Dileptons as Probes of High-Density Hadronic Matter Results from the SPS Heavy-Ion Programm
海洋学复习资料(董志南整理)

海洋学复习资料(董志南整理)个⼈观点,仅供参考,如有异议,欢迎讨论,敬请不吝赐教——董志南Water and Ocean Structure1.Why is water a polar molecule? What properties of water derive from its polar nature?Because Water structure is: one oxygen atom is in the above direction, two hydrogen atoms below are connected to the oxygen atoms. the bond angle of them is about 105 degrees,. The positively charged center of water is in the following, while the negative one is in the above. The two centers do not coincide, Polarity can not cancel each other out.Cohesion– the ability of water molecules to stick to each other, creating surface tensionAdhesion –the tendency of water molecules to stick to other materials, a good solventDissolving Property of WaterThese propertiese derive from water polar nature.2.How is heat different from temperature?Temperature is a measurement of the heat content of a body. Heat content is energy expressed in Joules or Calories. heat is thermal energy transferred from one object to another because of a temperature difference。
中国地质大学(北京)考博专业英复习材料

晶) is said to have a porphyritic texture(斑状结构). The classification of fine-grained rocks, then, is based on the proportion of minerals which form phenocrysts and these phenocrysts (斑晶)reflect the general composition of the remainder(残留) of the rock. The fine-grained portion of a porphyritic(斑岩) rock is generally referred to as the groundmass(基质) of the phenocrysts. The terms "porphyritic" and "phenocrysts" are not restricted to fine-grained rocks but may also apply to coarse-grained rocks which contain a few crystals distinctly larger than the remainder. The term obsidian(黑曜岩) refers to a glassy rock of rhyolitic(流纹岩) composition. In general, fine-grained rocks consisting of small crystals cannot readily be distinguished from③ glassy rocks in which no crystalline material is present at all. The obsidians, however, are generally easily recognized by their black and highly glossy appearanceass of the same composition as obsidian. Apparently the difference between the modes of formation of obsidian and pumice is that in pumice the entrapped water vapors have been able to escape by a frothing(起泡) process which leaves a network of interconnected pore(气孔) spaces, thus giving the rock a highly porous (多孔的)and open appearance(外观较为松散). ④ Pegmatite(结晶花岗岩) is a rock which is texturally(构造上地) the exact opposite of obsidian. ⑤ Pegmatites are generally formed as dikes associated with major bodies of granite (花岗岩) . They are characterized by extremely large individual crystals (单个晶体) ; in some pegmatites crystals up to several tens of feet in length(宽达几十英尺)have been identified, but the average size is measured in inches (英寸) . Most mineralogical museums contain a large number of spectacular(壮观的) crystals from pegmatites. Peridotite(橄榄岩) is a rock consisting primarily of olivine, though some varieties contain pyroxene(辉石) in addition. It occurs only as coarse-grained intrusives(侵入), and no extrusive(喷出的) rocks of equivalent chemical composition have ever been found. Tuff (凝灰岩)is a rock which is igneous in one sense (在某种意义上) and sedimentary in another⑥. A tuff is a rock formed from pyroclastic (火成碎 屑的)material which has been blown out of a volcano and accumulated on the ground as individual fragments called ash. Two terms(igneous and sedimentary) are useful to refer solely to the composition of igneous rocks regardless of their textures. The term silicic (硅质 的)signifies an abundance of silica-rich(富硅) and light-colored minerals(浅 色矿物), such as quartz, potassium feldspar(钾长石), and sodic plagioclase (钠长石) . The term basic (基性) signifies (意味着) an abundance of dark colored minerals relatively low in silica and high in calcium, iron, and
2023-2024学年山东省烟台市芝罘区八年级(上)期末英语试卷(五四学制)(含解析)

2023-2024学年山东省烟台市芝罘区八年级(上)期末英语试卷(五四学制)一、完形填空:本大题共10小题,共10分。
Wu Tianyi is 88 years old.As a doctor,he(1)______ in Qinghai for oversixty years.Wu came to Qinghai for work in 1958.There he saw many people have healthproblems and even die(2)______ the high altitude(海拔).At that time,noone in China studied on this area.He decided to work in this area.To find out the reasons (3)______ people got such health problems,Wu went on trips to places with a very high altitude.It was (4)______ for him.He had 14 bone fractures(骨折) during his trips.However,he never thought of(5)______ up.In the early 1990s,Wu made a hypobaric-hyperbaric chamber(高低压氧舱).The chamber played a very important(6)______ in the study of high altitude medicine.He (7)______ to be the first person to go into the chamber."I made it,and I (8)______ be the first one to try it," he said.But because the workers didn't have much experience with the chamber,Wu's hearing got damaged.He couldn't hear(9)______ from then on.Wu's study results are helpful.140,000 workers took part in the building of Qinghai-Tibet railway (青藏铁路),no one died.Today,Wu,in his(10)______,is still working hard.People say he is a guardian(守护者) of life.1.A. worked B. is working C. has worked D. will work2.A. because of B. instead of C. as for D. up to3.A. how B. why C. what D. where4.A. difficult B. easy C. exciting D. dangerous5.A. giving B. looking C. picking D. standing6.A. situation B. condition C. role D. environment7.A. volunteered B. refused C. agreed D. had8.A. can B. may C. must D. could9.A. correctly B. clearly C. exactly D. simply10.A. eighty B. eightieth C. eighty's D. eighties二、补全对话-填空:本大题共1小题,共5分。
Physical Chemistry of Solid State Electrolytes

Physical Chemistry of Solid StateElectrolytesSolid-state electrolytes (SSEs) have been studied extensively in recent years due to their potential to revolutionize energy storage technologies by enabling solid-state batteries with higher energy densities, longer cycle lives, and improved safety. Physical chemistry is an essential aspect of SSEs in understanding their fundamental properties and developing new materials with enhanced performances.Crystal Structures of SSEsThe crystal structure of SSEs is crucial for their ionic conduction properties. Most SSEs are composed of metal cations or non-metal anions arranged in a crystal lattice that forms a periodic network of voids or channels. The ionic conductivity of SSEs primarily depends on the accessibility of these channels for the movement of ions.For example, the lithium ion conductor Li10GeP2S12 (LGPS) features a tetragonal crystal structure composed of a three-dimensional network of corner-shared GeS4 tetrahedra. The large 12-coordinate Li+ ions occupy the large voids (12-fold coordination sites) between these tetrahedra, while the small 4-fold coordinated P5+ and S2- ions occupy the smaller voids (4-fold coordination sites), forming a disordered distribution pattern in the channels. This unique structure results in high lithium ion conductivity along the three crystallographic directions, achieving values up to 10^-3 S cm^-1 at room temperature.Defect Chemistry of SSEsThe presence of structural defects in SSEs can lead to enhanced ionic conductivity and electrochemical properties. Point defects (vacancies, interstitials) and line defects (dislocations, grain boundaries) can provide additional sites for charge carriers to move more easily through the material. These defects also affect the chemical stability andmechanical strength of SSEs, thus balancing the trade-off between ion conductivity and the electrolyte's structural integrity.For instance, the Li-ion conductor Li7La3Zr2O12 (LLZO) adopts a cubic garnet structure composed of alternating metal oxide layers and Li+ conducting channels. The presence of lithium and oxygen vacancies in the garnet structure can promote Li+ hopping between adjacent octahedral coordination sites, which is the rate-determining step of ionic conduction in LLZO. The introduction of excess lithium ions via Li2CO3 doping can further increase the ionic conductivity of LLZO by creating new lithium vacancies as well as enhancing the lithium-ion diffusivity.Interface Chemistry of SSEsThe interfacial behavior between the SSE and active electrode materials significantly impacts the battery's performance and stability. Understanding the interface chemistry can help design new SSE-electrode material combinations with enhanced electrochemical performance.For example, the Li-ion cathodes used in lithium-ion batteries usually feature a layered oxide structure, such as LiCoO2, which undergoes structural changes (e.g., structural phase transitions, oxygen loss) during cycling that can result in capacity fading and safety issues. The use of SSEs, such as LiPON (Li3.3PO3.8N0.2) or LLZO, as the electrolyte can suppress the side reactions and prevent the degradation of the electrode material. LiPON forms a thin, uniform, and dense interfacial layer between the cathode and electrolyte that blocks the diffusion of active species and protects the cathode from environmental degradation. LLZO, on the other hand, provides a greater degree of mechanical stability and electrochemical reliability due to its high chemical stability and compatibility with most electrodes.ConclusionThe physical chemistry of SSEs plays a critical role in determining their electrochemical properties and their interactions with other materials in energy storage devices such as batteries and supercapacitors. SSEs need to balance their ionicconductivity with thermal stability, mechanical integrity, and chemical compatibility to enable the development of solid-state batteries with better performance. Further studies on SSEs, including their crystal structures, defect chemistry, and interface chemistry, are necessary to improve the energy density, cycle life, and safety of SSE-based energy storage devices.。
TDLAS a laser diode sensor for the in situ monitoring of H2O, CO2 and their isotopes

TDLAS a laser diode sensor for the in situ monitoring of H 2O,CO 2and their isotopes in the Martian atmosphereT.Le Barbua,b,*,I.Vinogradov c ,G.Durry a,b ,O.Korablev c ,E.Chassefie`re a ,J.-L.Bertaux a aService d’Ae´ronomie du CNRS,Atmospheres Planetaires,BP 3–Reduit de Verrieres,Route des Gatines,91371Cedex Verrie `res-le-Buisson,France bGroupe de Spectrome´trie Mole ´culaire et Atmosphe ´rique,Moulin de la Housse 51687,Reims,France cSpace Research Institute (IKI),84/32Profsoyuznaya,117997Moscow,RussiaReceived 1November 2004;received in revised form 15April 2005;accepted 16April 2005AbstractWithin the framework of Pasteur-Exomars,we have proposed to measure in situ water vapor (H 2O,HDO,H 218O,H 217O)and carbon dioxide (CO 2,13C 16O 2,16O 12C 18O,16O 12C 17O)isotopes and also CO,CH 4and N 2O by absorption spectroscopy using nearinfrared laser diodes.The Service d ÕAe´ronomie has a relevant experience in trace-gas detection with laser diodes.We have devel-oped,with the support of the CNES and the CNRS,the SDLA diode laser spectrometer to measure in situ H 2O (at 1.39l m),CH 4(1.65l m)and CO 2(at 1.60l m)in the middle atmosphere from stratospheric balloons.The concentrations are obtained with a precision error of a few percent and with a high temporal resolution that ranges from 10ms to 1s.The developed laser probing technique should be also highly efficient to study the Martian atmosphere as there are much higher amounts of water vapor and carbon dioxide in the Martian atmosphere than in the lower stratosphere (H 2O:200ppmv at 6hPa on Mars,5ppmv at 10hPa in the low stratosphere (LS);CO 295%on Mars,360ppmv in the LS).Hence,we propose to adapt the laser probing technique to the Martian atmosphere.The main objectives are to determine water vapor and carbon dioxide fluxes and to study boundary layer properties.The sensor will provide in situ daily,diurnally resolved measurements of near-surface H 2O and CO 2concentrations over seasonal time scales.The additional isotopic measurements will provide quantitative constraints on the evolution of atmo-spheric composition and on the history of water on Mars.Ó2005COSPAR.Published by Elsevier Ltd.All rights reserved.Keywords:Laser diode;Absorption spectroscopy;Water vapor;Carbon dioxide;Isotopes;Mars atmosphere1.IntroductionThe laser diode probing technique is highly efficient to provide in situ trace-gas measurements at high tem-poral and spatial resolutions and with a high selectivity in the analyzed species (Durry et al.,2002a ).We have previously combined laser diodes and absorption spec-troscopy to monitor methane,carbon dioxide and water vapor in the middle atmosphere of the Earth fromballoon-borne platforms (Durry and Megie,1999).Fig.1shows an example of in situ vertical concentration profiles of H 2O,CH 4and CO 2yielded by the SDLA(Spectrome`tre a `Diodes Laser Accordables)balloon-borne diode laser spectrometer in the troposphere and the lower stratosphere.The profiles consist of a few thousands of in situ mea-surements yielded at 1s intervals with a precision error that ranges from 5%to 10%.The achieved dynamical range of the measurements is of five orders of magnitude which allows monitoring continuously H 2O in the upper troposphere and lower stratosphere despite the strong0273-1177/$30Ó2005COSPAR.Published by Elsevier Ltd.All rights reserved.doi:10.1016/j.asr.2005.04.049*Corresponding author.Tel.:+33326918812.E-mail address:tlebarbu@aerov.jussieu.fr (T.L.Barbu)./locate/asrAdvances in Space Research 38(2006)718–725concentration gradients between both regions of the Earth atmosphere (Durry et al.,2002a ).The developed laser probing technique should be also highly efficient to study the Martian atmosphere (May et al.,2001)as there are much higher amounts of water vapor and carbon dioxide in the Martian atmosphere than in the lower stratosphere (H 2O:200ppmv at 6hPa on Mars,5ppmv at 10hPa in the LS;CO 2:95%on Mars,360ppmv in the LS).Table 1shows the predicted absorption depths (i.e.,the percentage of absorbed laser energy)for the selected molecular species.Hence,we propose to adapt the laser probing tech-nique to the Martian atmosphere.With the support of the CNES,we have been developing for two years the TDLAS (Tunable Diode Laser Spectrometer)sensor that is described in this paper.The instrument is made within the framework of a collaboration between theService d ÕAe´ronomie (CNRS,Paris),the Space Research Institute (IKI,Moscow)and the Groupe de Spectrome´trie Mole´culaire et Atmosphe ´rique of the University of Reims (CNRS,Reims).The main objectives are to determine water vapor and carbon dioxide fluxes and to study boundary layer properties.The sensor will pro-vide in situ daily,diurnally resolved measurements of near-surface H 2O and CO 2concentration over seasonal time scales (Titov,2002;Tokano,2003).The additional isotopic measurements will provide quantitative con-straints on the evolution of atmospheric composition and on the history of water on Mars (Bertaux and Montmessin,2001;Krasnopolsky,2000).To reach the science objective,a precision error within a few percents in the concentration retrieval and a temporal resolution of 1s is needed for the developed sensor.2.MethodologyThe laser probing technique is based on the frequency tuning of a single mode emission laser diode over a rota-tion–vibration transition of a molecule of interest.The laser emission wavelength is scanned over the selected molecular transition by ramping of the laser driving cur-rent.The laser beam is propagated in the open atmo-sphere over an adequate absorption path length and is absorbed in situ by the ambient molecules.The absorp-tion of laser energy is related to the molecular absorp-tion by use of the Beer–Lambert law and a molecular model (Durry et al.,2002a ).The achieved detection limit is of 10À5(expressed in absorption units)for a 1-s mea-surement time (Durry et al.,2000).TDLAS is based on the use of distributed feedback (DFB)GaInSb near-infrared laser diodes emitting in the 1.5–2.1l m range.This laser technology iswell-Fig.1.(a)The SDLA balloon-borne spectrometer.(b)An example of achieved H 2O,CH 4and CO 2in situ vertical concentration profiles in the middle stratosphere.Table 1Simulation of molecular absorption (T =210K,P =9mbar)Molecule Spectral region (l m)Absorption path length Absorption (%)H 2O 200ppmv 1.88120cm 1.2CO 20.95% 1.88120cm 0.413CO 2TIR 2.04120cm 416O 12C 18O TIR 2.04120cm 0.7H 218O TIR 2.610m 0.02H 217O TIR 2.610m 0.02HDO2.610m0.04The molecular parameters are extracted from the HITRAN database.Terrestrial isotopic ratios (TIR)were used.Regarding HDO,the iso-topic ratio is found in Krasnopolsky (2000).T.L.Barbu et al./Advances in Space Research 38(2006)718–725719adapted to spectroscopic applications by its spectral emission properties;the spectral emission is monochro-matic,it is tunable over an average spectral range of 10cmÀ1,the line width is of a few MHz(much less than the average molecular line width at Martian pressure, i.e.,less than1GHz)and the output power is of a few mW.These lasers are operated at room temperature and a Peltier thermo-element is sufficient to obtain a sta-ble laser emission.Furthermore,highly sensitive and lin-ear detectors are available in the near infrared spectral range to develop compact sensors.A DFB GaInSb laser diode emitting at1877nm can be used for the simultaneous monitoring of H2O and CO2.Fig.2shows a simulated absorption spectrum un-der Martian conditions:95%of carbon dioxide and 200ppmv of water vapor for a120cm absorption path length.The absorption levels are of the same order of magnitude,despite the very different proportions,due to the line strengths(cm2moleculeÀ1cmÀ1)which are1.056·10À24for CO2and1.77·10À20for H2O accord-ing to the HITRAN databases(Rothman et al.,2003).Taking into account the limited tunability range ofthe laser used and the shape of the Martian near infraredspectrum,it is necessary to use one dedicated laser foreach selected specie and its isotopes.Hence,a second la-ser diode emitting around2042nm is used for CO2iso-topes(13C16O2and16O12C18O).In the absence of aprecise knowledge of the isotopic concentrations,itwas reasonable to take terrestrial ratio values as a start-ing point.Simulations(Fig.3),using the available linestrengths and terrestrial isotopic ratios given by HI-TRAN,show that,for a120cm absorption path length,the absorption levels(for example,7·10À3for 16O12C18O)are nearly3order of magnitude above the detection limit(detection limit of10À5expressed inabsorption units).Even with important differencewithFig.2.Simulated absorption level of CO2and H2O.Fig.3.Simulated absorption level of carbon dioxide isotopes.720T.L.Barbu et al./Advances in Space Research38(2006)718–725regards to the terrestrial values,it will be possible to make the measurements.The two laser diodes at1877and2042nm were pur-chased from Nanoplus GmbH and are presently under test in our laboratory.Regarding the water isotopes,HDO,H218O and H217O,a third laser diode is needed to reach strong molecular transitions in the2.6l m spectral range.This laser is under development with the support of the CNES by the Centre dÕElectronique et Micro-Optoe´lect-ronique de Montpellier(CEM2,CNRS,France).Water isotopes measurements require a much longer absorp-tion path length;at least10m are needed.With a10 m optical path length,simulations in Table1show that the absorptions of H217O and H218O(0.02%or2·10À4 expressed in absorption units)are roughly one order of magnitude above the detection limit.Considering lower isotopic ratios which may be encountered on Mars and water concentrationfluctuation,this length is to be con-sidered as the lower length limit.This would signifi-cantly increase the total mass of the instrument because it would make it necessary to use of a compact optical multipass cell(Durry et al.,2002b).So we can provide three versions of TDLAS accord-ing to the science objectives and size requirements.Two light versions(<500g):One version with a single laser (H2O and CO2measurements),a second version with two lasers(H2O,CO2and CO2isotopes measurements); and a third heavier version(<1kg)with the three lasers combined(H2O,CO2,13C16O2,16O12C18O,HDO, H218O,H217O).In the following section,we focus on the H2O/CO2sen-sor at1877nm.We also show the test of the available la-ser diode for carbon dioxide isotopes but the full isotopic version will be described in a further paper as soon as the needed2.6l m laser becomes available at the end boratory testsPresently,we are testing in the laboratory the spectral emission properties of the Nanoplus lasers to ensure they are monochromatic,by using Fabry–Perot confocal interferometers.A well-defined laser line shape(with no mode hops over the tunability range)is important toget boratory spectrum featuring CO2and H2O lines(see Fig.6.)with Fabry–Perot fringes used for frequency calibration;optical path69.6m, P=13.4mbar at roomtemperature.Fig.5.(Bottom)Layout for the spectroscopic study of water:PDstands for photodiode;FP for Fabry–Perot;Slow mod.for Slowmodulation;Temp.Cont.for temperature controller.(Top)For CO2study,a White type multipass optical cell is used.T.L.Barbu et al./Advances in Space Research38(2006)718–725721accurate measurements (Durry and Megie,1999)as the molecular profile is convolved with the apparatus func-tion (i.e.,the laser line shape).For example,Fig.4shows well-defined FP fringes,recorded simultaneously with the absorption spectrum of CO 2and H 2O,which indi-cate monochromatic wavelength emission over the re-gion of interest and also a good linearity in the laser frequency tuning.Furthermore,according to the Beer–Lambert law (Parvitte et al.,2002)the achieved accuracy in the con-centration retrieval is directly related to the accuracy in knowing the molecular line strength.Hence,the line strengths of CO 2and H 2O as well as carbon dioxide iso-topes are currently being revisited in our laboratory to improve accuracy.The experimental set-up is shown in Fig.5.The laser wavelength is temperature stabilized by means of a Peltier element and is driven by a low noise current supply.A low frequency ramp at 100Hz is used to scan the DFB diode over the selected absorp-tion lines by modulation of the driving current.The la-ser beam is divided into two beams.One beam is coupled with a confocal Fabry–Perot interferometer used for frequency calibration (free spectral range 0.00945cm À1).The other beam passes through an absorption cell:either a White type multipass cell of 69.6m for CO 2,or of 21.6m for its isotopes,or a sim-ple 10-cm cell for water.These absorption path lengths are only necessary for spectroscopic studies.They pro-vide strong absorption depths which enable the proper retrieval of line parameters.Once these spectroscopic parameters are accurately known,they can be used to retrieve the concentration from in the situ Martian spectra.Indeed,to record the in situ spectra in the Martian atmosphere shorter path lengths in combina-tion with differential detection technique will be used to dramatically reduce the overall weight of the sensor by simplifying the opticalscheme.boratory measurements with the laser diodes emitting at 1877nm (top)and 2042nm (bottom).722T.L.Barbu et al./Advances in Space Research 38(2006)718–725After this spectroscopic work,we will directly test the performance of TDLAS by coupling the sensor with a temperature stabilized 1m single pass cell to perform measurements at Martian low temperatures (Parvitte et al.,2002)and mixing ratios to check the matching of the achieved detection limit.The signals are sent to a digital oscilloscope and to a personal computer for data acquisition.We use the refer-ence spectrum of an empty cell to remove the sloping background (produced by the output power modulation due to the current ramping)and to extract the molecular transmission.To retrieve the coefficients of the line (intensity,pressure-broadening coefficient),we fit a Voigt profile to the molecular transmission using the known optical path lengths inside the cells,pressure,temperature and relative frequency calibration (given by FP fringes).The whole set up takes place in a closed box filled with dry nitrogen at atmospheric pressure in order to minimize the absorption by ambient water vapor.Fig.6shows laboratory measurements of the molec-ular transitions selected for TDLAS.The spectroscopic work (accurate determination of the line strengths)is under way and should be finished at the end of this year.Our tests of the spectral emission properties show that these laser diodes are suitable for trace-gas detection.4.TDLAS instrumentFig.7is a schematic diagram of the light-weight sin-gle-diode version of TDLAS which is the first step of the project.The sensor measures CO 2and H 2O simulta-neously by absorption spectroscopy using a DFB GaInSb laser diode at 1877nm.The laser emission wavelength is scanned over the selected rotation–vibra-tion transitions by modulation of the laser diode driving current at constant temperature.The temperature is measured with a thermistor bridge and regulated within±0.01°C with the proportional integral control of a thermoelectric cooler (i.e.,Peltier element).This precise control is achieved using a hybrid controller provided by Hytek Microsystems,Inc.The laser beam is propagated in the atmosphere over a 120cm folded path length and absorbed in situ by the ambient molecules (Figs.7and 8).The prototype uses the combination of a spherical mirror (focal length 30cm)and a flat mirror to achieve this folded optical path.The absorption spectra,consisting of 300sample points,are recorded at 10ms-intervals by means of a balance differential detection set-up using InGaAs pho-todiodes (Durry and Megie,1999;Durry et al.,2000).Ramping of the driving current to scan a spectral region also produces a modulation of the output power of the laser diode.The differential detection technique allows removal of this sloping background and to apply the full dynamic range of measurement (16bits)to the weak absorption signal.The electronic set up is displayed in Fig.9.The overall electronic control of the instrument is provided by a rad-hard 80C328-bit microcontroller from Atmel which is also used by the SPICAM instru-ment onboard Mars Express.The atmospheric mixing ratios are then retrieved from the in situ spectra using the Beer–Lambert law and a molecular model (Parvitte et al.,2002).The achieved precision error in the concentration re-trieval is of a few percents and can be enhanced by fur-ther co-adding successive 10-ms measurements.The detection limit is 10À5expressed in absorption unit (i.e.,0.001%of absorbed laser energy)when co-adding measurements for 1s.For instance,more details upon the performances of our detection technique are given in Durry et al.(2000),it was possible in the laboratory to reach the shot noise limit.The general characteristics of the sensor presently under development are summa-rized in Table 2.Fig.7.Schematic diagram of the single laser diode version of TDLAS.T.L.Barbu et al./Advances in Space Research 38(2006)718–725723In the usual processing way (onboard the balloon-borne instruments)the full spectrum is recorded with 256sample points taken on each channel (A,B,A–B)with a 16bit digitizer;the atmospheric spectra are then processed after the balloon flights.Regarding the Mar-tian sensor,for the processing,we intend to develop areal-time inversion model and also,if possible,a part of the raw spectra will be transmitted to the Earth.The development of a real time inversion model is facil-itated at Martian pressures because (compared to Earth)the collisional pressure-broadening effect is negligible;the Martian molecular profiles are dominated by the Doppler effect and the concentration is directly related to the absorption depth.Thus,data could be processed in situ with a simplified molecular model.Environmental effects,such as dust deposition on op-tics or frost,are also considered.With regard to dust,the laser power output is sufficient so that we can loose energy by partial occultation without significantly degrading the measurements,the atmospheric signal being balanced with the reference signal before each measurement.Of course,it would probably be necessary to implement protection hardware for extended mission scenarios.Nevertheless,the ultimate layout of the instrument will depend on the mission configuration (location on a lander,rover,or coupled with another instrument in a closed configuration with filtering and pumping system)and is therefore not further discussed.But we plan to implement a miniaturized version of the motorized shutters presently used with the SDLA to protect the mirrors Õsurfaces which would be used during intense dust activity or power offphases.And concern-ing frost,the mirror will be heated with flat Kapton resistor to avoid ice formation,similarly to what is done with SDLA.5.ConclusionPreliminary experimental results show that a high precision compact H 2O–CO 2laser sensor can be imple-mented using a DFB GaInSb laser diode emitting at 1877nm.Such instrument would give valuable informa-tion about the water and carbon cycles on a diurnal and a seasonal time scale at ground level.These kind of pre-cise in situ measurements are necessary to investigate the surface–atmosphere coupling which is of importance for a better understanding of the long-term evolution of subsurface water distribution and of carbon dioxide.AcknowledgmentThe described work was supported by Centre National d ÕEtudes Spatiales,by the Region Cham-pagne-Ardenne.ReferencesBertaux,J.L.,Montmessin,F.Isotopic fractionation through watervapour condensation:the Deuteropause,a cold trap for DeuteriumTable 2Characteristics of TDLAS sensor Mass 170g (without arm)SizeMain instrument:6cm (length);3cm (width);3cm (height),spherical mirror f =30cm;1.5cm (L)2cm (W);2cm (H)Power consumption 4–6W peakOptical path Open to the atmosphere 120cm Laser diode DFB GaInSb 1877nmOperating temperature:26°CDetectorsInGaAs photodiode (cut-offfrequency 2.2l m)Measurement time 10ms for one laser scanMinimum detectable absorption level 10À4(absorption units,one scan)10À5(1s)Precision error A few percentsData volume*600bytes/measurement (CO 2and H 2O)–Not compressed*Less if in situ processingFig.8.3D view of the instrument in the single laser diode configuration.724T.L.Barbu et al./Advances in Space Research 38(2006)718–725in the atmosphere of Mars.J.Geophys.Res.106(E12),32,879–32,884,2002.Durry,G.,Megie,G.Atmospheric CH4and H2O monitoring with near-infrared InGaAs laser diodes by the SDLA,a balloon-borne spectrometer for tropospheric and stratospheric in situ measure-ments.Appl.Opt.38,7342–7354,1999.Durry,G.,Pouchet,I.,Amarouche,N.,et al.Shot-noise-limited dual-beam detector for atmospheric trace-gas monitoring with near-infrared diode laser.Appl.Opt.39,5609–5619,2000.Durry,G.,Hauchecorne,A.,Ovarlez,J.,et al.In situ measurement of H2O and CH4with telecommunication laser diodes in the lower stratosphere:dehydration and indication of a tropical air intrusion at mid-latitudes.J.Atmos.Chem.43,175–194,2002a.Durry,G.,Danguy,T.,Pouchet,I.Open multipass absorption cell for the in situ monitoring of stratospheric trace gas with telecommu-nication laser diodes.Appl.Opt.41,3424–3433,2002b.Parvitte,B.,Zeninari,V.,Pouchet,I.,et al.Diode laser spectroscopy of H2O in the7165–7185cmÀ1range for atmospheric applications.J.Quantum Spectrosc.Radiat.Transf.75,493–507,2002. Krasnopolsky,V.On the deuterium abundance on Mars and some related problems.Icarus148,597–602,2000.May,R.D.,Forouhar,S.,Crisp,D.,et al.The MVACS tunable diode laser spectrometers.J.Geophys.Res.106,17673–17682,2001. Rothman,L.S.,Barbe, A.,Benner, D.C.,et al.The HITRAN molecular spectroscopic database:edition of2000including updates through2001.J.Quantum Spectrosc.Radiat.Transf.82, 5–44,2003.Titov,D.V.Water vapour in the atmosphere of Mars.Adv.Space Res.29,183–191,2002.Tokano,T.Spatial inhomogeneity of the Martian subsurface water distribution:implication from a global water cycle model.Icarus 164,50–78,2003.T.L.Barbu et al./Advances in Space Research38(2006)718–725725。
高考英语考前突破阅读理解能力科普类人福岛核电站地下水受到放射污染素材

福岛核电站地下水受到放射污染High levels of a toxic radioactive isotope have been found in groundwater at Japan's Fukushima nu clear plant, its operator says.福岛核电站附近的地下水中发现高剂量有毒的放射性同位素。
Tokyo Electric Power Company (Tepco) said tests showed strontium-90 was present at 30 times the legal rate.The radioactive isotope tritium has also been detected at elevated levels.The plant, crippled by the 2011 earthquake and tsunami, has recent ly see n a series of water leaks and power failures.The tsunami knocked out cooling systems to the reactors, which melted down.Water is now being pumped in to the re actors to cool them but this has left Tepco with the problem of how to safely store the cont aminated water.There have been several reports of leaks from storage tanks or pipes.Sea samplesStrontium-90 is for med as a by-product of nuclear fission. Tests showed that levels of stront ium in grou ndwater at the Fukushima plant had increased 100-fold since the end of last year, Toshihiko Fukuda, a Tepco official, told media.Mr Fukuda said Tepco believed the elevated levels originated from a lea k of contaminated water in April 2011 from one of the reactors."As it's near where the leak from reactor number two happened and taking into account the situation at the time, we believe that water left over from that time is the highest possibility," he said.Tritium, used in glow-in-the-dark watc hes, was found at eight times the allowable level.Mr Fukuda said that samples from the sea showed no rise in either substance and the company believed the groundwater was being contained by concrete foun dations."When we look at the impact that is having on the ocean, the levels seem to be within past trends and so we don't believe it's having an effect."But the discovery is another set-back for Tepco's plan to pump groundwater from the plant into the sea, correspondents say.Nuclear chemist M ichiaki Furukawa told Reuters news agency that Tepco should not release contaminated water into the ocean."They have to keep it somewhere so that it can't escape outside the plant," he said. "Tepco needs to carry out more regular testing in specific areas and disclose everything they find."The Fukushima power plant has faced a series of problems this ye ar. Early this month, radioactive water was found leaking from a storage tank.The plant also suffered three power failures in five weeks earlier this year. A leak of radioactive water from one of the plant's underground storage pools was also detected in April.。
Preparation of Novel Room-Temperature Molten Salts by Neutralization of Amines

Electrochemical capacitors and rechargeable batteries composed of nonaqueous organic liquids promise high power and energy de-vices with long life. The organic electrolytes in these devices should have excellent ionic conductivity and a wide electrochemical window over a large temperature range. Room-temperature molten salts or ionic liquids are acknowledged as the next generation of electrolytes. In spite of their excellent characteristics,chloroaluminate-type molten salts are unstable to air and decompose in the presence of water. Re-cently,nonchloroaluminate room-temperature molten salts have been studied extensively as potential electrolytes because of their low vis-cosity,lack of volatility,and greater thermal and electrochemical sta-bility than aqueous electrolytes and chloroaluminate-type ionic liq-uids.1-17Room-temperature ionic liquids have also been studied as clean aprotic solvents and reagents for organic synthesis.18-20A variety of ionic liquids,based on new anions and cations,are being studied in order to realize superior properties in various appli-cations. Ionic liquids with bis[(trifluoromethyl)sulfonyl]imide anion (TFSI-) or BF4Ϫgenerally have low melting point,low viscosity,and high ionic conductivity.5,7,12For the cation structure,quaternary ammonium,10,16,17pyridinium,11pyrazolium,15and imidazolium salts5are frequently used,producing molten salts at ambient tem-peratures. The characteristics of room-temperature molten salts are known empirically to depend strongly on the position and length of hydrocarbon constituents. Some asymmetric onium salts have a melting point below room temperature. However,the obvious corre-lation between cation structure and the capacity to form a room-tem-perature ionic liquid has never yet been reviewed.Synthesis of nonchloroaluminate molten salts requires two steps, the alkylation of a tertiary amine by alkyl halide,followed by the ex-change of the halide anion with the corresponding anion. This meth-od is very useful for hydrophobic products containing TFSIϪ,PF6Ϫ, AsF6Ϫ,or [C(SO2CF3)3]Ϫ,because the by-products can mostly be removed with water.2,4,5,17,21,22By contrast,hydrophilic ionic liq-uids are obtained by metathesis between onium halide and silver or ammonium salts with the corresponding anion.1,2,5,7,22This proce-dure has some drawbacks. It is troublesome to recover the media with high purity because of the difficulty of completely removing by-products. In addition,silver salts are expensive and are environ-mentally detrimental. Therefore it is not easy to prepare many dif-ferent kinds of molten salts and evaluate their properties.A convenient method of preparation of diverse kinds of amine salts is required in order to study the relation between cation struc-ture and physical characteristics such as ionic conductivity. Accord-ingly,tertiary amine was neutralized by various acids to form addi-tion compounds. This neutralization technique permits the resulting salts to include the corresponding anions in a single-step reaction.Also,the purification process is simple since there are no by-prod-ucts or residue. This method allows easy and inexpensive prepara-tion of various kinds of onium salt having high purity.In this article we report the synthesis of room-temperature molten salts by neutralizing21distinct tertiary amines with tetrafluo-roboric acid. The effect of cation structure on physical properties such as melting point,glass transition temperature,and ionic con-ductivity was then investigated.ExperimentalMaterials.—21 distinct tertiary amine-salts were prepared by titration of tetrafluoroboric acid in ethanol with the corresponding tertiary amines. The salts obtained are assigned numbers in the right column of Table I.Salts,from 1to 14and 21,were purified by dropwise addition to an excess of dehydrated diethyl ether. Salts 15 and 16 were washed by excess of toluene. Salts 17 and 18 were recrystallized from ace-tonitrile or methanol,respectively. Salts from 1 to 19 were dried in a vacuum at 60ЊC for 2 days. Salts20 and 21 were obtained by lyo-philization and were dried in a vacuum at room temperature. Since some of these salts were hygroscopic under air,sample preparation, conductivity measurements,and other processes were carried out in a glove box filled with dry nitrogen gas. The water content greatly affected the electrical characteristics,and the water was eliminated as much as possible by the vacuum drying as mentioned above. The water was not detected by the proton nuclear magnetic resonance (1H-NMR) measurements.Methods.—Ionic conductivity measurements were carried out using a Schlumberger Solartron 1260 impedance/gain-phase analyz-er with a frequency range from 10 Hz to 10 MHz. Impedance data were analyzed by the complex impedance method. The temperature range was from 10 to 60ЊC. All the measurements were carried out under dry nitrogen gas atmosphere.Differential scanning calorimetry (DSC) measurement was car-ried out with a DSC-120 (Seiko Instruments Inc.) in an atmosphere of nitrogen gas. The temperature varied from Ϫ150 to 200ЊC at a heating rate of 10ЊC minϪ1.The structure of the molten salts was confirmed by 1H-NMR spectroscopy (JEOL ␣-500).Results and DiscussionNeutralized amines were produced by acid-base neutralization as shown in Scheme 1. Ethanol was used for neutralization because of the high solubility involved. This reaction was carried out in a batch in an ice bath and required little time or labor. No peaks were found corresponding to the starting materials nor any trace amount of water molecules,according to 1H-NMR measurements. Neutralization ofPreparation of Novel Room-Temperature Molten Salts byNeutralization of AminesMichiko Hirao,Hiromi Sugimoto,and Hiroyuki Ohno zDepartment of Biotechnology,Tokyo University of Agriculture and Technology,Koganei,Tokyo 184-8588,JapanExamples of a new class of onium salts bearing the tetrafluoroborate anion (BF4Ϫ) were prepared by neutralization of the corre-sponding amines. This method greatly simplifies the preparation of many organic molten salts. Some of the resulting neutralized amines displayed an ionic conductivity greater than 10Ϫ2S cmϪ1at room temperature. The largest ionic conductivity was observed in 2-methyl-1-pyrroline neutralized by HBF4. In addition,the ionic conductivity above the melting point is well described by the V ogel-Tamman-Fulcher formula. There is a correlation between the ionic conductivity of neutralized amines and of the corre-sponding alkylated onium salts having the same heteroaromatic rings. These neutralized amines are convenient models of onium salts having high ionic conductivity.©2000 The Electrochemical Society. S0013-4651(00)03-120-7. All rights reserved.Manuscript submitted March 27,2000; revised manuscript received August 7,2000.z E-mail:ohnoh@cc.tuat.ac.jpamine is an excellent method for simplifying and facilitating the syn-thesis and mass production of molten salts inexpensively.We now discuss the thermal behavior and ionic conductivity ofthese neutralized amines. Then we study the effect of cation struc-ture on these properties.Thermal properties and ionic conductivity.—The glass transition temperature (Tg ),melting point (Tm ),and ionic conductivity (i ) of the neutralized amines are set out in Table I. Some neutralized amines were obtained as molten salts with a melting point below the ambient room temperature. Many neutralized amines had a higher melting point than the corresponding starting amine. This shows that not every neutralized amine becomes an ionic liquid at room temperature.The ionic conductivity is governed principally by the mobility of dissociated carrier ions. The glass transition temperature Tg is a measure of the mobility of the matrix,in that the matrix has higher mobility as Tg decreases. McEwen et al. have reported the Tg of sev-eral imidazolium salts.12The Tg of pyrrolidinium salts have been presented by MacFarlane et al.11Since the values of Tg were quite low,even below Ϫ80ЊC,it can be taken that these room-temperature molten salts had remarkable mobility. They also showed a high ionic conductivity,in some cases almost 10Ϫ2S cm Ϫ1at 25ЊC. By con-trast,low Tg values were found in some neutralized amines,specif-ically numbers 1,2,3,4,13,and 20. They showed Tg below Ϫ70ЊC,which is lower than in other neutralized amines. They should,there-fore,have high ionic conductivity,as observed in typical onium-type ionic liquids.Figure 1 shows the Arrhenius plots of ionic conductivity for these neutralized salts. The ionic conductivity of 1,2,3,4,and 13 was high,as expected. These were comparable to a well-known onium-type ionic liquid,1,3-diethyl imidazolium bis(trifluoromethylsul-fonyl) imide (shown as X in Fig. 1). Salt 21 showed a high ionic con-ductivity of over 10Ϫ2S cm Ϫ1at room temperature because it had the lowest melting point. From Table I the neutralized amines 1,2,and 3 have melting points in the range from 10 to 60ЊC. However,these salts maintained their high ionic conductivity at low tempera-tures (Fig. 1). In spite of their moderate Tm,around room tempera-ture,no drop in ionic conductivity based on the phase change was observed. We conclude that they exhibit a supercooled state below the melting point.We next investigated the relationship between ionic conductivity and Tg or Tm of neutralized amine salts,as shown in Fig. 2. It is eas-ily comprehended that the salt having lower Tm generally shows higher ionic conductivity. Since the ionic conductivity at 50ЊC was plotted in Fig. 2,the series of ionic liquids was classified into two groups,i.e.,those having Tm higher than 50ЊC and those having a lower one. It should be noted here that those salts having Tm of around 50ЊC show relatively high ionic conductivity; salt 6 has Tm at 59.6ЊC but a high ionic conductivity. These are explained by the supercooling phenomenon of the molten salts as mentioned in the discussion of Fig. 1. It is generally effective to prepare the molten salts with lower Tm for higher ionic conductivity. On the other hand,the ionic conductivity of neutralized salts decreased with increasing Tg,or in other words,with decreasing mobility of the fluid. Howev-er,salt 20 has a lower ionic conductivity of about 10Ϫ4S cm Ϫ1at ambient temperature despite its low Tg value. The mobility of the matrix is clearly not the only factor governing ionic conductivity. The basicity of starting amines is important for the electrostatic interac-tion,and this may influence the conductivity. The effect of salt struc-ture on the ionic conductivity will be analyzed in the near future.We then investigated the degree of salt dissociation as a factor influencing the ionic behavior of amine salts according to the V ogel-Tamman-Fulcher (VTF) formula,{(T ) ϭAT Ϫ1/2exp[ϪB /(T ϪT 0)]}. This formula represents the absolute-temperature dependenceScheme 1.Figure 1. Temperature dependence of ionic conductivity of neutralized amines. Structure of salts from 1 to 21,see Table I. The ionic conductivity of 1,3-diethylimidazolium TFSI salt was also plotted (X) as a reference for a typical onium-type molten salt.Figure 2. Relation between ionic conductivity and glass transition tempera-ture or melting point of neutralized amines.of the ionic conductivity of a glass-forming liquid. Here A is a pre-exponential factor,B is related to the activation energy Ea,and T0is the ideal glass transition temperature. The value of T0was compared to the observed Tg of neutralized amines [r > 0.997 for log (i T1/2) vs. 1/(T-T0)]. Their conductivities fitted the VTF equation closely,as shown in Fig. 3. According to the VTF theory,the conductivity is independent of the glass transition temperature. If Tg were the main factor governing the ionic conductivity,the VTF plots should all be identical. However,the conductivity dependence on the temperature and the B value of neutralized amines no. 1,2,3,4,5,7,13,and 20 are at variance with each other (Fig. 3 and Table II). The dominant factor on the ionic conductivity is the number of carrier ions. Since the mobility of the matrix is normalized in the VTF equation,differences in the conductivity of neutralized salts should be caused by different degrees of dissociation into ions. In other words,it can be assumed that the higher B value of the neutralized salts results from the stronger temperature dependence of the dissociation energy. Salt 20 exhibited a value for B about twice that of other neutralized amines in Table II. We suggest that the ion-conduction mechanism of salt 20 is different from the others,so that its ionic conductivity is lower even where it has a similar Tg value. Of these,salt 1had the lowest B and the highest ionic conductivity. This salt was an outstanding ionic liq-uid with high matrix mobility and dissociation into ions.Effect of amine structure on physical properties of the salts.—In reports on alkylated imidazolium,pyrrolidinium,and quaternary ammonium salts,salts with rather small asymmetry tend to be liq-uids at ambient temperature,with low Tm and Tg,and high ionic conductivity. It seems that the ionic conductivity is greatly affected by the structure of the amine. We searched for optimum conditions for the preparation of room-temperature ionic liquids. In general,the ionic conductivity decreases with increasing molecular mass be-cause the number of ions per unit mass is less. We studied the rela-tion between molecular weight of the starting amine and the ionic conductivity at 50ЊC. The molecular weight of the cation and the ionic conductivity of the salts were not correlated.Next,the effect of substituent position on the properties of neu-tralized amines was investigated. We compared the ionic conductiv-ities of 5,6,7,and 8,obtained by the neutralization of lutidines,with different substituent positions. The low-symmetry salt 5,which had -CH3at positions 2- and 4 of the lutidine ring,showed the lowest Tg and Tm and the highest ionic conductivity of its class. Salt 6,with -CH3at positions 2 and 3,had the next highest ionic conductivity. The lowest ionic conductivity was observed in the symmetric salt 8, with -CH3at positions 2- and 6,together with the highest values of Tg and Tm. For indolium salts,the ionic conductivity of 11,prepared by the neutralization of 1-methylindole,was quite low and could not be detected at room temperature. Salts 15 and 16 were obtained as powder samples and showed high Tm and correspondingly low ionic conductivity,as for 11. On the other hand,salt 3,obtained from 1,2-dimethylindole,showed the lowest Tg at about Ϫ75ЊC,had a Tm of 24.5ЊC,and the highest ionic conductivity of nearly 10Ϫ2S cmϪ1at room temperature. We suggest that neutralized amines with sub-stituents at both 1- and 2- positions tend to be room-temperature molten salts. Neutralized amines from indole derivatives have the capability of being room-temperature molten salts with high ionic conductivity. We expect neutralized carbazole to have a high ionic conductivity,since carbazole is considered to be an indole derivative. The neutralized carbazolium salt 18 had a Tg of approximately 60ЊC, and almost no conductivity was observed over the whole tempera-ture range of measurement. Against this,salt 4,synthesized from 1-ethylcarbazole,had Tg of Ϫ68.0 and a high ionic conductivity of 2.210Ϫ3S cmϪ1at room temperature.From a comparison of these results,room-temperature molten salts with low Tg,and Tm and high ionic conductivity are best pre-pared by starting with low-symmetry heterocyclic amines having alkylated substituents at positions 1- and 2 of their ring.Model of alkylated room-temperature molten salts.—We now turn to the relation of the ionic conductivity for neutralized and alkylated imidazolium ionic liquids containing BF4Ϫ. Salt 19,obtained by the reaction of 1-methylimidazole and tetrafluoroboric acid,had relative-ly low ionic conductivity below its melting point of 36.9ЊC (Table I, Fig. 1). However,the ionic conductivity of this salt above its melting point was high at 2.8 ϫ10Ϫ3S cmϪ1at 50ЊC. Alkylated imidazoli-um salts should also have high ionic conductivity above their melting points. The melting point and ionic conductivity of 1-ethyl-3-methylimidazolium tetrafluoroborate (EtMeImBF4),which is a typi-cal room-temperature molten imidazolium salt,are reported to be 15ЊC and 1.4 ϫ10Ϫ2S cmϪ1at 25ЊC.7We also prepared several di-alkylated imidazolium salts using the standard method.1,2,4,5,7,17,21,22 We determined the ionic conductivity of EtMeImBF4to be about 2.0ϫ10Ϫ2S cmϪ1at 50ЊC.The high ionic conductivity of EtMeImBF4confirms that neu-tralized amines have the potential to be excellent models for quater-nized onium salts. Accordingly,alkylated amine salts such as 1,2,3, 4,13,and 21 are expected to form ionic liquids and have high ionic conductivities at room temperature. In fact,alkylated pyrrolidinium salts having not BF4Ϫbut TFSIϪas counteranion have been reported to be room-temperature molten salts with high ionic conductivity.11ConclusionWe have investigated the ionic conductivity and thermal proper-ties of 21 types of amine salt obtained by neutralization with tetra-fluoroboric acid. Those salts deriving from 2-methyl-1-pyrroline,1-ethyl-2-phenylindole,1,2-dimethylindole,1-ethylcarbazole,1-methylpyrazole,and 1-methylpyrrolidine have lower glass transition temperatures and melting points,and higher ionic conductivities, than other neutralized amines. The temperature dependence of their ionic conductivity was well fitted by the VTF formula. The neutral-ized 2-methyl-1-pyrroline dissociated more easily into ions than the other salts prepared. Cation structure also has an effect on ionic con-ductivity,and heterocyclic amines with alkylated substituents at both 1- and 2- positions were excellent starting materials for synthesizing room-temperature molten salts with desirable properties. In compar-ison of ionic conductivity between corresponding alkylated and neu-tralized ionic liquids,the neutralized amines proved to be effective as model compounds for the analogous alkylated amines. The prop-erties of alkylated amines are elucidated by the properties of the cor-responding neutralized amines,which are relatively easy to prepare.Figure 3. VTF plot of ionic conductivity for neutralized amines.AcknowledgmentThis study was supported by the Grant-in-Aid for Scientific Research from the Ministry of Education,Science,Sports,and Cul-ture of Japan (no. 11555250).Tokyo University of Agriculture and Technology assisted in meeting the publication costs of this article.References1.J. S. Wilkes and M. J. Zaworotko,J. Chem. Soc.,Chem. 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1941克林贝尔The Permeability Of Porous Media To Liquids And Gases

THE PERMEABILITY OF POROUS MEDIA TO LIQUIDS AND GASES
air might be of no significance or even definitely misleading. The question to be discussed here, however, is whether porous media in which no changes in the internal structure take place will show different permeability constants to different fluids. I t has been a point of much discussion in the literature' whether the walls of small capillaries, a s they occur in porous media, are able to adsorb molecules to such a n extent a s to build up more or less .rigid layers several molecules thick. Such adsorbed layers would reduce the effective pore diameter to a different degree for different liquids and, a s a consequence, the permeability of a porous mass would depend on the nature of the liquid. Some authors8 prefer to speak about an increase in viscosity of the liquid with a decreasing distance to the solid wall-which amounts, of course, to the same thing.
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a rXiv:n ucl-e x /99123v17D ec1999Dileptons as Probes ofHigh-Density Hadronic Matter:Results from the SPS Heavy-Ion Programme Itzhak Tserruya 1Weizmann Institute of Science,Rehovot,Israel Abstract The most recent results on dileptons obtained in the CERN heavy-ion programme are reviewed.The emphasis is on the excess of low-mass lepton pairs observed in the CERES,HELIOS-3and NA38/50experiments which seems to point at modifications of the vector meson properties,and in particular the ρmeson,in a high density baryonic medium.Recent results on intermediate mass dileptons are also presented.1Introduction The heavy-ion programme at the CERN SPS started in 1986with the acceler-ation of O beams at an energy of 200GeV/c per nucleon followed soon after by a S beam at the same energy.Since 1994the programme uses a Pb beam of 158GeV/c per nucleon.Among the vast amount of experimental results that have been gathered the observation of an excess emission of low-mass dilepton pairs appears as one of the most notable and intriguing achievements of the programme along with the J/ψsuppression and strangeness enhancement [1].Dileptons emitted in ultra-relativistic heavy-ion collisions are considered unique probes in the study of hadronic matter under extreme conditions of temperature and baryon density and in particular the conjectured deconfine-ment and chiral phase transitions.These penetrating probes have a relativelylarge mean free path and consequently can leave the interaction region without final state interaction,carrying information about the conditions and proper-ties of the matter at the time of their production and in particular of the earlystages of the collision when temperature and energy density have their largest values2.A prominent topic of interest is the identification of thermal radiation emit-ted from the collision system.This radiation should tell us about the nature of the matter formed,a quark-gluon plasma(QGP)or a high-density hadron gas(HG).The elementary processes involved are well known:q2The same argument is in principle valid for real photons,since real and virtual(dileptons) photons are expected to carry the same physics information.However,the physics background for real photons is larger by orders of magnitude as compared to dileptons,making the measurement of photons much less sensitive to a new source.2over a very broad range of invariant masses.The enhancement is particularly pronounced in the continuum at low-masses(0.2<m<0.7GeV/c2)but it is also significant in the continuum at intermediate masses(1.5<m<3.0GeV/c2) and in theφmeson yield.The low-mass pair enhancement has triggered a huge amount of theoretical activity mainly stimulated by interpretations based on in-medium modifications of the vector mesons and in particular a decrease of theρ-meson mass as a precursor of chiral symmetry restoration.Table1.List of Dilepton Measurements at the CERN SPS Experiment System Mass7,8 CERES S-Au200GeV/u0–1.410-12µ+µ− 3.65-4.913 (completed)““HELIOS-3p-W,S-W200GeV/u0.3–4.0µ+µ− 3.0-4.015 NA50Pb-Pb158GeV/u0.3–7.0are displayed in Fig.1.On the positive side,one notes that the results appear consistent with each other within their error bars.The level of agreement is remarkable if one keeps in mind the huge filtering of the data 3,the fact that these are two different data sets,and that they have been analyzed with the same strategy but with a somewhat different technique 4.1010101010m ee (GeV/c 2)(d2N e e/d ηd me e ) /(d Nc h/d η)(100 M e V /c2)-1Figure 1:Inclusive e +e −mass spectrum measured by CERES in 158A GeV Pb–Au collisions in the ’95and ’96runs.The figure also shows the summed (solid line)and individual (dotted lines)contributions from hadronic sources in a thermal model [12].The predictions from the pp cocktail previously used by CERES [7]are shown by the dashed line.As previously observed with the S beam [9],the e +e −pair yield is clearlyenhanced in the mass range above∼200MeV/c2and below theρ/ωpeak,with respect to the expected yield from known hadronic sources.The solid line shows the total expected yield based on a generator[12]which uses measuredparticle production ratios whenever available or ratios calculated with a thermalmodel which describes well all these ratios[20].With respect to this cocktail the measured yield in the mass region m=0.25-0.7GeV/c2is enhanced bya factor of2.6±0.5(stat.)±0.6(syst.).For comparison thefigure also shows(dashed line)the standard pp cocktail previously used in the presentation of the CERES results[7]and which is based on yields directly measured in ppcollisions,scaled to the nuclear case with the charged particle rapidity density. The two generators predict closely similar results.The total yield of the thermalmodel is∼30%larger than the pp cocktail for masses m>200MeV/c2,themain difference occuring in the region of theφmeson.CERES has further characterized the properties of the low-mass excess bystudying its p t and multiplicity dependences,which indicate that the excess ismainly due to soft pair p t and increases faster than linearly with the charged particle density[10,11,12].An enhancement of low-mass dileptons has also been observed in the di-muon experiments HELIOS-3[14]and NA38[15]with the S beam.NA38hasan interesting set of results including p-U,S-S and S-U collisions at200A GeV.Whereas the p-U data are well reproduced by a cocktail of hadronic sources (with the somewhat uncertain extrapolation of the Drell-Yan contribution intolow masses),the S data shows an enhancement of low-mass pairs.The enhance-ment is most apparent in the S-U collision system and there it clearly extends over the intermediate mass region as illustrated in Fig.2.There is a striking difference in the shape of the low-mass dilepton spectrum as measured by CERES and NA38.A pronounced structure due to the reso-nance decays is clearly visible in the NA38spectrum,whereas in the CERESresults the structure is completely washed out(see Fig.1),raising the question of consistency between the two experiments.Resolution effects can be readilyruled out since the low-mass spectrum in p-Be and p-Au collisions measured byCERES with the same apparatus clearly shows theρ/ωpeak[7].We also note that the two experiments cover nearly symmetric ranges around mid-rapidity(η=2.1–2.65andη=3–4in CERES and NA38respectively).But CERES hasa relatively low p t cut of200MeV/c on each track whereas NA38is restricted to m t>0.9+2(y lab−3.55)2GeV/c2.Moreover,NA38has no centrality selec-tion in the trigger whereas the CERES data corresponds to the top30%of the geometrical cross section.These two factors are likely to explain the apparentdiscrepancy since,as noted previously,the excess observed by CERES is morepronounced at low pair p t and increases stronger than linearly with multiplic-511010101010M (GeV)A *d σ/d M (n b /50 M e V )Figure 2:Inclusive µ+µ−mass spectra measured by NA38in 200A GeV S-U collisions.The thick line represents the summed yield of all known sources.The individual contributions are also shown [15].ity.Given enough statistics it should be fairly easy for the two experiments to apply common m t and centrality cuts thereby making possible a direct and meaningful comparison between their results.3Low-mass Dileptons:Theoretical Evaluation The enhancement of low-mass dileptons has triggered a wealth of theoretical activity.Dozens of articles have been published on the subject and clearly it is not possible to review them here.I present thus a summary of the current leading approaches.There is a consensus that an additional source beyond a simple superposition of pp collisions is needed.Furthermore,it is commonly recognized that the pion annihilation channel (π+π−→l +l −),obviously not present in pp collisions,has to be taken into account.This channel accounts for a large fraction of the observed enhancement however it is not sufficient to reproduce the data in the mass region 0.2<m e +e −<0.5GeV/c 2.These data have been quantitatively explained by taking into account in-medium modifica-6tions of the vector mesons.Li,Ko and Brown[21]were the first to propose and use a decrease of the ρ-meson mass in the hot and dense fireball as a precursor of chiral symmetry restoration,following the original Brown-Rho scaling [22].With this approach,an excellent agreement with the CERES dat is achieved as demonstrated by the solid line in Fig.3(taken from [6]).101010101000.20.40.60.81 1.2 1.4m ee (GeV/c 2)(d 2N e e /d ηd m e e ) / (d N c h /d η) (100 M e V /c 2)-1Figure 3:CERES results compared to calculations using dropping ρmass (Brown-Rho scaling),in-medium ρ-meson broadening and RBUU transport model.The dash-dotted line represents the yield from hadrons after freeze-out as in Figure 1.Another avenue based on effective Lagrangians uses a ρ-meson spectral func-tion which takes into account the ρpropagation in hot and dense matter,in-cluding in particular the pion modification in the nuclear medium and the scattering of ρmesons offbaryons [23,24].This leads to a large broadening of the ρ-meson line shape and consequently to a considerable enhancement of low-mass dileptons.These calculations achieve also an excellent reproduction of the CERES results as illustrated by the dashed line in Fig.3.Although the two approaches are different in the underlying physical picture (in the Brown-Rho scaling the constituent quarks are the relevant degrees of freedom whereas ref.[23]relies on a hadronic description),it turns out that the dilepton pro-duction rates calculated via hadronic and partonic models are very similar at SPS conditions [6]thus explaining the similar results of the two approaches.7Several issues remain controversial.Both approaches rely on a high baryondensity for the dropping mass or the enlarged width of theρmeson but the role of baryons is still a question open to debate.Calculations based on chiralreduction formulae,although similar in principle to those of ref.[23],find verylittle effect due to baryons and are in fact low compared to the data[25].The RBUU transport calculations of Koch[26]find also very little effect due tothe baryons and come to a reasonably close description of the data as shownin Fig.3by the dash-dotted line.This could be due to an overestimation of theωDalitz decay yield as a consequence of an increasedωyield directlyreflected in thefigure at m∼800MeV,which is dominated by theω→e+e−decay.Finally,I wish to point out the discrepancy between transport[24]andhydrodynamic calculations[27]in treating the time evolution of thefireball,the former yielding a factor of2-3higher yields.4Intermediate-mass DileptonsThe results of HELIOS-3[14]and NA38/50[15,16]clearly show an excess of dileptons in the intermediate mass region1.5<m<3.0GeV/c2(see Figs.2and4).The excess refers to the expected yield from Drell-Yan and semi-leptonic charm decay which are the two main contributions in this mass region. The shape of the excess is very similar to the open charm contribution and infact doubling the latter nicely accounts for the excess.This is the basis for thehypothesis of enhanced charm production made by NA38/50[16].However it is very unlikely that at the SPS energies charm production could be enhanced bysuch a large factor[28].HELIOS-3points into a different direction.The excess plotted as a function of the dimuon transverse mass can befitted by a singleexponential shape below and above the vector mesons[14],suggesting a com-mon origin of the excess in the low and intermediate mass regions.Following this line,Li and Gale[29]calculated the invariant dimuon spectrum in centralS-W collisions at200A GeV.On top of the physics background of Drell-Yanand open charm pairs,they considered the thermal radiation of muon pairs resulting from secondary meson interactions including higher resonances andin particular theπa1→l+l−.The calculations are based on the same rela-tivisticfireball model used to calculate the low-mass dileptons discussed in theprevious section[21].Their results are presented in Fig.4showing the totalyield(physics background+thermal yield)with the assumption of free masses (dotted line)and dropping vector meson masses(solid line).The latter leads toa much better agreement with the data at low masses(from0.3to0.7GeV/c2),as already mentioned in the previous section,whereas in the intermediate mass region the difference between free and in-medium meson masses with respect8Figure4:HELIOS-3dimuon data compared to calculations with free and in-medium meson masses[29].to the data is not so large.The calculations with free masses slightly overes-timate the data whereas with dropping masses the situation is reversed.The intermediate mass region alone cannot be used to validate the dropping mass model,however it is important that the model can explain simultaneously the low and intermediate mass regions.5Summary and OutlookThe measurements of dileptons both at low and intermediate masses have pro-vided very intriguing results.The outstanding physics question is to further elucidate the origin of the observed excess and its possible relation to chiral symmetry restoration.There are a number of open questions on the theoretical front:the role of baryons,the difference between transport and hydrodynamic calculations,the approach to chiral restoration(do masses drop to zero and/or do their width increase to infinity?),With the present accuracy of the data it is not possible to discriminate between the various models.Major new steps are foreseen in the near future.First,CERES is planning to dramatically improve the mass resolution to achieveδm/m=1%,by the ad-dition of a TPC downstream of the present double RICH spectrometer.With this resolution,which is of the order of the natural line width of theωmeson,9it should be possible to directly measure the yield of all three vector mesons ρ,ωandφincluding any possible changes in their properties(mass shift or in-creased width)thereby providing a better experimental tool to reveal possible in-medium modifications of the vector mesons.Second,a measurement is pro-posed at the lowest energy attainable at the SPS,at about40GeV/nucleon, where the effect of baryon density on the vector meson masses is expected to be st but not least,RHIC start of operations is behind the corner of-fering the possibility to extend these studies under better conditions of energy density and lifetime and to explore a new domain where temperature rather than baryon density is expected to be the dominant factor. 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