On the metallicity of the Milky Way thin disc and photometric abundance scales

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27295384_关键金属元素铍的原位分析技术研究进展

27295384_关键金属元素铍的原位分析技术研究进展
elements with ~ 50% to trace elements as low as 100n × 10 -6 This paper summarizes the characteristics of insitu analysis
, , , techniques including electron microprobe analyzer laser ablation inductively coupled plasma mass spectrometry ion probe mass , , , spectrometry laserinduced breakdown spectroscopy automatic quantitative analysis system and discuss these instruments how to , , overcome these special difficulties of beryllium minerals obtain the beryllium mineral features from macro to micro minor to non , , destructive qualitative semiquantitative to quantitative major to trace content These provide technical support for scientific research ; ; and prospecting of beryllium resources
物、金绿宝石、蓝柱石、磷钙铍石、磷铍钠石、闽江石、孟宪民
石等(车旭东等, ; , ; , ; 2007 Rao et al 2015 Rao et al 2017

SCI写作句型汇总

SCI写作句型汇总

SCI写作句型汇总S C I论文写作中一些常用的句型总结(一)很多文献已经讨论过了一、在Introduction里面经常会使用到的一个句子:很多文献已经讨论过了。

它的可能的说法有很多很多,这里列举几种我很久以前搜集的:A.??Solar energy conversion by photoelectrochemical cells?has been intensively investigated.?(Nature 1991, 353, 737 - 740?)B.?This was demonstrated in a number of studies that?showed that composite plasmonic-metal/semiconductor photocatalysts achieved significantly higher rates in various photocatalytic reactions compared with their pure semiconductor counterparts.C.?Several excellent reviews describing?these applications are available, and we do not discuss these topicsD.?Much work so far has focused on?wide band gap semiconductors for water splitting for the sake of chemical stability.(DOI:10.1038/NMAT3151)E.?Recent developments of?Lewis acids and water-soluble organometalliccatalysts?have attracted much attention.(Chem. Rev. 2002, 102, 3641?3666)F.?An interesting approach?in the use of zeolite as a water-tolerant solid acid?was described by?Ogawa et al(Chem.Rev. 2002, 102, 3641?3666)G.?Considerable research efforts have been devoted to?the direct transition metal-catalyzed conversion of aryl halides toaryl nitriles. (J. Org. Chem. 2000, 65, 7984-7989) H.?There are manyexcellent reviews in the literature dealing with the basic concepts of?the photocatalytic processand the reader is referred in particular to those by Hoffmann and coworkers,Mills and coworkers, and Kamat.(Metal oxide catalysis,19,P755)I. Nishimiya and Tsutsumi?have reported on(proposed)the influence of the Si/Al ratio of various zeolites on the acid strength, which were estimated by calorimetry using ammonia. (Chem.Rev. 2002, 102, 3641?3666)二、在results and discussion中经常会用到的:如图所示A. GIXRD patterns in?Figure 1A show?the bulk structural information on as-deposited films.?B.?As shown in Figure 7B,?the steady-state current density decreases after cycling between 0.35 and 0.7 V, which is probably due to the dissolution of FeOx.?C.?As can be seen from?parts a and b of Figure 7, the reaction cycles start with the thermodynamically most favorable VOx structures(J. Phys. Chem. C 2014, 118, 24950?24958)这与XX能够相互印证:A.?This is supported by?the appearance in the Ni-doped compounds of an ultraviolet–visible absorption band at 420–520nm (see Fig. 3 inset), corresponding to an energy range of about 2.9 to 2.3 eV.B. ?This?is consistent with the observation from?SEM–EDS. (Z.Zou et al. / Chemical Physics Letters 332 (2000) 271–277)C.?This indicates a good agreement between?the observed and calculated intensities in monoclinic with space groupP2/c when the O atoms are included in the model.D. The results?are in good consistent with?the observed photocatalytic activity...E. Identical conclusions were obtained in studies?where the SPR intensity and wavelength were modulated by manipulating the composition, shape,or size of plasmonic nanostructures.?F.??It was also found that areas of persistent divergent surfaceflow?coincide?with?regions where convection appears to be consistently suppressed even when SSTs are above 27.5°C.(二)1. 值得注意的是...A.?It must also be mentioned that?the recycling of aqueous organic solvent is less desirable than that of pure organic liquid.B.?Another interesting finding is that?zeolites with 10-membered ring pores showed high selectivities (>99%) to cyclohexanol, whereas those with 12-membered ring pores, such as mordenite, produced large amounts of dicyclohexyl ether. (Chem. Rev. 2002, 102,3641?3666)C.?It should be pointed out that?the nanometer-scale distribution of electrocatalyst centers on the electrode surface is also a predominant factor for high ORR electrocatalytic activity.D.?Notably,?the Ru II and Rh I complexes possessing the same BINAP chirality form antipodal amino acids as the predominant products.?(Angew. Chem. Int. Ed., 2002, 41: 2008–2022)E. Given the multitude of various transformations published,?it is noteworthy that?only very few distinct?activation?methods have been identified.?(Chem. Soc. Rev., 2009,?38, 2178-2189)F.?It is important to highlight that?these two directing effects will lead to different enantiomers of the products even if both the“H-bond-catalyst” and the?cata lyst?acting by steric shielding have the same absolute stereochemistry. (Chem. Soc. Rev.,?2009,?38, 2178-2189)G.?It is worthwhile mentioning that?these PPNDs can be very stable for several months without the observations of any floating or precipitated dots, which is attributed to the electrostatic repulsions between the positively charge PPNDs resulting in electrosteric stabilization.(Adv. Mater., 2012, 24: 2037–2041)2.?...仍然是个挑战A.?There is thereby an urgent need but it is still a significant challenge to?rationally design and delicately tail or the electroactive MTMOs for advanced LIBs, ECs, MOBs, and FCs.?(Angew. Chem. Int. Ed.2 014, 53, 1488 – 1504)B.?However, systems that are?sufficiently stable and efficient for practical use?have not yet been realized.C.??It?remains?challenging?to?develop highly active HER catalysts based on materials that are more abundant at lower costs. (J. Am. Chem.Soc.,?2011,?133, ?7296–7299)D.?One of the?great?challenges?in the twenty-first century?is?unquestionably energy storage. (Nature Materials?2005, 4, 366 - 377?)众所周知A.?It is well established (accepted) / It is known to all / It is commonlyknown?that?many characteristics of functional materials, such as composition, crystalline phase, structural and morphological features, and the sur-/interface properties between the electrode and electrolyte, would greatly influencethe performance of these unique MTMOs in electrochemical energy storage/conversion applications.(Angew. Chem. Int. Ed.2014,53, 1488 – 1504)B.?It is generally accepted (believed) that?for a-Fe2O3-based sensors the change in resistance is mainly caused by the adsorption and desorption of gases on the surface of the sensor structure. (Adv. Mater. 2005, 17, 582)C.?As we all know,?soybean abounds with carbon,?nitrogen?and oxygen elements owing to the existence of sugar,?proteins?and?lipids. (Chem. Commun., 2012,?48, 9367-9369)D.?There is no denying that?their presence may mediate spin moments to align parallel without acting alone to show d0-FM. (Nanoscale, 2013,?5, 3918-3930)(三)1. 正如下文将提到的...A.?As will be described below(也可以是As we shall see below),?as the Si/Al ratio increases, the surface of the zeolite becomes more hydrophobic and possesses stronger affinity for ethyl acetate and the number of acid sites decreases.(Chem. Rev. 2002, 102, 3641?3666)B. This behavior is to be expected and?will?be?further?discussed?below. (J. Am. Chem. Soc.,?1955,?77, 3701–3707)C.?There are also some small deviations with respect to the flow direction,?whichwe?will?discuss?below.(Science, 2001, 291, 630-633)D.?Below,?we?will?see?what this implies.E.?Complete details of this case?will?be provided at a?later?time.E.?很多论文中,也经常直接用see below来表示,比如:The observation of nanocluster spheres at the ends of the nanowires is suggestive of a VLS growth process (see?below). (Science, 1998, ?279, 208-211)2. 这与XX能够相互印证...A.?This is supported by?the appearance in the Ni-doped compounds of an ultraviolet–visible absorption band at 420–520 nm (see Fig. 3 inset), corresponding to an energy range of about2.9 to 2.3 eVB.This is consistent with the observation from?SEM–EDS. (Chem. Phys. Lett. 2000, 332, 271–277)C.?Identical conclusions were obtained?in studies where the SPR intensity and wavelength were modulated by manipulating the composition, shape, or size of plasmonic nanostructures.?(Nat. Mater. 2011, DOI: 10.1038/NMAT3151)D. In addition, the shape of the titration curve versus the PPi/1 ratio,?coinciding withthat?obtained by fluorescent titration studies, suggested that both 2:1 and 1:1 host-to-guest complexes are formed. (J. Am. Chem. Soc. 1999, 121, 9463-9464)E.?This unusual luminescence behavior is?in accord with?a recent theoretical prediction; MoS2, an indirect bandgap material in its bulk form, becomes a direct bandgapsemiconductor when thinned to a monolayer.?(Nano Lett.,?2010,?10, 1271–1275)3.?我们的研究可能在哪些方面得到应用A.?Our ?ndings suggest that?the use of solar energy for photocatalytic watersplitting?might provide a viable source for?‘clean’ hydrogen fuel, once the catalyticef?ciency of the semiconductor system has been improved by increasing its surface area and suitable modi?cations of the surface sites.B. Along with this green and cost-effective protocol of synthesis,?we expect that?these novel carbon nanodots?have potential applications in?bioimaging andelectrocatalysis.(Chem. Commun., 2012,?48, 9367-9369)C.?This system could potentially be applied as?the gain medium of solid-state organic-based lasers or as a component of high value photovoltaic (PV) materials, where destructive high energy UV radiation would be converted to useful low energy NIR radiation. (Chem. Soc. Rev., 2013,?42, 29-43)D.?Since the use of?graphene?may enhance the photocatalytic properties of TiO2?under UV and visible-light irradiation,?graphene–TiO2?composites?may potentially be used to?enhance the bactericidal activity.?(Chem. Soc. Rev., 2012,?41, 782-796)E.??It is the first report that CQDs are both amino-functionalized and highly fluorescent,?which suggests their promising applications in?chemical sensing.(Carbon, 2012,?50,?2810–2815)(四)1. 什么东西还尚未发现/系统研究A. However,systems that are sufficiently stable and efficient for practical use?have not yet been realized.B. Nevertheless,for conventional nanostructured MTMOs as mentioned above,?some problematic disadvantages cannot be overlooked.(Angew. Chem. Int. Ed.2014,53, 1488 – 1504)C.?There are relatively few studies devoted to?determination of cmc values for block copolymer micelles. (Macromolecules1991, 24, 1033-1040)D. This might be the reason why, despite of the great influence of the preparation on the catalytic activity of gold catalysts,?no systematic study concerning?the synthesis conditions?has been published yet.?(Applied Catalysis A: General 2002, 226, ?1–13)E.?These possibilities remain to be?explored.F.??Further effort is required to?understand and better control the parameters dominating the particle surface passivation and resulting properties for carbon dots of brighter photoluminescence. (J. Am. Chem. Soc.,?2006,?128?, 7756–7757)2.?由于/因为...A.?Liquid ammonia?is particularly attractive as?an alternative to water?due to?its stability in the presence of strong reducing agents such as alkali metals that are used to access lower oxidation states.B.?The unique nature of?the cyanide ligand?results from?its ability to act both as a σdonor and a π acceptor combined with its negativecharge and ambidentate nature.C.?Qdots are also excellent probes for two-photon confocalmicroscopy?because?they are characterized by a very large absorption cross section?(Science ?2005,?307, 538-544).D.?As a result of?the reductive strategy we used and of the strong bonding between the surface and the aryl groups, low residual currents (similar to those observed at a bare electrode) were obtained over a large window of potentials, the same as for the unmodified parent GC electrode. (J. Am. Chem. Soc. 1992, 114, 5883-5884)E.?The small Tafel slope of the defect-rich MoS2 ultrathin nanosheets is advantageous for practical?applications,?since?itwill lead to a faster increment of HER rate with increasing overpotential.(Adv. Mater., 2013, 25: 5807–5813)F. Fluorescent carbon-based materials have drawn increasing attention in recent years?owing to?exceptional advantages such as high optical absorptivity, chemical stability, biocompatibility, and low toxicity.(Angew. Chem. Int. Ed., 2013, 52: 3953–3957)G.??On the basis of?measurements of the heat of immersion of water on zeolites, Tsutsumi etal. claimed that the surface consists of siloxane bondings and is hydrophobicin the region of low Al content. (Chem. Rev. 2002, 102, 3641?3666)H.?Nanoparticle spatial distributions might have a large significance for catalyst stability,?given that?metal particle growth is a relevant deactivation mechanism for commercial catalysts.?3. ...很重要A.?The inhibition of additional nucleation during growth, in other words, the complete separation?of nucleation and growth,?is?critical(essential, important)?for?the successful synthesis of monodisperse nanocrystals. (Nature Materials?3, 891 - 895 (2004))B.??In the current study,?Cys,?homocysteine?(Hcy) and?glutathione?(GSH) were chosen as model?thiol?compounds since they?play important (significant, vital, critical) roles?in many biological processes and monitoring of these?thiol?compounds?is of great importance for?diagnosis of diseases.(Chem. Commun., 2012,?48, 1147-1149)C.?This is because according to nucleation theory,?what really matters?in addition to the change in temperature ΔT?(or supersaturation) is the cooling rate.(Chem. Soc. Rev., 2014,?43, 2013-2026)(五)1. 相反/不同于A.?On the contrary,?mononuclear complexes, called single-ion magnets (SIM), have shown hysteresis loops of butterfly/phonon bottleneck type, with negligiblecoercivity, and therefore with much shorter relaxation times of magnetization. (Angew. Chem. Int. Ed., 2014, 53: 4413–4417)B.?In contrast,?the Dy compound has significantly larger value of the transversal magnetic moment already in the ground state (ca. 10?1?μB), therefore allowing a fast Q TM. (Angew. Chem. Int. Ed., 2014, 53: 4413–4417)C.?In contrast to?the structural similarity of these complexes, their magnetic behavior exhibits strong divergence.?(Angew. Chem. Int. Ed., 2014, 53: 4413–4417)D.?Contrary to?other conducting polymer semiconductors, carbon nitride ischemically and thermally stable and does not rely on complicated device manufacturing. (Nature materials, 2009, 8(1): 76-80.)E.?Unlike?the spherical particles they are derived from that Rayleigh light-scatter in the blue, these nanoprisms exhibit scattering in the red, which could be useful in developing multicolor diagnostic labels on the basis not only of nanoparticle composition and size but also of shape. (Science 2001,? 294, 1901-1903)2. 发现,阐明,报道,证实可供选择的词包括:verify, confirm, elucidate, identify, define, characterize, clarify, establish, ascertain, explain, observe, illuminate, illustrate,demonstrate, show, indicate, exhibit, presented, reveal, display, manifest,suggest, propose, estimate, prove, imply, disclose,report, describe,facilitate theidentification of?举例:A. These stacks appear as nanorods in the two-dimensional TEM images, but tilting experiments?confirm that they are nanoprisms.?(Science 2001,? 294, 1901-1903)B. Note that TEM?shows?that about 20% of the nanoprisms are truncated.?(Science 2001,? 294, 1901-1903)C. Therefore, these calculations not only allow us to?identify?the important features in the spectrum of the nanoprisms but also the subtle relation between particle shape and the frequency of the bands that make up their spectra.?(Science 2001,? 294, 1901-1903)D. We?observed?a decrease in intensity of the characteristic surface plasmon band in the ultraviolet-visible (UV-Vis) spectroscopy for the spherical particles at λmax?= 400 nm with a concomitant grow th of three new bands of λmax?= 335 (weak), 470 (medium), and 670 nm (strong), respectively. (Science 2001,? 294, 1901-1903)E. In this article, we present data?demonstrating?that opiate and nonopiate analgesia systems can be selectively activated by different environmental manipulationsand?describe?the neural circuitry involved. (Science 1982, 216, 1185-1192)F. This?suggests?that the cobalt in CoP has a partial positive charge (δ+), while the phosphorus has a partial negative charge (δ?),?implying?a tran sfer of electron density from Co to P.?(Angew. Chem., 2014, 126: 6828–6832)3. 如何指出当前研究的不足A. Although these inorganic substructures can exhibit a high density of functional groups, such as bridging OH groups, andthe substructures contribute significantly to the adsorption properties of the material,surprisingly little attention has been devoted to?the post-synthetic functionalization of the inorganic units within MOFs. (Chem. Eur. J., 2013, 19: 5533–5536.)B.?Little is known,?however, about the microstructure of this material. (Nature Materials 2013,12, 554–561)C.?So far, very little information is available, and only in?the absorber film, not in the whole operational devices. (Nano Lett.,?2014,?14?(2), pp 888–893)D.?In fact it should be noted that very little optimisation work has been carried out on?these devices. (Chem. Commun., 2013,?49, 7893-7895)E. By far the most architectures have been prepared using a solution processed perovskite material,?yet a few examples have been reported that?have used an evaporated perovskite layer. (Adv. Mater., 2014, 27: 1837–1841.)F. Water balance issues have been effectively addressed in PEMFC technology through a large body of work encompassing imaging, detailed water content and water balance measurements, materials optimization and modeling,?but very few of these activities have been undertaken for?anion exchange membrane fuel cells,? primarily due to limited materials availability and device lifetime. (J. Polym. Sci. Part B: Polym. Phys., 2013, 51: 1727–1735)G. However,?none of these studies?tested for Th17 memory, a recently identified T cell that specializes in controlling extracellular bacterial infections at mucosal surfaces. (PNAS, 2013,?111, 787–792)H. However,?uncertainty still remains as to?the mechanism by which Li salt addition results in an extension of the cathodicreduction limit. (Energy Environ. Sci., 2014,?7, 232-250)I.?There have been a number of high profile cases where failure to?identify the most stable crystal form of a drug has led to severe formulation problems in manufacture. (Chem. Soc. Rev., 2014,?43, 2080-2088)J. However,?these measurements systematically underestimate?the amount of ordered material. ( Nature Materials 2013, 12, 1038–1044)(六)1.?取决于a.?This is an important distinction, as the overall activity of a catalyst will?depend on?the material properties, synthesis method, and other possible species that can be formed during activation.?(Nat. Mater.?2017,16,225–229)b.?This quantitative partitioning?was determined by?growing crystals of the 1:1 host–guest complex between?ExBox4+?and corannulene. (Nat. Chem.?2014,?6177–178)c.?They suggested that the Au particle size may?be the decisive factor for?achieving highly active Au catalysts.(Acc. Chem. Res.,?2014,?47, 740–749)d.?Low-valent late transition-metal catalysis has?become indispensable to?chemical synthesis, but homogeneous high-valent transition-metal catalysis is underdeveloped, mainly owing to the reactivity of high-valent transition-metal complexes and the challenges associated with synthesizing them.?(Nature2015,?517,449–454)e.?The polar effect?is a remarkable property that enables?considerably endergonic C–H abstractions?that would not be possible otherwise.?(Nature?2015, 525, 87–90)f.?Advances in heterogeneous catalysis?must rely on?the rational design of new catalysts. (Nat. Nanotechnol.?2017, 12, 100–101)g.?Likely, the origin of the chemoselectivity may?be also closely related to?the H?bonding with the N or O?atom of the nitroso moiety, a similar H-bonding effect is known in enamine-based nitroso chemistry. (Angew. Chem. Int. Ed.?2014, 53: 4149–4153)2.?有很大潜力a.?The quest for new methodologies to assemble complex organic molecules?continues to be a great impetus to?research efforts to discover or to optimize new catalytic transformations. (Nat. Chem.?2015,?7, 477–482)b.?Nanosized faujasite (FAU) crystals?have great potential as?catalysts or adsorbents to more efficiently process present and forthcoming synthetic and renewablefeedstocks in oil refining, petrochemistry and fine chemistry. (Nat. Mater.?2015, 14, 447–451)c.?For this purpose, vibrational spectroscopy?has proved promising?and very useful.?(Acc Chem Res. 2015, 48, 407–413.)d.?While a detailed mechanism remains to be elucidated and?there is room for improvement?in the yields and selectivities, it should be remarked that chirality transfer upon trifluoromethylation of enantioenriched allylsilanes was shown. (Top Catal.?2014,?57: 967.?)e.?The future looks bright for?the use of PGMs as catalysts, both on laboratory and industrial scales, because the preparation of most kinds of single-atom metal catalyst is likely to be straightforward, and because characterization of such catalysts has become easier with the advent of techniques that readilydiscriminate single atoms from small clusters and nanoparticles. (Nature?2015, 525, 325–326)f.?The unique mesostructure of the 3D-dendritic MSNSs with mesopore channels of short length and large diameter?is supposed to be the key role in?immobilization of active and robust heterogeneous catalysts, and?it would have more hopeful prospects in?catalytic applications. (ACS Appl. Mater. Interfaces,?2015,?7, 17450–17459)g.?Visible-light photoredox catalysis?offers exciting opportunities to?achieve challenging carbon–carbon bond formations under mild and ecologically benign conditions. (Acc. Chem. Res.,?2016, 49, 1990–1996)3. 因此同义词:Therefore, thus, consequently, hence, accordingly, so, as a result这一条比较简单,这里主要讲一下这些词的副词词性和灵活运用。

关于用UPS测量功函数_张滨

关于用UPS测量功函数_张滨

第25卷第4期2007年7月物理测试P hysics Examination and T estingV ol.25,No.4July 2007作者简介:张 滨(1978),女,硕士生; E -mail:b inzhang@ ; 修订日期:2006-11-14关于用U PS 测量功函数张 滨, 孙玉珍, 王文皓(中国科学院金属研究所分析测试部,辽宁沈阳110016)摘 要:详细介绍了紫外光电子谱(U P S)测量功函数的原理与实验方法,测量了金属镍、银和IT O 靶材的功函数,并对测量方法和误差进行了讨论,表明这个方法更适用于测量功函数变化。

关键词:功函数;U P S中图分类号:O433.1 文献标识码:A 文章编号:1001-0777(2007)04-0021-03Work Function Measurements Using UPSZH NA G Bin, SU N Yu -zhen, WANG Wen -hao(Institut e o f M etal R esear ch,Chinese A cademy o f Sciences,Sheny ang 110016,L iaoning ,China)Abstract:T he pr inciple and method of measur ing o n the w ork funct ion using U PS w ere intr oduced in details.T he w or k funct ion of N i,A g and IT O tar get w as measured,and measuring method and er ror s w ere discussed.It was show that this metho d is av ailable t o measur e on change o f wo rk functio n.Key words:w ork function;U P S功函数是材料的重要物理参数,无论是功能材料还是结构材料,都离不开功函数这个物理量。

26134943_东昆仑中生代隆升剥露历史

26134943_东昆仑中生代隆升剥露历史

2021 37 12
起始时间从由南到北逐渐变老,体现东昆仑地区隆升剥蚀的不均一性。 关键词 构造演化;隆升剥蚀;热演化史;隆升冷却;裂变径迹热年代学;东昆仑 ; 中图法分类号 P542 P597 3
长达~2500km 的东昆仑造山带呈近东西向横亘于青藏 要的成果:1)低温热年代学数据研究表明昆仑地区山在晚三
中,记录下了始于晚三叠世的昆仑柴达木及羌塘地块之间 盆地的沉积记录表明,东昆仑在中生代中晚期至新生代早期
的俯冲碰撞过程。新生代以来的印度板块与欧亚板块的斜 经历长期剥蚀去顶作用(魏岩岩,2017;Yin et al ,2008);
向汇聚碰撞导致青藏高原强烈隆升(赵志丹等,2003;喻顺 3)古流向、碎屑矿物物源分析等一系列证据均指示东昆仑造
, ( ), , 1 Institute of Earth Sciences China University of Geosciences Beijing Beijing 100083 China
, , 2 Third Exploration Institute of Geology of Qinghai Province Xining 810029 China
, , , , , YANG Li1 YUAN WanMing1 ZHU ChuanBao2 HONG ShuJiong1 LI ShiYu1 FENG ZiRui1 and ZHANG AiKui2
1 中国地质大学(北京)科学研究院,北京 100083
2 青海省第三地质勘查院,西宁 810029
( ) 岩石学报 10000569 / 2021 / 037 12 378196 Acta Petrologica Sinica
: doi 10 18654 / 10000569 / 2021 12 11

OW型Pickering乳液的制备及其吸收紫外线性能研究

OW型Pickering乳液的制备及其吸收紫外线性能研究

第50卷第1期2021年1月应用化工Applied Chemical IndustryVol.50No.1Jan:2021 O/W型Pickering乳液的制备及其吸收紫外线性能研究杨惠,黄富宁,朱丽娜,宁娇,张容煜,贺拥军(西安科技大学化学与化工学院,陕西西安710054)摘要:自制芦荟水溶液为水相,以橄榄油为油相,以氧化锌、二氧化钛、云母、碳酸钙颗粒及其混合粒子作为稳定剂,制备出了一种新型0/W型Pickering乳液。

通过数码生物显微镜观察Pickering乳液的液滴粒径及稳定性,紫外分光光度计检测Pickering乳液的吸光度。

结果表明,用氧化锌、二氧化钛、碳酸钙和云母混合颗粒所制备Pickering 乳液均是0/W型,随着油水比的增大,Pmkeong乳液的液滴粒径增大;随着微小固体颗粒用量的增大,PAkeong乳液的液滴粒径也会增大。

以碳酸钙、氧化锌、二氧化钛、云母及其混合粒子为稳定剂制备的水包橄榄油Pickering乳液,对UVA段和UVB段紫外线均有较好的吸收。

关键词:Pickering乳液;紫外线;吸收;稳定性中图分类号:TQ658-4文献标识码:A文章编号:1671-3206(2021)01-0083-04Preparation of O/W Pickering emulsions and theirultraviolet absordhon performanceYANG Hui,HUANG Fu-ning,ZHU,NING Jiao,ZHANG Rong-yu,HE Yong-jun (Colleye of Chemistry and Chemical Engineering,Xi*an University of Science and Technology,Xi'an710054,China)Abstract:0/W typa Picke/ng emulsions were prepared by using/homemada alva water vs water phase,oliva oil vs oil phase,zinc oxiba,titanium dioxiba,mAa and calcium carbonate pa/icles vs stabilizers.Tha droplet siza and5-山00of tha Picke/ng emulsion were observed by a digital biomA/scopa,and tha ult/yiol/absogtion performanco of tha Picke/ng emulsions was mexsumd by an ult/yiol/spectmphv-tometer-Tha results showed that tha Picke/ng emulsions prepared by tha mixing pa/iclas of zinc oxiba,titanium dioxida,calcium carbonata and mAa was of0/W typa.Tha droplet siza of Picke/ng emulsion increxsed with tha incmcing of oiOwdar ratio.As tha amount of fina solid pa/iclas increxsed,tha droplet siza of Picke/ng emulsion wilt ado ba increxsed.Tha Picke/ng emulsions of oliva oil in watar prepared by using calcium carbonata,zinc oxida,titanium dioxida,MAa and mixed pctiAvs as stabilizers had good ultryviolet abso/tion perfo/nanco in tha UVA and UVB stages.Key—oSs:Picke/ng emulsion;u/raviomt;adso/tion;Wabilizar日光照射加速皮肤衰老[1]&氧化锌与二氧化钛能吸收和散射紫外线[2]&碳酸钙能降低细胞毒性W云母能提高防晒产品的透明和耐湿性[5]&然而,直接添加到防晒产品中易团聚,Picke/ng乳液以超细固体粒子为稳定剂[6],固体粒子组装在油水界面,可有效减少团聚。

碱金属气室参数测试教学实验平台搭建

碱金属气室参数测试教学实验平台搭建

实 验 技 术 与 管 理 第39卷 第1期 2022年1月Experimental Technology and Management Vol.39 No.1 Jan. 2022收稿日期: 2021-05-12基金项目: 北京航空航天大学研究生教育与发展研究专项基金;北京航空航天大学教学改革项目作者简介: 韩邦成(1974—),男,辽宁灯塔,博士,研究员,研究方向为精密仪器与测量方向的教学和研究,*********************.cn 。

通信作者: 陆吉玺(1986—),男,浙江宁波,博士,副研究员,研究方向为量子精密仪器与测量方向的教学和研究,***************.cn 。

引文格式: 韩邦成,陆吉玺,张少文,等. 碱金属气室参数测试教学实验平台搭建[J]. 实验技术与管理, 2022, 39(1): 56-58.Cite this article: HAN Bangcheng, LU Jixi, ZHANG Shaowen, et al. Construction of experimental platform for measuring parameters of alkali-metal vapor cell[J]. Experimental Technology and Management, 2022, 39(1): 56-58. (in Chinese)ISSN 1002-4956 CN11-2034/TDOI: 10.16791/ki.sjg.2022.01.011碱金属气室参数测试教学实验平台搭建韩邦成1,2,陆吉玺2,张少文1,翟跃阳2,胡朝晖1(1. 北京航空航天大学 仪器科学与光电工程学院,北京 100191; 2. 北京航空航天大学 前沿科学技术创新研究院,北京 100191)摘 要:碱金属气室是原子磁强计、原子陀螺仪、原子钟等量子传感器的核心敏感元件,其内部的碱金属原子蒸汽通过与激光、磁场等相互作用,实现对物理量的高精度测量。

帕米尔东缘晚中新世以来多阶段隆升-剥露过程:来自裂变径迹和(U-Th)/He低温热年代学的制约

帕米尔东缘晚中新世以来多阶段隆升-剥露过程:来自裂变径迹和(U-Th)/He低温热年代学的制约

2023/039(12):3685 3700ActaPetrologicaSinica 岩石学报doi:10.18654/1000 0569/2023.12.10孟云,尹继元,肖文交等.2023.帕米尔东缘晚中新世以来多阶段隆升 剥露过程:来自裂变径迹和(U Th)/He低温热年代学的制约.岩石学报,39(12):3685-3700,doi:10.18654/1000-0569/2023.12.10帕米尔东缘晚中新世以来多阶段隆升 剥露过程:来自裂变径迹和(U Th)/He低温热年代学的制约孟云1,2 尹继元2 肖文交3 THOMSONStuartN 4 王雅美1,2 陈文2 李大鹏1 吴明轩1,2MENGYun1,2,YINJiYuan2 ,XIAOWenJiao3,THOMSONStuartN 4,WANGYaMei1,2,CHENWen2,LIDaPeng1andWUMingXuan1,21 中国地质大学(北京)地球科学与资源学院,北京 1000832 中国地质科学院地质研究所,自然资源部同位素地质重点实验室,北京 1000373 中国科学院新疆生态与地理研究所,新疆矿产资源研究中心,乌鲁木齐 8300114 美国亚利桑那大学地球科学系,图森 857211 SchoolofEarthScienceandResources,ChinaUniversityofGeosciences(Beijing),Beijing100083,China2 MNRKeyLaboratoryofIsotopeGeology,InstituteofGeology,ChineseAcademyofGeologicalSciences,Beijing100037,China3 XinjiangResearchCenterforMineralResources,XinjiangInstituteofEcologyandGeography,ChineseAcademyofSciences,Urumqi830011,China4 DepartmentofEarthSciences,UniversityofArizona,Tucson85721,USA2023 05 01收稿,2023 09 04改回MengY,YinJY,XiaoWJ,ThomsonSN,WangYM,ChenW,LiDPandWuMX 2023 Multi stageupliftandexhumationprocessesintheeasternPamirsinceLateMiocene:Constrainedbyfissiontracksand(U Th)/Hethermochronology.ActaPetrologicaSinica,39(12):3685-3700,doi:10.18654/1000 0569/2023.12.10Abstract Thelargesteast westwardextensionalsysteminthePamirorogenicbeltisdevelopedintheeasternPamir,whichplaysacrucialroleinunderstandingregionaltectonicevolution However,thereisalackofeffectiveconstraintsonuplifttiminganddynamicmechanismsofthisarea Inthispaper,wepresentnewdataonapatitefissiontrack,zirconandapatite(U Th)/HeanalysesfromaseriessamplescollectedintheCenozoicintrusionrocksintheTashkurganareaoftheeasternPamir Combinedwithpreviousthermochronologicalresults,thesefindingsareusedtoexplorethetectono thermalevolutionanddynamicmechanismsoftheeasternPamirsinceLateCenozoic Theresultsoflowtemperaturethermochronologicalanalysisrevealthattheapatitefissiontrackagesarerangingfrom2 5Mato2 7Maandfrom8 7Mato11 5Ma,theapatite(U Th)/Heagesrangefrom2 3Mato4 5Ma,whilethezircon(U Th)/Heagesare3 2±0 3Ma Bycalculatingtheexhumationratesoftheaforementionedsamples,weproposedtheoccurrenceoftwoperiodsofrapidcoolingintheeasternPamir,i e ,theLateMiocene(12~8Ma)andthePliocene Quaternary(5~1Ma),andcalculatedtheirexhumationrateswhichiscorrespondentlyrangefrom0 19~0 48mm/yrand0 58~4 00mm/yr,respectively DuringtheLateMiocene,thetectonicdeformation,magmatismandmetamorphismeventsoccurrednearlysimultaneouslyintheeasternpartofthePamir,whichmaybelinkedtotheinitialcollisionbetweenthePamirandthesouthernTianshanorogenicbeltcausedbythenorthwardsubductionoftheIndianPlatebeneaththePamirTerraneduringtheLateMiocene Thiscollisioncontributedtofurthercrustalthickening,resultinginanunevendistributionofgravitywithinthePamirlithosphereandtriggeringgravitationalcollapse ThecoolingprocessfromthePliocenetotheQuaternarywaslikelyinfluencedbythecontinuousextensionaldeformationafterthegravitationalcollapse,whiletheerosionduringthisperiodcausedbyglaciers,riversandtheclimatevariationsfurtherenhancedtheexfoliation,leadingtoasignificantlyfasterexhumationratecomparedtotheLateMioceneoneKeywords EasternPamir;LateCenozoic;Lowtemperaturethermochronology;Upliftandexhumation;Gravitycollapse摘 要 帕米尔东缘发育帕米尔造山带内最大的东西向伸展系统,对理解区域构造演化具有重要意义。

期刊名影响因子及简称

期刊名影响因子及简称

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a r X i v :a s t r o -p h /0206500v 1 28 J u n 2002Mon.Not.R.Astron.Soc.000,??–??(2002)Printed 1February 2008(MN L A T E X style file v2.2)On the metallicity of the Milky Way thin disc andphotometric abundance scalesM.Haywood ⋆GEPI,Observatoire de Paris,F-92195Meudon Cedex,FranceAccepted.Received ;in original formABSTRACTThe mean metallicity of the Milky Way thin disc in the solar neighbourhood is still a matter of debate,and has recently been subject to upward revision (Haywood,2001).Our star sample was drawn from a set of solar neighbourhood dwarfs with photometric metallicities.In a recent study,Reid (2002)suggests that our metallicity calibration,based on Geneva photometry,is biased.We show here that the effect detected by Reid is not a consequence of our adopted metallicity scale,and we confirm that our findings are robust.On the contrary,the application to Str¨o mgren photometry of the Schuster &Nissen metallicity scale is problematic.Systematic discrepancies of about 0.1to 0.3dex affect the photometric metallicity determination of metal rich stars,on the colour interval 0.22<b −y <0.59,i.e including F and G stars.For F stars,it is shown that this is a consequence of a mismatch between the standard sequence m 1(b −y )of the Hyades used by Schuster &Nissen to calibrate their metallicity scale,and the system of Olsen (1993,1994ab).It means that although Schuster &Nissen calibration and Olsen photometry are intrinsically correct,they are mutually incompatible for metal rich,F-type stars.For G stars,the discrepancy is most probably the continuation of the same problem,albeit worsened by the lack of spectroscopic calibrating stars.A corrected calibration is proposed which renders the calibration of Schuster &Nissen applicable to the catalogues of Olsen.We also give a simpler calibration referenced to the Hyades sequence,valid over the same colour and metallicity ranges.Key words:stars:late-type –Galaxy:abundances –(Galaxy:)solar neighbourhood –Galaxy:evolution1INTRODUCTIONSolar neighbourhood stars serve as reference to which we compare the characteristics of the Galaxy outside the im-mediate solar vicinity,and their properties scale our mea-surements of the galactic structure and evolution.In view of their importance,it is somehow surprising that their general properties,such as the mean metallicity of the galactic disc stars,is still a matter of debate.In a recent paper (Haywood 2001),we constructed a metallicity distribution from stars within 20pc from the sun.This new metallicity distribution was shown to be centred on solar metallicity,or 0.1-0.2dex higher than the value found in most previous studies.We discussed that this discrepancy is the result of various bi-ases that enter the definition of these samples,the principal effect being caused by the selection of samples on the ba-sis of spectral type.Another sensitive effect comes from the adopted metallicity scale.The choice of a given metallicity⋆email :Misha.Haywood@obspm.frscale is determined from two criteria :the necessity to utilise stars with as low masses as possible,in order to avoid bi-ases favouring young stars,and available photometry.The most widely used photometry for studying the metallicity distribution is the Str¨o mgren photometry,with the metal-licity scale from Schuster &Nissen (1989)(hereafter SN).In our own study,and while the calibration of SN is given as valid down to b −y =0.59(B-V ≈1.0),we used Geneva photometry and the metallicity scale from Grenon (1978)for stars redder than b −y ≈0.42(B-V ≈0.67).The reason for this choice was that Geneva photometry is available for a larger set of solar neighbourhood K dwarfs.Hence,in the initial sample used by Haywood (2001),approximately half the stars had their metallicity determined from Str¨o mgren photometry,the other half from Geneva photometry.In a recent paper,Reid (2002)finds that the (B-V,[Fe/H])distribution of our sample shows a trend of about 0.2dex from B-V=0.5to B-V=1.0,suggesting that the cali-bration from Grenon (1978)is plagued by a systematic error.By constrast,his (B-V,[Fe/H])distribution,based entirely2M.Haywoodon the metallicity scale of SN,shows no such trend,if char-acterized by a simple linear regression.Most recently,and while terminating our paper,a study on the same subject was presented by Twarog,Twarog&Tanner(2002),exactly pointing to the problem we had discovered in Reid(2002) and that motivated the present work-a severe apparent deficiency in the metallicity scale of SN,causing underes-timates of the photometric metallicity of late G type and early K type metal rich stars.It appears however that the study by Twarog et al.has underestimated the discrepancy between photometric and spectroscopic abundances,in the sense that this problem also affects F-type stars,in contrast with their claim.More-over,while they suggest that the origin of this discrepancy is an unsuspected high dependence of the metallicity on the c1 index,we propose that it probably originates in a mismatch between the m1(b−y)standard sequence adopted in SN-which comes from Crawford(1975)-and the one that can be deduced from the photometric catalogues of Olsen(1993, 1994ab)(see also Olsen(1984),table VI),which constitute the vast majority of available measurements of Str¨o mgren photometry.The aim of the present paper is threefold:(1)In section2,wefirst present the discrepancy and quantify its amplitude on the whole colour range,that is between0.22<b−y<0.59.(2)In section3,we propose an explanation for the origin of this effect,and give a corrected calibration,for which we calculate new coefficients on the basis of an enlarged spec-troscopic ing the same spectroscopic calibrating stars,we also give an alternative calibration usingδm1and δc1.(3)Section4is a brief discussion of the impact of the photometric calibration on the metallicity distribution of the solar neighbourhood stars.In particular,it is demonstrated that the part of the sample in Haywood(2001)that is con-cerned by this effect is unchanged by the new calibration. That means that the results presented in Haywood(2001) are robust.2THE COLOUR-METALLICITYDISTRIBUTIONReid(2002)suggested that the Geneva calibration used in Haywood(2001)may be affected by a colour term.This is illustrated in his Fig.6b,also shown here(Fig.1a)for conve-nience.The linear regression on plot(a)shows that there is a trend of metallicity with colour.We note that although Reid (2002)presents the trend as being due to the Geneva metal-licity calibration,hisfit is however made on the entirety of our sample,which is a mixed of Geneva and Str¨o mgren metallicities(the Geneva metallicities being used for stars redder than B-V≈0.67).His remark stems from the fact that Str¨o mgren metallicities(using the calibration of SN)in his sample show no such trend(regression line on Fig.1b).It implies a priori that our calibration for red stars is question-able.Reid does not seem to envisage an intrinsic trend in our sample nor an effect caused by the metallicity scale of SN. He suggests that the trend is caused by the metallicity of the reddest stars in our sample.However,looking at the Fig.6a in Reid(2002)(our Fig.1b),wefind the strangely distorted feature that makes the upper part of the colour-metallicity distribution rather suspect(it seems to imply that there are no stars with super-solar metallicities at B-V=0.85-0.95).In order to elucidate the origin of these different trends,we de-cided to investigate in more detail the behavior of these two calibrations.There may be three reasons for the trend reflected in the linear regression of Fig.1a:(i)The Geneva calibration is biased,as suggested by Reid (2002),giving overestimated metallicities for red(B-V>0.8) objects.(ii)The Str¨o mgren calibration is biased,giving underes-timated metallicities in the blue(B-V<0.67).But then,we must understand why Reid’s(2002)sample shows no appar-ent trend in colour.(iii)The trend is real and is determined by the sample selection.But then it also must be explained why Reid’s sample shows no such effect.There are two different ways we can check the metallic-ity calibrations.We can use cluster data,and test each cal-ibration on clusters with well determined metallicities.The Hyades sequence is well appropriate for such work,and will be used below.A second way is to use spectroscopic data.A number of spectroscopic metallicities have been published in the recent years.And while they are still relatively sparse for K type stars,we shall pay particular attention to possi-ble colour effects.To complement these two,we can search for systematic effects with the position of stars in the HR diagram.For example,the scarcity of stars redder than B-V=0.8and more metal-poor than[Fe/H]=-0.4contributes to the trend that is seen on Fig.1a(we note,however,that this feature is also present in the Str¨o mgren sample,Fig. 1b).We may check if a corresponding feature is also seen in the HR diagram in our sample.2.1The Hyades cluster testFig.1ab shows the(B-V,[Fe/H]photo)diagrams for the sam-ples of Haywood(2001)and Reid(2002).The horizontal line shows the median metallicity of the Hyades cluster as determined from a sample of spectroscopic metallicities in Perryman et al.(1998)at[Fe/H]=+0.14.The star symbols show Hyades members with metallicity as determined from the calibration of Grenon(Fig.1a)and the calibration of SN(Fig.1b).Since the calibration by Grenon(1978)was designed by reference to the Hyades sequence,it is not sur-prising(but reassuring)that the plot shows consistency with the spectroscopic determination.Different is the result of the calibration of SN applied to the Hyades cluster members,as seen on Fig.1b.Thefig-ure shows systematic deviations from the Hyades metallic-ity,which follow those offield stars.The Hyades metallicity is underestimated by about0.15dex at B-V=0.5-0.60,and the effect is even stronger at B-V>0.8with a0.3-0.4dex offset.This last feature is the one discussed by Twarog et al.(2002).In the blue part of the interval,it is not clear how much solar metallicities(i.e[Fe/H]≈0)would be affected by the bias,at least solely from the Hyades cluster test.The bias may affect only metal-rich stars.At redder colours,it is however probable that even solar metallicity stars have their metallicities underestimated by at least0.15dex.This can be checked on spectroscopic data(section2.2).WhileOn the metallicity of the Milky Way thin disc and photometric abundance scales3Figure 1.Metallicity distribution as a function of B-V for our sample (a),and Reid (2002)sample (b).Our sample is a mixture of stars with Str¨o mgren metallicity (squares)and Geneva metallicity (circles).The horizontal line represents the metallicity of the Hyades cluster from Perryman et al.(1998),at [Fe/H]=+0.14.The star symbols are Hyades members from de Bruijne et al.(2001),with metallicity determined from the calibration of Grenon (1978).The region delimited on the right lower part of the plot is the region where Favata Micela &Sciortino (1997)found no objects in the their sample.In the sample of Reid (2002)(plot b),all stars have their metallicity determined from Str¨o mgren photometry,through Schuster &Nissen (1989)calibration.Star symbols also represent Hyades members for which metallicity has been calculated through the calibration of Schuster &Nissen (1989).Our Str¨o mgren metallicities in plot (a)were determined with the calibrations of SN but corrected as described in Haywood (2001),and are not strictly equal to those of Reid (2002),although patterns common to the two (B −V ,[F e/H ])distributions can be seen.we postpone our explanation to section 3,it is worth noting here that the calibration itself is not responsible for the effect that is seen on Fig.1b at b −y <0.375.It is its application to available Str¨o mgren photometry which is in question.What is relevant at the moment is that the (B-V,[Fe/H]SN )dis-tribution of Fig.1b is strongly biased and the apparent lack of correlation given by the linear regression is meaningless.Reid (2002)notes a general offset of about 0.1dex in the Str¨o mgren metallicity scale,following the similar result of Alonso,Arribas &Martinez-Roger (1996)and Haywood (2001).Since all the comparisons in Reid (2002)are rela-tive and made in the system of the SN calibrations,the zero point is a priori not crucial.However,the differential effect in colour is sufficiently strong that Reid (2002)acknowledges that his metallicity distribution (after rescaling by 0.1dex)still has a less extended tail towards metal rich stars com-pared to Favata et al.(1997)and Haywood (2001).Although Reid (2002)does not question further on the possible ori-gin of this discrepancy,the direct reason for this effect is particularly conspicious on the (B-V,[Fe/H]SN )distribution:SN metallicities are artificially lowered below [Fe/H]=-0.1at 0.8<B-V <0.95and below [Fe/H]=0.0at B-V <0.65.2.2Spectroscopic check 2.2.1Schuster &Nissen (1989)A second check can be done using spectroscopic metallicities from the literature.We have used mainly data from Edvards-son et al.(1993),Favata et al (1997),Fulbright (2000),Feltz-ing &Gustafsson (1998),plus some additional objects from4M.HaywoodFigure 2.Difference between photometric (Str¨o mgren)and spec-troscopic metallicities,for 3metallicityintervals.Figure 3.Difference between photometric (Grenon (1978))and spectroscopic metallicities,for 2metallicity intervals.the catalogue of metallicities by Cayrel de Strobel,Soubi-ran &Ralite (2001)for red (B-V >0.65)objects.Fig.2shows the difference between photometric (SN)and spectroscopic metallicities,for 4metallicity intervals.Around solar metal-licities,the colour variation is similar to the one detected on the Hyades.It confirms that the calibration of SN underes-timates metallicities above [Fe/H]>-0.25by 0.1-0.2dex for stars bluer than B-V <0.65,and by 0.1-0.3dex in the colour interval 0.75<B-V <0.9.At -0.25>[Fe/H]>-1.0,the combi-nation of the 2distinct calibrations is apparent,with the calibration for b −y >0.375overestimating the metallicity,and the calibration at b −y <0.375underestimating metallic-ities.Finally,the calibration seems to overestimate slightly the metallicity at [Fe/H]<-1.0.Because the calibration of SN has been applied mostly to F stars,the discrepancy of about 0.1dex that is vis-ible at B-V <0.65and for [Fe/H]>-1.0has already been noted by different authors,see in particular Alonso et al.(1996).In our own sample,it has been corrected as [Fe/H]=[Fe/H]SN /0.86+0.05(Haywood ,2001).2.2.2Grenon (1978)In Haywood (2001),we checked the calibration of Grenon(1978)with spectroscopic determinations.Fig.3shows the result of this calibration compared to the same data as for the calibration of SN,within colour limits that define the calibration,that is 0.40<B 2−V 1<0.65.The data is very sparse for red metal poor dwarfs,and not much can be said about the calibration below [Fe/H]≈-0.25dex.At [Fe/H]>-0.2,the spectroscopic data shows no offset.It it clear how-ever that a secure calibration would require a larger data set.The consistency of the Geneva metallicity scale can also be checked on the HR diagram.The Hyades cluster was al-ready used in Haywood (2001).We further detail our com-parison with the cleaner Hyades sequence of de Bruijne et al (2001).Fig.4shows our sample with the Hyades sequence.We note 2features :(i)There are no stars above the Hyades sequence around B −V =0.9in metallicity.A corresponding feature is visible in the HR diagram,Fig.4b.Only three stars stand clearly above the Hyades sequence between 0.82<B −V <0.93,consistently in both diagrams.(ii)There are no field stars in the HR diagram at B-V >0.87and M v >7.2.Such dwarfs would be expected to have [Fe/H]<-0.5,and we note a corresponding lack of stars in Fig.1a (one star only).It is appropriate to remind that this feature is visible on many studies of the solar neigh-bourhood metallicity distribution (even with pre-Hipparcos parallaxes).The first study to mention this effect was Fa-vata et al.(1997)(see also Flynn &Morell (1997),their Fig.5).The samples considered in solar neighbourhood studies are too small to investigate whether this is only a statisti-cal effect or a real absence of midly-deficient stars at that colour.In the HR diagram at B −V <0.7,field stars above the Hyades sequence probably have evolved offthe ZAMS (the turn-offB −V colour for solar metallicity stars at 12Gyrs is circa 0.70).At the bottom of the HR diagram (B-V >0.95),On the metallicity of the Milky Way thin disc and photometric abundance scales5Figure 4.The (B-V,metallicity)distribution of the stars in our sample with Geneva metallicities,and the corresponding HR di-agram.Star symbols are the Hyades,selected by deBruijne et al.(2001).There is a good overall consistency between the metallic-ity of the stars and their position in the HR diagram.See text for details.4stars with [Fe/H]>0.14lie clearly below the Hyades se-quence,which may be the signature of a bias overestimating metallicities in the Grenon calibration at B-V >0.95.Among these 4stars,only HIP 116745has a measured spectroscopic metallicity at [Fe/H]=-0.22in the catalogue of metallicities of Cayrel de Strobel et al.(2001).We conclude that there is no significant deviation be-tween the HR diagram and the colour-metallicity distribu-tion of Fig.1a.3THE STR ¨OMGREN METALLICITY SCALEThe calibration designed by Schuster &Nissen (1989)hasproved to be most useful for a variety of studies using Str¨o mgren photometry,and this has become still more ev-ident with the advent of Hipparcos data.Results of Sec.2shows however that its application to available data is problematic for metal rich stars.We now try to explain the probable cause of that problem.3.1A diagnosticContrary to the claim of Twarog et al.(2002),the Str¨o mgren metallicities at 0.22<b −y <0.40-0.41(or 0.35<B-V <0.65)are also affected,with the Hyades having theirabundanceFigure 5.The Hyades sequence as given by the Str¨o mgren pho-tometry from the GCPD (diamond).The b −y and m 1indices that are used are (in most cases)the mean of several measure-ments as given by the GCPD.In case the only source of pho-tometry is Olsen (1993)and/or Olsen (1994ab),the symbol is a black filled diamond.If the photometry is the mean of Olsen and other sources,the symbol is a grey-filled diamond.If the pho-tometry contains no measurement from either Olsen (1993)or Olsen (1994ab),the symbol is an empty diamond.The contin-uous line is the standard sequence of Crawford (1975),which is the main data used by SN to calibrate their metallicity scale at 0.22<b −y <0.375for metallicities around 0.13dex.The offset between the Crawford sequence and the Hyades from the GCPD is of the order of 0.01mag.For redder stars,it is suggested that,in practice,the calibration by SN follows an extrapolated sequence ressembling the one plotted as a dashed line.It is interesting to note that the 2outliers at b −y =0.345and b −y =0.259,are stars which have not been observed by Olsen.The open circles are the only 2stars we could find with both Str¨o mgren photometry at the time SN established their calibration,and metallicity above solar.One of them is the Hyades star vb79.underestimated by 0.1-0.2dex.Such strong effect is some-what puzzling since the F-star calibration of SN is said to be constrained using the standard (Hyades)sequence of Craw-ford (1975)at a metallicity of 0.13dex (and it is given double weight in the calibration of SN).This failure is interesting because it gives us some clue on the possible general origin of the problem.Since the photometric Hyades metallicity adopted by SN should be consistent with the spectroscopic value at [Fe/H]≈0.13,the only possible cause for the defect that is seen on Fig.1must come from the Str¨o mgren indices that are used to represent the Hyades sequence.(i)F stars 0.22<b −y <0.375Fig.5shows the m 1(b −y )sequence for the Hyades,on the relevant colour range,from two different sources.The con-tinuous line is the standard sequence from Crawford (1975)used by SN to calibrate their metallicities.Diamond sym-bols are Hyades members with Str¨o mgren photometry from the GCPD (The General Catalogue of Photometric Data,Mermilliod,Mermilliod,&Hauck,1997).The b −y and m 1indices of Fig.5are the mean of measurements from different sources as given by the GCPD.Most of these points include6M.Haywoodone or several measurements by Olsen(1993)and/or Olsen (1994ab).These various origins have been differentiated onFig.5as follows:Black diamonds are those stars for which indices contain only measurement from Olsen(1993)and/or Olsen(1994ab).Grey diamonds are a mixed of Olsen(1993 and/or1994ab)and measurements from other sources.Fi-nally,empty diamonds represent those stars which were not observed by Olsen(1993and1994ab).Since the Hyades se-quence is mostly dominated by the measurements of Olsen, we call it the‘Olsen sequence’herebelow.In the b−y range of interest(b−y<0.375),the two m1(b−y)scales(Craw-ford(1975)and the Olsen sequence)clearly show an offset of about∆m1≈0.01mag.For F-type stars,m1is the index sensitive to the metallicity,with∆m1=0.01mag correspond-ing to∆[Fe/H]≈0.1dex on the metallicity scale.Since the huge database established by Olsen is the main source for Str¨o mgren photometry,and since the calibration of SN is based on the sequence of Crawford (1975),it is expected that metallicity estimates that com-bine both will be incorrect by about0.1dex,even though the calibration of SN is correct and Olsen indices are precise. (ii)G stars0.375<b−y<0.59The continuity in the deviations of metallicity estimates on Fig.1b accross the limit that separate the2calibrations suggest a similar origin for the defects at b−y<0.375,and b−y>0.375.It is seen on Fig.1b that the photometric metallicity offset of0.1dex is continuous accross the two intervals,i.e it is left unaffected by the change of calibration, at least up to b−y=0.40.This comes in support to the fact that the discrepancy originates in the indices rather than in the calibration themselves.At0.375<b−y<0.59,and for the metal rich part of their calibration,SN have used the2reddest points in the sequence of Crawford(1975)(at b−y=0.394and0.412),and ‘to give more weight to the Hyades,four individual stars with an average[Fe/H]=+0.09from Cayrel de Strobel et al.(1985)and from Cayrel et al.(1985)were included with single weight’.We couldfind only one star from the Hyades satisfying this description and that had Str¨o mgren indices measurement available in1989.This star(vb79),sufficiently red to have been useful for calibrating the reddest part of the metallicity scale,has b−y=0.497and m1=0.341(Carney, 1983).Another star from the catalogue of Cayrel de Strobel et al.(1985),not belonging to the Hyades cluster,but with [Fe/H]spectro=0.25is also shown on Fig.5.On Fig.5,we have extrapolated the standard sequence of Crawford(1975)at b−y>0.41with a polynomial.The calibration given by SN is not explicitly referenced to the Hyades sequence,but the standard sequence is implicitly integrated in their functional form.Although we can’t quantify the difference between the Olsen sequence and the one de facto adopted by SN,we suggest that the lack of data and the functional form of the calibration of SN has probably led to a sequence resembling the one proposed as an extrapolation on Fig.5.Several features support this suggestion:First,it is significant that the Crawford and extrapo-lated sequence on Fig.5crosses the Olsen sequence between 0.40<b−y<0.45(0.65<B−V<0.74).It implies that on this interval,both m1indices from Olsen or theextrap-Figure6.The polynomial Hyades sequence(b−y,m1)(con-tinuous line,plot c),as reconstructed from the(b−y,[F e/H]), (b−y,c1)relations(plot a and b)and equation(1).The broken line is the extrapolated sequence of Fig.5.olated sequence overlap,and will give similar metallicities. As a matter of fact,this is precisely the interval where the calibration of SN(using Olsen Str¨o mgren indices),gives a metallicity for the Hyades nearest to the spectroscopic value. Second,between0.45<b−y<0.57,the offset∆m1 between the polynomial sequence and the Olsen sequence reaches0.03-0.05,which precisely is the offset that is neces-sary in order to level up the photometric Hyades metallicities to0.14dex,if Olsen m1indices are used in the calibration of SN.Third,the polynomial sequence rises more steeply than the observed sequence,whichflattens to reach a maximum in m1at b−y≈0.75.It is expected that the extrapolated polynomial sequence rejoins the observed(Olsen)sequence at some colour in the interval0.5<b−y<0.7.That means that at this colour,the two sequences should again give the same metallicity.This is precisely what is observed on Fig. 1at b−y=0.57(i.e the calibration of SN and Olsen indices give[Fe/H]≈+0.14,which is the metallicity expected from the standard relation).Altogether,these clues convey the impression that it is the offset between the two m1(b−y)sequences that is responsible for the strong colour dependence and the sys-tematic discrepancy seen on Fig.1.It is meaningful that the Crawford and extrapolated polynomial sequence of Fig. 5lies respectively above and below than the Olsen sequence in just the correct intervals to explain the behavior of the photometric metallicity seen on Fig.1b.On the metallicity of the Milky Way thin disc and photometric abundance scales7Figure 7.c 1dependence of photometric metallicities.Star symbols are metallicities from Geneva photometry,dots are metallicities of SN,for the same objects.Objects in the upper box have a mean m 1=0.445,and m 1=0.408in the lower box.See Sec.3.3for comments.3.2Consistency argumentFollowing this last remark,it is possible to use the cali-bration given by SN to recover the Hyades sequence and check the consistency of our argument.Assuming relations between (b −y ,c 1)and (b −y ,[F e/H ]SN ),m 1can be cal-culated as the root of the equation :(−53.8+145.5∗b −y −137.2∗c 1)∗m 21+(22.45+85.1∗c 1−62.04∗b −y )∗m 1−2.0965−13∗c 21−[F e/H ]SN =0(1)The (b −y ,[Fe/H]SN ),(b −y ,c 1)relations for the Hyades have been assumed as polynomial fits to the Hyades data,as shown on Fig.6ab.Because we don’t know the exact (b −y,c 1)sequence endorsed by SN at b −y >0.4,we have assumed a set of (b −y,c 1)relations,as given on Fig.6b.They are used to calculated the coefficients of the poly-nomial (1),which is solved for m 1,at different b −y .The result is shown on Fig.6c and is consistent with our discus-sion above.3.3Twarog et al.(2002)In their paper,Twarog et al.(2002)proposed another cause for the discrepancy.They state that the calibration of SN underestimates the c 1dependence of metallicity for stars redder than b-y=0.47.Their argument relies on their Fig.5,which shows the correlation between metallicity (both spec-troscopic and photometric)and c 1for stars with b-y >0.47.If the argument is correct,we would expect however that c 1correlates differently for spectroscopic and photometric (SN)metallicities.Their Fig.5seems to illustrate,at vari-ance with their claim,that the correlation is approximatelysimilar for both spectroscopic and photometric abundances,which means that the photometric metallicities of SN are correctly tied to the c 1index.The interpretation that Twarog et al.give of their Fig.5is qualitative and relies on a dozen of stars.Among these,two objects that are outliers can give the favourable impres-sion that the slopes of the photometric and spectroscopic [Fe/H]-c 1data sets are different.Even if this was the case,it would remain to be demonstrated that this is due solely to the c 1index.In order to extend the comparison of Twarog et al.(2002)to a greater number of stars,we use our Geneva pho-tometric metallicities instead of the spectroscopic metallic-ity scale.We select in our sample all stars having 0.85<B −V <0.95(equivalent to 0.50<b −y <0.55),giving 37objects (32are within the limits of Fig.7).We plot on Fig.7the photometric metallicities [Fe/H]SN and [Fe/H]GEN as a function of c 1,a figure similar to Fig.5in Twarog et al.(2002),but now with the Geneva photometric scale be-ing the reference.Of course,this comparison relies on the correctness of Geneva metallicities.Following the arguments developed in Sec.2,we assume that they are indeed valid.In-terestingly,it seems that our Fig.7reveals the patterns that were only suggested in the Fig.5of Twarog et al.(2002).That is,Geneva metallicities show that there is a second group of stars (upper box)standing 0.15-0.20dex above the sequence at c 1=0.25-0.30.Only a small part of that group is visible in Twarog et al.(2002),at c 1=0.28-0.30.What is interesting is that this group is not differenti-ated in the metallicities of SN.That means the calibration of SN lacks a dependence on one parameter,which clearly can-not be c 1.The mean and dispersion of m 1for the eight stars in the upper box are 0.445and 0.036.The lower box con-tains 9stars with a mean m 1=0.408and dispersion 0.030.。

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