最新化学专业英语(修订版)翻译
化学专业英语3.12翻译

selective precipitation选择性沉淀
IF语句的应用
3.12Additional Aspects of Aqueous Equilibria
The phenomenon of lowering the degree of ionization
of a weak electrolyte by adding a solution of a strong
剂是一种与其共轭碱或酸有一种不同颜色的弱酸或碱。在 滴定曲线中一种强酸强碱的滴定的pH在等当点附近呈现出 一个巨大的变化。强酸弱碱或弱酸强碱滴定,在等当点附 近的pH值的变化不是很大bility equilibrium exists when a chemical compound in the solid state is in chemical equilibrium with a solution of that compound. The equilibrium is an example of dynamic and heterogeneous equilibrium in that some individual molecules migrate between the solid and solution phases such that the rates of dissolution and precipitation are equal to one another. The Solubility-product constant(or simply the solubility product),Ksp, is an equilibrium constant that expresses quantitatively the extent to which the compound dissolves. The Ksp is equal to the product of the concentrations of the ions involved in the equilibrium, each raised to the power of its coefficient in the equilibrium equition. The value of Ksp can be obtained from the solubility, and vice versa. Substances that have Ksp<<1 are classified as insoluble. Salts that have Ksp, between 10-2 and 10-5 are slightly soluble , and solids which have Ksp>10-2 are soluble. The solubility of a slightly soluble substance can be decreased by the presence of a common ion. The solubility of compounds containing basic anions increase as pH decreases. Salts with anions of negligible basicity (the anions of strong acids ) are unaffected by pH changes.
马永祥《化学专业英语》课文翻译 第14课

化学专业英语马永祥,兰州大学出版社课文翻译14. 含氧化合物醇和酚在醇的取代物和连结体的命名中,羟基作为主要基团,是通过后缀“醇”来表示,省略母体化合物名称末尾“e”(如果有的话),例如:甲醇,2-丙醇,三苯甲醇等。
下面是一些被保留的俗名的例子:烯丙醇,叔丁醇,苄醇,乙二醇,芳香醇等。
苯和其它芳香碳环族的羟基衍生物是通过在碳氢化合物名称加后缀“醇”“二醇”等命名的,“ol”前末端的“e”要省略,例如:1,2,4-苯三醇。
以下是一些芳香族羟基化合物仍被保留的俗名。
例如:苯酚,甲酚,荼酚,邻苯二酚,间苯二酚,对苯二酚等等。
基团RO-是通过在R基名称后加后缀“氧基”而命名,例如:戊氧基,烯丙氧基,苄氧基等,仅有下列含氧基团名称的缩写是不符合这一被推荐规则的:甲氧基,乙氧基,丙氧基,丁氧基,苯氧基,异丙氧基。
除去部分成环体系,二价基团-o-x-o-通过给双二价基团-x-名称附加“二氧基”而命名,例如:乙撑二氧基,丙撑二氧基。
盐醇或酚衍生的阴离子的命名是将醇或酚名称末尾的“-ol”变成“-olate”。
这一方法适用于取代基,官能团和俗名。
例如:甲醇钾,苯酚钠。
醚化合物R1-O-R2总称为“醚”,可以通过取代基或官能团来命名。
不对称醚取代物命名法是将基团R1O-的名称作为前缀加在相应第二个基团R2前面而形成。
较高级的组分被选作母体化合物。
醚的官能团命名法则是在基团R1和R2名称后面加“醚”字即可。
例如:1-异丙氧基丙烷,甲乙醚,二乙醚,乙基乙烯基醚。
醛醛是含有连结在C原子上的(C=O)H基团的化合物,命名是通过后缀“-al”“-aldehyde”或“carbaldehyde”或者是通过加前缀“formyl-”(当作为一个碳链的末端基团存在时代表-(C=O)H),或者与俗名有关,加前缀“oxo”(代表=0),无支链的非环的单醛或二醛的名字是通过给含有相同碳原子数的烃化合物的名字加后缀“-al”(对单醛)或“dial”(对双醛)形成。
(完整word版)化学专业英语(修订版)翻译

01 THE ELEMENTS AND THE PERIODIC TABLE01 元素和元素周期表The number of protons in the nucleus of an atom is referred to as the atomic number, or proton number, Z. The number of electrons in an electrically neutral atom is also equal to the atomic number, Z. The total mass of an atom is determined very nearly by the total number of protons and neutrons in its nucleus. This total is called the mass number, A. The number of neutrons in an atom, the neutron number, is given by the quantity A-Z.在一个原子核中的质子数量被称为原子序数,或质子数,Z。
在一个电中性原子中的电子数量也等于原子序数,Z。
一个原子的总质量被测定是非常接近于原子核中质子和中子的总数。
这个总数被称为质量数,A。
在一个原子中的中子数量等于A – Z的数量。
The term element refers to, a pure substance with atoms all of a single kind. To the chemist the "kind" of atom is specified by its atomic number, since this is the property that determines its chemical behavior. At present all the atoms from Z = 1 to Z = 107 are known; there are 107 chemical elements. Each chemical element has been given a name and a distinctive symbol. For most elements the symbol is simply the abbreviated form of the English name consisting of one or two letters, for example:这个术语(指chemical element)也可以指由相同质子数的原子组成的纯化学物质。
化学专业英语翻译(修订版) 33 化学反应速度

化学专业英语翻译(校准版)33 化学反应速度Introduction介绍In this chapter we look into how chemical reactions occur. The principal aspect we examine is the rate of a reaction, and we shall see how it. depends on the temperature and the concentrations of the species that are present.在本章中,我们来看看化学反应是如何发生的。
我们研究的主要的方面是反应速率,我们将看到温度和存在的物质的浓度是如何影响化学反应速率的。
There are two main reasons for studying the rates of reactions. The first is the practical importance of being able to predict how quickly a reaction mixture will move its equilibrium state: the rate might depend on a number of factors under our control, such as the temperature, the pressure, and the presence of a catalyst, and, depending on our aims, we may be able to make the reaction proceed at an optimum rate. For instance, in an industrial process it might be economical for the reactions to proceed very rapidly; but not so rapidly as to produce an explosion. By contrast, in a biological process it may be appropriate for a reaction to proceed only slowly, and to be switched on and off at the demand of some activity.研究反应速率的主要原因有两个。
化学专业英语翻译

(or base) as a function of the volume of added base (or acid)
is called a pH titration curve. A pH indicator is a weak acid or base
that has a color that is different from that of its conjugate base or
IF语句的应用
缓冲液是一种由混合弱酸及其共轭碱或弱碱及其共轭 酸组成的水溶液。它具有当加入少量的强酸或强碱时,溶 液的pH变化不大的性质。缓冲溶液在各种化学应用中用来 保持pH的值几乎不变。溶液的缓冲能力指的是加入大量的 H3O+或OH-缓冲溶液不会超过规定的pH范围。缓冲范围是指 在pH范围内缓冲液有效的中和加入的酸或碱的量。缓冲溶 液的pH,pKa和弱酸及其共轭碱之间的关系可以用H-H方程 表示为: pH=pKa+lg{[共轭碱]/[弱酸]}
IF语句的应用
An acid-base titration is the determination of the concentration
of an acid or base by exactly neutralizing the acid/base with an
acid or base of known concentration. The plot of the pH of an acid
dissolution溶解
precipitation沉淀
Solubility-product constant溶度积常数
insoluble不溶的
slightly soluble微溶的
化学专业英语(删减版)翻译

20THE ROLE OF PROTECTIVE GROUPS IN ORGANIC SYNTHESIS20有机合成中保护基团的使用If a satisfactory protective group has not been located,the chemist has a number of alternatives:rearrange the order of some of the steps in the synthetic scheme so that a functional group no longer requires protection or a protective group that was reactive in the original scheme is now stable;redesign the synthesis,possibly making use of latent functionality(i.e.,a functional group in a precursor form;e.g.,anisole as a precursor of cyclohexanone).Or,it may be necessary to include the synthesis of a new protective group in the overall plan.如果找不到符合要求的保护基,化学家仍然具有大量可供选择的方法:重新安排合成系统中一些步骤的顺序,保证官能团不再需要保护或者在原来的系统中的活性保护基现在变得稳定;可能利用潜在的功能重新设计合成(也就是功能性基团以前驱体形式出现;例如:茴香醚作为环己酮的前驱体)。
或者,有必要在总体计划中包括新保护基的合成.22POLYMERS22聚合物The process by which small molecules undergo multiple combinations to form macromolecules is polymerization.Small molecules from which a macromolecule or polymer can be made are called monomers.Two types of polymerization are recognized: (1)condensation polymerization and(2)addition polymerization.A polymer-forming reaction involving elimination of a small molecule such as water or alcohol between monomer units is described as condensation polymerization.In addition polymerization, unsaturated or cyclic molecules add to each other without elimination of any portion of the monomer molecule.The empirical formula of the polymer is then,of course,the same as that of the monomer.小分子进行多重结合形成大分子的过程叫做聚合反应。
化学专业英语翻译

第一章化学物质和测量的科学改变它的物质和经历。
化学家们研究了组成、结构及性能的事。
他们观察问题的变化经历和测量能源生产和消费在这些变化。
提供了一个了解化学的许多自然事件,导致合成新形式的问题,已严重影响我们的生活方式。
在化学学科按传统的类型或类物质在研究的学习。
这些包括无机化学、有机化学、物理化学、分析化学、高分子化学、生物化学、和许多更多专业的学科,例如radiochemistry、理论化学。
化学通常被称为“中央科学”,因为它连接其他自然科学如天文、物理、材料1.1.问题分类的物质通常定义为任何质量和占有空间。
质量为量的物质对象。
一个物体的质量不会改变。
一个物体的体积是多少空间对象占用。
所有不同形式的物质世界分为两种主要大类:(1)和(2)纯物质的混合物。
一个纯物质也可以被定义为一种物质组成及既有明确的独特属性。
纯物质是分成两组:元素和化合物。
一个元素是最简单的一种材料具有独特的物理和化学性质,是不能被分解成简单的或任何物理或化学方法。
一个复合是一个纯粹的物质,由两个或两个以上元件连接在一起的比例在特征和明确的,它可以是一个由化学变化分解成更简单的物质有固定的质量比而改变。
混合物含有两个或两个以上的化学物质的变量比例纯物质保留他们的化学身份。
原则上,它们可以被分为组成物质由物理方法,涉及的生理变化。
一个样品均匀如果它总是有相同的成分,无论哪个部分样品检验。
纯粹的元素和纯化合物具有同质性。
混合物可以均匀、太;在一个均匀分布均匀混合组成的成分和外观的是均匀的混合贯穿始终。
一个解决方案是一种特殊类型的均匀混合。
多相混合物有身体上的不同性质的不同部分。
物质的分类进行了综述,如下图:物质也可以分为四个不同的阶段:固态、液态、气态,等离子体。
在固相物质的原子紧密地联系在一起的包装。
一个对象,是固体具有一定的形状和大小的空间,不能调整简单方便。
液相物质的原子挤紧密联系在一起,但他们互相围绕对方自由地流动。
液体物质具有一定的卷,不过很容易改变形状。
化学专业英语部分原文及翻译

U27 The acid-base titration starts with the dissolution of the solid acid sample in deioni zed water. Add the end-pointindica tor, whichis phenol phtha lein, with two dropsto each flaskcontai ningthe acid sample and deioni zed water.Proper ly labelthe flasks. Be consis tentin all of the sample s when adding the indica tor. Swirlthe flasks untilthe solidacid is comple telydissol ved. Finall y, rinsewith deioni zed waterthreetimesaround, whichis critic al to ensure that all solidacid has been remove d from the flaskwallsand dissol ved in the soluti on. All solidpartic les must be dissol ved priorto the titrat ion.7、酸碱滴定伴随着于固体酸溶解于去离子水中发生。
在每支装有酸样品和去离子水的试管中加入两滴终点指示剂——酚酞,并在试管上贴好标签。
在加指示剂的时候保持所有样品条件一致。
震荡试管直到所有固体酸完全溶解。
最后,用去离子水冲洗试管壁周围三次,确保试管壁上的固体酸从试管上脱落并溶解于溶液中。
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01 THE ELEMENTS AND THE PERIODIC TABLE01 元素和元素周期表The number of protons in the nucleus of an atom is referred to as the atomic number, or proton number, Z. The number of electrons in an electrically neutral atom is also equal to the atomic number, Z. The total mass of an atom is determined very nearly by the total number of protons and neutrons in its nucleus. This total is called the mass number, A. The number of neutrons in an atom, the neutron number, is given by the quantity A-Z.质子的数量在一个原子的核被称为原子序数,或质子数、周淑金、电子的数量在一个电中性原子也等于原子序数松山机场的总质量的原子做出很近的总数的质子和中子在它的核心。
这个总数被称为大量胡逸舟、中子的数量在一个原子,中子数,给出了a - z的数量。
The term element refers to, a pure substance with atoms all of a single kind. T o the chemist the "kind" of atom is specified by its atomic number, since this is the property that determines its chemical behavior. At present all the atoms from Z = 1 to Z = 107 are known; there are 107 chemical elements. Each chemical element has been given a name and a distinctive symbol. For most elements the symbol is simply the abbreviated form of the English name consisting of one or two letters, for example:这个术语是指元素,一个纯物质与原子组成一个单一的善良。
在药房“客气”原子的原子数来确定它,因为它的性质是决定其化学行为。
目前所有原子和Z = 1 a到Z = 107是知道的;有107种化学元素。
每一种化学元素起了一个名字和独特的象征。
对于大多数元素都仅仅是一个象征的英文名称缩写形式,一个或两个字母组成,例如:oxygen==O nitrogen == N neon==Ne magnesium == Mg氮氧= = = = N霓虹灯啊= = = =不镁镁Some elements,which have been known for a long time,have symbols based on their Latin names, for example:一些元素,长久以来,根据他们的拉丁名字符号,例如:iron==Fe(ferrum) copper==Cu(cuprum) lead==Pb(plumbum)铁= =铁(铁)的铜= =铜(缓蚀剂)引线= =铅(铅)A complete listing of the elements may be found in T able 1.一个完整的上市的元素可以被发现于表1。
Beginning in the late seventeenth century with the work of Robert Boyle, who proposed the presently accepted concept of an element, numerous investigations produced a considerable knowledge of the properties of elements and their compounds1. In 1869, D.Mendeleev and L. Meyer, working independently, proposed the periodic law. In modern form, the law states that the properties of the elements are periodic functions of their atomic numbers. In other words, when the elements are listed in order of increasing atomic number, elements having closely similar properties will fall at definite intervals along the list. Thus it is possible to arrange the list of elements in tabular form with elements having similar properties placed in vertical columns2. Such an arrangement is called a periodic在十七世纪后期开始的工作罗伯特·波以耳,提出当前一个元素的接受和运用的概念,产生了可观的知识大量调查的特性及其compounds1元素。
在1869年,D.Mendeleev和l .迈耶,独立工作能力,提出了周期性的律法。
在现代形式,法律规定的特性是周期函数的元素的原子编号。
换句话说,当元素的顺序列出增加原子序数、元素有相近的财产落在了明确的间隔沿名单。
由此,我们有可能安排的名单表格元素的元素有相似的性质columns2放置在垂直。
这样的安排被称为一个周期Each horizontal row of elements constitutes a period. It should be noted that the lengths of the periods vary. There is a very short period containing only 2 elements, followed by two short periods of 8 elements each, and then two long periods of 18 elements each. The next period includes 32 elements, and the last period is apparently incomplete. With this arrangement, elements in the same vertical column have similar characteristics. These columns constitute the chemical families or groups. The groups headed by the members of the two 8-element periods are designated as main group elements, and the members of the other groups are called transition or inner transition elements.每个水平排的元素构成一段时间。
但应该注意的是,不同长度的时期。
这是一个非常短只包含二元素,后面跟着两个短的每8元素,然后两个长期的18个元素组成。
下一个阶段包括32元素,最后一期明显不完整的。
这样的安排、元素在同一垂直柱有相似的特点。
这些圆柱构成化学家庭或组。
这个团体的成员为首的两8-element时期为主要集团指定的元素,其他组的成员被称为过渡或内在过渡元素。
In the periodic table, a heavy stepped line divides the elements into metals and nonmetals. Elements to the left of this line (with the exception of hydrogen) are metals, while those to the right are nonmetals. This division is for convenience only; elements bordering the line —the metalloids-have properties characteristic of - both metals and nonmetals. It may be seen that most of the elements, including all the transition and inner transition elements, are metals.在元素周期表,沉重的走线分元素到金属以及非金属矿物等。
元素的左本线(除氢)是金属,而那些右边是非金属矿物等。
这个师为方便使用,metalloids-have接壤的line-the元素的性质特点——两者都是金属以及非金属矿物等。
这可以被看见,大部分的元素,包括所有的过渡和内在过渡元素,是金属。
Except for hydrogen, a gas, the elements of group IA make up the alkali metal family. They are very reactive metals, and they are never found in the elemental state in nature. However, their compounds are widespread. All the members of the alkali metal family, form ions having a charge of 1+ only. In contrast, the elements of group IB —copper, silver, and gold—are comparatively inert. They are similar to the alkali metals in that they exist as 1+ ions in many of their compounds. However, as is characteristic of most transition elements, they form ions having other charges as well.除了氢气、气体、集团的元素是构成了碱金属的家庭。