07传质与分离工程期末考试题(含答案)
化工分离工程期末试题A答案

精品文档2007—2008学年第1、2学期分离工程课程期末考试试卷(A 卷)答案及评分标准精品文档.精品文档二、选择题(本大2分,每小分10 mol1-若体系加下达到汽液平衡两组分组成的混合物在一液相和汽相组成分别C,的组分下使体系重新达到汽液平衡,此时汽、液相的组成分别,在相)不确对于绝热闪蒸过程当进料的流量组成及热状态给定之后经自由度分析只剩下一个自由度由闪蒸罐确定则还应该确定的一个条件D)闪蒸罐的温)闪蒸罐的压)气化)任意选定其中之7时液相组时泡点与之相平衡的气相组某二元混合物其为易挥发组分相应的露点)不能确用郭氏法分析可知理论板和部分冷凝可调设计变量数分别1010、如果二元物系有最高压力恒沸物存在,则此二元物系所形成的溶液一定A)正偏差溶)理想溶)负偏差溶)不一、用纯溶剂吸收混合气中的溶质,逆流操作,平衡关系满足亨利定律。
当入塔气体浓上升,而其它入塔件不变,则气体出塔浓和吸收的变化C上升下下降上上升不上升变化不确逆流填料吸收塔当吸收因且填料为无穷高时气液两相将在哪个部位达到平B(A)塔(B塔(C塔中(D塔外平衡常数较小的组分D)难吸收的组)较轻组)挥发能力大的组)吸收剂中的溶解度、吸附等温线是指不同温度下哪一个参数与吸附质分压或浓度的关系曲线A(A)平衡吸附(B)吸附(C)满吸附(D最大吸附精品文1液相双分子吸附中型吸附是指在吸附过程中吸附A溶质和溶剂吸附量相当的情(B)始终优先吸附一个组分的曲(A)精品文档 A卷)答案及评分标准1、2学期分离工程课程期末考试试卷(2007—2008学年第答:分析可知:: 学号恒沸精馏塔:由于恒沸剂加入过量,塔底为甲醇-甲苯的混合物,塔顶烷烃-甲醇的二元恒沸物。
脱甲醇塔:塔底为甲苯,塔顶为甲苯-甲醇的二元恒沸物。
萃取塔:塔底为甲醇水溶液,塔顶为烷烃。
脱水塔:塔底为水,塔顶为甲醇。
相图如下:精品文档.精品文档烷二元恒沸(恒沸精馏塔顶二元恒沸原甲甲苯(脱甲醇塔底恒沸精馏塔二元恒沸(脱甲醇塔顶五、简答题(本大1分,每小分、试指出逐级计算法计算起点的确定原则(按清晰分割处理,分只有轻非关键组分的物系、只有重非关键分的物系两种情况论述答:逐级计算法计算起点的确定原则是以组分的组成估算最精确、误差最小的那块板开始逐板计算按清晰分割处理,轻非关键组分全部进入塔顶,重非关键组分全部进入塔底。
分离工程期末A卷试题答案

1 2007 —2008 学年第1、2学期分离工程课程期末考试试卷(学期分离工程课程期末考试试卷(A A 卷)答案及评分标准二、选择题(本大题20分,每小题2分)1、由1-2两组分组成的混合物,在一定T 、P 下达到汽液平衡,液相和汽相组成分别为 11,y x ,若体系加入10 mol 的组分(1),在相同T 、P 下使体系重新达到汽液平衡,此时汽、液相的组成分别为 '1'1,y x ,则,则 ( C )(A )1'1x x >和 1'1y y > (B )1'1x x <和1'1y y < (C )1'1x x =和1'1y y = (D )不确定)不确定2、对于绝热闪蒸过程,当进料的流量组成及热状态给定之后,当进料的流量组成及热状态给定之后,经自由度分析,经自由度分析,只剩下一个自由度由闪蒸罐确定,则还应该确定的一个条件是则还应该确定的一个条件是( D ) (A )闪蒸罐的温度)闪蒸罐的温度 (B )闪蒸罐的压力)闪蒸罐的压力 (C )气化率)气化率 (D )任意选定其中之一)任意选定其中之一3、某二元混合物,其中A 为易挥发组分,液相组成5.0=A x 时泡点为1t ,与之相平衡的气相组成75.0=A y 时,相应的露点为2t ,则 ( A )(A )21t t = (B )21t t > (C )21t t < (D )不能确定)不能确定4、用郭氏法分析可知理论板和部分冷凝可调设计变量数分别为用郭氏法分析可知理论板和部分冷凝可调设计变量数分别为 ( A ) (A )1,1 (B )1,0 (C )0,1 (D )0,0 5、如果二元物系有最高压力恒沸物存在,则此二元物系所形成的溶液一定是 ( A ) (A )正偏差溶液)正偏差溶液 (B )理想溶液)理想溶液 (C )负偏差溶液)负偏差溶液 (D )不一定)不一定6、用纯溶剂吸收混合气中的溶质,逆流操作,平衡关系满足亨利定律。
传质与分离课后练习题

传质与分离课后练习题一、填空题1. 传质过程主要包括________、________和________三种基本方式。
2. 在气体吸收过程中,根据溶质与溶剂的接触方式,可分为________和________两种类型。
3. 蒸馏操作中,将混合液加热至沸腾,产生的蒸汽通过________冷却后,可得到纯净的液体。
4. 萃取过程中,常用的萃取剂应具备________、________和________等特点。
5. 吸附分离技术中,根据吸附剂与吸附质之间的作用力,可分为________和________两种类型。
二、选择题1. 下列哪种传质方式属于质量传递?()A. 动量传递B. 能量传递C. 质量传递D. 热量传递2. 在下列吸收操作中,属于物理吸收的是()。
A. 氨气吸收B. 二氧化硫吸收C. 丙酮吸收D. 氯气吸收3. 下列哪种蒸馏方法适用于分离沸点相近的液体混合物?()A. 简单蒸馏B. 蒸馏C. 蒸馏D. 分子蒸馏A. 萃取剂的性质B. 混合液的温度C. 萃取剂的浓度5. 下列哪种吸附剂属于物理吸附剂?()A. 活性炭B. 离子交换树脂C. 氢氧化钠D. 氧化铝三、判断题1. 传质过程中,质量传递速率与浓度梯度成正比。
()2. 在气体吸收过程中,气膜控制表示溶质在气相中的扩散速率较慢。
()3. 蒸馏过程中,塔板数越多,分离效果越好。
()4. 萃取操作中,萃取剂的选择对萃取效果具有重要影响。
()5. 吸附分离过程中,吸附剂的选择与吸附质的性质无关。
()四、简答题1. 简述传质过程的基本原理。
2. 请列举三种常见的气体吸收设备,并简要说明其工作原理。
3. 蒸馏操作中,如何提高塔板的效率?4. 萃取过程中,影响萃取效果的因素有哪些?5. 简述吸附分离技术的应用领域。
五、计算题1. 某混合液中含有甲、乙两种组分,其摩尔分数分别为0.4和0.6。
现将该混合液进行蒸馏分离,求在塔顶和塔底得到的馏分中甲、乙组分的摩尔分数。
(完整版)传质与分离习题(含答案)

Problems for Mass Transfer and Separation ProcessAbsorption1 The ammonia –air mixture containing 9% ammonia(molar fraction) is contact with the ammonia-water liquid containing 5% ammonia (molar fraction). Under this operating condition, the equilibrium relationship is y*=0.97x. When the above two phases are contact, what will happen, absorption or stripping?Solution :09.0=y 05.0=x x y 97.0=*09.00485.005.097.0=<=⨯=*y y It is an absorption operation.2 When the temperature is 10 c 0 and the overall pressure is 101.3KPa , the solubility of oxygen in water can be represented by equation p=3.27⨯104x , where p (atm) and x refer to the partial pressure of oxygen in the vapor phase and the mole fraction of oxygen in the liquid phase, respectively. Assume that water is fully contact with the air under that condition, calculate how much oxygen can be dissolved in the per cubic meter of water?Solution: the mole fraction of oxygen in air is 0.21,hence:p = P y =1x0.21=0.21amt64410*24.610*27.321.010*27.3-===p x Because the x is very small , it can be approximately equal to molar ratio X , that is 610*42.6-=≈x XSo[])(/)(4.11)/(18*)(1)/(32*)(10*42.6lub 2322222226O H m O g O kmolH O kgH O kmolH kmolO kgO kmolO ility so ==-3 An acetone-air mixture containing 0.02 molar fraction of acetone is absorbed by water in a packed tower in countercurrent flow. And 99% of acetone is removed, mixed gas molar flow fluxis 0.03kmol ·s —1m -2 , practice absorbent flow rate L is 1.4 times as much as the min amountrequired. Under the operating condition, the equilibrium relationship is y*=1.75x. V olume totalabsorption coefficient is K y a=0.022 kmol ·s —1m -2y -1.. What is the molar flow rate of the absorbentand what height of packing will be required?solution :()0002.01=-=ηb a y y x a =0733.175.102.099.002.0*min =⨯=--=⎪⎭⎫ ⎝⎛ab a b x x y y V L 43.24.1min=⎪⎭⎫ ⎝⎛=V L V L s m kmol L 20729.003.043.2=⨯=720.043.275.1===L mV S Number of mass transfer units N oy =(y 1-y 2)/∆y=12(y b -y a )=0.02-0.0002∆y=[(y b -y*b )- (y a -y*a )]/ln[(y b -y*b )/ (y a -y*a )](y b -y*b )=0.02-1.75x b =0.0057X b =V/L (y b -y a )= (0.02-0.0002)/2.43=0.00815(y a -y*a )= y a =0.0002Or ])1)(ln[(11S S mx y mx y S N ba ab Oy +----==12 m Kya S V H OY 364.1022.003.0/=== m N H H OY OY 37.1612364.1=⨯==4 The mixed gas from an oil distillation tower contains H 2S=0.04(molar fraction). Triethanolamine (absorbent) is used as the solvent to absorb 99% H 2S in the packing tower, the equilibrium relationship is y*=1.95x, the molar flux rate of the mixed gas is 0.02kmol ·m -2·s -1,overall volumeabsorption coefficient is Kya=0.05 kmol ·s —1m -2y -1, The solvent free of H 2S enters the tower andit contains 70% of the H 2S saturation concentration when leaving the tower. Try to calculate: (a) the number of mass transfer units N oy , and (b) the height of packing layer needed, Z.solution :ya=yb(1-0.99)=0.04*1%=0.0004xb*=yb/m=0.04/1.95= 0.0205 xb=0.7xb*=0.0144yb*=1.95*0.0144=0.028yb-yb*=0.04-0.028=0.012△ym=0.0034Z=HoyNoyNoy=(yb-ya)/ △ym=11.6m a K G H y m oy 4.005.0/02.0/===Z=11.6*0.4=4.64m5 Ammonia is removed from ammonia –air mixture by countercurrent scrubbing with water in a packed tower at an atmospheric pressure. Given: the height of the packing layer Z is6 m, the mixed gas entering the tower contains 0.03 ammonia (molar fraction, all are the same below), the gas out of the tower contains ammonia 0.003; the NH 3 concentration of liquid out of the tower is 80% of its saturation concentration, and the equilibrium relation is y*=1.2x. Find:(1)the practical liquid —gas ratio and the min liquid —gas ratio L/V=?. (2) the number of overall mass transfer units.(3) if the molar fraction of the ammonia out of the tower will be reduced to 0.002 and the other operating conditions keep unchanged, is the tower suitable?solution :(1) 35.12.103.08.0003.003.0=⨯-=G L (2) 89.035.12.1==S 26.689.0003.003.011.089.011=⎥⎦⎤⎢⎣⎡+-=In N OY (3) m N Z H OY OY 958.026.66===47.889.0002.003.011.089.011=⎥⎦⎤⎢⎣⎡+⨯-='In N OY Since m N H Z OYOY 0.61.847.8958.0'>=⨯='= it is not suitable6 Pure water is used in an absorption tower with the height of the packed layer 3m to absorb ammonia in an air stream. The absorptivity is 99 percent. The operating conditions of absorber are 101.3kpa and 200c, respectively. The flux of gas V is 580kg/(m 2.h), and 6 percent (volume %) of ammonia is contained in the gas mixture. The flux of water L is 770kg/( m 2.h). The gas and liquid is countercurrent in the tower at isothermal temperature. The equilibrium equation y *=0.9x, and gas phase mass transfer coefficient k G a is proportional to V 0.8, but it has nothing to do with L. What is the height of the packed layer needed to keep the same absorptivity when the conditions of operation change as follows:(1)the operating pressure is 2 times as much as the original.(2)the mass flow rate of water is one time more than the original. 3) the mass flow rate of gas is two times as much as the original Solution: 3,1,293Z m p atm T K ===1210.060.063810.06(10.99)0.000638Y Y Y ==-=-= The average molecular weight of the mixed gas M=29×0.94+17×0.06=28.2822580(10.06)19.28/()28.2877042.78/()180.919.280.405642.78V kmol m h L kmol m h mV L =-=⋅Ω==⋅Ω⨯==12221ln[()(1)]110.06380ln[()(10.4056)0.4056]10.40560.0006386.88430.43586.884OG OG OG N mV LH Y mX mX mV Y mX L L Z m N =-+-=----+-==== 1) 2p p '=''p p m m = So 1222ln[()(1)]10.90.4520.4519.280.202842.78111ln[(100)(10.2028)0.2028]10.20285.496OG mp m p m V L Y mX m X m V N mV Y mX L L L-+='==⨯=''⨯==''-'=---+-= OG r G V V H K a K aP ==ΩΩSo:OG H changes with the operating pressure10.43580.21792OG OG OG OG H H H H ρρρρ'=''=⋅=⨯='So 5.4960.2179 1.198OGOG Z N H m '''=⋅=⨯= So the height of the packed section reduce 1.802m vs the original2) 2L L '=11()0.40560.20282225.496OGmV mV mV L L L N ===⨯=''=when the mass flow rate of liquid increases,G K a has not remarkable effect0.43585.4960.4358 2.395OG OG OG OG H H m Z N H m'=='''=⋅=⨯= the height of the packed section reduce 0.605m against the original3) 2V V '=(2)2()20.40560.81161ln[(100)(10.8116)0.8116]15.8110.8116OG mV m V mV L L L N '===⨯='=-+=- when mass flow rate of gas increaes,G K a also will increase. Since it is gas film control for absorption, we have as follows:0.80.80.80.20.80.2()222220.43580.50115.810.5017.92G G G G OG OG G G OGOG K a V V K a K a K a V V V H H K aP K aP mZ N H m m ∝''==''===Ω'Ω=⨯='''==⨯= So the height of the packed section increase 4.92m against the originalDistillation1 Certain binary mixed liquid containing mole fraction of easy volatilization component F x 0.35, feeding at bubbling point, is separated through a sequence rectify column. The mole fraction in the overhead product is x D =0.96, and the mole fraction in the bottom product is x B =0.025. If the mole overflow rates are constant in the column, try to calculate(a)the flow rate ratio of overhead product to feed(D /F)?(b)If the reflux ratio R=3.2, write the operating lines for rectifying and stripping sections solution :F x =0.35;x B =0.025;x D =0.96;R=3.2。
分离工程考试题及答案

分离工程考试题及答案一、选择题(每题2分,共20分)1. 在分离工程中,下列哪种方法不适用于液-液分离?A. 离心分离B. 过滤C. 蒸馏D. 吸附答案:D2. 哪种类型的分离过程是基于分子大小差异进行的?A. 萃取B. 膜分离C. 蒸发D. 结晶答案:B3. 以下哪个参数对过滤速率影响最大?A. 滤饼厚度B. 过滤面积C. 过滤压力D. 滤液粘度答案:B4. 在蒸馏过程中,提高哪种参数可以增加分离效率?A. 进料温度B. 回流比C. 塔板数D. 塔顶压力答案:C5. 反渗透膜分离技术主要应用于哪种类型的分离?A. 气-液分离B. 液-固分离C. 液-液分离D. 固-固分离答案:C6. 离心分离中,离心力的大小与哪个参数成正比?A. 转速的平方B. 转速的立方C. 转速的四次方D. 转速的五次方答案:A7. 以下哪种方法不适用于气体的分离?A. 吸收B. 吸附C. 膜分离D. 沉降答案:D8. 哪种类型的分离过程是基于分子间作用力差异进行的?A. 萃取B. 膜分离C. 蒸发D. 结晶答案:A9. 在液-液萃取中,选择性系数αAB/AC表示什么?A. 组分A与组分B的分配系数之比B. 组分A与组分C的分配系数之比C. 组分B与组分C的分配系数之比D. 组分A在两种溶剂中的分配系数之比答案:A10. 哪种类型的分离过程是基于分子质量差异进行的?A. 萃取B. 膜分离C. 超滤D. 蒸馏答案:C二、填空题(每空1分,共10分)1. 在过滤过程中,滤饼的厚度增加会导致过滤阻力_____。
2. 蒸馏操作中,提高回流比可以_____组分间的分离效果。
3. 反渗透膜分离技术中,水分子通过膜的驱动力是_____。
4. 离心分离中,离心力的大小与转速的_____次方成正比。
5. 在液-液萃取中,选择性系数αAB/AC越大,表示组分A与组分B 之间的_____越大。
6. 蒸馏过程中,塔板数的增加可以提高_____效率。
化工原理期末复习题答案

化⼯原理期末复习题答案化⼯原理2学习要求第7章传质与分离过程概论1、掌握平衡分离与速率分离的概念(基本原理)及各⾃有哪些主要类型。
平衡分离:借助分离媒介(热能、溶解、吸附剂)使均相混合物变为两相,两相中,各组分达到某种平衡,以各组分在处于平衡的两相中分配关系的差异为依据实现分离。
主要类型:(1)⽓液传质过程(2)汽液传质过程(3)液液传质过程(4)液固传质过程(5)⽓固传质过程速率分离:借助推动⼒(压⼒、温度、点位差)的作⽤,利⽤各组扩散速度的差异,实现分离。
主要类型:(1)膜分离:超滤、反渗透、渗析、电渗析(2)场分离:电泳、热扩散、⾼梯度磁场分离2、掌握质量传递的两者⽅式(分⼦扩散和对流扩散)。
分⼦扩散:由于分⼦的⽆规则热运动⽽形成的物质传递现象——分⼦传质。
对流扩散:运动流体与固体表⾯之间,或两个有限互溶的运动流体之间的质量传递过程—对流传质3、理解双膜理论(双膜模型)的论点(原理)。
(1) 相互接触的两流体间存在着稳定的相界⾯,界⾯两侧各存在着⼀个很薄(等效厚度分别为z G和z L)的流体膜层(⽓膜和液膜)。
溶质以分⼦扩散⽅式通过此两膜层。
(2) 溶质在相界⾯处的浓度处于相平衡状态。
⽆传质阻⼒。
(3) 在膜层以外的两相主流区由于流体湍动剧烈,传质速率⾼,传质阻⼒可以忽略不计,相际的传质阻⼒集中在两个膜层内。
4、理解对传质设备的性能要求、掌握典型传质设备类型及各⾃的主要特点。
性能要求:单位体积中,两相的接触⾯积应尽可能⼤两相分布均匀,避免或抑制沟流、短路及返混等现象发⽣流体的通量⼤,单位设备体积的处理量⼤流动阻⼒⼩,运转时动⼒消耗低操作弹性⼤,对物料的适应性强结构简单,造价低廉,操作调节⽅便,运⾏安全可靠第8章吸收1、掌握吸收的概念、基本原理、推动⼒,了解吸收的⽤途。
吸收概念:使混合⽓体与适当的液体接触,⽓体中的⼀个或⼏个组分便溶解于液体内⽽形成溶液,于是原混合⽓体的组分得以分离。
这种利⽤各组组分溶解度不同⽽分离⽓体混合物的操作称为吸收。
传质分离工程名词解释考试题库

传质分离工程名词解释考试题库第一篇:传质分离工程名词解释考试题库1.分离过程:将一股式多股原料分成组成不同的两种或多种产品的过程。
2.机械分离过程:原料本身两相以上,所组成的混合物,简单地将其各相加以分离的过程。
3.传质分离过程:传质分离过程用于均相混合物的分离,其特点是有质量传递现象发生。
按所依据的物理化学原理不同,工业上常用的分离过程又分为平衡分离过程和速率分离过程两类。
4.相平衡:混合物或溶液形成若干相,这些相保持着物理平衡而共存的状态。
从热力学上看,整个物系的自由焓处于最小状态,从动力学看,相间无物质的静的传递。
5.相对挥发度:两组分平衡常数的比值叫这两个组分的相对挥发度。
6.泡点温度:当把一个液相加热时,开始产生气泡时的温度。
7.露点温度:当把一个气体冷却时,开始产生气泡时的温度。
8.气化率:气化过程的气化量与进料量的比值。
9.冷凝率:冷凝过程的冷凝量与进料量的比。
10.设计变量数:设计过程需要指定的变量数,等于独立变量总数与约束数的差。
11.独立变量数:描述一个过程所需的独立变量的总数。
12.约束数:变量之间可以建立的方程的数目及已知的条件数目。
13.回流比:回流的液的相量与塔顶产品量的比值。
14.精馏过程:将挥发度不同的组分所组成的混合物,在精馏塔中同时多次地部分气化和部分冷凝,使其分离成几乎纯态组成的过程。
15.全塔效率:理论板数与实际板数的比值。
16.精馏的最小回流比:精馏时有一个回流比下,完成给定的分离任务所需的理论板数无穷多,回流比小于这个回流比,无论多少块板都不能完成给定的分离任务,这个回流比就是最小的回流比。
实际回流比大于最小回流比。
17.理论板:离开板的气液两相处于平衡的板叫做理论板。
18.萃取剂的选择性:加溶剂时的相对挥发度与未加溶剂时的相对挥发度的比值。
19.萃取精馏:向相对挥发度接近于1或等于1的体系,加入第三组分P,P体系中任何组分形成恒沸物,从塔底出来的精馏过程。
传质分离工程夏期末考试复习题

试卷A/B一、填空题:(共计25)1.按所依据的物理化学原理,传质分离过程可以分为平衡分离过程和速率分离过程,常见的平衡分离过程有精馏、吸收、闪蒸。
(5分)2.多组分精馏的FUG简捷计算法中,F代表 Fenske 方程,用于计算N m ,U代表Underwood 公式,用于计算R m ,G代表 Gilliland 关联,用于确定实际理论板数 N 。
(6分)2.在多组分精馏的FUG简捷计算法中,用 Fenske 方程计算N m ,用 Underwood 公式计算 R m,用 Gilliland 关联确定 N 。
(6分)driving force for gas absorption is 气相中溶质的实际分压与溶液中溶质的平衡蒸气压力之差。
(2分)4.泡点计算是分离过程设计中最基本的汽液平衡计算。
泡点计算可分两种:泡点温度计算和泡点压力计算。
(2分)4.露点计算是分离过程设计中最基本的汽液平衡计算。
露点计算可分两种:露点温度计算和露点压力计算。
(2分)5.多组分吸收简捷计算中所用到的Horton-Franklin方程关联了吸收因子、吸收率、和理论板数。
(3分)6.多组分多级分离过程严格计算中围绕平衡级所建立的MESH方程分别是指:物料衡算方程,相平衡关系,组分摩尔分率加和方程和热量衡算方程(4分)7共沸精馏是:原溶液加新组分后形成最低共沸物,塔顶采出。
(3分)7萃取精馏是:原溶液加新组分后不形成共沸物且新组分沸点最高,从塔釜采出。
(3分)二、单项或多项选择题(共计10)1.晰分割法的基本假定是:馏出液中除了 A 外没有其他 C 。
(2分)A. heavy key component;B. light key component;C. heavy non-key components;D. light non-key components.1.晰分割法的基本假定是:釜液中除了 B 外没有其他 D 。
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,考试作弊将带来严重后果!华南理工大学期末考试2007《传质与分离工程英文》试卷A (含答案)1. 考前请将密封线内填写清楚;所有答案请直接答在试卷上(或答题纸上);.考试形式:开(闭)卷;S in the air is absorbed by NaOH solution is ( A ).2B. liquid film “controls”;C. two film “controls”.AB=1. WhenC ).>x A; B. y A<x A; C. y A=x A. D. uncertainAD ) is true.>t d; B. t>t w=t d; C. t=t w>t d; D. t=t w=t dwo C, ( C ) of reading is o C B. 77 o C C. 77.01 o C; D. 77.010 o CB ).When the water content of some material is close to its equilibrium water content X*, its drying rate will ___ C _.B. decrease;C. be close to zero;D. be uncertainFor the desorption (stripping) process, when ( B ) increases and ( A )A ) increases, it is good for the operation.D ) decreases, it is good for the operation.A.dry-bulb temperature of air;B. wet-bulb temperature of air ;C. dew point temperature of air;D. size of material to be dried(9) For absorption process, when the coefficients k x a and k y a are of the same order of magnitude and equilibrium constant m is much greater than 1, ( B ) is said to be controlling. In order to increase mass transfer rate, it is better to increase ( E ).A. gas film;B. liquid film;C. both gas film and liquid film;D. gas phase flow rate;E. liquid phase flow rate;F. both gas phase flow rate and liquid phase flow rate;(10) For absorption process, if it is the liquid film control, ( D ) is feasible to increase mass transfer rate of absorption.A to decrease gas flow rate.B to decrease liquid flow rateC to increase gas flow rate.D to increase liquid flow rate.(11)When the reflux ratio R increases and other conditions keep the same, overflow of vapor V will (increase ); the concentration of overhead product x D will (increase ); steam consumption of reboiler will (increase ), the theoretic plate numbers required will (decrease ) for the same recovery percentage of overhead product.(12) The factors to influence mass transfer coefficients of gas phase include (T, P, gas flow rate).(13) When some moist air is preheated in a preheater, its humidity will (be the same ), its relative humidity will (decrease ), its enthalpy will (increase), its dew point will (be the same ), its wet-bulb temperature will (increase ).(14) When the liquid flooding at a packed tower occurs, (pressure drop ) increases remarkably and the entire tower may fill with (liquid )..(15) Mathematic expression of Fick’s law is ( J A=-DdC A/dz ).(16) The requirements to satisfy constant molal overflow are (vaporization heat of different components will be the same, sensible heat exchange of liquid and gas phases on the plates can be ignored, heat loss of column can be igored. )(17)Some wet solids are dried by air with temperature t and humidity H.(1)When air velocity increases and air temperature t and humidity H keep constant, the drying rate at constant-rate period will (increase); If air velocity and air conditions keep unchanged, but thickness of materials increases, the critical moisture content of wet material Xc will (decrease ).2. (20 points) At a constant pressure operation a continuous distillation column with reflux is used for the separation of a binary mixture with feed rate F=1000kmol/h and concentration x F=0.36 (mol fraction of more volatile component). Feed is saturated vapor, the relative volatility ofmixture α is 3, indirect steam heating is used at a rebolier, and total condenser and bubble point reflux at the top of column are employed and the reflux ratio R is 3.2, respectively. It is required that the recovery percent of more volatile component at the top of column is 92%, and that the concentration of more volatile component at the top x D is 0.9. Calculate:(1)Operating line equation for rectifying section;(2) Overhead product flow rate D, vapor overflow V for rectifying section and vapor overflow V ’ for stripping section, in kmol/h.(3)If the practical liquid concentration leaving the first plate (x 1) is 0.825, what is this plate efficiency of plate 1L M E ,?Solution (1) y=0.762x+0.214(2) D x D /Fx F =0.92, D=0.92(1000*0.36)/0.9=368kmol/hV=(R+1)D=4.2*368=1545.6kmol/hV’=V -F=1545.6-1000=545.6kmol/h(3) E mL =(x D -x 1)/(x D -x 1*)=(0.9-0.825)/(0.9-0.75)=0.5y 1=x D =αx 1*/([α-1)x 1*+1]=0.9=3x 1*/[(3-1)x 1*+1]x 1*=0.753.(20 points) Some gas mixture contains acetone vapor with 3%(molar fraction) which is absorbed by pure water at a countercurrent operation absorber. 98% acetone of outlet gas is removed. Ratio of liquid to gas flow rate is 2 and the equilibrium relation is =*y 1.05x Find(1)what is the acetone concentration of outlet water at the tower bottom?(2) what is the overall mass transfer unit number of gas phase?(3) if the inlet compositions of gas and liquid phases keep the same and the ratio of liquid to gas flow rate is 1.04, where (in what position of tower) is the equilibrium of gas and liquid phases when the packing layer height is infinite? What is the maximum recovery percentage of acetone? Solution: (1) x 1=V(y 1-y 2)/L=0.03*0.98/2=0.0147(2) N oy =(y 1-y 1)/∆y m =0.03*0.98/0.00438=6.71∆y m =[(0.03-1.05*0.0147)-0.0006]/ln[(0.03-1.05*0.0147)/0.0006]=0.00438(3) since104.105.104.1 05.1 ='=='=VL m S VL m So the equilibrium will be reached at the bottom of tower. Max removal efficiency of acetone is121max y y y '-=η0286.005.103.005.11*1===y x 0297.00286.004.1*121=⨯=='-x VL y y %9903.00297.0121max =='-=y y y η4. (15 points) A moist material is to be dried from water content 25% to 5% (wet basis) in an adiabatic dryer (constant enthalpy drying process) under atmospheric pressure. The feed of moist material solid into the dryer is 1000 kg/h. After some fresh air with a dry-bulb temperature of 25ºC and a humidity of 0.013 kg water/kg dry air is preheated to 100ºC, it is sent to the dryer. And the air temperature leaving the dryer is 65ºC.(1) What are the bore-dry air (in kg/h) and the volume of fresh air required per unit time (in m 3/h)?(2) How much heat is obtained by air when it passes through the preheater (in kJ/h)? [Hint: 273273)244.1772.0(00+⨯+=t H v H , enthalpy of moist air=(1.01+1.88H)t+2492H] Solution: (1) W=Gc(X1-X2)=1000*0.75(1/3-5/95)=210.5kg/hI 1=I 2(1.01+1.88H 1)t 1+2492H 1=(1.01+1.88H 2)t 2+2492H 2H 1=0.013, t 1=100,t 2=65, H 2=0.0268L=W/(H 2-H 1)=210.5/(0.0268-0.013)=15253.6kgdry air/hv H =(0.772+1.244*0.013)(298/273)=0.86m 3/kgdry airV=Lv H =15253.6*0.86=13118.1 m 3/h(2)Qp=L(I 1-I 0)=15253.6(1.01+1.88*0.013)(100-25)=1183420 kJ/h5. Question (5 points)Draw the capacity performance chart of plate column and indicate the meaning of every line, describe the satisfactory operation zone. When the liquid flow rate keeps constant and vapor flow rate increases remarkably, please explain what may happen to the column.Solution: When the liquid flow rate keeps constant and vapor flow rate increases remarkably, more liquid will be taken upward the plate. So make separation efficiency of column decrease.。