STRESS-STRAIN RESPONSE OF POLYMERS FOR PREDICTING THE BEHAVIOR OF INTEGRAL FASTENERS
stress、strain名词解释高分子化学

stress、strain名词解释高分子化学
在高分子化学中,stress(应力)和strain(应变)是描述材料在受力作用下的行为和性能的术语。
1.应力(stress):
应力是指物体单位面积上所承受的力,通常用于描述材料在受到外力作用时内部产生的抵抗力。
在高分子化学中,应力通常指材料的拉伸应力、压缩应力、弯曲应力等。
材料的应力与材料的弹性模量、泊松比等参数有关。
2.应变(strain):
应变是指物体在外力作用下发生的形变程度,即物体形状或尺寸的变化与原始尺寸的比值。
在高分子化学中,应变通常指材料的拉伸应变、压缩应变、弯曲应变等。
应变的数值可以反映材料在受力作用下的可变形性和刚度。
在研究高分子材料的力学性能时,应力-应变曲线是一个重要的工具。
这个曲线可以描述材料在受到外力作用时,应力和应变之间的关系。
通过这个曲线,可以评估材料的弹性模量、屈服强度、极限强度等力学性能参数。
这些参数对于高分子材料的加工、使用和设计都具有重要的意义。
聚合物材料力学响应特征简介

∑ 储能函数ΔGel =
n
μn an
(λaxn
+
λan y
+
λan z
− 3)
an为任意常数,无明确物理意义;μ
为弹性结构参数
n
对简单拉伸
∑ σ =
n
μn
(λa n
-1
-
1 λa n / i−1
)
μ(x)=6.2×105Pa μ(y)=0.012×105Pa μ(z)=0.10×105Pa a(x)=1.3, a(y)=5, a(z)=-2.0
1-1,1-2,1-3,1-4
---small molecule
2,2-2
---linear polymer
2-3,2-4,3-3,3-4
---crosslink
13
橡胶弹性的唯象理论
Mooney-Rivlin理论假定 (1)橡胶不可压缩,在未应变状态下是各向同性的 (2)简单剪切可由Hooke Law描述
Affine Transformation是一种坐标到坐标之间的线性变换,保持图形的 (1)“平直性”(straightness):即变换后直线还是直 线不会打弯,圆弧还是圆弧 (2)“平行性”(parallelness):指保持图形间的相对位置关系不变,平行线还是平 行线,相交直线的交角 不变 仿射变换可以通过一系列的原子变换的复合来实现,包括:平移 (Translation)、缩放(Scale)、翻转(Flip)、旋转 (Rotation)和剪切 (Shear)。
⎦
−
⎨⎧μkT ⎩
ln
Φ2c Φ2m
⎫ ⎬ ⎭
# Phantom#
ΔGel
=
3Aφ NkT 2
Stimuli-Responsive Polymer

DOI: 10.1126/science.1153307, 1370 (2008);319Science et al.Jeffrey R. Capadona,Inspired by the Sea Cucumber Dermis Stimuli-Responsive Polymer Nanocomposites (this information is current as of March 23, 2008 ):The following resources related to this article are available online at/cgi/content/full/319/5868/1370version of this article at:including high-resolution figures, can be found in the online Updated information and services, /cgi/content/full/319/5868/1370/DC1 can be found at:Supporting Online Material /cgi/content/full/319/5868/1370#otherarticles , 4 of which can be accessed for free:cites 26 articles This article/cgi/collection/mat_sci Materials Science: subject collections This article appears in the following/about/permissions.dtl in whole or in part can be found at: this article permission to reproduce of this article or about obtaining reprints Information about obtaining registered trademark of AAAS.is a Science 2008 by the American Association for the Advancement of Science; all rights reserved. The title Copyright American Association for the Advancement of Science, 1200 New York Avenue NW, Washington, DC 20005. (print ISSN 0036-8075; online ISSN 1095-9203) is published weekly, except the last week in December, by the Science o n M a r c h 23, 2008w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o mprocesses in the fiber,in particular stimulated Raman scattering (20),limit the optical shock.Assuming that the steepness at the shock front is comparable to twice the frequency of the pulse carrier,8×1014Hz,the Hawking temperature (Eq.8)reaches 103K,which is many orders of magnitude higher than that in condensed-matter analogs of the event horizon (10–12,18).Our scheme thus solves two problems at once in a natural way:how to let an effective medium move at superluminal speed,and how to generate a steep velocity profile at the horizon.Here the various aspects of the physics of artificial black holes conspire together,in contrast to most other proposals (1–4,10–16).References and Notes1.Artificial Black Holes ,M.Novello,M.Visser,G.E.Volovik,Eds.(World Scientific,Singapore,2002).2.G.E.Volovik,The Universe in a Helium Droplet (Clarendon Press,Oxford,2003).3.W.G.Unruh,R.Schützhold,Quantum Analogues:From Phase Transitions to Black Holes and Cosmology (Springer,Berlin,2007).4.W.G.Unruh,Phys.Rev.Lett.46,1351(1981).5.T.Jacobson,Prog.Theor.Phys.136(suppl.),1(1999).6.G.Rousseaux,C.Mathis,P.Maïssa,T.G.Philbin,U.Leonhardt,/abs/0711.4767.7.S.M.Hawking,Nature 248,30(1974).8.N.D.Birrell,P.C.W.Davies,Quantum Fields in Curved Space (Cambridge Univ.Press,Cambridge,1984).9.R.Brout,S.Massar,R.Parentani,Ph.Spindel,Phys.Rep.260,329(1995).10.L.J.Garay,J.R.Anglin,J.I.Cirac,P.Zoller,Phys.Rev.Lett.85,4643(2000).11.S.Giovanazzi,C.Farrell,T.Kiss,U.Leonhardt,Phys.Rev.A 70,063602(2004).12.S.Giovanazzi,Phys.Rev.Lett.94,061302(2005).13.R.Schützhold,W.G.Unruh,Phys.Rev.D 66,044019(2002).14.G.E.Volovik,J.Exp.Theor.Phys.Lett.76,240(2002).15.U.Leonhardt,P.Piwnicki,Phys.Rev.Lett.84,822(2000).16.U.Leonhardt,Nature 415,406(2002).onni,Fast Light,Slow Light and Left HandedLight (Institute of Physics,Bristol,UK,2004).18.T.A.Jacobson,G.E.Volovik,Phys.Rev.D 58,064021(1998).19.R.Schützhold,W.G.Unruh,Phys.Rev.Lett.95,031301(2005).20.G.Agrawal,Nonlinear Fiber Optics (Academic Press,SanDiego,CA,2001).21.W.H.Reeves et al .,Nature 424,511(2003).22.P.Russell,Science 299,358(2003).23.G.t'Hooft.Nucl.Phys.B 256,727(1985).24.T.Jacobson,Phys.Rev.D 44,1731(1991).25.See the supporting material on Science Online.26.U.Leonhardt,Rep.Prog.Phys.66,1207(2003).27.Few-Cycle Laser Pulse Generation and Its Applications ,F.X.Kärtner,Ed.(Springer,Berlin,2004).28.T.Brabec,F.Krausz,Rev.Mod.Phys.72,545(2000).29.We are indebted to G.Agrawal,M.Dunn,T.Hänsch,ler,R.Parentani,and W.Sibbett for discussions and technical support.We thank A.Podlipensky and P.Russell for measuring the dispersion of our fiber.Our work was supported by the Leverhulme Trust,Engineering and Physical Sciences Research Council,Continuous Variable Quantum Information with Atoms and Light,the Ultrafast Photonics Facility at St Andrews,and Leonhardt Group Aue.Supporting Online Material/cgi/content/full/319/5868/1367/DC1SOM TextFigs.S1to S13Table S1References and Notes30November 2007;accepted 24January 200810.1126/science.1153625Stimuli-Responsive Polymer Nanocomposites Inspired by the Sea Cucumber DermisJeffrey R.Capadona,1,2,3Kadhiravan Shanmuganathan,1Dustin J.Tyler,2,3Stuart J.Rowan,1,2,3,4*Christoph Weder 1,2,4*Sea cucumbers,like other echinoderms,have the ability to rapidly and reversibly alter the stiffness of their inner dermis.It has been proposed that the modulus of this tissue is controlled by regulating the interactions among collagen fibrils,which reinforce a low-modulus matrix.We report on a family of polymer nanocomposites,which mimic this architecture and display similar chemoresponsive mechanic adaptability.Materials based on a rubbery host polymer and rigid cellulose nanofibers exhibit a reversible reduction by a factor of 40of the tensile modulus,for example,from 800to 20megapascals (MPa),upon exposure to a chemical regulator that mediates nanofiber ing a host polymer with a thermal transition in the regime of interest,we demonstrated even larger modulus changes (4200to 1.6MPa)upon exposure to emulated physiological conditions.Many echinoderms share the ability to rapidly and reversibly alter the stiffness of their connective tissue (1).In thecase of sea cucumbers (Fig.1,A and B),this morphing occurs within seconds and creates con-siderable survival advantages (1,2).A series of recent studies on the dermis of these invertebrateshas provided evidence that this defense mecha-nism is enabled by a nanocomposite structure in which rigid,high-aspect ratio collagen fibrils reinforce a viscoelastic matrix of fibrillin micro-fibrils (2–4).The stiffness of the tissue is regu-lated by controlling the stress transfer between adjacent collagen fibrils through transiently established interactions (5,6).These interactions are modulated by soluble macromolecules that are secreted locally by neurally controlled effec-tor cells.The dermis of the Cucumaria frondosa and other sea cucumber species represents a compelling model of a chemoresponsive material in which a modulus contrast by a factor of 10(~5to ~50MPa)is possible (7).Intrigued by this capability and with the goal of creating new dynamic materials for biomedical applications,we set out to investigate whether nanocompositescan be created that exhibit similar architecture and properties.The control of nanofiber inter-actions exploited here in solid polymer materials is similar to that observed in aqueous dispersions of poly(acrylic acid)-coated carbon nanotubes (8)or cellulose nanofibers (9),which have been shown to exhibit large viscosity changes upon variation of pH.The materials further comple-ment other polymeric systems with morphing mechanical behavior —for example,cross-linked polymers that change cross-link density upon a change in pH or ionic concentration (10,11).The first series of nanocomposites studied is based on a rubbery ethylene oxide –epichlorohydrin 1:1copolymer (EO-EPI)(Fig.1C)into which a rigid cellulose nanofiber network was incorpo-rated (Fig.1,C and D).The EO-EPI matrix dis-plays a low modulus and can accommodate the uptake of several chemical stimuli.Cellulose nano-fibers,isolated for this study from the mantles of sessile sea creatures known as tunicates (12),were used as the reinforcing component.These “whiskers ”exhibit high stiffness (tensile modu-lus ~143GPa)(13)and dimensions at the nano-meter scale (26nm ×2.2m m)(fig.S1).Similar nanofibers can be obtained from a range of re-newable biosources,including wood and cotton.Whiskers from tunicates were used here because their aspect ratio is higher than that of cellulose from other sources,which is advantageous for the formation of percolating architectures.Because of the high density of strongly interacting surface hydroxyl groups,cellulose whiskers have a strong tendency for aggregation (9,14).The whisker-whisker interactions can be moderated by the in-troduction of sulfate surface groups (Fig.1C),which promote dispersibility in select hydrogen-bond –forming solvents (14,15).This balance of attractive and repulsive interactions is the key for the fabrication of cellulose-whisker nanocomposites.1Department of Macromolecular Science and Engineering,Case Western Reserve University,Cleveland,OH 44106,USA.2Rehabilitation Research and Development,Louis Stokes Cleveland DVA Medical Center,10701East Boulevard,Cleveland,OH 44106,USA.3Department of Biomedical Engineering,Case Western Reserve University,Cleveland,OH 44106,USA.4Department of Chemistry,Case Western Reserve University,10900Euclid Avenue,Cleveland,OH 44106,USA.*To whom correspondence should be addressed.E-mail:christoph.weder@ (C.W.);stuart.rowan@ (S.J.R.)7MARCH 2008VOL 319SCIENCE1370REPORTSo n M a r c h 23, 2008w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o mGood dispersion is achieved during processing when whisker self-interactions are “switched off ”by competitive binding with a hydrogen-bond –forming solvent (Fig.1D)(14,15).Upon evap-oration of the solvent,the interactions among thewhiskers are “switched on,”and they assemble into a percolating network.This architecture and strong interactions among the whiskers maximize stress transfer and therewith the overall modulus of the nanocomposite (13,15,16).Similar to the seacucumber dermis,it should be possible to dynam-ically alter the modulus of the nanocomposites through the addition or removal of a chemical regulator that,in this case,would alter the extent of hydrogen bonding of the whiskers.3OAcnOOClxy nCellulose whisker EO-EPI PVAcInteraction “on”A B CFig.1.Natural model and bioinspired design ofchemomechanical nanocomposites.Pictures of a sea cucumber in relaxed (A )and stiffened (B )state demonstrating the firming of dermal tissue in the vicinity of the contacted area.(C )Chemical structure of cellulose whiskers isolated through sulfuric acid hydrolysis of tunicate cellulose pulp and the EO-EPI and PVAc matrix polymers used.(D )Schematic representation of the architecture and switching mechanism in the artificial nano-composites with dynamic mechanical properties.In the “on ”state,strong hydrogen bonds between rigid,percolating nanofibers maximize stress transfer and therewith the overall modulus of the nanocomposite.The interactions are switched “off ”by the introduction of a chemical regulator that allows for competitive hydrogen bonding.10101010E '(P a )Volume fraction filler ABC0.20% S o l v e n t U p t a k e (v /v )Volume fraction fillerVolume fraction filler0.2010101010E ' (P a )Fig.2.EO-EPI/whisker nanocomposites.(A )Tensile storage moduli E ′of EO-EPI/whisker nanocomposites as a function of volume fraction of cellulose whiskers.The nanocomposites were conditioned by either drying in vacuum,equilibrium swelling in deionized water,or swelling to saturation in de-ionized water followed by redrying in vacuum.Lines represent values predicted by the percolation and Halpin-Kardos model.The arrow indicates changes in modulus and volume fraction of whiskers resulting from aqueous swelling of one selected sample (19%v/v whiskers).(B )Solvent uptake as a function of whisker volume fraction under ambient conditions,immersion in deionized water,or isopropanol at room temperature.(C )Tensile storage moduli E ′of IPA-swollen EO-EPI/whisker nanocomposites as a function of volume fraction of cellulose whiskers.Lines represent values predicted by the percolation and Halpin-Kardos model.Data points represent averages (number of individual measurements,N ,=3to 6)±standard error measurements. SCIENCE VOL 3197MARCH 20081371REPORTSo n M a r c h 23, 2008w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o mEO-EPI/whisker nanocomposites were pro-duced by solution casting from dimethylform-amide (DMF),as previously reported (16),and the whisker content was varied between 0and 19%v/v.The thermomechanical properties of these materials were established by dynamic mechanical analyses (DMA)and tensile tests.DMA temperature sweeps (figs.S2and S3)display a glass transition temperature (T g )around –37°C (maximum of loss tangent,tan d ),which is independent of the whisker content and matches the T g of the neat EO-EPI matrix (fig.S2).The intensity of tan d decreases more than proportionally with the whisker concentra-tion (fig.S2),which is indicative of attractive polymer-whisker interactions.Figure 2A shows the tensile storage moduli (E ′)of dry EO-EPI/whisker nanocomposites extracted from the DMA traces for a temperature of 25°C,that is,in the rubbery regime far above T g .E ′increased with the whisker content from ~3.7MPa (neat polymer)to ~800MPa (19%v/v whiskers).The observed reinforcement suggests the formation of a percolating nanofiber network in which stress transfer is facilitated by hydrogen-bonding be-tween the whiskers.This hypothesis is supported by calculations obtained using a percolation model (16).Within the framework of the model,the tensile storage modulus of the nanocomposites (E ′)can be expressed as (17,18)E ′¼ð1−2y þy X r ÞE ′s E ′r þð1−X r Þy E ′r 2ð1−X r ÞE ′r þðX r −y ÞE ′swithy ¼X rX r −X c 1−X c0:4where E ′s and E ′r are the experimentally deter-mined tensile storage moduli of the neat EO-EPI (3.7MPa)and a neat tunicate whisker film (4.0GPa),respectively;y is the volume fraction of whiskers that participate in the load transfer;X r is the volume fraction of whiskers;and X c is the critical whisker percolation volume fraction calculated by 0.7/A .A is the aspect ratio of the whiskers and has a value of 84as determined by analysis of transmission electron microscopy (TEM)images (fig.S1).Figure 2A shows that the experimentally determined E ′values of dry EO-EPI/whisker nanocomposites agree with values obtained from Eq.1.By contrast,the data deviate strongly from the Halpin-Kardos model (fig.S4).This behavior is indicative for the formation of a percolating network of strongly interacting cellulose whiskers within the EO-EPI matrix (15,16).This architecture is confirmed by atomic force microscopy (AFM)(Fig.3A)and scanning electron microscopy (SEM)(Fig.3B)images,which both show that the cellulose whiskers form a percolating network within the EO-EPI matrix.Stress strain curves (fig.S5)reveal that the formation of a percolating networkof cellulose whiskers within the EO-EPI matrix not only affects E ′but also has a considerable influence on the maximum tensile strength (s ),which increased from 0.27±0.04(neat EO-EPI,stress at break)to 1.71±0.23MPa (14.3%v/v whiskers,stress at yield),whereas the elongation at break was reduced from 360±20to 6.7±0.8%(table S1).In view of the outstanding dispersibility of sulfate-modified cellulose whiskers in water (15),we elected to explore whether water could act as a chemical regulator for the whisker-whisker interactions in the EO-EPI/whisker nanocompos-ites.The atmospheric water uptake of the ma-terials is negligible under ambient conditions,that is,if not placed in an aqueous medium (Fig.2B).Dry EO-EPI/whisker nanocomposites were immersed in deionized water for 48hours to achieve equilibrium swelling (Fig.2B).Under these conditions,all compositions investigated exhibit modest aqueous swelling (~30%v/v),in-dicating that in the case of these compositions the water uptake is mainly governed by the matrix polymer with only minor variations due to whisk-er content.The tensile storage moduli for water-swollen EO-EPI/whisker nanocomposites were measured by DMA at 25°C in de-ionized water.A pronounced reduction of E ′compared with the dry nanocomposites can be observed (Fig.2A).The greatest mechanical contrast is seen in the case of the nanocomposite with the highest whisker content (nominally 19%v/v)(19),where E ′was reduced from ~800to 20MPa upon equilibrium swelling.At the same time,swelling with water leads to a significant decrease of the tensile strength (1.71±0.23to 0.37±0.11MPa for a 14.3%v/v whisker nanocomposite)(fig.S5and table S1)and an increase of the elongation at break (6.7±0.8to 17.8±0.39%).Control ex-periments with the neat EO/EPI (fig.S5and table S1)show minimal changes in tensile strength upon deionized water swelling.One argument that could be made against the interpretation that the observed changes inmodulus,elongation at break,and tensile strength are the result of switching off the nanofiber-nanofiber interactions is that simple swelling of the matrix alone could lead to a plasticizing ef-fect;however,careful analysis of our data shows that this is not the case.DMA traces (fig.S2)indicate that the EO-EPI/whisker nanocompos-ites do not undergo any phase transition that would lead to a drop in modulus,such as cross-linked polymer hydrogels and hygroscopic poly-mers,which can display a decrease of the glass transition temperature upon water uptake (20).Although E ′s of the neat EO-EPI is reduced from 3.7to 0.8MPa upon equilibrium swelling with water (Fig.2A),analysis in the context of the percolation model (Eqs.1and 2and fig.S7)shows that a reduction of E ′s alone cannot ac-count for a significant reduction of E ′.Figure 2A also reveals that even after correcting X r for water uptake,the percolation model no longer ade-quately describes E ′of the water-swollen nano-composites.By contrast,the moduli now are in much closer agreement with the Halpin-Kardos model (21),which has successfully been used to describe the modulus of nanocomposites in which the filler is homogeneously dispersed in a polymer matrix and does not display pro-nounced filler-filler interactions (22).The model assumes that the materials are equivalent to many layers of unidirectional plies oriented in alter-nating directions (–45°,0°,45°,and 90°),and the properties of the unidirectional reference ply are predicted by the Halpin-Tsaïequations where the tensile storage modulus in the longitudinal (E ′L )and transverse (E ′T )directions are given by (22,23)E ′L =E ′s [1+2(A )h L f r ]/(1−h L f r )and E ′T =E ′s [1+2h T f r ]/(1−h T f r )Thus,all data indicate that the stiffness reduction achieved in the EO-EPI/whisker nano-composites is related to the decoupling of the stress-transferring rigid nanofiber networkuponFig.3.Morphology of EO-EPI/whisker nanocomposites.(A )Representative AFM phase image of an ultramicrotomed nanocomposite containing 9.5%v/v whiskers in EO-EPI.The inset shows an AFM phase image of a neat EO-EPI reference (horizontal scale bar =500nm,vertical scale bar =phase shift 120to 0°).The samples were briefly (10s)immersed in tetrahydrofuran and rinsed with IPA to partially dissolve the polymer at the surface of the sample and to expose the inner structure of the films.(B )Representative SEM image of an untreated nanocomposite containing 9.5%v/v whiskers in EO-EPI.(1)(2)(3)(4)7MARCH 2008VOL 319SCIENCE1372REPORTSo n M a r c h 23, 2008w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o mintroduction of water as a competitive hydrogen-bonding agent.Consistent with the proposed mechanism,the switching is fully reversible:The materials adapted their original stiffness upon drying (Fig.2A).To investigate the specificity of the switching mechanism,we investigated the effect of isopro-panol (IPA)as the swelling agent.IPA was selected because it swells neat EO-EPI to a similar degree as water (Fig.2B)but is incapable of dispersing cellulose whiskers (16).The nano-composites swelled upon immersion in IPA (Fig.2B)to a level similar to that of the composites in water;however E ′barely changed in comparison to the dry state (Fig.2C),and the data fit the percolation model.This result confirms that the chemomechanical response is largely a result of disruption of the whisker-whisker interactions and not just plasticization of the material.By contrast,EO-EPI is plasticized considerably upon IPA swelling (E ′drops from 3.6to 0.93MPa).This contrast highlights the most important advantage of the nanocomposite approach over simple plasticization of a neat polymer.Although plasticization through solvent uptake,which is inherent to the latter,is a nonspecific process,the responsive nanocomposites can be designed to display a response that is specific to the nature of the stimulus.In addition,the nanocomposite ap-proach provides the ability to increase the initial stiffness and strength of the material and allows for the use of host polymers that have no thermal transition in the temperature regime of interest,such as the EO-EPI matrix used here.We are interested in exploiting dynamic mechanical materials in biomedical applications,specifically as adaptive substrates for intracortical microelectrodes.These implants have the ability to record brain unit activity (24).Brain-machine interfaces that rely on these electrodes providesolutions to medical conditions such as Parkin-son ’s disease,stroke,and spinal chord injuries (25).One problem with current microelectrodes is that the signal quality usually degrades within a few months,making chronic applications chal-lenging (26).One hypothesis for the cause of possible failure,especially in recording applica-tions,is that the micromotion of rigid electrodes within the soft cortical tissue chronically inflicts trauma on the surrounding neurons (27).We hypothesize that a mechanically adaptive elec-trode could alleviate this problem,and we are thus interested in designing devices that are initially rigid to allow for penetration of the pia mater during implantation (28)but that soften slowly and without excessive expansion upon implantation in response to the chemical envi-ronment within the brain (for an emulation,see Movie S1).For this application,an initial E ′of >4GPa is desirable to allow for the insertion of an electrode with typical dimensions into the cortex (29).Because EO-EPI/whisker nanocomposites display a substantially lower E ′,we sought to combine the switching mechanism with a chem-ically influenced thermal transition.We discov-ered that nanocomposites based on poly(vinyl acetate)(PV Ac)(Fig.1C)and cellulose whiskers display such a “dual ”responsive behavior.Our data show that,upon exposure to physiological conditions,the materials undergo a phase tran-sition;in addition,the reinforcing whisker net-work is disassembled.DMA experiments (Fig.4A and fig.S8)reveal that the neat PV Ac dis-plays a T g around 42°C,that,just above phys-iological temperature.E ′s of the neat polymer is considerably reduced upon heating from room temperature (1.8GPa at 23°C)to above T g (0.39MPa at 56°C)(this corresponds to T g +16°C and marks the temperature at which E ′s is starting to level off).As evidenced by DMA data,the introduction of cellulose whiskers into PV Ac has only a minimal influence on T g in the dry state (Fig.4A and fig.S8).The thermal transition is sharpened,and the temperature at which E ′begins to drop is increased from ~25to >40°C.For certain biomedical applications,this effect is very desirable,because it prevents the thermally induced softening of the material just upon ex-posure to body temperature.As a consequence of the already rather high stiffness of the glassy PV Ac matrix,only a modest reinforcement is observed for the nanocomposites below T g (E ′=5.1GPa with 16.5%v/v whiskers)(fig.S8).However,a dramatic effect is observed above T g ,where E ′is increased from 1.0MPa for the neat polymer matrix up to 814MPa with 16.5%v/v whiskers (at 56°C).The experimental data above T g match well with the percolation model (fig.S8),which indicates that also in this series a percolating network of strongly interacting whiskers is formed (15,16,18).The nanocom-posites demonstrate significant swelling in both deionized water and artificial cerebrospinal fluid (ACSF).The solvent uptake increases with in-creasing whisker content and temperature (fig.S9),lowers the T g to below physiological tem-perature (19to 23°C)(fig.S10),and reduces E ′dramatically.For example,the E ′of a 16.5%v/v whisker nanocomposite above T g is reduced from 814MPa (dry)to 10.8MPa (water swollen;data are for 56and 37°C,respectively,that is,16°C above the respective T g ).As for the water-swollen EO-EPI/whisker nanocomposites,the moduli of the ACSF swollen PV Ac/whisker nanocompos-ites are better described by the Halpin-Kardos than the percolation model (fig.S8),again in-dicative of decoupling of the stress-transferring nanofiber network upon introduction of water.Exposure to brain tissue,simulated here by immersing the samples into ACSF and heating to25303540455055106107108109101016.5 % v/v whiskers 12.2 % v/v whiskers 8.1 % v/v whiskers 4.0 % v/v whiskers 0.8 % v/v whiskers 0.0 % v/v whiskersE ' (P a )Temperature (°C)E ' (M P a )Time(min)Temperature ramp ABFig.4.PVAc/whisker nanocomposites.(A )Tensile storage moduli E ′of dry films of PVAc/whisker nanocomposites as a function of temperature.The nanocomposites contain between 0and 16.5%v/v whiskers.(B )Time-dependent modulus decrease of neat PVAc and a 12.2%v/v PVAc/whisker nanocomposite upon immersion into ACSF and increasing the temperature from 23°C to 37°C.Lines represent time required for temperature to increase from 23°C to 37°C and isothermal control at 37°SCIENCE VOL 3197MARCH 20081373REPORTSo n M a r c h 23, 2008w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o ma physiological temperature of 37°C at ~2°C/min (30)(Movie S1),leads to a pronounced reduction of E ′.Whereas the neat PV Ac (dry E ′s =1.8GPa at 25°C)instantly softens under these conditions (Fig.4B),the E ′of the whisker-reinforced nano-composites (see Fig.4B for a 12.2%v/v nano-composite)is reduced slowly over a period of 15min.The whisker-reinforced nanocomposite dis-plays a much higher dry E ′(4.2GPa at 25°C)than the neat PV Ac,but both materials reach nearly identical moduli upon immersion in ACSF at 37°C (1.6MPa).Our data support a simple and versatile strat-egy for the creation of polymer nanocomposites,whose architecture and mechanical adaptability closely mimic the proposed architecture and ob-served response of the sea cucumber dermis.The mechanical properties of these chemoresponsive materials can selectively and reversibly be con-trolled through the formation and decoupling of a three-dimensional network of well-individualized nanofibers in response to specific chemical trig-gers.It will be interesting to explore whether the framework can be adapted to nonchemical trig-gers,for example,optical or electrical stimuli.References and Notes1.T.Heinzeller,J.Nebelsick,Eds.,Echinoderms (Taylor &Francis,London,2004).2.T.Motokawa,Comp.Biochem.Physiol.B 109,613(1994).3.F.A.Thurmond,J.A.Trotter,J.Exp.Biol.199,1817(1996).4.I.C.Wilkie,J.Exp.Biol.205,159(2002).5.J.A.Trotter,T.J.Koob,Matrix Biol.18,569(1999).6.G.K.Szulgit,R.E.Shadwick,J.Exp.Biol.203,1539(2000).7.J.A.Trotter et al .,Biochem.Soc.Trans.28,357(2000).8.J.C.Grunlan,L.Liu,Y.S.Kim,Nano Lett.6,911(2006).9.M.M.de Souza Lima,R.Borsali,Macromol.Rapid Commun.25,771(2004).10.J.A.Jaber,J.B.Schlenoff,J.Am.Chem.Soc.128,2940(2006).11.D.M.Loveless,S.L.Jeon,S.L.Craig,J.Mater.Chem.17,56(2007).12.P.S.Belton,S.F.Tanner,N.Cartier,H.Chanzy,Macromolecules 22,1615(1989).13.A.Sturcova,J.R.Davies,S.J.Eichhorn,Biomacromolecules 6,1055(2005).14.O.van den Berg,J.R.Capadona,C.Weder,Biomacromolecules 8,1353(2007).15.M.A.S.Azizi Samir,F.Alloin,A.Dufresne,Biomacromolecules 6,612(2005).16.J.R.Capadona et al .,Nat.Nanotech.2,765(2007).17.M.Takayanagi,S.Uemura,S.Minami,J.Polym.Sci.C 5,113(1964).18.N.Ouali,J.Y.Cavaillé,J.Pérez,J.Plast.Rubber Comp.Process.Appl.16,55(1991).19.Swelling increased the volume of the nanocompositesand reduced the volume fraction of whiskers,X r .For example,when a nanocomposite with X r =19%v/v was swollen with water,X r decreased to 14%.Therepresentation of data in Fig.2A considers this effect to allow for analysis by the Halpin-Kardos model.A direct comparison of dry versus wet composites for the same fiber loading is shown in fig.S6.20.J.Kunzelman,B.R.Crenshaw,C.Weder,J.Mater.Chem.17,2989(2007).21.J.C.Halpin,J.L.Kardos,J.Appl.Phys.43,2235(1972).22.P.Hajji,J.Y.Cavaillé,V.Favier,C.Gauthier,G.Vigier,pos.17,612(1996).23.h L =[(E lr /E ′s )–1]/[(E lr /E ′s )+2A ],and h T =[(E tr /E ′s )–1]/[(E tr /E ′s )+2].A is the aspect ratio of the whiskers,f is equal to the volume fraction of the phase,and the subscripts s and r represent the soft phase and the rigid phase,respectively.E lr is the longitudinal Young ’s Modulus (130GPa),and E tr is the transverse Young ’s Modulus (5GPa)of an individual cellulosewhisker (22).To determine the tensile storage modulus of the isotropic nanocomposite (E ′),E ′L and E ′T must beinserted into one equation using the Halpin-Kardos model:E ′=4U 5(U 1–U 5)/U 1where U 1=1/8(3Q 11+3Q 22+4Q 66);U 5=1/8(Q 11+Q 22–2Q 12+4Q 66);Q 11=E ′L /(1–n 12n 21);Q 22=E ′T (1–n 12n 21);Q 12=n 12Q 22=n 21Q 11;Q 66=G 12;n 12=f r n r +f s n s =0.3;G 12=G s (1+hf r )/(1–hf r );h =(G r /G s –1)/(G r /G s +1),n is the Poisson ’s ratio,G is the shear modulus,and G r =1.77GPa.24.D.M.Taylor,S.I.H.Tillery,A.B.Schwartz,Science 296,1829(2002).25.A.B.Schwartz,Annu.Rev.Neurosci.27,487(2004).26.R.Biran,D.C.Martin,P.A.Tresco,J.Biomed.Mater.Res.82A ,169(2007).27.W.L.C.Rutten,Annu.Rev.Biomed.Eng.4,407(2002).28.D.H.Szarowski et al .,Brain Res.983,23(2003).29.K.Najafi,J.F.Hetke,IEEE Trans.Biomed.Eng.37,474(1990).30.Materials and methods are available as supporting material on Science Online.31.We thank F.Carpenter for the photography of thesea cucumber and L.McCorkle,J.Johnson,and M.Hitomi for assistance with the SEM,AFM,and TEM experiments,respectively.Financial support from DuPont (Young Professor Award to C.W.),the L.Stokes Cleveland VAMC Advanced Platform Technology Center,an Ohio Innovation Incentive Fellowship (to K.S.),theDepartment of Veterans Affairs Associate Investigator Career Development Program (to J.C.),and the National Institutes of Health are gratefully acknowledged.The authors declare that they have no competing financial interest.Supporting Online Material/cgi/content/full/319/5868/1370/DC1Materials and Methods Figs.S1to 10Table S1References Movie S16November 2007;accepted 1February 200810.1126/science.1153307Heterogeneous Nucleation Experiments Bridging the Scale from Molecular Ion Clusters to NanoparticlesPaul M.Winkler,1Gerhard Steiner,1Aron Vrtala,1Hanna Vehkamäki,2Madis Noppel,3Kari E.J.Lehtinen,4Georg P.Reischl,1Paul E.Wagner,1Markku Kulmala 2*Generation,investigation,and manipulation of nanostructured materials are of fundamental and practical importance for several disciplines,including materials science and medicine.Recently,atmospheric new particle formation in the nanometer-size range has been found to be a global phenomenon.Still,its detailed mechanisms are mostly unknown,largely depending on the incapability to generate and measure nanoparticles in a controlled way.In our experiments,an organic vapor (n -propanol)condenses on molecular ions,as well as on charged and uncharged inorganic nanoparticles,via initial activation by heterogeneous nucleation.We found a smooth transition in activation behavior as a function of size and activation to occur well before the onset of homogeneous nucleation.Furthermore,nucleation enhancement for charged particles and a substantial negative sign preference were quantitatively detected.Condensational growth,evaporation,and heterogeneous chemistry are important phenomena in materials science,fluid dynamics,aerosol physics and technology,and atmospheric chemistry,including cloud micro-physics and cloud chemistry.A prerequisite for the start of condensation is homogeneous nu-cleation of new particles or the activation of preexisting particles by heterogeneous nuclea-tion.The latter can occur either on ions,soluble particles,or insoluble particles,and is energet-ically easier than homogeneous nucleation (1).Both particle formation processes are of fun-damental as well as practical importance andhave been the subject of investigations for more than a century (2).Important examples repre-senting the different processes are given by the use of the Wilson cloud chamber (3)in high-energy physics for the case of ions,the for-mation of cloud droplets in the troposphere for the case of soluble particles,and the occurrence of ice nucleation for the case of insoluble seed particles (4).Atmospheric observations suggest that the initial formation and growth are two uncoupled processes (5–7),and therefore the activation mechanism of small clusters is of vital importance.Understanding the formation and initial growth processes in detail is also crucial to control the production of nanomate-rials (8).In this paper,we present experimental results for the activation of molecular cluster ions,charged and neutral clusters,and nanometer-size particles having almost monodisperse size distributions,1Fakultät für Physik,Universität Wien,Boltzmanngasse 5,A-1090Wien,Austria.2University of Helsinki,Department of Physical Sciences,Post Office Box 64,00014University of Helsinki,Finland.3Institute of Physics,University of Tartu,18Ülikooli Street,50090Tartu,Estonia.4Department of Physics,University of Kuopio and Finnish Meteorological Institute,Post Office Box 1627,70211Kuopio,Finland.*To whom correspondence should be addressed.E-mail:markku.kulmala@helsinki.fi7MARCH 2008VOL 319SCIENCE1374REPORTSo n M a r c h 23, 2008w w w .s c i e n c e m a g .o r g D o w n l o a d e d f r o m。
北京大学硕士论文

iii
iv
目 录
摘 要 剪切流中的一维棒状液晶随机模型的分析 i 1 3 3 4 7 7 9 9
第一部分 第一章 前言
§1.1 引言 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . §1.2 问题的数学表述 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 第二章 解的存在唯一性
§A.0.1 小时间的不动点结果 . . . . . . . . . . . . . . . . . . . . . . 63 §A.0.2 大范围时间解的构造 . . . . . . . . . . . . . . . . . . . . . . 64 附录二 参考文献
n Θj tn (yi ) − Θi,j L2 ω
要
第一部分中, 我们考虑剪切流中的液晶聚合物的随机模型. 液晶聚合物分子的 运动通过带有分子间相互作用 Maier-Saupe 势的非线性随机微分方程来刻画. 宏观 的应力张量来自聚合物微观构象的系综平均. 我们首先通过压缩映射方法证明非线 性的随机微分方程强解的存在唯一性, 然后针对耦合的偏微分方程 – 随机微分方程 组进行先验估计,采用 Galerkin 方法证明耦合的流体 – 聚合物方程组存在小时间 范围内的唯一解. 在考虑系统的数值离散格式的时候, 由于随机微分方程的解是一 个非线性扩散过程, 经典的蒙特卡洛方法和大数定律不再适用, 我们采用弱相互作 用的随机过程来逼近, 并且在加上针对流体计算的交错网格差分格式之后, 证明了 1 2 完整的杂交耦合格式的收敛性,收敛速度为 O(h + δt + √M ). 本文的第二部分针对复杂流体的一种特殊物理现象 – spurt 现象,总结了一维 简单剪切流的情况下 spurt 现象的理论结果, 强调 spurt 现象和非单调的应变应力 关系的重要联系.回顾和发展了当前的针对全耦合模型的数值方法.数值计算了 1 维硬棒模型、 Hookean 模型、 FENE 模型和 FENE 近似模型的应变应力的单调函数 关系, 从而否定了这些模型出现 spurt 现象的可能性. 其中针对 2 维 FENE 模型的 计算采用的数值方法包括计算 Fokker Planck 方程的谱方法和求解随机微分方程的 布朗动力学随机模拟,两种方法都得出了相同的数值结果.针对 3 维 FENE 模型 的布朗动力学随机模拟表明 1 维简单剪切流中 2 维 FENE 模型和 3 维 FENE 模 型的应变应力的函数关系基本没有区别.
PEC材料工程英语证书考试-材料特性术语

PEC材料工程英语证书考试-材料特性术语DensityUnits: SI: Mg/m3; cgs: g/cm3; Imperial: lb/ft3The density is the weight per unit volume. We measure it today as Archimedes did: by weighing the material in air and in a fluid of known density.Atomic VolumeUnits: SI: m3/kmol; cgs: 106cm3/kmol; Imperial: in3/kmolThe atomic (or molecular) volume Vm is the average volume per 103N0 of atoms in the structure, where N0 is Avogadro's number (6.022 x 1023/mol). For a pure element, it is simply:where A is the atomic weight in kg/kmol and r is the density in kg/m3. For compounds the average atomic volume iswhere M is the molecular weight and n is the number of atoms in the molecule. Thus for a compound with the formula AxBy it iswhere AA is the atomic weight of element A, and AB is the atomic weight of element B. For a polymer (CxHyOz)n it is thereforewhere AC is the atomic weight of carbon, and so on. The atomic volume is involved in many property correlations (and thus is crucial for checking and estimating properties) and, together with the density, it gives the atomic weight.Energy ContentUnits: SI: MJ/kg; cgs: kcal/g; Imperial: kcal/lbThe energy content of a material is an approximate estimate of the energy used to make it from its naturally-occurring ores, feed stocks or sources, plus the energy content of the source material itself. (Usually the energy content of the source material is small, except, for example, when the source is oil.) Thus the energy content of Aluminium is dominated by the electric power absorbed in its extraction from Bauxite; that for polymers, for which the feed stock is crude oil is the energycontained in the oil itself plus that of the subsequent processing; and that for wood is the energy content of wood plus the energy required to harvest it.Young's ModulusUnits: SI: GPa; cgs: 1010dyne/cm2; Imperial: 106psiYoung's modulus, E, is the slope of the initial, linear-elastic part of the stress-strain curve in tension or compression. For isotropic materials it is related to the bulk modulus K and to the shear modulus G bywhere n is Poisson's ratio. Commonly n = 1/3, and hence E = K, and E = (8/3)G.Bulk ModulusUnits: SI: GPa; cgs: 1010dyne/cm2; Imperial: 106psiThe bulk modulus, K, measures the elastic response to hydrostatic pressure, p:where v is the volume. For isotropic solids it is related to Young's modulus E and to the shear modulus G bywhere n is Poisson's ratio. When n = 1/3, E = K, and K = (8/3)G.Shear ModulusUnits: SI: GPa; cgs: 1010dyne/cm2; Imperial: 106psiThe shear modulus is the initial, linear elastic slope of the stress-strain curve in shear. For isotropic materials it is related to Young's modulus E and to the bulk modulus K and Poisson's ratio byWhen n = 1/3, G = (3/8)E, and G = (3/8)K.Poissons RatioUnits: DimensionlessPoisson's ratio n is the negative of the ratio of the lateral strain to uniaxial strain, in axial loading.Its value for many solids, is close to 1/3. For elastomers it is just under 0.5.Elastic Limit/Yield StrengthUnits: SI: MPa; cgs: 107dyne/cm2; Imperial: 103psiThe 'elastic limit' sel, of a solid requires careful definition.For metals, the elastic limit is defined as the 0.2% offset yield strength. This represents the stress at which the stress-strain curve for uniaxial tensile loading deviates by a strain of 0.2% from the linear-elastic line. It is the same in tension and compression. It is the stress at which dislocations move large distance through the crystals of the metal.For polymers, the elastic limit is the stress at which the uniaxial stress-strain curve becomes markedly nonlinear: typically, a strain of 1%. This may be caused by 'shear yielding' (irreversible slipping of molecular chains) or by 'crazing' (formation of low density, crack-like volumes which scatter light, making the polymer look white).For fine ceramics and glasses, the database entry for the elastic limit is an estimate, based on the tensile strength (which is low due to brittle fracture). When based on direct measurements at high pressures, or on hardness measurements, of the stress required to cause plastic flow, it is very high: higher than the compressive strength, which is lowered by crushing.For composites, the elastic limit is best defined by a set deviation from linear-elastic uniaxial behaviour: 0.5% is taken in the database.Elastic limit depends on the mode of loading. For modes of loading other than uniaxial tension, such as shear and multiaxial loading, the strength is related to that in simple tension by a yield function. For metals, the V on Mises yield function works well. It specifies the relationship between the principal stresses s1, s2, s3 and the yield strength sy(elastic limit):The Tresca function is sometimes more convenient, because it is less complicated:For ceramics, a Coulomb flow law is used:Tensile StrengthUnits: SI: MPa; cgs: 107dyne/cm2; Imperial: 103psiThe Tensile strength is the nominal stress at which a round bar of the material, loaded in tension separates. For brittle solids: ceramics, glasses and brittle polymers—it is much less than the compressive elastic limit. For metals, ductile polymers and most composites—it is larger than the yield strength by a factor ranging from 1.1 to 3.Compressive StrengthUnits: SI: MPa; cgs: 107dyne/cm2; Imperial: 103psiFor metals, the compressive strength is the same as the tensile yield strength.Polymers are approximately 20% stronger in compression than in tension.In Ceramics, compressive strength sc is governed by crushing and is much larger than the tensile strength st. TypicallyComposites which contain fibres (including natural composites like wood) are a little weaker (up to 30%) in compression than tension because the fibres buckle.DuctilityUnits: Dimensionless (strain)The tensile ductility is the permanent increase in length of a tensile specimen before fracture, expressed as a fraction of the original gauge length.HardnessUnits: SI: MPa; cgs: 107dyne/cm2; Imperial: 103psiThe hardness of a material is measured by pressing a pointed diamond or hardened steel ball into its surface. The hardness H is defined as the indenter force divided by the projected area of the indent. It can be shown that the hardness is related to the yield strength sy of ductile materials by H = 3 sy.Many ceramics, and even glasses, are ductile under small indents, allowing the yield strength in compression (elastic limit) to be inferred from hardness tests.Modulus of RuptureUnits: SI: MPa; cgs: 107dyne/cm2; Imperial: 103psiWhen the material is difficult to grip (as is a ceramic), its strength can be measured in bending. The modulus of rupture (MOR) is the maximum surface stress in a bent beam at the instant of failure. One might expect this to be exactly the same as the strength measured in tension, but it is always larger (by a factor of about 1.3) because the volume subjected to this maximum stress is small, and the probability of a large flaw lying in the highly stressed region is also small. (In tension all flaws see the maximum stress.)The MOR strictly only applies to brittle materials. For ductile materials, the MOR entry in the database is the ultimate strength.Fracture ToughnessUnits: SI: MPa.m1/2; cgs: 108 dyne/cm3/2; Imperial ksi.in1/2The fracture toughness Kc, is a measure of the resistance of a material to the propagation of a crack. It can be measured by loading a sample containing a deliberately-introduced crack of length 2c and then recording the tensile stress s at which the crack propagates. Fracture toughness is then calculated fromwhere Y is a geometric factor, near unity, which depends on details of the sample geometry. Measured in this way, Kchas well defined values for brittle materials (ceramic, glasses, many polymers and low toughness metals like cast iron).In ductile materials, a plastic zone develops at the crack tip, which introduces new features into the way cracks propagate. This necessitates more complex characterisation. Nevertheless, values for Kc are cited and are useful as a way of ranking materials.Endurance LimitUnits: SI: MPa; cgs: 107dyne/cm2; Imperial: 103psiThe endurance limit is defined as the maximum applied cyclic stress amplitude for an 'infinite' fatigue life. Generally 'infinite' life means more than 107 cycles to failure.Loss-CoefficientUnits: DimensionlessThe loss-coefficient measures the degree to which a material dissipates vibrational energy. If a material is loaded elastically to a stress smax, it stores elastic energyper unit volume. If it is loaded and then unloaded, it dissipates energy equivalent to the area of the stress-strain hysteresis loop:The loss coefficient h is defined asThe cycle can be applied in many different ways—some fast, some slow. The value of h usually depends on the time-scale or frequency of cycling.TemperaturesUnits: SI: K; cgs: K; Imperial: °RThe Melting temperature, TmThe temperature at which a material turns suddenly from solid to liquid. The melting temperature of an alloy is usually less than the melting temperature of the parent metals.The Glass temperature, TgA property of non-crystalline solids which do not have a sharp melting point. It characterises the transition from true solid to viscous liquid in these materials.Thermal ConductivityUnits: SI: W/m.K; cgs: cal/cm.s.K; Imperial: Btu/h.ft.FThe rate at which heat is conducted through a solid at 'steady state' (meaning that the temperature profile does not change with time) is governed by the thermal conductivity l. It is measured by recording the heat flux J (W/m²) flowing from surface at temperature T1 to one at T2 in the material, separated by a distance X:In practice, the measurement is not easy (particularly for materials with low conductivities), but reliable data are now generally available.Specific HeatUnits: SI: J/kg.K; cgs: cal/g.K; Imperial: Btu/lb.FCp is the specific heat capacity at constant pressure. It specifies the amount of heat required to raise the temperature of 1 kg of material by 1°C (K). It is measured by the standard technique of calorimetry.Thermal Expansion CoefficientUnits: SI: 10-6/K; cgs: 10-6/K; Imperial: 10-6/FMost materials expand when they are heated. The linear thermal expansion coefficient a is the thermal strain per degree K.If the material is thermally isotropic, the volumetric expansion per degree is 3a. If it is anisotropic, two or more coefficients are required and the volumetric expansion is the sum of the principal thermal strains.Latent Heat of FusionUnits: SI: kJ/kg; cgs: cal/g; Imperial: Btu/lbThe latent heat of fusion, Lm, is the heat absorbed by a crystalline solid on melting; the heat is absorbed at constant temperature (the melting temperature), Tm. Amorphous solids (including many polymers) do not have a sharp melting point. When these pass from a solid state to one which is fluid they do so over a wide temperature range, centred roughly about the glass temperature Tg. It is then not appropriate to define a latent heat of melting.ResistivityUnits: SI: 10-8W.m; cgs: 10-6W.cm; Imperial: 10-8W.mThe resistivity R is the resistance of a unit cube with unit potential difference between a pair of faces. It varies over an immense range: from a little more than 1 in units of 10-8W.m (which are the same as mWcm) for good conductors, to more than 1024 in the same units, for the best insulators.Dielectric ConstantUnits: DimensionlessWhen a material (such as that used in a capacitor) is placed in an electric field, it becomes polarised and charges appear at its surfaces which tend to screen the interior from the external field. The tendency to polarise is measured by the dielectric constant.Power FactorUnits: DimensionlessPolarisation involves the movement of charged particles (electrons, ions or molecules which carry a dipole moment). In an oscillating external field, the charged particles move between two alternative configurations, and in doing so they dissipate energy. The energy lost in this way is measured by the power factor, which, for our purposes, can be thought of as the dielectric constant times the 'loss tangent'.Breakdown PotentialUnits: SI: 106 V/m; cgs: V/cm; Imperial: V/milIf the potential gradient becomes too steep, normal conduction is replaced by electrical breakdown: a catastrophic electron-cascade, usually causing permanent damage. The breakdown potential-gradient is the material property that characterises this effect.。
高分子物理(第三版)第七章--高分子的屈服和断裂(玻璃...

Thedevelopmentof materialsover time.The materialsof pre-history, onthe left,all occurnaturally;the challengefor theengineers ofthat era wasone ofshaping them.Thedevelopmentofthermochemist 11121314 1516 17在小伸长时,拉伸应变通常以单位长度的伸长来定义。
应变:。
:为材料的起始截面积。
当材料发生较大形变时,上式计算的应力与材料的真实应力会发生较大的偏差,这时正确计算应力应该以真实截面积真应力:相应地可提出真应变的定义,如果材料在某一时刻长度从+dl i,则真应变为:真应变:对于理想的弹性团体,应力与应变关系服从虎克定律,25简单拉伸时的杨氏模量:在简单剪切的情况下,材料受到的力F 是与截面相平行的大小相等、方向相反的两个力。
在这剪切力作用下,材料将发生偏斜,偏斜角的正切定义为切应变。
当切应变足够小时,。
相应地,材料的剪切应力为:剪切模量:θγ≈切应变:剪切位移S ,剪切角θ,剪切面间距d体积模量:必须注意的是,试样宽度和厚度在拉伸过程中是随试样的伸长屈服强度断裂强度Polymers with different properties增强途径增强机理:活性粒子吸附大分子,形成链间物理交联,活性粒子起物理交联点的作用。
惰性填料怎么办?例:PVC+CaCO,PP+滑石粉glassy fiber+polyester增强机理:纤维作为骨架帮助基体承担载荷。
Carbon fiber弯曲模量:增强机理:热致液晶中的液晶棒状分子在共混物中形成微纤结构而到增强作用。
由于微纤结构是加工过程中由液晶棒状分子在共混无物基体中就地形成的,故称做“原位”复合增强。
Charpy试验IZOD试验40补充材料:聚合物的韧性与增韧-----冲击强度Impact strength——是衡量材料韧性的一种指标高速拉伸试验测量材料冲击强度的依据。
应力应变的关系和行为外文文献翻译、中英文翻译、外文翻译
原文:Stress-Strain Relationships and Behavior5.1INRODUCTION5.2MODELS FOR DEFORMATION BEHAVIOR5.3ELASTIC DEFORMATION5.4ANISOTROPIC MATERIALS5.5SUMMARYOBJECTIVES•Become familiar with the elastic, plastic, steady creep, and transient creep types of strain, as well as simple rheological models for representing the stress-strain-time behavior for each.•Explore three-dimensional stress-strain relationships for linear-elastic deformation in isotropic materials, analyzing the interdependence of stresses or strains imposed in more than one direction.•Extend the knowledge of elastic behavior to basic cases of anisotropy, including sheets of matrix-and f iber composite material.5.1INRODUCTIONThe three major types of deformation that occur in engineering materials are elastic, plastic, and creep deformation. These have already been discussed in Chapter 2 from the viewpoint of physical mechanisms and general trends in behavior for metals, polymers, and ceramics. Recall that elastic deformation is associated with the stretching, but not breaking, of chemical bonds. In contrast, the two types of inelastic deformation involve processes where atoms change their relative positions, such as slip of crystal planes or sliding if chain molecules. If the inelastic deformation is time dependent, it is classed as creep, as distinguished from plastic deformation, which is not time dependent.In engineering design and analysis, equations describing stress-strain behavior, called stress-strain relationships, or constitutive equations, are frequently needed. For example, in elementary mechanics of materials, elastic behavior with a linear stress-strain relationship is assumed and used in calculating stresses and deflections in simple components such as beams and shafts. More complex situations of geometry and loading can be analyzed by employing the same basic assumptions in the form of theory of elasticity. This is now often accomplished by using the numerical technique called finite element analysis with a digital computer.Stress-strain relationships need to consider behavior in three dimensions. In addition to elastic strains, the equations may also need to include plastic strains and creep strains. Treatment of creep strain requires the introduction of time as an additional variable. Regardless of the method used, analysis to determine stresses and deflections always requires appropriate stress-strain relationships for the particular material involved.For calculations involving stress and strain, we express strain as a dimensionless quantity, as derived from length change, £= △L/L. Hence, strains given as percentages need to be converted to the dimensionless form, £=£%/100, as do strains given as microstrain, £=£/106.In the chapter, we will first consider one-dimensional stress-strain behavior and some corresponding simple physical models for elastic, plastic, and creep deformation. The discussion of elastic deformation will then be extended to three dimensions, starting with isotropic behavior, where the elastic properties are the same in all directions. We will also consider simple cases of anisotropy, where the elastic properties vary with direction, as in composite materials. However, discussion of three-dimensional plastic and creep deformation behavior will be postponed to Chapters 12 and 15, respectively.5.2MODELS FOR DEFORMATION BEHAVIORSimple mechanical devices, such as linear springs, frictional sliders, and viscous dashpots, can be used as an aid to understanding the various types of deformation. Four such models and their responses to an applied force are illustrated in Fig.5.1. Such devices and combinations of them are called rheological models.Elastic deformation, Fig.5.1(a), is similar to the behavior of a simple linear spring characterized by its constant k. The deformation is always proportional to force,x=P/k, and it is recovered instantly upon unloading. Plastic deformation, Fig.5.1(b), is similar to the movement of a block of mass m on a horizontal plane. The static and kinetic coefficients of friction M are assumed to be equal, so that there is a critical force for motion P0=M mg, where g is the acceleration of gravity. If a constant applied force P’ is less than the critical value, P5<P0, no motion occurs. However, if it is greater, P5>P0, the block moves with an accelerationa =(P’-P0)/m (5.1) When the force is removed at time t, the block has moved a distance a=at 2/2, and it remains at this new location. Hence, the model behavior produces a permanent deformation, x p.Creep deformation can be subdivided into two types. Steady-state creep, Fig.5.1(c),proceeds at a constant rate under constant force. Such behavior occurs in a linear dashpot, which is an element where the velocity,文=dx / dt , is proportional to the force. The constant of proportionality is the dashpot constant c, so that a constant value of force P ’ gives a constant velocity, X - P '/c , resulting in a linear displacement versus time behavior. When the force is removed, the motion stops, so that the deformation is permanent---that is, not recovered. A dashpot could be physically constructed by placing a piston in a cylinder filled with a viscous liquid, such as a heavy oil. When a force is applied, small amounts of oil leak past the piston, allowing the piston to move. The velocity of motion will be approximately proportional to the magnitude of the force, and the displacement will remain after all force is removed. 制P = KX(CT = &) 阕 Steady-slate creep P =点 何=哨 I'd) Transient creep P - kx + ex 旧-E E +侬) 面即熬:;2嚷?寰;吃黑黑 defamiation The (fisplarement-dme and The second type of creep, is called transient creep, Fig.5.1(d), slows down as time passes. Such behavior occurs in a spring mounted parallel to a dashpot. If a constant force P ’ is applied, the deformation increases with time. But an increasing fraction of the applied force is needed to pull against the spring as x increases, so that less force is available to the dashpot, and the rate of deformation decreases. The deformation approaches the value P 7k if the force is maintained for a long period of time. If the De script ion 173ModelP-x Path 43^Force加put。
材料科学工程专业论文 Advanced Engineering Materials
Advanced Engineering MaterialsTypes of MaterialsMaterials may be grouped in several ways. Scientists often classify materials by their state: solid, liquid, or gas. They also separate them into organic (once living) and inorganic (never living) materials. Today’s materials can be classified as metals and alloys, as polymers or plastics, as ceramics, or as composites; composites, most of which are man-made, actually are combinations of different materials.For industrial purposes, materials are divided into engineering materials or nonengineering materials. Engineering materials are those used in manufacture and become parts of products.Nonengineering materials are the chemicals, fuels, lubricants, and other materials used in the manufacturing process, which do not become part of the product.Engineering materials may be further subdivided into: ①Metal ②Ceramics ③Composite ④Polymers, etc.Metals and Metal AlloysMetals are elements that generally have good electrical and thermal conductivity. Many metals have high strength, high stiffness, and have good ductility. Some metals, such as iron, cobalt and nickel, are magnetic. At low temperatures, some metals and intermetallic compounds become superconductors.What is the difference between an alloy and a pure metal? Pure metals are elements which come from a particular area of the periodic table. Examples of pure metals include copper in electrical wires and aluminum in cooking foil and beverage cans.Alloys contain more than one metallic element. Their properties can be changed by changing the elements present in the alloy. Examples of metal alloys include stainless steel which is an alloy of iron, nickel, and chromium; and gold jewelry which usually contains an alloy of gold and nickel.Why are metals and alloys used? Many metals and alloys have high densities and are used in applications which require a high mass-to-volume ratio.Some metal alloys, such as those based on aluminum, have low densities and are used in aerospace applications for fuel economy. Many alloys also have high fracture toughness, which means they can withstand impact and are durable.What are some important properties of metals?Density is defined as a material’s mass divided by its volume. Most metals have relatively high densities, especially compared to polymers.Fracture toughness can be described as a material’s ability to avoid fracture, especially when a flaw is introduced. Metals can generally contain nicks anddents without weakening very much, and are impact resistant. A football player counts on this when he trusts that his facemask won’t shatter.Plastic deformation is the ability of bend or deform before breaking. As engineers, we usually design materials so that they don’t deform under normal conditions. You don’t want your car to lean to the east after a strong west wind.However, sometimes we can take advantage of plastic deformation. The crumple zones in a car absorb energy by undergoing plastic deformation before they break.The atomic bonding of metals also affects their properties. In metals, the outer valence electrons are shared among all atoms, and are free to travel everywhere. Since electrons conduct heat and electricity, metals make good cooking pans and electrical wires.It is impossible to see through metals, since these valence electrons absorb any photons of light which reach the metal. No photons pass through.Alloys are compounds consisting of more than one metal. Adding other metals can affect the density, strength, fracture toughness, plastic deformation, electrical conductivity and environmental degradation.Ceramics and GlassesA ceramic is often broadly defined as any inorganic nonmetallic material.By this definition, ceramic materials would also include glasses; however, many materials scientists add the stipulation that “ceramic” must also be crystalline.A glass is an inorganic nonmetallic material that does not have a crystalline structure. Such materials are said to be amorphous.Properties of Ceramics and GlassesSome of the useful properties of ceramics and glasses include high melting temperature, low density, high strength, stiffness, hardness, wear resistance, and corrosion resistance.Many ceramics are good electrical and thermal insulators. Some ceramics have special properties: some ceramics are magnetic materials; some are piezoelectric materials; and a few special ceramics are superconductors at very low temperatures. Ceramics and glasses have one major drawback: they are brittle.Ceramics are not typically formed from the melt. This is because most ceramics will crack extensively (i.e. form a powder) upon cooling from the liquid state. CompositesComposites are formed from two or more types of materials. Examples include polymer/ceramic and metal/ceramic composites. Composites are used because overall properties of the composites are superior to those of the individual components.For example: polymer/ceramic composites have a greater modulus than the polymer component, but aren’t as brittle as ceramics.Two types of composites are: fiber-reinforced composites and particle-reinforced composites.Fiber-reinforced CompositesReinforcing fibers can be made of metals, ceramics, glasses, or polymers that have been turned into graphite and known as carbon fibers. Fibers increase themodulus of the matrix material.The strong covalent bonds along the fiber’s length give them a very high modulus in this direction because to break or extend the fiber the bonds must also be broken or moved.Fibers are difficult to process into composites,making fiber-reinforced composites relatively expensive.Fiber-reinforced composites are used in some of themost advanced, and therefore most expensive sports equipment, such as a time-trial racing bicycle frame which consists of carbon fibers in a thermoset polymer matrix.Body parts of race cars and some automobiles are composites made of glass fibers (or fiberglass) in a thermoset matrix.Fibers have a very high modulus along their axis, but have a low modulus perpendicular to their axis. Fiber composite manufacturers often rotate layers of fibers to avoid directional variations in the modulus.Particle-reinforced compositesParticles used for reinforcing include ceramics and glasses such as small mineral particles, metal particles such as aluminum, and amorphous materials, including polymers and carbon black.Particles are used to increase the modulus of the matrix, to decrease the permeability of the matrix, to decrease the ductility of the matrix. An example of particle-reinforced composites is an automobile tire which has carbon black particles in a matrix of polyisobutylene elastomeric polymer.PolymersA polymer has a repeating structure, usually based on a carbon backbone. The repeating structure results in large chainlike molecules. Polymers are useful because they are lightweight, corrosion resistant, easy to process at low temperatures and generally inexpensive.Some important characteristics of polymers include their size (or molecular weight), softening and melting points, crystallinity, and structure. The mechanical properties of polymers generally include low strength and high toughness. Their strength is often improved using reinforced composite structures.Important Characteristics of PolymersSize. Single polymer molecules typically have molecular weights between 10,000 and 1,000,000g/mol—that can be more than 2,000 repeating units depending on the polymer structure!The mechanical properties of a polymer are significantly affected by the molecular weight, with better engineering properties at higher molecular weights.Thermal transitions. The softening point (glass transition temperature) and the melting point of a polymer will determine which it will be suitable for applications. These temperatures usually determine the upper limit for which a polymer can be used.For example, many industrially important polymers have glass transition temperatures near the boiling point of water (100℃, 212℉), and they are most useful for room temperature applications. Some specially engineered polymers can withstand temperatures as high as 300℃(572℉).Crystallinity. Polymers can be crystalline or amorphous, but they usually have a combination of crystalline and amorphous structures (semi-crystalline).Application of these materials depend on their properties; therefore, we need to know what properties are required by the application and to be able to relate those specification to the material.For example, a ladder must withstand a design load, the weight of a personusing the ladder. However, the material property that can be measured is strength, which is affected by the load and design dimension. Strength values must therefore be applied to determined the ladder dimensions to ensure safe use. Therefore, in general, the structures of metallic materials have effects on their properties.In a “tensile test” a sample is gradually elongated to failure and the tensile force required to elongate the sample is measured using a load cell throughout the test. The result is a plot of tensile force versus elongation.True stress and true strain provide the most accurate description of what actually happens to the material during testing and so are widely used in materials science. For engineering design, however, there are two problems.Firstly, true stress requires a knowledge of the value of A throughout the test, whereas in real world applications the designer of structures chooses an initial cross sectional area (A0). Secondly true strain is not very easy to visualize. Consequently for engineering applications an “engineering” stress (s) and strain (e) are used in place of true stress and true strain:s = F / A0 and e = (l1 - l0) / l0Stress has units of Pa (i.e. N m-2) and strain is dimensionless. The concept of a stress is clearly closely related to that of pressure. Using the definitions of stress and strain given above, the load versus elongation curve produced by the tensile test can be converted into true stress - strain or engineering stress - strain curves. Using these curves, it is now possible to describe the mechanical properties of metals and alloys.In true and engineering stress-strain relationships for a “typical” metal, linear portion of the stress strain curves the material is deforming elastically at the Initial.In other words, if the load were removed the material will return to its initial, undeformed condition. In the linear elastic region, the “stiffness” or “elastic modulus” is the amount of stress required to produce a given amount of strain.For a tensile test, stiffness is described by Young’s modulus (E), which is given by: E = s / e or E = s / eThe greater the value of the stiffness, the more difficult it will be to produce elastic deformation. Thus, for example, in selecting a material for the springs of a vehicle, stiffness would be a key engineering design criterion.On exceeding a certai n stress, known as the “yield stress” or “yield strength” (sy or sy in true and engineering stress respectively), the stress - strain curve ceases to be linear and the material begins to undergo permanent “plastic” deformation.In the plastic region of the stress - strain curve, it is apparent that the stressrequired to continue plastic deformation is higher than that required to make the material yield. This phenomenon is called “work hardening” or “strain hardening”.In the true stress - strain curve, it can be seen that work hardening actually continues right up until failure at the failure stress sf. In contrast the engineering stress - strain curve shows a maximum stress, the “ultimate ” (UTS), prior to final failure.。
应力应变英语
应力应变英语Stress and Strain in EngineeringStress and strain are fundamental concepts in the field of engineering, as they are crucial in understanding the behavior of materials and structures under various loading conditions. These two interrelated quantities are essential for the design, analysis, and optimization of engineering systems, from small components to large-scale structures.Stress, in the context of engineering, can be defined as the internal force per unit area acting within a material or structure. It is a measure of the intensity of the internal forces that arise due to the application of external loads or constraints. Stress can be classified into different types, such as normal stress, shear stress, and torsional stress, depending on the direction and nature of the forces acting on the material.Normal stress is the stress that acts perpendicular to the surface of a material, and it can be either compressive or tensile. Compressive stress occurs when the material is subjected to forces that tend to push it together, while tensile stress occurs when the material issubjected to forces that tend to pull it apart. Shear stress, on the other hand, is the stress that acts parallel to the surface of a material, causing the material to slide or deform in a particular direction.Strain, on the other hand, is a measure of the deformation of a material or structure due to the application of stress. It is the change in the size or shape of a material relative to its original dimensions. Strain can be classified into different types, such as normal strain and shear strain, just like stress.Normal strain is the change in the length of a material divided by its original length, and it can be either compressive or tensile. Shear strain, on the other hand, is the change in the angle between two originally perpendicular lines in the material, caused by the application of a shear stress.The relationship between stress and strain is governed by the material's mechanical properties, which can be determined through various testing methods. The most fundamental relationship between stress and strain is described by Hooke's law, which states that for small deformations, the stress in a material is proportional to the strain. This linear relationship is valid for many materials, such as steel and aluminum, within their elastic range.However, not all materials exhibit a linear stress-strain relationship.Some materials, such as rubber and certain polymers, exhibit a non-linear relationship, where the stress-strain curve is curved and the material exhibits more complex behavior, such as viscoelasticity or plasticity.Understanding the stress-strain relationship of materials is essential for the design and analysis of engineering structures and components. By knowing the stress and strain values, engineers can determine the safety and reliability of a structure under various loading conditions, as well as optimize the design to ensure that the material is being used efficiently and effectively.For example, in the design of a bridge, engineers need to consider the stresses and strains that will be experienced by the structure due to the weight of the bridge, the traffic load, and environmental factors, such as wind and earthquakes. By analyzing the stress and strain distribution within the bridge, engineers can ensure that the structure is designed to withstand the expected loads without exceeding the material's strength or deformation limits.Similarly, in the design of a mechanical component, such as a gear or a shaft, engineers need to consider the stresses and strains that will be experienced by the component during operation. By analyzing the stress and strain distribution within the component, engineers can optimize the design to minimize the risk of failure and ensurethe component's reliability and longevity.In conclusion, stress and strain are fundamental concepts in engineering that are essential for the design, analysis, and optimization of engineering systems. By understanding the relationship between stress and strain, engineers can ensure the safety, reliability, and efficiency of their designs, ultimately contributing to the advancement of technology and the betterment of society.。
注塑中英文对照
不良标签标示单整理整顿清扫清洁教养安全来料不良刮伤压痕螺栓热注射成型控制面板显示器安全门注射座螺杆料膛加热圈喷嘴定模板动模板成型机顶杆手动操作半自动操作全自动操作料膛清洗上料机温调机控制模具温度,保持在设定温度以内的温度控制设备参数监控画面对设备具体参数设定的画面,一般配有图表生产管理画面模板控制画面顶出控制画面加热管理画面注射速度画面注射压力画面保压控制画面计量控制画面报警显示画面最大高度最小高度能满足成型机性能的最小模具厚度锁模力锁模系统控制系统抽芯距白化制品破坏前变形引起的颜色差异缩痕收缩差异熔接线亮线冷熔接困气烧伤黑斑料纹烧焦色差脆化蠕变位移分层表面剥离三角洲效应方向收缩尺寸变化尺寸稳定性密度翘曲变形迟滞垂直于流动方向的收缩热变形温度脱模脱模斜度脱模困难内应力长链高分子凝固层比例取出粗加工伺服马达工序塑料件注射模斜销斜滑块悬臂搭扣连接模套型芯支架推块推杆推板复位杆扇形浇口浇口镶块圆柱头推杆扁顶杆连接推杆导套导柱浇口浇口长度浇口位置嵌件楔紧块凹模凹模拼块定模座板顶出系统设计顶出时间推板导套推板导柱冷料穴公模面模具温度支撑板隔板掏空型心拼块强度设计型芯固定板斜度母模面动模面斜槽导板推杆固定板弹性模量模具的 弹性变形加热圈定距拉板热流道板水平分型面热流道模具热塑性塑料注射模垫片拼块限位块限位丁浇口镶块钩型拉料杆球头拉料杆标准模架滑块煤油定位工作台车间故障低碳钢修正包装面板绘图机装模工花键条形码操作员课长外观检查内部检查前面板后面板电源按键工作间品质管理部门机械手车床工业酒精生锈换模装模修模到角淬火回火退火套筒无流道首件确认特采电极稳定性好气阀斜顶锁模块压条二板模三板模热嘴快接头扭距样品变形疲劳延展性翘曲熔接线脱模困难扭曲留痕鱼眼疲劳龟裂现象缩痕冻结浇口固化喷泉流动自由收缩中心趋向热熔接平均温度平均速度回流计量背压料筒溢料共混凸台分流道计算机辅助工程充填基本流动方式悬臂式卡扣毛细管流变仪型腔压力型腔 压力曲线中心温度热膨胀系数位移分布可压缩冷却效率冷却过程冷却速率冷却速度冷却阶段冷却系统冷却时间冷却水管锥板式流变仪冷却模拟冷却通道模面温度差分布弧制品产品轴钳工工作坯料黄铜毛刺铸钢压板轮廓制图点火花加工电极套管装配工磨光硬度应力集中应力断裂应力松弛应力集中源应力应变特性浇注系统纤维增强性材料纤维添加剂流动充填方式充填过程充填速率充填阶段充填时间注射力体积弯曲流动平衡流动控制流动长度流长比流动趋向流动模拟圆形流道三角筋半圆形流道热传导系数热传控制热传导速率冷却水管配置方式 玻璃化转变温度静置段冲击强度模内收缩流动方向的收缩率注射压力注射速度注射系统模内压力定压冷却阶段各向同性坚韧体积收缩率体积特性体积收缩率体积收缩 率分布长径比长度—厚度比线性收缩长期载荷隔热板热应力壁薄件螺纹型心螺纹型环熔体波前熔融指数成型温度计量区熔体流动速度微观结构带圆角的梯形流道再吸水模内收缩模具温度高分子链分子链的取向分子质量分布锥形定位件模架(注射模)塑料成型模具热塑性 塑料模具热固性塑料模具开模力模板闭合高度成型压力活动镶件动模动模座板多点进浇牛顿流体非牛顿流体喷嘴压力曲线过保压保压模拟保压流动保压压力保压过程保压阶段保压时间潜流效应冷却不均均匀度阀式浇口排气槽壁厚过度区域模具加工精度梯形流道护耳浇口絮流圆柱形塑料制品超声波焊接平头螺钉平行板流变仪制品装配制品设计制品尺寸制品收缩制品刚度制品强度制品顶出温度制品壁厚制品公差流道重量分型面点浇口塑料制品塑化平板型塑料制品脱膜后定压冷却入口压力压力控制压力差压力分布压力变化过程压力-体积-温度 关系成型循环加工参数投影面积赛马现象矩形流道增强增强成分增强筋筋筋的形状环行浇口流道浇道平衡流道截面积流道直径流道尺寸流道长度流道板份流道拉料杆螺杆旋转推流道板流道系统流道系统布局无流道模具封口压力半结晶型塑料半结晶齿壮设定的注塑压力曲线轴剪切剪切率切应力切应力分布剪切变稀特性短射短期载荷注射能力带肩推杆收缩率收缩收缩变形翘曲模拟收缩应力收缩空洞侧型心滑块导板银纹单浇口或多浇口表面层搭扣配合连接固化层,凝固层主流道浇口套拉料杆圆锥头拉料杆状态方程式阶跃式变化吸水程度吸水性塑料容积温度纤维素结晶型塑料玻璃纤维玻璃态低密度聚乙烯力学性能共塑物热物理特性热塑性塑料耐冲击聚苯乙烯黏度粘滞加热粘弹性交联结晶膨胀比热比体积热卡特性温度梯度热通量结晶热融化相变热高弹态热点相变温度熔点晶格英文术语qualitytolerancedefective product label identifying sheet listSeiriSeitonSeiketsuSeisoShitsukeSafedeficient purchasescratchdentsboltthermoplastic injection molding contorl platpro-facesaft doorenjection blendscrewfabbrelheaternozzleplammoving plamejector pinmansengle manautopurgeloaderproduct menutplam controlejector controlheat controlspeed controlfulling pressure controlpacking pressure controlexcit controlalarm viewmaximum daylightclamping forceclamping systemcontrol systemcore-pulling distancecore-pulling forcehydraulic systemshort shotjettingshrinkageasymmetric shrinkagelinescolor changeCold weldingair trapsburnblack specksblack streadsburn marksdiscolorationbrittlenessCreepDisplacementdelaminationdelta effectdiectional shrinkagedimensional variation dimensional stabilityDensitywarpagedistortionhesitationcross-flowshrinkagedeflection temperatu re demoldingdraftejection difficultiesinternal stresslong chain macromoleculesfrozen layer fractionremovalrough machiningservomotorworkstageplastic partsinjection mouldangle pin / finger camangled-lift / splitscantilever snap jointschase / bolster / frame Coreejector housing / mould base leg ejector padejector pinejector platepush-pack pinGate dimensions(sizes)disk gateedge gatefan gategating insertejector pin with cylindrical head flat ejector pinejector tie rodguide bushguide pillargategate lengthGate locationinsertheel lockcavity platecavity splitsfixed clamp plateejection system designejection timeejector bushingejector guide pillarcold-slug wellmale mold facemold temperaturebacking plate / support plate bafflecore outcore splitsDesign for strengthcore-retainer platedraft angleFamale mold facedynnamic mold facefinger guide plateejector retainer plateelastic moduluselastic deformation of toolheaterpuller plate; limit platehot-runner manifoldhorizontal parting linehot runner mouldinjection mold for thermoplastics gasketsplits(of a mould)stop blockstop pingating insertsprue puller,z-shapedsprue puller, ball headedstandard mould basescam slidestripper platesubmarine gatesupport pillarmould insertkerosenelocatemachine tablemachine shopmalfunctionlow carbon steelmodificationpackpanelplotterpress settersplinebarcodeoperatorsupervisorcosmetic inspectinner parts inspectfront platerear platepower buttonwork cellQC Sectionrobotlatheiudustrial alcoholrustdie changeto fix a dieto repair a diereverse angle = chamfer quenchingtemperingannealingsleaveRunner lessFAA first article assurance L/N Lot Number 特copper electrodegood stabilityvalvesangle from pinlock plateplate2-plate mold3-plate moldhot spruejiffy quick connector plug torquesamplecause analysisdefective productflashjettingdistortionfatigueductileWarpageweld lineejection difficultiestorsionflow marksfish eyesfatigueenvironmental stress crackresistancesink marksfreezegate freeze-offFountain Flowfree shrinkagecore orientationhot weldingAverage Temperatureaverage velocityback flowback pressurebarrelbleedingblendBossesBranched runnersCAE(computer aid engineering)Basic Flow Pattern in FillingCantilever snap (hook)Capillary viscometerCavity pressurecavity pressure profileCenter Temperaturecoefficient of thermal expansion displacement distributioncompressiblecooling efficiencycooling processcooling ratecooling rateCooling stagecooling systemcooling timecooling channelcone-and-plate viscometercool simulationcooling channel / cooling linedistribution of mold temperature difference cushionsectionapertureapplied loadsarcarticleaxisbench-workblankbrassburrcast steelclampcontourdrawingelectrochemical machining electrodeferrulefittergrindinghardnessStress concentrationstress crackingstress relaxationstress risersStress-strain behaviorfeed systemfiber-filled polymersfibersfillerfilling patternfilling processfilling ratefilling stagefilling timeejection forcefree volumeFlexuralflow balanceflow controlflow lengthflow length to thicknessflow orientationflow simulationFull-round runnerGussetsHalforound runnerheat transfer coefficientheat transfer controlheat transfer ratelayout of cooling channels Glass Transition Temperature,Tg holding stageholding timeImpact strengthin mold shrinkagein-flow shrinkageinjection pressureinjection speedinjection systemintemal mould pressure/cavity pressure isobaric coolingisotropictoughvolume shrinkagewolumetric Propertiesvolumetric shrindagevolumetric shrindage distribution, length-to-diameter ratiolength-to-thicknesslinear shrinkageLong-term loadthermal insulation boardthermal stressthinner walled partthread plug / threaded corethread ring /threaded cavitymeltmelt front (Advancement)melt index,MImelt temperaturemetering zoneMFRmicrostructureModified trapezoidal runnermoisture reabsorptionmold shrindagemold temperaturemolecular chainmolecular Chain Orientationmolecular weihght distribution,(MWD) mould ases locating elementsmould basesmould for plasticsmould for thermoplasticsmould for thermosetsmould opening forcemould platemould shut heihgtmoulding pressuremovable insert ,loose detailmovable mould / moving mouldmoving clamp plate / bottom clamp plate multiple gatingNewtonian fluidnon-Newtonian fluidNon-uniform Shrinkagenozzle pressure profileoverpackpack simulationpacking flowpacking pressurePacking ProcessPacking stagepacking timeunderflow effectuneven coolinguniformityvalve gatevent (of a mould)wall thickness transition regionstool tolerancesTrapezoidal runnertube gateturbulancecylinder-like partsUltrasonic weldingpan-head screwsparallel-plate viscometerPart AssemblyPart desingnpart dimensionPart ShrinkagePart StiffnessPart Strengthpart temperature at ejection/ejection tem Part thickness,thinkness of partPart Tolerancepart weightparting linepin-point gateplastic partsplasticizationplate-like partspost mold isobaric coolingPressure at the entrancepressure controlPressure differencePressure |DistributonPressure Historyprssure-volume-temperature relationship PVT process cycleprocessing parametersprojected arearace trackRectangular runnerreinforcedreinforcement contentreinforcing ribrelaxationResidual stressReynolds numberRheologyRibRib geometryring gaterunnerrunner balancerunner cross sectionrunner diameterrunner dimensions (sizes)runner lengthrunner platerunner pullerScrew rotation speedrunner stripper platerunner systemrunner system layoutsrunnerless mouldsealing pressuresemi-crystalline polymerssemi-crystallineserrationsSetted injection pressure profile shaftShearshear rateshear stressShear Stress Distributionshear-thinningshort shotshort term loadshot capacityshouldered ejector pinshrinkage rateshrinkageshrindage &warpage simulation shrinkage stressShrindage voidsslide coreside guide pinSilver streaksSingle vs.multiple gatesskin layersnap-fit Jointssolidification layerspruesprue bush / sprue busingsprue pullersprue puller,conical headedstate equationstep changeswitch-over positionthermal degradation temperature Amorphous polymersdegree of crystallinity degree of moisture absorption hygroscopic polymersBulk temperatureCA(Cellulosics)crystalline polymersGF (glass-fiber)glsaay stateLDPE (Low Density Polyethylene) mechanical performancecpolymerThermophysical Properties thermoplasticsHIPS(high impact polystyrene) viscosityviscous heatingViscoelastic behaviorcross-linkcrystallineswellSpecific HeatSpecific VolumeCalorimertric properties temperature gradientheat fluxHeat of CrystallizationHeat of Fusionheat of phase transitionHigh elastics satatehot spotTransition TemperatureMelting Temperature/TMlattice通用翻译满足或高于消费者期望的产品综合质量保证质量前提下允许尺寸的波动范围表明制品,不良或不合格内容的小说明表明制品,物品,地点等特性或作用的小说明必要与不必要的物品分开处理物品分门别类,按规定摆放并标识去除赃污防止再次发生将整理、整顿清扫制度化、标准化人人按照规定和制度行事,养成良好习惯自身安全,他人安全和设备安全上一工序的产品质量不符合本工序质量要求在制品表面因手或其它物体摩擦形成的影响制品外观质量的现象由于重力或压力引起接触面的痕迹,可影响外观美观起固定作用的栓件通过加热使物料熔化在注射到模具内形成期望的制品对设备参数控制的简易操作平台显示设备必要信息的屏幕防止事故发生,增大安全系数的保护装置门注射成型机组成部件,支撑并协助注射的金属平台起旋转计量作用的螺纹状部件.是成型机的核心机械件树脂预塑的炮膛状部件,和螺杆配合俎件质量要求较高围绕在料膛周围,起迅速并均匀加热作用的片状加热器连接注射成型机料筒与模具浇口套接触的像针头状的组件可固定模具在成型机上的铁板,是成型机的一部分成型机曲臂连接板,使模具固定在成型机上做开合模运动的动模板连接到模具上控制模具顶杆顶出或回退作用的连接杆只能手动单一步骤状态操作可半自动状态操作根据设置的程序在全自动状态动作一般用PE料做射出动作来清除或淡化料膛内物料或颜色在料杯树脂不足在传感器监控下吸取储备树脂的成型辅助设备在全自动生产状态下对产品质量和数量控制的页面模板动作状态控制页面顶出动作状态控制画面材料加热控制画面注射过程中对速度控制的画面注射过程中注射压力控制画面注射后保持设定压力提高制品质量的控制画面计量尺寸和相关参数控制画面设备动作异常或监控报警预览成型机模板打开的最大尺寸成型过程中为保证动,定模相互紧密配合而需施加的在模具上的力模板控制系统,注塑机上系统的一部分计算机通过检测、处理信息并重新输入计算机进行控制相关参数将侧型心抽至不防碍制品脱落的滑块滑动的距离从模内的成型塑件中,抽拔出侧型心所需要的力生产每个制品的时间或是单位时间内生产制品的个数液压动力注射机上的压力系统由于一次注射压力不足或速度偏低引起的浇不足现象材料水份超标,结构不良引起的表面气泡等不良现象热熔体在收缩情况下表面会形成凸凹状现象的统称制品厚度不均匀或分子排列不同引起的不均匀收缩两股或多股熔体结合位置形成的线状痕迹一种有明亮痕迹的注塑成型缺陷,一般为线状少为带状低温区域的熔接,多见于冲填结束,不同塑料熔前交汇造成又称包气,熔体流动将气体堵住或包住不能及时排出填充时模具内部气体不能迅速排出产生压缩高温,导致制品局部变色注射成型过程中因高温或树脂分解等原因引起的黑色不良现象树脂在模具腔内流动时由于层流因素引起的外观不良现象因高温引起的成型缺陷的一种制品本身颜色有其他杂质颜色混入形成的不良现象成型缺陷(因树脂性质发生变化引起的脆化或者破裂)高聚物在恒定温度和应力下,长度随时间延长而逐步深长的现象熔体内部压力差引起高压部份向低压部分推移现象,可产生层次感同一树脂或不同树脂发生层流后产生的 现象局部温度差由大分子链排列引起的具有方向特性的收缩生产出的制品在不同的环境下都会产生尺寸的变化制品尺寸的稳定性和一致性单位体积的质量有多种原因引起的变形现象,如收缩翘曲,配向翘曲等产品在内应力或外力的作用下产生的尺寸变化以及形状变化熔体的某一部份发生停止流动或极缓慢流动的现象发生在垂直于熔体流动方向上的收缩热力的作用下,塑料可以发生变形的温度保压后制品在模具内部成型完毕脱离模具的现象方便成型制品脱离模具而设计的角度成型制品不容易脱离模具的现象残留在制品内部因各种原因产生的应力很多小分子连接而成的具有较大质量的长分子连熔体在模具内冷却状态之一的数学表示方法成型后制品拿出的过程毛坯加工或留有大量余量的待加工品配合CPU工作的马达完成一个组件或产品经过的步骤以塑料为原料生产的制品通过注射方式成型的模具倾斜于分型面、随模具的开闭产生相对运动的圆柱零件斜向镶块或滑动的镶块组合方式之一使镶件或拼块定位并紧固在一起的框套形结构零件成型模具内表面突起的组件使动模能固定在压机或注塑机上的L型垫块在腔内起部分成型作用,并在开模时把塑件从型腔内推出的零件用于推出塑件或浇注系统凝料的杆件支撑推出和复位零件,直接传递机床推出力的板件借助模具的闭合动作,强制推出机构复位的杆件浇口的相关尺寸熔融塑料经主流道直接进入型腔的进料方式沿塑料件内圆周扩展进料的浇口设置在模具的分型处 从塑件的内或外侧进料的方式从分流道道型腔方向的宽度逐渐增加的呈扇型的浇口浇口以镶块的形式存在推杆的一种,头部形状是圆柱型形工作截面为矩形的顶杆连接推件板与推杆固定板,传递推力的杆件与导柱相配合,用于初步确定模具起导向作用的部件,一般为圆柱体连接分流道合型腔的进料通道浇口的长度树脂流入模腔的点相对整体模腔的位置成型中埋入或随后压入塑件中的金属或其他材料的部件带有楔角,用于合模时楔紧滑块的零件成型塑件外表面的凹壮零件(包括零件的内腔和实体两部分)母模中的镶件拼块使定模固定在注塑机的固定工作台面上的板件 是模具的基座顶出制品机构的类型,布置方式的设计 包括模具和成型机两部分制品脱离模具可安全取出的时间与导柱滑配合,用于推出机构导向的圆柱形零件与推板导柱滑配合,用于推出机构导向的圆柱形零件在浇口流道末端用于储藏低温熔体的槽指凸模面或是动模面注射成型使用的模具的实际温度或设置温度支撑模具芯体和其它运动结构的板状模块为改变蒸汽或冷却水的流向而在模具内部设置的金属条或板将制品的一 部分设计成掏空的部分凸模中的镶拼件,一般成型出制品内表面的某个部分对应制品使用环境要求而设计的强度用于固定型心的板状零件为了方便出型或脱模设计的斜度指凹模面也叫定模指凸模面也叫公模具有斜导槽,用以使滑块随槽动作抽芯合复位动作的板状零件用于固定推杆位置,使其不发生位置变化的压板衡量材料产生弹性变形难易程度的指标模具在行腔压力下发生的弹性变形用于加热使用的环行加热部件在开模时限定某一板动作距离的板件为开设分流道设置的加热元件,保持融料的温度立式成型机中,模具天地开模(上下),分型面为水平状态也称无流道,浇口料在模具内部保持熔融状态的模具热塑性材料使用的注射成型模具调整高度使用的薄金属片按设计和工艺要求,用以拼合模具型腔或型芯的零件限制活动范围的零件限制位置的丁状零件以浇口形式存在的镶块形状像钩子,起拉料作用拉料部位呈圆型的零件但不是规范的圆形通用并具有互换性的模架可以滑动,带动侧型心完成出型,抽芯和复位动作的零件直接推出塑件的板壮零件起局部或整体推出塑件作用的环行或盘型零件位置不明显,一般可自动剪切的浇口为增强动模的钢度设在动模支撑板和动模座板之间的支撑零件在工艺上便于加工或修理与主体部件分开制造的局部零件石油提炼出的油脂,一般在模具行业中清洗附着的分解物或异物固定在要求位置操作或加工的区域,可能是安全区域也可能是非接触区域.工作的场合,一般指一线工作人员的工作区域而非文件处理办公室影响机械设备正常工作的现象含碳量在0.10%至0.30%之间,也称为软钢一般指在接近标准的基础上进行小尺寸的修改以达到更高的要求为了美观或防止潮湿,灰尘,碰伤等采取的保护措施多指可视或裸露在外面的并起到遮盖作用的部件可联网专用于绘制图纸的机械组装并研磨模具的工人齿轮状起到连接固定作用的部件用于储存部件相关信息的条状代码使用或控制机械设备人员外来语,日本,韩国称为课长,中国一般称科长对制品外观质量目视或测量的过程对制品内部质量目视或测量的过程组件前部或正对着使用者方向的部件组件后部或背向使用者方向的部件控制电源开启或关闭的按键小型工作车间或有几个人协作完成的一道工序的线体品质控制和管理的部门,国际上多与生产分开管理代替操作人员手动工作的半自动或自动机械设备用车刀对对旋转的工件进行车削加工的机床可以导致人体中毒的甲醇模具因潮湿和空气中的氧气发生的一种化学反应成红赫色物质换模就是切换其它模具,将原来的模具卸下换上另一副开机生产前将模具使用手动或机械自动夹持在成型机上一种对模具非正常状态进行处理并修理到正常状态的过程为了防止金属锐利的角划伤或使外形美观将锐角去处的一种方法提高钢强度和硬度的一种工艺方法淬火后一般都经过回火,可提高组织稳定性生产中常用的预备热处理工艺中空的小管,和套筒芯组成组件形成孔,顶出时只有套筒动作即热流道,熔体不形成冷却废弃的材料,在模具内保持熔体状态对生产的第一个制品进行外观检查或组装等实验,确保可继续生产在不防止阻碍制品正常应用的条件下被允许生产的托词铜制品,在电加工上对坯放电造型质量在允许范围内波动控制气体的阀与推板动作方向不一直的顶杆防止模具在运输过程中打开的锁紧件固定相关组件的条状零件无中间板的模具,看模后只见两个板有中间板的模具,可见三个板可加热的端口区域实现快速连接的接头扭转变形时,内力偶距称为扭距可代表综合质量的个别产品通常采用人,机,料,法,环来剖析问题的过程符合质量规定的产品不符合质量规定的产品在模具缝隙中形成的不良现象,片状的称为飞边树脂熔体形成泉流后在制品表面形成的不良现象由于收缩和其它原因引起的形状变化高聚物材料在长期应用情况下所表现出来的特性可锤炼可压延的程度,材料特性之一由于非均匀收缩或分子排列等引起的抽曲熔体相遇后在连接位置形成的不良现象制品脱落时发生的困难一种载荷类型注塑成型缺陷的一种包括料留痕,气留痕和型腔结构留痕注射成型缺陷的一种,表面有颗粒状物质高聚物材料在长期应用情况下所表现出来的特性由于内应力的存在发生的制品段列,裂纹现象熔体遇冷后产生的收缩现象大分子链停止运动,熔体开始凝固浇口中的熔体由流动到冷却静止的过程像泉水涌出,中间层熔体向两侧翻出的现象在常温常压以及不受载荷时发生的自由收缩现象注塑成型工艺中的有一个重要参数熔体分流后再次融合的一起的现象不同测控点的温度平均值熔体在流动时候速度的平均值由于不同区域压力差引起的熔体倒流现象树脂在计量时候形成推动螺杆向后移动的压力树脂计量时的外部部件,与螺杆配合进行计量融体在充填或保压时刻发生熔体溢出的现象聚合物该性方法的一种呈突起状区域,具体作用与设计相关流道系统的一部分,与主流道相连的小流道分支计算机模拟流动,保压,变形,气辅等模拟手段融体在充填时流动的基本模式类是于“ 7 ” 型的钩子妆连接方式测量流体黏度的测量仪器熔体填充到模具内部时,模具内的压力以曲线的形式描绘出腔内随时间,速度变化的压力曲线制品中心层处的温度单位长度的材料温度每升一度的伸长量制品各个部分尺寸的线形伸长或缩短的分布情况塑料在不同的温度下体积发生变化的现象单位时间内带走热量多少的度量塑料冷却的全过程熔体冷却的速度塑件冷却的速度成型周期的一部分,制品冷却直至可安全取出用于冷却塑件的系列冷却装置以及布置方式塑件从保压开始一直到顶出的一段时间用于冷却塑件分布在模具外部的水路一种流体的黏度测试仪器CAE辅助分析的一种,用于模拟冷却过程设计在模具内部的冷却液通道,用以控制所要求的模温制品的两个和模具接触表面的温度差分布情况保压后螺杆所剩余的计量长度塑料制品壁部的厚度变化断开的端面起到组装或固定作用的孔(不一定是圆形)实际载荷或受力直线的过度联系常使用的弧,可以起到加强或美观的作用物品,制造生产的部件应用在不同环境下的轴,可起到对称基准或连接等作用研磨,组装,修理模具等工作没有进行细致加工的原材料由铜和锌组成的合金尖锐的比较小的突出部分用于浇注铸件的钢用于固定模具的夹具造型艺术术语,指界定表现对象形体范围的边缘线给予说明加工尺寸或外观图纸制作过程一种采用高压放电对金属部件加工的工艺铜材料,用于放电加工的阴模,放电加工完毕后被加工部件形成阳模筒装管子组装研磨工人研磨抛光材料局部抵抗硬物压入其表面的能力在应力的情况下出现在应力聚集的现象在应力的情况下发生断裂在恒温和应变情况下应力随时间延长而减小的情况产生 应力集中的区域应力发生变化的特点由喷嘴到型腔之间的进料通道组成包括主,分,浇口合冷料穴为了提高或降低某中特性在塑料材料中添加了其它成分高分子材料的一种添加到高分子内部改善塑料有关性能的成分填充过程熔体流动的各种形式熔体填充到模具的整个过程单位时间内添入模腔的熔体量熔体填充到模具阶段熔料充满型腔所用的时间严格上讲包括保压填充时间熔体从料膛注入模具内所需要的力一定量的熔体材料占据空间的部分一种可发生弯曲的载荷类型熔体填充到模具内流动均匀性的一种表现形式螺杆速度及压力控制模具腔内熔体的体积流量形式熔体流过的长度壁厚与熔体流动距离的比塑料在流动或冷却的过程呢中,发生在分子链定向的一种行为CAE辅助分析虚拟流动的一种方式截面为圆形的流道三角形状起到加强或者支撑作用的筋等截面的形状为半圆形的流道将热量从热的地方向冷的地方传导速度的量度控制热量传导的仪器设备单位时间内热能传递的量度冷却水管在墨菊内部布置和排列的方式粘流态树脂冷却成玻璃态时刻的温度Pack结束后,螺杆基本静止不动而维持压力不便的阶段填补收缩时保持设置压力的时间盛放待加工树脂塑料的容器。
- 1、下载文档前请自行甄别文档内容的完整性,平台不提供额外的编辑、内容补充、找答案等附加服务。
- 2、"仅部分预览"的文档,不可在线预览部分如存在完整性等问题,可反馈申请退款(可完整预览的文档不适用该条件!)。
- 3、如文档侵犯您的权益,请联系客服反馈,我们会尽快为您处理(人工客服工作时间:9:00-18:30)。
Experimental Approach
The standard engineering stress-strain tension test is performed on uniform section shaped test samples which are placed in an Instron 4204 load frame [20] with an extensometer attached to measure the elongation on the sample. Load readings are taken from an Instron 50 kN
load cell. Tests are performed at three crosshead rates: 1, 10, and 100 mm/min. Next, true local stress and true local strain tension tests are performed in a similar manner, except that the uniform section specimen is replaced with an hourglass sample as shown in figure 1. Here the accepted definition of true strain is observed as defined in equation 1, εtrue=ln( λ) (1) where εtrue is the true strain measure and λ is the stretch. The hourglass sample allows an extensometer to be attached transversely to the waist of the sample to measure the change in width of the sample during the test. In this manner the extensometer can be used to measure the local true strain at the waist of the hourglass sample, and continue to do so after yielding and the formation of the neck which is typical of polymer tension tests. It is assumed that the material is isotropic and the deformation is volume preserving. This allows the calculation of the extensional true strain. The true stress is determined from the load cell readings, the local true strain measurements, and the initial cross-section of the sample. This type of test is performed at the same three crosshead rates as for the standard uniform section samples. Depth 3.18 mm 31.75 mm Radius y x Width 6.73 mm z
The tensile stress-strain response of polymers for large deformations can be obtained in many ways. Two methods are presented and compared to a true constant strain rate controlled tension test. The differences in the results suggest that improved modeling of polymers with respect to strain rate can be achieved using the true constant strain rate test method. These improved models can have a large impact on the predictive capabilities of finite element models. Such improvements are necessary for accurately predicting insertion, retention, and drop-test performance of integral fasteners. A simple finite element material model is implemented incorporating experimental results. focused mainly on addressing the issues of convergence in the models. Several authors [14-18] have proposed rate dependent material models for polymers, however they are aimed at modeling material response at moderate strain rates (<0.01 sec-1 ), or extremely high rates such as those experienced when an anvil crushes a small, short cylindrical test sample [19]. Strain rates encountered in integral fastening tend to be between these two groups. There are a variety of standard tension testing techniques used to determine the stress-strain behavior of a material, and eventually aide in developing a material model. The problem is that the test specimen is often subjected to a variety of strain rates during the test making determination of material properties with respect to strain rate rather difficult. Some of the different types of tension tests conducted are as follows: •Standard displacement controlled engineering stress-strain tension tests using standard uniform section test samples. •Displacement controlled tension tests that measure local true strain and local true stress using hourglass shaped test samples. •True constant strain rate controlled tests that measure local true strain and local true stress using hourglass shaped test samples. In this paper the results are compared for each of the three test methods. Then, the last method of controlling the tension test in a true constant strain rate manner, which is considered to be more useful in determining rate dependent properties for polymers, is implemented in a finite element analysis (FEA) to verify that the experimental data can indeed be used in a basic “rate dependent” material model. Differences in the resulting material response are also compared and show significant difference in the results obtained based on the test mete of integral fasteners has many benefits for both design for assembly, product safety, and design for disassembly [1-6]. However, not much is known about the performance characteristics of plastic integral fasteners. The proper design and application of integral fasteners is often a time consuming, risky task. In particular, one of the most common areas of failure for integral fastening occurs when they are subjected to high rates such as in a product drop test. Typically, drop tests occur late in the development process using production parts. A product failure at this late stage can be extremely costly. Ideally, it would be beneficial for a development team to be able to run a simulation of the drop test early in the development process before money has been committed to tooling. However, adequate material models do not currently exist that adequately capture high strain rate properties of plastics to allow for a finite element simulation of a drop test. This paper details an approach used to more accurately determine the rate dependent behavior and material properties of a polymer with the goal of eventually using this type of test to improve existing rate dependent models. Work has been performed in the are of modeling integral fasteners and their performance [7-13]. However all of these works have used basic rate independent material models while performing a quasi-static analysis. Little effort has been focused on improving the material model to include rate effects. The efforts have been