挥发气回收
甲醇罐区及装车无组织排放气回收项目的介绍

甲醇罐区及装车无组织排放气回收项目的介绍甲醇罐区及装车无组织排放气回收项目是针对甲醇储罐区和甲醇装车过程中的无组织排放气体进行回收利用的环境保护项目。
该项目旨在减少甲醇罐区和装车过程中产生的挥发性有机物(VOCs)和二氧化碳(CO2)等有害气体的排放,实现气体的资源化利用,降低对环境的影响。
甲醇是一种广泛应用的化工原料,其储罐区和装车操作过程中会产生大量的挥发性有机物,包括甲醇、甲酸、甲醛等有害气体。
这些气体具有较高的毒性和易燃性,对环境和人身安全造成威胁。
甲醇燃烧产生的二氧化碳是导致温室气体排放增加的主要因素之一。
对甲醇罐区和装车过程中的无组织排放气体进行回收利用具有重要的意义。
1. 建立高效的气体收集系统:在甲醇罐区和装车站点安装集中式的气体收集设备,包括气体抽取罩、管道系统和气体收集罐等。
通过这些设备,能够有效地捕获并收集罐区和装车过程中产生的有害气体。
2. 采用适当的气体处理技术:对收集到的有害气体进行处理,采用适当的气体处理技术,如吸附、脱附、吸收、膜分离等,将挥发性有机物和二氧化碳等有害气体从气流中剥离。
对剥离出的有害气体进行净化处理,降低其污染物含量。
3. 实施气回收和再利用:对经过处理的有害气体进行气回收和再利用。
对甲醇和甲酸等有机物的回收利用可以通过进一步处理、蒸馏等方法实现。
而对二氧化碳的回收则可以利用压缩和液化等技术,将其用于工业生产、农业温室气体增施肥和碳酸饮料等领域。
通过这些措施,甲醇罐区及装车无组织排放气回收项目能够有效地减少甲醇罐区和装车过程中产生的有害气体的排放量,将资源化利用的理念应用于甲醇生产和运输过程中。
该项目不仅有助于改善环境质量,减少对大气的污染,还能够实现资源的节约和循环利用,提升企业的环保形象和经济效益。
为确保项目的顺利实施,需要从以下几个方面进行工作:1. 技术选型和设备采购:针对不同的甲醇罐区和装车站点,选择合适的气体收集、处理和回收设备。
与具备相关经验和资质的企业合作,确保设备的采购和安装工作。
酒精挥发气体处理

酒精挥发气体处理
酒精挥发气体处理是指对含有酒精的气体进行处理,以降低或消除有害的酒精挥发气体。
常见的酒精挥发气体处理方法包括以下几种:
1.活性炭吸附:将含有酒精的气体经过活性炭床,利用活性炭
的吸附作用将酒精分子吸附下来,从而实现酒精挥发气体的处理和净化。
2.氧化处理:利用催化剂或高温氧化的方法将酒精挥发气体进
行氧化反应,将其转化为二氧化碳和水等无害物质,从而达到处理和净化的目的。
3.冷凝技术:通过降低酒精挥发气体的温度,使其冷凝成液体,然后进一步处理或进行回收利用。
4.脱水处理:对酒精挥发气体进行脱水处理,降低酒精的含量,从而减少其挥发性。
此外,根据实际需要和要求,还可以采用其他一些方法进行酒精挥发气体的处理,比如吸收法、生物降解法等。
需要注意的是,在进行酒精挥发气体处理时,应遵循相关的环保法规和安全操作规程,确保处理过程安全可靠,并合理利用可再生资源。
石化挥发性有机物(VOC)回收和催化燃烧处理技术应用

石化挥发性有机物(VOC)回收和催化燃烧处理技术应用摘要:介绍了三种典型石油化工有机废气的voc回收以及采用催化燃烧技术进行处理的应用。
应用"冷凝一催化燃烧”技术处理橡胶废气。
冷凝水和环己烷的回收量分别为1050 kgh和1.0 kgh,催化燃烧反应器空速为2000h"',入口温度210~ 300"C;应用“浓缩催化燃烧”技术处理PTA废气,空速为2000h"',入口温度300C;应用“吸收及总烃浓度均化催化燃烧”技术处理聚酯废气,空速为1500h',入口温度250'C.经过处理,上述废气均达标排放.关键词:有机废气回收催化燃烧冷凝浓缩浓度均化在石油化工行业的生产过程中,会产生以挥发性有机物为主要组分的废气。
这些有机物如果百接排入大气,将危害人体健康,污染周围环境。
因此,我国《大气污染物综合排放标准(CB16297-1996)》对有机物的排放作出了严格限制,其中非甲烷总烃≤120 mg/m',苯≤12 mg/m',二甲苯≤70 mgm',乙醛≤125 mg/m3.有机废气的治理方法包括吸收、吸附、冷凝、直接燃烧、热力燃烧和催化燃烧等。
其中,催化燃烧是处理有机废气的种行之有效的方法,它在较低的温度F(250~ -400C),利用催化剂使有机物尤焰燃烧,燃烧产物是CO2和H2O.为了保护催化剂,在进行催化燃烧处理时,常常需要根据废气性质的不同,采取不同的预处理方式。
中国石化抚顺石油化工研究院(FRIPP)从上世纪九十年代开始从事有机废气的催化燃烧治理研究,曾先后对多种有机发气进行了催化燃烧实验室、中试及工业化应用研究。
通过对橡胶厂热塑性丁苯橡胶(SBS)废气、化工厂精对苯二甲酸(PTA)废气、化纤厂聚酯(PET)废气等的工业化及中试治理研究,结果表明,采用以催化燃烧为核心的治理技术,可使净化气达到国家排放标准;而且,该技术还具有能耗低、操作方便、处理效果好等优点:对橡胶废气的冷凝预处理还会回收冷凝水和环已烷,从而带来一定的经济效益。
车间集中回收废气的方法

车间集中回收废气的方法
车间集中回收废气的方法有以下几种:
1. 烟气回收:通过安装烟气回收设备,将车间产生的燃烧废气中的有用成分进行回收利用,如热能回收、有机物回收等。
2. 尾气回收:对车间产生的尾气进行集中回收处理,常见的方法包括尾气净化技术、尾气蓄能技术等。
3. VOCs(挥发性有机物)回收:车间中的挥发性有机物是造成空气污染的主要因素之一,通过安装VOCs回收系统,对车间中的挥发性有机物进行回收和再利用,减少排放。
4. 烟尘回收:通过安装过滤装置,对车间产生的烟尘进行集中回收处理,常见的装置有除尘设备、静电除尘器等。
5. 焚烧废气回收:将车间产生的废气经过处理后进行焚烧,产生的热能可以用于车间的供热、供电等用途。
6. 冷凝回收:对车间产生的废气进行冷凝处理,将其中的有用成分进行回收,如冷凝水中的溶解物、挥发性物质等。
需要根据车间的具体情况选择合适的废气回收方法,同时还要符合当地的环保法规要求。
油气回收解决方案(最新)

近年来,废气治理引起各界关注,空气质量成为公众关注焦点。
不同行业的废气治理有不同的特点,下面是油气回收解决方案,欢迎阅读了解。
1. 概述1.1 项目背景石油成品油中的轻质油,如汽油和溶剂油等具有容易蒸发的性质。
油气挥发容易造成油品数量损失。
汽油等轻质油从炼油厂到中转油库到加油站,直至加给汽车油箱的储、运、销过程中,会有4-5次装卸,每次装卸都有与汽油液体体积相等的饱和油蒸气排放。
中国2012年石油消耗量4.9亿吨,我国依赖进口石油54.8%,要排放油气约8亿m,每m油气中含碳氢化合物浓度1100-1380g/m,因此会造成油品损失数量高达90-108万吨。
按照每吨0.9万元计算,损失高达81—95亿元。
油气污染对人类生态环境、安全环境、健康环境隐患无穷。
油气的挥发带来火灾隐患。
国内石化企业统计资料显示,在222例火灾爆炸事故中,由散发油气引起的就有101起,占到总数的45.50%。
油气回收是在成品油储、运、销环节,对汽油等轻质油蒸发的油气采取的回收利用和治理污染措施。
1.2 有机废气排放特性油气的挥发主要是在储存及装卸过程中挥发的,具有小风量(10-102 m3/h)、高浓度(102-103 m3/h)的特点。
2.治理方案选择2.1 常见处理方法比较目前实际中采用的油气回收的技术主要包括吸收法、吸附法、冷凝法和膜分离法(见图1)。
1)吸收法:根据混合油气中各组分在吸收剂中的溶解度的大小,来进行油气和空气的分离。
该法回收率低,排放很难达标,现在已经很少单独使用。
2)吸附法:利用活性炭或者其它孔隙率较大的物质作为吸附剂,由此达到使油气与空气分离的目的。
由于填装技术、解吸技术以及活性炭本身质量等方面存在的诸多问题,活性炭使用寿命短。
同时,吸附法油气回收装置的转动设备比较多,炭床需要进行频繁解吸,因此维修量大。
当环境湿度过大时,其吸附能力会有一定程度的降低。
3)冷凝法:利用冷凝剂通过热交换器冷凝油气,大部分油蒸气会被冷凝成液态,而空气则可以通过通风口被排出,从而达到分离的目的。
储油罐挥发性有机物的回收与利用

环保·安全/Environment Protection&Security储油罐广泛应用于石油石化站场中,储油罐的挥发气通过呼吸阀直接排放到大气中,这部分挥发出的有机物不仅造成了能源的浪费和环境污染,也存在较大的安全隐患。
随着《大气污染防治行动计划》的颁布,国家对挥发性有机物(VOCs)的排放有了更加明确的限制,各省环保部门也制定了更为严格的治理要求[1]。
因此,充分利用站内设备设施,回收储油罐挥发性有机物,提高原油商品率,降低环境污染势在必行。
由于现用大部分储油罐均为常压罐,溶解在原油中的伴生气在储存和运输过程中会挥发出来,又称挥发性有机物(VOCs),这类重要的空气污染物,通常沸点在50~260℃、室温下饱和蒸气压超过133.3Pa的有机化合物,包括烃类、卤代烃、芳香烃、多环芳香烃等。
某站库通过对部分储罐进行呼吸损耗测试,其中56座储罐总呼吸损耗量为23513m3/d,充分回收这些挥发性有机物,合理利用能源,消除环境污染,已成为安全环保生产的首要任务。
1储油罐挥发性有机物回收技术1.1储油罐油气损耗的类型储油罐的挥发气按照挥发原理分为油罐自然通风损耗、“小呼吸”损耗、“大呼吸”损耗三种类型,损耗数量最大的是“大、小呼吸”损耗,约占损耗的98.3%[2-4]。
一是自然损耗是由于罐顶孔眼高度不同而造成的空气从上部孔眼进入罐内,罐内油品蒸汽随混合气体从下部孔眼挤出或从罐顶另一孔眼流出而造成的损耗。
二是小呼吸损耗是指在油罐静止储存时,由于罐内气体空间温度的昼夜变化和储罐内外壁的温差引起的损耗。
三是大呼吸损耗是储罐在收发油和装卸油过程中因罐内液位上升或下降造成的呼吸损耗,这部分呼吸损耗占总体损耗的95%左右。
影响储油罐油气损耗的主要参数包括呼吸气体流量、温度、压力、组分以及环境温度和大气压力等[5]。
其中自然通风损耗和小呼吸损耗与环境和储油罐的设计有关,通常情况下损耗量较小,不好控制;而大呼吸损耗因为占比较大,是治理挥发气的主要对象。
油气回收技术

油气回收技术
油气回收技术是一种环保技术,用于收集、运输、处理和利用在石油、天然气等化石能源的开采、运输、储存和使用过程中产生的挥发性有机气体(VOCs)。
这些气体包含大量的有害物质,如烃类、硫化物等,对环境和人体健康具有潜在危害。
油气回收技术的主要目的是减少VOCs的排放,保护环境和人类健康。
该技术可以有效地减少大气中的VOCs含量,降低光化学烟雾和其他大气污染物的形成,从而改善空气质量。
根据处理对象的不同,油气回收技术可以分为以下几类:
石油石化行业油气回收技术
该技术主要用于石油和天然气的开采、运输、储存和加工过程中产生的VOCs的回收和处理。
常用的技术包括吸附法、冷凝法、膜分离法等。
加油站油气回收技术
该技术主要用于加油站加油过程中产生的VOCs的回收和处理。
常用的技术包括吸附法、冷凝法、吸附-冷凝组合法等。
汽车尾气排放油气回收技术
该技术主要用于汽车尾气排放的VOCs的回收和处理。
常用的技术包括吸附法、催化燃烧法等。
有机化工行业油气回收技术
该技术主要用于有机化学工业中产生的VOCs的回收和处理。
常用的技术包括吸附法、冷凝法、吸收法、膜分离法等。
其他油气回收技术
除了上述几种油气回收技术外,还有生物法、光催化法、等离子体法等新型油气回收技术。
油气回收技术是一项重要的环保技术,可以有效地减少VOCs的排放,保护环境和人类健康。
未来,随着环保要求的不断提高和技术的不断进步,油气回收技术将会更加成熟和普及。
三次油气回收设备工作原理

1.三次油气回收设备工作原理是什么?
答:三次油气回收设备工作原理是通过控制储油罐压力回收处理加油站储油罐内的挥发油气和回收油气,将绝大部分油气以液态油和过饱和油气的形式返回至储油罐中,油气中的空气组分净化后环保的排放的油气回收处理装置。
当三次油气回收设备检测到油罐内压力达到预设的启动压力(如+150Pa)时,设备开始工作;压缩机从油罐中抽取油气并进行压缩,升高温度的油气通过冷凝装置进行常温冷却,部分油气被直接冷凝为液态油;剩下的油气/空气混合物继续进入具有选择渗透功能的膜组件进行分离,混和气被分为富含油气的渗透相—超饱和油气和净化了的空气,超饱和油气通过真空泵抽回油罐,净化空气则可以直接排放到大气中。
随着油气回收设备的运行,油罐上方的压力会逐渐下降,当油罐顶部的压力下降到低于停止压力(如-150Pa)或设备停止时间时,设备会自动停止直至油罐顶部压力再次升高达到设定启动压力时,设备再次启动。
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R-300R-1000LEAN OIL ABSORPTIONA gas with hydrocarbon vapors enters the bottom of an ABSORBER column and flows upward contacting the counter-flowing LEAN OIL system. The LEAN OIL preferentially absorbs the vapors from the gas, becoming ENRICHED OIL.RICH OIL is sent to a STRIPPER where the absorbed vapors are removed by heating the RICH OIL, vaporizing the absorbed vapors. The rich oil is, thus, regenerated as lean oil and recycled to the ABSORBER to complete the process loop. The vaporized vapors are liquefied and transferred to storage.PETROGAS Absorption Systems are designed to operate continuously, or intermittently, in a fully automatic mode. PETROGAS offers a basic system, with options to allow each unit to be customized to meet your unique specifications at a fraction of the cost of a custom designed and fabricated system.PETROGAS systems have proven superior efficiency in the recovery of hydrocarbons and chemicals from vapor streams. PETROGAS Absorption Systems are supplied as complete factory package units, including instrumentation, piping and electrical, on a structural skid.NATURAL GAS STREAMSGas absorption is an operation in which a soluble component of a gas is dissolved in a liquid.The PETROGAS absorbent liquid (Lean Oil) selectively absorbs propanes+, or other selected components, from a natural gas stream in accordance with the client specifications for meeting pipeline specifications (by control of the BTU or reduction of the pentanes+) or the economic benefit of the spread between selling liquids as a gas or as a liquid.The PETROGAS Model A System is available to process natural gas stream flow rates of 5 mcfd to 5,000 mcfd.PHOTOSAbsorption SystemModel A SystemTURBOEXPANDERCryogenic chilling in the PETROGAS Model TE System utilizes a TURBOEXPANDER which replaces the Joule-Thompson expansion valve in a conventional refrigeration system. The expansion valve is adiabatic, while a turbine, taking work out of the expansion makes it isentropic.Isentropic expansion allows for a lower temperature of the expanded refrigerant at the same pressure reduction. The more efficient turboexpansion cycle allows the use of aliphatic hydrocarbons, such as ethane, as a refrigerant.In the Model TE series, a gas turbine with a shaft connecting it to a single stage gas compressor is known as a TURBOEXPANDER, in which a high pressure refrigerant gas flows into the gas turbine, expanding across the turbine blades, rotating a shaft and cooling through the isentropic gas expansion to a cryogenic temperature of less than-100°F. The existing low pressure, cryogenic temperature gas is used to cool theair/vapor mixture to a temperature of -100°F, condensing the contained vapors.The transfer of heat from the air/vapor mixture, raises the temperature of the refrigerant gas, which then enters the compressor side of the TURBOEXPANDER, partially recompressing the refrigerant gas to the inlet design pressure of the gas turbine, completing the cycle. The TURBOEXPANDER is able to cool a gas to cryogenic temperatures using 30%-60% less compressor horsepower than is required for conventional cascade type refrigeration systems.Service Station RecoveryService stations can now directly benefit from Jordan’s vapor recovery technology through our M2 and MT vapor recovery units (VRU).Our miniaturized VRU—the M2—recovers vapors already captured during vehicle fueling (Stage II) and returns them to your service station storage tank as liquid product you can resell. The MT unit recovers vapor during the delivery truck process of unloading volatile organic liquids and does the same. While the M2 operates independently as a stand-alone system, a MT unit requires the installation of an M2 unit to function. The Jordan Technologies M2 VRU is unique in the world marketplace today.Jordan understands that typical service stations use a vapor balance system or a vacuum assist system to recover vapors from car refueling. Theoretically, for every gallon of gasoline removed from your storage tank, equivalent vapor is returned. Even though the system is balanced, additional air and gasoline vapors are generated as a result of heat expansion, dispenser nozzle inefficiencies, or splashloading of product. Jordan Technologies M2 VRU and MT units allow you to recover all of the vapors produced at Stage II and realize fuel savings that pay for the technology and reduce air pollution. Financial BenefitsIt has been estimated that Stage II recovery alone could prevent the loss of millions of gallons of gasoline per year to the atmosphere—at today’s prices this means a great amount of lost inventory which translates into lost money. At today’s gasoline prices recovered product more than pays for the equipment investment.With the addition of the MT VRU the retail site not only recovers the gasoline vapor from car refueling but also recovers the vapor from stage I (truck unloading) at the facility. This additional recovery rate can be as high as .02% of the transferred product.For more information and detailed specifications for your service station’s M2 and MT units, contact us. Vapor CombustionAs an alternative to recovery, hydrocarbon vapors may be destroyed in a flare, combustor or a thermal oxidizer. For many applications, a device known as a combustor can be successfully used as a safe and economical method of controlling vapors from the handling, storage, or loading of volatile liquid hydrocarbons or ethanol when recovery of the vapors is not a viable option.Jordan Technologies has experience manufacturing and servicing all types of vapor combustion units (VCUs) including units for special applications such as marine vapor control or non-motor fuel vapor control. Jordan's VCUs are guaranteed to meet all safety regulations and currently mandated emissions limits. Custom vapor combustion devices are also available.Vapor combustors are designed to safely burn vapor mixtures consisting of hydrocarbons. This mixture may, or may not, be within the flammable range of the vapors being destroyed. Vapor combustors can be configured as an open type, where the flame is elevated and visible; or as an enclosed type, w here the flame is generally near grade level and enclosed in an insulated combustion chamber or stack.The equipment provided for both systems is similar. The major equipment items included in a combustor system are the stack, anti-flash back burners with an ignition system, assist air blowers for smokeless burning, velocity control or staging valve(s) and deflagration arrestor(s).Jordan has the knowledge and experience to ensure you end up with the best vapor control system for your application. Contact us today to have one of our specialists assess your needs and discuss how Jordan’s energy can go toward making the most of yours.Vapor RecoveryJordan Technologies designs, manufactures and has actively serviced vapor recovery units (VRUs) since 1980. Jordan Technologies' units recover a variety of VOCs in truck, rail, marine and tank breathing applications as well as crude, ethanol, and natural gases. As the largest service company for VRUs in the world market, Jordan provides service to the majority of the world’s operational VRUs, including other manufacturer's equipment.In 1995 our company expanded to not only servicing competitor's equipment, but also to building a technologically advanced and reliable VRU. These systems include innovations and modifications based on our many years of service experience. A Jordan Technologies VRU is the most efficient, cost effective unit on the market.Refining the science of environmental protectionJordan Technologies has developed several patented energy saving and recovered product measurement devices that can be applied to all manufacturer’s units. These innovations lend functional solutions to problems we've found in typical systems. Our power saving devices have been installed and are operational in the field, have shown excellent results, and allow for substantial power savings on existing VRU equipment.We make our PLC control package more user-friendly and equip our systems with advanced computer technology designed to limit your downtime.Our experience has confirmed that the most efficient and reliable VRUs are carbon bed units. Other types of units: refrigeration, membrane and lean oil units have not proved as reliable, nor provided the pay back in recovered product that customers demand. The Jordan carbon bed VRU recovers greater than 99% of VOCs generated during product loading providing an attractive pay back on capital invested.Whether you have been a longstanding customer or are using our services for the first time, Jordan Technologies will give your job 110%. Jordan’s energy goes toward making the most of yours. For more information about Jordan Technologies' VRUs contact us.Vapor RecoveryDry Pump Wet PumpBASIC OPERATIONThe basic vapor recovery unit system is comprised of a pressure swing absorption (PSA) process with two activated carbon bed vessels, alternating on a 15 minute time cycle. Regeneration of the carbon reactors is accomplished primarily by vessel evacuation with a vacuum pump to a pressure level of-27 Hg (3 Hg absolute) and secondly, with ambient air purge into the bed in a controlled manner during the last 25% of the regeneration cycle.The VOCs (volatile organic compounds) desorbed from the carbon during reactor regeneration are effectively recovered in a single step process that is absorption in a packed tower, counter current flow, absorber. Supply tank absorbent is pumped on skid for use as lean oil in the absorber and as a heat exchange fluid for the vacuum pump.All product recovered by the system is pumped back to the absorbent supply tank mentioned. Here the enriched recovered liquid product is allowed to disperse throughout the supply tank environment. Jordan Technologies offers both the dry vacuum pump regeneration system as well as the liquid ring regeneration system.Vapor RecoveryVRU FEATURESBased on many years of field service experience, we have taken our knowledge and incorporated it into equipment and systems offering unique design and features that exceed industry needs.∙Patented auto tuned vent and regeneration valves to protect vacuum pumps and carbon;increasing the life of the carbon∙Patented return pump variable frequency drive level control to prevent gasoline spills∙Self cleaning absorber tower with dished head bottom to eliminate confined space entry∙Complete HMI control of all components and set points to allow for ease of operation∙Remote web access for troubleshooting to reduce downtime∙Historical trending of all VRU parameters and alarms∙Skid mounted system; shipped and installed in four major parts∙All components mounted and completely wired from the factory to skid mounted junction boxes ∙Skid and components designed for easy accessibility for maintenance and system checks ∙Reporting package specifically designed to meet Subpart BBBBBB regulations∙Smallest industry footprint allows for reduced civil installation cost∙Lowest industry energy consumption; reduces energy consumption on average 50% over competitive models∙Typical return on investment less than 1 year; providing a quick payback and immediate profit increase∙Robust design proven to pass HAZOP reviews by major oil companies globallyEvery Jordan Technologies VRU meets local legislative requirements and is backed by Jordan’s unmatched worldwide service base. We have ten manufacturing sites located worldwide. Please contact us today to discuss your vapor recovery options.EmissionsEMISSIONS TESTINGNo one knows more about industrial emissions testing than Jordan Technologies. We are the recognized leader in providing state of the art testing services for environmental emissions.Jordan Technologies revolutionized hydrocarbon emissions testing in the petrochemical industry by automating the process. Our computer-controlled equipment provides immediate results for diagnostic purposes or to maximize operating flexibility. We have the most advanced, reliable testing equipment and full service lab available in the industry. Jordan’s lab was the first to develop accurate and useful carbon analysis methods, and the first to develop a records system that helps you make appropriatecarbon-maintenance decisions.Jordan Technologies’ emission testing reso urces include:∙professionally staffed and fully equipped mobile testing labs ready to dispatch to any global location∙ a track record of testing thousands of units∙an intricate knowledge of environmental regulations and the equipment we test∙the ability to create and perform custom-designed tests to meet your specialized requirements No other laboratory offers the range of services, with experienced technical personnel, as Jordan. From flat sheet efficiency tests to industrial vapor emissions testing, Jordan Technologies can perform the testing services you need reliably and economically. For more information about our emission testing services, contact us.。