immediately call a poison center or doctor. Effects of exposure (skin contact) to substance may be delayed. Remove and wash contaminated clothing before re-use. Remove and isolate contaminated clothing and shoes. In case of contact with substance, immediately flush skin with running water for at least 20 minutes. Treat symptomatically and supportively. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.Eye contact: If this chemical contacts the eyes, immediately wash (irrigate) the eyes with large amounts of water, occasionally lifting the lower and upper eyelids. If eye irritation persists get medical advice/attention. Move victim to fresh air. Check for and remove any contact lenses. Keep victim warm and quiet. Treat symptomatically and supportively. Effects of exposure to substance may be delayed. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.Ingestion: Harmful if swallowed. Effects of exposure (ingestion) to substance may be delayed. Call a physician or Poison Control Center immediately. Do not use mouth-to-mouth method if victim ingested the substance; give artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device. Loosen tight clothing such as a collar, tie, belt or waistband. If a person vomits place them in the recovery position so that vomit will not reenter the mouth and throat. Rinse mouth. Keep victim warm and quiet. Treat symptomatically and supportively. Ensure that medical personnel areaware of the material(s) involved and take precautions to protect themselves.Symptoms/effects:Acute: Dizziness. Drowsiness.Delayed: No data availableImmediate medical attention: WARNING: It might be dangerous to the person providing aid to give mouth-to-mouth respiration, becausethe inhaled material is toxic. CAUTION: Victim may be a source of contamination. If breathing has stopped, perform artificial respiration. Use first aid treatment according to the nature of the injury. Ensure that medical personnel are aware of the material(s) involved and take precautions to protect themselves.5. FIRE-FIGHTING MEASURESSuitable extinguishing media: Dry chemical, CO2 or water spray. Consult with local fire authorities before attempting large scale fire fighting operations.Specific hazards arising from the chemicalHazardous combustion products: These products include: Carbon oxides Nitrogen oxidesOther specific hazards: Closed containers may explode from heat of a fire.Special precautions for fire-fighters:Use water spray or fog; do not use straight streams. Dike fire-control water for later disposal; do not scatter the material. Containers may explode whenheated. Move containers from fire area if you can do it without risk.Special protective equipment for fire-fighters:Wear positive pressure self-contained breathing apparatus (SCBA). Structural fire fighters' protective clothing provides limited protection in fire situationsONLY; it may not be effective in spill situations. Wear chemical protective clothing which is specifically recommended by the manufacturer. It mayprovide little or no thermal protection.Molecular Weight: 137.14Components: 2-NitrotoluenePercent: >99.0%(GC)CAS Number: 88-72-26. ACCIDENTAL RELEASE MEASURESPersonal precautions: Avoid contact with skin, eyes, and clothing. Keep people away from and upwind of spill/leak. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing (Section 8). Warn unnecessary personnel to move away. Stop leak if you can do it without risk. Ensure adequate ventilation.Isolate the hazard area and deny entry to unnecessary and unprotected personnel.Personal protective equipment: Splash goggles. Wear protective clothing (chemical resistant suit and chemical resistant boots). Vapor respirator. Be sure to use a MSHA/NIOSH approved respirator or equivalent. Wear protective gloves (nitrile).Emergency procedures: Do not clean-up or dispose except under supervision of a specialist. In case of a spill and/or a leak, always shut off any sources of ignition, ventilate the area, and excercise caution. Do nottouch damaged containers or spilled material unless wearing appropriate protective clothing. Warn personnel to move away. Prevent entry into sewers, basements or confined areas; dike if needed.Methods and materials for containment and cleaning up:ELIMINATE all ignition sources (no smoking, flares, sparks, or flames in immediate area). Stop leak if without risk. Absorb with an inert material and put the spilled material in an appropriate waste disposal container. Use clean non-sparking tools to collect absorbed material. Dike far ahead of spill; use drysand to contain the flow of material. Ventilate the area.Environmental precautions:Keep away from living quarters. Environmental hazard. Do not let product enter drains. Prevent further leakage or spillage if safe to do so. Water runoff can cause environmental damage. Prevent entry into sewers, basements or confined areas; dike if needed.7. HANDLING AND STORAGEPrecautions for safe handling: Do NOT breath gas, fumes, vapor, or spray. Manipulate under an adequate fume hood. Do not ingest.Avoid contact with skin and eyes. Avoid contact - obtain special instructions before use. Avoid prolongedor repeated exposure. Normal measures for preventive fire protection. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Keep container dry. Handle and open container with care. Wear suitable protective clothing, gloves and eye/face protection. When using do not eat, drink, or smoke. Keep away from sources of ignition. Conditions for safe storage: Store locked up. Keep containers tightly closed in a cool, well-ventilated place. Keep away from incompatibles. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Avoid prolonged storage periods.Storage incompatibilities: Store away from oxidizing agents8. EXPOSURE CONTROLS / PERSONAL PROTECTIONExposure limits:ACGIH TLV (TWA): 2 ppm (skin)OSHA PEL (TWA): 5 ppm (skin)Appropriate engineering controls:Handle only in a fully enclosed system and equipment. Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. Ventilation is normally required when handling or using this product. Eyewash fountains should be providedin areas where there is any possibility that workers could be exposed to the substance. Follow safe industrial engineering/laboratory practices when handling any chemical.Personal protective equipmentRespiratory protection: Vapor respirator. Be sure to use a MSHA/NIOSH approved respirator or equivalent.Hand protection: Wear protective gloves.Eye protection: Splash goggles.Skin and body protection: Wear protective clothing (chemical resistant suit and chemical resistant boots).9. PHYSICAL AND CHEMICAL PROPERTIESPhysical state (20°C): LiquidForm: ClearColor: Pale yellow - YellowOdor: Weakly AromaticOdor threshold: No data availableMelting point/freezing point: No data availableBoiling point/range: 222°C (432°F)Decomposition temperature: No data availableRelative density: 1.17Kinematic viscosity: No data availablePartition coefficient: 2.3n-octanol/water (log Pow)Flash point: 106°C (223°F)Flammability (solid, gas): No data availablepH: No data availableVapor pressure: 0.02kPa/20°CVapor density: 4.73Dynamic Viscosity: No data availableEvaporation rate: No data available(Butyl Acetate = 1)Autoignition temperature: 305°C (581°F)Flammability or explosive limits:Lower: 2.2%Upper: .?%Solubility(ies):Water: Insoluble (0.044g/100mL, 20°C)Miscible: EtherSoluble: Alcohols, Benzene, Acetone, Chloroform, Petroleum ether, Petroleum benzine, Sulfur dioxide Slightly soluble: Ammonia10. STABILITY AND REACTIVITYReactivity: Not Available.Chemical Stability: Stable under recommended storage conditions. (See Section 7)Possibility of Hazardous Reactions: No hazardous reactivity has been reported.Conditions to avoid: Avoid excessive heat and light.Incompatible materials: Oxidizing agentsHazardous Decomposition Products: No data available11. TOXICOLOGICAL INFORMATIONRTECS Number: XT3150000Acute Toxicity:ihl-mus LC50:328 mg/m3ihl-rat LC50:790 mg/m3orl-mus LD50:970 mg/kgorl-rat LD50:891 mg/kgSkin corrosion/irritation:No data availableSerious eye damage/irritation:No data availableRespiratory or skin sensitization:No data availableGerm cell mutagenicity:dna-rat-orl 150 mg/kg dns-rat-lvr 500 ug/Ldns-rat-orl 200 mg/kgCarcinogenicity: orl-rat TDLo:10.1 g/kg/12W-CIARC: Group 3 (Not classifiable ascarcinogenic to humans).NTP: No data availableOSHA: No data availableReproductive toxicity:orl-mus TDLo:140 g/kg(13W male) orl-rat TDLo:32123 mg/kg(13W male)Routes of Exposure: Inhalation, Eye contact, Ingestion, Skin contact.Symptoms related to exposure:Overexposure may result in serious illness or death. Inhalation causes irritation of the lungs and respiratory system.Potential Health Effects:Inhalation causes irritation of the lungs and respiratory system.Target organ(s):Causes damage to: BloodMay cause drowsiness or dizziness.Causes damage to organs: Blood through prolonged or repeated exposure.May cause damage to organs: Liver through prolonged or repeated exposure.12. ECOLOGICAL INFORMATIONEcotoxicityFish: 48h LC50:88 ppm (Oryzias latipes)Crustacea: No data availableAlgae: No data availablePersistence and degradability: 0.5% (by BOD), 2.3% (by UV-VIS), 0.8% (by GC) Bioaccumulative potential (BCF): 12.5 - 29.9 (conc. 0.1 ppm), 6.6 - 29.7 (conc. 0.01 ppm) Mobillity in soil: No data availablePartition coefficient: 2.3 n-octanol/water (log P ow)n-octanol/water (log Pow)Soil adsorption (Koc): No data availableHenry's Law: 5.7constant (PaM3/mol)13. DISPOSAL CONSIDERATIONSDisposal of product: Recycle to process if possible. It is the generator's responsibility to comply with Federal, State and Local rules and regulations. You may be able to dissolve or mix material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber system. This section is intended to provide assistance but does not replace these laws, nor does compliance in accordance with this section ensure regulatory compliance according to the law. US EPA guidelines for Identification and Listing of HazardousWaste are listed in 40 CFR Parts 261. The product should not be allowed to enter the environment, drains, water ways, or the soil.Disposal of container: Dispose of as unused product. Do not re-use empty containers.Other considerations: Observe all federal, state and local regulations when disposing of the substance.14. TRANSPORT INFORMATIONDOT (US)IATAIMDGEmS number: F-A, S-AReportable Quantitiy: 1000 Pounds (454 Kilograms)UN.NO.：1664Dangerous Goods Code: 6105815. REGULATORY INFORMATIONToxic Substance Control Act (TSCA 8b.):This product is ON the EPA Toxic Substances Control Act (TSCA) inventory.US Federal RegulationsCERCLA Hazardous substance and Reportable Quantity:SARA 313: Not ListedSARA 302: Not ListedState RegulationsState Right-to-KnowMassachusetts Not ListedPacking Group:IIUN number:UN1664Proper Shipping Name:Nitrotoluenes, liquidClass or Division:6.1 Toxic material.UN number:UN1664Packing Group:IIUN number:UN1664Proper Shipping Name:Nitrotoluenes, liquidProper Shipping Name:Nitrotoluenes, liquidClass or Division:6.1 Toxic material.Packing Group:IIClass or Division:6.1 Toxic material..15. REGULATORY INFORMATIONNew Jersey ListedPennsylvania Not ListedCalifornia Proposition 65: ListedOther InformationInternational InventoriesWHMIS hazard class: D1B: Materials causing immediate and serious toxic effects. (Toxic) D2A: Materials causing other toxic effects. (Very Toxic)D2B: Materials causing other toxic effects. (Toxic)Canada: DSL On DSLEC-No: 201-853-3Notice Through Official Gazettes Reference Number: (Japan)ENCS: (3)-43716. OTHER INFORMATIONRevision date: 11/20/2013HMIS Classification:2-NitrotolueneHealth: 3Health: 3Flammability: 1 Flammability: 1NFPA Rating:Instability: 0 Physical: 0。