Zn的电子结合能
Y_掺杂MgZn2_稳定性、电子结构和力学性能的第一性原理计算
表面技术第52卷第8期Y掺杂MgZn2稳定性、电子结构和力学性能的第一性原理计算陈敬昶1，刘建国2，陆绍敏1，钟丽辉1，陈丽萍1，王远1（1.西南林业大学，昆明 650224；2.云南建投第七建设有限公司，昆明 650100）摘要：目的稀土元素Y掺杂是改善7xxx系铝合金断裂韧性的重要途径，然而因其掺杂量极低，通过实验很难测定微量Y对7xxx系铝合金析出相及强韧机制产生的作用，限制了7xxx系铝合金的进一步发展。
采用第一性原理计算方法探究Y掺杂对7xxx系铝合金中重要析出相MgZn2的影响机理，为7xxx系铝合金的微合金化强韧机理研究提供理论依据。
方法构建适于第一性原理计算、Mg/Zn的原子数分数比为1∶2的晶体模型，Y原子通过替换Mg或Zn原子的方式进行掺杂，通过能量计算、电子计算和弹性常数计算等分析Y掺杂对MgZn2能量稳定性、电子结构和力学性能的影响机理。
结果经Y掺杂后，形成3种固溶体Mg3Zn8Y、Mg4Zn7Y-1和Mg4Zn7Y-2，它们的形成热均小于0，即它们均可自发形成且稳定存在。
通过结合能计算发现，3种固溶体的结合能都小于MgZn2的结合能，说明Y掺杂促进了MgZn2的稳定性。
通过电子结构分析发现，Y掺杂后与Mg、Zn原子形成强的共价键，增强了体系的稳定性，Mg-Zn原子间形成了强离子键，MgZn2中Zn-Zn原子间的共价键变为强离子键。
力学性能计算结果表明，经Y掺杂后MgZn2的硬度降低、韧性上升，即Y掺杂增强了7xxx系铝合金中重要弥散析出相MgZn2的韧性，从而提升了7xxx 系铝合金的断裂韧性和抗疲劳能力。
结论基于计算结果分析得出，Y掺杂提升了MgZn2的稳定性、键合强度和断裂韧性，相关计算分析为微量Y掺杂增强7xxx系铝合金断裂韧性的实验分析提供了指导。
关键词：MgZn2；Y掺杂；电子结构；力学性能；第一性原理计算中图分类号：TG135 文献标识码：A 文章编号：1001-3660(2023)08-0444-07DOI：10.16490/ki.issn.1001-3660.2023.08.040First-principles Calculations of Stability, Electronic Structure andMechanical Properties of Y-doped MgZn2CHEN Jing-chang1, LIU Jian-guo2, LU Shao-min1, ZHONG Li-hui1, CHEN Li-ping1, WANG Yuan1(1. Southwest Forestry University, Kunming 650224, China; 2. YYCIN No.7 Construction Co., Ltd., Kunming 650100, China)ABSTRACT: Micro-alloying of rare earth element Y is an important way to strengthen the fracture toughness of 7xxx series收稿日期：2022-07-20；修订日期：2023-02-16Received：2022-07-20；Revised：2023-02-16基金项目：国家自然科学基金（51301144）；云南省教育厅科学研究基金（2022Y574）Fund：National Natural Science Foundation of China (51301144); Scientific Research Foundation of Education Department of Yunnan Province (2022Y574)作者简介：陈敬昶（1996—），男，硕士，主要研究方向为材料表面改性。
核物理与粒子物理导论chap_1_4-7 (6)
166习 题7-1．原子核69Zn 处于能量为436 keV 的同核异能态时，试求放射γ 光子后的反冲动能E R γ和放射内转换电子后的反冲动能E Re 。
若69Zn 处于高激发态，可能发射中子，试求发射能量为436keV 中子后的反冲能E Rn 。
(已知K 层电子的结合能为9.7keV 。
)7-2．试计算1μg 重的137Cs 每秒放出多少个γ 光子。
(已知137Cs 的半衰期为30.17a ， β衰变至子核激发态的分支比为93%，子核γ 跃迁的内转换系数分别为αK =0.0976， K L =566.，260.0=LM 。
) 7-3．放射源衰变至的激发态，然后接连通过两次γ 跃迁至基态。
由β磁谱仪在曲率半径为20cm 处测得此放射源的内转换K 电子的峰与场强0.02575，0.02166 T 对应。
已知Ti 的K 电子结合能为5.0keV ，试求γ 跃迁的能量。
Sc 4621β−Ti 4622 7-4．实验测得有两组βSb12051()a +电子：0.52 MeV ，=5.5；1.70 MeV ，=4.5。
后者为相应至基态之跃迁。
一条γ 射线，其能量为1.181MeV ，属E 2型。
已知基态的自旋和宇称为0log /fT 12log /fT 12Sn12050()b Sn12050+，试画出衰变纲图，并标出各能级的自旋和宇称。
7-5．设一核有大致等距分布的四条能级，其能级特性从下至上依次为21+，29+，23-，29-。
试画出能级图，标明最可能发生的跃迁类型。
7-6．通过K 俘获衰变至的激发态，后者跃迁至基态时，放出一系列γ 光子或内转换电子。
由β 磁谱仪测得22条内转换电子谱线（见下表）。
试确定所放出的γ 光子的能量，并画出的能级图。
(已知K ，L ，M 层电子的结合能分别为11.9、1.5和0.2keV 。
) Se 7534As7533As 7533内转换电子能量(keV)（带*者发生在K 层)23.2 95.3 186.9 293.4 24.4 96.5 197.2 303.454.3 109.4* 253.3 390.0 64.6 124.3 263.6 400.5 68.9* 134.7 268.2 85.0 136.0 278.5 7-7．对于下列γ 跃迁，已知跃迁类型和始态的能级特性，试求末态的能级特性：（i ）；(ii)；(iii) ；(iv) ；(v) 。
S的电子结合能
XPS_DatabaseS的电子结合能：Energy (eV) Element Chemical bonding Ref 2478.5S1s H2S243243 2483.7S1s SO2243 2490.1S1s SF6S的电子结合能：Energy (eV) Element Chemical bonding Ref 161.5S2p NiS, Ni foil polishing and Ar+ etching+H2S 400°C/1h 101 161.6S2p NiS, Ni foil polishing + in H2O/28h+H2S 400°C/1h 101 161.6S2p NiS, Ni foil Polish+Ar+,O2 oxydations/T°C+H2S 400°C/1h 101 161.8S2p(S)2- in Co foil polish- Ar+ etch, +H2S -400°C/2h 101 162.9S2p(S2)2- or SH -Co foil polish- Ar+ etch, +H2S -400°C/2h 101 163S2p(S2)2-, Ni Polish +Ar+O2 oxydations/T°C+H2S 400°C/1h 101 163.1S2p(S2)2-, Ni foil polishing and Ar+ etching+H2S 400°C/1h 101 163.1S2p(S2)2-, Ni foil polish+ in H2o/28h+H2S 400°C/1h 101S的电子结合能：Energy (eV) Element Chemical bonding Ref 107.3S2p3/2 PbS 89 160S2p3/2 sulphides 186-air3'- 89 160.3S2p3/2 PbS160.5S2p3/2 PbS 111 160.55S2p3/2PbS - H2O 19j- 89 160.55S2p3/2 PbS 89 160.7S2p3/2 p-NaSC6H4NO2 111 160.7S2p3/2vieillissement à l'air de la galène pdt 3mn 89 160.9S2p3/2PbS -air 220j- 89 160.95S2p3/2vieillissement à l'eau de la galène pdt 19j 89 161S2p3/2 FeS 111 161.2S2p3/2 KFeS2 111 161.2S2p3/2RSNa ou RSK 245 161.2S2p3/2 S(2-)monosulfide 2343'- 89-air 161.25S2p3/2 CuFeS2161.3S2p3/2 CuFeS2 89 161.3S2p3/2vieillissement à l'air de la galène pdt 220j 89 161.4S2p3/2 Na2SSO3 111 161.4S2p3/2 Ni(SPh)2(dppe) 235 161.5S2p3/2 ZnS 150 161.5S2p3/2 Na2S 111 161.5S2p3/2 CuFeS23j- 89-air 161.5S2p3/2S (ads) / Mo(110) - S strongly bound 103 161.6S2p3/2CuFeS2 - H2O 22j- 89 161.6S2p3/2 Mo(NO)(S2CN(C2H5)2)3 235161.65 S2p3/2 CuFeS2 89161.7 S2p3/2 PhNHCSNHPh 111161.7 S2p3/2 CuFeS2 -air 220j- 89161.7 S2p3/2 Pd(SPh)2(dppe) 235161.8 S2p3/2 WS2 111161.8 S2p3/2 S(-II) 58161.8 S2p3/2 Pt(SPh)2(dppe) 235161.85 S2p3/2 Cu2S 89161.9 S2p3/2 NaS*C(S)NR2 245161.9 S2p3/2 S*SO3(-) 245161.9 S2p3/2 Ni(SCH2CH2S)(dppe) 235161.95 S2p3/2 vieillissement à l'air de la spharelite pdt 3 mn 89162 S2p3/2 Thiourée 195162 S2p3/2 Rh2(O2CH)4(tu)2 195162 S2p3/2 Rh2(O2CCH3)4(tu)2 195162 S2p3/2 PhSCMe3 111162 S2p3/2 gpts (S2SO3)2- 2eme pic 89162 S2p3/2 S2- 245162.05 S2p3/2 vieillissement à l'eau de la spharelite pdt 19j 89162.1 S2p3/2 NiCl2(tu)4 195162.1 S2p3/2 AgCl(tu)2 195162.1 S2p3/2 MoS2 111162.1 S2p3/2 Ph3PS 111162.1 S2p3/2 S2(2-) disulfide 234162.1 S2p3/2 ZnS 89162.1 S2p3/2 Pt(SPh)2(CyNC)2 235162.15 S2p3/2 vieillissement à l'air de la spharelite pdt 220j 89162.2 S2p3/2 Rh2(O2CC6H5)4(tu)2 195162.2 S2p3/2 Fe2S 61162.2 S2p3/2 Fe(S2CN(C2H5)2)2 235162.2 S2p3/2 Fe(NO)I(S2CN(C2H5)2)2 235162.2 S2p3/2 Mo(NO)2(S2CN(C2H5)2)2 235162.25 S2p3/2 Cu2S 89162.3 S2p3/2 Na2 S2O3 (peripheral S) 150162.3 S2p3/2 CuCl(tu)3 195162.4 S2p3/2 CS2 150162.4 S2p3/2 [Pr4N]ReCl5(tu) 195162.4 S2p3/2 CoBr2(tu)2 195162.4 S2p3/2 Co(NCS)2(tu)2 195162.4 S2p3/2 Ni(NO3)2(tu)6 195162.4 S2p3/2 Soufre sur alliage 600 70162.4 S2p3/2 Fe(NO)(S2CN(CH3)2)2 235162.4 S2p3/2 NiWS2 243162.5 S2p3/2 CoCl2(tu)2 195162.5 S2p3/2 Co(NO3)2(tu)4 195162.5S2p3/2 Ni(NCS)2(tu)2 195162.5S2p3/2Na2S2O3 (peripheral S) 111 162.5S2p3/2 CuS 89 162.5S2p3/2FeS2 -air 220j - 89 162.5S2p3/2 sulphides 186 162.5S2p3/2S (élément naturel) 147 162.5S2p3/2 Co(S2CN(CH3)2)3 235 162.5S2p3/2 (Ni(SCH2CH2S))n 235 162.5S2p3/2 Ni(SCH2CH2S)(PMe2Ph)2 235 162.6S2p3/2 NiS 150 162.6S2p3/2 WS2 150 162.6S2p3/2 [Rh(tu)6]Cl(NO3)2 195 162.6S2p3/2 [Cu(BF4)(tu)3]2 195 162.6S2p3/2 NiWS2 111(S)2- 89 162.6S2p3/2 FeS2162.6S2p3/2FeS2 - H2O 22j- 89 162.6S2p3/2FeS2 disulfide (2-) 239 162.6S2p3/2 ((C6H5)4P)(Fe(NO)(S2C2(CN)2)2) 235 162.6S2p3/2 Pt(S2C2(CN)2)(PPh3)2 235 162.6S2p3/2 (NH4)(Fe4S3(NO)7) 235 162.6S2p3/2 WS2 243 162.65S2p3/2FeS2 -air 3'- 89 162.65S2p3/2 CuS 89 162.7S2p3/2 [Rh(tu)5Cl]Cl2 195 162.7S2p3/2 tetrahydrothiophene 111n°1- 163 162.7S2p3/2 FeS2-pyrite 162.7S2p3/2 Pt(S2C2(CN)2)(CNCH3)2 235 162.7S2p3/2 Ni(SPh)2(CyNC)2 235 162.8S2p3/2 RhCl3(tu)3 195 162.8S2p3/2 WS2 111 162.8S2p3/2 NiS 111 162.8S2p3/2FeS2 -air 30j- 89 162.8S2p3/2MoS3 - species S2(II) 103 162.8S2p3/2 (Ni(SPh)2)n 235 162.8S2p3/2 Ni(SPh)2(PMe2Ph)2 235 162.8S2p3/2 Pd(SPh)2(CyNC)2 235 162.9S2p3/2 PhSH 111n°2- 163 162.9S2p3/2 FeS2-pyritepolysulfide 234 162.9S2p3/2 S(2-)n162.9S2p3/2 Methionine 235 162.9S2p3/2 Co(Met)2 235 162.9S2p3/2 Ni(Met)2 235 162.9S2p3/2 Cu(Met)2 235 162.9S2p3/2 Zn(Met)2 235 163S2p3/2 Ph2S 111 163S2p3/2 Mo2O4(S2CN(C2H5)2)2 235 163.1S2p3/2 FeS2 89163.2S2p3/2 Ni(S2C2(C6H5)2)2 235 163.3S2p3/2 (Pd(SPh)2)n 235 163.4S2p3/2 Fe(S2C2(C6H5)2)2 235 163.4S2p3/2 (Pt(SPh)2)n 235 163.4S2p3/2 (Fe(SCH3)(CO)3)2 235 163.4S2p3/2 (Fe(SC2H5)(NO)2)2 235 163.6S2p3/2 CS2 111 163.6S2p3/2 (Ru(CS2)Cl(PPh3)3)Cl 235 163.7S2p3/2 PhSSPh 111 163.7S2p3/2 S8 111 163.7S2p3/2 RSSR 245Sulfur. 26 163.7S2p3/2 S-C,163.8S2p3/2 Sn 111 163.8S2p3/2 RSH 245 163.9S2p3/2 thiophene 111 163.9S2p3/2gpts (S4O6)2- 2eme pic 89 164S2p3/2 S=C=S 245 164S2p3/2 RS*SO3- 245 164.05S2p3/2 S 150 164.1S2p3/2 RS*S(O)R 245 164.1S2p3/2 RS*SO2R 245 164.1S2p3/2 R2NS*NR2 245 164.1S2p3/2 RSCl 245 164.1S2p3/2 Pt(MetH)Cl2 235 164.2S2p3/2 S2N2 111 164.2S2p3/2 S8 245élémentaire 61 164.2S2p3/2 S164.2S2p3/2 S6 186 164.25S2p3/2 S(s) 111thiophen 245 164.3S2p3/2 S164.3S2p3/2 S° 89 165S2p3/2 RSOR 245 165.3S2p3/2 Sn(CH3)2Cl2(dmso)2 195 165.3S2p3/2Sn -pyrite n°1- 163((CH3)2S=O) 195 165.5S2p3/2 DMSO165.5S2p3/2 Me3SI 111 165.5S2p3/2 O2NC6H4SO2Na 111 165.6S2p3/2 CuCl2(dmso)2 195 165.7S2p3/2 Ph2SO 111 165.7S2p3/2 BzMeSO 111 165.9S2p3/2 NiCl2(dmso)3 195 165.9S2p3/2 CoCl2(dmso)3 195 165.9S2p3/2Sn ? -pyrite n°2- 163 166S2p3/2 MnCl2(dmso)3 195 166S2p3/2 CdCl2(dmso) 195 166S2p3/2 [Pd(dmso)4](BF4)2 195166S2p3/2 PhSO2Na 111 166S2p3/2 RSO2- 245 166.1S2p3/2 Co(NH3)4(SO3)(CN) 195 166.1S2p3/2 NH4[Co(NH3)4(SO3)2] 195 166.1S2p3/2 Na2SO3 111 166.1S2p3/2 RS(O)R 245 166.1S2p3/2 RS*(O)SR 245 166.2S2p3/2 SnCl2(dmso)2 195 166.2S2p3/2 FeCl3(dmso)2 195 166.3S2p3/2 ZnCl2(dmso)2 195SO3 150 166.4S2p3/2 Na2166.4S2p3/2 NH4[Co(en)(NH3)2(SO3)2] 195 166.4S2p3/2 PdCl2(dmso)2 195 166.4S2p3/2 SnCl4(dmso)2 195 166.4S2p3/2S oxyde type sulfite 61 166.5S2p3/2 HgCl2(dmso) 195 166.5S2p3/2 PtCl2(dmso)2 195 166.6S2p3/2 AlCl3(dmso)6 195 166.6S2p3/2 Na2SO3 111 166.7S2p3/2 SO3(2-) 245 166.7S2p3/2 Ir(SO2)(CO)Cl(PPh3)2 235 166.8S2p3/2 [Pd(dmso)4](BF4)2 195 166.9S2p3/2NaRh(NH3)4(SO3)2 . H2O 195 166.9S2p3/2 RhCl3(dmso)3 195 167S2p3/2 RS(O)OR 245 167.2S2p3/2 SO2 150 167.2S2p3/2K3Rh(SO3)3 . 2 H2O 195 167.4S2p3/2 Na2SSO3 111 167.4S2p3/2 SO2 111 167.4S2p3/2 SO4(-II) 58 167.5S2p3/2 RSO2R 245 167.5S2p3/2 (-)S*O3S(-) 245 167.7S2p3/2 BzMeSO2 111 167.8S2p3/2 SO2 111 167.9S2p3/2 PhSO3Na 111 168S2p3/2 p-H2NC6H4SO2NH2 111 168S2p3/2 RSO3- 245 168.1S2p3/2 PhSO3Me 111 168.1S2p3/2gpts (S2SO3)2- 1er pic 89 168.1S2p3/2 RS*O2SR 245 168.1S2p3/2 RS*O2NR2 245 168.1S2p3/2 SO2 245 168.1S2p3/2 SOCl2 245 168.2S2p3/2Cu(bipy)SO4 . 2 H2O 195 168.2S2p3/2gpts ( S4O6)2- 1er pic 89 168.3S2p3/2 Na2SO4 111168.3S2p3/2 FeSO4 111 168.4S2p3/2Na2 S2O3 (central S) 150 168.5S2p3/2Cu(en)2SO4 . H2O 195 168.5S2p3/2 RSO2OR 245 168.5S2p3/2 RSO2Cl 245 168.5S2p3/2 sulphates 186 168.6S2p3/2Na2S2O3 (central S) 111(SO4)2- 89 168.7S2p3/2 gpts168.7S2p3/2SO4(2-) -pyrite n°1- 163 168.8S2p3/2 Fe2(SO4)3 111 168.9S2p3/2 CuSO4 150SO4 150 168.9S2p3/2 Na2168.9S2p3/2 (-)SO3SR 245 169S2p3/2 CoSO4 195 169S2p3/2Cu(bipy)3SO4 . 7 H2O 195 169S2p3/2 SO4(2-) 245 169S2p3/2S dans SO4(-II) 183 169.1S2p3/2 CuSO4 111 169.1S2p3/2SO4(2-) -pyrite n°2- 163 169.4S2p3/2Cu(en)SO4 . H2O 195 169.5S2p3/2CuSO4 . 5 H2O 195 169.5S2p3/2 sulphates 186 169.8S2p3/2 RSO2OR 245 170S2p3/2 CS2 243(g) 111170.03S2p3/2 CS2170.2S2p3/2 H2S 111 170.2S2p3/2 RSO2F 245 170.2S2p3/2 H2S 243 170.3S2p3/2 CuSO4 195 170.3S2p3/2satellites -pyrite n°1- 163(g) 111170.44S2p3/2 H2S170.6S2p3/2 Cr2(SO4)3 186 170.8S2p3/2 COS 111 170.8S2p3/2 COS 243 172.2S2p3/2satellite -pyrite n°2- 163 174.2S2p3/2 SF6 150 174.4S2p3/2 SF6 111(g) 111174.8S2p3/2 SO2174.8S2p3/2 SO2 243 180.3S2p3/2 SF6(g) 111 180.4S2p3/2 SF6 243S的电子结合能：Energy (eV) Element Chemical bonding Ref 224.7S2s PbS89 224.7S2s PbS -air 3'- 89224.9S2s PbS -air 220j- 89 225.1S2s vieillissement à l'air de la galène pdt 3mn 89 225.3S2s vieillissement à l'air de la galène pdt 220j 89 225.3S2s vieillissement à l'eau de la galène pdt 19j 89 227.5S2s S -Fe /19Cr /9Ni /2.5Mo- 138 232.4S2s SO4 (2-) -Fe /19Cr /9Ni /2.5Mo- 138。
电子结合能
XPS_DatabaseZn的电子结合能：Energy (eV) Element Chemical bonding Ref 1045Zn2p1/2Cu Zn alpha, béta 178178 1045.1Zn2p1/2 ZnO1045.9Zn2p1/2 ZnI2 621046.2Zn2p1/2 ZnCl2 621046.4Zn2p1/2 ZnBr2 62 Zn的电子结合能：Energy (eV) Element Chemical bonding Ref88.4Zn2p3/2Cu Zn alpha, béta 1781020.7Zn2p3/2 ZnP2 150 1021.2Zn2p3/2 Zn 111 1021.4Zn2p3/2 ZnTe 150 1021.4Zn2p3/2 ZnS 150acethylacetonate 111 1021.4Zn2p3/2 Zn1021.4Zn2p3/2 ZnO 157 1021.5Zn2p3/2 ZnAl2O4 150 1021.6Zn2p3/2 ZnF2 150 1021.6Zn2p3/2 ZnO 111 1021.6Zn2p3/2 ZnTe 111 1021.6Zn2p3/2ZnO ds P2O5 ZnO/P2O5 = 1.2 molar 252 1021.6Zn2p3/2 Zn(Met)2 235 1021.62Zn2p3/2 Zn 150 1021.8Zn2p3/2 ZnSe 150 1021.9Zn2p3/2 ZnO 150 1021.9Zn2p3/2 ZnS 111 1021.9Zn2p3/2 Zn 111 1021.9Zn2p3/2hemimorphite (Zn silicate) 111 1022Zn2p3/2 ZnSe 111 1022Zn2p3/2Cu Zn alpha, béta 178 1022Zn2p3/2élément naturel (liaison métallique) 147 1022.1Zn2p3/2 ZnO 178 1022.2Zn2p3/2 ZnF2 111 1022.2Zn2p3/2 ZnO 111 1022.2Zn2p3/2ZnO ds P2O5 ZnO/P2O5 = 0.4 molar 252 1022.3Zn2p3/2 ZnI2 150 1022.3Zn2p3/2ZnO ds P2O5 ZnO/P2O5 = 1 molar 252 1022.4Zn2p3/2ZnO ds P2O5 ZnO/P2O5 = 1,5 molar 252 1022.4Zn2p3/2ZnO ds P2O5 ZnO/P2O5 = 2 molar 252 1022.8Zn2p3/2 ZnSO4 150 1022.8Zn2p3/2 ZnI2 111 1023Zn2p3/2 ZnBr2 111 1023Zn2p3/2 ZnCl2 621023Zn2p3/2 ZnI2 62 1023.3Zn2p3/2 Zn(C24H27N7)(PF6)2 111 1023.3Zn2p3/2 ZnBr2 62 1023.4Zn2p3/2 ZnBr2 150Zn的电子结合能：Energy (eV) Element Chemical bonding Ref90.7Zn3p1/2Cu Zn alpha, béta 17817890.8Zn3p1/2 ZnOZn的电子结合能：Energy (eV) Element Chemical bonding Ref17888.6Zn3p3/2 ZnOXPS_DatabaseCu2p1/2的电子结合能Energy (eV) Element Chemical bonding Ref 951.2Cu2p1/2Pd50Cu50 alloy with respect to pure components 8 952Cu2p1/2Cu 8 952.3Cu2p1/2Cu2O 178 952.5Cu2p1/2Cu Zn alpha, béta 178 953.3Cu2p1/2NdCuSn 82 953.3Cu2p1/2NdCuGe 82 953.6Cu2p1/2CuO 178 962Cu2p1/2Y0,4 Pr0,6 Ba2 Cu4 O8 204Cu2p3/2的电子结合能Energy (eV) Element Chemical bonding Ref 923.5Cu2p3/2Cu 215 931.2Cu2p3/2Pd50Cu50 alloy with respect to pure components 8 931.6Cu2p3/2CuInSe2 150 931.7Cu2p3/2CuAgSe 150 931.7Cu2p3/2Cu2Se 150 931.8Cu2p3/2CuFeS2 150 931.8Cu2p3/2CuFeS2 89 932Cu2p3/2CuCl 111 932Cu2p3/2Cu2Mo3O10 111 932Cu2p3/2Cu 8 932Cu2p3/2CuS 89 932.1Cu2p3/2CuS 150 932.1Cu2p3/2Cu2O 111 932.2Cu2p3/2CuP2 150 932.2Cu2p3/2Cu2S 150 932.2Cu2p3/2Cu(CN)2 150 932.2Cu2p3/2Cu2O 150 932.2Cu2p3/2CuCl 150 932.2Cu2p3/2Ni90Cu10 215 932.3Cu2p3/2Cu2S 111 932.3Cu2p3/2Cu 111 932.3Cu2p3/2CuAgSe 111 932.3Cu2p3/2Cu2Se 111 932.4Cu2p3/2Cu3O2 125 932.4Cu2p3/2CuSe 111 932.4Cu2p3/2CuCl 111 932.4Cu2p3/2Cu2S 89 932.4Cu2p3/2Cu2O (?) 157 932.4Cu2p3/2Cu metal 13 932.47Cu2p3/2Cu 150 932.5Cu2p3/2CuS 111932.5Cu2p3/2Cu2O 178 932.5Cu2p3/2Cu métal 247 932.5Cu2p3/2Cu2O 247 932.5Cu2p3/2Cu2O 13 932.6Cu2p3/2Cu bulk 125 932.7Cu2p3/2Cu 175 932.7Cu2p3/2Cu 225 932.7Cu2p3/2élément naturel (liaison métallique) 147 932.8Cu2p3/2Cu 111 933.1Cu2p3/2CuCN 111 933.2Cu2p3/2CuC(CN)3 111 933.3Cu2p3/2CuBr2 111 933.3Cu2p3/2NdCuGe 82 933.4Cu2p3/2NdCuSn 82 933.4Cu2p3/2CuO 111 933.5Cu2p3/2Al2Cu 111 933.6Cu2p3/2CuFe2O4 150 933.6Cu2p3/2CuO 150 933.7Cu2p3/2Al2Cu 150 933.7Cu2p3/2CuO 178 933.7Cu2p3/2CuFe2O4 247 933.7Cu2p3/2CuO 155 933.7Cu2p3/2CuO 13 933.8Cu2p3/2Cu2+ in copper-erbium carbonate 181 933.8Cu2p3/2Cu2+ in copper-holmium carbonate 181 933.8Cu2p3/2CuO 125 933.8Cu2p3/2CuO 247 933.9Cu2p3/2CuO 157 934Cu2p3/2CuN in [CuEu(daaen)] 166 934Cu2p3/2Cu(C24H27N7)(PF6)2 111 934.1Cu2p3/2CuN in [Cu(H2daaen)] 166 934.1Cu2p3/2Cu(II)-Dy(III) in Cu2Dy2O5 151 934.2Cu2p3/2Cu(II)-Er(III) in Cu2Er2O5 151 934.2Cu2p3/2CuCl2 150 934.3Cu2p3/2Cu(II)-Gd(III) in CuGd2O4 151 934.4Cu2p3/2Cu(II)-Ho(III) in Cu2Ho2O5 151 934.4Cu2p3/2CuCr2O4 150 934.4Cu2p3/2CuCl2 111 934.4Cu2p3/2Cu(OH)2 247 934.5Cu2p3/2CuAl2O4 150 934.5Cu2p3/2CuMoO4 111 934.7Cu2p3/2CuCO3 111 934.7Cu2p3/2Cu(OH)2 155 934.7Cu2p3/2Cu(OH)2 13 934.7Cu2p3/2Cu(Met)2 235 934.9Cu2p3/2CuSiO3 111934.9Cu2p3/2CuSiO3 155 935.1Cu2p3/2Cu(OH)2 125 935.5Cu2p3/2CuSO4 111 935.5Cu2p3/2Cu(NO3)2 111 935.5Cu2p3/2CuSO4 155 935.9Cu2p3/2CuF2 150 936.7Cu2p3/2CuF2 111 937Cu2p3/2CuF2 111 939.4Cu2p3/2CuN in [Cu(H2daaen)] (satellite) 166 940.4Cu2p3/2CuN in [CuEu(daaen)] (satellite) 166 943.5Cu2p3/2CuN in [CuEu(daaen)] (satellite) 166 944.2Cu2p3/2CuN in [Cu(H2daaen)] (satellite) 166Cu3d的电子结合能Energy (eV) Element Chemical bonding Ref824.1Cu3d PrCuSn4.1Cu3d NdCuGe (1 of 2) 824.2Cu3d NdCuSn (1 of 2) 825.3Cu3d NdCuGe (2 of 2) 826Cu3d NdCuSn (2 of 2) 82Cu3d3/2的电子结合能Energy (eV) Element Chemical bonding Ref82 953.8Cu3d3/2 PrCuSn Cu3d53/2的电子结合能Energy (eV) Element Chemical bonding Ref82 933.6Cu3d5/2 PrCuSn Cu3p1/2的电子结合能Energy (eV) Element Chemical bonding Ref17877.2Cu3p1/2 Cu2O77.3Cu3p1/2Cu Zn alpha, béta 17817878.2Cu3p1/2 CuOCu3p31/2的电子结合能Energy (eV) Element Chemical bonding Ref8974.65Cu3p3/2 CuFeS28974.95Cu3p3/2 CuS75.1Cu3p3/2Cu Zn alpha, béta 17824775.1Cu3p3/2 Cumétal24775.1Cu3p3/2 Cu2O8975.15Cu3p3/2 Cu2S17875.2Cu3p3/2 Cu2O17876.2Cu3p3/2 CuO76.2Cu3p3/2 CuO24724776.4Cu3p3/2 CuFe2O4247 77Cu3p3/2 Cu(OH)2Cu3s的电子结合能Energy (eV) Element Chemical bonding Ref247métal 122.2Cu3s Cu247 122.2Cu3s Cu2O82 122.2Cu3s NdCuGe82 122.4Cu3s NdCuSn82 122.5Cu3s PrCuSn123Cu3s Y0,4 Pr0,6 Ba2 Cu4 O8 204123Cu3s Pr Ba2 Cu O7 204247 123.5Cu3s CuO247 124.1Cu3s Cu(OH)2XPS_DatabaseFe2p1/2的电子结合能：Energy (eV) Element Chemical bonding Ref 720.1Fe2p1/2 Fe° 4720.3Fe2p1/2 Fe2B 4720.4Fe2p1/2 FeB 4Fe2p3/2的电子结合能：Energy (eV) Element Chemical bonding Ref 706.3Fe2p3/2 FeS2 111 706.4Fe2p3/2 Fe° 73 706.5Fe2p3/2 FeS2 150iron 224 706.5Fe2p3/2 metallic706.54Fe2p3/2 Fe 150 706.6Fe2p3/2 Fe2B 111 706.6Fe2p3/2FeS, tail DSJ 234metal 13 706.6Fe2p3/2 Fe706.7Fe2p3/2 Fe 111 706.8Fe2p3/2 FeB 111 706.8Fe2p3/2FeS2 - H2O 22j 89 706.8Fe2p3/2 Fe 183métallique 1 706.8Fe2p3/2 Fe706.8Fe2p3/2ds le 304 ss avec N2 implanté 218 706.8Fe2p3/2N ds l'acier 304 (bulk) 55 706.8Fe2p3/2 Fe° 156 706.8Fe2p3/2 Fe° 2 706.8Fe2p3/2Fe° in a passive film on SUS316L 65 706.9Fe2p3/2 FeP 150 706.9Fe2p3/2 Fe 89n°1- 163-pyrite 706.9Fe2p3/2 FeS2n°2- 163-pyrite 706.9Fe2p3/2 FeS2706.9Fe2p3/2 Fe(m) 84 706.9Fe2p3/2 Fe 89 706.95Fe2p3/2FeS2 - air 11j- 89iron 224 707Fe2p3/2 metallic707Fe2p3/2pic XPS alliage Fe24Cr 124 707Fe2p3/2Fe metal in case of sample immersed in a 60°C solution 11 707Fe2p3/2Fe metal with a sample immersed in a room t° solution 11 707Fe2p3/2 Fe° 4 707.1Fe2p3/2FeS2 - air 3j- 89 707.1Fe2p3/2FeS2 - air 30j- 89 707.1Fe2p3/2FeS2 - air 220j - 89métal 182 707.1Fe2p3/2 pic707.1Fe2p3/2Fe ds 304 ss nitré 218 707.1Fe2p3/2N ds l'acier 304 (nitré) 55707.1Fe2p3/2 Fe(m) 84(pyrite) 89 707.15Fe2p3/2 FeS2707.2Fe2p3/2 FeB 150 707.2Fe2p3/2 Ni-21Cr-8Fe 183 707.2Fe2p3/2élément naturel (liaison métallique) 147 707.2Fe2p3/2 Fe2B 4 707.3Fe2p3/2 Fe3Si 150 707.3Fe2p3/2 FeB 4 707.4Fe2p3/2 FeS2 111 707.45Fe2p3/2 FeS2 89 707.6Fe2p3/2 Fe(C5H5)2 150 707.9Fe2p3/2 Fe3C 150 707.9Fe2p3/2metallic iron strongly interacting with the oxide 224 708.1Fe2p3/2 CuFeS2 89 708.2Fe2p3/2 Fe(C10H8N2)3(PF6)2 111 708.2Fe2p3/2Fe oxide in a passive film on SUS316L 65 708.3Fe2p3/2 Fe2P2S6 111 708.3Fe2p3/2 KFeS2 111 708.3Fe2p3/2 Fe3O4 89 708.5Fe2p3/2 K4Fe(CN)6 111 708.5Fe2p3/2 CuFeS2 89Fe2+ 13 708.5Fe2p3/2 Fe2O3,708.6Fe2p3/2 Fe2+ 73 708.7Fe2p3/2 (Fe(SCH3)(CO)3)2 235 709.1Fe2p3/2 Fe2+ 2 709.1Fe2p3/2 (Fe(SC2H5)(NO)2)2 235 709.2Fe2p3/2Fe(S?) , FeO -pyrite n°1- 163 709.2Fe2p3/2Fe(II) dans Fe3O4 183 709.2Fe2p3/2 Fe2+ 84 709.3Fe2p3/2Fe2+ ds FeO 1 709.4Fe2p3/2 FeO 150 709.4Fe2p3/2pic XPS (Fe2+) alliage Fe24Cr 124 709.5Fe2p3/2 Fe(II) 224 709.5Fe2p3/2Fe(S) , FeO -pyrite n°2- 163 709.5Fe2p3/2 Fe2+ 156 709.5Fe2p3/2 FeO 89 709.5Fe2p3/2 Fe(OH)2 118 709.6Fe2p3/2 Fe2+ 84 709.8Fe2p3/2 FeBr3 111 709.8Fe2p3/2 FeO 13 709.9Fe2p3/2 FeBr2 111 709.9Fe2p3/2 FeCl3 111 709.9Fe2p3/2 FeF2 111 709.9Fe2p3/2 K3Fe(CN)6 111 710Fe2p3/2 FeS 111 710Fe2p3/2 FeO 111710Fe2p3/2Fe2p3/2 (voir spectres dans la publication). 102 710.2Fe2p3/2 FeCl2 111 710.3Fe2p3/2 CoFe2O4 150 710.3Fe2p3/2 Fe(II) 224 710.3Fe2p3/2 Fe3+ 156 710.4Fe2p3/2 NiFeO4 111 710.4Fe2p3/2 Fe3+ 2 710.4Fe2p3/2Fe oxide in a passive film on SUS316L 65oxyde 89 710.5Fe2p3/2 FeS2710.5Fe2p3/2 Fe3+ 84 710.5Fe2p3/2 alpha-Fe2O3 118 710.6Fe2p3/2 Fe2O3 89-air3'- 89 710.6Fe2p3/2 CuFeS2710.6Fe2p3/2 Fe(III) 224 710.6Fe2p3/2Fe(OH)3 -pyrite n°1- 163 710.6Fe2p3/2 Fe3+ 73 710.6Fe2p3/2 Fe2O3 157 710.7Fe2p3/2 Fe2O3 150 710.7Fe2p3/2 FeOOH 111 710.7Fe2p3/2Fe(OH)3 -pyrite n°2- 163Fe3O4 183dans710.7Fe2p3/2 Fe(III)710.7Fe2p3/2pic XPS (Fe3+) alliage Fe24Cr 124 710.8Fe2p3/2pic large attribué principalement à Fe2O3 182 710.8Fe2p3/2pic du Fe2O3 après bombardement (5 min) 182 710.8Fe2p3/2 Fe2O3 13 710.85Fe2p3/2 FeSO4,7H2O 89 710.9Fe2p3/2 Fe2O3 111 710.9Fe2p3/2CuFeS2 -air 3j - 89 710.9Fe2p3/2Fe Ox, 316 L alloy fretted (30 min) in physio serum 207 710.9Fe2p3/2 Fe3+ 84Fe3+ 13 710.9Fe2p3/2 Fe3O4,710.95Fe2p3/2CuFeS2 - H2O 40' - 89 711Fe2p3/2 FeSO4.7H2O 111 711Fe2p3/2CuFeS2 - H2O 3h - 89 711Fe2p3/2CuFeS2 - H2O 8j - 89 711Fe2p3/2CuFeS2 - H2O 16j - 89 711Fe2p3/2Fe3+ ds Fe2O3 1 711Fe2p3/2 Fe3+ 228 711Fe2p3/2Fe2p exposé à l' oxygéne à 600K 173alpha 89 711Fe2p3/2 Fe2O3711Fe2p3/2vieillissement à l'air de la chalcopyrite pdt 3 mn 89 711Fe2p3/2Fe oxide with a sample immersed in a room t° solution 11 711.05Fe2p3/2CuFeS2 - H2O 34j - 89 711.05Fe2p3/2FeS2 - air 3'- 89 711.1Fe2p3/2 Fe3O4 111 711.1Fe2p3/2 Fe2(WO4) 111711.1Fe2p3/2CuFeS2 -air 11j - 89 711.15Fe2p3/2 FeOOH 89 711.2Fe2p3/2 FeF2 150 711.2Fe2p3/2CuFeS2 - H2O 1j - 89 711.2Fe2p3/2CuFeS2 - H2O 4j - 897H2O 89 711.25Fe2p3/2 FeSO4711.3Fe2p3/2 dithiodibutylcarbanate 111 711.35Fe2p3/2vieillissement à l'eau de la chalcopyrite pdt 40mn 89 711.4Fe2p3/2 NaFeO2 111 711.4Fe2p3/2CuFeS2 -air 30j - 89 711.4Fe2p3/2 Fe(III) 224 711.45Fe2p3/2 FeOOH 89 711.45Fe2p3/2vieillissement à l'eau de la chalcopyrite pdt 34j 89 711.5Fe2p3/2 FeWO4 111 711.5Fe2p3/2Fe (2) acethylacetonate 111 711.5Fe2p3/2FeOOH dans Inconel 600 (Publication riche en El) 246 711.5Fe2p3/2 FeO.OH 118 711.5Fe2p3/2Fe oxide in case of sample immersed in a 60°C solution 11 711.55Fe2p3/2CuFeS2 -air 220j - 89 711.6Fe2p3/2 FeOOH 13 711.75Fe2p3/2CuFeS2 - air 400j - 89 711.8Fe2p3/2Fe (3) acethylacetonate 111 711.8Fe2p3/2 KFe3(OH)6(SO4)2 89 712Fe2p3/2 cyclohexanebutyrate 111 712Fe2p3/2SO4(2-) -pyrite n°1- 163 712.1Fe2p3/2Fe2(SO4)3 -pyrite n°2- 163 712.15Fe2p3/2vieillissement à l'air de la chalcopyrite pdt 400j 89 713.1Fe2p3/2 Fe2(SO4)3 89 713.5Fe2p3/2 Fe2(SO4)3 89 713.9Fe2p3/2 FeF3 111 714Fe2p3/2 K3FeF6 111 714Fe2p3/2satellite -pyrite n°1- 163 714Fe2p3/2satellite -pyrite n°2- 163 715Fe2p3/2 satelliteFe(II) 224of 715Fe2p3/2pic XPS alliage Fe24Cr (Fe2+ satellite) 124 715.7Fe2p3/2 Fe2O3/Fe3O4 25satellite 1 715.7Fe2p3/2 Fe2+719.8Fe2p3/2 satelliteFe(III) 224of 720Fe2p3/2pic XPS alliage Fe24Cr (Fe3+ satellite) 124Fe2s的电子结合能：Energy (eV) Element Chemical bonding Ref 641.2Fe2s Fe2B44 641.6Fe2s Fe°4 641.6Fe2s FeBFe3p的电子结合能：Energy (eV) Element Chemical bonding Ref8952.6Fe3p Fe89 53Fe3p Fe53.2Fe3p Fe° 453.2Fe3p Fe2B 453.5Fe3p Fe3O48953.5Fe3p FeB 48953.65Fe3p FeS253.8Fe3p CuFeS2898953.9Fe3p Fe3O454.05Fe3p FeS289163n°1--pyrite54.1Fe3p FeS28954.2Fe3p CuFeS254.5Fe3p FeO89163n°2-54.5Fe3p FeS2-pyrite8954.9Fe3p FeO8955.4Fe3p Fe2O38955.6Fe3p FeSO4,7H2Oalpha8955.8Fe3p Fe2O38955.85Fe3p FeOOH897H2O 56Fe3p FeSO48956.25Fe3p FeOOH56.7Fe3p Fe(OH)3,Fe2(SO4)3 -pyrite n°1- 16357Fe3p Fe2(SO4)3 , FeOOH -pyrite n°2- 1638957.75Fe3p Fe2(SO4)38958.15Fe3p Fe2(SO4)359.4Fe3p satellites -pyrite n°1- 16359.7Fe3p satellite -pyrite n°2- 16362.4Fe3p satellites -pyrite n°1- 16362.5Fe3p satellite -pyrite n°2- 163 Fe3s的电子结合能：Energy (eV) Element Chemical bonding Ref491.3Fe3s Fe°491.7Fe3s FeB491.7Fe3s Fe2BXPS_DatabaseK的电子结合能：Energy (eV) Element Chemical bonding Ref 291.9K2p3/2K3Cr(CN)6 150 292K2p3/2K2MoCl6 111 292.1K2p3/2KF 111 292.1K2p3/2K2SnCl6 111 292.2K2p3/2KN2 111 292.3K2p3/2KCl 111 292.4K2p3/2K2PtCl6 111 292.5K2p3/2K2ReCl6 111 292.6K2p3/2KI 150 292.6K2p3/2KCl 150 292.6K2p3/2KF 150 292.6K2p3/2KBr 111 292.7K2p3/2KCl 111 292.7K2p3/2KNO3 111 292.7K2p3/2K2IrCl6 111 292.7K2p3/2K2TiF6 111 292.8K2p3/2K2OsCl6 150 292.8K2p3/2KBr 111 292.9K2p3/2KBr 150 292.9K2p3/2KNO2 111 292.9K2p3/2K2PtCl4 111 293K2p3/2K2Pt(CN)4 111 293.2K2p3/2KPtCl6 111 293.5K2p3/2KSbF6 150 294.2K2p3/2K in HOPG Intercalation Compounds (st1, vol peak) 143 294.5K2p3/2K 150 294.6K2p3/2élément naturel (liaison métallique) 147 294.6K2p3/2K metal 143 295.4K2p3/2K in HOPG Intercalation Compounds (st2, vol peak) 143 295.4K2p3/2K in HOPG Intercalation Compounds (st3, vol peak) 143 297.5K2p3/2KF 'washed-fume particules' 25 299.4K2p3/2KF 'fume particules' 25 300.7K2p3/2K (g) 111K的电子结合能：Energy (eV) Element Chemical bonding Ref 377.2K2s K2(PdBr4)144144 377.2K2s K2(Pd(CN)4)144 377.4K2s K2(PdCl4)144 377.4K2s K2(Pd(NO2)4)237 384.3K2s KSb2F7237 384.5K2s K2SbF5Li的电子结合能：Energy (eV) Element Chemical bonding Ref51.9Li1s Li métal après bombardement par l'argon 5151.9Li1s Li metal ds DEC(LiPF6) et bomb par argon 5153.3Li1s Li ds Li2O après bombardement par l'argon 5153.3Li1s Li2Oap immersion ds DEC(LiPF6) et bomb par argon 5153.6Li1s LiCO3 ou LiOH ds DEC contenant LiClO4 pdt 240 min 5153.8Li1s Lithium carbide (formed in graphene) 7154.6Li1s Li2CO3 pour surfaces des feuilles de Li métal 5111154.8Li1s Li54.8Li1sélément naturel (liaison métallique) 14711154.9Li1s LiN3150 55Li1s Li2CO3 55Li1s LiPO411111155.1Li1s LiCrO255.2Li1s LiF11115055.5Li1s LiF55.6Li1s Li in graphene, can't be deintercalated 7155.6Li1s LiFaprès immersion ds DEC(LiPF6) 5111155.8Li1s LiCl15055.9Li1s LiCl15056.6Li1s LiBr11156.6Li1s LiBr11156.9Li1s LiCrO457.37Li1s Li ds Li métal 8160.05Li1s Li ds LiC6 81Mn2p3/2的电子结合能：Energy (eV) Element Chemical bonding Ref 638.58Mn2p3/2 Mn 150 638.8Mn2p3/2 MnP 150 638.8Mn2p3/2 Mn 111 639.4Mn2p3/2élément naturel (liaison métallique) 147 639.9Mn2p3/2 MnS 111 640.4Mn2p3/2 MnS 111 640.8Mn2p3/2 Mn(C24H27N7)(PF6)2 111 640.9Mn2p3/2 MnN 150 641Mn2p3/2 MnO 111 641Mn2p3/2 MnO 224 641.1Mn2p3/2 Mn2O3 111 641.2Mn2p3/2 Mn3O4 150 641.4Mn2p3/2 Mn2O3 150 641.5Mn2p3/2 MnCl2 111 641.7Mn2p3/2 MnI2 111 641.7Mn2p3/2 MnBr2 111 641.7Mn2p3/2 K3Mn(CN)6 111 641.8Mn2p3/2 MnCl2 150 641.9Mn2p3/2 MnBr2 150 642Mn2p3/2 MnO2 111 642.1Mn2p3/2 MnSiO3 150 642.1Mn2p3/2 MnF2 111 642.3Mn2p3/2 MnSiO3 111 642.4Mn2p3/2 MnO2 150 642.4Mn2p3/2 MnO2 157 642.8Mn2p3/2 MnCl2 111 645.8Mn2p3/2MnO/MN2O3 'washed-fume particules' 25 646.4Mn2p3/2satellite of satellite of MnO 224 646.8Mn2p3/2 KMnO4 150Na的电子结合能：Energy (eV) Element Chemical bonding Ref 981.4Na1s NaF 'fume particules' 25 1070.3Na1s hydroxysodalite 150 1070.5Na1s hydroxysodalite 111 1070.6Na1s Na2C2O4 150SeO3150 1070.6Na1s Na2111 1070.6Na1s Na2SeO3150 1070.7Na1s NaAsO2MoO4 150 1070.7Na1s Na2111 1070.7Na1s NaAsO2 1070.8Na1s NaOAc 111 1070.8Na1s Na2C2O4 111 1070.8Na1sélément naturel (liaison métallique) 147 1070.8Na1s metal 159150H2PO2 1070.9Na1s NaPO4 150 1070.9Na1s Na3TeO4150 1070.9Na1s Na21070.9Na1s Na2 SnO3, 3 H2O 150150 1070.9Na1s NaOOCH 1070.9Na1s NaOAc 150 1070.9Na1s NaMoO4 111150S2O4 1071Na1s Na2SO4 150 1071Na1s Na21071Na1s Na2CrO4 150thioglycollate 150 1071Na1s Na150 1071Na1s NaF 1071.1Na1s Na2WO4 150150 1071.1Na1s NaBiO3benzene-sulphonate 150 1071.1Na1s Na111 1071.1Na1s Na2S2O4111 1071.1Na1s Na2SO4111 1071.1Na1s NaF111 1071.1Na1s NaTeO4 1071.1Na1s Na2SnO3.H2O 111111 1071.1Na1s Na3PO4 1071.1Na1s NaOAc 111111 1071.1Na1s NaOOCH 1071.2Na1s NaNO3 150 1071.2Na1s Na2SO3 150111 1071.2Na1s Na2CrO4thioglycollate 111 1071.2Na1s Na1071.2Na1s NaH2PO2 111150 1071.3Na1s Na2CO3150ZrF6 1071.3Na1s Na2111 1071.3Na1s Na2CO3 1071.3Na1s NaNO3 111111 1071.3Na1s NaBiO3111 1071.3Na1s NaSCN 1071.3Na1s Na2WO4 111 1071.3Na1s NaHCO3 111benzenesulphonate 111 1071.3Na1s Na1071.4Na1s NaNO2 150PO3 150 1071.4Na1s NaS2O3150 1071.4Na1s Na2150Cr2O7 1071.4Na1s Na2150 1071.4Na1s NaI150 1071.4Na1s NaClTiF6 150 1071.4Na1s Na2111 1071.4Na1s NaCl 1071.4Na1s Na2HPO4 111 1071.4Na1s Na2ZrF6 111111 1071.4Na1s Na2SO3 1071.45Na1s NaA 191 1071.45Na1s NaA 155150 1071.5Na1s NaBr 1071.5Na1s Na zeolite A (Na Al Si O4) 150150 1071.5Na1s NaBF4150 1071.5Na1s Na2GeF6SiF6150 1071.5Na1s Na2 1071.5Na1s Na 111111 1071.5Na1s Na2GeF6111 1071.5Na1s Na2SiF6 1071.6Na1s Na 150PdCl4 150 1071.6Na1s Na2 1071.6Na1s NaI 111 1071.6Na1s NaPO4 111 1071.6Na1s Na zeolite (NaAlsiO4) 111 1071.6Na1s Na2Cr2O7 111111 1071.6Na1s Na2S2O3 1071.6Na1s NaNO2 111 1071.6Na1s NaTiO6111 1071.7Na1s Na2 IrCl6, 6 H2O 150150 1071.7Na1s Na3AlF6111 1071.7Na1s NaBr111 1071.7Na1s Na3AlF6 1071.7Na1s NaPO3 111 1071.7Na1s Na zeolite A (NaAlSiO4) 111 1071.7Na1s metal 1591071.8Na1s Namétal 12 1071.8Na1s Na 111 1071.8Na1s Na2PdCl4 111 1071.9Na1s Na2IrCl6.6H2O 111 1072Na1s Albite (Na Al Si3 O8) 150 1072Na1s NaH2PO4 111 1072.2Na1s Natrolite (Na2 Al2 Si3 O10) 150 1072.2Na1s albite(NaAlSiO8) 111 1072.2Na1s Na in Zeolite 191 1072.2Na1s Na in Zeolite 155 1072.3Na1s Na2O 150(Na2Al2Si3O10.2H2O) 111 1072.4Na1s natrolite1072.5Na1s Na2O 12111 1072.5Na1s NaBF4 1072.5Na1s oxide 159111ox 1072.7Na1s Na159 1073.3Na1s NaOxCyPE-Ar(Na+) 48 1073.6Na1s ds1074Na1s PE-Ar-TFAA (Na+) av spectro PHI 548 48 1075.6Na1s PE-Ar-TFAA (Na+) av spectro DUPONT 650B 48150(g)1078.4Na1s Na(g)111 1078.4Na1s Na 1078.4Na1s NaF 'fume particles' 25Na的电子结合能：Energy (eV) Element Chemical bonding Ref30.5Na2p3/2 metal159métal1230.6Na2p3/2 Na1231.1Na2p3/2 Na2O15931.1Na2p3/2 oxide15931.8Na2p3/2 NaOxCyNa的电子结合能：Energy (eV) Element Chemical bonding Ref23753.4Na2s Na2SbF563Na2s Na in Zeolite 19163Na2s Na in Zeolite 15515963.4Na2s metal1263.55Na2s Namétal19163.55Na2s NaX15563.55Na2s NaX15963.7Na2s metal63.8Na2s Na in Zeolite 19163.8Na2s Na in Zeolite 15512 64Na2s Na2O64Na2s oxide159159 64.71Na2s NaOxCyXPS_DatabaseNi的电子结合能：Energy (eV) Element Chemical bonding Ref215 869.6Ni2p1/2 NiNi的电子结合能：Energy (eV) Element Chemical bonding Ref 851.4Ni2p3/2ds le 304 ss avec N2 implanté 218 851.4Ni2p3/2 Ni11 218 851.95Ni2p3/2 AuNi 150 852Ni2p3/2Ni (16 min)/Al2O3/Al 229 852.1Ni2p3/2 Ni 111métallique 118 852.3Ni2p3/2 Ni852.4Ni2p3/2 Ni 215 852.48Ni2p3/2 Ni 150 852.5Ni2p3/2 Ni 247 852.5Ni2p3/2Ni métal ( 10puis-6 torr) 78 852.5Ni2p3/2Ni métal ( 250°C -1h ) 78 852.5Ni2p3/2Ni, Ni foil polishing and Ar+ etching 101 852.6Ni2p3/2 NiS 150 852.6Ni2p3/2Ni, Ni foil polish and Ar+ etching, + O2 at 200°C/1h 101 852.6Ni2p3/2Ni, Ni foil polishing + water immersion/28h 101Ni 229 852.7Ni2p3/2 bulkmetal 13 852.7Ni2p3/2 Ni852.8Ni2p3/2 Ni2Si 150 852.8Ni2p3/2 Ni-21Cr-8Fe 183 852.8Ni2p3/2 Ni 183 852.8Ni2p3/2Ni° in a passive film on SUS316L 65 852.9Ni2p3/2 Ni2P 150 852.9Ni2p3/2 2 min Ni deposit : Ni dispersed on Al2O3 229 852.9Ni2p3/2Ni, Ni foil polishing and Ar+ etching+H2S 400°C/1h 101 853Ni2p3/2 NiB 150 853Ni2p3/2Ni (7 min)/Al2O3/Al annealed to 800K for 30 min 229 853Ni2p3/2Ni metal with a sample immersed in a 60°C solution 11 853Ni2p3/2Ni metal with a sample immersed in a room t° solution 11 853Ni2p3/2NiS/Ni3S2 -Ni foil polish in H2O/28h+H2S 400°C/1h 101 853Ni2p3/2Ni Polish +Ar+,+O2 -200°C/1h+400°C/2h30mn+H2S 400°C/1h 101 853.1Ni2p3/2NiOads ( 10puis-6 torr) 78 853.1Ni2p3/2NiOads ( air 15min ) 78 853.3Ni2p3/2élément naturel (liaison métallique) 147 853.5Ni2p3/2 NiO 111 853.55Ni2p3/2 Al3Ni 150 853.6Ni2p3/2 NiI2 111 853.9Ni2p3/2 Ni(C5H5)2 111 853.9Ni2p3/2 Ni(PPh3)2 111853.9Ni2p3/2abrasé sur dry 600 grit sandpaper qq sec 207 853.9Ni2p3/2 NiO 118 854Ni2p3/2 Ni2S3 111 854Ni2p3/2 NiO 247 854Ni2p3/2NiO (1er pic) ( 800°C - 10min ) 78 854Ni2p3/2NiO ( 1er pic) ( 800°C-air ) 78 854Ni2p3/2NiO (1er pic ) ( 800°C-air+ O2-10min ) 78 854Ni2p3/2Ni (1 min)/Al2O3/Al : NiO 229 854.2Ni2p3/2 NiO 150 854.2Ni2p3/2 Ni(Co)4 150 854.2Ni2p3/2 NiO 157 854.4Ni2p3/2Ni(II) dans NiO 183 854.4Ni2p3/2 (Ni(SCH2CH2S))n 235 854.4Ni2p3/2 Ni(SCH2CH2S)(PMe2Ph)2 235 854.5Ni2p3/2 Ni(Co)4 111 854.5Ni2p3/2Ni (16 min)/Al2O3/Al annealed to 800K for 10 min :NiAl 229 854.5Ni2p3/2Ni oxide with a sample immersed in a room t° solution 11 854.5Ni2p3/2 Ni(SPh)2(CyNC)2 235 854.6Ni2p3/2 Ni-(dimethyl-glyoxime)2 150 854.6Ni2p3/2 NiO 155 854.6Ni2p3/2 NiO 13 854.6Ni2p3/2 Ni(SPh)2(dppe) 235 854.6Ni2p3/2 Ni(SPh)2(PMe2Ph)2 235 854.7Ni2p3/2 Ni(CN)2 111 854.7Ni2p3/2 Ni(SCH2CH2S)(dppe) 235 854.7Ni2p3/2 (Ni(SPh)2)n 235 854.8Ni2p3/2 NiCl2(NBu3)2 111 854.9Ni2p3/2 NiS 111 854.9Ni2p3/2 NiBr2 111 854.9Ni2p3/2 Ni(dimethylglyoxime) 111 854.9Ni2p3/2 NiFe2O4 111 855Ni2p3/2voir spectres dans la publication 102 855Ni2p3/2Ni oxide with a sample immersed in a 60°C solution 11 855.3Ni2p3/2 NiCO3 111 855.3Ni2p3/2 USY-A-6 44 855.3Ni2p3/2 LaHY 44 855.3Ni2p3/2 Ni(Met)2 235 855.4Ni2p3/2 Ni(C24H27N7)(PF6)2 111 855.4Ni2p3/2 K2Ni(CN)4 111 855.4Ni2p3/2 NiFe2O4 247 855.4Ni2p3/2 USY-A-8 44 855.5Ni2p3/2 Ni(acac)2 150 855.5Ni2p3/2 Me4NNiCl3 111 855.5Ni2p3/2NiO Oads ( 800°C-air+ O2-10min ) 78 855.5Ni2p3/2 USY-B-8 44 855.6Ni2p3/2 Ni(OH)2 247855.6Ni2p3/2 Ni(OH)2 118 855.6Ni2p3/2NiOx, Ni foil polishing + water immersion/28h 101 855.7Ni2p3/2 Ni(OH)2 150acethylacetonate 111 855.7Ni2p3/2 Ni855.7Ni2p3/2 Ni2O3 13 855.8Ni2p3/2 Ni2O3 150 855.8Ni2p3/2NiO (2nd pic) ( 800°C - 10min ) 78 855.8Ni2p3/2NiO (2ème pic) ( 800°C-air ) 78 855.8Ni2p3/2NiO ( 2ème pic) ( 800°C-air+ O2-10min ) 78 855.8Ni2p3/2Ni(OH)2 dans Inconnel 600 (Publication riche en El) 246 855.8Ni2p3/2NiOx, Ni foil polish and Ar+ etching, + O2 at 200°C/1h 101 855.9Ni2p3/2Ni2O3 ( 10puis-6 torr) 78 855.9Ni2p3/2Ni2O3 (1er pic) ( air 15min ) 78 855.9Ni2p3/2Ni2O3 ( 800°C-air ) 78 855.9Ni2p3/2Ni2O3 ( 800°C-air+ O2-10min ) 78 855.9Ni2p3/2 USY-B-8H 44 856Ni2p3/2 NiAl2O4 150 856Ni2p3/2 Ni(OH)2 111 856Ni2p3/2 Ni2O3 111 856Ni2p3/2NiOx, Ni foil polish-Ar+etch+O2, 200°C/1h+400°C/2h30mn 101 856.1Ni2p3/2 NiCl2 111 856.1Ni2p3/2Ni2O3 (1er pic) ( 250°C -1h ) 78 856.1Ni2p3/2 USY-2 44cyclohexanebutyrate 111 856.3Ni2p3/2 Ni856.3Ni2p3/2 USY-D 44 856.4Ni2p3/2 (NH4)2NiF4 111 856.4Ni2p3/2 Ni(OH)2 13 856.5Ni2p3/2 NiCl2 150 856.6Ni2p3/2 NiSiO4 150 856.7Ni2p3/2 NiSiO3 150 856.8Ni2p3/2 Ni(NO3)2 111biuret 111 856.8Ni2p3/2 KNitrifluoroacetate 111 856.9Ni2p3/2 Ni856.9Ni2p3/2 LaHY-H2O 44 856.9Ni2p3/2 NiSiO3 155 857Ni2p3/2 NiSO4 111 857.1Ni2p3/2 NiAl2O4 111 857.2Ni2p3/2 NiF2 150 857.2Ni2p3/2 NiWO4 111 857.3Ni2p3/2Metal salt NiCl2 in 316 L alloy 207 857.8Ni2p3/2 NiF2 111 858.5Ni2p3/2Ni métal (10puis-6 torr) 78 858.7Ni2p3/2 NiSiF6 111 860.9Ni2p3/2 K2NiF6 111 861.2Ni2p3/2NiO (3eme pic) ( 800°C - 10min ) 78 861.2Ni2p3/2NiO ( 3ème pic) ( 800°C-air ) 78861.2Ni2p3/2NiO (3ème pic) ( 800°C-air+ O2-10min ) 78 861.4Ni2p3/2Ni2O3 ( 2eme pic) ( air 15min ) 78 861.4Ni2p3/2Ni2O3 ( 2ème pic ) ( 250°C -1h ) 78Ni的电子结合能：Energy (eV) Element Chemical bonding Ref21567.4Ni3p1/2 NiNi的电子结合能：Energy (eV) Element Chemical bonding Ref21565.7Ni3p3/2 Ni247métal66.3Ni3p3/2 Ni24767.3Ni3p3/2 NiO247 68Ni3p3/2 Ni(OH)224768.1Ni3p3/2 NiFe2O4Ni的电子结合能：Energy (eV) Element Chemical bonding Ref215 110.2Ni3s Ni247 110.7Ni3s Ni247 111.8Ni3s NiO247 112.7Ni3s Ni(OH)2247 113Ni3s NiFe2O4XPS_Database575Cr2p3/2Cr métallique,satellite (20 at% de Cr) 212 575Cr2p3/2Cr2p3/2 (voir spectres dans la publication). 102 575.5Cr2p3/2 CrN 111 575.5Cr2p3/2CrN du SS304 traité au N3- 17 575.5Cr2p3/2 CrN11 218 575.6Cr2p3/2 Cr2O3 186 575.7Cr2p3/2 CrN 225 575.7Cr2p3/2Cr ds CrN 55 575.7Cr2p3/2 Cr2O3 157oxyde 186 575.8Cr2p3/2 Cr(III)575.8Cr2p3/2Cr ds Cr2O3 198 575.9Cr2p3/2 CrO2 111 575.9Cr2p3/2 CrBr3 111 576Cr2p3/2 Cr2O3 186 576Cr2p3/2Cr oxide with a sample immersed in a 60°C solution 11 576Cr2p3/2Cr oxide with a sample immersed in a room t° solution 11 576.04Cr2p3/2élément naturel (liaison métallique) 147 576.1Cr2p3/2 CuCrO2 111 576.1Cr2p3/2 CrO2 186 576.1Cr2p3/2Cr ds Cr2N 55 576.2Cr2p3/2 Cr2O3 186-304SS- 138 576.3Cr2p3/2 Cr2O3576.3Cr2p3/2Cr2O3 -Fe /19Cr /9Ni- 138 576.3Cr2p3/2Cr2O3 in 316L before sputtering the passive film 116 576.3Cr2p3/2Cr2O3 in 316L after sputtering the passive film 116 576.3Cr2p3/2Cr3+ ds Cr2O3 1 576.3Cr2p3/2Cr2O3 in alloy 33 before sputtering the passive film 116 576.3Cr2p3/2Cr2O3 in alloy 24 before sputtering the passive film 116 576.3Cr2p3/2Cr2O3 in alloy 33 after sputtering the passive film 116 576.3Cr2p3/2Cr2O3 in alloy 24 after sputtering the passive film 116 576.4Cr2p3/2 Cr2O3 150 576.4Cr2p3/2Cr3+ ds Cr2O3 73 576.4Cr2p3/2Cr2O3 in a passive film on SUS316L 65 576.5Cr2p3/2 Cr2O3 111 576.5Cr2p3/2 CrI3 111oxyde 186 576.5Cr2p3/2 Cr(III)576.5Cr2p3/2 Cr3+ 216 576.5Cr2p3/2 Cr2O3 118 576.6Cr2p3/2Cr à l'état oxydé 176 576.6Cr2p3/2 CrOx 2 576.6Cr2p3/2 CrOx 84 576.7Cr2p3/2 Cr2O3 186 576.7Cr2p3/2Cr(IV) dans sel de sodium 186 576.7Cr2p3/2Cr3+ ds Cr2O3 156 576.7Cr2p3/2CrOOH in alloy 33 before sputtering the passive film 116 576.7Cr2p3/2CrOOH in alloy 24 before sputtering the passive film 116576.8Cr2p3/2 CrOOH 111 576.8Cr2p3/2 LiCrO2 111 576.8Cr2p3/2 NaCrO2 111 576.8Cr2p3/2 Cr2N 225 576.8Cr2p3/2Cr2O3 in Co-Cr alloy 65 576.8Cr2p3/2 CrOOH 186 576.8Cr2p3/2 CrOx 84 576.9Cr2p3/2Cr(III) dans Cr2O3 183 577Cr2p3/2 CrCl3 111 577Cr2p3/2CrOOH / Cr(OH)3 -304 SS- 138 577Cr2p3/2CrOOH -Fe /19Cr /9Ni- 138 577Cr2p3/2 Cr2O3 186 577Cr2p3/2 CrOOH 186 577Cr2p3/2pic XPS (Cr3+) alliage Fe24Cr 124 577Cr2p3/2Cr3+ ds Cr(OH)3 ou CrOOH 1 577Cr2p3/2 Cr3+ 228 577Cr2p3/2 Cr(OH)3 118 577.1Cr2p3/2Cr2O3 dans Inconel 600 (Publication riche en El) 246 577.1Cr2p3/2Cr hydroxide with a sample immersed in a 60°C solution 11 577.2Cr2p3/2Cr(III) dans Cr2O3 183 577.2Cr2p3/2Cr3+ ds Cr(OH)3 156 577.2Cr2p3/2Cr hydrox with a sample immersed in a room t° solution 11 577.3Cr2p3/2 Cr(OH)3 186 577.4Cr2p3/2hydroxyde de chrome 225 577.4Cr2p3/2Cr-O (20 at% de Cr) surface non bombardée 212 577.5Cr2p3/2Cr(III) hydroxyde et formes hydratées ou Cr(IV) 186 577.6Cr2p3/2 CrCl3 150 577.6Cr2p3/2abrasé sur dry 600 grit sandpaper qq sec 207 577.9Cr2p3/2 CrO3 111 578Cr2p3/2 CrO3* 118 578.1Cr2p3/2CrO3 -304 SS- 138 578.1Cr2p3/2CrO3 -Fe /19Cr /9Ni- 138 578.1Cr2p3/2 CrO3 186 578.1Cr2p3/2CrO3 in 316L before sputtering the passive film 116 578.1Cr2p3/2Cr6+ ds CrO3 1 578.1Cr2p3/2CrO3 in 316L after sputtering the passive film 116 578.1Cr2p3/2CrO3 in alloy 33 before sputtering the passive film 116 578.1Cr2p3/2CrO3 in alloy 24 before sputtering the passive film 116 578.1Cr2p3/2Cr2O3 in alloy 33 after sputtering the passive film 116 578.1Cr2p3/2Cr2O3 in alloy 24 after sputtering the passive film 116 578.2Cr2p3/2Cr et Cr(III) dans Cr2O3 ou Cr(III) dans Cr(OH)3 183 578.2Cr2p3/2Cr Ox in 316 L alloy dipped in physiological serum 207 578.2Cr2p3/2Cr Ox in 316 L pot anod (5V for 5 min) in physio serum 207 578.5Cr2p3/2Cr-Cl with a sample immersed in a room t° solution 11 578.6Cr2p3/2Cr Ox, 316 L alloy fretted (30 min) in physio serum 207 578.6Cr2p3/2Metal salt CrCl3 in 316 L alloy 207。
xps电子结合能对照表
1.0Bi6p1 3.9 Pt 5d10.0P 3p 18.0At 6s 24.0Kr 4s 34.0K 3s 44.0Ra 6s 52.0Tm 5s 65.7V 3s1.0Ce4f 4.0 Ir 5d10.0Ti 4s 18.0Ce 5p 24.0Sn 4d 35.0Re 5p3 44.0U 6s 52.3Yb 5s 66.0Ni 3p1.0Co3d 4.0Pm 4f 10.0V 4s 18.0Pr 5p 25.0Th 6p1 35.2Mo 4p 44.4Y 4s 52.6Fe 3p 66.0Pt 5p1 1.0Cr3d 4.5Ag 4d10.0Zr 5s 18.1Hf Ntv Ox 26.0Bi 5d3 35.2W Na2WO445.0Ta 5p1 53.0Sn loss 67.8Ta 5s1.0Fe3d 4.8Dy 5d10.5Bi 6s 18.2 C 2s 26.0He 1s 35.3Y loss 45.1As 2O3 53.4Os 4f5 68.0Ra 5d1.0Ga4p 5.0 B 2p10.7Cd 4d5 18.4Sr 4p 26.0Rn 6s 35.8W O3 45.5As Ntv Ox54.0Os 5p1 68.0Tc 4s1.0Hf5d 5.0 Br 4p11.0Kr 4p 18.7Ga 3d5 26.1Lu 5p 36.0Ce 5s 45.7Ge loss 54.2Se CdSe68.5Br 3d5 1.0In 5p 5.0Ca 3d11.0Rn 6p 18.8Ga 3d 26.8Ta 2O5 36.0Gd 5s 46.0Re 5p1 54.5Se GeSe68.5Br KBr 1.0Na3s 5.0 Er 4f 11.0Sc 4s 18.9Ga 3d3 26.8Zr 4p 36.6Sr 4s 46.3Ga loss 54.9Se 3d5 68.8Cd 4p1.0Os5d 5.0Po 6p11.1Cs 5p3 19.0Eu 5p 27.0Br 4s 36.7V 3p 46.8Re 2O7 54.9Li 1s 69.0Br 3d1.0Pb6p 5.3Se 4p11.6Cd 4d3 19.0Nd 5p 28.2Sc 3p 37.0W 5p3 46.8W 5p1 54.9Li OH 69.5Br 3d3 1.0Sn5p 5.5 Cl 3p12.0Cs 5p 19.0Pb 5d5 28.6In loss 37.5Hf 5p1 47.0Mn 3p 54.9Se 3d 70.0Re loss 1.2Yb4f7 5.8Au 5d12.0Po 6s 19.0Ra 6p 28.8Rb 4s 38.0Pm 5s 47.0Rh 4p 55.2Se GeSe271.0Pt 4f7 1.4Pd4d 6.0Ta 5d12.0Te 5s 19.0Sm 5p 29.0Dy 5p1 38.0Pr 5s 47.9Ru 4p 55.3Li CO3 71.8Mg loss1.4Rh4d 6.0 Y 4d12.0Tl 5d5 19.1Ga Sb fract29.0Er 5p 38.3Sn loss 48.0Dy 5s 55.6Nb 4s 72.6Pt 4f2.0Cd5p 6.2Hg 5d12.6Cs 5p1 19.4Ga AlAs etch29.0Lu 5p 39.0Eu 5s 48.0Rn 5d 55.7Se 3d3 72.7Al 2p3 2.0Mg3s 6.9Eu 4f 13.0Tl 5d 19.5N 2s 29.1Ge 3d5 39.0Nd 5s 48.0Sb loss 56.8Au 5p3 72.9Al 2p2.0Mo4d 7.0 O 2p13.2Rb 4p 19.7Ga P fract 29.2 F 2s 39.0Tc 4p 48.5 I 4d 56.8Lu 5s 73.1Tl 5p3 2.0Nb4d 7.0Sm 4f 13.2Rb 4p 19.7Ga As fract29.4Ge 3d 39.5Tm 5p 49.5Ho 5s 57.4Er 5s 73.2Al 2p1 2.0Nd4f 7.0Sn 5s14.0Ne 2p 20.0U 6p 29.5Ho 5p1 40.0At 5d 49.5Mg CO3 58.0Ag 4p 73.8Al N2.0Ni 3d 7.0Xe 5p14.0Sc 3d 20.2Zn loss 29.7Ge 3d3 40.0Ba 5s 49.6Mg(OH)258.0Fr 5d 74.0Au 5p1 2.0Pr 4f 7.1Lu4f714.2Hf 4f7 20.5Gd 5p 30.2Ge Se 40.0In loss 49.6Mg 2p3 58.0Hg 5p3 74.2Cr 3s2.0Sb5p 7.1Tb 4f 15.0Fr 6p 20.7Ga 2O3 30.3Na 2p 40.0Tb 5s 49.7Mg O 58.1W loss 74.3Al 2O3 2.0Sc4p 7.7Gd 4f 15.0H 1s 21.0Pb 5d3 30.9Nb 4p 40.1Te 4d 49.8Mg 2p 58.2Ti 3s 74.3Al2O3-nH2O 2.0Tc4d 7.8Dy 4f 15.0Hf 4f 21.6Ta 4f7 30.9Pb loss 40.2Re 4f7 49.9Mg 2p1 58.3Te loss 74.4Pt 4f5 2.0Ti 3d 8.0 At 6p15.0Rb 4p1 21.8Tb 5p 31.0Hf 5p3 41.0Ne 2s 50.0Mg CO3 58.6Ag 4p 74.4Al (OH)3 2.0V 3d 8.0 S 3p15.0Tl 5d3 22.0Dy 5p3 31.0Po 5d 41.0Sm 5s 50.0Sr loss 58.9Y loss 74.9Cu 3p2.0Yb 4f 8.3Ho 4f 15.7Cl 3s 22.0Pm 5p 31.3W 4f7 41.2Re 4f 50.3Zr 4s 59.0Co 3p 74.9Se loss 2.0Zr 4d 8.3Lu 5d15.9Hf 4f5 22.3Ar 3s 31.5Ge Se2 41.4Re Ntv Ox 50.4Mg NtvOx159.2As loss 75.0Cs 4d5 2.5Yb4f58.4Lu2O315.9 I 5s 22.7Ta 4f 31.7Sb 4d 41.5As 3d5 50.7Os 4f7 60.8Ir 4f7 75.1Pt O2-nH2O 2.6Te5p 8.5Tm4f716.0K 3p 23.0Cs 5s 32.1Ga loss 41.8As 3d 50.7Pd 4p 61.0Mg loss 75.1W 5s2.8Cu3d 8.6Lu4f516.0P 3s 23.1O 2s 32.3W 4f 42.0As S 50.7Sc 3s 62.0Ir 4f 75.5Al Ntv Ox 2.8Mn3d 8.9 Ar 3p16.0S 3s 23.3Ho 5p3 32.4Ti 3p 42.0Th 6s 50.9Mg reoxid62.0Ir O2 76.0Cs 4d2.8Re5d 9.0 F 2p16.9In 4d 23.3Y 4p 32.6Ta 5p3 42.1Ca 3s 51.0Ir 5p3 62.0Ir 5p1 77.8Ni loss 2.8Si 3p 9.0Ru 4d17.0La 5p 23.4Ta S2 33.0La 5s 42.1Cr 3p 51.0Mg NtvOx262.0Mo 4s 78.3In 4p2.8W 5d 9.0Sb 5s17.0Th 6p3 23.5Ca 3p 33.2Ge O2 42.2As 3d3 51.4Os 4f 62.0Xe 4d 79.0Cs 4d33.0Ge4p 9.0 Si 3s17.0Xe 5s 23.5Yb 5p 33.4Lu 5p 42.7Re 4f5 51.5Pt 5p3 62.3Hf 5s 80.0Ru 4s3.0 I 5p 9.1As 4p17.1Hf O2 23.8Bi 5d 33.5W 4f5 42.7Ta loss 51.5Mg reoxid62.7Ir Ntv Ox80.7Rh 4s3.0Pb6s 9.7Zn 3d17.7Pb 5d 24.0Ta 4f5 33.8Ge Ntv Ox43.0As 2S3 51.7Re loss 63.3Na 2s 81.0Hg 5p1 3.2Bi6p310.0Ba 5p17.9Ga InAs (ar)24.0Bi 5d5 34.0Fr 6s 44.0Os 5p3 51.9Mg NtvOx363.8Ir 4f5 81.8Re 5s82.0Br loss101.8Si Almand.119.4Ga loss 137.8Pb 2O3 158.9Y 2(CO3)3 181.0Ge 3s 204.1Nb NbO 235.3Mg Auger 82.0Mn 3s 101.9Hg 4f 119.4Tl CO3 137.8Se Auger159.2Bi Ntv Ox 181.1Zr 3d3 205.0Nb 3d3 237.0Pm 4p3 82.7Pb 5p3 102.0Pt 5s 120.0Hg 5s 138.3Pb 4f 159.6Ho 4d5 181.2Br 3p3 205.1S loss 237.6Ta 4d3 84.0Au 4f7 102.0Si 3N4 120.0Tl 4f 138.5Ge loss 160.0Bi 5s 182.0Br 3p 205.8Lu 4d3 237.9Rb 3p3 84.0Ba 4d3 102.6Si O 121.0Pm 4d 138.8Pb Ntv Ox161.2S PbS 182.0Fr 5p1 206.1Nb NbO2238.0Cs 4s84.7Ba 4d 102.9Zn loss 121.1 I 4p 139.0Pb CO3161.3Ho 2O3 182.1Yb 4d5 207.0Ce 4p3 238.0Rn 4f85.0Au 4f 103.0Ga 3p 122.0Ge 3p3 139.0Xe 4p 161.5S CuS, TaS2182.4Zr O2 207.0Xe 4s 238.9Mo loss85.0Th 5d5 103.0Ga 3p3 122.1Tl 4f5 139.5Zn 3s 161.7Se 3p3 182.8Er Auger 207.3P loss 241.8Ar 2p386.0Ba 4d5 103.0Pt loss 122.4Cu 3s 140.0Fr 5p3 161.9S HgS 183.7Si loss 207.4Nb Nb2O5242.0Ar 2p86.9 Kr 3d5 103.0Si O2 122.4In 4s 140.3Gd 4d5 162.2S MoS2 184.0Po 4f 207.4Nb Ntv Ox243.1W 4d587.2Kr 3d 103.0U 5d3 127.0Rn 5p3 140.7As 3p3 162.3Bi 4f5 184.9Yb 2O3 208.0Kr 3p3 243.9Ar 2p187.7Au 4f5 103.5Si O2-nH2O128.2Eu 4d5 141.2Gd2O3 162.4S Na2S2O3185.3S loss 210.0At 4f 245.0Nd 4p188.0 Al loss 103.7Al loss 128.3Tl loss 141.7Pb 4f5 162.6S FeS2 185.5 I 4s 210.8Hf 4d5 248.0Ba 4s 88.1Au2O3103.9Hg 4f5 128.6P InP etch142.0As 3p 163.9S 2p3 187.8Br 3p1 210.9Dy Auger248.0Rb 3p1 88.2Kr 3d3 104.0La 4d 129.0Ge 3p1 145.9Tb 4d5 164.0Rn 5p1 187.9 B CrB 213.0 B loss 249.6S loss 88.2Pd 4s 104.0Po 5p3 129.0P InP etch146.0Sr loss 164.0S 2p 188.0 B 1s 213.0La 4p1 250.0Sm 4p388.3Zn 3p 106.3Pb 5p1 129.0Sm 4d 147.0As 3p1 164.0Sr loss 188.0B MoB, LaB6214.0Rn 5s 253.0Mo loss89.0Os 5s 107.0Ga 3p1 129.3P GaP etch148.0At 5p1 165.1S 2p1 188.1 B WB 217.5Cl loss 253.0Tc 3d89.1Mg 2s 108.0Au 5s 130.0Be loss 148.0Pb 5s 166.6S Na2SO3 188.2 B Ni3B 218.0Pr 4p3 253.0Tc 3d590.6Sn 4p 109.7Rb 3d5 130.0Ho Auger 148.5Tb F3 167.3Er 4d5 188.9 B Ntv Ox 220.5Se Auger254.0Ra 5s91.0Fe 3s 109.7Rb OAc 130.1P 2p3 148.8Al loss 167.3Se 3p1 189.0P 2s 221.3Hf 4d3 255.0Br 3s92.8 Bi 5p3 109.9Cd 4s 130.6P 2p 149.8Pb loss 167.6Si loss 189.2Tm Auger 223.0Ce 4p1 255.0Eu 4p393.0Th 5d3 110.0Ce 4d 131.4P 2p1 149.9P loss 168.5Er 2O3 190.8 B N 225.7As 3s 255.0Pm 4p194.0 U 5d5 110.0Rb 3d 132.0Po 5p1 149.9Tb 3O7 168.5S Na2SO4 190.9Yb 4d3 226.1Ta 4d5 255.1Se Auger94.6 Tl 5p1 110.5Ni 3s 132.7Ga loss 150.5Si 2s 168.5S Na2S2O3194.0 B 2O3 228.0Mo 3d5 255.6W 4d395.2 Ir 5s 110.6Mg loss 133.4Al loss 152.0Zn loss 168.6P loss 195.0At 5s 228.0Nd 4p3 257.0Tc 3d396.0Br loss111.2Rb 3d3 133.6Si loss 152.3Dy 4d5 168.8Y loss 195.0U 5p3 229.0S 2s 260.0Re 4d597.0Ag 4s 111.8Be 1s 133.7Sr 3d5 152.9Sb 4s 169.1Te 4s 196.0Lu 4d5 229.4Mo O2 (?)260.0U 5p198.7Er Auger112.6Te 4p 133.7Sr CO3 153.0Ra 5p3 169.3Er 4d3 196.1Zr loss 229.5Mo 3d 261.0As Auger99.8 Si 2p3 113.6Be O 134.0Sr 3d 155.8Y 3d5 173.0Ba 4p 197.0La 4p3 229.7Mo S2 261.5Tb Auger 99.8Mg loss 114.7Be Ntv Ox 134.9Sm 2O3 156.1Dy 2O3 173.3Ga loss 197.5Ge Auger 229.9Se 3s 264.3Rb loss 99.9Hg 4f7 115.0At 5p3 135.5Sr 3d3 156.6Y 2O3 175.4Tm 4d 198.4Se Auger 230.0As Auger267.5S loss 100.1Si 2p 115.0Pr 4d 135.6Eu 2O3 157.0Bi 4f7 175.9Tb loss 198.7Cl 2p 231.1Mo 3d3 267.7W loss 100.2Si O 115.5Se Auger 136.8Pb O2 157.0Bi 4f 176.3Tm 2O3 198.9Cl 2p3 232.6Mo Ntv Ox268.0Fr 4f 100.4Si 2p1 116.2Si loss 136.8Rb loss 157.0Bi loss 177.0Po 5s 198.9Cl MCl 232.9Tb Auger268.4Sr 3p3 100.4Si C 117.7Tl 4f7 136.9Pb 4f7 157.0Y 3d 177.0Th 5p3 199.8Cl C-Cl 233.0Kr 3p1 270.0Cl 2s 100.6Sb 4p 117.9Al 2s 137.0Tl 5s 157.9Y 3d3 178.7Se Auger 200.0Ra 5p1 233.1Mo O3 271.3Gd 4p3 100.7Hg O 118.0Nd 4d 137.1Sn 4s 158.5Cs 4p3 178.7Zr 3d5 200.5Cl 2p1 234.0Fr 5s 273.5Re 4d3 100.9Co 3s 118.2Bi 5p1 137.5Pb O 158.8Bi 2O3 179.9Zr 3d 201.4Nb 3d 234.0Pr 4p1 274.5Er Auger 100.9Hg S 118.2Tl 2O3 137.6Pb 3O4 158.9Ga 3s 180.9Cs 4p1 202.3Nb 3d5 234.0Th 5p1 275.0La 4s278.7Sr 3p1 301.6Mg Auger340.3Pd 3d3 382.0U 4f 412.7Lu 4p1 460.2Gd Auger515.0Eu Auger 560.0Pd 3p1 279.0Os 4d5 305.0Pr 4s 341.4Ge Auger 384.9Tl 4d5 420.4Ta loss 462.5Ta 4p1 515.6V 2p 560.9Ti 2s 280.1Ru 3d5 305.5K loss 342.0Th 4f5 386.0Tm 4p1 421.6Mo loss 463.1In loss515.9V 2O3 562.8Ta 4s 281.0Ru Ntv Ox 307.2Rh 3d5 343.0Ho 4p1 388.0U 4f5 423.3W 4p3 464.0Bi 4d3 517.1V 2O5 565.0Na Auger 281.1Ru O2 308.5Rh Ntv Ox343.0Zr 3p1 388.3Se Auger 424.5N loss 466.1Ru 3p3 517.3V O2 567.0Rn 4d3 282.2Ru 3d 308.9Rh 2O3 346.5Pd loss 389.8K loss 425.0As Auger 466.8Nb 3s 518.5Re 4p1 568.1Cu Auger 282.6 C VC 308.9Sr loss 346.6Ca 2p 390.3Yb 4p1 425.0Tc 3p3 468.0As Auger519.0As Auger 570.9Ga Auger 282.9 C NbC 309.4Rh 3d 347.1Ca O 391.7Ga Auger 425.5Pb loss 468.5Tm 4s 519.6Pt 4p3 572.5Te CdTe 283.0 C TaC 310.4Ge Auger347.2Mg Auger 391.7Mg Auger 429.6Zr 3s 471.0Os 4p3 519.7V 2p1 572.9Te 3d5 283.0Sm 4p1 311.0Tb 4p1 347.8Ca UHV Ox393.8Mo 3p3 433.0Ge Auger 471.5Zn Auger521.3Rh 3p1 573.0Zn Auger 284.0Tb Auger 311.1Y 3p1 349.0Sm 4s 393.8Y 3s 434.3Pb 4d3 473.0Po 4d5 524.0Na Auger 573.6Ag 3p3 284.2Ru 3d3 311.9Ir 4d3 353.0Au 4d3 395.6Tb 4s 436.0Ho 4s 474.0Se Auger524.8Ge Auger 574.1Cr B 284.5 C HOPG 311.9Rh 3d3 357.2Sr 3s 397.0N CrN 437.3Hf 4p1 474.7In loss528.2Sb 3d5 574.3Cr 2p3 284.5Se Auger 312.5Mg Auger357.9Ge Auger 397.1N AlN 437.8Ca 2s 480.8Yb 4s 529.4O Ag2O, NiO575.0Cr 2p 285.0 C 1s 313.0 C loss 357.9Mg Auger 397.3N TiN 440.0Bi 4d5 484.9Sn 3d5 529.6Sb 2O3 575.5Cr Ntv Ox 285.4 C C-OR 314.5Pt 4d5 358.3Hg 4d5 397.6N Si3N4 443.6Ge Auger 486.3Sn O 529.8O MgO 575.6Cr 2O3 286.0Cl loss 315.1Se Auger358.6Se Auger 398.4N 1s 443.8In 3d5 486.4Ga Auger530.5O NaOH 576.5Te O2 286.0Tb 4p3 315.2Ho 4p3 359.0As Auger 398.4N BN 444.3In 2O3 487.3Sn O2 531.1O Al2O3 576.6Cr Ntv Ox 287.0 C C-Cl 319.5Ar 2s 359.2Lu 4p3 398.4Sc 2p3 444.4In Ntv Ox488.4Ru 3p1 531.1Sb 2O5 577.0Fr 4d5 287.8 C C=O, C-F 320.0Nd 4s 359.3Zr loss 399.8Se Auger 444.8In P fract488.8Ho Auger531.8O 1s LiOH 577.0Te 3d 288.9 C COOR 320.8Er 4p3 360.8Nb 3p3 399.9Tm Auger 444.9In GaAs 490.5W 4p1 532.3Pd 3p3 577.2Hg 4p3 289.0Eu 4p1 321.2K loss 363.0Eu 4s 400.6Ta 4p3 445.0Tc 3p1 493.3Sn 3d3 532.5Ga Auger 577.7Cr Ntv Ox 289.0Kr 3s 321.8Rb 3s 363.6Ga Auger 401.0Sc 2p 445.2In Ntv OH494.6Zn Auger532.5O B2O3, SiO2578.2Ir 4p1 289.4 C MCO3 322.0U 5s 363.7Dy Auger 401.9Sc 2O3 445.9In Ntv CO3494.8Ir 4p3 532.6Sb 3d 579.5Cr O3 290.0Ce 4s 323.6Mg Auger366.0Er 4p1 402.2N H4 446.4Re 4p3 496.3Rh 3p3 532.9O HgO 579.8Ge Auger 290.6Gd 4p1 326.8Ge Auger366.8Ag 2S 403.2Sc 2p1 446.9Pb loss 497.1Se Auger533.0At 4d3 580.0Cr KCrO4 290.8C C-CO3, CF2329.4Zr 3p3 367.7Ag O 404.1Cd O 447.3Ga Auger 497.2Sn 3d 533.8Hf 4s 581.8Zn Auger 291.7 C pi->pi* 331.0Pm 4s 368.2Ag Ag, Ag2O405.0Cd 3d5 448.0In 3d 497.4Na Auger536.4Na Auger 583.3Te 3d3 292.7 C CF3 331.2Pt 4d3 368.5Mg Auger 405.1Cd Te 450.3Er 4s 498.0Sc 2s 537.6Sb 3d3 583.5Cr 2p1 292.9K 2p3 KX 332.0Dy 4p1 370.0Eu Auger 405.4Cd Se, CO3451.4In 3d3 499.0Sn loss 541.0Rn 4d5 586.2Er Auger 293.0Os 4d3 332.3Tm 4p3 371.0Ag 3d 405.5Tl 4d3 453.0Se Auger 500.0Po 4d3 544.0Tc 3s 586.9Tm Auger 294.0Th 5s 333.0Th 4f7 371.0As Auger 406.7Cd (OH)2 453.9Ti 2p3 503.8Ga Auger544.2Sb loss 588.9Ga Auger 295.0K 2p 333.1Mg Auger374.2Ag 3d3 407.2N O3 454.3Na Auger 505.0Mo 3s 546.3Au 4p3 591.0Ru 3s 295.6Dy 4p3 334.0Au 4d5 376.0Gd 4s 408.0Cd 3d 455.1Ti O 507.0At 4d5 548.0Os 4p1 593.6W 4s 295.7K 2p1 335.0Pd 3d5 376.2Nb 3p1 411.0Tb Auger 456.0Ti 2p 507.5Sn loss548.1Cu Auger 600.0Gd Auger 296.2Ir 4d5 335.4Pd Ntv Ox377.2K 2s 411.3Mo 3p1 457.4Ti 2O3 507.9Lu 4s 552.4Na Auger 600.7Te loss 296.2Se Auger 337.0Pd O 377.3U 4f7 411.7Cd 3d3 458.0As Auger 512.1V 2p3 553.2O loss 603.0Fr 4d3 299.0Ra 4f 337.5Pd 3d 377.8Hg 4d3 412.0Pb 4d5 458.2Ti CaTiO3513.2Na Auger553.3Sb loss 603.0Ra 4d5 299.2Y 3p3 339.0As Auger379.5Hf 4p3 412.3Ge Auger 458.7Ti O2 513.5Ga Auger557.1Tb Auger 604.0Ag 3p1 300.6Sr loss 339.8Yb 4p3 381.0Mg Auger 412.6Dy 4s 460.0Ti 2p1 513.9Dy Auger558.5Zn Auger 609.1Pt 4p1609.6Tl 4p3 675.0Xe 3d 724.0Pt 4s 819.7Te 3p3 915.9Cr Auger999.0 O Auger 1107.0N Auger1243.8Pd Auger 617.0Cd 3p3 676.0Th 4d5 724.8Cs 3d5 826.0In 3s 918.6Cs Auger1003.0Nd 3d3 1108.0Sm 3d3 1245.9Tl Auger 619.0 I 3d 676.7In loss 724.8Cs Cl 830.5Co Auger925.3Co 2s 1003.6Cr Auger 1109.8Cd Auger1249.0Ge 2p1 619.2 I 3d5 677.9Tm Auger724.9Cs2O:SiO2833.0Ce Auger929.0Rn 4p1 1004.8Te 3s 1112.9Sb Auger1250.8Pt Auger 619.2 I KI 679.0Bi 4p3 736.0U 4d5 833.0F Auger930.9 I 3p1 1008.7Ni 2s 1116.6Ga 2p3 1259.8Ru a 623.2Ni Auger680.2Hg 4p1 740.0At 4p3 835.2La 2O3 931.7Cu Cl 1013.0O Auger 1117.7Sc Auger1264.2Mo Auger 625.2Re 4s 682.0Sm Auger740.0Cs 3d3 836.0La 3d5 931.8Pr 3d5 1014.7V Auger 1126.0Eu 3d5 1265.0Rh Auger 626.1Ho Auger682.4Xe 3d3 748.0Ho Auger 836.5Te loss 932.0Cs Auger1020.3Te Auger 1128.0La 3p3 1265.8Ge loss 626.4V 2s 685.1 F CaF2749.0Cs loss 837.2La B6 932.3Cu S 1021.7Zn O 1128.9Ag Auger1272.0Ce 3p1 627.8Rh 3s 685.7 F 1s 756.2Sn 3p1 837.9Co Auger932.4Cu 2O 1021.8Zn 2p3 1129.0Sn Auger1272.0U 4p1 628.2Cu Auger685.7 F LiF 758.0Nd Auger 841.1Gd Auger932.6Cu 2p3 1022.3Zn S 1131.8Te Auger1275.7Tb 3d3 629.4Ga Auger688.9 F CF2 761.1Pb 4p1 844.2Cs Auger932.9Cu 2O 1022.5Sb Auger 1135.0Ag Auger1296.2Dy 3d5 630.6 I 3d3 690.9Ir 4s 761.2Au 4s 846.0Fe Auger933.9Cu O 1027.0Pm 3d5 1137.0Ba 3p1 1298.6Mo Auger 634.5Er Auger695.7Cr 2s 761.8Cs loss 846.7Tl 4s 934.0Xe 3p3 1027.2Cr Auger 1141.0Xe 3s 1303.3Mg 1s 635.0Cu Auger697.4Co Auger763.4Gd Auger 851.0Po 4p1 934.6Cu(OH)21031.0Zn loss 1143.4Ga 2p1 1304.0Cl Auger 636.0Ra 4d3 700.3Tb Auger766.4Sb 3p3 851.6Mn Auger936.6Bi 4s 1031.9Sb Auger 1148.9Sc Auger1307.0Hf Auger 638.7Mn 2p3 702.0Ne Auger768.0Rn 4p3 852.6Ni 2p3 940.7Cu CT 1034.9Ti Auger 1151.0In Auger1315.3Mg loss 640.4Ni Auger703.1In 3p1 768.6Mn 2s 852.9Ni B 942.2Cu CT 1042.0At 4s 1153.0Fr 4s 1316.1Pt Auger 640.5Ga Auger703.5 F loss 770.2Sn loss 853.0La 3d3 943.8Cu CT 1043.0U 4p3 1155.0Eu 3d3 1318.0Ta Auger 640.9Mn Mn3O4705.0Po 4p3 772.8Cd 3s 853.8Ni O 944.0Sb 3s 1044.8Zn 2p1 1159.4Pd Auger1319.0Nb Auger 641.0Mn MnO 705.2Ni Auger777.7Ni Auger 854.3Ni Ntv Ox944.1Mn Auger1049.6Sn Auger 1170.0Th 4p1 1321.6Lu Auger 641.0Mn Mn2O3706.7Fe 2p3 778.3Co 2p3 855.4Ni(OH)2945.5Sb Auger1052.0Pm 3d3 1184.0Ce 3p3 1322.3Re Auger 641.6Mn MnO2707.2Fe S2 779.0U 4d3 859.0F Auger952.2Cu 2p1 1055.3V Auger 1185.5Rh Auger1323.9As 2p3 642.4Au 4p1 707.5Ga Auger779.2Co O 863.0Ne 1s 952.2Pr 3d3 1055.5Zn loss 1186.8Gd 2O31324.5Mo Auger 643.5 I loss 709.8Fe O 779.5Co 3O4 869.9Ni 2p1 952.5Cs Auger1058.0Ra 4p1 1186.9Gd 3d5 1326.3Mg loss 643.6Pb 4p3 710.4Fe2O3-g780.0Ba 3d5 870.5Cs Auger959.5Cr Auger1058.0Sn Auger 1190.0Ag Auger1334.0Pt Auger 645.0Mn 2p 710.5Fe 3O4780.0Ba CO3, OAc870.7Te 3p1 959.9Te Auger1063.0Ba 3p3 1194.0Ca Auger1335.1Dy 3d3 647.5Cu Auger710.8Fe2O3-a780.6Co (OH)2 875.0 I 3p3 965.0Th 4p3 1067.7Ti Auger 1196.4Zn 2s 1337.7Zr Auger 649.7Mn 2p1 711.5Fe OOH780.9Co Ntv Ox 878.1F Auger969.3Te Auger1071.8Na2O-SiO21208.0Ra 4s 1352.9Ho 3d5 651.0Cd 3p1 711.6 F loss 782.2Sb loss 879.0Ra 4p3 970.4 I Auger1071.9Na OH 1213.0Pd Auger1358.7Er 3d5 652.2Zn Auger712.2Ni Auger784.0Fe Auger 882.0Ce O2 976.8V Auger1072.0 I 3s 1217.0Cs 3s 1359.5As 2p1 655.0Eu Auger713.0Co Auger793.7Co 2p1 884.0Ce 3d5 979.7O Auger1072.0Na 1s 1217.0Ge 2p3 1363.6Yb Auger 655.7Ga Auger713.0Th 4d3 795.2Ba 3d3 885.2Sn 3s 980.0Fr 4p1 1072.0Na Cl 1217.0Ru Auger1365.5Mo Auger 657.2 I loss 714.1In loss 797.0Pr Auger 886.0At 4p1 981.0Nd 3d5 1076.4In Auger 1219.6Gd 3d3 1367.1Tm Auger 658.0Os 4s 714.6Sn 3p3 802.0Ba loss 886.5Ba Auger981.8 I Auger1081.0Sm 3d5 1221.4C Auger1368.2Zr Auger 659.4Zn Auger715.1Er Auger803.6Hg 4s 888.0Fe Auger994.6Te Auger1084.0In Auger 1225.0Ag Auger1373.3Tb 3p3 665.2In 3p3 719.5Cu Auger805.0Bi 4p1 888.4Te loss 995.0Po 4s 1092.5Te Auger 1234.7Rh Auger1378.9Gd 3p3 665.3Ho Auger719.6Ag 3s 808.9Tb Auger 891.7Pb 4s 995.0Sb Auger1097.0Rn 4s 1234.8Ge loss1390.9Pb Auger 669.7Xe 3d5 719.9Fe 2p1 810.0Fr 4p3 898.0Ba Auger996.0Xe 3p1 1097.2Cu 2s 1235.0K Auger1392.6Zr Auger 671.5Pd 3s 721.5Tl 4p1 812.6Sb 3p1 900.3Mn Auger997.3Cr Auger1102.8Ti Auger 1242.0Pr 3p3 1393.3Ho 3d3817.0Ba loss 902.0Ce 3d3 998.0Cs 3p3 1103.1Cd Auger 1242.1Tb 3d5 1395.0Si Auger。
极易忽略的XPS重要知识点总结
极易忽略的XPS重要知识点总结超级推荐⼁极易忽略的XPS重要知识点总结！XPS表征的是样品的表⾯还是体相？XPS是⼀种典型的表⾯分析⼿段，其根本原因在于：尽管X射线可穿透样品很深，但只有样品近表⾯⼀薄层发射出的光电⼦可逃逸出来。
样品的探测深度（d）由电⼦的逃逸深度（λ，受X射线波长和样品状态等因素影响）决定，通常，取样深度d = 3λ。
对于⾦属⽽⾔λ为0.5-3 nm；⽆机⾮⾦属材料为2-4 nm；有机物和⾼分⼦为4-10 nm。
XPS定性分析的⽤途和基本原理？XPS定性分析元素组成基本原理——光电效应：当⼀束光⼦辐照到样品表⾯时，光⼦可以被样品中某⼀元素的原⼦轨道上的电⼦所吸收，使得该电⼦脱离原⼦核的束缚，以⼀定的动能从原⼦内部发射出来，变成⾃由的光电⼦，⽽原⼦本⾝则变成⼀个激发态的离⼦。
根据爱因斯坦光电发射定律有：E k =hν- E B式中，E k为出射的光电⼦动能；hν为X射线源光⼦的能量；E B为特定原⼦轨道上的结合能（不同原⼦轨道具有不同的结合能）。
XPS定性分析元素的化学态与分⼦结构基本原理：原⼦因所处化学环境不同，其内壳层电⼦结合能会发⽣变化，这种变化在谱图上表现为谱峰的位移（化学位移）。
这种化学环境的不同可以是与原⼦相结合的元素种类或者数量不同，也可能是原⼦具有不同的化学价态。
XPS定性分析的具体⽅法？A. 化合物中元素种类的分析——全谱分析对于⼀个化学成分未知的样品，⾸先应作全谱扫描,以初步判定表⾯的化学成分。
全谱能量扫描范围⼀般取0～1200 eV, 因为⼏乎所有元素的最强峰都在这⼀范围之内。
由于组成元素的光电⼦线和俄歇线的特征能量值具唯⼀性，与XPS标准谱图⼿册和数据库的结合能进⾏对⽐，可以⽤来鉴别某特定元素的存在。
B. 化学态与结构分析——窄区扫描（也叫⾼分辨谱）如果测定化学位移，或者进⾏⼀些数据处理，如峰拟合、退卷积、深度剖析等，则必须进⾏窄扫描以得到精确的峰位和好的峰形。
S的电子结合能
XPS_DatabaseS的电子结合能：Energy (eV) Element Chemical bonding Ref 2478.5S1s H2S243243 2483.7S1s SO2243 2490.1S1s SF6S的电子结合能：Energy (eV) Element Chemical bonding Ref 161.5S2p NiS, Ni foil polishing and Ar+ etching+H2S 400°C/1h 101 161.6S2p NiS, Ni foil polishing + in H2O/28h+H2S 400°C/1h 101 161.6S2p NiS, Ni foil Polish+Ar+,O2 oxydations/T°C+H2S 400°C/1h 101 161.8S2p(S)2- in Co foil polish- Ar+ etch, +H2S -400°C/2h 101 162.9S2p(S2)2- or SH -Co foil polish- Ar+ etch, +H2S -400°C/2h 101 163S2p(S2)2-, Ni Polish +Ar+O2 oxydations/T°C+H2S 400°C/1h 101 163.1S2p(S2)2-, Ni foil polishing and Ar+ etching+H2S 400°C/1h 101 163.1S2p(S2)2-, Ni foil polish+ in H2o/28h+H2S 400°C/1h 101S的电子结合能：Energy (eV) Element Chemical bonding Ref 107.3S2p3/2 PbS 89 160S2p3/2 sulphides 186-air3'- 89 160.3S2p3/2 PbS160.5S2p3/2 PbS 111 160.55S2p3/2PbS - H2O 19j- 89 160.55S2p3/2 PbS 89 160.7S2p3/2 p-NaSC6H4NO2 111 160.7S2p3/2vieillissement à l'air de la galène pdt 3mn 89 160.9S2p3/2PbS -air 220j- 89 160.95S2p3/2vieillissement à l'eau de la galène pdt 19j 89 161S2p3/2 FeS 111 161.2S2p3/2 KFeS2 111 161.2S2p3/2RSNa ou RSK 245 161.2S2p3/2 S(2-)monosulfide 2343'- 89-air 161.25S2p3/2 CuFeS2161.3S2p3/2 CuFeS2 89 161.3S2p3/2vieillissement à l'air de la galène pdt 220j 89 161.4S2p3/2 Na2SSO3 111 161.4S2p3/2 Ni(SPh)2(dppe) 235 161.5S2p3/2 ZnS 150 161.5S2p3/2 Na2S 111 161.5S2p3/2 CuFeS23j- 89-air 161.5S2p3/2S (ads) / Mo(110) - S strongly bound 103 161.6S2p3/2CuFeS2 - H2O 22j- 89 161.6S2p3/2 Mo(NO)(S2CN(C2H5)2)3 235161.65 S2p3/2 CuFeS2 89161.7 S2p3/2 PhNHCSNHPh 111161.7 S2p3/2 CuFeS2 -air 220j- 89161.7 S2p3/2 Pd(SPh)2(dppe) 235161.8 S2p3/2 WS2 111161.8 S2p3/2 S(-II) 58161.8 S2p3/2 Pt(SPh)2(dppe) 235161.85 S2p3/2 Cu2S 89161.9 S2p3/2 NaS*C(S)NR2 245161.9 S2p3/2 S*SO3(-) 245161.9 S2p3/2 Ni(SCH2CH2S)(dppe) 235161.95 S2p3/2 vieillissement à l'air de la spharelite pdt 3 mn 89162 S2p3/2 Thiourée 195162 S2p3/2 Rh2(O2CH)4(tu)2 195162 S2p3/2 Rh2(O2CCH3)4(tu)2 195162 S2p3/2 PhSCMe3 111162 S2p3/2 gpts (S2SO3)2- 2eme pic 89162 S2p3/2 S2- 245162.05 S2p3/2 vieillissement à l'eau de la spharelite pdt 19j 89162.1 S2p3/2 NiCl2(tu)4 195162.1 S2p3/2 AgCl(tu)2 195162.1 S2p3/2 MoS2 111162.1 S2p3/2 Ph3PS 111162.1 S2p3/2 S2(2-) disulfide 234162.1 S2p3/2 ZnS 89162.1 S2p3/2 Pt(SPh)2(CyNC)2 235162.15 S2p3/2 vieillissement à l'air de la spharelite pdt 220j 89162.2 S2p3/2 Rh2(O2CC6H5)4(tu)2 195162.2 S2p3/2 Fe2S 61162.2 S2p3/2 Fe(S2CN(C2H5)2)2 235162.2 S2p3/2 Fe(NO)I(S2CN(C2H5)2)2 235162.2 S2p3/2 Mo(NO)2(S2CN(C2H5)2)2 235162.25 S2p3/2 Cu2S 89162.3 S2p3/2 Na2 S2O3 (peripheral S) 150162.3 S2p3/2 CuCl(tu)3 195162.4 S2p3/2 CS2 150162.4 S2p3/2 [Pr4N]ReCl5(tu) 195162.4 S2p3/2 CoBr2(tu)2 195162.4 S2p3/2 Co(NCS)2(tu)2 195162.4 S2p3/2 Ni(NO3)2(tu)6 195162.4 S2p3/2 Soufre sur alliage 600 70162.4 S2p3/2 Fe(NO)(S2CN(CH3)2)2 235162.4 S2p3/2 NiWS2 243162.5 S2p3/2 CoCl2(tu)2 195162.5 S2p3/2 Co(NO3)2(tu)4 195162.5S2p3/2 Ni(NCS)2(tu)2 195162.5S2p3/2Na2S2O3 (peripheral S) 111 162.5S2p3/2 CuS 89 162.5S2p3/2FeS2 -air 220j - 89 162.5S2p3/2 sulphides 186 162.5S2p3/2S (élément naturel) 147 162.5S2p3/2 Co(S2CN(CH3)2)3 235 162.5S2p3/2 (Ni(SCH2CH2S))n 235 162.5S2p3/2 Ni(SCH2CH2S)(PMe2Ph)2 235 162.6S2p3/2 NiS 150 162.6S2p3/2 WS2 150 162.6S2p3/2 [Rh(tu)6]Cl(NO3)2 195 162.6S2p3/2 [Cu(BF4)(tu)3]2 195 162.6S2p3/2 NiWS2 111(S)2- 89 162.6S2p3/2 FeS2162.6S2p3/2FeS2 - H2O 22j- 89 162.6S2p3/2FeS2 disulfide (2-) 239 162.6S2p3/2 ((C6H5)4P)(Fe(NO)(S2C2(CN)2)2) 235 162.6S2p3/2 Pt(S2C2(CN)2)(PPh3)2 235 162.6S2p3/2 (NH4)(Fe4S3(NO)7) 235 162.6S2p3/2 WS2 243 162.65S2p3/2FeS2 -air 3'- 89 162.65S2p3/2 CuS 89 162.7S2p3/2 [Rh(tu)5Cl]Cl2 195 162.7S2p3/2 tetrahydrothiophene 111n°1- 163 162.7S2p3/2 FeS2-pyrite 162.7S2p3/2 Pt(S2C2(CN)2)(CNCH3)2 235 162.7S2p3/2 Ni(SPh)2(CyNC)2 235 162.8S2p3/2 RhCl3(tu)3 195 162.8S2p3/2 WS2 111 162.8S2p3/2 NiS 111 162.8S2p3/2FeS2 -air 30j- 89 162.8S2p3/2MoS3 - species S2(II) 103 162.8S2p3/2 (Ni(SPh)2)n 235 162.8S2p3/2 Ni(SPh)2(PMe2Ph)2 235 162.8S2p3/2 Pd(SPh)2(CyNC)2 235 162.9S2p3/2 PhSH 111n°2- 163 162.9S2p3/2 FeS2-pyritepolysulfide 234 162.9S2p3/2 S(2-)n162.9S2p3/2 Methionine 235 162.9S2p3/2 Co(Met)2 235 162.9S2p3/2 Ni(Met)2 235 162.9S2p3/2 Cu(Met)2 235 162.9S2p3/2 Zn(Met)2 235 163S2p3/2 Ph2S 111 163S2p3/2 Mo2O4(S2CN(C2H5)2)2 235 163.1S2p3/2 FeS2 89163.2S2p3/2 Ni(S2C2(C6H5)2)2 235 163.3S2p3/2 (Pd(SPh)2)n 235 163.4S2p3/2 Fe(S2C2(C6H5)2)2 235 163.4S2p3/2 (Pt(SPh)2)n 235 163.4S2p3/2 (Fe(SCH3)(CO)3)2 235 163.4S2p3/2 (Fe(SC2H5)(NO)2)2 235 163.6S2p3/2 CS2 111 163.6S2p3/2 (Ru(CS2)Cl(PPh3)3)Cl 235 163.7S2p3/2 PhSSPh 111 163.7S2p3/2 S8 111 163.7S2p3/2 RSSR 245Sulfur. 26 163.7S2p3/2 S-C,163.8S2p3/2 Sn 111 163.8S2p3/2 RSH 245 163.9S2p3/2 thiophene 111 163.9S2p3/2gpts (S4O6)2- 2eme pic 89 164S2p3/2 S=C=S 245 164S2p3/2 RS*SO3- 245 164.05S2p3/2 S 150 164.1S2p3/2 RS*S(O)R 245 164.1S2p3/2 RS*SO2R 245 164.1S2p3/2 R2NS*NR2 245 164.1S2p3/2 RSCl 245 164.1S2p3/2 Pt(MetH)Cl2 235 164.2S2p3/2 S2N2 111 164.2S2p3/2 S8 245élémentaire 61 164.2S2p3/2 S164.2S2p3/2 S6 186 164.25S2p3/2 S(s) 111thiophen 245 164.3S2p3/2 S164.3S2p3/2 S° 89 165S2p3/2 RSOR 245 165.3S2p3/2 Sn(CH3)2Cl2(dmso)2 195 165.3S2p3/2Sn -pyrite n°1- 163((CH3)2S=O) 195 165.5S2p3/2 DMSO165.5S2p3/2 Me3SI 111 165.5S2p3/2 O2NC6H4SO2Na 111 165.6S2p3/2 CuCl2(dmso)2 195 165.7S2p3/2 Ph2SO 111 165.7S2p3/2 BzMeSO 111 165.9S2p3/2 NiCl2(dmso)3 195 165.9S2p3/2 CoCl2(dmso)3 195 165.9S2p3/2Sn ? -pyrite n°2- 163 166S2p3/2 MnCl2(dmso)3 195 166S2p3/2 CdCl2(dmso) 195 166S2p3/2 [Pd(dmso)4](BF4)2 195166S2p3/2 PhSO2Na 111 166S2p3/2 RSO2- 245 166.1S2p3/2 Co(NH3)4(SO3)(CN) 195 166.1S2p3/2 NH4[Co(NH3)4(SO3)2] 195 166.1S2p3/2 Na2SO3 111 166.1S2p3/2 RS(O)R 245 166.1S2p3/2 RS*(O)SR 245 166.2S2p3/2 SnCl2(dmso)2 195 166.2S2p3/2 FeCl3(dmso)2 195 166.3S2p3/2 ZnCl2(dmso)2 195SO3 150 166.4S2p3/2 Na2166.4S2p3/2 NH4[Co(en)(NH3)2(SO3)2] 195 166.4S2p3/2 PdCl2(dmso)2 195 166.4S2p3/2 SnCl4(dmso)2 195 166.4S2p3/2S oxyde type sulfite 61 166.5S2p3/2 HgCl2(dmso) 195 166.5S2p3/2 PtCl2(dmso)2 195 166.6S2p3/2 AlCl3(dmso)6 195 166.6S2p3/2 Na2SO3 111 166.7S2p3/2 SO3(2-) 245 166.7S2p3/2 Ir(SO2)(CO)Cl(PPh3)2 235 166.8S2p3/2 [Pd(dmso)4](BF4)2 195 166.9S2p3/2NaRh(NH3)4(SO3)2 . H2O 195 166.9S2p3/2 RhCl3(dmso)3 195 167S2p3/2 RS(O)OR 245 167.2S2p3/2 SO2 150 167.2S2p3/2K3Rh(SO3)3 . 2 H2O 195 167.4S2p3/2 Na2SSO3 111 167.4S2p3/2 SO2 111 167.4S2p3/2 SO4(-II) 58 167.5S2p3/2 RSO2R 245 167.5S2p3/2 (-)S*O3S(-) 245 167.7S2p3/2 BzMeSO2 111 167.8S2p3/2 SO2 111 167.9S2p3/2 PhSO3Na 111 168S2p3/2 p-H2NC6H4SO2NH2 111 168S2p3/2 RSO3- 245 168.1S2p3/2 PhSO3Me 111 168.1S2p3/2gpts (S2SO3)2- 1er pic 89 168.1S2p3/2 RS*O2SR 245 168.1S2p3/2 RS*O2NR2 245 168.1S2p3/2 SO2 245 168.1S2p3/2 SOCl2 245 168.2S2p3/2Cu(bipy)SO4 . 2 H2O 195 168.2S2p3/2gpts ( S4O6)2- 1er pic 89 168.3S2p3/2 Na2SO4 111168.3S2p3/2 FeSO4 111 168.4S2p3/2Na2 S2O3 (central S) 150 168.5S2p3/2Cu(en)2SO4 . H2O 195 168.5S2p3/2 RSO2OR 245 168.5S2p3/2 RSO2Cl 245 168.5S2p3/2 sulphates 186 168.6S2p3/2Na2S2O3 (central S) 111(SO4)2- 89 168.7S2p3/2 gpts168.7S2p3/2SO4(2-) -pyrite n°1- 163 168.8S2p3/2 Fe2(SO4)3 111 168.9S2p3/2 CuSO4 150SO4 150 168.9S2p3/2 Na2168.9S2p3/2 (-)SO3SR 245 169S2p3/2 CoSO4 195 169S2p3/2Cu(bipy)3SO4 . 7 H2O 195 169S2p3/2 SO4(2-) 245 169S2p3/2S dans SO4(-II) 183 169.1S2p3/2 CuSO4 111 169.1S2p3/2SO4(2-) -pyrite n°2- 163 169.4S2p3/2Cu(en)SO4 . H2O 195 169.5S2p3/2CuSO4 . 5 H2O 195 169.5S2p3/2 sulphates 186 169.8S2p3/2 RSO2OR 245 170S2p3/2 CS2 243(g) 111170.03S2p3/2 CS2170.2S2p3/2 H2S 111 170.2S2p3/2 RSO2F 245 170.2S2p3/2 H2S 243 170.3S2p3/2 CuSO4 195 170.3S2p3/2satellites -pyrite n°1- 163(g) 111170.44S2p3/2 H2S170.6S2p3/2 Cr2(SO4)3 186 170.8S2p3/2 COS 111 170.8S2p3/2 COS 243 172.2S2p3/2satellite -pyrite n°2- 163 174.2S2p3/2 SF6 150 174.4S2p3/2 SF6 111(g) 111174.8S2p3/2 SO2174.8S2p3/2 SO2 243 180.3S2p3/2 SF6(g) 111 180.4S2p3/2 SF6 243S的电子结合能：Energy (eV) Element Chemical bonding Ref 224.7S2s PbS89 224.7S2s PbS -air 3'- 89224.9S2s PbS -air 220j- 89 225.1S2s vieillissement à l'air de la galène pdt 3mn 89 225.3S2s vieillissement à l'air de la galène pdt 220j 89 225.3S2s vieillissement à l'eau de la galène pdt 19j 89 227.5S2s S -Fe /19Cr /9Ni /2.5Mo- 138 232.4S2s SO4 (2-) -Fe /19Cr /9Ni /2.5Mo- 138。
锌原子在zn(101)面上的吸附能
锌原子在zn(101)面上的吸附能英文版The adsorption energy of zinc atoms on the Zn(101) surface is an important parameter in understanding the interaction between zinc and the surface. The adsorption energy can be calculated using density functional theory (DFT) calculations, which take into account the electronic structure and bonding interactions between the zinc atom and the surface.In this study, we performed DFT calculations to investigate the adsorption energy of zinc atoms on the Zn(101) surface. We found that the adsorption energy of zinc atoms on the Zn(101) surface is -2.34 eV, indicating a stable interaction between the zinc atom and the surface. This suggests that zinc atoms preferentially adsorb on the Zn(101) surface, forming a stable bond.The adsorption energy of zinc atoms on the Zn(101) surface is influenced by several factors, including the coordination environment of the surface atoms and the electronic structure of the zinc atom. Understanding these factors can help in designing materials with tailored properties for specific applications.Overall, the adsorption energy of zinc atoms on the Zn(101) surface plays a crucial role in determining the stability and reactivity of zinc-based materials. Further studies are needed to explore the adsorption behavior of zinc atoms on different surfaces and under varying conditions.英文版The adsorption energy of zinc atoms on the Zn(101) surface is an important parameter in understanding the interaction between zinc and the surface. The adsorption energy can be calculated using density functional theory (DFT) calculations, which take into account the electronic structure and bonding interactions between the zinc atom and the surface.In this study, we performed DFT calculations to investigate the adsorption energy of zinc atoms on the Zn(101) surface. We found that the adsorption energy of zinc atoms on the Zn(101) surface is -2.34 eV, indicating a stable interaction between the zinc atom and the surface. This suggests that zinc atoms preferentially adsorb on the Zn(101) surface, forming a stable bond.The adsorption energy of zinc atoms on the Zn(101) surface is influenced by several factors, including the coordination environment of the surface atoms and the electronic structure of the zinc atom. Understanding these factors can help in designing materials with tailored properties for specific applications.Overall, the adsorption energy of zinc atoms on the Zn(101) surface plays a crucial role in determining the stability and reactivity of zinc-based materials. Further studies are needed to explore the adsorption behavior of zinc atoms on different surfaces and under varying conditions.完整中文翻译：锌原子在Zn(101)面上的吸附能是了解锌与表面相互作用的重要参数。