X-ray properties of the Composite SeyfertStar-forming galaxies
激光熔覆马氏体

第27卷第2期粉末冶金材料科学与工程2022年4月V ol.27 No.2 Materials Science and Engineering of Powder Metallurgy Apr. 2022DOI:10.19976/ki.43-1448/TF.2021090激光熔覆马氏体/铁素体涂层的组织与抗磨耐蚀性能张磊1, 2,陈小明1, 2,霍嘉翔1,张凯1, 2,曹文菁1, 2,程新闯3(1. 水利部产品质量标准研究所浙江省水利水电装备表面工程技术研究重点实验室,杭州 310012;2. 水利部杭州机械设计研究所水利机械及其再制造技术浙江省工程实验室,杭州 310012;3. 绍兴市曹娥江大闸管理局,绍兴 312000)摘要:为提高液压活塞杆的耐腐蚀和抗磨损性能,在45号钢表面采用激光熔覆技术在不同激光功率下制备具有马氏体/铁素体组织的Fe基合金熔覆层。
利用X射线衍射仪、扫描电镜、X射线能谱仪等手段表征涂层的物相组成、微观形貌和元素分布,采用维氏硬度计和干滑动摩擦试验机对涂层的显微硬度和抗磨损性能进行测试,并通过电化学工作站研究熔覆层的耐腐蚀性能。
结果表明:Fe基合金熔覆层的主要物相为α-Fe、Ni-Cr-Fe、γ-(Fe,C)和Fe9.7Mo0.3等,主要组织为马氏体、铁素体和少量残余奥氏体。
熔覆层的枝晶态组织均匀致密,无裂纹和孔隙缺陷,涂层与基体呈冶金结合。
涂层的硬度与耐磨性能随激光功率增大而提高,当功率为2.4 kW时,涂层的平均显微硬度(HV)为647.64,耐磨性能为45号钢的9.37倍,磨损机制为磨粒磨损。
随激光功率提高,Fe基合金熔覆层的耐腐蚀性能先升高后降低,当激光功率为2.0 kW时涂层具有最佳耐腐蚀性能,显著高于活塞杆常用碳钢、不锈钢以及电镀硬铬等材料,可在相关领域替代电镀铬。
关键词:激光熔覆;Fe基合金;组织;磨损;腐蚀;活塞杆中图分类号:TG174.44文献标志码:A 文章编号:1673-0224(2022)02-196-09All Rights Reserved.Microstructure and wear-corrosion resistance performance oflaser cladding martensite/ferrite coatingZHANG Lei1, 2, CHEN Xiaoming1, 2, HUO Jiaxiang1, ZHANG Kai1, 2, CAO Wenjing1, 2, CHENG Xinchuang3(1. Key Laboratory of Surface Engineering of Equipment for Hydraulic Engineering of Zhejiang Province, Standard &Quality Control Research Institute, Ministry of Water Resources, Hangzhou 310012, China;2. Water Machinery and Remanufacturing Technology Engineering Laboratory of Zhejiang Province, HangzhouMechanical Research Institute, Ministry of Water Resources, Hangzhou 310012, China;3. Shaoxing Municipal Cao’e River Floodgate Construction Administration Committee, Shaoxing 312000, China)Abstract: To improve the corrosion resistance and wear resistance of piston rod, Fe-based coatings with martensite andferrite structure were prepared on 45# steel by laser cladding. The phase compositions, microstructure and elementsdistribution of the coatings were characterized by X-ray diffractometer, scanning electron microscope and X-ray energydispersive spectrometer. The microhardness and wear resistance of the coatings were tested by Vickers hardness testerand dry sliding friction wear tester. Furthermore, the corrosion resistance of laser cladding Fe-based coatings was studiedby electrochemical workstation. The results show that the phase of laser cladding Fe-based alloy coating is mainlycomposed of α-Fe, Ni-Cr-Fe, γ-(Fe,C), Fe9.7Mo0.3. The main microstructure is martensite, ferrite and a small amount ofresidual austenite. The dendritic structure of coating is uniform, compact, without cracks or pores. The coating and thesubstrate are bonded metallurgically. The hardness and wear resistance of the coatings increase with increasing基金项目:浙江省“一带一路”国际科技合作项目(2019C04019);浙江省公益性技术应用研究计划资助项目(GC22E017317,LGC19E090001,2018C37029)收稿日期:2021−11−02;修订日期:2021−12−23通信作者:张磊,工程师,硕士。
x射线大纲要求

目的:掌握X-ray的性质要求:掌握X-ray的基本性质,连续、特征X-ray谱产生的机理,以及X-ray与物质的相互作用。
重点、难点:掌握X-ray的基本性质,连续、特征X-ray谱产生的机理,以及X-ray与物质的相互作用。
了解X-ray发展历史及防护,了解X-ray在现代材料分析中的重要用途。
英语词汇:diffraction\wave’length\target\intensity\filter\Auger effect\思考题:X-ray与物质的相互作用能产生哪些信号?连续、特征X-ray谱的强度、波长与哪些因素有关?X-ray产生的基本条件?作业题:课后习题。
参考资料:《X射线晶体学导论》[英]M.M.乌尔福逊著,科学出版社,1981年。
《X射线结构分析材料性能表征》藤风嗯、王熠明、姜小龙,科学出版社,1997年。
《材料评价的分析电子显微方法》[日]进藤、及川等著,冶金工业出版社,2001年。
《电子衍射图在晶体中的应用》郭可信、叶恒强、呈玉琨著,科学出版社,1983年。
目的:掌握X-ray衍射方向的基本原理—布拉格方程。
要求:在学习晶体几何学的基础上,掌握X-ray衍射原理以及衍射方向与布拉格方程的关系。
重点、难点:复习、掌握晶体几何学基础,理解X-ray衍射的条件与原理----布拉格方程的导出,掌握布拉格方程的意义与应用,理解不同X-ray衍射方法的特点,了解X-ray衍射发展历史。
英语词汇:amorphous\lattice point\space lattice\unit lattice\unit cell\crystallographicaxis\lattice parameter\incident angle\wave frant\Bragg’s law\reflection\angle of diffraction\structrue analysislaue method\rotating-crystal method\power method思考题:布拉格方程的意义与应用?不同X-ray衍射方法的区别?作业题:课后习题。
X-RAY测量厚度的原理

X-RAY荧光测厚法原理X-RAY是原子内层电子在高速运动电子的冲击下产生跃迁而发射的光辐射,可分为连续X-RAY和特征X-RAY两种,常用波段为0.1-20埃(A0)。
X-RAY分析法按照产生的机理可以划分为X-RAY荧光法(X-RAY fluorescence analysis)和X-RAY吸收光谱法(X-RAY absorption spectroscopy)和X-RAY衍射分析法(X-RAY diffraction analysis)等。
在PCB行业,对于金属层厚度一般采用X-RAY荧光法(X-RAY fluorescence analysis)。
X-RAY荧光测厚法原理是利用X-RAY射击到待测量的物体表面上,而反射出荧光,利用皮膜反射的荧光与基材反射荧光的不同性质,与基材反射回来的荧光量的多少,得以计算出皮膜厚度。
当一种物料受到X-RAY的撞击(Bombardment)时,原子中的某些电子在获得足够的能量而脱离(Spin Off)各原子正常轨道的制约后,在原来脱离的价层(Shell)中便产生一个“空洞”(Void)。
当另外有其他的电子从高价层中落下来填补该空洞的时候,其多余的能量便以X-RAY能量的光子释放出来,此X-RAY又在射击到其他物质上,并再度产生第二次的X-RAY荧光(X-RAY fluorescence),参见图2。
各种荧光X-RAY的发射能阶(Limitted Energy Lenel,也就是波长)与其再原子序(Atomic Number)成正比,而且和该物质的特性有关系,其谱线的数量(Quantity,也就是强度)是与该物质的厚度有关。
通过这样的机理,可以对物质进行定性和定量分析。
也就是如果能够采用适当的仪器(Instrumentaition),通过计算机便可以很快利用X-RAY去测量该材料的厚度。
X-RAY测量仪器的基本结构包括X-RAY光管/光源(X-RAY Tude)、准直器(Collimator,或叫瞄准仪)及一个比例记数器(Propertional Counter),参见图3。
x射线荧光光谱法 英文

x射线荧光光谱法英文X-Ray Fluorescence Spectrometry (XRF)。
X-ray fluorescence spectrometry (XRF) is an analytical technique used to determine the elemental composition of materials by measuring the X-rays emitted by the material when it is exposed to a high-energy X-ray beam. This method is widely used in various fields, including geology, environmental science, forensic science, archaeology, and materials science.Principle of Operation.XRF is based on the principle that when a material is irradiated with high-energy X-rays, electrons in the atoms of the material are excited and ejected from their orbits. The resulting vacancies are filled by electrons from higher energy levels, releasing X-rays with energiescharacteristic of the elements present in the material.The energy of the emitted X-rays is specific to each element, and the intensity of the X-rays is proportional to the concentration of the element in the material. By measuring the energies and intensities of the emitted X-rays, it is possible to identify and quantify the elements present in the sample.Instrumentation.A typical XRF spectrometer consists of the following components:X-ray source: Generates high-energy X-rays that bombard the sample.Sample chamber: Holds the sample to be analyzed.Detector: Converts X-rays into electrical signals.Multichannel analyzer (MCA): Digitizes and analyzes the electrical signals from the detector.Types of XRF Spectrometers.There are several types of XRF spectrometers, each with its own advantages and limitations:Energy-dispersive XRF (EDXRF): Uses a solid-state detector to measure the energies of the emitted X-rays. EDXRF is relatively inexpensive and easy to operate, but it has lower energy resolution compared to other types of XRF spectrometers.Wavelength-dispersive XRF (WDXRF): Uses a crystal monochromator to separate the emitted X-rays by wavelength. WDXRF offers higher energy resolution than EDXRF, but it is more complex, expensive, and time-consuming to operate.Total reflection XRF (TXRF): Utilizes total reflection conditions to enhance the sensitivity for analyzing trace elements in liquids. TXRF is highly sensitive, but it requires sample preparation and is not suitable for solid samples.Applications of XRF.XRF is a versatile analytical technique with a wide range of applications:Geochemistry: Determining the elemental composition of rocks, minerals, and soils.Environmental science: Monitoring pollutants in air, water, and soil.Forensic science: Analyzing trace evidence, such as gunshot residue and paint chips.Archaeology: Studying the composition of artifacts and ancient materials.Materials science: Characterizing the elemental composition of metals, alloys, and other materials.Advantages of XRF.Nondestructive: Does not damage the sample being analyzed.Multi-elemental: Can identify and quantify multiple elements simultaneously.Rapid: Provides real-time analysis results.Sensitive: Can detect elements at trace levels.Versatile: Can be applied to various sample types, including solids, liquids, and powders.Limitations of XRF.Limited sensitivity: Cannot detect elements present in very low concentrations.Matrix effects: The presence of other elements in the sample can affect the accuracy of the analysis.Sample preparation: May require sample preparation,such as grinding or homogenization.Cost: XRF spectrometers can be expensive, especially WDXRF systems.Conclusion.X-Ray Fluorescence Spectrometry is a powerful analytical technique that provides valuable information about the elemental composition of materials. It is widely used in various fields and offers advantages such as non-destructiveness, multi-elemental analysis, and rapid results. However, it has limitations in sensitivity and potential matrix effects, which should be considered when selecting this technique for specific applications.。
Spectral and temporal properties of X-ray emission from the ultra-luminous source X-9 in M8

We have analysed the spectra and the variability of individual X-ray sources in the M-81 field using data from the available ROSAations of this nearby spiral galaxy.
2 The data
We analysed the available archival data from ROSAT PSPC (12 observation, with 8 pointed on M 81 nucleus for a total exposure time of 146 ksec) and HRI (7 observations pointed on M 81 nucleus for a total exposure time of 135 ksec). We also used a SAX observation pointed on M 81 and one ASCA observation pointed on X-9.
Figure 3: Radial profiles of the calibration source HZ43 (stars), compared to X9 profile (diamonds). Left panel: external sector. Right panel: internal sector. Data points are normalized to the total number of counts within 2 arcmin. Extraction annuli are 2 arcsec wide (1 detector pixel = 0.5 arcsec)
X射线衍射和小角X射线散射

晶体的X射线衍射特征
[Crystal Structure Analysis, 3rd Edition, p. 48]
晶体结构及其晶胞类型
[Methods of Experimental Physics Volume 16: Polymers, Part B Crystal Structure and Morphology, p. 5]
X射线衍射需要在广角范围内测定,因此又 被称为广角X射线衍射(Wide-Angle X-ray Scattering, WAXS)。
小角X射线散射
如果被照射试样具有不同电子密度的非周 期性结构,则次生X射线不会发生干涉现象, 该现象被称为漫射X射线衍射(简称散射)。
X射线散射需要在小角度范围内测定,因此 又被称为小角X射线散射(Small-Angle Xray Scattering, SAXS)。
晶面指数与晶胞参数
[Fundamentals of Powder Diffraction and Structural Characterization of Materials, 2nd Edition, p. 9]
Bragg方程
设晶体的晶面距为 d,X射线以与晶面间交
角为 的方向照射,从晶面散射出来的X射
粉末衍射条纹摄制及处理
[Fundamentals of Powder Diffraction and Structural Characterization of Materials, 2nd Edition, p. 265]
粉末衍射平板图案摄制
[Fundamentals of Powder Diffraction and Structural Characterization of Materials, 2nd Edition, p. 153]
X-ray Absorption Spectroscopy (XAS)

X-ray Absorption Spectroscopy (XAS)When the x-rays hit a sample, the oscillating electric field of the electromagnetic radiation interacts with the electrons bound in an atom. Either the radiation will be scattered by these electrons, or absorbed and excite the electrons.xA narrow parallel monochromatic x-ray beam of intensity I 0 passing through a sample of thickness x will get a reduced intensity I according to the expression: ln (I 0 /I) = µ x (1)where µ is the linear absorption coefficient , which depends on the types of atoms and the density ρ of the material. At certain energies where the absorption increases drastically, and gives rise to an absorption edge . Each such edge occurs when the energy of the incident photons is just sufficient to cause excitation of a core electron of the absorbing atom to a continuum state, i.e . to produce a photoelectron. Thus, the energies of the absorbed radiation at these edges correspond to the binding energies of electrons in the K, L, M, etc, shells of the absorbing elements. The absorption edges are labelled in the order of increasing energy , K, L I , L II , L III , M I ,…., corresponding to the excitation of an electron from the 1s (2S ½), 2s (2S ½), 2p (2P ½), 2p (2P 3/2), 3s (2S ½), … orbitals (states), respectively. Bohr Atomic Modeled K L L L Continuumge: 2 S ½2P ½2P 32IIIII IWhen the photoelectron leaves the absorbing atom, its wave is backscattered by the neighbouring atoms. The figure below shows the sudden increase in the x-ray absorption of the platinum Pt L III edge in K 2[Pt(CN)4] with increasing photon energy. The maxima and minima after the edge correspond to the constructive and destructive interference between the outgoing photoelectron wave and backscattered wave. 11300115001170011900121001230012500Energy (eV)µ (E )An x-ray absorption spectrum is generally divided into 4 sections: 1) pre-edge (E < E 0); 2) x-ray absorption near edge structure (XANES ), where the energy of the incident x-ray beam is E = E 0 ± 10 eV; 3) near edge x-ray absorption fine structure (NEXAFS ), in the region between 10 eV up to 50 eV above the edge; and 4) extended x-ray absorption fine structure (EXAFS ), which starts approximately from 50 eV and continues up to 1000 eV above the edge.The minor features in the pre-edge region are usually due to the electron transitions from the core level to the higher unfilled or half-filled orbitals (e.g, s → p , or p → d ). In the XANES region, transitions of core electrons to non-bound levels with close energy occur. Because of the high probability of such transition, a sudden raise of absorption is observed. In NEXAFS, the ejected photoelectrons have low kinetic energy (E-E 0 is small) and experience strong multiple scattering by the first and even higher coordinating shells. In the EXAFS region, the photoelectrons have high kinetic energy (E-E 0 is large), and single scattering by the nearest neighbouring atoms normally dominates.11400.00.51.01.52.001150011600117001180011900Multiple scatteringSingle scatteringHome Research Publications Synchrotron XANES EXAFS XAS Measurement。
Exploring the complex X-ray spectrum of NGC 4051

a r X i v :a s t r o -p h /0310257v 2 16 J a n 2004Mon.Not.R.Astron.Soc.000,1–??(2003)Printed 2February 2008(MN L A T E X style file v1.4)Exploring the complex X-ray spectrum of NGC 4051.K.A.Pounds 1,J.N.Reeves 2,A.R.King 1and K.L.Page,11Department of Physics and Astronomy,University of Leicester,Leicester,LE17RH,UK2Laboratory for High Energy Astrophysics,NASA Goddard Space Flight Center,Greenbelt,MD 20771,USAAccepted ;SubmittedABSTRACTArchival XMM-Newton data on the nearby Seyfert galaxy NGC 4051,taken in rela-tively high and low flux states,offer a unique opportunity to explore the complexity of its X-ray spectrum.We find the hard X-ray band to be significantly affected by reflec-tion from cold matter,which can also explain a non-varying,narrow Fe K fluorescent line.We interpret major differences between the high and low flux hard X-ray spectra in terms of the varying ionisation (opacity)of a substantial column of outflowing gas.An emission line spectrum in the low flux state indicates an extended region of pho-toionised gas.A high velocity,highly ionised outflow seen in the high state spectrum can replenish the gas in the extended emission region over ∼103years,while having sufficient kinetic energy to contribute significantly to the hard X-ray continuum.Key words:galaxies:active –galaxies:Seyfert:general –galaxies:individual:NGC 4051–X-ray:galaxies1INTRODUCTIONThe additional sensitivity of XMM-Newton and Chandra has emphasised the complexity in the X-ray spectra of AGN.While there is broad agreement that the X-ray emission is driven by accretion onto a supermassive black hole,the detailed emission mechanism(s)remain unclear.Significant complexity -and diagnostic potential -is introduced by re-processing of the primary X-rays in surrounding matter.Scattering and fluorescence from dense matter in the pu-tative accretion disc has been recognised as a major fac-tor in modifying the observed X-ray emission of bright Seyfert galaxies since its discovery 13years ago (Nandra et al.1989,Pounds et al.1990).Additional modification of the observed X-ray spectra arises by absorption in passage through ionised matter in the line of sight to the continuum X-ray source.The high resolution X-ray spectra obtained with XMM-Newton and Chandra have shown the consider-able complexity of this ‘warm absorber’(eg Sako et al.2001,Kaspi et al.2002),including recent evidence for high veloc-ity outflows (eg Chartas et al.2002,Pounds et al.2003a,b;Reeves et al.2003)which constitute a significant component in the mass and energy budgets of those AGN.In this paper we report on the spectral analysis of two XMM-Newton ob-servations of the bright,nearby Seyfert 1galaxy NGC 4051taken from the XMM-Newton data archive.We find further support for the suggestion made in an early survey of XMM-Newton Seyfert spectra (Pounds and Reeves 2002),that the full effects of ionised absorption in AGN have often been underestimated.NGC 4051is a low redshift (z =0.0023)narrow lineSeyfert 1galaxy,which has been studied over much of the history of X-ray astronomy.Its X-ray emission often varies rapidly and with a large amplitude (Lawrence et al.1985,1987),occasionally lapsing into extended periods of ex-treme low activity (Lamer et al.2003).When bright,the broad band X-ray spectrum of NGC 4051appears typical of a Seyfert 1galaxy,with a 2–10keV continuum being well represented by a power law of photon index Γ∼1.8–2,with a hardening of the spectrum above ∼7keV being attributable to ‘reflection’from ‘cold’,dense matter,which might also be the origin of a relatively weak Fe K emission line (Nandra and Pounds 1994).However,NGC 4051also exhibits strong spectral variability,apparently correlated with source flux.The nature of this spectral variability has remained contro-versial since the GINGA data were alternatively interpreted as a change in power law slope (Matsuoka et al.1990)and by varying partial covering of the continuum source by op-tically thick matter (Kunieda et al.1992).Later ROSAT observations provided good evidence for a flux-linked variable ionised absorber,and for a ‘soft excess’below ∼1keV (Pounds et al.1994,McHardy et al.1995,Komossa and Fink 1997).Extended ASCA observations led Guainazzi et al.(1996)to report a strong and broad Fe K emission line (implying reflection from the inner accretion disc),and a positive correlation of the hard power law slope with X-ray flux.A 3-year monitoring campaign of NGC 4051with RXTE ,including a 150-day extended low interval in 1998,produced clear evidence for the cold reflection com-ponent (hard continuum and narrow 6.4keV Fe K line)re-c2003RAS2K.A.Pounds et al.maining constant,while againfinding the residual power law slope to steepen at higher X-rayfluxes(Lamer et al.2003). More surprisingly,a relativistic broad Fe K line component was found to be always present,even during the period whenthe Seyfert nucleus was‘switched off’(Guainazzi et al.1998, Lamer et al.2003).One other important contribution to the extensive X-ray literature on NGC4051came from an early Chandra observation which resolved two X-ray absorption line systems,with outflowing velocities of∼2300and∼600 km s−1,superimposed on a continuum soft excess with sig-nificant curvature(Collinge et al.2001).Of particular inter-est in the context of the present analysis,the higher velocity outflow is seen in lines of the highest ionisation potential. The Chandra data also show an unresolved Fe K emission line at∼6.41keV(FWHM≤2800km s−1).In summary,no clear picture emerges from a review of the extensive data on the X-ray spectrum of NGC4051, with the spectral variability being(mainly)due to a strong power law slope-flux correlation,or to variable absorption in(a substantial column of)ionised matter.Support for the former view has recently come from a careful study of the soft-to-hardflux ratios in extended RXTE data(Taylor et al.2003),while the potential importance of absorption is underlined by previous spectralfits to NGC4051requiring column densities of order∼1023cm−2(eg Pounds et al.1994, McHardy et al.1995).Given these uncertainties we decided to extract XMM-Newton archival data on NGC4051in order to explore its spectral complexities.After submission of the present paper, an independent analysis of the2002November EPIC pn data by Uttley et al.(2003)was published on astro-ph,reaching different conclusions to those wefind.We comment briefly on these alternative descriptions of the spectral variability of NGC4051in Section9.4.2OBSER V ATION AND DATA REDUCTION NGC4051was observed by XMM-Newton on2001May 16/17(orbit263)for∼117ksec,and again on2002Novem-ber22(orbit541)for∼52ksec.The latter observation was timed to coincide with an extended period of low X-ray emis-sion from NGC4051.These data are now public and have been obtained from the XMM-Newton data archive.X-ray data are available in both observations from the EPIC pn (Str¨u der et al.2001)and MOS2(Turner et al.2001)cameras, and the Reflection Grating Spectrometer/RGS(den Herder et al.2001).The MOS1camera was also in spectral mode in the2002observation.Both EPIC cameras were used in small window mode in thefirst observation,together with the mediumfilter,successfully ensuring negligible pile-up. The large window mode,with mediumfilter,was used in the second,lowflux state observation.The X-ray data were first screened with the latest XMM SAS v5.4software and events corresponding to patterns0-4(single and double pixel events)were selected for the pn data and patterns0-12for MOS1and MOS2.A low energy cut of300eV was applied to all X-ray data and known hot or bad pixels were removed. We extracted EPIC source counts within a circular region of45′′radius defined around the centroid position of NGC 4051,with the background being taken from a similar re-gion,offset from but close to the source.The netexposures Figure 1.Background-subtracted EPIC pn data for the2001 May(black)and2002November(red)observations of NGC4051 available for spectralfitting from the2001observation were 81.7ksec(pn),103.6ksec(MOS2),114.3ksec(RGS1)and 110.9ksec(RGS2).For the2002observation thefinal spec-tral data were of46.6ksec(pn),101.9ksec(MOS1and2), 51.6ksec(RGS1)and51.6ksec(RGS2).Data were then binned to a minimum of20counts per bin,to facilitate use of theχ2minimalisation technique in spectralfitting. Spectralfitting was based on the Xspec package(Arnaud 1996).All spectralfits include absorption due to the NGC 4051line-of-sight Galactic column of N H=1.32×1020cm−2 (Elvis et al.1989).Errors are quoted at the90%confidence level(∆χ2=2.7for one interesting parameter).We analysed the broad-band X-ray spectrum of NGC 4051integrated over the separate XMM-Newton observa-tions,noting the meanflux levels were markedly different, and perhaps representative of the‘high state’and‘low state’X-ray spectra of this Seyfert galaxy.[In fact the2001May X-rayflux is close to the historical mean for NGC4051, but we will continue to refer to it as the‘high state’for convenience].To obtain afirst impression of the spectral change we compare infigure1the background-subtracted spectra from the EPIC pn camera for orbits263and541. The same comparison for the EPIC MOS2data(not shown) is essentially identical.From∼0.3–3keV the spectral shape is broadly unchanged,with the2001flux level being a fac-tor∼5higher.From∼3keV up to the very obvious emission line at∼6.4keV theflux ratio decreases,indicating aflatter continuum slope in the low state spectrum over this energy band.On this simple comparison the∼6.4keV emission line appears essentially unchanged in energy,width and photon flux.We will defer a more detailed comparison of the‘high’and‘low’state data until Section5,afterfirst modelling the individual EPIC spectra.3HIGH STATE EPIC SPECTRUM3.1Power law continuumWe began our analysis of the EPIC data for2001May in the conventional way byfitting a power law over the hard X-ray (3–10keV)band,thereby excluding the more obvious effectsc 2003RAS,MNRAS000,1–??X-ray spectrum of NGC40513 Figure2.Ratio of data to power lawfits over the3–10keV bandfor the pn(black)and MOS(red)spectra in the high state2001May observation of NGC4051.of soft X-ray emission and/or low energy absorption.Thisfityielded a photon index ofΓ∼1.85(pn)andΓ∼1.78(MOS),but thefit was poor with significant residuals.In particularthe presence of a narrow emission line near6.4keV,and in-creasing positive residuals above9keV(figure2),suggestedthe addition of a cold reflection component to refine the con-tinuumfit,which we then modelled with PEXRAV in Xspec(Magdziarz and Zdziarski1995).Since the reflection compo-nent was not well constrained by the continuumfit,we leftfree only the reflection factor R(=Ω/2π,whereΩis thesolid angle subtended at the source),fixing the power lawcut-offat200keV and disc inclination at20◦,with all abun-dances solar.The outcome was an improvedfit,with∆χ2of40for R=0.8±0.2.The power law indexΓincreased by0.1for both pn and MOSfits.In all subsequentfits we thenset R=0.8(compatible with the strength of the6.4keVemission line).Based on this broad bandfit we obtained a2-10keVflux for the2001May observation of NGC4051of2.4×10−11erg s−1cm−2corresponding to a2-10keVluminosity of2.7×1041erg s−1(H0=75km s−1Mpc−1).3.2Fe K emission and absorptionThe power law plus reflection continuumfit at3–10keVleaves several residual features in both pn and MOS data,the significance of which are indicated by the combinedχ2of2068for1740degrees of freedom(dof).Visual examinationoffigure2shows,in particular,a narrow emission line near6.4keV and evidence of absorption near∼7keV and between∼8–9keV.To quantify these features we then added further spec-tral components to the model,beginning with a gaussianemission line with energy,width and equivalent width asfree parameters.This addition improved the3–10keVfit,toχ2/dof of1860/1735,with a line energy(in the AGN restframe)of6.38±0.01keV(pn)and6.42±0.03keV(MOS),rms width≤60eV and lineflux of1.6±0.4×10−5photons−1cm−2(pn)and1.4±0.6×10−5photon s−1cm−2(MOS),corresponding to an equivalent width(EW)of60±15eV.Next,wefitted the most obvious absorption feature near7keV with a gaussian shaped absorption line,again withenergy,width and equivalent width free.The best-fit ob-served line energy was7.15±0.05keV(pn)and7.05±0.05keV(MOS)in the AGN rest-frame,with an rms width of150±50eV,and an EW of100±20eV.The addition of thisgaussian absorption line gave a further highly significantimprovement to the overallfit,withχ2/dof=1802/1730.Fitting the less compelling absorption feature at∼8–9keVwith a second absorption line was not statistically signifi-cant.However,an absorption edge did improve thefit toχ2/dof=1767/1728,for an edge energy of8.0±0.1keV andoptical depth0.15±0.05.In summary,the3-10keV EPIC data from the highstate2001May observation of NGC4051is dominated by apower law continuum,with a photon index(after inclusionof cold reflection plus an emission and absorption line)of1.90±0.02(pn)and1.84±0.02(MOS).The narrow emissionline at∼6.4keV is compatible withfluorescence from thesame cold reflecting matter,while-if identified with reso-nance absorption of FeXXVI or FeXXV-the∼7.1keV lineimplies a substantial outflow of highly ionised gas.Wefindno requirement for the previously reported strong,broad FeK emission line,the formal upper limit for a line of initialenergy6.4keV being70eV.3.3Soft ExcessExtending the above3–10keV continuum spectralfit downto0.3keV,for both pn and MOS data,shows very clearly(figure3)the strong soft excess indicated in earlier observa-tions of NGC4051.To quantify the soft excess we againfitted the com-bined pn and MOS data,obtaining a reasonable overallfit with the addition of blackbody continua of kT∼120and270eV,together with absorption edges at∼0.725keV(τ∼0.24)and∼0.88keV(τ∼0.09).Based on this broad bandfit we deduced soft X-rayflux levels for the2001May ob-servation of NGC4051of2.9×10−11erg s−1cm−2(0.3–1keV),with∼61percent in the blackbody components,and1.1×10−11erg s−1cm−2(1–2keV).Combining these re-sults with the higher energyfit yields an overall0.3–10keVluminosity of NGC4051in the‘high’state of7×1041ergs−1(H0=75km s−1Mpc−1).4LOW STATE EPIC SPECTRUMThe above procedure was then repeated in an assessment ofthe2002November EPIC data,when the X-rayflux fromNGC4051was a factor∼4.5lower(figure1).Fitting the hard X-ray continuum was now more un-certain since the spectrum was more highly curved in thelowflux state(comparefigs4and2),making an underlyingpower law component difficult to identify.To constrain thefitting parameters we therefore made two important initialassumptions.Thefirst,supported by the minimal changeapparent in the narrow Fe K line,was to carry forward thecold reflection(normalisation and R)parameters from the‘high state’spectralfit(in fact,as noted above,appropri-ately at aflux level close to the historical average for NGC4051).The second assumption was that the power law con-tinuum changed only in normalisation,but not in slope(as c 2003RAS,MNRAS000,1–??4K.A.Pounds etal.Figure3.Extrapolation to0.3keV of the3–10keV spectralfit(detailed in section3.2)showing the strong soft excess in both pn(black)and MOS(red)spectra during the2001May observationof NGC4051.found in the extended XMM-Newton observation of MCG-6-30-15,Fabian and Vaughan2003).This is in contrast to theconclusions of Lamer et al.(2003)but-as we see later-isconsistent with the difference spectrum(figure8),whichfitsquite well at3–10keV to a power law slope ofΓ∼2,whilealso showing no significant residual reflection features.With these initial assumptions,the3–10keVfit to thelow state spectrum yielded the data:model ratio shown infig-ure4.A visual comparison withfigure2shows a very similarnarrow emission line at∼6.4keV,but with strong curvatureto the underlying continuum,and significant differences inthe absorption features above7keV.These strong residualsresulted in a very poorfit at3–10keV,withχ2of1610/990.We note the spectral curvature in the3–6keV band is rem-iniscent of an extreme relativistic Fe K emission line;how-ever,since our high state spectrum showed no evidence forsuch a feature,and it might in any case be unexpected whenthe hard X-ray illumination of the innermost accretion discis presumably weak,we considered instead a model in whicha fraction of the power law continuum is obscured by anionised absorber.We initially modelled this possibility withABSORI in Xspec,finding both the3–6keV spectral cur-vature and the absorption edge at∼7.6keV were wellfittedwith∼60percent of the power law covered by ionised matterof ionisation parameterξ(=L/nr2)∼25and column densityN H∼1.2×1023cm−2.The main residual feature was then the narrow Fe Kemission line.4.1The narrow Fe K emission lineA gaussian linefit to the emission line at∼6.4keV in thelow state EPIC data was again unresolved,with a meanenergy(in the AGN rest frame)of6.41±0.01keV(pn)and6.39±0.02keV(MOS),and linefluxes of1.9±0.3×10−5pho-ton s−1cm−2(pn)and2.0±0.4×10−5photon s−1cm−2(MOS),corresponding to an EW against the unabsorbedpower law component of500±75eV.The important pointis that,within the measurement errors,the measuredfluxesof the∼6.4keV line are the same for the twoobservations.Figure4.Ratio of data to power law plus continuum reflectionmodelfit over the3–10keV band for the pn(black)and MOS(red)spectra in the low state2002November observation of NGC4051.Figure5.Partial covering model spectrumfitted over the3–10keV band for the2002November observation of NGC4051.Alsoshown are the separate components in thefit:the unabsorbedpower law(green),absorbed power law(red)and Gaussian emis-sion line(blue).See Section4.1for details.For clarity only thepn data are shown.This lends support to our initial assumption that both EPICspectra include a‘constant’reflection component,illumi-nated by the long-term average hard X-ray emission fromNGC4051.With the addition of this narrow emission linethe overall3–10keVfit obtained with the partial coveringmodel was then good(χ2/dof=1037/1037).Figure5illus-trates the unfolded spectrum and spectral components ofthisfit.4.2Soft ExcessExtrapolation of the above partial covering3–10keV spec-tralfit down to0.3keV shows a substantial soft X-ray excessremains(figure6),with a similar relative strength to thepower law component seen in the high state data.We notethat the‘soft excess’,ie relative to the power law component,c 2003RAS,MNRAS000,1–??X-ray spectrum of NGC40515 Figure6.Partial covering modelfits over the3–10keV bandextended to0.3keV,for the pn(black)and MOS(red)data fromthe low state2002November observation of NGC4051.would have been extremely strong(data:model ratio∼8)had we taken the simple power lawfit(Γ∼1.4)to the lowstate3–10keV data.Extending the partial covering model to0.3keV,with the addition-as in the high state-of a black-body component of kT∼125eV(the hotter component wasnot required),gave an initially poorfit(χ2of2348for1265dof for the pn data),with a broad deficit in observedfluxat∼0.7-0.8keV being a major contributor(figure6).Theaddition of a gaussian absorption line to the partial coveringmodel gave a large improvement to the broad-bandfit(toχ2of1498for1262dof),for a line centred at0.756±0.003keV,with rms width50±15eV and EW∼40eV.We show thiscomplex spectralfit infigure7,and comment that the modeldependency of unfolded spectra is relatively unimportant inillustrating such strong,broad band spectral features.Sig-nificantly,the broad-band spectralfit remains substantiallyinferior to the similarfit to the high state data.Examina-tion of the spectral residuals shows this is due to additionalfine structure in the soft band of the low state spectrum,structure that is also evident infigures6and7.We examinethe RGS data in Section6to explore the nature(absorptionor emission)of this structure.The deduced soft X-rayflux levels for the2002Novem-ber observation of NGC4051were6.3×10−12erg s−1cm−2(0.3–1keV),with∼53percent in the blackbody component,and1.8×10−12erg s−1cm−2(1–2keV).Combining these re-sults with a2-10keVflux of5.8×10−12erg s−1cm−2yieldedan overall0.3–10keV luminosity of NGC4051in the‘low’state of1.5×1041erg s−1(H0=75km s−1Mpc−1).5COMPARISON OF THE HIGH AND LOWSTATE EPIC DATAThe above spectralfitting included two important assump-tions,that the cold reflection was unchanged between thehigh and lowflux states,and the variable power law com-ponent was of constant spectral index.We now compare theEPIC data for the two observations to further explore thenature of the spectral change.Figure8illustrates the dif-ference spectrum obtained by subtracting thebackground-Figure7.Extrapolation to0.3keV of the3–10keV partial cov-eringfit offig5showing the strong soft excess modelled by ablackbody component(blue),and a broad absorption trough at∼0.76keV.For clarity only the pn data are shown.subtracted low state data from the equivalent high state data(corrected for exposure).To improve the statistical signifi-cance of the higher energy points the data were re-groupedfor a minimum of200counts.The resulting difference spec-trum is compared infigure8with a power lawfitted at3–10keV.Several points are of interest.First,the power law indexof the difference spectrum,Γ∼2.04(pn)andΓ∼1.97(M2),is consistent with the assumed‘constant’value in the indi-vidual spectralfits.Second,the narrow Fe K emission lineand high energy data upturn are not seen,supporting ourinitial assumption of a‘constant’cold reflection component.The narrow feature observed at∼7keV corresponds to theabsorption line seen(only)in the high state spectrum,whilewe shall see in Section6that the deficit near0.55keV inthe MOS data(which has substantially better energy reso-lution there than the pn)is probably explained by a strongand‘constantflux’emission line of OVII.Finally,the smallpeak near8keV can be attributed to the absorption edgeshifting to lower energy as the photoionised gas recombinesin the reduced continuum irradiation.While the arithmetic difference of two spectra providesa sensitive check for the variability of additive spectral com-ponents,a test of the variability of multiplicative compo-nents is provided by the ratio of the respective data sets.Figure9reproduces the ratio of the high and low state data(pn only)after re-grouping to a minimum of500counts perbin.From∼0.3–3keV theflux ratio averages∼5,as seen infigure1,falling to higher energies as the mean slope of thelow state spectrum hardens.The large positive feature at∼0.7–0.8keV is of particular interest,indicating a variablemultiplicative component,almost certainly corresponding toenhanced absorption in the low state spectrum.In fact thatfeature can be clearly seen in the low state EPIC data infigures6and7.We suggest the broad excess at∼1–2keVcan be similarly explained by greater absorption affectingthe low state spectrum,lending support to our overall inter-pretation of the spectral change.Finally,we note that thenarrow dip in the ratio plot at∼6.4keV is consistent withthe Fe K emission line having unchangedflux,but corre-spondingly higher EW in the low state spectrum.c 2003RAS,MNRAS000,1–??6K.A.Pounds etal.Figure8.High minus low state difference spectral data(pn-black,M2-red)compared with a simple power law,as describedin Section5.Figure9.Ratio of high state to low state spectral data(pn only),as described in Section5.6SPECTRAL LINES IN THE RGS DATABoth EPIC spectra show a strong soft excess,with the lowstate(2002)spectrum also having more evidence offinestructure.To study the soft X-ray spectra in more detailwe then examined the simultaneous XMM-Newton gratingdata for both observations of NGC4051.Figures10and11reproduce thefluxed spectra,binned at35m˚A,to showboth broad and narrow features.The continuumflux level ishigher in the2001data(consistent with the levels seen in theEPIC data),with a more pronounced curvature longwardsof∼15˚A.Numerous sharp data drops hint at the presence ofmany narrow absorption lines.In contrast,the2002Novem-ber RGS spectrum exhibits a lower andflatter continuumflux,and a predominance of narrow emission lines.We began an analysis of each observation by simultane-ouslyfitting the RGS-1and RGS-2data with a power lawand black body continuum(from the corresponding EPIC0.3–10keVfits)and examining the data:model residuals byeye.For the2001May observation the strongest featureswere indeed narrow absorption lines,most beingreadilyFigure10.Fluxed RGS spectrum from the XMM-Newton ob-servation of NGC4051in2001May.Figure11.Fluxed RGS spectrum from the XMM-Newton ob-servation of NGC4051in2002November.identified with resonance absorption in He-and H-like ionsof C,N,O and Ne.In contrast,the combined RGS data forthe low state data from2002November showed a mainlyemission line spectrum,more characteristic of a Seyfert2galaxy(eg Kinkhabwala et al.2002).Significantly,the NVI,OVII and NeIX forbidden lines are seen in both high andlow state RGS spectra at similarflux levels.Taking note ofthat fact we then analysed the low state(2002)datafirst,and subsequently modelled the RGS high-minus-low differ-ence spectrum,to get a truer measure of the absorption linestrengths in the high state(2001)spectrum.6.1An emission line spectrum in the low statedataTo quantify the emission lines in the2002spectrum weadded gaussian lines to the power law plus blackbody contin-uumfit in Xspec,with wavelength andflux as free parame-ters.In each case the line width was unresolved,indicating aFWHM≤300km s−1.Details of the8strongest lines therebyidentified are listed in Table1.The statistical quality of thec 2003RAS,MNRAS000,1–??X-ray spectrum of NGC40517fit was greatly improved by the addition of the listed lines,with a reduction inχ2of251for16fewer dof.When ad-justed for the known redshift of NGC4051all the identified lines are consistent with the laboratory wavelengths indi-cating that the emitting gas has a mean outflow(or inflow) velocity of≤200km s−1.Figure12illustrates the OVII triplet,showing the dom-inant forbidden line and strong intercombination line emis-sion,but no residual resonance line emission(at21.6˚A).Theline ratios,consistent with those found in the earlier Chandra observation(Collinge et al.2001),give a clear signature of a photoionised plasma,with an electron density≤1010cm−3(Porquet and Dubau2000).A similarly dominant forbidden line in the NVI triplet yields a density limit a factor∼10 lower.We note the absence of the OVII resonance emission line may be due to infilling by a residual absorption line ofsimilar strength.After removal of the emission lines listed in Table1,sev-eral additional emission features(seefigure11)remained. Although narrow and barely resolved,the wavelength of these features allows them to be unambiguously identifiedwith the radiative recombination continua(RRC)from the same He-and H-like ions of C,N,O and(probably)Ne. Table2lists the properties of these RRC as determined byfitting in Xspec with the REDGE model.While the RRC of CV,CVI,NVI and OVII are well determined,wefixed the other threshold energies at their laboratory values to quan-tify the measured equivalent widths.What is clear is that the RRC are very narrow,a combinedfit yielding a mean temperature for the emitting gas of kT∼3eV(T∼4×104K).We note this low temperature lies in a region of thermal stability for such a photoionised gas(Krolik et al.1981). Furthermore,the low temperature indicates collisional ion-isation and excitation will be negligible,and radiative re-combination should be the dominant emission process.Additional constraints on the emitting gas in NGC4051can be derived by noting that the2002November XMM-Newton observation took place some20days after the source entered an extended lowflux state.Furthermore,the emis-sion line strength of the OVII forbidden line is essentially the same as when NGC4051was much brighter in2001 May.This implies that the emission spectrum arises fromionised matter which is widely dispersed and/or of such low density that the recombination time is>∼2×106s.At a gas temperature of∼4×104K,the recombination time for OVIIis of order150(n9)−1s,where n9is the number density of the ionised matter in units of109cm−3(Shull and Van Steenberg 1982).The persistent low state emission would therefore in-dicate a plasma density≤105cm−3.Assuming a solar abundance of oxygen,with30per-cent in OVII,50percent of recombinations from OVIII di-rect to the ground state,and a recombination rate at kT ∼3eV of10−11cm3s−1(Verner and Ferland1996),we deduce an emission measure for the forbidden lineflux oforder2×1063cm−3.That corresponds to a radial extent of >∼3×1017cm for a uniform spherical distribution of pho-toionised gas at the above density of≤105cm−3.Coinci-dentally,the alternative explanation for a constant emission lineflux,via an extended light travel time,also requires an emitting region scale size of>∼1017cm.We note,furthermore, that these values of particle density and radial distance from the ionising continuum source are consistent with theioni-Figure12.Emission lines dominate the2002November RGS data.The OVII triplet is illustrated with only the forbidden and intercombination lines clearly visible.The gaussian linefits in-clude only the RGS resolution showing the emission lines are in-trinsically narrow.See Section6.1for details.sation parameter derived from our XSTARfit to the RGS absorption spectrum(Section7).The scale of the soft X-ray emitting gas is apparently much greater than the BLR, for which Shemmer et al.2003find a value of3.0±1.5light days(∼3−10×1015cm).In fact it has overall properties,of density,temperature and velocity consistent with the NLR in NGC4051.The above emission lines and RRC provide an accept-ablefit to the RGS data for the2002November observation of NGC4051.However a coarse binning of the data:model residuals(figure13)shows a broad deficit offlux remaining at∼15−17˚A.It seems likely that this feature is the same as that seen in the broad bandfits to the EPIC data for 2002November(Section4)and tentatively identified with an unresolved transition array(UTA)from Fe M-shell ions (Behar et al.2001).Whenfitted with a gaussian absorp-tion line wefind an rms width ofσ=∼30eV and EW of 25eV against the low state continuum,consistent with the absorption trough required in the partial coveringfit to the low state EPIC data(section4.2).6.2Absorption lines in the high state differencespectrum.The observed wavelengths of the main emission lines in the 2002spectrum and their equivalent absorption lines in the 2001spectrum are the same within the resolution of our gaussian linefitting.(At higher resolution the absorption lines appear to have a mean outflow velocity of∼500km s−1,while the emission lines are close to the systemic veloc-ity of NGC4051.)Furthermore,from our analysis in Section 6.1it seems clear that the emission line spectrum represents an underlying component that responds to some long-term averageflux level of the ionising continuum of NGC4051. We thereforefirst subtracted the2002RGS spectrum from the2001spectrum with the aim of obtaining a truer mea-sure of the absorption line strengths in the high state data. Quantifying the main absorption lines by adding gaussianc 2003RAS,MNRAS000,1–??。
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a rXiv:as tr o-ph/47585v128J ul24Mem.S.A.It.Vol.73,23c SAIt 2002Memoriedella A.Wolter 1,G.Trinchieri 1,R.Della Ceca 1,F.Panessa 2,3,M.Dadina 2,L.Bassani 2,M.Cappi 2,A.Fruscione 3,S.Pellegrini 4,and G.Palumbo 41Osservatorio Astronomico di Brera via Brera 28,20121MILANO e-mail:anna@brera.mi.astro.it 2INAF/IASF,via P.Gobetti 101,40129Bologna 3Center for Astrophysics,60Garden St.,Cambridge,MASS 4Dipartimento di Astronomia,Universit`a di Bologna,via Ranzani 1,40127Bologna Abstract.An enigmatic,small class of IR and X-ray luminous sources,named “Composite”starburst/Seyfert galaxies,has been defined from IRAS and RASS data.The objects have optical spectra dominated by the features of HII galaxies (plus,in some cases,weak Seyfert signatures)but X-ray luminosities higher than expected from starbursts and more typical of Seyfert nuclei.The true nature of this class of objects is still unknown.We present Chandra data of four of these galaxies that were obtained to investigate the nature of the X-ray source.The X-ray spectrum,the lack of any significant extended component,and the observed variability indicate that the AGN is the dominant component in the X-ray domain.Key words.Galaxies:active –Galaxies:starburst –X-rays:galaxies 1.Introduction An enigmatic class of six low redshift galax-ies has been defined during a spectro-scopic survey of bright IRAS and RASS sources (Moran et al.1996).They werenamed “Composite”to indicate their dualnature:the optical spectrum typical of a star forming galaxy is characterized by ad-24 A.Wolter et al.:“Composite”Seyfert/Star-forminggalaxiesFig.1.The light curve ofIRAS20069+5929,in bins of1000sec,and residuals with respect to a constant(inσ);thefitχ2is46.8/25,indicating thatvariability is present.tailed description of the X-ray data will ap-pear in Panessa et al.(in preparation).2.X-ray dataThe sources were all observed with theACIS-I instrument on board Chandra fora nominal exposure of∼25ksec.Relevantdata for the sources are listed in Table1.Based on the RASSfluxes we had requesteda Chandra configuration that would allowmore frequent read-out of the data by us-ing a smallerfield of view to avoid pile-up.The results however indicate that the pre-cautions taken were not necessary,since theobserved count rates(see Table1)are wellbelow the expected value and the pile-up isnot significant.2.1.VariabilityWe compare the total Chandra luminosi-ties to previous RASS data(Moran et al.1996).Wefind consistency only forIRAS20069+5929.The luminosity issmaller by a factor∼10for IRAS04392-0123,and a factor∼2for IRAS01072+4954Fig.2.Profile of IRAS20069+5929(squares)compared to the chart-derivedPSF with the same spectral distribution ofthe source(histogram).X-axis is in arcsec.&IRAS01319-1604,as indicated by R inTable1.A discrepancy of a factor∼25was also reported for IRAS00317-2142(Georgantopoulos et al.2003),whileno information is available so far forIRAS20051-1117that has been observedby Chandra and XMM-Newton.The longterm variability alone already indicatesthat the dominant source of emission isdue to a point sources.We have further investigated short termvariability.We compute light curves by ex-tracting the source counts in a region of4′′radius and background in a larger,sourcefree,annulus around it.We bin light curvesat1000sec to have enough statistics perbin.We show in Figure1the non constantlight curve of source IRAS20069+5929,which has the largest statistics of the4Chandra observations.We highlight thisvariability detection since it indicates thepresence of a point source even if the av-erage luminosity of this source has notchanged since RASS.2.2.Spatial distributionNo extent is evident in any of the foursources,although a low surface brightnesscomponent might be present;more detailedA.Wolter et al.:“Composite”Seyfert/Star-forming galaxies25 Table1.Properties of the4“Composite”galaxies under study.Name Redshift c/s R∗L X(2-10keV)L(FIR)ACIS-I cgs(Chandra)cgs26 A.Wolter et al.:“Composite”Seyfert/Star-forming galaxiesaccording to Persic et al.(2004)(dotted line is contribution from HMXB;dashed line is the total from the Starburst)or David et al.(1992)(solid line).The cur-rently observed X-ray luminosities of the sources are still at least about a factor of 10higher than both estimates.The AGN dominates in X-rays or the starburst com-ponent is anomalous.3.ConclusionsFrom the X-ray Chandra observations we conclude that the sources are:1)point-like in the Chandra images,although we can-not exclude a low surface brightness com-ponent;2)variable-both within the sin-gle Chandra observation(as in the case of IRAS20069+5929)and with respect to older data;3)a thermal component is in general not present,even if in a few cases it might account for part of the soft emis-sion;4)the intrinsic absorption measured in the X-ray band is small or not required by thefit;5)the current L X is still at least an order of magnitude higher than the pre-dictions from the starburst power,which is of the order of SFR=10-100M⊙/yr.Since the emission lines from the AGN are weak in the optical band,and absorp-tion is not detected in X-rays,we cannot suggest obscuration as responsible for hid-ing the optical AGN.Therefore we conclude that an AGN is present and dominant in X rays, but probably of low luminosity:L X(2-10 keV)=3.5×1041-7.×1042erg/s.This could explain the optical faintness observed by Moran et al.(1996). 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