melamine 三聚氰胺 MSDS
三聚氰氨事件溯源真蛋白检测的缺失三聚氰胺Melamine化学式
三聚氰氨事件溯源，真蛋白检测的缺失三聚氰胺（Melamine）（化学式：C3H6N6），俗称密胺、蛋白精，是一种三嗪类含氮杂环有机化合物，被用作化工原料，可用于塑料及涂料工业，也可作纺织物防摺、防缩处理剂，对身体有害，不可用于食品加工或食品添加物。
2008年，三鹿奶粉添加三聚氰胺事件爆发，一种主要用于工业，并且具有毒性的物资为何会出现在奶粉食品中呢？如何从根本上防止此类现象在中国再次发生，是我们企业、学术、科技届和政府都必须要思考的一个课题。
传统蛋白质检测方法是凯式定氮法，这种方法检测蛋白质是间接法，先测总氮含量，根据总氮含量再计算出蛋白质含量，而非直接测定蛋白含量。
在奶源紧张遭抢购、原料奶粉暴涨近一倍的情况下，一些不法厂商就利用这个检测漏洞，加入高含氮量的三聚氰胺，骗过凯氏定氮法获得虚假的蛋白质含量，造成蛋白质检测值虚高，来蒙混过关。
蛋白质检测方法的缺陷导致了致命的造假。
检测蛋白质含量的传统和现行标准方法依然是凯式定氮法和杜马斯燃烧定氮法，即还原无机氮或单质氮，用还原后无机氮或单质氮元素含量表征氨基酸，并反推蛋白质含量。
如果有人就把无机氮加到系统中去，干扰反推法检测蛋白质的含量，因为含氮量的提高有助于蛋白质含量反推结果的提高，会导致蛋白质含量的虚高。
1.凯氏定氮仪：这种方法是Mr. Johan Kjeldahl在1883年发明的。
凯氏定氮法，即采用化学方法，样品消解后含氮化合物转化成氨气，被吸收后经滴定后，测定出总氮元素含量，后经换算转化成蛋白质含量，由于不同的氨基酸序列，凯氏定氮法需要许多不同的校正因子。
并且需要使用浓硫酸和较长时间的加热。
所以造成了凯氏定氮法只能粗略的测量总蛋白质含量。
更致命的缺陷是，测总氮指标后再换算成蛋白指标，造成非蛋白氮会干扰测定的漏洞和机会。
2.杜马斯燃烧定氮法：样品经完全燃烧后转变为氮气，后经测定出的总氮含量后转化为蛋白质含量，步骤是：燃烧→还原→净化→检测，问题依然在于只测总氮指标后再换算成蛋白指标，非蛋白氮会干扰测定，造成蛋白含量值虚高。
三聚氰胺树脂 MSDS
Synonyms
Chemical Formula Product Codes Supplier Information
Emergency phone numbers
mixture MELAMINE CHENGDU WEITE CHEMICAL CO., LTD. Chengdu, Qionglai sheep sheep An Industrial Park, Chang'an Town, China. 86-028-88733931
Applicable Regulations
16. Other Information
NFPA Ratings Label Hazard Warning the ECDIN databank Literature References
ALL OF THE MSDS DATA ARE FOR REFERENCE ONLY. THE USERS SHOULD JUDGE THE USABILITY BY THEMSELVES.
Adverse Human Health Effects
Inhalation:move to where is with fresh air,induce vomiting and see doctor. Ingestion:move to where is with fresh air,induce vomiting and see doctor.
powder
Form
TABLET
Color
for customer need
Odor
No
pH
7
Boiling Point/Boiling Range
Melting point 90~110℃
三聚氰胺(Melamine)化学式C3H6N6,俗称密胺、蛋白精.
三聚氰胺（Melamine）化學式：C3H6N6，俗稱密胺、蛋白精。
1.什麼是三聚氰胺以及它的主要用途？
是一種三嗪類含氮雜環有機化合物，主要被用作化工原料，製造塑膠容器，最常見的是塑料碗碟。
但此器皿遇高熱會散發毒素，所以不可用於微波。
三聚氰胺還可以與乙醚配合作紙張處理劑，在一些塗料中作交聯劑，以及阻燃化學處理劑。
2.三聚氰胺的毒性。
具有輕微毒性，對身體有害，不可以用於食品加工或食品添加物。
三聚氰胺經常和結構類似的氰尿酸一起添加，攝入人體後進入腎細胞中，三聚氰胺在氰尿酸存在下兩者形成結晶沉積造成腎結石，堵塞腎小管，最終造成腎衰竭。
3.為什麼三聚氰胺會被加到食物中？
由於三聚氰胺（含氮量66%)比蛋白質（平均含氮量16%）含有更高比例的氮原子，所以被一些不肖的業者利用，添加在食品中以造成食品蛋白質含量較高的假象來欺騙消費者。
三聚氰胺完整资料北京清科奥博仪器设备有限公司完整文档
三聚氰胺完整资料北京清科奥博仪器设备有限公司完整文档(可以直接使用，可编辑完整文档，欢迎下载）三聚氰胺分子立体模型目录一、界说二、物理化学特性三、毒性危害及诊治四、人体对三聚氰胺耐受尺度五、假卵白原理六、牛奶添加三聚氰胺的作用七、合成工艺八、相关致病案例•九、家庭如何检测奶制品中是否含有三聚氰胺•十、专业的化学检测法测试三聚氰胺•十一、三聚氰胺事件导致伤亡人员数量•十二、15分钟可检测三聚氰胺的快速要领编辑本段一、界说三聚氰（qíng）胺（àn）（英文名Melamine），是一种三嗪类含氮杂环有机化合物，重要的氮杂环有机化工原料。
简称三胺，又叫2 ,4 ,6- 三氨基-1,3,5-三嗪、1,3,5-三嗪-2,4,6-三胺、2,4,6-三氨基脲、蜜胺、三聚氰酰胺、氰脲三酰胺。
更多英文名称：1,3,5-Triazine-2,4,6-triamine；2,4,6-Triamino-1,3,5-triazine；2,4,6-Triamino-s-triazine；Aero；Cyanuramide；Cyanuric triamide；Cyanurotriamide；Cyanurotriamine；DG 002 (amine)；Hicophor PR；Isomelamine；Melamine；NCI-C50715；Pluragard；Pluragard C 133；s-Triazine, 2,4,6-triamino-；Teoharn；Theoharn；Virset 656-4；分子结构分子式C3N6H6分子量126.12CAS 登录号108-78-1EINECS 登录号203-615-4编辑本段二、物理化学特性三聚氰胺性状为纯白色单斜棱晶体，无味，密度1.573g／cm3 (16℃)。
常压熔点354℃（剖析）；快速加热升华，升华温度300℃。
溶于热水，水溶性 3 G/L (20 ºC)，微溶于冷水，极微溶于热乙醇，不溶于醚、苯和四氯化碳，可溶于甲醇、甲醛、乙酸、热乙二醇、甘油、吡啶等。
三聚氰胺贴花树脂LG MSDS
CHENGDU WEITE PLASTIC. CO.,LTD三聚氰胺樹脂Melamine resin物質安全資料表MSDS一、物品與廠商資料Product and Company物品名稱Item Name：三聚氰胺樹脂Melamine resin decals LG建議用途Proposed Use: 美耐皿產品貼花與表面塗料Decals and melamine products surface coating製造商Manufacturers:地址Manufacturer'sAddress：成都維特塑膠有限公司CHENGDU WEITE PLASTIC CHEMICAL CO.,LTD 中國.四川省成都市邛崍市羊安鎮(羊安工業園區)China, Chengdu, Sichuan Province, Chang'an Town, Qionglai sheep電話/傳真電話Phone :+86-28-88733931 / Fax:+86-28-88733932二、危害辨識資料Hazard Identification物品危害分類Hazard Classification：皮膚過敏物質標示內容Mark Content：象徵符號Symbols：警示語Warning sign：警告危害警告訊息Hazard：可能致癌; 可能對水生生物產生長期持續的有害影響; 如果吞食並進入呼吸道可能有害危害防範措拖Hazardprecautionsdrag：遠離高溫Keep away from heat勿讓小孩接觸Do not let children touch使用時勿吃、喝Do not use to eat, drink勿吸入粉塵Do not breathe dust避免接觸皮膚、眼睛接觸Avoid contact with skin and eyes穿戴適當的防護衣物及呼吸防護具Wear appropriate protective clothing and respiratory protective equipment 帶上合適的手套Wear suitable gloves容器保持乾燥Keep container dry and安全許可下移除所有引火源Secure permission to remove all ignition sources 置放陰涼處Placed in the shade勿倒入排水溝Do not pour into drains混合物Mixture：。
三聚氰胺msds
Material Safety Data SheetMelamine MSDSSection 1: Chemical Product and Company IdentificationProduct Name: MelamineCatalog Codes: SLM3256CAS#: 108-78-1RTECS: OS0700000TSCA: TSCA 8(b) inventory: MelamineCI#: Not available.Synonym: 2,4,6-Triamino-s-Triazine; Isomelami;neChemical Name: MelamineChemical Formula: C3-H6-N6Section 2: Composition and Information on IngredientsComposition:NameCAS #% by WeightMelamine108-78-1100Toxicological Data on Ingredients: Melamine: ORAL (LD50): Acute: 3161 mg/kg [Rat]. 3296 mg/kg [Mouse]. DERMAL(LD50): Acute: >1000 mg/kg [Rabbit].Section 3: Hazards IdentificationPotential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation(lung irritant).Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Classified 3 (Equivocal evidence.) by NTP. 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.Section 4: First Aid MeasuresEye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention.Skin Contact:In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention.Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention.Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.Serious Inhalation: Not available.Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.Serious Ingestion: Not available.Section 5: Fire and Explosion DataFlammability of the Product: May be combustible at high temperature.Auto-Ignition Temperature: Not available.Flash Points: CLOSED CUP: Higher than 93.3°C (200°F).Flammable Limits: Not available.Products of Combustion:These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), cyanide fumes, irritating and toxic fumes and gases.Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of heat.Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available.Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.Special Remarks on Fire Hazards: Not available.Special Remarks on Explosion Hazards: Not available.Section 6: Accidental Release MeasuresSmall Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements.Large Spill:Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system.Section 7: Handling and StoragePrecautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids.Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23°C (73.4°F).Section 8: Exposure Controls/Personal ProtectionEngineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit.Personal Protection:Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product.Exposure Limits: Not available.Section 9: Physical and Chemical PropertiesPhysical state and appearance: Solid. (Crystalline solid.)Odor: Not available.Taste: Not available.Molecular Weight: 126.12 g/moleColor: White.pH (1% soln/water): Not available.Boiling Point: Not available.Melting Point: <250°C (482°F)Critical Temperature: Not available.Specific Gravity: 1.573 (Water = 1)Vapor Pressure: Not applicable.Vapor Density: 4.34 (Air = 1)Volatility: Not available.Odor Threshold: Not available.Water/Oil Dist. Coeff.: Not available.Ionicity (in Water): Not available.Dispersion Properties: See solubility in water.Solubility:Partially soluble in cold water. Insoluble in diethyl ether.Section 10: Stability and Reactivity DataStability: The product is stable.Instability Temperature: Not available.Conditions of Instability: Dust generation, excess heat, incompatible materials.Incompatibility with various substances: Reactive with oxidizing agents, acids.Corrosivity: Not available.Special Remarks on Reactivity: Not available.Special Remarks on Corrosivity: Not available.Polymerization: Will not occur.Section 11: Toxicological InformationRoutes of Entry: Inhalation. Ingestion.Toxicity to Animals:Acute oral toxicity (LD50): 3161 mg/kg [Rat]. Acute dermal toxicity (LD50): >1000 mg/kg [Rabbit].Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 3 (Equivocal evidence.) by NTP. 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast.Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant).Special Remarks on Toxicity to Animals: Not available.Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (fertility, fetotoxicity), and may affect genetic material based on animal data. May also be tumorigenic (carcinogenic) based on animal data.Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: May cause eye irritation. Inhalation: May cause irritation of the respiratory tract and affect respiration. May affect behavior and sense organs, liver and blood. Ingestion: May cause irritation of the digestive tract with nausea, vomiting and diarrhea. May affect the urinary system.Section 12: Ecological InformationEcotoxicity: Not available.BOD5 and COD: Not available.Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.Special Remarks on the Products of Biodegradation: Not available.Section 13: Disposal ConsiderationsWaste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.Section 14: Transport InformationDOT Classification: Not a DOT controlled material (United States).Identification: Not applicable.Special Provisions for Transport: Not applicable.Section 15: Other Regulatory InformationFederal and State Regulations:Pennsylvania RTK: Melamine Massachusetts RTK: Melamine New Jersey: Melamine TSCA 8(b) inventory: MelamineOther Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.Other Classifications:WHMIS (Canada): Not controlled under WHMIS (Canada).DSCL (EEC):R36/37/38- Irritating to eyes, respiratory system and skin. S24/25- Avoid contact with skin and eyes. S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.HMIS (U.S.A.):Health Hazard: 2Fire Hazard: 1Reactivity: 0Personal Protection: ENational Fire Protection Association (U.S.A.):Health: 2Flammability: 1Reactivity: 0Specific hazard:Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.Section 16: Other InformationReferences: Not available.Other Special Considerations: Not available.The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes.。
(37)三聚氰胺试剂盒说明书(1ppb)Ver1403
三聚氰胺（MEL）ELISA检测试剂盒说明书产品编号：HE09037/HE12003一、概要三聚氰胺(melamine)是一种低毒、无味的纯白色单斜棱晶体，形似蛋白粉，属于三嗪类含氮杂环有机化合物，广泛应用于塑料、染料、化肥的生产和纺织行业。
由于三聚氰胺分子含氮量很高，只要添加到食品中就可在检测中造成蛋白质含量较高的假象。
目前在饲料、牛奶、奶粉、饼干、奶糖等相关产品均发现有三聚氰胺残留现象。
动物实验结果表明，三聚氰胺的摄入可能会导致繁殖障碍、膀胱炎、慢性肾炎、肾结石、甚至膀胱癌。
现有的检测三聚氰胺方法如液相色谱-质谱联用法、质谱电喷射离子技术其样品前处理复杂、所需仪器昂贵、操作复杂、耗费时间。
而使用三聚氰胺ELISA试剂盒能够既快速又准确的分析样本中三聚氰胺残留。
本试剂盒是应用ELISA技术研发而成的检测产品，与仪器分析技术相比具有快速、简便、准确和灵敏度高等优点，操作时间为45min，能最大限度地减少操作误差和工作强度。
二、实验原理本试剂盒采用间接竞争ELISA方法，在酶标板微孔上预包被三聚氰胺抗原，样本残留的三聚氰胺和微孔上预包被的抗原竞争三聚氰胺抗体（抗试剂），同时加入酶标二抗（酶标物）反应，再加入TMB底物显色，样本吸光值与其残留物三聚氰胺成负相关，与标准曲线比较再乘以其对应的稀释倍数，即可得出样本中三聚氰胺的含量。
三、适用范围可定性、定量检测奶粉、牛奶、酸奶等乳制品、鸡蛋及饲料样本中三聚氰胺的残留量。
四、交叉反应率三聚氰胺………………………………………………100％五、使用单位需自备的设备及试剂设备：┅┅微孔板酶标仪450/630nm┅┅涡旋仪┅┅天平：感量0.01g┅┅聚苯乙烯离心管┅┅微量移液器：单道10μL~100μL、100μL~1000μL、多道30μL~300μL试剂：----去离子水----乙腈（分析纯）----氢氧化钠（分析纯）----三氯乙酸----浓盐酸（分析纯）六、提供的材料与试剂组份名称96T装量48T装量酶标板96T 48T标准品×6瓶* 1 mL 0.5 mL 高浓度标准品(10 ppm) 1 mL 0.5 mL 三聚氰胺酶标物 6 mL 3 mL三聚氰胺抗试剂 6 mL 3 mL底物液A液 6 mL 3 mL底物液B液 6 mL 3 mL终止液 6 mL 3 mL 浓缩洗涤液（10×）40 mL×2瓶40 mL 三聚氰胺浓缩样本稀释液12mL 6 mL 试剂盒说明书1份1份检测报告1份1份盖板膜2个1个*注：标准品浓度为0 ppb, 1 ppb, 3 ppb, 9 ppb, 27 ppb, 81 ppb。
三聚氰胺安全数据表
误服者漱口，用1：5000的高锰酸钾或5%硫代硫酸钠洗胃。就医。
防护措施
工程控制
密闭操作，全面排风。
呼吸系防护
空气中浓度超标时，应该佩戴防毒面具。高于NIOSH REL浓度或尚未建立REL，任何可检测浓度下：自携式正压全面罩呼吸器、供气式正压全面罩呼吸器辅之以辅助自携式正压呼吸器。逃生：装有机蒸汽滤毒盒的空气净化式全面罩呼吸器（防毒面具）、自携式逃生呼吸器。
毒性危害
接触限值
中国MAC：未制订标准前熟练MAC：0.5mg/m3，美国TLV-TWA：未制订标准，TLV-STEL：未制订标准
侵入途径
吸入食入
毒性
属低毒类LD50：小鼠经口：4.55g/kg；大鼠经口：3g/kg；LC50：接触者可发生皮炎。未见职业中毒报道。注意，本品在高温下能分解产生高毒的氰化物气体。IARC评价：3组；未分类物质，人类证据不足，动物证据不充分。NTP：动物致癌物健康危害（蓝色）:0
急救
皮肤接触
脱去污染的衣着，立即用肥皂水及流动清水冲洗受污染的皮肤。对少量皮肤接触，避免将物质播散面积扩大。注意患者保暖并且保持安静。吸入、食入或皮肤接触该物质可引起迟反应。确保医务人员了解该物质相关的个体防护知识，注意自身保护。
眼睛接触
立即翻开上下眼脸，用流动清水冲洗，至少15分钟。就医。
吸入
脱离现场至空气新鲜处。就医。如果患者呼吸停止，给予人工呼吸。如果呼吸困难，给予吸氧。如果患者食入或吸入该物质不要用口对口进行人工呼吸，可用单向阀小型呼吸器或其他适当的医疗呼吸器。
燃烧分解产物
一氧化碳、二氧化碳、氮氧化物、氰化氢。
稳定性
稳定
禁忌物
强氧化剂、强酸。
聚合危害
不能出现
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Section 3: Hazards Identification
Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation (lung irritant). Potential Chronic Health Effects: CARCINOGENIC EFFECTS: Classified 3 (Equivocal evidence.) by NTP. 3 (Not classifiable for human.) by IARC. MUTAGENIC EFFECTS: Mutagenic for bacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated or prolonged exposure is not known to aggravate medical condition.
Material Safety Data Sheet
Melamine MSDS
Section 1: Chemical Product and Company Identification
Product Name: Melamine Catalog Codes: SLM3256 CAS#: 108-78-1 RTECS: OS0700000 TSCA: TSCA 8(b) inventory: Melamine CI#: Not available. Synonym: 2,4,6-Triamino-s-Triazine; Isomelami;ne Chemical Name: Melamine Chemical Formula: C3-H6-N6 Contact Information: HE BEI NEIL CHEMICAL CO.,LTD No.148 Yuhua road,Shijiazhuang City, Hebei Province Country: China (Post Code:050000) Phone: Fax: 0086-311-89279929 0086-311-85250322
Composition: Name Melamine CAS # 108-78-1 % by Weight 100
Toxicological Data on Ingredients: Melamine: ORAL (LD50): Acute: 3161 mg/kg [Rat]. 3296 mg/kg [Mouse]. DERMAL (LD50): Acute: >1000 mg/kg [Rabbit].
p. 1
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention. Serious Inhalation: Not available. Ingestion: Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear. Serious Ingestion: Not available.
p. 2
Section 8: Exposure Controls/Personal Protection
Engineering Controls: Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection: Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: Not available.
Section 4: First Aid Measures
Eye Contact: Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Cold water may be used. Get medical attention. Skin Contact: In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminated clothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medical attention.
Section 5: Fire and Explosion Data
Flammability of the Product: May be combustible at high temperature. Auto-Ignition Temperature: Not available. Flash Points: CLOSED CUP: Higher than 93.3°C (200°F). Flammable Limits: Not available. Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...), cyanide fumes, irritating and toxic fumes and gases. Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of heat. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Fire Fighting Media and Instructions: SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available.
Section 7: Handling and Storage
Precautions: Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, acids. Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23°C (73.4°F).