汽巴精化荧光增白剂Tinopal CBS

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荧光增白剂BL和BW的应用研究

摘要：研究了荧光增白剂BL、BW、CF-351、CBS-X对洗衣粉的粉体白度、棉织物白度、棉织物色光等的应用效果。

结果表明，荧光增白剂BL和BW在洗衣粉粉体白度、棉织物白度、棉织物色光等方面都较传统CF-351、CBS-X应用效果有较大提高，其中BL应用效果优于BW。

关键词：荧光增白剂；BL；BW；CF-351；CBS-X；增白强度；色光；棉织物；洗衣粉；粉体白度中图分类号：TQ649.4 文献标识码：A 文章编号：1672-2701（2021）01-33-04荧光增白剂BL和BW的应用研究荧光增白剂是一种利用光学上的补色原理，提高物质白度和光泽的有机化合物，主要用于纺织、造纸、塑料及合成洗涤剂等领域[1-3]。

其中二苯乙烯联苯类荧光增白剂，具有可低温增白、添加量小、增白效果显著、易于被降解等优点，被誉为超级荧光增白剂[4]。

随着该类增白剂的广泛应用，客户对其应用性能提出了更高要求，我们在CF-351的基础上，新开发出荧光增白剂BL、BW两个品种，在洗衣粉粉体白度、棉织物白度、棉织物色光等方面都较传统二苯乙烯联苯增白剂应用效果有较大提高。

1 实验部分1.1 原料与仪器BL、BW、CF-351均为沈阳新纪化学有限公司自产，其余增白剂为国产某品牌CBS-X、进口CBS-X，标准无磷洗衣粉、标准棉布、去离子水、无水硫酸钠。

WSD-3全自动白度仪、DL-6000（Starlet-3）红外染色机、datacolor550分光测色仪、恒温鼓风干燥箱、电子天平(万分之一)、容量瓶、烧杯等。

1.2 洗衣粉增白性能的测定(1)样品的配制在5个烧杯中加入等量的标准无磷洗衣粉，然后加入同比例的不同荧光增白剂，用水配成料浆，在70℃的水浴中搅拌10 min，将料浆平摊于培养皿中，于（130±5）℃的干燥箱中干燥至恒重，对已干燥的物料进行粉碎、过筛，收集细粉得到实验所需的待测产品。

共测3组不同浓度数据，并制作出曲线图。

塑料增白剂的配方

塑料增白剂的配方一、塑料增白剂的类型1.领域增白剂：主要用于塑料制品的成型过程中，如注塑、挤出和吹塑等。

常见的领域增白剂有荧光增白剂、白色颜料、白色无机颜料。

2.专用增白剂：专用增白剂适用于特定类型的塑料，如聚氯乙烯(PVC)、聚丙烯(PP)、聚乙烯(PE)等。

常见的专用增白剂有荧光增白剂、紫外线防护剂。

二、塑料增白剂的制备方法1.荧光增白剂的制备方法：荧光增白剂是一类能吸收紫外光，再发射可见光的化合物。

其制备过程通常包括合成荧光增白剂原料、精细调节增白剂分子结构和制备增白剂粉末等步骤。

2.无机颜料的制备方法：无机颜料主要是利用铁、钛、锌等金属及其化合物的特性，通过溶解、沉淀、煅烧等工艺制备而成。

其制备过程涉及物料选择、溶解、反应、过滤、洗涤、干燥等工艺步骤。

三、塑料增白剂的配方设计1.荧光增白剂的选择：聚丙烯(PVC)常用的荧光增白剂有OB、OB-1、FP-127、KCB等。

根据所需效果和成本考虑，选择合适的荧光增白剂。

2.配方设计：将荧光增白剂按一定比例与聚氯乙烯(PVC)树脂混合。

通常增白剂的添加量为塑料总量的0.05%至0.5%，具体比例可根据需求实际调整。

同时，可适当添加稳定剂、抗氧化剂等辅助添加剂，以提高PVC 塑料的性能和稳定性。

3.混炼过程：将荧光增白剂和聚氯乙烯(PVC)树脂加入混炼机中，通过高温和剪切力使增白剂均匀分散于塑料中。

4.吹塑成型：将混炼好的PVC料粒再次加热、挤出，并通过吹塑机制成所需的塑料制品。

四、塑料增白剂应用总结：塑料增白剂是通过合理选择增白剂和塑料树脂的配方，通过混炼和成型等处理工艺，提高塑料制品的白度和质量。

在实际生产中，需要根据不同塑料类型和应用需求进行配方设计，并合理控制增白剂的添加量和混炼工艺，以获得理想效果。

荧光增白剂210

荧光增白剂APCC.I.220 CAS ：16470-24-9结构式：分子式：C 40H 40N 12O 16S 4Na 4相对分子质量：1165.12 (按1997年国际相对原子质量) 最大紫外吸收波长：350nm 执行标准： HG/T 3727-2003 质量指标：性能特点：1、使用方便，可与水任意比例混溶，适宜于自动化连续添加计量。

2、有良好的耐酸性，即使在较低的PH 值下，也有优异的增白效果。

3、本产品采用先进的纳滤技术，使其含盐量较低，在常温下，具有较好的贮存稳定性。

4、与同类产品比较，具有相当的日晒牢度及耐酸碱牢度。

5、在0℃以上产品保持稳定，-3℃以下可能会结冰，但加热后会溶解，不影响使用效果。

适用范围：1、在纸浆中进行荧光增白。

2、在表面施胶中进行荧光增白。

3、在涂布过程中进行荧光增白。

使用方法：1、在浆内可直接加入，常规用量：0.05-1.2%（绝对干浆）。

2、在表面施胶中与常用的淀粉、CMC 、PV A 一起使用可获得较好的增白效果，常规用量：0.5-10g/L 。

C NCNC NNHNH CH CH SO 3NaNH SO 3NaHNCN CNC NSO 3NaNaO 3SN(C 2H 4OH)2N(C 2H 4OH)23、在涂布过程中，任意位置添加均可，在与PV A、CMC、淀粉一起使用时会获得更好的效果，常规用量：0.1-1.4%(对涂料重量)。

包装与贮存：1000 kg、200 kg塑料桶包装，根据客户需要可提供特殊包装。

应贮存于阴凉、干燥、通风的库房内，贮存期为六个月。

注意事项：1、本产品的资料仅供参考、研究和鉴定，本公司并不承担由此所引起的责任和专利纠纷。

2、如您有任何技术或使用问题，请及时与我公司联系。

荧光增白剂KCB

■聚合物添加剂荧光增白剂 KCB 化学成分化学名称2,2-(1,4-亚萘基)双(苯并恶唑) CAS5089-22-5 分子式C24H14N2O2 分子量362化学结构规格指标及物理特性规格单位标准外观黄绿色粉末熔点℃ 210-212 含量 % ≥99.0包装25公斤纸板桶产品特点及应用●荧光增白剂 KCB 属苯并恶唑类型荧光增白剂,最大吸收波长370nm●本品具有极强的增白效果,色调为蓝亮白色光，不溶于水●荧光增白剂 KCB 主要用于合成纤维与塑料的增白,对有色塑料制品有明显的增加艳丽的效果,大量用于塑料薄膜,压膜成型材料的增白,对聚烯烃、发泡PVC ，TPR ，EVA 及聚氨酯泡沫具有极强的增白增艳效果；还可用于聚酯纤维以及涂料,天然漆的增白，对发泡塑料特别是EVA ，PE 有特效 ●根据具体应用的不同， FP127 在未加颜料的聚烯烃中用量为0.0005-0.0010%，在其他塑料中为0.005-0.050%特性：-有良好的热稳定性，特殊的增白性能，良好的光稳定性和低挥发性-无毒无味-不与发泡剂、交联剂反应●更多信息请参考化学品安全说明书搬运及储存在搬运或使用该产品之前请查阅安全数据表。

若以适当的方式贮存在25°C以下的干燥区域，保质期为一年声明*以下信息替代了买方文件。

关于适销性或适用于特定用途，不存在任何明示或暗示担保。

我们所提供的使用建议，不得被视为侵犯任何专利权的原因。

对于因疏忽或违反条款、严格赔偿责任、民事侵权行为或与产品有关合同而产生的附带、结果性或间接损失，杰得佳概不负责。

买方唯一能要求赔偿的是买方的买价。

数据和结果以受监控的研究或实验室研究为依据，买方应根据预定使用条件进行检测，确认这些数据和结果的准确性。

并未针对以下应用进行检测，因此不建议将产品用于：长期接触粘膜、破损的皮肤或血液；或植入人体。

New Effective Optical Brightener KCB (荧光增白剂KCB)

New Effective Optical Brightener KCB （荧光增白剂KCB）Chemical Component:Benzoxazolyl Naphthalene Optical BrightenerTypical Properties:Appearance: Yellowish Crystal PowderEffective Assay: 99%minAsh Content: 0.5%maxV olatile: 0.3%maxCharacters:New effective optical brightener SP-KCB is an improved product of current widely used normal KCB(Hostalux KCB), whose temperature and weather resistance capability is much better than normal KCB. It’s extremely effective in brightening and present blue optical light when mixed in synthetic fiber and plastics, especially in colorful plastics. Much convenient, less dosage, better whiteness and lower price are the superior characters.Application :SP-KCB can be widely used in EV A, PET, and is the best choice for making sports shoes material. It is also good at applying into plastic films such as PE, PP, PVC, PS, ABS, and extrude molding material, injection molding material. The whiteness of coating and natural painting could also be greatly improved by SP-KCB.Safety and stock:Keeping in stock as ordinary chemicals. Wear protective goggles and gloves while applying.A void direct contact with skin and eyes. Soap clean if skin contaminated.Packing:25kg / fiber drum with PE linerOptical Brightener Odyssey OB-1 （荧光增白剂OB-1）Optical brighteners are added to many materials to reduce yellowing, improve whiteness, and to enhance the brightness of a product. Odyssey OB-1 is used widely in the plastic market. Because of its excellent brightening ability,good thermal stability,and compatibility with many polymers. Typical PropertiesChemical name: 2,2-(1,2-Ethenediyldi-4, 1-phenylene) bisbenzoxazoleMolecular weight: 414.4CAS No.: 1533-45-5C.I.: 393Specifications:Ash %Empirical FormulaMelting Point(DTA),CAppearanceOdorV olatile Content %Assay %Particle Size0.3maxC28H18N2O2353-359Y ellowish Green PowderFree of odor0.3max99min200 meshesEffect of Optical Brighteners on the Whiteness of PolymersOptical brighteners function by absorbing ultraviolet radiation and remitting blue light. The emitted blue light will reduce the yellow color of a polymer. In the presence of a whitening agent, such as TiO2, the use of Odyssey OB-1 will produce a brilliant white o r “white than white” appearance.Two primary factors affect the whiteness/yellowness of a formulation. They are the color of the base polymer and the level of brightener added. If no whitening agent, such as TiO2, is used, the level of Odyssey OB-1 required will likely be lower than when a whitening agent is preset. This level might be as little as 25-50 ppm. In determining the optimum concentration of brightener, the effect of any other UV-absorbing materials in the plastic should be considered. It is important that users perform sufficient evaluations to determine the optimum level of Odyssey OB-1 for their specific end uses.Methods of AdditionTo be effective, an optical brightener must dissolve in the polymer to which it is added. Since the typical addition levels for Odyssey OB-1 in the range of 100-400 ppm, the use of a concentrate, or masterbatch, is recommended. Concentrates are containing 1%-10% by weight of Odyssey OB-1 typical.The concentrate can be produced on an extruder using normal processing conditions for the polymer, including drying if necessary. The concentrate is then let down to typical use levels in the final formulation. Plastics compounding equipment is normally adequate for producing Odyssey OB-1 brightener formulations. The key requirement is to thoroughly disperse the brightener so that it will dissolve uniformly throughout the molten polymer. This is usually achieved most readily with a concentrate.Improving Whiteness of Recycled PolymerThe business of processing post consumer plastics and waste polymer continue to grow. These materials can be recycled into a variety of useful products, from plastic lumber to synthetic fiber. Polyester bottle polymer, polyester plastic waste, and waste fiber polymer can be recycled into polyester fiber that can be used in carpets, filling and insulation material, nonwovens, and apparel. One of the shortcomings of processing these materials is the uncertainty of the color of the source material.By using optical brighteners, the value of the recycled materials can be significantly enhanced by providing a more uniform white. Odyssey OB-1 will greatly improve the whiteness, Normal fiber applications require only 200-300 ppm in new polymer, but recycled material may require as much as 300-450 ppm. Optical brighteners are very effective in improving the appearance of the polymer or fiber. Off-class or second-quality nylon polymer can also be improved in the same way.Food Industry ApplicableOdyssey OB-1 complies with regulations for indirect food additives. Odyssey OB-1 is restricted to use as an optical brightener for all polymers at a level not to exceed 0.025% by weight of polymer and at the temperatures not to exceed 135"C(275"F).Packing:25kg / fiber drum with PE linerHomepage Chinese V ersionWelcome you to visit the website of Beijing Odyssey Chemicals Co.,Ltd.© Beijing Odyssey Chemicals Co.,Ltd. All Rights Reserved.Optical Brightener Odyssey OB （荧光增白剂OB）Odyssey OB is a high molecular weight optical bright ener of the thiophenediyl benzoxazole class, suitable for the optical brightener of polymers at all stage of processing.Typical PropertiesChemical Name: 2,2-(2,5-Thiophenediyl) Bis[5-(1,1-dimethylethy)]BenzoxazoleMolecular Formula: C27H27O2N2SMolecular Weight: 443CAS No.: 7128-64-5C.I.: 184Specifications:Appearance: Yellowish or yellowish green crystal powderAssay: 99% min.Melting Point: 196-203?Ash: 0.3% max.V olatile Content: 0.3%max.Particle size: 200 meshesMax. Absorption Wavelength: 375nm(in ethanol)Properties:Optical Brightener Odyssey OB is highly effective in polymer substrates such as engineering plastics, e.g. PE, PC, PVC, PS, ABS, and PP, adhesive and other organic substrates.Main applications include fibers, molded articles, films and sheets. And also can be used in clear lacquers, pigmented lacquers, paints, printing ink and synthetic leather. It will produce brilliant brightness with dyestuff, which is very efficient in directions for multicolor.Optical Brightener Odyssey OB can be used as a tracer in a variety of applications.Odyssey OB features excellent resistance to heat, exceptional whitening properties, good light fastness and low volatility. It is readily soluble in organic solvents and features good compatibility in various substrates. The product is especially suitable for applications such as films and fiber. Odyssey OB enhances the whiteness of the substrate. In combination with dyes, the product produces particularly bright shades. Its excellent heat resistance renders Odyssey OB suitable for all relevant processing conditions. It is suitable for packing applications but local regulations must be observed.Application (in each 100kg polymer):PVC: White 0.01-0.05 (10g-50g)Transparent 0.0001-0.001% (0.1g-1g)PS: White 0.001% (1g)Transparent 0.0001-0.001% (0.1g-1g)ABS: Primitive color 0.01-0.05% (10g-50g)(effectively eliminate the intrinsic yellow color in ABS)White 0.01-0.05% (10g-50g)PE, PP: Achromaticity 0.0005-0.001% (0.5g-1g)White 0.005-0.05% (5g-50g)Other Plastics: Refer to the directions given above.When Odyssey OB is used in PMMA polymerization, take care that the polymerization is conducted to full completion since interaction with residual monomer can cause discoloration in the final application.Attention:Please mix thoroughly to obtain best effect. OB concentrated master batch can be even better mixed.Safety and Stock:Keeping in stock as ordinary chemicals. Wear protective goggles and gloves while applying.A void direct contact with skin and eyes. Soap clean if skin contaminated.Packing:25kg / fiber drum with PE linerProduct name: Optical Brightening Agent PF （荧光增白剂PF）·Chemical name: 1.2 di(5-mythyl-benziazolyl)ethylene·Structural No: C.i 135·CAS NO: 12224-12-3·Structural formula:·Molecular formula: C18H14N2O2·Molecular weight: 290·Technical index: Appearance:Light yellow crystal powderMelting Point:184~186°CPurity:≥98.0%·Uses: It is mainly used in increasing the brightening and beauty of PVC,PS,PP,polyester film, high or low voltage PE,ABS, organic glass, business card,high quality paper,etc.. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent PF-3 （荧光增白剂PF-3）·Chemical name: 1.2 di(5-mythyl-benziazolyl)ethylene·Structural No: C.i 135·CAS NO: 12224-12-3·Structural formula:·Molecular formula: C18H14N2O2·Molecular weight: 290·Technical index: Appearance:Light yellow crystal powderMelting Point:188~190°CPurity:≥99.0%·Uses: It is mainly used in increasing the brightening and beauty of PVC,PS,PP,polyester film, high or low voltage PE,ABS, organic glass, business card,high quality paper,etc..·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent ER-1（荧光增白剂ER-1）·Chemical name: 1,4'-bis(2-cyanostyryl) Benzene·Structural No: C.i 199·CAS NO: 13001-40-6·Structural formula:·Molecular formula: C24H16N2·Molecular weight: 332·Properties: It has high whitening brightening effect and excellent fastness to sublimation. ·Technical index: Appearance:greenish yellow crystalline powder Melting Point:230-232°C Purity:≥98.0% Maximum UV Absorption Spectrum:365nm·Uses: Mainly be used in whitening of polyester fiber and as the raw material of paste form brightening agent in textile dyeing.·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent ER-Ⅱ（荧光增白剂ER-11）·Chemical name: 1,4'-bis(2,4'-cyano-phenlene)-benzene·Structural No: C.i 199:1·CAS NO: 13001-40-6·Molecular formula: C24H16N2·Molecular weight: 332·Properties: bluish color shade with high whitening brightening effect and excellent fastness to sublimation.·Technical index: Appearance:slight yellow powder Melting Point:183~185°C Purity:≥98.0% Maximum UV Absorption Spectrum:369nm·Uses: mainly be used as whitening agent for polyester fiber, as well the raw material of makingpaste form brightening agent in textile dyeing.·Precaution: The information of our products is for reference only. We are not responsible forany unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent KSN （荧光增白剂KSN）·Chemical name: 4.4-bis(5-methyl-2-benzoxoazol)-ethylene·Structural formula:·Properties: 1. being highly whiteness with small usage.2. multipurpose used for whitening of polyester fiber and plastic.3. having a good compatibility and good fastness to light and sublimation. Can be used for high temperature process.·Treating Process: Overlay plastic:0.5-2g/100kgPolyester fiber:10-20g·Package: 20kg cardboard drum·Technical index: Appearance: greenish yellow powderMelting process: 275~280°CAsh content:≤0.5%Purity:≥98.0%V olatile content:≤0.5%Fineness(300 mesh):100%·Uses: mainly be used in whitening of polyester, polyamide, polyacrylonitrile fiber, the plastic film and all plastic pressing process. Can suitable for synthesizing high polymer including polymeric process.·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by itFLUORESCENT BRIGHTENER CBS-X（洗涤用荧光增白剂CBS-X）MOLECULAR FORMULA: C28H20S2O6Na2MOLECULAR WEIGHT: 562.60(As International relative Atom Mass 1997)EXCUTIVE STANDARD: Q/LQH005-2002PARAMETERS:APPEARANCE: Pistachio granuleSMELL: No special smellMAX UV ABSORPTION SPECTRUM: 348nm±1nmEXTINCTION V ALUE: 0.829-0.8851% EXTINCTION INDEX: 1105-1181PROPERTY:Optical Brightener CBS-X is a disulfonic distyrylbiphenyl biphenyl compound, which is the most excellent brightener used in detergent industry. It can soluble in water easily and has betterwhitener effect on cellulose fiber, polyamide and proteinic fiber at room temperature. It has high brighten intensity on cotton cloth as much 2.7times diphenylethylene tristriazine derivatives, and has well optical blue color moniter, dissolve and disperse properties. It has extremely high stability with hypochloride sodium, it is a bleaching resistenct optical brightener.APPLICA TION:Used in detergent industry and soap industry.PROCEDURE:1. It can be added in any procedure of the process of synthetic detergent and soap. It can get excellent and soap. It can get excellent effect if used together with optical brightener 31#.2. Recommended dosage:Common washing powder: 0.005-0.03% Soap: 0.01-0.05%Concentrated washing powder: 0.01-0.05% Soften agent of fabric fiber: 0.01-0.05%Liquid detergent: 0.02-0.06% Washing syrup: 0.005-0.02% PACKAGE: Packed per 25kg in cardboard bucket or cardboard box after being packed in plastic bag first.TRANSPORTA TION: A void upside down, sunlight, wet and crash, avoide damage the package. STORAGE: Should be stored in cool, dry and ventilate place, stored term shouldn’t exceed 2 yearsProduct name: Optical Brightening Agent EBF （荧光增白剂EBF）·Chemical name: 2.5-bis-(benzoxazol-2-)thiophene·Structural No: C.i 185·CAS NO: 12224-40-6·Structural formula:·Molecular formula: C18H10N2O2S·Molecular weight: 318·Technical index: Appearance:Bright-colored light yellowist crystal powderMelting Point:216~220°CPurity:≥98.0%·Uses: It is used in making commercialized Brightener-EB,and can also be used in various polyolefing plastics,ABS engineering plastics and organic glass to make their color brighter. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Product name: Optical Brightening Agent FP-127 （荧光增白剂FP-127）·Chemical name: 1,1'-biphenyl-4,4'-bis-benzoxazole·Structural No: C.i 378·CAS NO: 40470-68-6·Structural formula:·Molecular formula: C30H26O2·Molecular weight: 418·Technical index: Appearance:slight yellow powderMelting Point:219-221°CPurity:≥98.0%Maximum UV Spectrum Absorption:359nm·Uses: Mainly be used in whitening of plastics such as PVC,PS,ABS,TPR,etc. ·Precaution: The information of our products is for reference only. We are not responsible for any unexpected results or patent dispute caused by it.Fluorescent Whitening Agent HW A（荧光增白剂HW A二磺酸型）1.Properties:Appearance:yellow-brown clear viscous liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicPH V alue:8-10Resistance to acid and alkali:suitable for PH5-13Solubility:soluble in water in any ratio2.Applications:Fluorescent whitening agent(FWA) for cotton/cellulose fibres,nylon fibres,rayon fibres,wool and silk and their blends.High affinity,extremely suitable for exhaust application.Extremely good light and wet fastness properties.Good stability in peroxide and reductive bleaching liquors.Can be used in boiling-off baths.Extremely suitable for fluorescent whitening of viscose and modal fibres3.Amounts required:Cotton and bast fibres:0.18-0.7%HW A;Viscose and bast fibres:0.4-1.5% HWA,3-5 g/l sodium sulphate calc.Polyamide fibres:0.5-2% HWA,2-4 g/L hydrosulphite-based reducing agent.Wool,silk:0.5-1.5%HWA,2-4 g/L hydrosulphite-based reducing agent4.Packaging and storing:20/25/50/220KGS plastic drums.Stored in cool place and prevented it from being shone by sunlight.Fluorescent Whitening Agent HPE（荧光增白剂HPE四磺酸型）1.Properties:Appearance:amber clear viscous liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicResistance to acid and alkali:suitable for PH2-12Solubility:soluble in water in any ratio.2.Applications:This product is especially suitable for whitening and brightening paper pulp,knitted goods and cotton fabrics.The whitening effect of VBL will decrease remarkably when the PH value is lower than 6,while NT-3,since more water-soluble groups have been introduced into its structure,does not only have a very good water solubility,but also has a much higher resistance to acid,and thus has a very good whitening effect on cellulose fiber even if the PH value is only 3-4.3.Directions for use and dosage:Since HPE is a liquid,not so hard to dissolve as VBL and will not cause dust pollution,it is only necessary to weigh out it according to the whitenes required and dilute it in water in any ratio.The dosage recommended is as follow:1)For whitening paper pulp:3-10‰ on weight of dry paper pulp.2)For whitening knitted goods:4-8g/l when using paddyeing process,and if 2-4g anhydrous sodium sulfate is added in the padding bath,the whiteness of fabric will be greatly increased.0.4-1.2% O.W.F..when using dipdyeing process.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.Fluorescent Whitening Agent HST（荧光增白剂HST六磺酸型）1.Properties:Appearance:slight yellow liquidStructure:a compound of diphenylethylene triazine typeIonicity:anionicResistance to acid and alkali:suitable for PH2-12Solubility:soluble in water in any ratio.2.Applications:This product is especially suitable for whitening and brightening paper pulp,knitted goods and cotton fabrics.The whitening effect of VBL will decrease remarkably when the PH value is lower than 6,while HST,since more water-soluble groups have been introduced into its structure,does not only have a very good water solubility,but also has a much higher resistance to acid,and thus has a very good whitening effect on cellulose fiber even if the PH value is only 3-4.This product has very excellent resistance to disturbance of cation,it is more superior to common fluorescent whitening agents,so it is specially suitable to coating and sizing press in paper-making when cation auxiliaries is necessary.3.Directions for use and dosage:Since RSB is a liquid,not so hard to dissolve as VBL and will not cause dust pollution,it is only necessary to oweigh out it according to the whiteners required and dilute it in water in any ratio.The dosage recommended is as follows:1)For whitening paper pulp:3-10‰ on weight of dry paper pulp.2) For whitening knitted goods:4-8g/l when using pad-dyeing process,and if 2-4g anhydrous sodium sulfate is added in the padding bath,the whiteness of fabric will be greatly increased.0.4-1.2% O.W.F.when using dip-dyeing process.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.Fluorescent Whitening Agent HS（荧光增白剂HS特殊型）1.Properties:Appearance:light yellow transparent clear liquid.Structure:a compound of diphenylethylene xenene type.Solubility:soluble in water,alcohol,ether,DMF,etc.Fluorescence tone:slight greenish blue.Resistance to chlorine-bleaching and oxygen-bleaching:extremely strong resistance to chlorine-and oxygen-bleaching,and having very good whitening effect even if under strong acidic or alkalic conditions.2.Applications:Because of its extremely strong resistance to chlorine-and oxygen-bleaching,HS is the best whitening agent for natural fibres,and could be widely used in detergent,dyeing & printing and paper-making industries,etc.It is also the most excellent whitening agent for washing powder,washing cream and liquid detergent.As its solvent is polyhydric alcohol,preventing pollution of liquid detergent by bacteria propagation,so it is specially suitable for liquid detergent.3.Directions for use and dosage:Since HS has a very good affinity for cellulose fiber and is soluble in water,it can be used at room temperature for whitening cellulose fiber,polyamide fiber and protein fiber.For whitening textiles,the dosage should normally be 0.1-1.0% O.W.F.When used in detergents,it can be added at any stage of production process and the dosage should be 0.15-1.2% on weight of detergent.4.Packaging and storing:Packaged in plastic barrels,25kg or 50kg each.Stored in dry room.。

荧光增白剂FP127

■聚合物添加剂荧光增白剂FP127化学成分化学名称4,4’-双[2-(2-甲氧基苯基)亚乙基]-1,1’-联苯CAS 40470-68-6分子式C30H26O2分子量419化学结构规格指标及物理特性规格单位标准外观淡黄色结晶粉末熔点℃218-224含量%≥99.0产品特点及应用●FP127是一种联苯类的光学增亮剂(荧光增白剂)，它适合对聚合物所有加工阶段产生光学增亮作用●FP127在丙烯酸类，热塑性聚氨酯，聚氯乙烯，苯乙烯的共聚与均聚体，聚烯烃和其他有机基体中非常有效。

-主要应用还包括纤维，模塑产品，膜及片材。

-其他应用有清漆，颜色漆，涂料，印刷油墨及有机皮革中。

-适合于合成洗衣粉，液体洗涤剂，香（肥）皂等洗涤品种；也可直接用于棉、麻、丝、羊毛、锦纶和纸张常温下的光学增白●根据具体应用的不同，FP127 在未加颜料的聚烯烃中用量为0.0005-0.0010%，在其他塑料中为0.005-0.100%特性：-有良好的热稳定性，特殊的增白性能，良好的光稳定性和低挥发性-优异的蓝绿效果-易溶于有机溶剂并在不同基体中有良好的相容性，该产品特别适用于膜类及纤维类。

-增进了基体的白度。

它与染料并用产生一种特别的明亮效果●更多信息请参考化学品安全说明书包装25公斤纸板桶搬运及储存在搬运或使用该产品之前请查阅安全数据表。

若以适当的方式贮存在25°C以下的干燥区域，保质期为一年声明*以下信息替代了买方文件。

关于适销性或适用于特定用途，不存在任何明示或暗示担保。

我们所提供的使用建议，不得被视为侵犯任何专利权的原因。

对于因疏忽或违反条款、严格赔偿责任、民事侵权行为或与产品有关合同而产生的附带、结果性或间接损失，概不负责。

买方唯一能要求赔偿的是买方的买价。

数据和结果以受监控的研究或实验室研究为依据，买方应根据预定使用条件进行检测，确认这些数据和结果的准确性。

并未针对以下应用进行检测，因此不建议将产品用于：长期接触粘膜、破损的皮肤或血液；或植入人体。

增白剂(荧光剂)的种类及用途(最新整理)

增白剂（荧光剂）的种类及用途增白剂俗称白色染料，是一种无色并在紫外光照射下能激发出荧光的有机化合物，它能提高物质的白度和光泽。

增白作用是利用光学上的补色原理，使泛黄物质经荧光增白剂处理后，不仅能反射可见光，还能吸收可见光以外的紫外光并转变为具有紫蓝色或青色的可见光反射出来。

黄色和蓝色互为补色，抵消了物质原有的黄色，使之显得洁白。

按化学结构可分为五类：①二苯乙烯型，用于棉纤维及某些合成纤维、造纸、制皂等工业，具有蓝色荧光；②香豆素型，具有香豆酮基本结构，用于赛璐璐、聚氯乙烯塑料等，具有较强的蓝色荧光；③吡唑啉型，用于羊毛、聚酰胺、腈纶等纤维，具有绿色荧色；④苯并氧氮型，用于腈纶等纤维及聚氯乙烯、聚苯乙烯等塑料，具有红色荧光；⑤苯二甲酰亚胺型，用于涤纶、腈纶、锦纶等纤维，具有蓝色荧光。

增白剂主要用于纺织、造纸、塑料、涂料、洗涤剂、印刷油墨、蜡、包装材料等。

增白剂只是光学上的增亮补色，并不能代替化学漂白。

因此，带色物不经漂白，直接用增白剂处理，不能从根本上获得洁白效果，使用时应注意。

商品名焦亚硫酸钾成分焦亚硫酸钾性能及用途白色单斜晶系结晶或白色结晶性粉末或颗粒。

通常具有氧化硫气味。

相对密度2.3 00。

190时分解。

在空气中缓慢氧化成硫酸钾。

遇无机酸分解成二氧化硫气体。

呈强还原性。

溶于水，难溶于乙醇。

pH（1%水溶液）3.54.5。

含量90.0%。

本品为漂白剂、防腐剂、抗氧化剂。

可用于葡萄酒、果酒、速冻虾、干燥水果、淀粉糖浆等。

安全注意事项ADI0～0.7mg/kg(以SO2计，FAO/WHO，1985）。

LD50600～700mg/ kg（以SO2计，兔，经口）。

GRAS（FDA，§182.3637,1985）。

商品名亚硫酸氢钠成分亚硫酸氢钠与焦亚硫酸钠混合而成性能及用途白色或黄白色单斜晶系晶体或粗粉。

带二氧化硫气味。

在空气中不稳定，缓慢氧化成硫酸盐和二氧化硫。

易溶于水，难溶于乙醇。

pH（1%水溶液）4.05.5。

卡尔科弗卢尔荧光增白剂液体分子量

卡尔科弗卢尔荧光增白剂液体分子量1. 荧光增白剂的基本知识1.1 什么是荧光增白剂？你有没有发现，洗衣店的衣物总是看起来特别亮白？那就是荧光增白剂在发挥作用啦。

简单来说，荧光增白剂是一种让衣物看起来更白更亮的化学物质。

当你用它的时候，它会吸收一些光线，然后发出一种人眼看不到的光线，最后让衣物看起来更干净、更白。

这就像是让衣物穿上了超级白的“魔法衣”，让你看到的白色更加闪亮。

1.2 卡尔科弗卢尔荧光增白剂的特性。

提到卡尔科弗卢尔，嗯，听名字就有点高大上对吧？别担心，听我说，这种荧光增白剂液体，它的分子量可是有点儿意思的。

分子量其实就是衡量一个分子多重的标准，简单来说，就是告诉我们这种物质的“体重”。

卡尔科弗卢尔的分子量比较大，像一支超级壮汉，给衣物的增白效果特别强，所以它能让你的衣物白得像雪一样。

2. 如何计算分子量？2.1 分子量的计算方式要计算分子量，我们得先知道分子里面的原子都有哪些。

想象一下，这就像是你把一瓶汽水倒进一个大的测量杯里，看看里面的液体有多重。

计算分子量也是类似的，我们要把组成这个分子的每个原子的“重量”加起来。

比如，卡尔科弗卢尔的分子中有很多的碳、氢和氧，每个原子的重量我们都知道了，然后把它们加在一起，就能得出整体的分子量了。

2.2 实际应用中的作用知道了分子量，咱们就可以在实际中知道这种荧光增白剂的“强度”了。

比如在洗衣粉中，它的分子量决定了它能处理多少污垢和发亮的效果。

如果分子量很大，说明它的“能力”也很强。

这样一来，洗出来的衣物更白，更能吸引目光。

就像你用了一款超级有效的洗面奶，脸上的污垢都能被清理得干干净净一样。

3. 影响分子量的因素3.1 结构对分子量的影响一个分子的分子量不仅仅跟它的原子数量有关，还跟这些原子怎么排列组合有关。

就像你做个大拼图，拼的方式不同，最终的效果也不同。

如果原子排列得特别复杂，分子量自然就会更大。

所以，卡尔科弗卢尔这种荧光增白剂，分子量大，也跟它的分子结构有关系，它的结构设计就是为了能发挥最佳的增白效果。

PS-1涤纶荧光增白剂(C.I.199)使用说明

PS-1涤纶荧光增白剂（C.I.199）使用说明生产厂商:保定市嘉德化工有限公司
技术指标外观淡黄色浆状液体色光蓝紫光
PH值5-7
颗粒度2-3µ以下≥90%比重1.038±0.001
性能及特点
1、C.I.199(CAS:13001-40-6)白度高、荧光强、用量少、能够提高印染质量、降低生产成本；
2、C.I.199(CAS:13001-40-6)不含国际上禁用的24种芳香胺、无毒、无致癌物、使用安全可靠。

用途本品主要适用于涤纶、涤棉、涤丝、涤麻等混纺织物的增白、增艳，本品可适用于轧染、高温高压浸染，也适用于低温吸附固着浸染法高温定型工艺。

使用方法1、轧染法：
用量：1.5-3克/升（按实际用量而定），焙烘定型185-190℃,30秒。

2、高温高压浸染法：
用量：0.2-0.5%（相对染织物）；
浴比：1:20-40；
上染温度：120-130℃；
上染时间：30-60分钟；
PH值：4.5-5（用乙酸调节）
3、低温吸附固着浸染法；
用量：0.5-1.0%（相对染织物）；。

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汽巴精化荧光增白剂Tinopal CBS-X与国内仿制品的比较

慧聪网 2005年11月30日16时16分信息来源：汽巴精化网友评论 0 条进入论坛

【hc360慧聪网化工行业】：在日用化工行业，清洁去污是洗涤剂的最基本功能，人们总是期望洗涤后的织物能亮白
如新，持久不发黄，因为白色代表了干净，纯洁。所以洗涤剂的外观白度、去污力和洗后织物白度是决定产品的品质优劣
的重要因素。

针对市场上林林总总的品牌产品，最后的赢家必然是比拼修炼
内功即内在质量的过硬能力的强者。由于白度对消费者来说是一种
感官评价，所以有必要制定一种符合人性化，具可比性、重复性和
稳定性的白度测定方法来检测洗涤剂的质量指标来满足制造商的要
求。

作为世界上荧光增白剂最大制造商的汽巴精化公司经过多年研
究推出了白度的Ganz/Griesser测定法（这两位科学家均就职于
汽巴精化公司）。由于测定结果的高度可重复性即可比性，同时根
除了仪器测定结果于人眼观测的不一致性Ganz/Griesser法被认
为是目前最为合理的白度测定方法，并已为国际照明协会所推荐，并被世界主要生产测色仪器的生产商所采用。

对于亚洲人的室外晒干的洗衣习惯，衣物势必要承受频繁的日光暴晒，因此在亚洲为了保持衣物的白净，洗涤剂必须
提供充分的具有充分高的光稳定性的荧光增白剂。

荧光增白剂对于保持织物白度的最理想状态是，在反复洗涤过程中既不改变织物的荧光强度和也不改变荧光增白剂的
总浓度。超级荧光增白剂Tinopal CBS-X (天来宝 CBS-X)的最大荧光发射波长在435-440nm之间，因此用其洗涤的
纤维素纤维织物具有相当明亮的中性兰色色光。同时，它使洗衣粉的粉体具有相当高的中性兰色白度。而绝大多数二苯乙
烯型普通荧光增白剂在纤维素纤维上的荧光发射波长则在440-450nm之间，呈现兰绿色色光，因而反复洗涤织物后，由
于荧光增白剂的聚集及积累会使白色织物带有明显的绿色色光（同时色泽变暗）。

那么如何选用和识别优秀的增白剂呢？
众所周知，汽巴精化是最早发明Tinopal CBS-X (天来宝 CBS-X)环保型的超级增白剂的专利拥有者，拥有最先进
的研发中心、测试技术和仪器、生产工艺及设备及制造技术，决定了Tinopal CBS-X (天来宝 CBS-X)的质量和技术永
远保持着全球领先的水平。尽管目前国内外有一些小厂在仿造其分子结构并实施生产，但是其产品质量仍存在很大问题（由
于技术、仪器、设备等的限制）。

主要表现在如下方面：
1．杂质含量高于标准如Fe等重金属含量。众所周知，Fe离子含量高，易引起白色衣服发黄而且此结果不可逆转。
2．活性物太偏低。尽管一些厂家宣称能达到90%，但实测值往往只有85%，这样最后吃亏的就是洗涤剂厂家。
3．质量不稳定。如时好时坏，有时活性物可至87-90%,有时只有83-85%.
4．关键核心技术和设备未达到要求。为节省成本，工艺和技术未达到国际标准，容易引起洗衣粉发黄现象。（某些知
名国际公司已屡次发现使用国产仿造产品引起的粉体发黄问题）
5．织物多次洗涤增白效果差不如汽巴产品。Tinopal CBS-X (天来宝 CBS-X)经多次洗涤后则织物越洗越白，持久
亮白不发黄。
6．无相应技术支持。因这些小厂本身对该产品技术缺乏了解，更无研发中心对该产品应用于洗涤进行研究，所以无法
对客户进行技术支持和问题解答。

附表：Tinopal CBS-X (天来宝 CBS-X)与某仿造品之比较。
天来宝CBS-X 某仿造品
外观自由流动的黄色颗粒淡黄色粉末
流动性极好，无粉尘差，极大粉尘
活性物 90% 85-90%
溶解度清澈溶液浊液，有黑色颗粒
DMSO 0g/kg 53g/kg
Fe离子 <6ppm 46ppm