二乙烯三胺MSDS
二乙烯三胺MSDS
1.物质的理化常数国标编号————CAS号111-40-0中文名称二亚乙基三胺英文名称Diethylenetriamine别名二乙撑三胺；二乙烯三胺分子式C4H13N3；H2NCH2CH2NH2CH2CH2NH2外观与性状无色或黄色透明液体，略有氨的气味分子量103.17蒸汽压0.03kPa/20℃闪点：94℃熔点-39℃沸点：207℃溶解性溶于水、乙醇，不溶于乙醚密度相对密度(水=1)0.96；相对密度(空气=1)3.48稳定性稳定危险标记主要用途用凭据这羧络合指示剂、气体净化剂、环氧树脂固化剂，也用于合成橡胶2.对环境的影响一、健康危害侵入途径：吸入、食入、经皮吸收。
健康危害：蒸气或雾对鼻、喉和粘膜有腐蚀性，可引起支气管炎、化学性肺炎或肺水肿。
蒸气、雾或液体对眼有强烈腐蚀性，重者可导致失明。
皮肤接触可造成灼伤；对皮肤有致敏性。
口服灼伤口腔和消化道，出现剧烈腹痛、恶心、呕吐和虚脱。
慢性影响：本品有明显的致敏作用。
二、毒理学资料及环境行为毒性：属低毒类。
急性毒性：LD501080mg/kg (大鼠经口)；1090mg/kg(兔经皮)危险特性：遇明火、高热可燃。
与氧化剂能发生强烈反应。
若遇高热，容器内压增大，有开裂和爆炸的危险。
燃烧(分解)产物：氧化氮、一氧化碳、二氧化碳。
3.现场应急监测方法4.实验室监测方法水杨酸分光光度法(GB/T14378-93，水质)纳氏试剂比色法《化工企业空气中有害物质测定方法》，化学工业出版社5.环境标准美国(1982)车间卫生标准 4mg/m3(皮)前苏联地面水中最高容许浓度 0.2mg/L6.应急处理处置方法一、泄漏应急处理疏散泄漏污染区人员至安全区，禁止无关人员进入污染区，切断火源。
应急处理人员戴自给式呼吸器，穿化学防护服。
不要直接接触泄漏物，在确保安全情况下堵漏。
喷水雾可减少蒸发但不要使水进入储存容器内。
用砂土、蛭石或其它惰性材料吸收，然后收集运至废物处理场所。
二乙烯三胺标准物质
二乙烯三胺标准物质
二乙烯三胺（CAS号：111-40-0）是一种有机化合物，化学式为C4H13N3，分子量为115.17。
它是无色液体，具有强碱性。
二乙烯三胺主要用作金属离子的螯合剂和氧化还原过程中电子传递的中间体。
此外，它还广泛应用于催化剂、阻燃剂、表面活性剂等领域。
二乙烯三胺的生产工艺较为复杂，一般采用化工合成的方法如烟碱催化还原法或溶剂萃取法。
在实验室中，二乙烯三胺可作为标准物质用于定量分析与质谱分析等研究中。
使用时需注意其强碱性和毒性，遵守相关安全操作规程。
三乙烯二胺MSDS
10.6 危险的分解产物 其它分解产物 - 无数据资料
11. 毒理学资料
11.1 毒理学影响的信息
急性毒性 半数致死剂量 (LD50) 经口 - 大鼠 - 1,700 mg/kg
皮肤刺激或腐蚀 眼睛刺激或腐蚀 眼睛 - 兔子 - 眼睛刺激
呼吸道或皮肤过敏 无数据资料
生殖细胞突变性 无数据资料
致癌性 IARC:
国际海运危规: 4.1
国际空运危规: 4.1
14.4 包裹组 欧洲陆运危规: II
国际海运危规: II
国际空运危规: II
14.5 环境危险 欧洲陆运危规: 否
国际海运危规 海运污染物: 否
国际空运危规: 否
14.6 对使用者的特别提醒 无数据资料
15. 法规信息
15.1 专门对此物质或混合物的安全，健康和环境的规章 / 法规
漱口。 如发生皮肤刺激：求医/ 就诊。 如仍觉眼睛刺激：求医/就诊。 如仍觉眼睛刺激：求医/就诊. 脱掉沾染的衣服，清洗后方可重新使用。 火灾时： 用干的砂子，干的化学品或耐醇性的泡沫来灭火。
存放于通风良的地方。 保持容器密闭。 存放处须加锁。
将内容物/ 容器处理到得到批准的废物处理厂。
: TED Triethylenediamine
14. 运输信息
14.1 联合国危险货物编号 欧洲陆运危规: 1325
二乙烯三胺(DETA)物性安全数据表
DIETHYLENETRIAMINE (DETA)2/5/2008.Material Safety Data SheetValidation date ::Product name MSDS #00010093Product UseIntermediate.Huntsman Petrochemical CorporationP.O.Box 4980The Woodlands,TX 77387-4980TELEPHONE NUMBERS Transportation Emergency Company:(800)328-8501CHEMTREC:(800)424-9300Medical Emergency:(409)722-9673(24Hour)General MSDS Assistance:(281)719-6000Technical Information:(281)719-7780E-MAIL:MSDS@:Physical state Liquid.[Liquid.]:Odor:Amine-like.OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29CFR 1910.1200).GENERAL INFORMATION Read the entire MSDS for a more thorough evaluation of the hazards.:Emergency overviewWARNING !CAUSES EYE AND SKIN BURNS.CAUSES RESPIRATORY TRACT IRRITATION.MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED.ASPIRATION HAZARD IF SWALLOWED -CAN ENTER LUNGS AND CAUSE DAMAGE DO NOT ADD NITRITES -MAY FORM SUSPECTED CANCER CAUSING NITROSAMINES Corrosive to eyes and skin.Causes burns.Harmful in contact with skin and if swallowed.Irritating to respiratory system.May cause sensitization by inhalation and skin contact.Do not breathe vapor or mist.Do not ingest.Do not get in eyes or on skin or e only with adequate ventilation.Keep container tightly closed and sealed until ready for use.Wash thoroughly after handling.:Diethylenetriamine111-40-060-100NameCAS number %Get medical attention immediately.Wash out mouth with water.Move exposed person to fresh air.Do not induce vomiting unless directed to do so by medical personnel.Chemical burns must be treated promptly by a physician.Never give anything by mouth to an unconscious person.Get medical attention immediately.Immediately flush eyes with plenty of water,occasionally lifting the upper and lower eyelids.Check for and remove any contact lenses.Continue to rinse for at least 10minutes.Chemical burns must be treated promptly by a physician.Get medical attention immediately.Flush contaminated skin with plenty of water.Remove contaminated clothing and shoes.Wash contaminated clothing thoroughly with water before removing or wear gloves.Continue to rinse for at least 10minutes.Chemical burns must be treated promptly by a physician.In the event of any complaints or symptoms,avoid further exposure.Wash clothing before reuse.Clean shoes thoroughly before reuse.Get medical attention immediately.Move exposed person to fresh air.If it is suspected that fumes are still present,the rescuer should wear an appropriate mask or self-contained breathing apparatus.Keep person warm and at rest.If not breathing,ifbreathing is irregular or if respiratory arrest occurs,provide artificial respiration or oxygen by trained personnel.It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation.If unconscious,place in recovery position and get medical attention immediately.Maintain an open airway.Loosen tight clothing such as a collar,tie,belt or waistband.In case of inhalation of decomposition products in a fire,symptoms may be delayed.The exposed person may need to be kept under medical surveillance for 48hours.Eye contactSkin contactInhalationIngestionNotes to physician:Symptomatic and supportive therapy as needed.Following severe exposure medical follow-up should be monitored for atleast 48hours.Decomposition products may include the following materials:carbon oxides nitrogen oxidesUse an extinguishing agent suitable for the surrounding fire.Products of combustionExtinguishing media Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire.No action shall be taken involving any personal risk or without suitable training.In a fire or if heated,a pressure increase will occur and the container may burst.Special protectiveequipment for fire-fightersFire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA)with a full face-piece operated in positive pressure mode.::Special exposure hazards:None known.Suitable :Not suitable:Flash point:Closed cup:98°C (208.4°F)No action shall be taken involving any personal risk or without suitable training.Evacuate surrounding areas.Keep unnecessary and unprotected personnel from entering.Do not touch or walk through spilled material.Avoid breathing vapor or mist.Provide adequate ventilation.Wear appropriate respirator when ventilation is inadequate.Put on appropriate personal protective equipment (see section 8).Stop leak if without risk.Move containers from spill area.Approach release from upwind.Prevent entry into sewers,water courses,basements or confined areas.Wash spillages into an effluent treatment plant or proceed as follows.Contain and collect spillage with non-combustible,absorbent material e.g.sand,earth,vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see section 13).Dispose of via a licensed waste disposal contractor.Contaminated absorbent material may pose the same hazard as the spilled product.Note:see section 1for emergency contact information and section 13for waste disposal.Environmental precautions:Avoid dispersal of spilled material and runoff and contact with soil,waterways,drains and rm the relevant authorities if the product has caused environmental pollution (sewers,waterways,soil or air).Personal precautions:Methods for cleaning up:Store in accordance with local regulations.Store in original container protected from direct sunlight in a dry,cool and well-ventilated area,away from incompatible materials (see section 10)and food and drink.Separate from acids.Keep container tightly closed and sealed until ready for use.Containers that have been opened must be carefullyresealed and kept upright to prevent leakage.Do not store in unlabeled e appropriate containment to avoid environmental contamination.Put on appropriate personal protective equipment (see section 8).Eating,drinking and smoking should be prohibited in areas where this material is handled,stored andprocessed.Workers should wash hands and face before eating,drinking and smoking.Persons with a history of skin sensitization problems or asthma,allergies or chronic or recurrent respiratory disease should not be employed in any process in which this product is used.Do not get in eyes or on skin or clothing.Do not breathe vapor or mist.Do not e only with adequate ventilation.Wear appropriate respirator when ventilation is inadequate.Keep in the original container or an approved alternative made from a compatible material,kept tightly closed when not in use.Keep away from acids.Empty containers retain product residue and can be hazardous.Do not reuse container.HandlingStorage::DiethylenetriamineACGIH TLV (United States,1/2006).Skin TWA:4.2mg/m³8hour(s).TWA:1ppm 8hour(s).NIOSH REL (United States,12/2001).Skin TWA:4mg/m³10hour(s).TWA:1ppm 10hour(s).OSHA PEL 1989(United States,3/1989).TWA:4mg/m³8hour(s).TWA:1ppm 8hour(s).Product name Exposure limitsConsult local authorities for acceptable exposure limits.Preventive MeasuresConditions of use,adequacy of engineering or other control measures,and actual exposures will dictate the need for specific protective devices at your workplace.:Use a properly fitted,air-purifying or air-fed respirator complying with an approvedstandard if a risk assessment indicates this is necessary.Respirator selection must be based on known or anticipated exposure levels,the hazards of the product and the safe working limits of the selected respirator.Safety eyewear complying with an approved standard should be used when a riskassessment indicates this is necessary to avoid exposure to liquid splashes,mists,gases or dusts.Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product.Personal protection EyesSkinRespiratory:::Chemical-resistant,impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary.Hands:respiratory equipment should be used in cases of insufficient ventilation or whereoperational procedures demand it.For guidance on engineering control measures refer to publications such as the ACGIH current edition of 'Industrial Ventilation,a manual of RecommendedPractice.'General information Appearance Physical state Color Odor Odor threshold ::::Liquid.[Liquid.]Colorless to light yellow.Amine-like.Not available.Important health,safety and environmental information pH Boiling point Melting point Flash pointOxidizing properties Vapor pressure Relative densityOctanol/water partition coefficient ViscosityVapor densityAuto-ignition temperature :395°C (743°F): 3.48[Air =1]:4cSt at 25°C -1.30.95<0.013kPa (<0.1mm Hg)Not available.Closed cup:98°C (208.4°F)<-20°C (<-4°F)199°C (390.2°F)12::::::::VOC content:Not available.The product is stable.Reactive or incompatible with the following materials:oxidizing materials,organic materials and metals.Not available.Stability and reactivityIncompatibility with various substancesHazardous polymerization ::Decomposition products may include the following materials:carbon oxides nitrogen oxidesHazardousdecomposition products:Toxicity dataAcute toxicityProduct/ingredient name Test Species Result Exposure Diethylenetriamine LD50Dermal Rabbit >1000mg/kg -LD50Oral Rat >1080mg/kg-Conclusion/Summary :Long term toxicity tests show no oncogenic potential.Ingestion :Harmful if swallowed.May cause burns to mouth,throat and stomach.Inhalation :Irritating to respiratory system.May cause sensitization by inhalation.Eyes :Corrosive to eyes.Causes burns.Skin:Corrosive to the skin.Causes burns.Harmful in contact with skin.May cause sensitization by skin contact.Potential acute health effects Potential chronic health effects Target organs :Carcinogenicity Mutagenicity TeratogenicityDevelopmental effects Fertility effects:::::No known significant effects or critical hazards.No known significant effects or critical hazards.No known significant effects or critical hazards.No known significant effects or critical hazards.No known significant effects or criticalhazards.None known.Environmental effects:Not readily biodegradable.This product shows a low bioaccumulation potential.Aquatic ecotoxicityProduct/ingredient name Test Diethylenetriamine-Acute EC5017mg/LDaphnia 48hours -Acute LC50332mg/LFish 96hours Result Species Exposure Product/ingredient name Aquatic half-life Photolysis Biodegradability Diethylenetriamine--Not readily Bioaccumulative potential Product/ingredient name LogP ow BCF Potential Diethylenetriamine -1.3-lowThe generation of waste should be avoided or minimized wherever possible.Dispose of surplus and non-recyclable products via a licensed waste disposal contractor.Disposal of this product,solutions and any by-products should at all times comply with therequirements of environmental protection and waste disposal legislation and any regional local authority requirements.Avoid dispersal of spilled material and runoff and contact with soil,waterways,drains and sewers.Waste disposal:Transportation Emergency Number 1-800-424-9300(CHEMTREC).PG*:Packing groupCorrosive material Sensitizing materialU.S.Federal regulationsWHMIS (Canada)Class D-2A:Material causing other toxic effects (Very toxic).Class D-2B:Material causing other toxic effects (Toxic).Class E:Corrosive material ::::CanadaUnited StatesSARA 313United States inventory (TSCA 8b):All components are listed or exempted.This product does not contain nor is it manufactured with ozone depleting substances.CEPA (DSL):Canada inventory:All components are listed or exempted.California Prop 65:No ingredients listed.HCS Classification No ingredients listed.CERCLA:Hazardous substances.:No ingredients listed.information requiredby the CPR.Hazardous MaterialInformation System (U.S.A.)National Fire Protection Association (U.S.A.)CAUSES EYE AND SKIN BURNS.CAUSES RESPIRATORY TRACT IRRITATION.MAY CAUSE ALLERGIC RESPIRATORY AND SKIN REACTION.MAY BE HARMFUL IF ABSORBED THROUGH SKIN OR IF SWALLOWED.ASPIRATION HAZARD IF SWALLOWED -CAN ENTER LUNGS AND CAUSE DAMAGE DO NOT ADD NITRITES -MAY FORM SUSPECTED CANCER CAUSING NITROSAMINES Label requirements:Notice to readerDate of printingDate of issueDate of previous issue 2/5/2008.2/5/2008.No previous validation.:::::While the information and recommendations in this publication are to the best of our knowledge,information and belief accurate at the date of publication,NOTHING HEREIN IS TO BE CONSTRUED AS A WARRANTY,EXPRESS OR OTHERWISE.IN ALL CASES,IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE APPLICABILITY OF SUCH INFORMATION AND RECOMMENDATIONS AND THE SUITABILITY OF ANY PRODUCT FOR ITS OWN PARTICULAR PURPOSE.THE PRODUCT MAY PRESENT HAZARDS AND SHOULD BE USED WITH CAUTION.WHILE CERTAIN HAZARDS ARE DESCRIBED IN THIS PUBLICATION,NO GUARANTEE IS MADE THAT THESE ARE THE ONLY HAZARDS THAT EXIST.Hazards,toxicity,and behavior of the products may differ when used with other materials and are dependent upon the manufacturing circumstances or other processes.Such hazards,toxicity and behavior should be determined by the user and made known to handlers,processors and end users.NO PERSON OR ORGANIZATION EXCEPT A DULY AUTHORIZED HUNTSMAN EMPLOYEE IS AUTHORIZED TO PROVIDE,OR MAKE AVAILABLE,DATA SHEETS FOR HUNTSMAN PRODUCTS.DATA SHEETS FROM UNAUTHORIZED SOURCES MAY CONTAIN INFORMATION THAT IS NO LONGER CURRENT OR ACCURATE.NO PART OF THIS DATA SHEET MAY BE REPRODUCED OR TRANSMITTED IN ANY FORM,OR BY ANY MEANS,WITHOUT PERMISSION IN WRITING FROM HUNTSMAN.ALL REQUESTS FOR PERMISSION TO REPRODUCE MATERIAL FROM THIS DATA SHEET SHOULD BE DIRECTED TO HUNTSMAN,MANAGER,PRODUCT SAFETY,AT THE ABOVE ADDRESS.13HealthInstabilityFlammability。
二乙烯三胺组分
二乙烯三胺组分
一、二乙烯三胺的概述
二乙烯三胺（简称EDTA，全称是乙二胺四乙酸二钠）是一种多功能的化学组分，具有很强的螯合能力，广泛应用于化工、食品、医药等行业。
二、二乙烯三胺的组分分析
二乙烯三胺的化学式为C8H12N2O4，分子量为228.18。
它由两个乙烯基团、一个乙氨基团和两个羧酸钠组成。
乙烯基团和乙氨基团使得二乙烯三胺具有很强的极性，从而具有良好的螯合性能。
三、二乙烯三胺在各领域的应用
1.化工行业：二乙烯三胺主要用于电镀、金属清洗、石油化工等领域，作为螯合剂、缓冲剂和络合剂等。
2.食品行业：二乙烯三胺可用于食品添加剂，如防腐、抗氧化、增稠等。
3.医药行业：二乙烯三胺用于制药，如生产头孢类抗生素等。
4.环境保护：二乙烯三胺可用于污水处理、重金属回收等环保领域。
四、二乙烯三胺的安全与储存
1.安全防护：操作时应佩戴防护用品，避免与皮肤、眼睛直接接触。
如不慎接触，应立即用大量清水冲洗。
2.储存要求：二乙烯三胺应存放在密封、干燥、避光的环境中，远离火源、热源。
五、总结
二乙烯三胺作为一种重要的化学组分，在多个领域发挥着重要作用。
了解
其组分、应用领域以及安全储存方法，有助于更好地利用这一资源，发挥其最大价值。
二乙烯三胺111-40-0
化学品安全技术说明书
15 法规信息
15.1 专门对此物质或混合物的安全，健康和环境的规章 / 法规
法规信息 请注意废物处理也应该满足当地法规的要求。 若适用，该化学品满足《危险化学品安全管理条例》（2002年1月9号国务院通过）的要求。
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2.3 其它危害物
-无
3 成分/组成信息
3.1 物质
分子式 - C4H13N3 分子量 - 103.17
4 急救措施
4.1 必要的急救措施描述
一般的建议 请教医生。出示此安全技术说明书给到现场的医生看。 如果吸入 如果吸入,请将患者移到新鲜空气处。如果停止了呼吸,给于人工呼吸。请教医生。 在皮肤接触的情况下 立即脱掉污染的衣服和鞋子。用肥皂和大量的水冲洗。请教医生。 在眼睛接触的情况下 用大量水彻底冲洗至少15分钟并请教医生。 如果误服 禁止催吐。切勿给失去知觉者从嘴里喂食任何东西。用水漱口。请教医生。
2.2 GHS 标记要素，包括预防性的陈述
危害类型
GHS05:腐蚀性物质; GHS07:感叹号; GHS08:健康危害;
信号词
【危险】
危险申明
代码
无数据资料
H314
引起严重的皮肤灼伤,以及眼睛损伤。
H334
吸入可能引起过敏或哮喘症状或呼吸困难。
警告申明
P261
避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
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化学品安全技术说明书
无数据资料
特异性靶器官系统毒性（反复接触）
无数据资料
潜在的健康影响
吸入
吸入可能有害。 该物质对组织、粘膜和上呼吸道破坏力强
二乙烯三胺-安全技术说明书MSDS
第1部分化学品及企业标识化学品中文名：二乙烯三胺化学品英文名：2,2'-iminodi(ethylamine)CAS号：111-40-0分子式：C4H13N3分子量：103.17产品推荐及限制用途：工业及科研用途。
第2部分危险性概述紧急情况概述：吞咽有害。
皮肤接触有害。
造成严重皮肤灼伤和眼损伤。
可能导致皮肤过敏反应。
GHS危险性类别：急性经口毒性类别4急性经皮肤毒性类别4皮肤腐蚀/刺激类别1B皮肤致敏物类别1标签要素：象形图：警示词：危险危险性说明：H302吞咽有害H312皮肤接触有害H314造成严重皮肤灼伤和眼损伤H317可能导致皮肤过敏反应防范说明：•预防措施：——P264作业后彻底清洗。
——P270使用本产品时不要进食、饮水或吸烟。
——P280戴防护手套/穿防护服/戴防护眼罩/戴防护面具。
——P260不要吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
——P261避免吸入粉尘/烟/气体/烟雾/蒸气/喷雾。
——P272受沾染的工作服不得带出工作场地。
•事故响应：——P301+P312如误吞咽：如感觉不适，呼叫解毒中心/医生——P330漱口。
——P302+P352如皮肤沾染：用水充分清洗。
——P312如感觉不适，呼叫解毒中心/医生——P362+P364脱掉沾染的衣服，清洗后方可重新使用——P301+P330+P331如误吞咽：漱口。
不要诱导呕吐。
——P303+P361+P353如皮肤(或头发)沾染：立即脱掉所有沾染的衣服。
用水清洗皮肤/淋浴。
——P363沾染的衣服清洗后方可重新使用。
——P304+P340如误吸入：将人转移到空气新鲜处，保持呼吸舒适体位。
——P310立即呼叫解毒中心/医生——P305+P351+P338如进入眼睛：用水小心冲洗几分钟。
如戴隐形眼镜并可方便地取出，取出隐形眼镜。
继续冲洗。
——P333+P313如发生皮肤刺激或皮疹：求医/就诊。
•安全储存：——P405存放处须加锁。
•废弃处置：——P501按当地法规处置内装物/容器。
五甲基二乙烯三胺MSDS
吸入 摄入 皮肤 眼睛
吸入可能有害。 该物质对组织、粘膜和上呼吸道破坏力强 误吞对人体有害。 引致灼伤。 如果被皮肤吸收会有毒性 引起皮肤烧伤。 引起眼睛烧伤。
接触后的征兆和症状 该物质对粘膜组织和上呼吸道、眼睛和皮肤破坏巨大。, 咳嗽, 呼吸短促, 头痛, 恶心
附加说明 化学物质毒性作用登记: IE2100000
12. 生态学资料
12.1 生态毒性 无数据资料
12.2 持久存留性和降解性 无数据资料
12.3 潜在的生物蓄积性 无数据资料
12.4 土壤中的迁移性 无数据资料
12.5 PBT 和 vPvB的结果评价 无数据资料
12.6 其它不利的影响 无数据资料
13. 废弃处置
13.1 废物处理方法
产品 在装备有加力燃烧室和洗刷设备的化学焚烧炉内燃烧处理,特别在点燃的时候要注意,因为此物质是高度易燃 性物质 将剩余的和未回收的溶液交给处理公司。
14.3 运输危险类别 欧洲陆运危规: 8 (3)
国际海运危规: 8 (3)
国际空运危规: 8 (3)
14.4 包裹组 欧洲陆运危规: II
国际海运危规: II
国际空运危规: II
14.5 环境危险 欧洲陆运危规: 否
国际海运危规 海运污染物: 否
国际空运危规: 否
14.6 对使用者的特别提醒 无数据资料
2. 危险性概述 2.1 GHS分类
易燃液体 (类别3)
3030-47-5
: +86 18301903159
页码 1 的 9
急性毒性, 经口 (类别4) 急性毒性, 经皮 (类别3) 皮肤腐蚀 (类别1B) 严重的眼损伤 (类别1)
2.2 GHS 标记要素，包括预防性的陈述 象形图
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1.物质的理化常数
2.对环境的影响
一、健康危害
侵入途径：吸入、食入、经皮吸收。
健康危害：蒸气或雾对鼻、喉和粘膜有腐蚀性，可引起支气管炎、化学性肺炎或肺水肿。
蒸气、雾或液体对眼有强烈腐蚀性，重者可导致失明。
皮肤接触可造成灼伤；对皮肤有致敏性。
口服灼伤口腔和消化道，出现剧烈腹痛、恶心、呕吐和虚脱。
慢性影响：本品有明显的致敏作用。
二、毒理学资料及环境行为
毒性：属低毒类。
1080mg/kg (大鼠经口)；1090mg/kg(兔经皮) 急性毒性：LD
50
危险特性：遇明火、高热可燃。
与氧化剂能发生强烈反应。
若遇高热，容器内压增大，有开裂和爆炸的危险。
燃烧(分解)产物：氧化氮、一氧化碳、二氧化碳。
3.现场应急监测方法
4.实验室监测方法
水杨酸分光光度法(GB/T14378-93，水质)
纳氏试剂比色法《化工企业空气中有害物质测定方法》，化学工业出版社
5.环境标准
美国(1982)车间卫生标准 4mg/m3(皮)
前苏联地面水中最高容许浓度 0.2mg/L
6.应急处理处置方法
一、泄漏应急处理
疏散泄漏污染区人员至安全区，禁止无关人员进入污染区，切断火源。
应急处理人员戴自给式呼吸器，穿化学防护服。
不要直接接触泄漏物，在确保安全情况下堵漏。
喷水雾可减少蒸发但不要使水进入储存容器内。
用砂土、蛭石或其它惰性材料吸收，然后收集运至废物处理场所。
也可以用大量水冲洗，经稀释的洗液放入废水系统。
如大量泄漏，利用围堤收容，然后收集、转移、回收或无害处理后废弃。
废弃物处置方法：用焚烧法。
废料同易燃溶剂掺和后焚烧，焚烧系统要装置后燃烧室。
焚烧炉排出的气体要通过洗涤器除去有害成分。
二、防护措施
呼吸系统防护：可能接触其蒸气时，佩戴防毒面具。
紧急事态抢救或撤离时，建议佩戴自给式呼吸器。
眼睛防护：戴化学安全防护眼镜。
防护服：穿防腐工作服。
手防护：戴橡皮手套。
其它：工作现场严禁吸烟、进食和饮水。
工作后，淋浴更衣。
实行就业前和定期的体检。
三、急救措施
皮肤接触：脱去污染的衣着，用肥皂水及清水彻底冲洗。
若有灼伤，就医。
眼睛接触：立即翻开上下眼睑，用流动清水或生理盐水冲洗至少15分钟。
就医。
吸入：迅速脱离现场至空气新鲜处。
保持呼吸道通畅。
保暖并休息。
呼吸困难时给输氧。
呼吸停止时，立即进行人工呼吸。
就医。
食入：误服者立即漱口，饮牛奶或蛋清。
就医。