2,5-二甲基吡嗪
2_3_二甲基吡嗪合成工艺的改进
1. 影响缩合反应的因素 ( 1) 反应温度 固定丁二酮与乙二胺的投料配比( 摩尔比) 为 1∶1. 05, 丁二酮与乙醇投料配 比( 体积比) 为 1∶10, 在不同温度下由丁二酮与乙二胺缩合成 2, 3-二甲基-5, 6-二氢吡嗪的实验结 果列于表 1。
反应温度 ( ℃)
- 15 - 10 -5
( 2) 溶剂用量 固定丁二酮与乙二胺投料配比( 摩尔比) 为 1∶1. 05, 缩合反应温度为- 5± 2℃, 考察了溶剂乙醇的用量对反应的影响, 结果见表 2。
表 2 溶剂用量对缩合反应的影响
丁二酮∶乙醇 (V/V)
1∶4 1∶6 1∶8
加料时间 丁二酮 转化率 Ⅱ的产率
( min)
( %)
3. 分析测试 用 P E-783 型红外光谱仪和日立 R-24B 型核磁共振仪分析产品的结构。原料、中间体和产物的 组成用上海分析仪器厂产 1102 型气相色谱仪分析, OV-101 石英毛细管柱( 30m ×0. 25mm ID) , FID 检测器, 以 N 2 为载气, 柱温 140℃。
结 果与 讨论
( %)
80
97. 0
63. 0
85
98. 2
66. 8
70
97. 6
72. 7
丁二酮∶乙醇 (V/ V)
1∶1 0 1∶1 5
加料时间 丁二酮转化率 Ⅱ的产率
( min)
(%)
(%)
68
96. 8
73. 6
65
95. 7
73. 5
从表 2 结果可以看出, 随着溶剂用量的增加, 缩合产物的产率逐渐增加。当反应物与溶剂的投
表 4 KOH 用量对脱氢反应的影响
K O H 用量 ( mo l/ mol)
美拉德反应
美拉德反应1912年，L.C.Maillard 发现了发生在氨基酸与还原糖之间的非酶褐变反应（后称Maillard反应），1953年Hodge对该反应的机理提出的解释。
在该反应中有大量的呋喃、吡嗪、噻吩等小分子化合物生成，这些化合物赋予了各种食品独特的香气。
例如：葡萄糖与不同氨基酸之间的混合搅拌加热发生的气味，请看下图：谷氨酸和葡萄糖的Maillard反应刘国珍，朱巍，黄龙,李丹,马舒翼(武汉烟草集团技术中心，武汉市汉阳区十升路特5号430051)关键词Maillard反应；葡萄糖；谷氨酸；烟草；增香剂摘要研究了由谷氨酸和葡萄糖反应合成烟草增香剂的反应条件对反应产物加香效果的影响。
结果表明：摩尔比为1∶2的葡萄糖与谷氨酸在100℃、反应2h的反应产物具有较好的增香效果。
GC/MS测定证明，在反应体系中添加少量乙醛，可促进多种挥发性致香成分的生成，且主要生成吡嗪类化合物。
Maillard Reaction of Glucose and Glutamic AcidLIU GUO-ZHEN, ZHU WEI, HUANG LONG, LI DAN, and MA SHU-YITechnology Center of Wuhan Tobacco Group, Wuhan 430051, ChinaKeywords: Maillard reaction; Glutamic acid; Glucose; Tobacco flavorantAbstract: The effects of reaction conditions on the flavoring function of the Maillard reaction products of glutamic acid and glucose were studied. The results showed that when the mixture of glutamic acid and glucose under their molar ratio of one to two reacted at 100℃ for 2hrs., the resulting Maillard reaction products had a better function for flavoring cigarette filler. By gas chromatography-mass spectrometry, it was proved that more volatile aroma components in the Maillard reaction products, particularly pyrazines, were produced by adding a small amount of acetaldehyde to the reaction system of glutamic acid and glucose.目前，有关Maillard反应产物对食品色、香、味方面影响的研究很多[1-4]，但有关反应条件对Maillard反应产物在卷烟中的加香效果的影响则报道较少。
咸味香精香原料香气特征
咸味香精香原料香气特征一、天然香料⑴、精油1. 大蒜油(Garlic Oil;['ɡɑrl?k])主要成分有烯丙基硫醚、甲基烯丙基二硫、丙基丙烯基二硫、乙基丙烯基二硫、烯丙基二硫、甲基烯丙基三硫、水芹烯等。
感官特征：具有强烈刺激的大蒜特征香气和香味。
可直接用于食品中，也可调配肉香、海鲜、辛香等食用香精，用于食品加香。
2. 洋葱油(Onion Oil;['?nj?n])主要成分有甲基丙基二硫、甲基丙基三硫、二丙基三硫、二乙烯基硫醚、乙烯基丙基硫醚、大蒜素等。
感官特征：具有强烈刺激而持久的洋葱辛辣气味。
主要用于食品香精中。
3. 姜油(Ginger Oil;['d??nd??])主要成分有姜油酮、姜油酚、姜烯、水芹烯、金合欢烯、桉叶油素、龙脑、乙酸龙脑脂、香叶醇、芳樟醇、壬醛、癸醛等。
感官特征：具有似鲜姜的气味，口感较辣。
主要用于调配食用香精。
4. 枯茗子油(Cumin Seed Oil;['kju:m?n])主要成分有枯茗醛、枯茗醇、松油醇、松油烯、柠檬烯、蒎烯等。
感官特征：具有强烈的小茴香气味。
可用来调配食用香精，用于肉类、腌制干酪、调味品及其他食品的加香，也用于酒用香精和日用香精中。
5. 胡椒油(Pepper Oil;['p?p?])主要成分有蒎烯、月桂烯、胡椒醛、水芹烯、石竹烯、松油烯、二氢葛缕酮等。
感官特征：具有温和的辛香气味。
主要用于调配食用香精。
6. 肉桂皮油(Cassia Bark Oil; ['k?s??])主要成分有桂醛、苯甲醛、水杨醛、桂酸、水杨酸、丁香酚、香兰素、乙酸桂脂等。
感官特征：具有肉桂的特征香气、辛辣香味。
主要用于调配食品用香精、烟用香精、酒用香精等。
7. 肉豆蔻油(Nutmeg Oil; ['n?tm?ɡ])主要成分有肉豆蔻酚醚、丁香酚、异丁香酚、芳樟醇、香叶醇、黄樟油素、龙脑、柠檬烯、蒎烯等。
感官特征：具有浓郁清甜辛香。
烟草添加剂名录
烟草添加剂许可名录（征求意见稿）二零一一年五月表１烟草添加剂（合成）中文名称英文名称参考文献1乙缩醛，乙醛二乙缩醛ACETAL 5,18,192对甲氧基苯乙酮p-METHOXYACETOPHENONE 1,2,3,4,5,6,7,8,11,12,15,17,18,193乙酸ACETIC ACID 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19 43-羟基-2-丁酮ACETOIN 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19 5丙酮ACETONE 4,5,18,196苯乙酮ACETOPHENONE 1,2,3,4,5,6,7,8,10,11,12,14,15,16,17,18,1976-乙酰氧基二氢茶螺烷6-ACETOXYDIHYDROTHEASPIRANE 1,5,18,198乙酰甲基纤维素ACETYL METHYL CELLULOSE 4,592-乙酰呋喃2-ACETYLFURAN 4,18,19102-乙酰吡嗪2-ACETYL PYRAZINE 1,2,5,7,8,9,10,12,13,16,17,18,19 112-乙酰吡啶2-ACETYL PYRIDINE 1,2,5,17,18,19123-乙酰吡啶3-ACETYL PYRIDINE 1,5,17,18,19132-乙酰基吡咯2-ACETYLPYRROLE 1,2,3,4,8,15,16,17,18,19142-乙酰噻唑2-ACETYLTHIAZOLE 2,3,7,8,18,1915D,L-丙氨酸D,L-ALANINE 1,6,17,18,1916己酸烯丙酯ALLYL HEXANOATE 1,2,3,5,17,18,1917降龙涎醚AMBROX 5,8,10,16,17,18,1918藻酸铵AMMONIUM ALGINATE 3,4,15,18,1919甘草酸铵AMMONIUM GLYCYRRHIZINATE 8,17,18AMMONIUM PHOSPHATE DIBASIC 1,2,3,4,5,15,1721戊醇AMYL ALCOHOL 1,2,3,5,17,18,1922丁酸戊酯AMYL BUTYRATE 1,2,3,4,5,7,8,12,13,14,15,17,18,1923甲酸戊酯AMYL FORMATE 1,2,3,5,6,7,15,17,18,1924己酸戊酯AMYL HEXANOATE 5,8,17,18,1925异戊酸戊酯AMYL ISOVALERATE 5,11,1926辛酸戊酯AMYL OCTANOATE 1,2,3,5,17,18,1927戊酸异戊酯ISOAMYL VALERATE 5,1828α-戊基肉桂醛α-AMYL CINNAMALDEHYDE 1,2,3,8,17,18,1929茴香醚ANISOLE 1,2,3,4,5,6,17,18,1930乙酸茴香酯ANISYL ACETATE 1,2,3,4,5,6,7,8,17,18,1931茴香醇ANISYL ALCOHOL 1,2,4,5,6,7,8,11,17,18,1932甲酸茴香酯ANISYL FORMATE 1,2,7,8,17,18,1933苯乙酸茴香酯ANISYL PHENYLACETATE 1,7,8,17,1834丙酸茴香酯ANISYL PROPIONATE 8,17,18,1935L-精氨酸L-ARGININE 2,3,18,1936抗坏血酸ASCORBIC ACID 1,2,3,4,5,6,8,15,17,18,1937L-天冬氨酸L-ASPARTIC ACID 1,2,3,17,18,1938苯甲醛BENZALDEHYDE 1,2,3,4,5,6,7,8,9,10,12,13,14,15,16,17,18,19 39苯甲醛甘油缩醛BENZALDEHYDE GLYCERYL ACETAL 1,2,3,8,15,17,18,1940苯甲酸BENZOIC ACID 1,2,3,4,5,8,11,12,13,15,17,18,1941二苯乙醇酮,安息香BENZOIN 1,5,17,18,1942二苯甲酮BENZOPHENONE 1,2,6,7,8,17,18,1943乙酸苄酯BENZYL ACETATE 4,5,18,1944苯甲醇BENZYL ALCOHOL 1,2,3,4,5,6,7,8,10,11,12,13,14,15,16,17,18,19 45苯甲酸苄酯BENZYL BENZOATE 1,2,3,4,5,6,7,8,10,11,15,16,17,18,19BENZYL BUTYRATE 1,2,5,6,7,8,11,15,17,18,1947肉桂酸苄酯BENZYL CINNAMATE 1,2,3,4,5,6,7,8,10,11,12,15,16,17,18,19 48甲酸苄酯BENZYL FORMATE 5,8,17,18,1949异丁酸苄酯BENZYL ISOBUTYRATE 5,8,17,18,1950异戊酸苄酯BENZYL ISOVALERATE 8,17,18,1951苯乙酸苄酯BENZYL PHENYLACETATE 2,3,5,18,1952丙酸苄酯BENZYL PROPIONATE 1,2,5,7,17,18,1953水杨酸苄酯BENZYL SALICYLATE 1,2,7,17,18,1954红没药烯BISABOLENE 1,7,17,18,1955龙脑BORNEOL 1,2,7,17,18,1956乙酸龙脑酯BORNYL ACETATE 1,2,3,5,6,7,12,13,14,15,17,18,1957异戊酸龙脑酯BORNYL ISOVALERATE 2,7,15,18,19581,3-丁二醇1,3-BUTANEDIOL 1,2,3,4,5,17592,3-丁二酮2,3-BUTANEDIONE 1,4,7,8,9,14,16,17,18,1960正丁醇1-BUTANOL 1,2,3,6,7,8,11,15,17,18,1961乙酸丁酯BUTYL ACETATE 1,2,3,4,5,6,8,17,18,1962丁酸丁酯BUTYL BUTYRATE 2,4,5,6,7,8,11,13,18,1963丁酰乳酸丁酯BUTYL BUTYRYL LACTATE 1,2,3,7,15,17,18,1964异戊酸丁酯BUTYL ISOVALERATE 1,7,8,12,13,14,17,18,1965苯乙酸丁酯BUTYL PHENYLACETATE 1,2,5,7,17,18,1966戊酸丁酯BUTYL VALERATE 8,17,18,19673-亚丁基-1(3H)-异苯并呋喃酮3-BUTYLIDENEPHTHALIDE 1,2,3,6,7,15,17,18,1968丁酸BUTYRIC ACID 1,2,3,4,5,6,7,8,9,10,11,12,13,14, 15,16,17,18,19 69γ-丁内酯γ-BUTYROLACTONE 4,6,18,1970杜松烯CADINENE 1,5,1771乙酸钙CALCIUM ACETATE 5,1972莰烯CAMPHENE 1,2,5,6,7,18,1973二氧化碳CARBON DIOXIDE 1,2,3,5,6,9,10,15,16,1774羧甲基纤维素钠盐CARBOXYMETHYL CELLULOSE SODIUM SALT 4,5,8,1675β-胡罗卜素β-CAROTENE 1,2,3,17,1876甲基异丙基苯酚CARVACROL 1,2,5,8,15,17,18,1977香芹薄荷醇,1-对-烯4-CARVOMENTHENOL, 1-p-MENTHEN-4-OL 1,2,3,5,7,8,17,18,19 -4-醇78L-香芹酮L-CARVONE 2,5,7,8, 10,18,1979D-香芹酮D-CARVONE 5,8,17,18,1980β-石竹烯β-CARYOPHYLLENE 1,2,3,4,6,7,8,11,12,15,17,18,19 81β-石竹烯醇β-CARYOPHYLLENE ALCOHOL 5,1882β-氧化石竹烯β-CARYOPHYLLENE OXIDE 1,2,3,5,6,8,15,17,18,1983柏木醇CEDROL 1,5,17,1984乙酸柏木酯CEDRYL ACETATE 5,1885纤维素纤维CELLULOSE FIBER 1,2,3,4,5,6,8,9,10,15,16,1786叶绿素CHLOROPHYLL 4,5871,4-桉叶素1,4-CINEOLE 2,3,15,18,1988肉桂醛CINNAMALDEHYDE 1,2,3,5,6,7,11,15,17,18,1989肉桂酸CINNAMIC ACID 1,2,4,5,7,8,10,15,17,18,1990乙酸肉桂酯CINNAMYL ACETATE 1,2,3,5,6,8,15,17,18,1991肉桂醇CINNAMYL ALCOHOL 1,2,3,5,6,7,8,11,12,14,17,18,19 92丁酸肉桂酯CINNAMYL BUTYRATE 5,18,1993肉桂酸肉桂酯CINNAMYL CINNAMATE 1,2,3,5,6,7,8,17,18,19CINNAMYL ISOBUTYRATE 5,8,17,18,1995异戊酸肉桂酯CINNAMYL ISOVALERATE 1,2,5,6,7,11,12,13,14,17,18,1996柠檬醛CITRAL 1,2,3,5,6,7,8,10,11,12,13,14,15,16,17,18,19 97柠檬酸CITRIC ACID 1,2,3,4,5,6,7,8,10,11,12,13,14,15,16,17,18,19 98香茅醛CITRONELLAL 5,8,10,16,17,18,1999香茅酸CITRONELLIC ACID, 3,7-DIMETHYL-6-OCTENOIC ACID 1,2,3,7,8,10,15,17,18,19100D,L-香茅醇D,L-CITRONELLOL 2,4,5,6,7,8,11,12,13,14,18,19101乙酸香茅酯CITRONELLYL ACETATE 1,5,8,17,18,19102丁酸香茅酯CITRONELLYL BUTYRATE 1,5,17,18,19103甲酸香茅酯CITRONELLYL FORMATE 5,18,19104异丁酸香茅酯CITRONELLYL ISOBUTYRATE 1,5,17,18,19105苯乙酸香茅酯CITRONELLYL PHENYLACETATE 2,5,15,18,19106丙酸香茅酯CITRONELLYL PROPIONATE 5,18,19107枯茗醛CUMINALDEHYDE 1,2,5,8,17,18,19108仙客来醛CYCLAMEN ALDEHYDE 5,8,17,18,19109β-环糊精β-CYCLODEXTRIN 4,18,19110对-伞花烃，对异丙基甲苯p-CYMENE 1,2,5,6,7,17,18,19111L-半胱氨酸L-CYSTEINE 2,6,18,19112β-二氢大马酮β-DAMASCONE 3,5,6,7,8,10,11,12,14,18,19113β-大马酮DAMASCENONE 4,5,6,7,8,9,10,11,12,16,18,19114δ-癸内酯δ-DECALACTONE 1,2,3,5,7,8,10,15,17,18,19115γ-癸内酯γ-DECALACTONE 1,2,3,4,5,7,8,11,12,13,14,15,17,18,19 116癸醛DECANAL 1,2,3,5,6,7,8,11,17,18,19117癸酸DECANOIC ACID 1,2,3,4,5,6,7,8,10,11,12,13,14,15,17,18,19 118辛癸酸甘油酯CAPRYLIC /CAPRIC TRIGLYCERRIDE 2,3,1-DECANOL 1,4,7,17,18,19120二苄醚DIBENZYL ETHER 5,18,19121糊精DEXTRIN 4,5,8,17,122葡萄糖DEXTROSE 2,3,4,9,10,15,16,18123丙二酸二乙酯DIETHYL MALONATE 1,2,3,6,8,15,17,18,19124癸二酸二乙酯DIETHYL SEBACATE 1,2,5,7,17,18,191252,3-二乙基吡嗪2,3-DIETHYLPYRAZINE 1,2,3,5,7,8,11,13,15,17,18,191262,3-二乙基-5-甲基吡嗪2,3-DIETHYL-5-METHYL PYRAZINE 3,5,18,19127二氢猕猴桃内酯DIHYDROACTINIDIOLIDE 5,18,19128乙酸二氢葛缕酯DIHYDROCARVYL ACETATE 5,18,19129二氢香豆素DIHYDROCOUMARIN 5,6,18,19130间二甲氧基苯m-DIMETHOXYBENZENE 1,7,8,17,18,19131对二甲氧基苯p-DIMETHOXYBENZENE 1,5,7,8,11,17,18,19 1322,6-二甲氧基苯酚2,6-DIMETHOXYPHENOL 1,2,3,4,5,8,15,17,18,19 1332,4-二甲基苯乙酮2,4-DIMETHYLACETOPHENONE 1,2,7,17,19134丁二酸二甲酯,琥珀酸二甲酯DIMETHYL SUCCINATE 1,5,17,18,191353,4-二甲基-1,2-环戊二酮3,4-DIMETHYL-1,2-CYCLOPENTANEDIONE 1,3,4,5,8,15,17,18,191363,5-二甲基-1,2-环戊二酮3,5-DIMETHYL-1,2-CYCLOPENTANEDIONE 1,4,17,18,19137罗勒烯3,7-DIMETHYL-1,3,6-OCTATRIENE,OCIMENE 1,2,3,7,17,18,19 138薄荷内酯DIMETHYLTETRAHYDROBENZOFURANONE, MINTLACTONE 1,2,7,17,18,19139二氢呋喃4,5-DIMETHYL-3-HYDROXY-2,5-DIHYDROFURAN-2-ONE 1,2,3,8,15,17,18,191404-羟基-2,5-二甲基-3(2H)呋喃酮2,5-DIMETHYL-4-HYDROXY-3(2H)-FURANONE 1,2,3,4,5,7,8,15,17,18,19141香叶基丙酮6,10-DIMETHYL-5,9-UNDECADIEN-2-ONE 1,2,7,8,15,17,18,19 1422,4-二甲基苯甲醇2,4-DIMETHYLBENZYL ALCOHOL 1,2,3,15,17,18,19143乙酸α,α-二甲基苯乙酯α,α-DIMETHYLPHENETHYL ACETATE 5,7,18,19144丁酸α,α-二甲基苯乙酯α,α-DIMETHYLPHENETHYL BUTYRATE1,5,7,17,18,191453,4-二甲基苯酚3,4-DIMETHYL PHENOL 5,191462,3-二甲基吡嗪2,3-DIMETHYLPYRAZINE 1,2,3,4,8,10,16,17,18,191472,5-二甲基吡嗪2,5-DIMETHYLPYRAZINE 1,2,3,4,5,7,8,10,11,12,13,15,16,17,18,19 1482,6-二甲基吡嗪2,6-DIMETHYLPYRAZINE 1,2,4,5,8,15,16,17,18,191493,5-二甲基吡啶3,5-DIMETHYL PYRIDINE 5,181502,4-二甲基苯乙烯2,4- DIMETHYL STYRENEP 5,19151二苯醚DIPHENYL ETHER 5,18,19152δ-十二内酯δ-DODECALACTONE 1,2,3,4,5,7,8,10,15,16,17,18,19153γ-十二内酯γ-DODECALACTONE 1,2,3,5,7,8,17,18,19154D-山梨醇D-SORBITOL 2,4,6,8,10,12,13,14,16,19155β-榄香烯β-ELEMENE 5156β-榄香醇β-ELEMOL 5157龙蒿脑ESTRAGOLE 5,6,18,19158对乙氧基苯甲醛p-ETHOXYBENZALDEHYDE 1,8,17,1915910-十一碳烯酸乙酯ETHYL 10-UNDECENOATE 5,18,191602-甲基丁酸乙酯ETHYL 2-METHYLBUTYRATE 5,6,7,8,15,18,19ETHYL ACETATE 1,2,3,4,5,7,8,9,10,11,12,13,14,15,16,17,18,19 162乙酰乙酸乙酯ETHYL ACETOACETATE 1,2,8,17,18,19163丙烯酸乙酯ETHYL ACRYLATE 5,18,19164乙醇ETHANOL 1,2,3,4,5,6,7,8,9,10,15,16,17,191654-乙基苯甲醛4-ETHYLBENZALDEHYDE 1,2,8,17,18,19166苯甲酸乙酯ETHYL BENZOATE 1,2,3,4,5,6,7,8,15,17,18,19167丁酸乙酯ETHYL BUTYRATE 1,2,3,4,5,6,7,8,10,11,12,13,14,15,16,17,18,19 168反式-2-丁烯酸乙酯ETHYL trans-2-BUTENOATE 1,8,17,18,19169乙基纤维素ETHYL CELLULOSE 4,5,9,16,170肉桂酸乙酯ETHYL CINNAMATE 1,2,3,4,5,6,7,8,11,12,15,17,18,19171癸酸乙酯ETHYL DECANOATE 1,2,3,4,5,6,7,8,15,17,18,19172甲酸乙酯ETHYL FORMATE 5,18,19173庚酸乙酯ETHYL HEPTANOATE 1,2,3,5,6,7,8,10,11,12,13,14,17,18,19174己酸乙酯ETHYL HEXANOATE 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19 1752-乙基己醇2-ETHYL HEXANOL 2-ETHYL-1-HEXANOL 1,2,3,17,18,191765-乙基-4-羟基-2-甲基-3(2H)-呋喃酮5-ETHYL-4-HYDROXY-2-METHYL-3(2H)-FURANONE, SHOYUFURANONE8,17,18,19177异丁酸乙酯ETHYL ISOBUTYRATE 8,17,18,19178异戊酸乙酯ETHYL ISOVALERATE 1,2,3,4,5,6,7,8,10,11,12,13,14,15,16,17,18,19 179乳酸乙酯ETHYL LACTATE 1,2,3,4,5,6,7,8,12,13,14,15,17,18,19180月桂酸乙酯ETHYL LAURATE 1,2,3,5,6,7,8,15,17,18,19181乙酰丙酸乙酯ETHYL ACETYLPROPANOATE 1,2,3,4,6,10,15,17,18,19182乙基麦芽酚ETHYL MALTOL 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,17,18,19 183草莓醛，十六醛ETHYL METHYL PHENYLGLYCIDATE 1,2,3,17,18,19184肉豆蔻酸乙酯ETHYL MYRISTATE 1,2,3,5,6,8,15,17,18,19185壬酸乙酯ETHYL NONANOATE 1,2,3,4,5,6,7,8,11,13,17,18,19ETHYL OCTADECANOATE 1,2,3,6,10,15,17,18,19187辛酸乙酯ETHYL OCTANOATE 1,2,3,4,5,6,7,8,12,15,17,18,19188油酸乙酯ETHYL OLEATE 1,2,3,6,17,18,19189棕榈酸乙酯ETHYL PALMITATE 1,2,3,5,6,8,10,15,17,18,19190苯乙酸乙酯ETHYL PHENYLACETATE 1,2,3,4,5,6,7,8,9,10,11,12,15,17,18,19 191丙酸乙酯ETHYL PROPIONATE 1,2,3,4,5,6,7,8,10,11,12,13,14,17,18,19 192水杨酸乙酯ETHYL SALICYLATE 1,5,8,17,18,19193戊酸乙酯ETHYL VALERATE 1,2,3,5,8,17,18,19194乙基香兰素ETHYL VANILLIN 1,2,3,4,5,6,7,8,10,11,12,14,15,16,17,18,19 195乙基香兰素葡糖苷ETHYL VANILLIN GLUCOSIDE 2,3,15,191963-乙基-2-羟基-2-环戊烯-1-酮3-ETHYL-2-HYDROXY-2-CYCLOPENTEN-1-ONE 1,2,3,5,8,17,18,191972-乙基-3,5-二甲基吡嗪2-ETHYL-3,5-DIMETHYLPYRAZINE 1,2,3,4,5,7,8,10,13,15,16,17,18,191982-乙基-3,6-二甲基吡嗪2-ETHYL-3,6-DIMETHYLPYRAZINE 1,2,3,4,5,7,8,10,13,15,16,17,18,191993-乙基-2,5-二甲基吡嗪3-ETHYL-2,5-DIMETHYL PYRAZINE 52003-羟基-4-甲基-5-乙基-2(5H)-呋喃酮5-ETHYL-3-HYDROXY-4-METHYL-2(5H)-FURANONE 1,2,3,5,7,8,10,11,13,15,16,17,18,192012-乙基-3-甲基吡嗪2-ETHYL-3-METHYLPYRAZINE 1,2,3,4,5,7,8,13,15,16,17,18,19 2024-乙基愈创木酚4-ETHYLGUAIACOL 1,2,8,15,17,18,19203对乙基苯酚p-ETHYLPHENOL 1,2,3,5,8,15,17,18,192043-乙基吡啶3-ETHYLPYRIDINE 1,2,3,4,5,15,17,2051,8-桉叶素EUCALYPTOL, 1,8-CINEOLE 1,5,7,8,17,18,19206丁香酚EUGENOL 4,5,18,19EUGENYL METHYL ETHER 5,18,19208金合欢醇FARNESOL 1,2,5,6,8,17,18,19 209D-葑酮D-FENCHONE 1,2,3,15,17,18,19210松香甘油酯,马来松香甘油酯GLYCEROL ESTER OF ROSIN, FORAL 85 4,18,19211甲酸FORMIC ACID 5,18,19 212果糖FRUCTOSE 2,3,18 213硫代甲酸糠酯2-FURAN METHANE THIOLFORMATE 5,19 214乙酸糠酯FURFURYL ACETATE 4,18,19215丙酸糠酯,丙酸2-呋喃甲酯FURFURYL PROPIONATE 4,18,19216糠醛FURFURAL 4,18,19217糠醇FURFURAL ALCOHOL 4,5,18,19218糠基甲基硫醚FURFURYL METHYL SULPHIDE 5,18,19219糠基硫醇FURFURYL MERCAPTAN 1,2,4,6,17,18,192204-(2-呋喃基)-3-丁烯-2-酮4-(2-FURYL)-3-BUTEN-2-ONE 1,2,3,17,18,19221香叶醇GERANIOL 1,2,3,4,5,6,7,8,10,11,12,13,14,15,16,17,18,19 222乙酸香叶酯GERANYL ACETATE 1,2,4,5,6,7,8,11,17,18,19223丁酸香叶酯GERANYL BUTYRATE 1,2,4,5,6,7,8,11,17,18,19224甲酸香叶酯GERANYL FORMATE 1,2,5,6,7,8,11,17,18,19225异丁酸香叶酯GERANYL ISOBUTYRATE 5,18,19226苯乙酸香叶酯GERANYL PHENYLACETATE 1,2,3,5,7,10,17,18,19227丙酸香叶酯GERANYL PROPIONATE 5,18,19228L-谷氨酸L-GLUTAMIC ACID 2,6,18,19GLYCEROL 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19 2301,2-二乙酸甘油酯GLYCEROL-1,2-DIACETATE 4,5,19231三乙酸甘油酯GLYCERYL TRIACETATE 4,5,7,8,9,16,18,19232氨化甘草甜素GLYCYRRHIZIN AMMONIATED 1,3,17,233愈创木酚GUAIACOL 1,2,3,5,6,8,10,15,17,18,192342,4-庚二烯醛2, 4-HEPTADIENAL 1,2,3,5,6,7,8,11,15,17,18,19235γ-庚内酯γ-HEPTALACTONE 1,2,3,4,5,6,7,8,12,14,15,17,18,19236庚酸HEPTANOIC ACID 1,2,3,4,5,6,8,10,15,16,17,18,192372-庚酮2-HEPTANONE 1,2,3,5,7,8,11,12,14,15,17,18,192384-庚烯醛4-HEPTENAL 1,2,3,5,8,15,17,18,192393-庚烯-2-酮3-HEPTEN-2-ONE 1,2,7,17,18,19240乙酸庚酯HEPTYL ACETATE 1,6,17,18,19241ω-6-十六烯酸内酯，黄葵内酯ω-6-HEXADECENLACTONE, AMBRETTOLIDE 1,2,3,5,7,8,17,18,19242γ-己内酯γ-HEXALACTONE 1,4,5,7,8,12,14,16,17,18,19243δ-己内酯δ-HEXALACTONE 8,18,19244己醛HEXANAL 1,2,3,6,7,8,12,13,14,17,18,19245己酸HEXANOIC ACID 1,2,3,4,5,6,7,8,10,11,12,13,14,15,16,17,18,19 2463,4-己二酮3,4-HEXANEDIONE 5,18,192472-己烯醇2-HEXEN-1-OL 1,2,3,8,10,17,18,19248叶醇，顺式-3-己烯-1-醇LEAF ALCOHOL，cis-3-HEXEN-1-OL 1,2,3,5,7,8,16,17,18,19249顺式-3-己烯-1-醇乙酸酯cis-3-HEXEN-1-YL ACETATE 1,2,3,4,5,8,10,12,13,14,15,16,17,18,19250乙酸2-己烯酯2-HEXEN-1-YL ACETATE 5,8,17,18,19 2512-己烯醛2-HEXENAL 1,5,7,8,11,17,18,193-HEXENOIC ACID 1,2,3,8,15,17,18,19 253反式-2-己烯酸trans-2-HEXENOIC ACID 1,2,7,8,17,18,19254顺式-3-己烯醇甲酸酯，甲酸叶醇酯cis-3-HEXENYL FORMATE 1,2,3,8,17,18,19255己醇HEXYL ALCOHOL 1,2,3,4,5,6,8,10,15,17,18,19 2562-甲基丁酸己酯HEXYL 2-METHYLBUTYRATE 1,7,17,18,192572-羟基-4-甲基苯甲醛2-HYDROXY-4-METHYLBENZALDEHYDE 1,8,17,18,19258苯乙酸己酯HEXYL PHENYLACETATE 1,2,3,5,7,15,17,18,19 2594-羟基苯甲酸4-HYDROXY BENZOIC ACID 4,5,192604-羟基苯甲酸丙酯4-HYDROXY BENZOIC ACID PROPYL ESTER 4,5,7,19261α-当归内酯α-ANGELICA LACTONE 1,2,3,4,8,17,18,19262羟基香茅醛HYDROXYCITRONELLAL 1,2,5,6,8,17,18,19263羟基香茅醇HYDROXYCITRONELLOL 5,18,192646-羟基二氢茶螺烷6-HYDROXYDIHYDROTHEASPIRANE 6,18,192655-羟乙基-4-甲基噻唑5-HYDROXYETHYL-4-METHYLTHIAZOLE,4-METHYL-5-THIAZOLEETHANOL1,2,4,8,17,18,192664-对羟苯基-2-丁酮,覆盆子酮4-(4-HYDROXYPHENYL)-2-BUTANONE 4,5,7,8,12,13,14,15,16,18,19267羟丙基纤维素HYDROXYPROPYL CELLULOSE 2,5,8,15268吲哚INDOLE 4,5,18,19269α-紫罗兰酮α-IONONE 1,2,3,4,5,6,7,8,10,11,12,15,17,18,19270β-紫罗兰酮β-IONONE 1,2,3,4,5,6,7,8,9,11,12,13,14,15,16,17,18,19 271α-鸢尾酮α-IRONE 1,3,5,8,10,16,17,18,19272乙酸异戊酯ISOAMYL ACETATE 1,2,3,5,6,7,8,10,11,12,13,14,15,16,17,18,19 273异戊醇ISOAMYL ALCOHOL 5,6,18,19274苯甲酸异戊酯ISOAMYL BENZOATE 1,2,3,5,7,15,18,19ISOAMYL BUTYRATE 1,2,3,6,7,8,10,12,13,14,15,16,17,18,19 276肉桂酸异戊酯ISOAMYL CINNAMATE 1,2,4,5,7,8,10,16,17,18,19277甲酸异戊酯ISOAMYL FORMATE 1,2,3,6,7,11,12,13,14,17,18,19278丙酸异戊酯ISOAMYL PROPIONATE 8,17,18,19279水杨酸异戊酯ISOAMYL SALICYLATE 5,8,17,18,19280水杨酸异丁酯ISOBUTYL SALICYLATE 1,7,17,18,19281己酸异戊酯ISOAMYL HEXANOATE 1,7,8,12,17,18,19282异戊酸异戊酯ISOAMYL ISOVALERATE 1,2,3,5,6,7,8,10,11,12,13,14,15,16,17,18,19 283辛酸异戊酯ISOAMYL OCTANOATE 1,4,8,17,18,19284苯乙酸异戊酯ISOAMYL PHENYLACETATE 1,2,3,5,6,7,8,10,11,12,13,14,16,17,18,19 285乙酸异龙脑酯ISOBORNYL ACETATE 1,5,8,17,18,19286乙酸异丁酯ISOBUTYL ACETATE 1,2,3,5,6,7,8,12,13,14,17,18,19287异丁醇ISOBUTYL ALCOHOL 1,2,5,6,7,8,11,12,17,18,19288丁酸异丁酯ISOBUTYL BUTYRATE 4,5,8,17,18,19289肉桂酸异丁酯ISOBUTYL CINNAMATE 1,2,3,4,5,6,7,8,15,17,18,192902-异丁基-3-甲氧基吡嗪2-ISOBUTYL-3-METHOXYPYRAZINE 1,5,6,17,19291α-异丁基苯乙醇α-ISOBUTYLPHENETHYL ALCOHOL 1,2,3,15,17,18,19292苯乙酸异丁酯ISOBUTYL PHENYL ACETATE 5,7,8,10,16,18,19293异丁醛ISOBUTYRALDEHYDE 1,2,3,4,5,6,7,8,10,16,17,18,19294异丁酸ISOBUTYRIC ACID 1,2,3,4,5,6,7,8,10,11,12,13,14,15,16,17,18,19 295异丁香酚ISOEUGENOL 5,18,19296异丁香酚甲醚ISOEUGENYL METHYL ETHER 5,18,19297D,L-异薄荷酮D,L-ISOMENTHONE8,17,18,19298异戊烷ISOPENTANE 4,5,9,10299异佛尔酮ISOPHORONE 5,18,19ISOPROPYL ACETATE 9, 10,18,19 301异丙醇ISOPROPYL ALCOHOL 4,5,18,19302肉豆蔻酸异丙酯，十四酸异丙酯ISOPROPYL MYRISTATE 5,8,17,18,193032-异丙基苯酚2-ISOPROPYLPHENOL 1,2,3,17,18,19304异胡薄荷醇ISOPULEGOL 5,18,19305异戊酸ISOVALERIC ACID 1,2,3,4,5,6,7,8,10,12,13,14,15,16,17, 18,19 3064-氧化二氢异佛尔酮4-KETO DIHYDROISOPHORONE 53074-氧化异佛尔酮，2,6,6-三甲基-2-环己烯-1,4-二酮4-KETO ISOPHORONE，2,6,6-TRIMETHYLCYCLOHEX-2-ENE-1,4-DIONE5,18,19308乳酸LACTIC ACID 1,2,3,4,5,6,8,11,12,13,14,15,17,18,19309月桂酸,十二酸LAURIC ACID 1,2,3,5,7,8,11,15,17,18,19310L-亮氨酸L-LEUCINE 1,6,17,18,19311乙酰丙酸LEVULINIC ACID 1,2,3,15,17,18,19312D-柠檬烯D-LIMONENE 5,18,19313芳樟醇LINALOOL 1,2,3,4,5,6,7,8,11,12,13,14,15,17,18, 19314氧化芳樟醇LINALOOL OXIDE 1,2,3,4,5,6,8,15,17,18,19315乙酸芳樟酯LINALYL ACETATE 1,2,3,4,5,7,8,10,15,17,18,19316苯甲酸芳樟酯LINALYL BENZOATE 8,17,18,19317丁酸芳樟酯LINALYL BUTYRATE 5,18,19318甲酸芳樟酯LINALYL FORMATE 5,18,19319异丁酸芳樟酯LINALYL ISOBUTYRATE 5,8,17,18,19320L-赖氨酸L-LYSINE 2,3,18,19321苹果酸MALIC ACID 1,2,4,8,17,19322麦芽酚MALTOL 1,2,3,5,6,7,8,9,10,11,12,13,14,15,16, 17,18,19p-MENTHA-8-THIOL-3-ONE 1,5,8,17,18,19324紫苏醇p-MENTHA-1,8-DIEN-7-OL，PERILLA ALCOHOL 5,18,193253-甲硫基丙醛METHIONAL 8,17,18,19326D,L-薄荷醇D,L-MENTHOL 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19 327薄荷酮MENTHONE 1,7,8,12,17,18,19328乙酸薄荷酯MENTHYL ACETATEMENTHOL ACETATE 1,2,5,6,7,8,10,17,18,19329异戊酸薄荷酯MENTHYL ISOVALERATE 2,5,8,17,18,193302-甲氧基-4-甲基苯酚2-METHOXY-4-METHYLPHENOL 1,2,3,4,7,8,14,15,17,18,19331邻-甲氧基肉桂醛2-METHOXY CINNAMALDEHYDE,o-METHOXYCINNAMALDEHYDE5,18,193322,5二-甲氧基-3-甲基吡嗪2,5-DIMETHOXY-3-METHYL PYRAZINE 6,7,8,10,16,18,193332,6二-甲氧基-3-甲基吡嗪2,6-DIMETHOXY-3-METHYL PYRAZINE 6,8,16,18,193342-甲氧基-4-乙烯基苯酚2-METHOXY-4-VINYLPHENOL 1,2,3,5,6,8,10,15,16,17,18,19335大茴香醛，对甲氧基苯甲醛4-METHOXYBENZALDEHYDE, p-ANISALDEHYDE 1,2,3,4,5,7,8,9,10,11,12,13,14,17,193361-(对甲氧基苯基)-2-丙酮1-(4-METHOXYPHENYL)-2-PROPANONE 1,5,8,17,18,19337糠酸甲酯METHYL 2-FUROATE 1,2,6,15,17,18,19 3382-辛炔酸甲酯METHYL 2-OCTYNOATE 1,2,3,8,17,18,19339乙酸甲酯METHYL ACETATE 5,18,19340茴香酸甲酯METHYL ANISATE, METHYL p-ANISATE 1,2,5,6,8,17,18,19 341邻氨基苯甲酸甲酯METHYL ANTHRANILATE 1,2,4,6,7,11,17,18,19 342苯甲酸甲酯METHYL BENZOATE 1,2,3,5,6,8,15,17,18,19METHYL CINNAMATE 1,2,3,4,5,6,7,8,11,12,15,17,18,19 344甲基环戊烯醇酮METHYLCYCLOPENTENOLONE 4,5,6,7,8,16,17,18,19345二氢茉莉酮酸甲酯METHYL DIHYDROJASMONATE 1,2,3,8,17,18,19346异戊酸甲酯METHYL ISOVALERATE 1,5,7,12,17,18,19347亚油酸甲酯METHYL LINOLEATE 1,2,3,5,6,7,11,15,17,18,19348亚麻酸甲酯METHYL LINOLENATE 1,2,3,5,6,15,17,18,19349甲硫醇METHYL MERCAPTAN 5,18,19350甲基-β-萘基酮METHYL-β-NAPHTHYL KETONE 1,5,17,18,19351壬酸甲酯METHYL NONANOATE 5,18,19352苯乙酸甲酯METHYL PHENYLACETATE 1,2,3,4,5,6,7,8,11,15,17,18,19 353水杨酸甲酯METHYL SALICYLATE 1,2,3,4,5,6,7,8,15,17,18,19354二甲基硫醚DIMETHYL SULFIDE 1,2,5,17,18,193554-(对甲氧基苯基)-2-丁酮4-(4-METHOXYPHENYL)-2-BUTANONE 1,8,17,18,19356α-甲基紫罗兰酮METHYL-ALPHA-IONONE 8,18,19 3571-甲基-2,3-环己二酮1-METHYL-2,3-CYCLOHEXADIONE 8,17,18,193585-甲基-2-苯基-2-己烯醛5-METHYL-2-PHENYL-2-HEXENAL 1,7,17,18,19359对甲基苯甲醚p-METHYLANISOLE 1,2,8,17,19360麝香酮，3-甲基环十五烷酮3-METHYL-1-CYCLOPENTADECANONE 1,2,5,17,18,193616-甲基-3,5庚二烯-2-酮6-METHYL-3,5-HEPTADIEN-2-ONE 1,2,3,5,7,8,11,15,17,18,193621-甲基-3-甲氧基-4-异丙基苯1-METHYL-3-METHOXY-4-ISOPROPYLBENZENE 1,2,8,15,17,18,193632-甲基-4-苯基丁醛2-METHYL-4-PHENYLBUTYRALDEHYDE 1,2,5,15,17,18,196-METHYL-5-HEPTEN-2-ONE 1,2,3,5,6,7,8,11,15,17,18,193654-甲基-5-乙烯基噻唑4-METHYL-5-VINYLTHIAZOLE 1,4,17,18,193662-甲基-反式-2-丁烯酸2-METHYL-trans-2-BUTENOIC ACID 1,2,8,15,17,18,193674-甲基苯乙酮4-METHYLACETOPHENONE 1,2,3,4,6,7,8,10,12,14,15,17,18,19368乙酸苏合香酯ALPHA-METHYLBENZYL ACETATE, STYRALYL ACETATE 1,2,3,8,17,18,193693-甲基-2-丁烯醛3-METHYL-2-BUTEN-1-AL, 3-METHYL-2-BUTENAL 4,18,193702-甲基丁醛2-METHYLBUTYRALDEHYDE 1,2,3,5,6,8,17,18,193713-甲基丁醛，异戊醛3-METHYLBUTYRALDEHYDEISOVALERALDEHYDE 1,2,3,4,6,7,8,10,12,13,14,16,17,18,19 3722-甲基丁酸2-METHYLBUTYRIC ACID 1,2,3,4,5,6,7,8,9,10,12,13,14,15,16,17,18,19 3736-甲基香豆素6-METHYL COUMARIN 4,18,19374甲基纤维素METHYL CELLULOSE 4,5,18,19375（5H）-5-甲基-6,7-二氢环戊基并[b]吡嗪(5H)-5-METHYL-6,7-DIHYDROCYCLOPENTA-[B]-PYRAZINE 4,8,17,18,193765-甲基糠醛5-METHYL FURFURAL 5,18,19377威士忌内酯WHISKEY LACTONE 4,18,193782-甲基庚酸2-METHYLHEPTANOIC ACID 1,2,3,5,15,17,18,193792-甲基己酸2-METHYLHEXANOIC ACID 1,2,3,4,5,7,15,17,18,19 3802-甲基-5-甲硫基呋喃2-METHYL-5-METHYLTHIOFURAN 5,18,193813-甲基戊酸3-METHYL PENTANOIC ACID 1,2,3,8,10,16,17,18,19 3822-甲基戊酸2-METHYLPENTANOIC ACID 1,7,8,17,18,193832-甲基吡嗪2-METHYL PYRAZINE 1,2,3,4,5,8,10,15,16,17,18,19 3845-甲基喹啉5-METHYL QUINOXALINE 1,2,3,8,16,17,18,193852-甲基四氢呋喃-3-酮2-METHYLTETRAHYDROFURAN-3-ONE 1,7,8,17,18,193864-甲基噻唑4-METHYL THIAZOLE 4,18,193873-甲硫基丙酸甲酯METHYL 3-METHYLTHIOPROPIONATE 4,8,18,193882-甲基十一醛2-METHYL UNDECANAL 5,18,19cis-JASMONE 5,18,19390月桂烯MYRCENE 5, 18,19391十四酸，肉豆蔻酸MYRISTIC ACID 1,2,3,6,10,15,17,18,19 392β-萘乙醚β-NAPTHYL ETHYL ETHER 1,5,17,18,19393β-萘甲醚β-NAPHTHYL METHYL ETHER 5394橙花醇NEROL 1,2,3,5,7,8,17,18,19 395橙花叔醇NEROLIDOL 1,2,3,5,8,15,17,18,19 396乙酸橙花酯NERYL ACETATE 8,17,18,19397氮NITROGEN 4,5,9,10398反式-2-顺式-6-壬二烯醛NONA-2-trans, 6-cis-DIENAL 1,2,6,7,17,18,19399反式-2-顺式-6-壬二烯-1-醇2,6-NONADIEN-1-OL 1,2,3,5,8,15,17,18,19400δ-壬内酯δ-NONALACTONE 8, 18,19401γ-壬内酯γ-NONALACTONE 1,2,3,5,7,8,9,10,11,12,13,14,15,17,18,19 402壬醛NONANAL 1,5,7,8,17,18,19403壬酸NONANOIC ACID 1,2,3,5,6,7,8,15,17,18,194042-壬酮2-NONANONE 1,2,3,8,17,18,19405反式-2-壬烯-1-醇trans-2-NONEN-1-OL 1,2,3,7,17,18,194062-壬烯醛2-NONENAL 1,5,17,18,19407乙酸壬酯NONYL ACETATE 1,7,17,18,19408壬醇NONYL ALCOHOL 2,3,4, 18,19409δ-辛内酯δ-OCTALACTONE 1,2,3,4,5,7,8,12,14,15,16,17,18,19410γ-辛内酯γ-OCTALACTONE 1,2,3,4,5,7,8,9,10,12,15,16,17,18,19 411辛醛OCTANAL 1,2,7,8,17,18,19412辛酸OCTANOIC ACID 1,2,3,4,5,6,7,8,10,11,14,15,16,17,18, 191-OCTANOL 1,4,5,8,17,18,194142-辛酮2-OCTANONE 1,2,3,17,18,194151-辛烯-3-醇1-OCTEN-3-OL 1,2,3,8,10,15,16,17,18,194162-辛烯醛2-OCTENAL 1,2,3,5,15,17,18,194171-辛烯-3-醇乙酸酯1-OCTEN-3-YL ACETATE 1,7,17,18,19418乙酸辛酯OCTYL ACETATE 5, 18,19419异丁酸辛酯OCTYL ISOBUTYRATE 1,2,7,17,18,19420油酸OLEIC ACID 1,6,17,18,19421棕榈酸PALMITIC ACID 1,2,3,5,8,10,15,17,18,19422石蜡PARAFFIN WAX 4,9,16,19423十五内酯PENTADECANOLIDE 1,2,4,5,7,8,15,17,18,194242,3-戊二酮2,3-PENTANEDIONE 1,2,3,5,8,15,16,17,18,194252-戊酮2-PENTANONE 1,2,3,5,8,10,15,16,17,18,19426α-水芹烯α-PHELLANDRENE 1,6,7,8,17,18,19427乙酸苯乙酯PHENETHYL ACETATE 1,4,5,6,7,8,11,15,16,17,18,19428苯乙醇PHENETHYL ALCOHOL 1,2,3,5,6,7,8,9,10,11,12,13,14,15,17, 18,19 429丁酸苯乙酯PHENETHYL BUTYRATE 1,2,6,7,8,11,15,17,18,19430肉桂酸苯乙酯PHENETHYL CINNAMATE 1,2,6,8,17,18,19431异丁酸苯乙酯PHENETHYL ISOBUTYRATE 1,2,4,5,6,7,8,10,11,16,17,18,19432异戊酸苯乙酯PHENETHYL ISOVALERATE 1,2,3,5,7,8,10,17,18,19433苯乙酸苯乙酯PHENETHYL PHENYLACETATE 1,2,3,5,7,8,10,17,18,19434苯丙醇3-PHENYL-1-PROPANOL, PHENYLPROPYL ALCOHOL 1,2,3,4,5,6,8,10,16,17,18,194352-苯基-2-丁烯醛2-PHENYL-2-BUTENAL 1,2,7,8,17,18,194364-苯基-3-丁烯-2-酮4-PHENYL-3-BUTEN-2-ONE 1,2,4,6,7,8,18,19437苯乙醛PHENYLACETALDEHYDE 5,7,8,11,12,14,19438苯乙酸PHENYL ACETIC ACID 1,2,3,4,7,8,9,10,11,12,14,16,17,18,193-PHENYLPROPIONALDEHYDE 1,2,5,8,17,18,194403-苯基丙酸3-PHENYLPROPIONIC ACID 1,2,3,5,8,17,18,19441乙酸-3-苯丙酯3-PHENYLPROPYL ACETATE 1,5,15,17,18,19442磷酸PHOSPHORIC ACID 1,2,6,17,443α-蒎烯α-PINENE 1,2,3,5,7,8,11,16,17,18,19444β-蒎烯β-PINENE 1,2,7,8,17,18,19445D-胡椒酮D-PIPERITONE 1,2,7,17,18,19446胡椒醛PIPERONAL 1,2,3,4,5,7,8,9,10,11,12,13,14,15,16,17,18,19 447乙酸钾POTASSIUM ACETATE 5448碳酸钾POTASSIUM CARBONATE 2,3,4,5,15,449柠檬酸钾POTASSIUM CITRATE 4,8,9,16,17450磷酸钾POTASSIUM PHOSPHATE 5451山梨酸钾POTASSIUM SORBATE 1,2,3,4,6,7,8,15,16,17,452L-脯氨酸L-PROLINE 1,4,17,18,194533-丙烯基-6-乙氧基苯酚PROPENYL GUAETHOL 1,2,3,5,6,7,8,9,10,11,12,13,14,15,17,18,19454丙酸PROPIONIC ACID 1,2,3,4,5,6,8,17,18,19455乙酸丙酯PROPYL ACETATE 1,2,3,8,17,18,19456正丙醇n-PROPYL ALCOHOL 5,18,19457丁酸丙酯PROPYL BUTYRATE 5,18,19458苯乙酸丙酯PROPYL PHENYL ACETATE 5,19459丙二醇PROPYLENE GLYCOL，1,2-PROPANEDIOL 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19 4603-丙叉苯酞3-PROPYLIDENEPHTHALIDE 1,2,3,5,7,8,15,16,17,18,19461丙酮酸PYRUVIC ACID 1,2,3,5,6,7,8,10,11,16,17,18,19462L-鼠李糖L-RHAMNOSE 2,3,15,18,19463玫瑰醇RHODINOL 1,2,3,5,7,8,11,12,13,14,15,17,18, 19RHODINYL ACETATE 5,18,19465玫瑰醚ROSE OXIDE 4,5,8,17,18,19466朗姆醚RUM ETHER 1,2,3,5,6,17,18,19467水杨醛SALICYLALDEHYDE 1,2,3,4,5,6,7,8,12,15,17,18,19 468香紫苏内酯SCLAREOLIDE 1,2,7,11,12,13,14,17,18,19469乙酸钠SODIUM ACETATE 1,4,8,9,17,18,19470藻酸钠SODIUM ALGINATE 4,5,19471对羟基苯甲酸丙酯钠SODIUM PROPYL 4-HYDROXYBENZOATE 4,8,17472磷酸钠SODIUM PHOSPHATE 5,9,16473苯甲酸钠SODIUM BENZOATE 1,2,3,4,6,8,11,12,13,17474碳酸氢钠SODIUM BICARBONATE 1,2,4,5,15,17475碳酸钠SODIUM CARBONATE 1,2,3,4,5,8,15,17476柠檬酸钠SODIUM CITRATE 1,2,3,4,6,8,9,10,16,17477磷酸二氢钠SODIUM DIHYDROGENORTHOPHOSPHATE 4478对羟基苯甲酸乙酯钠SODIUM ETHYL 4-HYDROXYBENZOATE 8,17479对羟基苯甲酸甲酯钠SODIUM METHYL 4-HYDROXYBENZOATE 8,17480山梨酸SORBIC ACID 2,4,5,6,8,17,19481蔗糖SUCROSE 2,3,5,7,9,10,11,12,13,14,15,17,18 482八乙酸蔗糖酯SUCROSE OCTAACETATE 1,2,3,15,17,18,19483单宁酸TANNIC ACID 1,4,5,17,18,19484酒石酸TARTARIC ACID 1,4,5,8,12,17,19485酒石酸钾(钠) TARTARIC ACID POTASSIUM AND SODIUM SALTS 4,5,18486α-松油醇α-TERPINEOL 1,2,3,4,7,8,12,13,15,17,18,19 487萜品油烯,异松油烯TERPINOLENE 1,2,4,6,7,8,11,12,17,18,19488乙酸松油酯TERPINYL ACETATE 1,2,5,7,8,15,17,18,194894,5,6,7-TETRAHYDRO-3,6-DIMETHYL BENZOFURAN 5, 18,19基苯并呋喃490δ-十四内酯TETRADECALACTONE, δ-TETRADECALACTONE 5,8,17,18,194915,6,7,8-四氢喹喔啉5,6,7,8-TETRAHYDROQUINOXALINE 1,2,8,15,17,18,194922,3,5,6-四甲基吡嗪2,3,5,6-TETRAMETHYLPRAZINE 4,5,7,8,10,12,16,18,19493百里香酚THYMOL 1,2,5,6,8,17,18,19494维生素E TOCOPHEROLS(MIXED) 1,2,4,7,8,17,184953-甲基苯甲醛m-TOLYL ALDEHYDE, 3-METHYLBENZALDEHYDE 1,2,5,6,7,8,17,18,194962-甲基苯甲醛o-TOLYL ALDEHYDE; 2-METHYLBENZALDEHYDE 1,2,5,6,7,8,17,18,194974-甲基苯甲醛p-TOLYL ALDEHYDE; 4-METHYLBENZALDEHYDE 1,2,5,6,7,8,17,18,194983-甲基-2-丁烯-1-醇3-METHYL-2-BUTEN-1-OL 4,18,19499乙酸对甲苯酯p-TOLYL ACETATE 1,2,3,5,6,7,8,15,17,18,19500异丁酸对甲苯酯p-TOLYL ISOBUTYRATE 1,2,7,8,17,18,19501苯乙酸对甲苯酯p-TOLYL PHENYLACETATE 1,7,17,18,195022-十三酮2-TRIDECANONE 1,2,3,10,15,17,18,19503柠檬酸三乙酯TRIETHYL CITRATE 1,2,3,4,5,6,8,10,15,17,18,195043,5,5-三甲基-1-己醇3,5,5-TRIMETHYL-1-HEXANOL 1,2,6,8,17,18,195052,2,6-三甲基环己酮2,2,6-TRIMETHYLCYCLOHEXANONE 1,2,3,5,15,17,18,195062,3,5-三甲基吡嗪2,3,5-TRIMETHYLPYRAZINE 1,2,3,4,6,7,8,10,11,12,13,15,16,17,18,19 507δ-十一内酯δ-UNDECALACTONE 1,2,3,8,15,17,18,19508γ-十一内酯，桃醛γ-UNDECALACTONE 1,2,3,4,5,7,8,9,10,11,12,13,14,15,16,17,18,19 5092-十一酮2-UNDECANONE 1,2,3,8,15,17,18,1951010-十一烯醛10-UNDECENAL 5,18,19UREA 1,2,3,4,5,6,8,15,17512戊醛VALERALDEHYDE 1,2,5,6,7,8,17,18,19513戊酸VALERIC ACID 1,2,5,7,8,17,18,19514γ-戊内酯γ-VALEROLACTONE 1,2,3,4,5,7,8,10,13,15,17,18,19515D,L-缬氨酸D,L-VALINE 1,6,17,18,19516香兰素VANILLIN 1,2,3,4,5,6,7,8,9,10,11,12,13,14,15,16,17,18,19 5174-羟基-3-甲氧基苄醇VANILLYL ALCOHOL 4,195183,4-二甲氧基苯甲醛VERATRALDEHYDE 3,4-DIMETHOXYBENZENECARBONAL 1,2,3,5,6,7,8,12,15,17,18,19519水WATER 1,2,3,4,5,6,7,8,10,11,12,13,14,15,16,17520木糖醇XYLITOL 1,17,18521D-木糖D-XYLOSE6,18,19表2 烟草添加剂（天然）中文名称英文名称参考文献1金合欢胶，阿拉伯树胶ACACIA GUM 5,8,18,192紫苜蓿提取物ALFALFA EXTRACT 1,2,3,6,7,8,10,17,18,193海藻树脂ALGA RESINOID 5,184多香果提取物、油树脂及油ALLSPICE EXTRACT, OLEORESIN, AND OIL 1,2,4,5,7,13,17,18,195苦杏仁油ALMOND BITTER OIL 1,5,17,18,196琥珀油AMBER OIL 5,197龙涎香酊AMBERGRIS TINCTURE 1,5,7,17,18,198黄葵籽油和净油AMBRETTE SEED OIL AND ABSOLUTE 5,18,199脂檀油AMYRIS OIL 1,2,6,7,8,17,1810反式-大茴香醚trans-ANETHOLE 1,2,3,5,6,9,10,15,17,18,19 11当归根油ANGELICA ROOT OIL 1,2,3,5,6,7,8,9,10,17,19 12当归根提取物ANGELICA ROO EXTRACT 1,2,3,5,6,8,9,10,17,1913独活酊ANGELICA ROOT TINCTURE/EXTRACT 1,2,3,5,6,8,9,10,17,1914当归籽油ANGELICA SEED OIL 1, 5, 6, 3, 2, 17, 9, 10,18,19 15八角茴香提取物及油ANISE, ANISE STAR, EXTRACT AND OILS 1,2,3,5,6,9,10,17,18,1916苹果提取物APPLE EXTRACT 1,2,3,4,6,8,10,16,1717苹果汁浓缩物, 提取物和皮提取物APPLE JUICE CONCENTRATE, EXTRACT, AND SKINS 1,2,3,4,6,7,8,10,16,17APRICOT EXTRACT 1,2,4,6,7,8,10,16,17,19 19杏汁及其浓缩液APRICO JUICE, CONCENTRATE 1,2,4,6,8,10,16,1720花生油ARACHIS OIL 521秘鲁油BALSAM PERU OIL 1,2,3,6,7,8,10,15,17,18,19 22秘鲁香膏BALSAM PERU 1,2,3,6,7,10,15,17,18,19 23香蕉提取物BANANA EXTRACT 8,1724月桂叶油BAY LEAF OIL 1,2,5,6,17,1925甜月桂叶油BAY LEAF OIL, SWEET 1,2,5,6,17,18,1926山毛榉焦油提取物BEECH TAR EXTRACT 527白色蜂醇蜡BEES WAX WHITE 1,2,3,5,6,10,15,17,1828甜菜汁浓缩物BEET JUICE CONCENTRATE 1,2,3,4,1729安息香树脂BENZOIN RESIN 1,2,3,5,6,7,8,10,11,12,13,14,15,16,17,18 ,1930香柠檬油BERGAMOT OIL 1,2,4,5,6,7,12,13,17,18,19 31红醋栗净油BLACK CURRANT BUDS ABSOLUTE 1,4,8,17,1932黑莓及其提取物BLACKBERRY FRUITS, FRESH EXTRACTS 5,1933波罗尼净油BORONIA ABSOLUTE 8,17,18,1934玫瑰木油BOIS DE ROSE OIL 2,6,7,8,18,1935白兰地净油BRANDY ABSOLUTE 8,1736布枯叶油BUCHU LEAF OIL 1,2,4,7,8,16,17,18,1937奶油, 奶油酯和奶油油BUTTER, BUTTER ESTERS, AND BUTTER OIL 1,2,3,17,18,1938白千层油CAJEPUT OIL 5,18,19。
酱香型白酒中吡嗪类化合物的检测及特点
酱香型白酒中吡嗪类化合物的检测及特点孙棣;赵贵斌;杨波【摘要】建立了白酒中8种吡嗪化合物的液相色谱串联质谱检测方法.通过检测结果找出酱香型白酒中吡嗪化合物的特点(8种吡嗪化合物中三甲基吡嗪和四甲基吡嗪含量较高),同时对真假茅台酒酒样中8种吡嗪化合物进行测定,并将检测结果进行分析,其中真茅台酒四甲基吡嗪的含量远远高于其他吡嗪化合物,含量在9.25～28.3 mg/L,假茅台酒中四甲基吡嗪的含量在0.89～12.5 mg/L.该方法对提高酱香型白酒质量及真伪酒的鉴别提供参考.【期刊名称】《中国酿造》【年(卷),期】2015(034)012【总页数】5页(P162-166)【关键词】液相色谱-质谱联用;酱香白酒;吡嗪类化合物【作者】孙棣;赵贵斌;杨波【作者单位】贵州省产品质量检验检测院,贵州贵阳550004;贵州省产品质量检验检测院,贵州贵阳550004;贵州省产品质量检验检测院,贵州贵阳550004【正文语种】中文【中图分类】TS262.33;O657.63在白酒产业群中，酱香型白酒其香型、名声和价值居首要位置，其生产工艺在中国白酒行业中具有唯一性。
研究表明，酱香型白酒中吡嗪类化合物种类和含量最高，不仅是特征风味物质，其中四甲基吡嗪也是公认的功能因子。
其中吡嗪类化合物与酱香型白酒的感官特征密切相关，吡嗪含量高低从某种意义上来说也影响酱香白酒的品质［1-5］。
目前关于白酒中吡嗪类化合物的检测手段主要集中在气相色谱和气质联用法［6-12］，检测方法较为单一，前处理过程较为复杂，需要经过多次样品转移从而引起目标化合物的损失，影响定量的准确性。
本研究建立了酱香型白酒中吡嗪类化合物的高效液相色谱-串联质谱（high performance 1iquid chromatography-tandem mass spectrometry，HPLCMS/MS）检测方法，可以对酱香型白酒中主要的8种吡嗪类化合物进行准确定量，用建立的方法分别对31个酱香型白酒的代表酒样进行测定，找到了酱香型白酒中吡嗪类化合物的一些特点，同时也对同一规格的20个真茅台酒和20个假茅台酒分别进行了测定，对检测结果进行了分析。
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中文名称： 2,5-二甲基吡嗪
英文名称： 2,5-Dimethylpyrazine
CAS号：4965-29-1
分子式：C6H8N
分子量：108.14
理化性质：为无色液体，能溶于水和乙醇，熔点15℃，沸点155℃，相对密度d204 0.9900，折射率n20D 1.4997，
天然存在：存在于猪肉、可可、咖啡、土豆片、河虾中。
感官特征：具有坚果香、花生、霉味、壤香、土豆、脂肪香、可可粉的气味；7.5 mg/kg的溶液具有坚果、土豆、脂肪的味道。
应用建议：用于调配可可、花生、咖啡、坚果、土豆、调味品用食用香精中。
建议用量：在最终加香食品中浓度约为0.5～10mg/kg。
安全管理情况：2,5-二甲基吡嗪的FEMA编号为3272，CoE编号为2210。
中国GB 2760－1996批准为允许使用的食用香料。
SPT有最丰富、最齐全的香精香料产品线，了解更多产品信息。