无溶剂PU合成革环保催化剂CUCAT-LCA
丙烯酸 催化剂
丙烯酸 催化剂 丙烯酸催化剂是指在丙烯酸反应过程中能够提高反应速率和效率，并且可以在反应结束后被回收利用的物质。常见的丙烯酸催化剂有以下几种：
1. 酸性催化剂：如硫酸、磷酸等。酸性催化剂能够促进丙烯酸的开环反应，使其转化为丙烯酸铵盐或丙烯酸碱金属盐。
2. 苯基二酚铜（CuPc）催化剂：CuPc催化剂具有高催化活性和选择性，能够在相对低的温度下催化合成丙烯酸。
3. 钛、锑、铋等过渡金属催化剂：这些过渡金属催化剂常用于丙烯酸的氧化反应，能够提高反应速率和丙烯酸的产率。
4. 氧化物催化剂：如二氧化锰、过氧化氢等。氧化物催化剂可以促进丙烯酸的氧化反应，使其转化为丙烯酸酐。
需要注意的是，选择合适的丙烯酸催化剂需要考虑催化剂的活性、选择性、稳定性以及对环境的影响等因素。此外，不同类型的丙烯酸反应可能需要不同的催化剂，因此选择催化剂应根据具体的反应要求进行合理选择。 另外还有一些特殊的丙烯酸催化剂，例如：
1. 酸性离子液体催化剂：离子液体是一种特殊的液体，具有较高的热稳定性和催化活性。酸性离子液体催化剂在丙烯酸的反应中具有较好的催化效果。 2. 银基催化剂：银基催化剂可以在常温下催化丙烯酸的氧化反应，与氧气反应产生丙烯酸酐。
3. 高温催化剂：在高温条件下，常用的催化剂有氨基甲酸钒、氧化铥、钼酸盐等。这些催化剂能够促进丙烯酸的反应，提高反应速率和丙烯酸的收率。
总之，丙烯酸催化剂的选择主要取决于具体反应条件和反应要求。不同催化剂具有不同的催化性能和应用范围。在使用催化剂时，需要充分考虑其活性、选择性、稳定性、成本以及对环境的影响，并结合具体的反应要求进行选择和优化。
聚氨酯阻聚剂NCAT-YC03
聚氨酯阻聚剂 NCAT-YC03
1
不含重金属及多环芳烃、邻苯增塑剂等环保限制成分， 符合国际通用环保法规。
2 芳香族异氰酸酯特别是 MDI 的反应活性较高，双组份原料混合后的可流动时间相对较短，不能满足需要较长可流动 时间的某些产品的工艺要求，阻聚剂 NCAT-YC0
3 正是针对上述问题而研发， 尤其适用于黑料（PAPI ）+蓖麻油体系，具 有如下性能：。
可有效延缓聚氨酯反应的反应速度，使材料具有更长的低粘度操作时间。
YC03 为非反应型阻聚剂，不参与高分子链段的增长反应，不影响材
料物性。
与聚氨酯原料相容性好，不分相、不析出。
不含限制类物质，环保应用不受限。
3 可广泛用于聚氨酯行业要求延长可操作时间的工艺场合，特别推荐 PAPI+蓖麻油的反应体系，如要求良好流平性的地 坪涂料、结构胶、铝蜂窝胶等。
4 适用于各种单、双组分聚氨酯，用于单组分，建议在反应结束后出料前加入搅拌均匀；用于双组份可在任意阶段加入 白料(多元醇组分)中。
一般用量为PU 重量的0.05～0.3%。
使用后务必马上封口密封保存。
5
HDPE 塑料桶， 25/200kg/桶。
储存于干燥阴凉仓库内，避免日光照射和雨淋。
不开封保质期 18 个月，过期后若检验合格仍可使用。
click反应催化剂种类
click反应催化剂种类
Click反应催化剂有多种，其中最常见的是铜催化点击化学（CuAAC）中的铜催化剂。
铜催化点击化学（CuAAC）是一种在末端炔烃和叠氮化物之间的反应中使
用的反应，其中铜（Cu(I)）作为催化剂。
尽管这种反应的偶联效果很好，
但添加铜（Cu(I)）催化剂会对生物分子造成损害。
请注意，Click反应的催化剂种类繁多，除铜催化外，还有其他的金属（如银、金、铁等）或非金属物质（如锡、硫等）作为催化剂。
因此，如需获取更多关于Click反应催化剂的信息，建议查阅化学专业书籍或咨询专业人士。
鲁米诺化学反应中的催化剂
鲁米诺化学反应中的催化剂
鲁米诺化学反应是一种有机合成反应，它通常需要催化剂来促进反应的进行。
以下是可能用于催化鲁米诺化学反应的催化剂：
1. 铂、钯、钯铂合金等贵金属催化剂，在醇或反式醇中催化鲁米诺化学反应。
2. 铜镉铟硫化物（CIS）或铜铟硫化物（CIS）这类复杂的金属硫化物，在无溶剂环境中催化鲁米诺化学反应。
3. 盐酸钴催化剂和乙二胺催化剂，可以在无溶剂环境中催化鲁米诺化学反应。
4. 银蒙脱石催化剂在纳米级别上催化鲁米诺化学反应。
5. 铜、钯、以及钯铜催化剂可以在含氧醇中催化鲁米诺化学反应。
催化剂的选择主要取决于反应条件和所需的产物。
king_brochure 美国金氏催化剂 Nacure
King Industries, Inc. High Performance Products for Coatings, Inks, Adhesives andSealantsNACURE® & K-CURE®Acid & Blocked Acid CatalystsK-KAT®Non-tin Catalysts for UrethanesNACURE® SUPER CATALYSTSCationic Cure of EpoxiesK-FLEX®Resin Modifiers & Reactive DiluentsK-STAY®Rheology ModifiersK-SPERSE®Wetting & Dispersing AdditivesNACORR®Rust & Corrosion InhibitorsDISPARLON®Thixotropes & Surface Control AdditivesTechnology OverviewSince 1932, King Industries has been supplying specialty chemical products to a variety of industries that are performance driven with ever changing requirements. This is especially true for the coatings, inks, adhesivesand sealant markets, the audience for this product guide. While the brochure covers our standard products,this overview has been designed to give you a summary of our areas of technical expertise and to urge youto contact us if you feel we may be of assistance for your specific product needs.CATALYSISWith over four decades of experience in catalysis, King offers the industry’s broadest spectrum of catalysts including:• Acid and blocked acid (latent) catalysts for amino thermoset systems• Non-tin, mercury-free catalysts for urethanes, foams and cast elastomers• Latent and super acid catalysts for the cationic cure of epoxies• Hydrophobic catalysts for the moisture cure of siloxane functional polymers• Powder catalysts for uretdione crosslinked powder coatings and caprolactam blocked isocyanate powder systemsCORROSION INHIBITIONKing offers ferrous and non-ferrous protection for a wide variety of metals and systems based on threeunique platforms:• Modified trialzole compounds• Amino acid derivativesDISPERSANT TECHNOLOGYWhether organic or inorganic pigment/fillers, King offers a variety of dispersant technologies including:• Solvent free polymeric wetting and dispersing agents for solventless and epoxy systems• Sulfonate based dispersants for non-aqueous, solvent-free and powder systemsRESIN MODIFIERS/REACTIVE DILUENTS• Unique polyester polyols based upon low molecular weight, linear, saturated aliphatic structures with pendent hydroxyl groups• Novel, low molecular weight diols with an all urethane backbone• Acetoacetate functional reactive diluentsRHEOLOGY MODIFIERS• Unique sulfonate based modifiers for non-aqueous systems• Polyamide based thixotropes• Hydrophobically modified ethoxylated urethane thickeners for waterborne systemsSURFACE CONTROL ADDITIVESIn addition to King’s internally developed products, the Disparlon® product line represents over 25 years of a technology alliance with Kusumoto Chemical Ltd. of Japan. The Disparlon line offers a broad range of level-ing, defoaming, anti-popping and anti-cratering additives for aqueous, solvent, solventless, UV and powder systems.© All materials copyrighted 2006, King Industries, Inc., Norwalk, CT, USAPRODUCT LINESSYSTEMHigh SolidsWaterborneConventionalPowderUVSECTION I - CATALYSTSNACURE® & K-CURE®ACID & BLOCKED ACID CATALYSTS 3 K-KAT® NON-TIN CATALYSTS FOR URETHANES9NACURE® SUPER CATALYSTS LATENT CURE OF EPOXIES13SECTION II - RESIN MODIFIERS/REACTIVE DILUENTSK-FLEX®SPECIALTY PRODUCTS 15 K-FLEX®POLYESTER POLYOLS 17K-FLEX®URETHANE DIOLS21SECTION III - SPECIALTY ADDITIVESK-STAY®RHEOLOGY MODIFIERS23 NACORR®RUST & CORROSION INHIBITORS 25 K-SPERSE®WETTING & DISPERSING ADDITIVES 28 DISPARLON® THIXOTROPES30 DISPARLON® DEFOAMERS & ANTI-POPPING AGENTS35 DISPARLON® DISPERSANTS,ANTI-FLOOD & ANTI-FLOAT AGENTS 36DISPARLON® LEVELING & ANTI-CRATERING ADDITIVES37CONTACT INFORMATION: PAGEAPPLICATION CHART Centerfold Table of Contents and System Reference ChartWorld Headquarters King Industries, Inc.Science Road, CT 06852 USA(800) 431-7900 or (203) 866-5551 (203) 866-1268coatings@European Sales Office King International EuropeNoordkade 64, 2741 EZ Waddinxveen The Netherlands+31 182-631360 +31 182-621002 info@kingintl.nlNACURE ® & K-CURE ®Acid & Blocked Acid CatalystsCatalyst By Acid Type Acid Type Acid Catalysts Blocked Catalysts NACURE 155 NACURE X49-110 NACURE 3525NACURE 3327 NACURE 3483 NACURE 1051 NACURE 1323 NACURE 1419NACURE 1557 NACURE 1953NACURE 5076 NACURE 5225NACURE 5414NACURE 5528 NACURE 5925 K-CURE 1040 K-CURE 1040W NACURE 4054 NACURE XC-C207 NACURE 4167 NACURE XP-297 NACURE 4575 NACURE 2107 NACURE 2500 NACURE 2501NACURE 2522 NACURE 2530 NACURE 2547 NACURE 2558AAP & PAPAlkyl Acid Phosphate Phenyl Acid Phosphate Why Use Catalysts? Today’s need for high solids and waterborne coatings requires greater use of high reactivity, lowviscosity resins and crosslinkers. Conversion ofthese systems into tough, chemically resistant, high performance coatings at reduced cure temperatures can be accomplished with the use of a catalyst. Acrylics, alkyds, epoxies and polyesters with reactive functional groups, such as hydroxyl, carbamate or amide can be reacted with melamine, urea and benzoguanamine crosslinkers. Selection of the proper catalyst can facilitate the crosslinking reaction resulting in the following benefits:• Shorter cure schedules• Lower cure temperatures for thermoset highsolids and waterborne coatings• Improved hardness, gloss, humidityand corrosion resistance • Improved mechanical propertiesKing Industries continues to develop catalysts to meet the ever expanding needs of a rapidly changing market.Free Acid Or Latent Catalyst? While acid catalysts provide the fastest cure and lower curing temperatures, blocked catalysts aretypically chosen for systems requiring greater package stability. In addition, troublesome catalyst-pigment interaction can be reduced oreliminated.As can be seen in the table which follows, King’s catalyst line is based upon a variety of acids shownin their structural form. The middle column denotesthe free acid versions while the far right columnshows amine blocked or covalently bondedderivatives for applications requiring extended package stability.Catalyst SelectionThe first thing to consider when selecting a catalyst is what type of crosslinking agent is being used. High solids and waterborne coatings are typicallyformulated with monomeric crosslinkers such as hexa(methoxymethyl)melamine (HMMM) or mixed ether melamine; reaction of these crosslinkers with hydroxy or carbamate functional groups is best achieved with strong acid catalysts like DNNDSA or p-TSA.N A C U R E & K -C U R E A C I D & B L O C K E D A C I D C A T A L Y S T SSO 3H C 9H19HO 3S H 19C9DNNDSAC 9H 19SO 3H H 19C 9DNNSA SO 3HC 12H 25DDBSA CH3SO 3HpTSAMore reactive crosslinkers, which are more polymeric but contain high levels of -NH groups, respond better to a weaker acid such as acid phosphates or low dosages of amine blocked sulfonic acids. The chemical structure of the catalyst, as well as the quantity used, can have a profound impact on such film properties as adhesion, corrosion resistance, flexibility and impact resistance. These differences are apparent not only among different acid types but also among different products within the same chemical family. The table that follows matches the type of crosslink-ing agent and the acid catalyst most suitable for each class.Formulating ConsiderationspH Range - Both fully and partially alkylated amino resins are reactive under acidic pH conditions andrelatively stable in the neutral range. To acceleratethe reaction between binder resin and amino crosslinker, it is necessary to reduce the pH of thesystem through the addition of an acid catalyst. Forfully alkylated melamines, a pH of 3 or lower isrequired to induce cure. Partially alkylated melamines of the high imino type will react in the pH range of 3 to 5.Blocking the acid catalyst with an amine will effectively raise the pH, inhibiting the cure at low temperatures and allowing the formulation of stable one package systems. Amine blocked catalysts canCrosslinking Agent General Acid Category Acid Types Fully alkylated monomeric M/F resins: Fully methylated Fully butylated Mixed ethers Urea formaldehyde resins Benzoguanamine resinsGlycoluril resinsStrong Acids pKa<1 Highly alkylated, high imino M/F resins Partially alkylated poly-meric M/F resinsWeak Acids pKa 1-3Metal SaltsCarboxylic Acid PhosphatesRELATIVE ACID STRENGTH:p-TSA>DNNDSA>DDBSA>DNNSA>Phosphates>CarboxylatesP-TSA DNNDSADDBSADNNSA be prepared at virtually any pH, but usually the best combination of cure and package stability is obtained in the 6.5-7.5 range. Cure Schedule and Temperature Generally, the time and temperature conditions of cure can prescribe the correct catalyst for the application. Strong acids with typical pKa strengths of approximately 0.5-0.7 should give equivalent rates of cure at equal molar concentrations of the acid group. Amine neutralized or polymeric blocked catalysts will demand higher temperatures for full activation, and the pKa of the amine and type of polymer attached to the acid will also influence therate of reactivity. On the next page a table can be found that providesthe various cure profiles for acid catalysts basedupon a 30 minute cure schedule for a typicalResin/HMMM (75/25 ratio) coating. Likewise, priorto the blocked catalyst descriptions, a graph showscure profiles for blocked catalysts under the same conditions.In both cases, the data should be viewed as astarting point and a ladder study should be conducted to optimize the formulation.Quick Formulating Tips Do not over catalyze. Using too much catalyst canbe a costly mistake and one that can cause film properties to suffer significantly.As with any component in a coating, the level, method and order of addition may mean the difference between formulation success or failure. When incorporating catalysts, the following factors should be considered: method of mixing, solvents used, pigments used, pH sensitivity of the resins, temperature at time of addition, substrate and stability/pot life requirements. While some general recommendations can be found in the product description charts, feel free to contactKing’s Technical Service Department at (800) 431-7900 or by email coatings@ for assistance in selecting the proper catalyst for your particular application. N A C U R E & K -C U R E A C I D & B L O C K E D A C I D C A T A L Y S T S4NACURE ® & K-CURE ® Acid CatalystsPRODUCT Acid Type Volatile % Active Acid # lbs./gal. Gardner Color Minimum Cure*Attributes/UsesNACURE 155DNNDSA Isobutanol 55 112-116 8.16 12 max. RT General purpose catalyst. Excellent water, detergent and salt spray resistance.NACURE 1051 DNNSA2-Butoxyethanol50 60-64 8.16 N/A 125°C Best water and corrosion resistance. Recommended for high temperature applications on metal. NACURE 5076 DDBSA Isopropanol 70 130-140 8.27 4 RT Complies with FDA 21 CFR, Sec. 175.300 (b) (3) xiii (a&b)NACURE 4054 AAP Isobutanol50155-165 7.49 1 110°C Weak acid for high NH/polymeric melamines and phenolic crosslinkers.K-CURE 1040 p-TSA Isopropanol 40 130-140 8.25 1 RT Highest gloss. Fastest cure. Excellent weathering and exterior durability.K-CURE 1040W p-TSA Water 40 130-140 9.40 2 RT As above, non-flammable for waterborne applications.K-CURE 129B Mixed AcidsMethanol/n-Butanol50 200-210 8.90 1 RT Fastest cure.Wood and paper coatings.NACURE XC-C207Alkyl Acid Phosphate10065011.8180˚CBroad solubility and excellent ad-hesion, Good package stabilityRT= Room Temperature, cures are possible at catalyst levels of 4-10% *30 minute cure schedule – Resin/Urea (60/40 ratio)NACURE 4046 Phosphate Xylene/Butanol 17 100-112 7.60 2 80°C Complies with FDA 21 CFR, Sec. 175.300 (b) (3) xiii (a&b) Acid Catalysts - Suggested Starting LevelsProduct 70°C90°C110°C125°C150°C175°C200°CNACURE 155 4.7% 2.7% 1.6% 1.2% 0.6% 0.5% 0.3% NACURE 1051 NR NR NR 2.2% 1.4% 0.9% 0.6% NACURE 5076 4.5% 2.5% 1.5% 1.1% 0.7% 0.5% 0.3% NACURE 4054 NR NR 4.0% 2.0% 1.0% NR NR K-CURE 1040/W 4.2% 2.3% 1.4% 1.0% 0.7% 0.4% 0.3% K-CURE 129B 2.6%1.5%0.9%0.7%0.4%0.3%0.2%30 Minute Cure Schedule, catalyst as supplied on Total Resin Solids, Resin/HMMM (75/25 ratio), NR=Not recommendedNACURE 4046 NR 3.0% 2.0% 1.5% 1.0% 0.8% 0.5% NACURE XC-C2072.5% 2.0% 1.0% 0.75% 0.5% 0.3% 0.2%Acid Catalysts - Typical Use LevelsThe chart below can be used as a starting point guideline. The suggested cure schedules are based upon a 30 minute cure for typical Resin/HMMM (75/25 ratio) coatings. The suggested starting levelis the percentage of catalyst based on total resin solids.Once a schedule is established, a ladder study should be conducted to optimize the formulation.N A C U R E & K -C U R E A C I D & B L O C K E D A C I D C A T A L Y S T SNACURE® Blocked Acid CatalystsPRODUCT Acid TypeVolatile%ActivepH lbs./gal. GardnerColorMinimumCure*Attributes/UsesNACURE X49-110 DNNDSAIsobutanolIsopropanol25 6.5 - 7.5 7.55 10 max. 90°CBest overall properties. Excellentwater and corrosion resistance, andadhesion.NACURE 3525 DNNDSAIsobutanolIsopropanol25 7.0 - 8.5 7.65 10 max. 120°CBetter solubility than X49-110,slower curing. Good salt sprayresistance and adhesion.NACURE 3327 DNNDSAIsobutanolIsopropanol25 6.5 - 7.5 7.40 N/A 107°CBetter solubility than other amineblocked DSA catalysts.NACURE 3483 DNNDSAXylene25 N/A 8.20 10 max. 120°CLow conductivity for electrostaticspray. High gloss, reduced pigmentinteraction.NACURE 1323 DNNSAXylene 21 6.8 - 7.5 7.43 N/A 150°CHigh temperature applications.Excellent solubility in aromaticand aliphatic solvents.NACURE 1419DNNSAXylene/MIBK 30 N/A 7.74 N/A 150°CElectrostatic spray. High bakeapplications for water, detergentand salt spray resistance.NACURE 1557DNNSAButanol2-Butoxyethanol25 6.5 - 7.5 7.56 N/A 150°CResolves solvent popping in thickfilms. Excellent humidity anddetergent resistance.NACURE 1953DNNSAButanol2-Butoxyethanol25 6.5 - 6.9 7.48 N/A 150°CHigh bake amino crosslinkedsystems such as coil coatingsand metal decorating.NACURE 5225DDBSAIsopropanol 25 6.0 - 7.0 7.40 2 120°CBest solubility in high solidsenamels. Good solubility inaliphatic solvents.NACURE 5414 DDBSAXylene 25 N/A 8.30 4 130°CPolymeric blocked. Excellentelectrostatic spray (non-aqueous).Good intercoat adhesion.NACURE 5528DDBSAIsopropanol 25 7.0 - 8.0 7.50 2 120°CBroad solubility.Excellent color stability.NACURE 5925DDBSAIsopropanol 25 7.0 - 7.5 7.50 2 120°CComplies with FDA 21 CFR, Sec.175.300 (b) (3) xiii (a&b)NACURE 2107p-TSAIsopropanol 25 8.0 - 9.0 7.57 1 90°CGood metal mark resistance.NACURE 2500p-TSAIsopropanol 26 6.0 - 7.0 8.15 1 80°CLow temperature cure.Excellent stability.NACURE 2501TSAMethanolIsopropanol25 6.0 - 7.2 8.01 1 80°CSlightly higher resistivity than 2500.Better ketone solubility.NACURE 2522p-TSAIsopropanolMethanol25 3.5-3.9 7.85 1 80°CPartially neutralized to provide fastercure and reduce wrinkling at highercuring temperatures.NACURE 2530p-TSAMethanolIsopropanol25 5.7 - 6.5 7.90 1 80°CLow temperature cure.Low tendency to yellow or wrinkle.More Blocked Catalysts Continued On Next PageNACURE&K-CUREACID&BLOCKEDACIDCATALYSTSPRODUCTAcid Type Volatile % Active pHlbs./gal.Gardner ColorMinimum Cure* Attributes/UsesNACURE 2547 p-TSA Water 258.0 - 9.0 9.18 1 107°C Readily soluble in waterborne systems. Solvent-free.NACURE 2558 p-TSA Ethylene Glycol 25 3.5 - 4.5 9.64 1 80°C Excellent control of popping and blistering.NACURE XC-8224Mixed Acids Water258.0 - 9.09.08180°CFast cure response and solubility in waterborne coatings.NACURE 4167 Acid PhosphateIsopropanol Isobutanol25 6.8 - 7.5 7.16 2 80°C Blocked phosphate for high NH/polymeric melamines.NACURE XP-297 Acid PhosphateWater Isopropanol25 6.5 - 7.5 8.20 2 90°C Aqueous systems using high NH/polymeric melamines.NACURE 4575Acid PhosphateMethanol Butanol257.0 - 8.08.302100°CHigh gloss. Superb storage stability with polymeric amino resins.NACURE ® Blocked Acid Catalysts - ContinuedTypical Use Levels - Blocked CatalystsThe chart below can be used to as a starting point reference for blocked catalysts. Cure schedules and use levels are based upon a 30 minute cure for typical Resin/HMMM (75/25 ratio) coatings. The percent of catalyst shown is as supplied on TRS.Once a temperature and use level is established from the chart, a ladder study should be conducted to optimize the formulation.Typical Use Levels for Blocked Catalysts Based On Cure Temperature30 Minute Cure - 75/25 Ratio - Resin/HMMM, % Catalyst (as supplied) on Total Resin Solids100 150 200 250 300 350 400 °F(38) (65) (93) (121) (150) (177) (204) °CBlocked p-TSA - (25% Active) 5%1.6% 0.4%Blocked DDBSA - (25% Active)3%1.3% 0.8%Blocked DNNDSA - (25% Active)6% 2.4% 0.7%Blocked DNNSA - (21% Active)3% 2% 1.1%HydrophobicHydrophilicN A C U R E & K -C U R E A C I D & B L O C K E D A C I D C A T A L Y S T SCatalyst Selection by Applications & PerformanceApplication areas for acid and blocked acid catalysts cover a broad spectrum of end-uses, from medium to high solid solvent-based formulations to water reducible and latex systems. Typical applications are summarized below.The cross reference chart shows you specific performance properties to types of catalysts. As always, our technical service staff can assist you with meeting your particular requirements .ApplicationSolvent SystemsWaterborne SystemsAppliancesNACURE 1323, NACURE X49-110 NACURE 1419, NACURE 3483 NACURE 155, NACURE X49-110NACURE 3525 Automotive BasecoatNACURE 5525, NACURE 2500 NACURE 5528, NACURE 3525NACURE 2500, NACURE 5076 NACURE 2547, NACURE 5528Automotive Topcoat/Clearcoat NACURE 5225, NACURE 2500, 2522, 4054, 5414 & 5528 NACURE 2500, NACURE 5076NACURE 2547, 5528, 5225 and 4167 Can NACURE 5925, NACURE 155NACURE 3483, NACURE 3525 & 4046 NACURE 155, NACURE 5925NACURE 5076 Coil (PCM) NACURE 1051, NACURE 1323 NACURE 1419, NACURE 2107 & 4046NACURE 2500, NACURE 5225NACURE X49-110InksNACURE 155, NACURE 1051K-CURE 1040 NACURE 155 K-CURE 1040W Metal Decorating NACURE 155, K-CURE 1040K-CURE 129B NACURE 155 K-CURE 1040WPaper Coatings K-CURE 1040, K-CURE 129BNACURE 155 K-CURE 1040W, NACURE 155NACURE 2530 Primers NACURE X49-110, NACURE 3525NACURE 1323 NACURE 155, NACURE X49-110NACURE 3525 Wood FinishingNACURE 155, K-CURE 1040K-CURE 129BNACURE 155, K-CURE 1040WNACURE 2530Catalyst Selection by Performance PropertiesPerformance Property Adhesion ▲ ■ ■ Chip Resistance ▲ ■ Corrosion Resistance ▲ ▲ Detergent Resistance ■ ▲ Electrostatic Conductivity ■ ▲ ■ FDA 175.300 ▲ Film Flexibility ▲ ■ Film Hardness ■ ▲ Flow & Leveling ■ ▲ ■ High Gloss▲ ▲ Moisture Resistance ▲ ▲ ■ Package Stability ▲ ■ QUV Resistance▲■KEY: ▲ - Highly Recommended ■ - RecommendedDNNDSA DNNSA DDBSA p-TSA AAP/PAPN A C U R E & K -C U R E A C I D & B L O C K E D A C I D C A T A L Y S T SK-KAT ® Non-Tin Catalysts for PolyurethanesIntroductionAmines and organometallic catalysts are commonlyused as accelerators in the polyol/isocyanate reac-tion to produce polyurethanes. When formulating a polyurethane coating, it has been found that bothperformance and properties can be affected by the choice of catalyst.Amine catalysts are typically used in foam applica-tions. Their catalytic activity accelerates the reactionof aromatic isocyanates with water and alcohols, releasing carbon dioxide. Use of amines in coatingapplications, however, is generally not acceptablebecause of their negative effect on film properties,especially yellowing.King Industries has developed a range ofcatalysts for isocyanate-hydroxyl crosslinking that are based on bismuth, aluminum and zirconium metal chelates and complexes. These K-KAT cata-lysts are not only environmentally more acceptable than organotin compounds, but can offer perform-ance advantages as well.PRODUCT Composition%Non-volatilelbs./gal.Typical Use Levels(% on total resin solids) 2K Blocked NCO Attributes/UsesK-KAT 348 Bismuth Carboxylate7510.00.03-0.1 0.5-2Similar to DBDTL, particularly effective for blocked isocyanates and elastomers K-KAT XC-B221 Bismuth Carboxylate1009.40.03-0.1 0.5-2Improved hydrolytic stability. Especially effective in cationic electro-coatings.K-KAT XC-C227 Bismuth Carboxylate 88 9.3 0.05-0.5 0.5-2Resistant to hydrolysis. Im-proved potlife & high reactivity in forced dried applications K-KAT 4205 Zirconium Chelate 2,4 - PentanedioneN/A 8.11-2 NotRecommendedGood potlife, recommended for ambient cure (not bake/force dry)K-KAT 5218 Aluminum ChelateComplex Reactive Diluent 659.11-2 NotRecommendedExcellent potlife with 2,4, pentanedioneK-KAT 6212 Zirconium Complex Reactive Diluent 95 8.20.3-2 NotRecommended Fast cure, waterborne systems Plural componentK-KAT XK-602 Metal Complex100 Powder 1.0-5.0 Powder CoatingsUretdione crosslinked andcaprolactam blocked isocyanate powder coatings.K-KAT XK-604Organometallic Complex100 10.0 0.1-0.5%100% solids 2K urethanes for cast elastomers. Similar cure profile to mercury catalysts.K-KAT A209 Zirconium Complex Reactive Diluent 35 7.9O0.05-1 NotRecommendedFast cure, waterborne, slow reacting systems Resin synthesisSpecific K-KAT catalysts can be selected to enhance these advantages, including reduced water reaction, improved pot life, faster cure, improved catalysis in cationic electrocoating and reduced hydrolysis of ester groups. Unique Non-tin Catalysts K-KAT 348, XC-B221 and XC-C227 - Bismuth Carboxylate Catalysts Provide properties similar to DBTDL. They are particularly effective in blocked isocyanate and elastomer systems.K-KAT 4205, 6212, and A209 - Zirconium Catalysts can offer fast, selective catalysis of 2K urethane coatings. K-KAT 5218 - Aluminum Chelate Catalyst is used in 2K systems where extended potlife is desired.K-KAT XK-602 - Metal complex designed for powder coatings. K-KAT XK-604 - Mercury Replacement Catalyst based on a proprietary organometallic complexes.K -K A T C A T A L Y S T S F O R U R E T H A N E SK-KAT Products and PerformanceK-KAT 348K-KAT 348 is a bismuth carboxylate which can be used in blocked isocyanate and two component urethane systems offering: • Excellent exterior durability • Non-yellowing characteristics • Excellent gloss retention K-KAT 348 Vs. DBTDL - YellowingA good indicator of resistance to yellowingisb* Color Value where a higher number corresponds to increased yellowing. The graph below demonstrates that similar QUVdurability is obtainable with K-KAT 348 as compared to DBTDL. K-KAT 4205K-KAT 4205 is a liquid zirconium complex which isan effective catalyst for 2K urethane coatings offering: • Fast tack free time • Excellent viscosity stability/pot life • Excellent exterior durability • Use levels at low metal concentrations K-KAT 4205/DBTDL TACK-FREE TIME COMPARISON Polyester/Isocyanate , Ambient Cure, Equal Pot LifeK-KAT 4205 (0.0012% metal) DBTDL (0.0042% metal) 0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 HOURSK-KAT 5218K-KAT 5218 can be used in both baked and ambient cured 2K urethane systems offering:• Synergy with pot life extenders such as2,4 - Pentandione• Excellent exterior durabilittyK-KAT 5218/DBTDL POT LIFE COMPARISON 2K Polyester/HDI Trimer, Ambient Cure, Equal Dry TimeK-KAT XC-C227K-KAT XC-C227 offers excellent resistance to hydrolysis compared to conventional bismuth carboxylate catalysts as shown in the photos below.K-KAT XC-C227 Conventional Bismuth CatalystTwo Months Humidity Exposure Open ContainerBismuth carboxylate catalysts will also hydrolyze when diluted with solvents that contain trace amounts of water.K -K A T C A T A L Y S T S F O R U R E T H A N E SQUV STUDY - K-KAT 348/DBTDLAcrylic/Blocked NCO - 30 Minutes/138˚CK-KAT A209 K-KAT A209 is a concentrated version of 6212 that is best suited for slower curing formulations. Typical uses include:• Slow curing formulations such as IPDIcrosslinked coatings• Resin synthesis• NCO terminated prepolymersK -K A T C A T A L Y S T S F O R U R E T H A N E SK-KAT XK-602K-KAT KX-602 was specifically designed to for use in uretdione crosslinked powder coatings to lower cure temperatures while preventing yellowing which is a common problem associated with standard amine based catalysts used in these coatings. These performance characteristics are shown in the table which follows.Polyester/Uretdione Powder CostingTest results show the use of K-KAT XK-602 can lower cure temperatures and even under overbake curing conditions reduce yellowing.TEST RESULTS(Overbake)Control1.25% XK-602 On TRS 5.0% XK-602 On TRSSubstrate Initial Cure Schedule 20 minutes at 200˚ 20 minutes at 170˚C30 minutesat 150°C b*0.12 -0.2 0.43 White index 89.5 90.8 90.8 Yellow index -0.8 -1.7 -0.03 1st Overbake Schedule (∆) 20 minutes at 200˚C 20 minutes at 170˚C 30 minutes at 150°C b*2.5 (2.4) -0.05 (0.20) 0.5 (0.1) White index 79.2 (10.3) 90.1 (0.7) 90.3 (0.5) Yellow index3.7 (4.5) -1.1 (0.6) 0.16 (0.2) 2nd Overbake Schedule (∆) 20 minutes at 200˚C 20 minutes at 170˚C 20 minutes at 200°C b* 3.3 (3.2) 0.09 (0.3) 3.2 (2.8) White index 73.8 (15.7) 89.3 (1.5) 76.9 (13.9) BONDERITE 1000 With the use of an acid scavenger, K-KAT XK-602 has shown to be effective at temperatures as low as 140˚C. K-KAT XK-604 K-KAT XK-604 is based on a blend of proprietaryorganometallic complexes and is highly effectivewhen used to cure cast elastomers, such as 100% solids 2K urethanes. As shown in the profile belowK-KAT XK-604 offers a similar cure profile to mer-cury catalysts without the environmental and toxicity issues.In addition to offering good latency before snap curing, XK-604 can also provide improved post-gel cure compared to other mercury replacement cata-lysts. Gel Cure Profile K-KAT XK-604 to Mercury Catalyst K-KAT XK-604Mercury CatalystK-KAT 6212 K-KAT 6212 is recommended for use in two com-ponent plural gun or in-line mixing applications pro-viding advantages as follows. • Rapid cure response and fast tack free time • Excellent low temperature cure response • High selectivity for - NCO/OH reaction overthe NCO/water reaction K-KAT 6212 must be added to the isocyanate com-ponent.。
无味综合促进剂EG-4
格雷促无味橡胶综合促进剂EG-4 改善合成橡胶如EPDM，NBR,SBR等橡胶制品气味
产品说明无味橡胶综合促进剂EG-4用多种无味环保型橡胶促进剂配合而成。
主要成分为二硫代氨基甲酸盐，苯并噻唑，秋兰姆和硫脲类传统促进剂的增效组合，经多道工艺加工而成。
符合欧盟ROHS指令于国家环保产品质量监督检验中心检测达标的相关指标。
VOC检测
指标小于2.5级，达到国际先进水平。
产品广泛应用于高端橡胶密封条，鞋材等。
产品性能促进剂EG-4在胶料中分散性佳，提高EPDM的硫化速率，在橡胶制品中可以避免吐霜现象。
促进剂EG-4具有较低的气味。
促进剂EG-4能让EPDM快速硫化的不喷霜特殊促进剂，尤其适用于挤出制品，例如型材和
密封条．
用量使用本产品无需再加硫磺和促进剂，建议添加量为6.0-9.0ph r
应用各种模压和挤出制品、发泡橡胶制品、硬质橡胶，和食品接触的橡胶制品。
包装25 公斤装，牛皮纸袋。
存稳定性阴凉、干燥处，原包装密封存放1年。
卡斯特催化剂
卡斯特催化剂礼尔科穆克斯催化剂（Leucocmes catalysts）由德国化学家礼尔科穆克斯（Leucocmes）于1915年发明，它是有机化学反应中最重要的催化剂之一。
它是一种单硫醇催化剂，由苯乙醇和硫酸铵两种材料经过水解反应合成而成。
礼尔科穆克斯催化剂最好地用于不对称氧化反应，包括醛氧化反应和醇氧化反应。
礼尔科穆克斯催化剂具有优势的结构和性能特点，即低活性和精确的取向性，这使其适用于多种有机反应，如不对称氧化、缩合、加氢和交换反应等。
礼尔科穆克斯催化剂可以极大地提高有机反应的速度，并能够有效地增加反应产物的产量，是有机合成的重要工具。
礼尔科穆克斯催化剂的使用主要有4个步骤：选择反应组份，组装反应混合液，加入催化剂，和控制反应温度。
首先，应根据反应类型，选择正确的反应物组份。
其次，将反应物组件加入混合液中，并以规定的pH值和比例进行混合，并加入礼尔科穆克斯催化剂。
然后，控制反应温度，使其适宜。
最后，调整溶液pH值，使催化剂处于最佳性能状态，完成反应。
礼尔科穆克斯催化剂在有机合成反应中的应用日益增加。
它在芳香酸缩合反应中的应用成功提高了反应速度和产物产率，缩短了反应时间。
礼尔科穆克斯催化剂在类似氧化还原反应中也具有优势，可以显著提高反应速度和产率。
有一种传统的有机合成反应——格蒙德加氢反应，采用礼尔科穆克斯催化剂的运用能够实现更高的产物多样性和更高的反应效率。
礼尔科穆克斯催化剂的发明已经有100多年的历史，它的应用将推动有机反应的发展。
它的结构优势和可调性优势使它成为有机合成反应的理想选择。
礼尔科穆克斯催化剂今后依然会有更多的应用，它能够在有机反应中发挥重要作用，促进有机合成反应的发展。
齐格尔纳塔催化剂合成
齐格尔纳塔催化剂合成
齐格勒-纳塔催化剂（Ziegler-Natta Catalyst）是由意大利化学家Giulio Natta和德国化学家Karl Ziegler在20世纪50年代共同开发的一种用于聚烯烃合成的高效催化剂。
这类催化剂主要用于生产高分子量、立体规整度高的聚合物，尤其是聚乙烯和聚丙烯。
齐格勒-纳塔催化剂的主要成分包括：
1. 主催化剂：通常采用四氯化钛（TiCl4）或者其与镁化合物形成的络合物，如镁三甲基氯化钛（TiCl3-MgCl3）等。
2. 助催化剂：早期使用的是烷基铝化合物，如三乙基铝（Al(C2H5)3），也称为TEA或Et3Al，它们可以激活主催化剂，并提供引发烯烃聚合所需的活性中心。
合成过程大致如下：
-主催化剂TiCl4与MgCl2反应生成活性中间体。
-助催化剂如Al(C2H5)3加入到体系中，进一步与中间体作用，形成有催化活性的络合物。
-在适当温度和压力下，这些催化剂能够非常有效地引
发乙烯或丙烯等α-烯烃进行定向聚合，生成具有高度立体选择性的聚烯烃产品。
由于齐格勒-纳塔催化剂的重大发现，Karl Ziegler 和Giulio Natta 共同获得了1963年的诺贝尔化学奖。
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无溶剂 PU 合成革环保催化剂 CUCAT-LCA
1．性状描述
微黄透明液体，色度（Fe-Co）≤6；密度 1.072g/cm3(25℃)，粘度
30±10mPa.s(25℃)；具特殊化合物气味，易溶于常用聚氨酯原料如聚
醚、聚酯等。 不含有机锡等限制金属及多环芳烃、邻苯增塑剂等限制成
分，符合国际严格环保法规，是替代有机锡、铋等催化剂的理想取代品。
2．独特性能
CUCAT-LCA 是适用于无溶剂 PU 合成革浆料的新一代高效催化剂，不同
于常用铋锡类催化剂，具有如下特性：
⚫ 不含锡金属，环保性确保满足国内外市场。
⚫
催化活性适配辊涂工艺，具热敏性。操作期充裕，浆料流平性好，
高温后熟化快。解决添加有机铋类催化 剂致体系前期粘度上升过
快、物料流动性差、后熟化慢弊端，缩短 PU 浆料高温下（80-
120℃）的成型和 不沾手时间。
⚫
不降低浆料成膜后的撕裂强度和伸长率，解决成品皮革崩线问题。
CUCAT-LCA 是靶向生成氨基甲酸酯化学 基团的凝胶类催化剂，不产
生过多副反应和交联，相比无溶剂 PU 浆料领域使用产生交联副反
应的热敏胺类 催化剂，PU 整体力学性能特别是撕裂强度和扯断伸
长率提高了 30%以上。
3．应用领域
推荐用于无溶剂 PU 合成革浆料的催化剂。
4．使用说明
使用时加入多元醇（Polyol，P 料）组份，搅拌均匀即可，建议生产现场
添加。不建议加入异氰酸酯（ISO，I 料）组份中，有凝胶可能性危险，如
必须加入异氰酸酯组分务必先行适用性试验。 使用量与产品体系和配方等
有关，一般用量为 P 料重量的 0.05～0.5% 。 平常使用后注意必须马上
封闭罐口，避免敞开放置。
5．规格储存：
HDPE 塑料桶，25/200kg/桶。储存于干燥阴凉仓库内，避免日光照射和雨
淋。不开封保质期 24 个月，保质期后如检测催化活性未降低，仍可按合
格品使用。
特别声明：我们所提供之说明及技术建议（无论是口头、书面或通过实验途径）均不构成任何保证，并在有关第三方权益出现时仍然适用。我们的建议并不表示客户可以免去验证我方建议的有效性及试
验我方产品在相关使用过程中的适用性的责任。客户在我方的技术建议的基础上使用我们产品的方法、过程以及由此生产出的产品已超过我方可以控制的范围，因此客户应自己负责。并且，如果发生任
何赔偿争议，我们只负责承担我们的产品本身的价值，不承担任与我们的产品牵连的其他任何附加的价值或赔偿.(2018-02)