NTA-3Na 英文版 MSDS
叠氮化钠安全技术说明书[MSDS]
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性
质 临界温度（℃）：
临界压力（MPa）：
燃烧热（KJ/mol）：
最小点火能（mJ）：
相对密度（水＝1）： 1.846 相对密度（空气＝1）： 饱和蒸汽压（KPa）：
燃烧性：
燃烧分解产物：
燃 闪点（℃）：
聚合危害：
烧 爆炸下限（％）：
稳定性：
爆 爆炸上限（％）： 炸 引燃温度（℃）：
最大爆炸压力（MPa）： 禁忌物：酸类、重金属及其盐类。
叠氮化钠安全技术说明书[MSDS]
中文名：叠氮化钠；三氮化钠 标 识 分子式：NaN3
危规号：61033
英文名：smide，sodium azide
分子量：271.50
CAS 号：7487－94－7
性状：无色至白色六面晶系结晶。
理 溶解性：溶于水。溶于液氨。不易溶于有机溶剂。
化
熔点（℃）：
沸点（℃）：
危 危险特性：本品与酸类剧烈反应产生爆炸性叠氮酸。与重金属及其盐类形成十分敏感的化合物。 险 受热或撞击会发生爆炸。剧毒，本品比亚硝酸毒性强。许多中毒症状如氰化物。 性 灭火方法：消防人员必须穿戴全身防护服，在有爆炸掩蔽处用雾状水、泡沫灭火机扑救，禁止用
砂土。
大鼠腹腔注射本品 3～5 mg/kg，1～5 天后表现为无力、震颤、痉挛、青紫、体温下降、昏迷、 毒 严重呼吸抑制和死亡。
储运条件：防止容器破损。储存于阴凉、通风的地方。远离容易起火的地方。与酸类、重金属
及其盐类，特别是铅、铜、银及其其他化合物隔离储运。较大批量须存放在炸药库内。
防 对泄漏物处理必须穿戴防毒面具与手套。
护
泄 对泄漏物处理必须穿戴防毒面具与手套。用水冲洗，经稀释的污水放入废水系统。
NMSDS氨三乙酸MSDS
LiShui Brandt Chemcial Co.,LtdAdd：No.121JinLong Road QiLi,Jinyun,Lishui,ZhejiangTel：0086-0578-*******Fax：0086-0578-*******P.C.：321400 ======================================================================NTA-3Na MSDSThe first part：Chemical NameProduct Name：Nitrilotriacetic acidSynonyms：TriglycineEINECS：205-355-7CAS No.：139-13-9Formula：C6H9NO6Molecular Weight：191.14g/molThe second part：Composition/informationIngredient name：Nitrilotriacetic acidIngredients：≥99.0%The third part：HazardsRisk category：1.2Relevant identified uses of the substance or mixture and uses advised againstIdentified uses:Laboratory chemicals,Manufacture of substances SECTION2:Hazards identification2.1Classification of the substance or mixtureClassification according to Regulation(EC)No1272/2008Acute toxicity,Oral(Category4),H302Eye irritation(Category2),H319Carcinogenicity(Category2),H351For the full text of the H-Statements mentioned in this Section,see Section16.Classification according to EU Directives67/548/EEC or1999/45/ECR40Xn Harmful R22Xi Irritant R36Hazard statement(s)：H302Harmful if swallowed.H319Causes serious eye irritation. H351Suspected of causing cancer.Precautionary statement(s)：P281Use personal protective equipment as required.P305+P351+P338IF IN EYES:Rinse cautiously with water for several minutes.Removecontact lenses,if present and easy to do.Continue rinsing.Supplemental Hazard：noneThe fourth part：First aid measuresIn case of skin contact:Wash off with soap and plenty of water.Consult a physician.In case of eye contact:Rinse thoroughly with plenty of water for at least15minutes and consult a physicianIf swallowed:Never give anything by mouth to an unconscious person.Rinse mouth with water.Consult a physician.If inhaled:If breathed in,move person into fresh air.If not breathing,give artificial respiration.Consult a physician.The fifth part：Firefighting measuresHazardous combustionproducts:Carbon monoxide,carbon dioxide,nitrogen oxides.Extinguishing media:Use water spray,alcohol-resistant foam,dry chemical or carbon dioxide. Advice for firefighters:Wear self contained breathing apparatus for fire fighting if necessary.The sixth part：Accidental release measuresEmergency treatment:Use of personal protective equipment.Avoid dust formation.Avoid breathing vapors,fumes or gases.Ensure adequate ventilation.Evacuation to a safe area.Avoid breathing dust.The Seventh part：Handling and storageHandling Precautions:Avoid contact with skin and eyes.Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Conditions for safe storage：Store in cool place.Keep container tightly closed in a dry and well-ventilated place.Specific and use(s)：noneThe Eighth part：Exposure controls/personal protection Allowableconcentration:Components with workplace control parametersExposure Controls:Operate in accordance with good industrial hygiene and safety regulations.Before breaks and at the end of the work of their hands.Eye protection:Wear protective chemical safety glasses. Body protection:Wear protective overalls on infiltration.Respiratory protection:When the dust in the air concentrations exceeding have to wear self-absorption filter respirators.Emergency rescue or evacuation,air respirator should be worn.Other protection:Shower and change clothes after work.Attention to personal hygiene.The Ninth part：Physical and chemical propertiesThe main ingredients:Pure productAppearance:white crystalline powder.pH:noneMelting freezing point:246℃（decomposition）Boiling point andboiling range:noneFlash point:noneThe Tenth part：Stability and reactivityReactivity:noneChemical stability:nonePossibility of hazardous reactions:noneConditions to avoid:noneIncompatiblematerials:Strong oxidizing agents,Strong bases Hazardousdecompositionproducts:noneThe Eleventh part：Toxicological informationAcute toxicity:LD50Oral-rat-male and female-1470mg/kg (OECD Test Guideline401)Skin corrosion/irritation:Skin-rabbitResult:No skin irritation-24h (OECD Test Guideline404)Serious eye damage/eye irritation:Eyes-rabbitResult:Irritating to eyes.-24h (OECD Test Guideline405)Respiratory or skin sensitisation:guinea pigResult:Does not cause skin sensitisation. (OECD Test Guideline406)Germ cell mutagenicity:Mutagenicity(micronucleus test) mouse-maleResult:negativeCarcinogenicity:This product is or contains a component that has been reported to be possibly carcinogenic based on itsIARC,ACGIH,NTP,or EPA classification.The National Cancer Institute(NCI)has found clear evidence forcarcinogenicity.Found positive for carcinogenicity in EPA Genetox program.Limited evidence of carcinogenicity in animal studiesIARC:2B-Group2B:Possibly carcinogenic to humans(Trisodium nitrilotriacetate)Reproductive toxicity none Specific target organ toxicity-single exposure:none Specific target organ toxicity-repeatedexposure:none Aspiration hazard:noneAdditional Information:Repeated dose toxicity-rat-male-Oral-No observed adverse effect level-9mg/kgRTECS:MB8400000The Twelfth part：Ecological informationToxicity:Toxicity to fish flow-through test LC50-Pimephales promelas(fathead minnow)-127mg/l-96hToxicity to daphnia and other aquatic invertebratesstatic test EC50-Daphnia magna(Water flea)-560-1.000mg/l-48h Toxicity to algae static test EC50-Desmodesmus subspicatus (Scenedesmus subspicatus)->100mg/l-72hPersistence and degradability:Biodegradability aerobic-Exposure time28d Result:96%-Readily biodegradable. (OECD Test Guideline302B)Bioaccumulative potential:none Mobility in soil:noneResults of PBT and vPvB assessment:PBT/vPvB assessment not available as chemical safety assessment not required/not conductedOther adverse effects:noneThe Thirteenth part：Disposal considerationsWaste treatment methods:Offer surplus and non-recyclable solutions to a licensed disposal company.Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.Contaminated packaging dispose of as unusedThe Fourteenth part：Transport informationUN number:ADR/RID:-IMDG:-IATA:-UN proper shipping name:ADR/RID:Not dangerous goods IMDG:Not dangerous goods IATA:Not dangerous goodsTransport hazardclass(es):ADR/RID:-IMDG:-IATA:-Packaging group ADR/RID:-IMDG:-IATA:-Environmental hazards:ADR/RID:no IMDG Marine pollutant:no IATA:no Special precautions foruser:noneThe Fifteenth part：Regulatory informationRegulatory Information:For this product a chemical safety assessment was not carried out SECTION15:Regulatory informationThis safety datasheet complies with the requirements of Regulation(EC) No.1907/2006.。
三甲胺(无水)物质安全数据表
储存于阴凉、通风的库房。远离火种、热源。库温不宜超过30℃。保持容器密封。应与氧化剂、酸类、卤素分开存放，切忌混储。采用防爆型照明、通风设施。禁止使用易产生火花的机械设备和工具。储区应备有泄漏应急处理设备。
职业接触限值(mg/m3)
毒理学资料
运
输
信
息
危规号:21045
UN编号:1083
MAC
燃烧产物
吸入
迅速脱离现场至空气新鲜处。保持呼吸道通畅。如呼吸困难，给输氧。如呼吸停止，立即进行人工呼吸。就医。
灭火方法
食入
泄露应急处理
迅速撤离泄漏污染区人员至上风处，并进行隔离，严格限制出入。切断火源。建议应急处理人员戴自给正压式呼吸器，穿防静电工作服。从上风处进入现场。尽可能切断泄漏源。用工业覆盖层或吸附/吸收剂盖住泄漏点附近的下水道等地方，防止气体进入。合理通风，加速扩散。喷雾状水稀释、溶解。构筑围堤或挖坑收容产生的大量废水。如有可能，将残余气或漏出气用排风机送至水洗塔或与塔相连的通风橱内。漏气容器要妥善处理，修复、检验后再用。
LD50：无资料LC50：无资料
包装类别:O52
包装标志:
PC-TWA
包装方法
钢质气瓶；安瓿瓶外普通木箱；罐车（充装系数0.55吨/立方米）。
PC-STEL
侵入途径
吸入、食入
防
护
措
施
工程控制
生产过程密闭，加强通风。提供安全淋浴和洗眼设备。
呼吸系统
空气中浓度超标时，佩戴过滤式防毒面具（半面罩）。紧急事态抢救或撤离时，建议佩戴氧气呼吸器或空气呼吸器。
眼睛防护
戴化学安全防护眼镜。
环境危害
身体防护
穿防静电工作服。
化学品安全技术说明书(MSDS)中英文对照及翻译完整版
化学品安全技术说明书(MSDS)中英文对照及翻译完整版篇一：化学品安全技术说明MSDS-亚硫酸氢钠(中英文对照版本) Sodium Bisulfite1) Chemical Product and Company IdentificationMSDS Name: Sodium Sulfite, AnhydrousCatalog Numbers: S80195, 1MSS44-20, 1MSS4420, BP355 500, BP355-500, BP355500, S430 10, S430 3, S430 500, S430-10, S430-3, S430-500, S43010, S4303, S430500, S447 3, S447 500, S447-3, S447-500, S4473, S447500Synonyms: Sulfurous acid, disodium saltRisk Phrases: 22 36/37/383) Hazards IdentificationEMERGENCY OVERVIEWAppearance: white. Air sensitive. Moisture sensitive. Warning! Causes eye and skin irritation. May cause digestive tract irritation. Causes respiratory tract irritation. May be harmful if swallowed.Target Organs: Central nervous system.Potential Health EffectsEye: Causes eye irritation. May cause chemicalconjunctivitis.Skin: Causes skin irritation.Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed.Inhalation: Causes respiratory tract irritation. Can produce delayed pulmonary edema.Chronic: Effects may be delayed.4) First Aid MeasuresEyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. Notes to Physician: Treat symptomatically and supportively.5) Fire Fighting MeasuresGeneral Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Wear appropriate protective clothing to prevent contact with skin and eyes. Wear a self-contained breathing apparatus (SCBA) to prevent contact with thermal decomposition products.Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire. Do NOT get water inside containers. Use water spray, dry chemical, carbon dioxide, or appropriate foam.6) Accidental Release MeasuresGeneral Information: Use proper personal protective equipment as indicated in Section 8.Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Place under an inert atmosphere. Do not get water inside containers.7) Handling and StorageHandling: Wash thoroughly after handling. Use withadequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Handle under an inert atmosphere. Store protected from air. Do not allow contact with water. Wash clothing before reuse. Keep from contact with moist air and steam.Storage: Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep away from strong acids. Do not expose to air. Store protected from moisture. Store under an inert atmosphere.8) Exposure Controls, Personal ProtectionEngineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.listed for this chemical.Personal Protective EquipmentEyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA’s eye and face protection regulations in 29 CFR or European Standard EN166.Skin: Wear appropriate protective gloves to prevent skinexposure.Clothing: Wear appropriate protective clothing to prevent skin exposure.Respirators: A respiratory protection program that meets OSHA’s 29 CFR and ANSI requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator’s use. Follow the OSHA respirator regulations found in 29CFR or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.9) Physical and Chemical PropertiesPhysical State: SolidAppearance: whiteOdor: odorlesspH: Not available.Vapor Pressure: Not available.Vapor Density: Not available.Evaporation Rate: Not available.Viscosity: Not available.Boiling Point: Not available.Freezing/Melting Point: Not available.Autoignition Temperature: Not available.Flash Point: Not available.Decomposition Temperature: > 500 deg CNFPA Rating: (estimated) Health: 2; Flammability: 0; Reactivity: 0Explosion Limits, Lower: Not available.Upper: Not available.Solubility: 23 g/100 mL water (20° C)Specific Gravity/Density: /cm3Molecular Formula: Na2O3SMolecular Weight:10) Stability and ReactivityChemical Stability: Stable at room temperature in closed containers under normal storage and handling conditions.Conditions to Avoid: Incompatible materials, dust generation, moisture, exposure to air, excess heat.Incompatibilities with Other Materials: Strong oxidizing agents, acids, organics, moisture, air, combustible materials.Hazardous Decomposition Products: Oxides of sulfur.Hazardous Polymerization: Has not been reported.11) Toxicological InformationRTECS#:CAS# 7757-83-7: WE2150000LD50/LC50:CAS# 7757-83-7:Oral, mouse: LD50 = 820 mg/kg;Carcinogenicity:CAS# 7757-83-7: Not listed by ACGIH, IARC, NIOSH, NTP, or OSHA.Epidemiology: No information available.Teratogenicity: No information available.Reproductive Effects: No information available.Neurotoxicity: No information available.Mutagenicity: No information available.Other Studies: No data available.12) Ecological InformationEcotoxicity: No data available. No information available.Environmental: No information found.Physical: No information found.Other: No information available.13) Disposal ConsiderationsChemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts Additionally, waste generators must consult state and local hazardous waste regulations to ensure completeand accurate classification. RCRA P-Series: None listed.RCRA U-Series: None listed.US FEDERALTSCACAS# 7757-83-7 is listed on the TSCA inventory.Health & Safety Reporting ListNone of the chemicals are on the Health & Safety Reporting List.Chemical Test RulesNone of the chemicals in this product are under a Chemical Test Rule.Section 12bNone of the chemicals are listed under TSCA Section 12b.TSCA Significant New Use RuleNone of the chemicals in this material have a SNUR under TSCA.SARASection 302 (RQ)None of the chemicals in this material have an RQ.Section 302 (TPQ)None of the chemicals in this product have a TPQ.SARA CodesCAS # 7757-83-7: acute.Section 313No chemicals are reportable under Section 313.Clean Air Act:This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.Clean Water Act:None of the chemicals in this product are listed as Hazardous Substances under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.OSHA:None of the chemicals in this product are considered highly hazardous by OSHA. STATECAS# 7757-83-7 is not present on state lists from CA, PA, MN, MA, FL, or NJ.California No Significant Risk Level: None of the chemicals in this product are listed. European/International RegulationsEuropean Labeling in Accordance with EC DirectivesHazard Symbols:XNRisk Phrases:R 22 Harmful if swallowed.R 36/37/38 Irritating to eyes, respiratory systemand skin.Safety Phrases:S 24/25 Avoid contact with skin and eyes.WGK (Water Danger/Protection)CAS# 7757-83-7: 1CanadaCAS# 7757-83-7 is listed on Canada’s DSL List. CAS# 7757-83-7 is listed on Canada’s DSL List.This product has a WHMIS classification of D2B.CAS# 7757-83-7 is not listed on Canada’s Ingredient Disclosure List.Exposure Limits16) Additional InformationMSDS Creation Date: 7/15/1999Revision #1 Date: 8/02/2000The information above is believed to be accurate andrepresents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.亚硫酸氢钠1）化学品名称化学品中文名称：亚硫酸氢钠化学品英文名称：sodium bisulfite篇二：化学品安全技术说明书(MSDS)篇三：详细化学品安全技术说明书(MSDS)化学品安全技术说明书二〇〇六年二月目录表1－001 乙炔气 ............ 1 表1－002 表1－003 表1－004 表1－005 表1－006 表1－007 表1－008 表1－009 表1－010 表1－011 表1－012 表1－013 氧气 .............. 二氧化碳 ......... 氢气 ............. 氩气 ............. 甲烷 ............. 四氢噻吩 ......... 活性炭 ........... 三乙胺 ........... 硫代磷酰氯 ....... 硫黄 ............ 甲胺磷 ........... 多聚甲醛 ........ 5 11 13 15 17 19 21 23 25 27 30 32表1－014（附表1－3）甲缩醛 34 表1－015 黄磷 ............36 表1－016 氯 .............. 38 表1－017 表1－018 表1－019 表1－020 表1－021 表1－022 表1－023 表1－024 表1－025 表1－026 表1－027 表1－028 三氯化磷 ......... 甲醇 ............. 液碱 ............. 氨水 ............. 硫酸二甲酯 ....... 甲胺磷 ........... 液氨 ............. 氯仿 ............. 二氯乙烷 ......... 二硫化碳 ......... 甲苯 ............. 盐酸 ............. 41 45 47 49 52 54 57 59 61 64 66 68表1－029 氯甲烷........... 71 表1－030 硫酸 ............. 73 表1－031 二甲苯 ........... 76 表1－032 表1－033 表1－034 表1－035 表1－036 表1－037 表1－038 表1－039 表1－040 表1－041 表1－042 表1－043 醋酸酐 ........... 多聚甲醛 ......... 草甘膦 ........... 稻瘟灵 ........... 异丙胺 ........... 漂白粉 ........... 氯化氢 ........... 氰化氢 ........... 氰化钠 ........... 氯乙酸 ........... 甲缩醛 ........... 丙烯腈 .......... 78 81 82 84 86 88 90 93 95 97 99 102。
MSDS物质安全资料表(大全)
MSDS大全目录表1－001 乙炔气 (1)表1－002 氧气 (2)表1－003 二氧化碳 (3)表1－004 氢气 (4)表1－005 氩气 (5)表1－006 甲烷 (6)表1－007 四氢噻吩 (7)表1－008 活性炭 (8)表1－009 三乙胺 (9)表1－010 硫代磷酰氯 (10)表1－011 硫黄 (11)表1－012 甲胺磷 (12)表1－013 多聚甲醛 (13)表1－014（附表1－3）甲缩醛 (14)表1－015 黄磷 (15)表1－016 氯 (16)表1－017 三氯化磷 (17)表1－018 甲醇 (19)表1－019 液碱 (20)表1－020 氨水 (21)表1－021 硫酸二甲酯 (22)表1－022 甲胺磷 (23)表1－023 液氨 (24)表1－024 氯仿 (25)表1－025 二氯乙烷 (26)表1－026 二硫化碳 (27)表1－027 甲苯 (28)表1－028 盐酸 (29)表1－029 氯甲烷 (30)表1－030 硫酸 (31)表1－031 二甲苯 (33)表1－032 醋酸酐 (34)表1－033 多聚甲醛 (35)表1－034 草甘膦 (36)表1－035 稻瘟灵 (37)表1－036 异丙胺 (38)表1－037 漂白粉 (39)表1－038 氯化氢 (40)表1－039 氰化氢 (41)表1－040 氰化钠 (42)表1－041 氯乙酸 (43)表1－043 丙烯腈 (45)表1－044 氧化亚铜 (46)表1－045 四氯化锡 (47)表1－046 四氧化三铅 (48)表1－047 三氯化铝（无水） (49)表1－048 松香水 (50)表1－049红丹油性防锈漆 (52)表1－050 酚醛树脂 (53)表1－051 硫磺粉(补充) (54)表1－052 一乙胺 (55)表1－053三聚氯氰 (56)表1－054 三氯乙烯 (57)表1－055 磷酸 (58)表1－056 四丁基锡 (59)表1－057 柴油 (61)表1－058 对氨基苯酚 (62)表1－059 醋酸乙酯 (63)表1－060 对氯硝基苯 (64)表1－061 氮气 (65)表1－062莠去津 (66)表1－063 扑草净 (67)表1－064 八氯二丙醚 (68)表1－065 硫化钠 (69)表１－066 异丙醇 (70)表１－067 丙酮 (71)表１－068 二氯丙烷 (72)表１－069 环己酮 (73)表１－070 乙酸异戊酯 (74)表1－071 锌粉 (75)表1－072 乙醇 (76)表1－073 次氯酸钠溶液 (77)表1－074 石脑油 (78)表1－075 双环戊二烯 (79)表1－076 乙酸丁酯 (80)表1－077 双氧水 (81)表1－078 丙烯酸丁酯 (82)表1－079 丙烯酸 (83)表1－080 苯乙烯 (84)表1－081 过硫酸铵 (85)表1－082 过硫酸钾 (86)表1－083 丙烯酰胺 (87)表1－084 甲醛 (88)表1－085 甲基丙烯酸甲酯 (89)表1－087 汽油 (91)表1－088 乙酸 (92)表1－089 丙烯酸树脂 (93)表1－090 丙烯酸清漆 (94)表1－091 丙烯酸漆稀释剂 (95)表1－092 丙烯酸磁漆 (96)表1－093 二乙醇胺 (98)表1－094 煤油 (99)表1－095 漂白粉 (100)表1－096 漂粉精 (101)表1－097 三氯异氰尿酸 (102)表1－098 松香 (103)表1－099 松节油 (104)表1－100 硫化钠 (105)表1－101 保险粉 (106)表1－102 7385聚氨酯清漆（分装） (107)表1－103 甲酸 (108)表1－104 乙酸乙二醇乙醚 (109)表1－105 H－3聚氨酯漆固化剂 (110)表1－106 聚氨酯漆稀释剂 (111)表1－107 263醇酸树脂 (112)表1－108 异噻唑啉酮 (113)表1－109 N-乙基苯胺 (114)表1－110苯胺 (115)表1－111 乙酰甲胺磷 (116)表1－112 亚磷酸 (118)表1－113 亚磷酸二甲酯 (119)表1－114 氯甲烷 (120)表1－115 乙醚 (121)表1－116 丙烯酸甲酯 (122)表1－117 一甲胺 (123)表1－118 硝酸镁 (124)表1－119 硫化氢 (125)表1－120 硫化铵 (126)表1－121 一甲胺水溶液 (127)表1－122 兔宝宝面漆 (128)表1－123 兔宝宝稀释剂 (129)表1－124 硫氢化钠 (130)表1－125丙酸 (131)表1－126乙酰氯 (132)表1－127丙酰氯 (133)表1－128 丁醇 (134)表1－129 醇酸调合漆（未列名） (135)表1－130 硝酸钠 (137)表1－131 溴甲烷 (138)表1－132 磷化铝 (139)表１－133 正丁醇 (140)表１－134 硝基木器漆 (141)表１－135 硝化棉（含氮≤12.6％） (142)表１－136 单丁醚 (143)表1－137 砷 (144)表1－138 碘化汞 (145)表1－139 氯化汞 (146)表1－140 叠氮化钠 (147)表1－141 重铬酸钠 (148)表1－142 高锰酸钾 (149)表1－143 氰化金钾 (150)表1－144丙烯酸 (151)表1－145甲基丙烯酸甲酯 (152)表1－146苯乙烯 (153)表1－147丙烯酸丁酯 (154)表1－148丁醇 (155)表1－149偶氮二异丁腈 (156)表1－150甲基丙烯酸异丁酯 (157)表1－151 甲基丙烯酸（正）丁酯 (158)表1－152 乙酰丙酮 (159)表1－153 2－丁酮 (161)表1－154 生松香 (162)表1－155 硫酸铜 (163)表1－155 硝酸 (164)表1－155 氰化钾 (165)表1－156硝基苯 (166)表1－157 氟化钠 (167)表1－158 氢氟酸 (168)表1－159蓄电池（注有酸液） (169)表1－160 环氧树脂 (170)表1－161 氯苯 (171)表1－162 乙苯 (172)表1－163 樟脑 (173)表1－164 赛璐珞 (174)表1-165 氢氧化钾 (175)表1-166 乙酸丁酯 (176)乙炔气MSDS表1－002 氧气表1－003 二氧化碳表1－004 氢气表1－005 氩气表1－006 甲烷表1－007 四氢噻吩表1－008 活性炭活性炭 C 12.0Active carbon别名：Activated chlarcoal危规分类及编号：自燃物品。
IsoparE MSDS 英文版
Page 1 of 11______________________________________________________________________________________________________________________MATERIAL SAFETY DATA SHEETPRODUCTProduct Name: ISOPAR E SOLVENTProduct Description: Isoparaffinic Hydrocarbon MSDS Number: 9113Intended Use: SolventCOMPANY IDENTIFICATIONSupplier: IMPERIAL OIL CHEMICALS DIVISION240 4th Avenue S.W.CALGARY, ALBERTA. T2P 3M9 Canada24 Hour Environmental / Health Emergency Telephone519-339-2145 Transportation Emergency Phone Number 519-339-2145 Product Technical Information 1-800-663-4109Reportable Hazardous Substance(s) or Complex Substance(s)NameCAS#Concentration*Acute ToxicityNAPHTHA (PETROLEUM), LIGHT ALKYLATE64741-66-8100%None* All concentrations are percent by weight unless ingredient is a gas. Gas concentrations are in percent by volume.PHYSICAL/CHEMICAL EFFECTSFLAMMABLE. Material can release vapours that readily form flammable mixtures. Vapour accumulation could flash and/or explode if ignited. Material can accumulate static charges which may cause an ignition.HEALTH EFFECTSRepeated exposure may cause skin dryness or cracking.Danger of serious irreversible effects by a single exposure. If swallowed, may be aspirated and cause lung damage. May be irritating to the eyes, nose, throat, and lungs. May cause central nervous system depression.Target Organs: Nervous system |NFPA Hazard ID: Health: 1 Flammability: 3 Reactivity: 0HMIS Hazard ID: Health: 1 Flammability: 3 Reactivity: 0NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person.Page 2 of 11INHALATIONRemove from further exposure. For those providing assistance, avoid exposure to yourself or others. Useadequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or usemouth-to-mouth resuscitation.SKIN CONTACTWash contact areas with soap and water. Remove contaminated under contaminated clothingbefore reuse.EYE CONTACTFlush thoroughly with water. If irritation occurs, get medical assistance.INGESTIONSeek immediate medical attention. Do not induce vomiting.NOTE TO PHYSICIANIf ingested, material may be aspirated into the lungs and cause chemical pneumonitis. Treat appropriately.This light hydrocarbon material, or a component, may be associated with cardiac sensitisation following very high exposures (well above occupational exposure limits) or with concurrent exposure to high stress levels or heart-stimulating substances like epinephrine. Administration of such substances should be avoided.EXTINGUISHING MEDIAAppropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.Inappropriate Extinguishing Media: Straight streams of waterFIRE FIGHTINGFire Fighting Instructions: Evacuate area. If a leak or spill has not ignited, use water spray to disperse the vapours and to protect personnel attempting to stop a leak.Prevent run-off from fire control or dilution fromentering streams, sewers or drinking water supply.Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposedsurfaces and to protect personnel.Unusual Fire Hazards: Highly flammable. Vapour is flammable and heavier than air. Vapour may travelacross the ground and reach remote ignition sources, causing a flashback fire danger.Hazardous Combustion Products: Smoke, Fume, Incomplete combustion products, Oxides of carbon FLAMMABILITY PROPERTIESFlash Point [Method]: 7C (45F) [ ASTM D-56]Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 6.2Autoignition Temperature: 395°C (743°F)Page 3 of 11 ______________________________________________________________________________________________________________________ NOTIFICATION PROCEDURESIn the event of a spill or accidental release, notify relevant authorities in accordance with all applicableregulations.PROTECTIVE MEASURESAvoid contact with spilled material. Warn or evacuate occupants in surrounding and downwind areas ifrequired, due to toxicity or flammability of the material. See Section 5 for fire fighting information. See theHazard Identification Section for Significant Hazards. See Section 4 for First Aid Advice. See Section 8 forPersonal Protective Equipment.SPILL MANAGEMENTLand Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Use clean non-sparking tools to collect absorbed material.Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers. Large Spills: Water spray may reduce vapour, but may not prevent ignition in enclosed spaces.Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient Air Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants.Water spill and land spill recommendations are based on the most likely spill scenario for this material;however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.ENVIRONMENTAL PRECAUTIONSLarge Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways,sewers, basements or confined areas.HANDLINGAvoid contact with skin. Prevent exposure to ignition sources, for example use non-sparking tools andexplosion-proof equipment. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitatedmaterial. Use only with adequate ventilation. Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). Use proper bondingand/or ground procedures. However, bonding and grounds may not eliminate the hazard from staticaccumulation. Consult local applicable standards for guidance. Additional references include AmericanPetroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) orNational Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity).Loading/Unloading Temperature: [Ambient]Transport Temperature: [Ambient]Transport Pressure: [Ambient]Page 4 of 11 ______________________________________________________________________________________________________________________ Static Accumulator: This material is a static accumulator. A liquid is typically considered a nonconductive, static accumulator if its conductivity is below 100 pS/m (100x10E-12 Siemens per meter) and is considered a semiconductive, static accumulator if its conductivity is below 10,000 pS/m. Whether a liquid is nonconductive or semiconductive, the precautions are the same. A number of factors, for example liquid temperature,presence of contaminants, anti-static additives and filtration can greatly influence the conductivity of a liquid. STORAGEAmple fire water supply should be available. A fixed sprinkler/deluge system is recommended. The container choice, for example storage vessel, may effect static accumulation and dissipation. Keep container closed.Handle containers with care. Open slowly in order to control possible pressure release. Store in a cool, well-ventilated area. Outside or detached storage preferred. Storage containers should be earthed and bonded.Fixed storage containers, transfer containers and associated equipment should be grounded and bonded toprevent accumulation of static charge.Storage Temperature: [Ambient]Storage Pressure: [Ambient]Suitable Containers/Packing: Tank Cars; Tank Trucks; Drums; Tank VesselSuitable Materials and Coatings (Chemical Compatibility): Carbon Steel; Stainless Steel; Polyethylene;Polypropylene; Polyester; TeflonUnsuitable Materials and Coatings: Natural Rubber; Butyl Rubber; Ethylene-proplyene-diene monomer(EPDM); PolystyreneSubstance Name Form Limit/Standard Note SourceNAPHTHA (PETROLEUM), LIGHT ALKYLATE Vapour. RCP-TWA1200mg/m3241 ppm TotalHydrocarbonsSupplierNOTE: Limits/standards shown for guidance only. Follow applicable regulations.ENGINEERING CONTROLSThe level of protection and types of controls necessary will vary depending upon potential exposure conditions.Control measures to consider:Adequate ventilation should be provided so that exposure limits are not exceeded. Use explosion-proof ventilation equipment.PERSONAL PROTECTIONPersonal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respiratorselection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:Half-face filter respiratorPage 5 of 11 ______________________________________________________________________________________________________________________ For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode.Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate,gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.Hand Protection: Any specific glove information provided is based on published literature and glovemanufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions.Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your useconditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:Chemical resistant gloves are recommended.Eye Protection: If contact is likely, safety glasses with side shields are recommended.Skin and Body Protection: Any specific clothing information provided is based on published literature ormanufacturer data. The types of clothing to be considered for this material include:Chemical/oil resistant clothing is recommended.Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing afterhandling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned.Practise good housekeeping.ENVIRONMENTAL CONTROLSSee Sections 6, 7, 12, 13.Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data.GENERAL INFORMATIONPhysical State: LiquidForm: ClearColour: ColourlessOdour: Mild Petroleum/SolventOdour Threshold: N/DIMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATIONRelative Density (at 15.6 C): 0.724Flash Point [Method]: 7C (45F) [ ASTM D-56]Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 6.2Autoignition Temperature: 395°C (743°F)Boiling Point / Range: 115C (239F) - 140C (284F)Vapour Density (Air = 1): 4.1 at 101 kPaVapour Pressure: 2.37 kPa (17.82 mm Hg) at 20°CEvaporation Rate (n-butyl acetate = 1): 2.08pH: N/ALog Pow (n-Octanol/Water Partition Coefficient): N/DSolubility in Water: NegligibleViscosity: 0.72 cSt (0.72 mm2/sec) at 40°C | 0.85 cSt (0.85 mm2/sec) at 25COxidizing Properties: See Hazards Identification Section.Page 6 of 11 ______________________________________________________________________________________________________________________ OTHER INFORMATIONFreezing Point: N/DMelting Point: N/DPour Point: -63°C (-81°F)Molecular Weight: 118Hygroscopic: NoCoefficient of Thermal Expansion: 0.00085 V/V/DEG CSTABILITY: Material is stable under normal conditions.CONDITIONS TO AVOID: Avoid heat, sparks, open flames and other ignition sources.MATERIALS TO AVOID: Strong oxidizersHAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures. HAZARDOUS POLYMERIZATION: Will not occur.ACUTE TOXICITYRoute of Exposure Conclusion / RemarksInhalationToxicity: Data available. Minimally Toxic. Based on test data for the material.Irritation: Data available. Negligible hazard at ambient/normal handling temperatures.Based on test data for structurally similar materials.IngestionToxicity: LD50 > 10000 mg/kg Minimally Toxic. Based on test data for the material.SkinToxicity: LD50 > 3160 mg/kg Minimally Toxic. Based on test data for the material.Irritation: Data available. Mildly irritating to skin with prolonged exposure. Based on testdata for structurally similar materials.EyeIrritation: Data available. May cause mild, short-lasting discomfort to eyes. Based on testdata for the material.CHRONIC/OTHER EFFECTSFor the product itself:Vapour/aerosol concentrations above recommended exposure levels are irritating to the eyes and respiratory tract, may cause headaches, dizziness, anaesthesia, drowsiness, unconsciousness and other central nervous system effects including death. Small amounts of liquid aspirated into the lungs during ingestion or fromvomiting may cause chemical pneumonitis or pulmonary edema. Very high exposure (confined spaces / abuse) to light hydrocarbons may result in abnormal heart rhythm (arrhythmias).Concurrent high stress levels and/or co-exposure to high levels of hydrocarbons (above occupational exposure limits), and to heart-stimulatingsubstances like epinephrine, nasal decongestants, asthma drugs, or cardiovascular drugs may initiatearrhythmias.Page 7 of 11 ______________________________________________________________________________________________________________________ Additional information is available by request.CMR Status: None.--REGULATORY LISTS SEARCHED--1 = IARC 1 3 = IARC 2B 5 = ACGIH A12 = IARC 2A 4 = ACGIH ALL 6 = ACGIH A2The information given is based on data available for the material, the components of the material, and similar materials. ECOTOXICITYMaterial -- Expected to be toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.MOBILITYMaterial -- Highly volatile, will partition rapidly to air. Not expected to partition to sediment and wastewater solids.PERSISTENCE AND DEGRADABILITYBiodegradation:Material -- Expected to be inherently biodegradableHydrolysis:Material -- Transformation due to hydrolysis not expected to be significant.Photolysis:Material -- Transformation due to photolysis not expected to be significant.Atmospheric Oxidation:Material -- Expected to degrade rapidly in airOTHER ECOLOGICAL INFORMATIONVOC (EPA Method 24): 6.042 lbs/galDisposal recommendations based on material as supplied.Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.DISPOSAL RECOMMENDATIONSProduct is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervisedincineration at very high temperatures to prevent formation of undesirable combustion products. REGULATORY DISPOSAL INFORMATIONEmpty Container Warning Empty Container Warning (where applicable): Empty containers may containresidue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Emptycontainers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.Page 8 of 11 ______________________________________________________________________________________________________________________LAND (TDG)Proper Shipping Name: PETROLEUM DISTILLATES, N.O.SHazard Class & Division: 3UN Number: 1268Packing Group: IIMarine Pollutant: YesFootnote: Marine Pollutant designation is applicable only if shipped over water.LAND (DOT)Proper Shipping Name: PETROLEUM DISTILLATES, N.O.SHazard Class & Division: 3ID Number: 1268Packing Group: IIMarine Pollutant: YesERG Number: 128Label(s): 3Transport Document Name: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, PG II, MARINE POLLUTANT (Octanes)SEA (IMDG)Proper Shipping Name: PETROLEUM DISTILLATES, N.O.SHazard Class & Division: 3EMS Number: F-E, S-EUN Number: 1268Packing Group: IIMarine Pollutant: YesLabel(s): 3Transport Document Name: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, PG II, (7°C c.c.), MARINE POLLUTANT (Octanes)AIR (IATA)Proper Shipping Name: PETROLEUM DISTILLATES, N.O.SHazard Class & Division: 3UN Number: 1268Packing Group: IILabel(s) / Mark(s): 3Transport Document Name: UN1268, PETROLEUM DISTILLATES, N.O.S., 3, PG IIWHMIS Classification: Class B, Division 2: Flammable LiquidsThis product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations.CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA.Page 9 of 11 ______________________________________________________________________________________________________________________ NATIONAL CHEMICAL INVENTORY LISTING: AICS, IECSC, DSL, EINECS, ENCS, KECI, PICCS, TSCAThe Following Ingredients are Cited on the Lists Below: None.--REGULATORY LISTS SEARCHED--1 = TSCA 4 3 = TSCA 5e 5 = TSCA 12b2 = TSCA 5a2 4 = TSCA 6 6 = NPRITHIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:Revision Changes:Section 04: First Aid Notes was modified.Section 04: First Aid Eye - Header was modified.Section 04: First Aid Ingestion - Header was modified.Section 06: Notification Procedures - Header was modified.Section 01: Company Mailing Address was modified.Section 11: Acute Toxicity Table Header was modified.Section 09: Physical State was modified.Section 11: Inhalation - Header was modified.Section 09: Evaporation Rate - Header was modified.Section 09: Vapour Pressure - Header was modified.Section 07: Handling and Storage-Handling was modified.Section 07: Handling and Storage-Storage Phrases was modified.Section 01: Company Mailing Address was modified.Hazard Identification: Physical/Chemical Hazard was modified.Section 07: Static Accumulator was modified.Section 07: Suitable Materials and Coatings - Header was modified.Section 07: Materials/Coatings - Suitable was modified.Section 07: Materials/Coatings - Unsuitable was modified.Section 09 Viscosity was modified.Section 09 Viscosity was modified.Section 15: National Chemical Inventory Listing - Header was modified.Hazard Identification: Hazards Note was modified.Composition: Component table was modified.Section 16: Health Hazards - Header was modified.Section 16: Physical Hazards - Header was modified.Section 16: CA Contains was modified.Section 16: CA Prepared by - Header was modified.Section 08: Exposure Limits Table was modified.Section 16: Physical Hazards additional was modified.Section 16: First Aid Inhalation - Header was modified.Section 16: Precautions was modified.Page 10 of 11 ______________________________________________________________________________________________________________________ Section 16: Precautionary Label Text - Header was modified.Section 11: Other Health Effects was modified.Section 09: Oxidizing Properties was modified.Section 09: Physical State was modified.Section 13: Regulatory Disposal Information - Header was modified.Section 14: TDG Footnote was added.-----------------------------------------------------------------------------------------------------------------------------------------------------PRECAUTIONARY LABEL TEXT:Contains: NAPHTHA (PETROLEUM), LIGHT ALKYLATEWHMIS Classification: Class B, Division 2: Flammable LiquidsHEALTH HAZARDSRepeated exposure may cause skin dryness or cracking. Danger of serious irreversible effects by a single exposure. If swallowed, may be aspirated and cause lung damage.Target Organs: Nervous system |PHYSICAL HAZARDSFLAMMABLE. Material can accumulate static charges which may cause an ignition.PRECAUTIONSAvoid contact with skin. Prevent exposure to ignition sources, for example use non-sparking tools and explosion-proof equipment. Potentially toxic/irritating fumes/vapour may be evolved from heated or agitated material. Use only with adequate ventilation. Use proper bonding and/or earthing procedures.However, bonding and earthing may not eliminate the hazard from static accumulation.FIRST AIDInhalation: Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.Eye: Flush thoroughly with water. If irritation occurs, get medical assistance.Oral: Seek immediate medical attention. Do not induce vomiting.Skin: Wash contact areas with soap and water. Remove contaminated under contaminated clothing before reuse.FIRE FIGHTING MEDIAUse water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.SPILL/LEAKLand Spill: Eliminate all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop leak if you can do so without risk. Prevent entry into waterways, sewer, basements or confined areas. A vapour-suppressing foam may be used to reduce vapour. Absorb or cover with dry earth, sand or other non-combustible material and transfer to containers.Water Spill: Stop leak if you can do so without risk. Eliminate sources of ignition. Warn other shipping. If the Flash Point exceeds the Ambient Temperature by 10 deg C or more, use containment booms and remove from the surface by skimming or with suitable absorbents when conditions permit. If the Flash Point does not exceed the Ambient AirProduct Name: ISOPAR E SOLVENTRevision Date: 29 Mar 2010Page 11 of 11 ______________________________________________________________________________________________________________________ Temperature by at least 10C, use booms as a barrier to protect shorelines and allow material to evaporate. Seek the advice of a specialist before using dispersants.-----------------------------------------------------------------------------------------------------------------------------------------------------The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted.-----------------------------------------------------------------------------------------------------------------------------------------------------DGN: 5007525 (1006345)-----------------------------------------------------------------------------------------------------------------------------------------------------Copyright 2002 Imperial Oil Limited, All rights reservedPrepared by: Imperial Oil Limited, Solvents。
氰化钠(山奈钠)化学品安全技术说明书MSDS
皮肤接触：
立即脱去污染的衣着，用流动清水冲洗15分钟。
眼睛接触：
立即提起眼睑，用流动清水或生理盐水冲洗至少15分钟。
吸入：
迅速脱离现场至空气新鲜处。呼吸停止者，立即进行人工呼吸(勿用口对口)。必要时进行人工呼吸。给吸入亚硝酸异戊酯，立即就医。
食入：
误服者用1：5000高锰酸钾或5％硫代硫酸钠洗胃。立即就医。
氰化钠；山奈钠
标识
中文名：
氰化钠；山奈钠英文名：Sodium cyanide
分子式：
NaCN分子量：49.02
CAS号：
143-33-9RTECS号：VZ7525000
UN编号：
1689IMDG规则页码：6257
危险货物编号：
61001
理化性质
外观与性状：
白色或灰色粉末状结晶，有微弱的氰化氢气味。
主要用途：
其他
工作现场禁止吸烟、进食和饮水。工作后，彻底清洗。单独存放被毒物污染的衣服，洗后再用。车间应配备急救设备及药品。有关人员应学会自救互救。
用于提炼金、银等贵重金属和淬火，并用于塑料、农药、医药、染料等有机合成工业。
相对密度(水=1)：
1.60饱和蒸汽压(kPa)：0.13/817℃
溶解性：
易溶于水，微溶于液氨、苯、乙醇、乙醚。
燃烧爆炸危险性
避免接触的条件：
接触潮湿空气。
燃烧性：
不燃
危险特性：
本身不能燃烧。受高热或与酸接触会产生剧毒的氰化物气体。与硝酸盐、亚硝酸盐、氯酸盐反应剧烈，有发生爆炸的危险。
毒性危害
接触限值：
中国MAC：0.3mg[HCN]/m3；苏联MAC：0.3mg[HCN]/m3；美国TWA：OSHA 5mg[CN]/m3[皮]；ACGIH 5mg[CN/m3[皮]；美国8TEL：未制定标准
叠氮化钠;三氮化钠-化学品安全技术说明书MSDS
最初浮在水中，可溶。
燃烧爆炸危险性
燃烧性：
摩擦或遇水、热易爆
危险特性：
与水接触能形成氢氯酸。与酸和金属接触发生反应。随时间变化，叠氮化钠能与铜、铅、黄铜、抽送系统的焊料反应，生成具有强爆炸性的叠氮化铅和叠氮化铜等化合物。快速受热或机械震动能引发物质爆炸。腐蚀铝。易燃性(红色)：0；反应活性(黄色)：3
EPA有害废物代码：P105。资源保护和回收法：款261，有毒物或无其他规定。应急计划和社区知情权法：款302极端有害物质，临界规划值(TPQ) 227kg。应急计划和社区知情权法：款304应报告量454kg。应急计划和社区知情权法：款313表R最低应报告浓度1．0％。
叠氮化钠；三氮化钠
标识
中文名：
叠氮化钠；三氮化钠英文名：SODIUM AZIDE分子式：N3Na；NaN3
CAS号：
26628-22-8RTECS号：VY8050000
UN编号：
1687危险货Βιβλιοθήκη 编号：61033理化性质外观与性状：
白色晶体，加热至275～330℃时分解
熔点(℃)：
275(分解)相对密度(水=1)：1.85
侵入途径：
吸入，食入，皮肤及眼睛接触
毒性：
剧毒。LD50：27mg／kg(大鼠经口)
健康危害：
皮肤接触后，发红、疼痛，眼睛接触后发红、疼痛、视力模糊；吸入或食入会引起头昏、虚弱、视力模糊、轻度呼吸短促、血压降低、腹痛、痉挛，严重者昏迷，甚至死亡；本品为新陈代谢抑制剂，干扰酶的氧化，抑制细胞核的磷酸；本品又属诱发突变剂，可破坏神经系统，引起死亡。OSHA：表Z—1空气污染物。健康危害(蓝色)：3
食入：
吸入、食入或皮肤接触该物质可引起迟发反应。确保医务人员了解该物质相关的个体防护知识，注意自身防护。
叠氮化钠 MSDS
标识
中文名：叠氮化钠；三氮化钠
英文名：smide，sodium azide
分子式：NaN3
分子量：271.50
CAS号：7487－94－7
危规号：61033
理化性质
性状：无色至白色六面晶系结晶。
溶解性：溶于水。溶于液氨。不易溶于有机溶剂。
熔点（℃）：
沸点（℃）：
相对密度（水＝1）：1.846
灭火方法：消防人员必须穿戴全身防护服，在有爆炸掩蔽处用雾状水、泡沫灭火机扑救，禁止用砂土。
毒性
大鼠腹腔注射本品3～5 mg/kg，1～5天后表现为无力、震颤、痉挛、青紫、体温下降、昏迷、严重呼吸抑制和死亡。
LD50：27mg/kg（小鼠经口）；18mg/kg（小鼠腹腔）；19mg/kg（小鼠静脉）；60mg/kg（大鼠）；45mg/kg（兔）；
临界温度（℃）：
临界压力（MPa）：
相对密度（空气＝1）：
燃烧热（KJ/mol）：
最小点火能（mJ）：
饱和蒸汽压（KPa）：
燃烧爆炸危险性
燃烧性：
燃烧分解产物：
闪点（℃）：
聚合危害：
爆炸下限（％）：
稳定性：
爆炸上限（％）：
最大爆炸压力（MPa）：
引燃温度（℃）：
禁忌物：酸类、重金属及其盐类。
危险特性：本品与酸类剧烈反应产生爆炸性叠氮酸。与重金属及其盐类形成十分敏感的化合物。受热或撞击会发生爆炸。剧毒，本品比亚硝酸毒性强。许多中毒症状如氰化物。
对人体危害
健康危害：粉尘与溶液能刺激眼睛和皮肤，引起水泡。
急救
眼睛受刺激用大量水冲洗，并就医诊治。皮肤接触先用水冲洗。再用肥皂彻底洗涤。误服立即漱口，急送医院救治。
2危险化学品氰化钠(山奈钠)理化特性表MSDS
沸点（℃）：1496
相对密度（水=1）：1.6
相对密度(空气=1)：无资料
饱和蒸气压(kpa)：0.13（817℃）
燃烧热（kJ.mol）：无意义
临界温度(℃)：
临界压力(Mpa)：
溶解性：易溶于水、微溶于液氨、乙醇、乙醚、苯。
最小点火能（mJ）：无意义
燃爆特性与消防
燃烧性：不燃 闪点（oC）：无意义
储运注意事项
容器必须密封，宜专仓专储，并保持干燥。远离火种、热源。储存于阴凉、通风、干燥处，库温不宜超过30℃，相对湿度不超过80%，切忌与酸类混储混运。应与碱类、铵化合物等分开存放。应严格执行极毒物品“五双”管理制度。搬运时要轻装轻卸，防止包装及容器损坏。分装和搬运作业要注意个人防护。运输按规定路线行驶，中途不得停留。
防护措施
车间卫生标准：中国MAC（mg/m3）：0.3（HCN）[皮]
美国TVL-TWA：OSHA 5mg [CN]/ m3[皮]
美国TLV-STEL： ACGIH 5mg [CN]/ m3[皮]
工程控制 严加密闭，提供充分的局部排风和全面通风。尽可能机械化、自动化。提供安全淋浴和洗眼设备。
呼吸系统防护 可能接触毒物时，必须佩戴头罩型电动送风过滤式防尘呼吸器。紧急事态抡救或撤离时，建议佩戴自给式呼吸器。
氰化钠（山奈钠）理化特性表
标
识
中文名：氰化钠；山奈钠
英文名：sodium cyan2
CAS号：143-33-9
化学类别：金属氰化物
危险性类别：第6.1类毒害品
危规号：61001
UN编号：1689
理
化
性
质
性状与用途：白色或灰色粉末状结晶，有微弱的氰化氢气味。主要用于提炼金、银等贵重金属和淬火，并用于塑料、农药、医药、染料等有机合成工业。
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LiShui Brandt Chemcial Co.,LtdAdd：No.121JinLong Road QiLi,Jinyun,Lishui,ZhejiangTel：0086-0578-*******Fax：0086-0578-*******P.C.：321400 ======================================================================NTA-3Na MSDSThe first part：Chemical NameProduct Name：Nitrilotriacetic acid trisodium saltSynonyms：NTA trisodium salt，Trisodium nitrilotriacetateEINECS：225-768-6CAS No.：5064-31-3Formula：C6H6NNa3O6Molecular Weight：257.08g/molThe second part：Composition/informationIngredient name：Nitrilotriacetic acid trisodium saltIngredients：≥99.0%The third part：HazardsRisk category：1.2Relevant identified uses of the substance or mixture and uses advised againstIdentified uses:Laboratory chemicals,Manufacture of substances SECTION2:Hazards identification2.1Classification of the substance or mixtureClassification according to Regulation(EC)No1272/2008Acute toxicity,Oral(Category4),H302Eye irritation(Category2),H319Carcinogenicity(Category2),H351For the full text of the H-Statements mentioned in this Section,see Section16.Classification according to EU Directives67/548/EEC or1999/45/ECR40Xn Harmful R22Xi Irritant R36Hazard statement(s)：H302Harmful if swallowed.H319Causes serious eye irritation. H351Suspected of causing cancer.Precautionary statement(s)：P281Use personal protective equipment as required.P305+P351+P338IF IN EYES:Rinse cautiously with water for several minutes.Removecontact lenses,if present and easy to do.Continue rinsing.Supplemental Hazard：noneThe fourth part：First aid measuresIn case of skin contact:Wash off with soap and plenty of water.Consult a physician.In case of eye contact:Rinse thoroughly with plenty of water for at least15minutes and consult a physicianIf swallowed:Never give anything by mouth to an unconscious person.Rinse mouth with water.Consult a physician.If inhaled:If breathed in,move person into fresh air.If not breathing,give artificial respiration.Consult a physician.The fifth part：Firefighting measuresHazardous combustionproducts:Carbon oxides,nitrogen oxides(NOx),Sodium oxides Extinguishing media:Use water spray,alcohol-resistant foam,dry chemical or carbon dioxide. Advice for firefighters:Wear self contained breathing apparatus for fire fighting if necessary.The sixth part：Accidental release measuresEmergency treatment:Use of personal protective equipment.Avoid dust formation.Avoid breathing vapors,fumes or gases.Ensure adequate ventilation.Evacuation to a safe area.Avoid breathing dust.The Seventh part：Handling and storageHandling Precautions:Avoid contact with skin and eyes.Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Conditions for safe storage：Store in cool place.Keep container tightly closed in a dry and well-ventilated place.Specific and use(s)：noneThe Eighth part：Exposure controls/personal protection Allowableconcentration:Components with workplace control parametersExposure Controls:Operate in accordance with good industrial hygiene and safety regulations.Before breaks and at the end of the work of their hands.Eye protection:Wear protective chemical safety glasses. Body protection:Wear protective overalls on infiltration.Respiratory protection:When the dust in the air concentrations exceeding have to wear self-absorption filter respirators.Emergency rescue or evacuation,air respirator should be worn.Other protection:Shower and change clothes after work.Attention to personal hygiene.The Ninth part：Physical and chemical propertiesThe main ingredients:Pure productAppearance:white crystalline powder.pH:noneMelting freezing point:400℃Boiling point andboiling range:noneFlash point:noneThe Tenth part：Stability and reactivityReactivity:noneChemical stability:nonePossibility of hazardous reactions:noneConditions to avoid:noneIncompatiblematerials:Strong oxidizing agents,Strong bases Hazardousdecompositionproducts:noneThe Eleventh part：Toxicological informationAcute toxicity:LD50Oral-rat-male and female-1.740mg/kg (OECD Test Guideline401)Skin corrosion/irritation:Skin-rabbitResult:No skin irritation-24h (OECD Test Guideline404)Serious eye damage/eye irritation:Eyes-rabbitResult:Irritating to eyes.-24h (OECD Test Guideline405)Respiratory or skin sensitisation:guinea pigResult:Does not cause skin sensitisation. (OECD Test Guideline406)Germ cell mutagenicity:Mutagenicity(micronucleus test) mouse-maleResult:negativeCarcinogenicity:This product is or contains a component that has been reported to be possibly carcinogenic based on itsIARC,ACGIH,NTP,or EPA classification.The National Cancer Institute(NCI)has found clear evidence forcarcinogenicity.Found positive for carcinogenicity in EPA Genetox program.Limited evidence of carcinogenicity in animal studiesIARC:2B-Group2B:Possibly carcinogenic to humans(Trisodium nitrilotriacetate)Reproductive toxicity none Specific target organ toxicity-single exposure:none Specific target organ toxicity-repeatedexposure:none Aspiration hazard:noneAdditional Information:Repeated dose toxicity-rat-male-Oral-No observed adverse effect level-9mg/kgRTECS:MB8400000The Twelfth part：Ecological informationToxicity:Toxicity to fish flow-through test LC50-Pimephales promelas(fathead minnow)-127mg/l-96hToxicity to daphnia and other aquatic invertebratesstatic test EC50-Daphnia magna(Water flea)-560-1.000mg/l-48h Toxicity to algae static test EC50-Desmodesmus subspicatus (Scenedesmus subspicatus)->100mg/l-72hPersistence and degradability:Biodegradability aerobic-Exposure time28d Result:96%-Readily biodegradable. (OECD Test Guideline302B)Bioaccumulative potential:none Mobility in soil:noneResults of PBT and vPvB assessment:PBT/vPvB assessment not available as chemical safety assessment not required/not conductedOther adverse effects:noneThe Thirteenth part：Disposal considerationsWaste treatment methods:Offer surplus and non-recyclable solutions to a licensed disposal company.Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.Contaminated packaging dispose of as unusedThe Fourteenth part：Transport informationUN number:ADR/RID:-IMDG:-IATA:-UN proper shipping name:ADR/RID:Not dangerous goods IMDG:Not dangerous goods IATA:Not dangerous goodsTransport hazardclass(es):ADR/RID:-IMDG:-IATA:-Packaging group ADR/RID:-IMDG:-IATA:-Environmental hazards:ADR/RID:no IMDG Marine pollutant:no IATA:no Special precautions foruser:noneThe Fifteenth part：Regulatory informationRegulatory Information:For this product a chemical safety assessment was not carried out SECTION15:Regulatory informationThis safety datasheet complies with the requirements of Regulation(EC) No.1907/2006.。