QSOP 0006-4100C - Crocking Test

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一种检测禽产品中甲氧苄啶和磺胺氯吡嗪钠的方法[发明专利]

一种检测禽产品中甲氧苄啶和磺胺氯吡嗪钠的方法[发明专利]

专利名称:一种检测禽产品中甲氧苄啶和磺胺氯吡嗪钠的方法专利类型:发明专利
发明人:刘刚
申请号:CN201610116018.7
申请日:20160302
公开号:CN105758960A
公开日:
20160713
专利内容由知识产权出版社提供
摘要:一种检测禽产品中甲氧苄啶和磺胺氯吡嗪钠的方法,属于兽药残留检测技术领域。

本发明其特征在于利用液相色谱?串联三重四级杆质谱一次性同步检测家禽产品中甲氧苄啶和磺胺氯吡嗪钠,其步骤主要包括提取、净化浓缩和检测等步骤。

本方法使用液相色谱?串联三重四级杆质谱进行检测,分析时间大大缩短且定量下限更低10ug/kg,检测结果更为准确。

另外,此方法前处理步骤简单,未采用SPE净化柱,成本较低。

申请人:青岛海润检测股份有限公司
地址:266555 山东省青岛市黄岛区江山南路458号创业大厦908室
国籍:CN
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岛津TOC-4100标准版

岛津TOC-4100标准版
- 由于使用强酸(硫酸)和强氧化剂(重铬酸钾),易造成 部件腐蚀。
• TOC(总有机碳含量)
- 应用领域:各种排污水、地表水、自来水、冷却水、纯净 水中有机物的测定。 - 几乎所有的有机物均可检测,约达100% - 测试周期短,约4分钟。 - 测试迅速、精确度高、灵敏度高。 - 不使用药品,日常维护费用少。 - 无二次污染。 - 非常适用于有机物在线监测。 - 在欧美、日本以及国内已被广泛应用到废水及水处理中。 - 由自动COD仪改为TOC仪将逐渐增多(为了减少故障率 以及减轻维护管理负担)。 - TOC与CODcr之间有很好的相关性,可以换算成COD。
20
T 158.1 56.1
OC与
C
OD

相关
TOC 25
8.4
1散3.5布図お1よ13び.4回帰直線とCODの推定値の95%信頼限界
7.2
14
100..8
11.61
18.9
TOC 与 COD 相互关系
样品名称 相关系数
化纤厂 啤酒厂 污水处理厂 染料厂 化学工厂 化学工厂 啤酒工厂
- 利用注射器进行稀释,因此精度及稳定性高,稀释水用量少。 - 在操作画面上可简便地设定稀释倍率。 - 在采集水样的同时进行稀释,大大缩短稀释时间。 - 在稀释的同时可进行校正,可用一瓶标准液进行多个不同量 程的校正。
• 新增加节气功能,47L氮气从原来1个月1瓶延长为2~3个月1瓶。 • 具有检测器灵敏度自动切换、自动稀释功能。 • 具有远程控制功能。 • 具有对外部采水泵的控制功能。 • 可以通过零及跨度标准液对仪器进行自动校正。 • 可在每次测试后通过稀释水对所有样品流路进行清洗。 • 最多可测试6个流路(通过切换方式)。 • 试剂消耗量少(HCL:1L/月),运行费用低。 • 中文显示画面。 • 具有自动报警功能。 • 具有自动停/开机功能。

畜禽肉中多类兽药残留的快速检测

畜禽肉中多类兽药残留的快速检测

畜禽肉中多类兽药残留的快速检测黄 立(昆明市食品药品检验所,云南昆明 650032)摘 要:建立了猪肉、牛肉、鸡肉中磺胺类、四环素类、喹诺酮类共15种兽药残留量的快速检测方法。

样品经过Na2EDTA-Mcllvaine缓冲液-2.5%乙酸乙腈溶液提取,经氯化钠、无水硫酸钠除水盐析后取乙腈相用高含碳量的C18吸附粉吸附净化,再用0.1%甲酸水乙腈(75+25)定容后上机检测。

结果显示,本方法测定三类混合药物的回收率在63.9%~104.0%,RSD在1.1%~12.2%,检测快速、灵敏度高、重复性好,定性定量准确可靠,适用于猪肉、牛肉及鸡肉中磺胺类、四环素类、喹诺酮类药物残留的快速检测。

关键词:液相色谱-串联质谱法;磺胺;四环素;喹诺酮Rapid Detection of Multiple Types of Veterinary Drug Residues in Livestock and Poultry MeatHUANG Li(Kunming Institute for Food and Drug Control, Kunming 650032, China) Abstract: A rapid method was established for the determination of 15 veterinary drug residues of sulfonamides, tetracyclines and quinolones in pork, beef and chicken. The samples were extracted by Na2EDTA-Mcllvaine buffer-2.5% acetic acid acetonitrile solution, and the acetonitrile phase was purified by adsorption with high carbon content C18 adsorbent powder after dehydration salting by sodium chloride and anhydrous sodium sulfate, and then fixed with 0.1% formic acid aqueous acetonitrile (75+25) and detected on the machine. The results showed that the method determines the recovery of the three types of mixed were 63.9%~104.0%, RSD were 1.1%~12.2%, rapid detection, high sensitivity, good repeatability, accurate and reliable qualitative and quantitative, suitable for the rapid detection of sulfonamides, tetracyclines, quinolones drug residues in pork, beef and chicken.Keywords: liquid chromatography-tandem mass spectrometry; sulfonamide; tetracycline; quinolone合理使用兽药可以提高畜禽养殖效率,节省成本,缩短出栏周期,进而增加收益,但越来越多的人为追求经济效益滥用药物,导致了一些兽药以残留的形式流入人体,从而对身体健康造成威胁[1]。

Mattel QSOP

Mattel QSOP

TABLE OF CONTENTSNUMERICAL(Revised July 2006)SAFETY OPERATING PROCEDURESNewRevision Procedure # Title0006-3010 Accessibility APoints F 0006-3020 SharpEdges E 0006-3030 Sharp0006-3035 Projections BParts M 0006-3040 SmallMaterial PR 0006-3042 Expandable0006-3046 Product Intended to be Placed in a Freezer/Refrigerator PRCombinations PR 0006-3047 Toy/FoodImitations B 0006-3048 FoodTest F 0006-3049 EntanglementShapes R 0006-3050 Choking/Suffocation/Hazardous0006-3051 Caps for Writing and Marking Instruments B0006-3052 SoakingTest PR 0006-3053 Cup Shaped Objects D0006-3055 Preschool Play-Figure Standard A0006-3060 Torque/Tension D 0006-3063 Switches Used in Battery Powered Ride-On Toys PR0006-3065 Buckle Webbing Adjuster Test A0006-3066 Buckle False Latch Test BSeats C 0006-3068 BouncerSwings PR 0006-3069 Infant0006-3070 Seam And Attachment Strength DTest B 0006-3080 BiteProducts B 0006-3090 Mouth-Actuated0006-3092 Pacifiers A 0006-3100 Wires/Rods & Stiffening Materials D0006-3110 Compression G 0006-3115 Polyethylene Stress Cracking B0006-3116 Rotomolded PVC Curing Test A0006-3120 Drop, Impact and Tip-Over Test DTest B 0006-3130 BarImpactFilledToys PR 0006-3132 LiquidTest A 0006-3140 Tumble0006-3145 Handles D 0006-3151 Static and Dynamic Strength B0006-3152 Stability A 0006-3153 Static Strength –Product Likely but Not Intended to Support a Child’s Weight PR 0006-3160 Cords Strings & Elastics J0006-3163 Infant Bedding and Related Accessories ATABLE OF CONTENTSNUMERICAL(Revised July 2006)NewRevision Procedure # TitleSupport PR 0006-3164 Mattress0006-3170 Projectiles and Flying Toys LTest AImpact0006-3171 ProjectilesAssembly A 0006-3180 Wheel/Axle0006-3183 Entrapment – Intended to Bear the Weight of a Child PR 0006-3184 Entrapment – Crib & Playpen Attached Toys C 0006-3185 Entrapment – Pop-up Feature PRChutes A 0006-3186 Entrapment–0006-3187 Entrapment – Rods and Axles PR 0006-3188 Entrapment – Bucket Shaped Objects PR 0006-3189 Entrapment – Openings in Rigid Materials PR 0006-3191 Hair Entrapment – Products with Wheels C 0006-3192 Entrapment – Products Likely to be Batted with the Feet A 0006-3193 Entrapment - Products with Complete or Partial Openings D 0006-3194 Entrapment – Play Yard PR 0006-3195 Entrapment – Toys Under 18 Months with Undercuts PR 0006-3196 Entrapment – Toy Chests A 0006-3197 Entrapment – Strollers with Grab Bars or Trays PR 0006-3200 Moveable Parts & Hinge Line Clearance J 0006-3201 Springs PR 0006-3210 Plastic Bags and Films JTest EDischarge0006-3220 Electrostatic0006-3225 Electromagnetic Compatibility (EMC) Assessment A 0006-3251 Crib/Play Yard Rattling Test A 0006-3265 Abnormal Operation of Battery & Transformer Toys G 0006-3266 Electrical Strength of Battery & Transformer Toys D 0006-3267 Moisture Resistance of Battery & Transformer Toys B 0006-3268 Mechanical Strength of Battery & Transformer Toys C 0006-3269 Plugs/Sockets/Exposed Wires of Battery & Transformer Toys B 0006-3270 Components of Battery & Transformer Toys C 0006-3271 Screws & Fastners of Battery & Transformer Toys C 0006-3272 Creepage Distances & Clearances of Electronic Assemblies CProtection GLeakage0006-3273 Battery0006-3300 Flammability of Solids and Stuffed Toys H 0006-3301 Flammability of Vinyl Plastic Film Used As Wearing Apparel PR 0006-3302 Flammability of Stuffed & Soft Toys D 0006-3303 Flammability of Liquids, Gels & Pressurized Containers B 0006-3310 Flammability of Stuffed Toys & Costume Pieces FFabrics Iof0006-3320 Flammability0006-3321 Flammability of Products With Fabrics For DI Into Canada A 0006-3322 Flammability of Hair And Mane BTABLE OF CONTENTSNUMERICAL(Revised July 2006)NewRevision Procedure # Title0006-3330 Flammability of Enclosures & Costumes F 0006-3400 Sound Pressure Levels G 0006-3450 Promotional Media Depictions of Crib Scenes A 0006-3451 Promotional Media Depictions of Water Scenes PR 0006-3452 Promotional Media Depictions of Wheel & Street Scenes PRFill PR 0006-3456 SlackLabelingFormat K 0006-3500 Safety0006-3501 Labeling Marking Permanency Test PR 0006-3505 Labeling of Activity Gyms PRCopy AE 0006-3510 Package0006-3517 Labeling of Products Sold in India D 0006-3520 Labeling of Hazardous Art Materials (LHAMA) C 0006-3522 Labeling of Products With PVC Softeners B 0006-3524 Labeling of Products With Long Cords for Sale in Brazil PR 0006-3525 Labeling of Products With Monofilament Hair A 0006-3526 Labeling of Hair Entrapment – Product with Wheels A 0006-3530 Labeling for Small Parts, Balls & Marbles Y 0006-3531 Labeling of Balloons A 0006-3534 Labeling & Marking of Electrical Products J 0006-3535 Labeling & Marking of Battery Operated Products W 0006-3540 Markings of Toy Guns C 0006-3541 Labeling of Water Function Products A 0006-3542 Labeling of Caps PR 0006-3543 Labeling of Cosmetics F 0006-3544 Labeling of Products with Circuit Boards F 0006-3545 Labeling of Mobiles A 0006-3547 Labeling of Food Contact Surfaces PR 0006-3548 Labeling of Pacifiers, Nipples & Teethers B 0006-3549 Labeling of Products With Functional Sharp Points/Edges A 0006-3550 Labeling of Chemical Products for Sale in Brazil PR 0006-3551 Labeling of Mineral Oil Filled Toys A 0006-3552 Labeling of Pressurized Containers A 0006-3553 Labeling of Simulated Protective Devices A 0006-3554 Labeling of Nonprescription Sunglasses & Fashion Wear Glasses. B 0006-3555 Labeling of Ride-On/In Products F 0006-3556 Labeling of Products Intended to be Assembled by An Adult D 0006-3557 Labeling of Projectiles and Flying Toys B 0006-3558 Labeling of Infant Bedding and Related Accessories PR 0006-3559 Labeling of Product Material PR 0006-3560 Labeling of Products Requiring The “C” Tick Mark B 0006-3561 Labeling of Toy Highchairs and Strollers PRTABLE OF CONTENTSNUMERICAL(Revised July 2006)NewRevision Procedure # Title0006-3567 Labeling of Videocassettes PR 0006-3568 Labeling of DVD-Rom & VCD B 0006-3569 Labeling of Toy Chests PR 0006-3570 Labeling of Food Products for Sale in European Union PR 0006-3571 Labeling of Food Products for Sale in LAAM PR 0006-3572 Labeling of Food Products for Sale in USA PR 0006-3573 Labeling of Food Products for Sale in Australia & New Zealand PR 0006-3574 Labeling of Food Products for Sale in Canada PR 0006-3576 Labeling Costumes and Toys a Child can Enter PR 0006-3577 Labeling – Warning Statements For Stationary Activity Centers PR 0006-3578 Labeling – Warning Statements For Stand “N” Ride Duo Stroller PR 0006-3579 Labeling – Warning Statements For Infant T0 Toddler Rockers PR 0006-3580 Labeling – Warning Statements For Infant Seats PR 0006-3581 Labeling – Warning Statements For Infant Tubs PR 0006-3582 Labeling – Warning Statements For Bouncer Seats B 0006-3583 Labeling – Warning Statements For Full Size Swing-Rockers A 0006-3584 Labeling – Warning Statements For Gliders With Toy Bars PR 0006-3585 Labeling – Warning Statements For Collapsible Wagon with Seats PR 0006-3586 Labeling – Warning Statements For High Chairs PR 0006-3587 Labeling – Warning Statements For Swings A 0006-3589 Labeling – Warning Statements For Booster Seats PR 0006-3590 Labeling – Warning Statements For Potty Seats PR 0006-3593 Labeling – Warning Statements For Air Mattresses PRElements H 0006-3600 Heavy0006-3601 Nickel Release Rate B 0006-3602 R.o.H.S. PR 0006-3603 Ventilation for Plastic Blisters & Plastic Packing PR 0006-3608 Nitrosamines & Nitrosatable Substances In Pacifiers, Nipples & Teethers PR 0006-3610 Stabilizers & Plasticizers in Polyvinyl Chloride (PVC) MRetardants B 0006-3614 Flame0006-3615 Azo Dyes in Soft Goods GBase C 0006-3616 AcidTest B 0006-3617 ColorMigration0006-3625 Polyethylene Glycol (PEG) Level in Polypropylene Webbing A 0006-3630 Cleanliness of Materials F 0006-3635 Cleanliness of Stuffing Materials AChallenge E 0006-3640 MicrobialSusceptibilityCapability ADesign0006-3801 Critical-To-Safety0006-3802 Critical-To-Safety Test Plan BQualification E 0006-3803 ProductSelf-Certification B 0006-3804 EuropeanCommunityTABLE OF CONTENTSNUMERICAL(Revised July 2006)NewRevision Procedure # TitleFit B 0006-4006 Restraint0006-5000 Packaging Heavy Elements (Hg, Cd, Pb, Cr) B 0006-5010 Total Cadmium in Plastics B 0006-5015 Environmental -Toxic Substance Control Act (TOSCA) E 0006-5020 Environmental – Substances that Deplete the Ozone Layer B 0006-5030 Environmental – Rigid Plastic Container Material Code System B 0006-5031 Environmental – Rigid Plastic Packaing Container A 0006-5040 Environmental – Guide for the Use of Environmental Marketing Claims B 0006-5050 Environmental – Battery Operated Product I** 0006-37XX Mattel Internal use, not distribute to vendor. **RELIABILITY OPERATING PROCEDURESRevision NewProcedure # Title0006-4000 StepTest D On0006-4005 Defect Classification Catalog A 0006-4010 Sand Abrasion to Surface Coatings BAdhesion C 0006-4020 Label0006-4030 Surface Coatings Adhesion (Tape Pull) CTest A 0006-4040 ScratchAbrasion A 0006-4050 Eraser0006-4065 Labeling of Textiles Content A 0006-4066 CareLabels ATest B 0006-4070 DishwashingWashability F 0006-4080 FabricWashability A 0006-4085 SurfaceMigration A 0006-4090 DyeTest B 0006-4100 Crocking0006-4110 Stain Test on Fabric B 0006-4120 Carpet/Upholstery Stain Test BMigration C 0006-4130 Plasticizer0006-4140 Plush and Hair Loss CComprehension A 0006-4150 PhrasePolicy D 0006-4200 DateCodeTABLE OF CONTENTSNUMERICAL(Revised July 2006)NewRevision Procedure # TitlePolicy C 0006-4201 WarrantyIntegrity G 0006-4300 PackageColor C 0006-4320 Packaging0006-4340 Bar Code for Master Carton (SCC-14 12/5) C 0006-4341 Bar Code For Individual Product Package (UPC) D 0006-4342 Bar Code (Voluntary) For Master Carton Dash Codes B0006-4350 Transportation B 0006-4360 Master Carton Compression Test B 0006-4361 MasterStability BCarton0006-4362 Master Carton Flap Alignment PR 0006-4370 Labeling of Chemical Products A 0006-4371 Labeling of Color Change/Glow in the Dark Products A 0006-4372 Labeling of CD-Roms and Peripherals A 0006-4373 Labeling of Products that Use Warm or Hot Water A 0006-4400 Simulated Aging & Storage C 0006-4405 Cold Storage & Drop A 0006-4410 Humidity A 0006-4415 RainTest PRStability B 0006-4420 Freeze-ThawLoss C 0006-4421 Vapor0006-4425 High-Temperature Chemical Stability Test BProducts B 0006-4430 Preconditioning-WaterExposure B(UV)0006-4450 UltravioletDEFINITIONSRevision NewProcedure # Title0006-8000 Definitions Obsolete。

聚碳酸酯苯酚端基的测定

聚碳酸酯苯酚端基的测定

聚碳酸酯苯酚端基的测定
聚碳酸酯(PC)是一种常见的工程塑料,广泛应用于各种领域。

在制造过程中,可能会引入一些杂质,如苯酚。

这些杂质会对产品的性能产生不利影响,因此需要对聚碳酸酯进行检测,以确保其质量符合标准。

测定聚碳酸酯苯酚端基的方法有很多,常见的包括高效液相色谱法(HPLC)、红外光谱法(IR)、核磁共振法(N MR)和质谱法(MS)等。

其中,高效液相色谱法因其准确度高、重复性好、灵敏度高等优点,被广泛应用于苯酚端基的测定。

高效液相色谱法的原理是:样品经过适当的预处理后,注入高效液相色谱仪。

在色谱柱中,样品中的各组分受到固定相(固定床)和流动相(溶剂)的作用,不同组分会因为分子大小、极性、分配系数等差异,而被分离。

苯酚端基由于其特定的化学性质,可以通过特定的检测器(如紫外检测器)进行检测,从而确定其含量。

在实际操作中,为了提高检测的准确性和可靠性,需要对仪器进行校准,同时对样品进行充分的预处理,如过滤、稀释等,以确保样品中的苯酚端基可以被准确测定。

为了保障人民的利益和产品的质量,我国对聚碳酸酯产品的质量有严格的标准和规定。

企业和研究机构在使用高效
液相色谱法进行聚碳酸酯苯酚端基的测定时,需要遵守相应的国家或行业标准,确保其产品或研究成果的可靠性和准确性。

在您的实验室中,如果需要进行聚碳酸酯苯酚端基的测定,建议采用高效液相色谱法,并根据《中华人民共和国药典》(ChP)或相关行业标准进行操作,以保证实验结果的科学性和法律效力。

同时,也建议定期对高效液相色谱仪进行维护和校准,以保证仪器的稳定性和准确性。

农残速测仪使用技术说明书

农残速测仪使用技术说明书

农残速测仪使用技术说明书农残速测仪简介农残速测仪是浙江托普仪器有限公司根据国标GB/T5009.199-2003,采用酶抑制原理和光电比色法原理研制而成。

主要型号一般为NY-8D/NY-16D、NY-8DL/NY-16DL。

农残速测仪用途农药是把“双刃剑”,对促进农业增产有着及其重要的作用,但由于农药本身固有的化学性和对其使用不当,导致农产品农药残留超标,危害广大人民的身体健康。

2012年全国各地《基层农技推广体系建设项目》已经启动,农药残留速测仪可以快速检测水果、蔬菜中的农药残留,从而能够有效的控制农药的使用量。

同时该仪器广泛应用于产品质量监督检验、卫生防疫、环境保护、工商管理、蔬菜批发市场、蔬菜生产基地、超市、商场、农药残留监测系统等部门的蔬菜和水果中的农药残毒检测。

农残速测仪原理在一定条件下,有机磷和氨基甲酸类农药对胆碱酯酶正常功能有抑制作用,其抑制率与农药的浓度呈正相关。

正常情况下,酶催化神经传导代谢产物(乙酰胆碱)水解,其水解产物与显色剂反应,产生黄色物质,用分光光度计测定412nm下吸光度随时间的变化值,计算出抑制率,通过抑制率可以判断出样品中是否含有有机磷或氨基甲酸酯类农药的残留。

可以实现有机磷及氨基甲酸酯类农药残留量的现场快速检测。

它可以广泛应用于产品质量监督检验、卫生防疫、环境保护、工商管理、蔬菜批发市场、蔬菜生产基地、超市、商场、农药残留监测系统等部门的蔬菜和水果中。

农残速测仪的功能特点:多通道测试,支持多样品同时检测测试结果定性和定量均可,定性显示结果为抑制率,定量显示结果为mg/kg(PPM)主机上可以自动判别检测结果是否合格仪器自带嵌入式微型打印机,与仪器一体,可以直接将定性定量的结果同时打印出来。

带有反应时间设定和合格标准设定具有自动保存检测结果,并能查询保存的记录7寸彩色液晶大屏幕触摸屏显示,可直接点击屏幕操作也可用鼠标操作,柱状图显示,直接读数。

主机内置客户管理系统,每个用户可设定密码并支持多用户分别登陆,可按检测日期和检测编号查阅,打印,删除存储测量数据。

希森美康血凝仪

希森美康血凝仪

CS-2100i/2000i根据SYSMEX在血栓与止血领域多年积累的经验,为全面满足各类实验室的需求率先开发CS-2100i/2000i。

四种方法学:凝固法/发色底物法/免疫比浊法/聚集法unique!多波长高精度光学检测:5种波长检测提供可靠数据新型智能监测:特有的HIL check 功能排除溶血/黄疸/脂血干扰更多新检测项目的选择:FXIII,vWF:Rco等更可靠的实验室质量保证:SNCS实时在线质控全面满足血栓与止血检测需求!CA-7000以全球最快的分析速度提供全面和高精准的止凝血项目检测结果,仪器集中了凝固法,发色底物法和免疫法于一体,设计高度人性化和智能化,操作简便,成为大规模实验室的首选。

● 多参数测试,500测试/小时高速分析能力● 操作简便,灵活对待各种需求● 优秀的试剂管理系统(SRS)● 安全、实用的系统设计● 大容量的数据管理能力,完整的质控系统CA-1500汇集了当今血栓/止血分析仪最新的各种先进功能于一身,是市场上少见的性能/价格比极高的一台仪器,是大型教学医院,综合医院实验室的首选。

它具有快速处理能力,最快180测试/小时,集多种检测功能于一身:凝固法、发色底物法、免疫法。

具有全能随机组合能力,两种方法测定纤维蛋白质,适合常规大量和急诊使用。

● 拥有高速处理能力、随机测试功能和自动再检查功能● 三种分析方式,包括多规则监视的广泛质控文件和平行线生物分析功能● 卓越的性能可以灵活适应实验室的多样化需求CA-500系列CA-500系列包含了六款机型,设计新颖、符合经济原则,是各中小型实验室开展血栓/止血实验的最佳选择,也是半自动升级到全自动的理想机型。

小型台式仪实用可靠,具备三种检测系统即凝固法、发色底物法、免疫法的自由组合用户可根据需要选择相应机型。

CA-50设计上完全沿用了全自动CA系列的检测原理,锁定人为误差因素的设计确保它有别于其他半自动血凝仪,达到全自动仪器的准确性与重复性效果,四通道即可批量检测又可单独检测,内置质控文件,适用于小标本量实验室使用。

三重四级杆液相质谱联用仪参数

三重四级杆液相质谱联用仪参数

三重串联四极杆液质联用仪品牌:WA TERS1、设备名称:液相色谱串联四极杆质谱联用仪2、主要用途:用于多种农、兽药残留、生物毒素残留、食品添加剂的检测,动物及动植物源食品的残留监控工作,特别是对检测结果为阳性的样品,可进行结果确证,并且可以对预期要开展的检测项目进行检测技术储备,以加强对出口食品、农产品安全卫生质量的监管和控制。

3、工件条件:工作电压:230V±10%温度:18-250C湿度:350-85%4、技术指标:1)超高效液相色谱系统技术要求1.1二元或四元泵*1.1.1压力:0-15,000 psi1.1.2流量:0.001-2.000ml/min, 以0.001ml/min 为增量1.1.3精度:≤0.075%RSD1.1.4流速准确度:±1.0%1.1.5延迟体积:<120μL1.1.6溶剂数量:4种1.1.7设定范围:室温上5 – 60 °C,1°C 步距1.1.8温度控制精度:±0.1oC温度1.2自动进样器1.2.1精度:< 0.5%1.2.2样品交叉污染度:<0.005%1.2.3进样准确度:±1 μL1.2.4进样体积:0.1 ~50μl1.2.5进样线性度: > 0.9991.3在线真空脱气机1.4二极管阵列检测器1.4.1波长范围:190-800nm1.4.2二极管个数:1024个1.4.3光学分辨率:1.2nm1.4.4狭缝宽度:1,2,4,8,16nm1.4.5实时信号:同时输出8个实时信号1.4.6波长精度:1nm1.4.7基线噪音:±1.0 x 10-5 AU,在254nm和750nm(1mL/min甲醇)1.4.8基线漂移: 2 x 10-3AU/hr , 在254nm(1mL/min甲醇)1.4.9数据采集率:〉80Hz2)质谱部分指标*2.1质量范围m/z: MS1及MS2:30-3,000amu2.2分辨率:?2.5M2.3质量数稳定性:≤0.1 amu /8H2.4电喷雾灵敏度指标(相同绝对量,不同浓度下的灵敏度):1pg利血平,m/z 609-195,信噪比≥500:12.5ESI负离子:2.5pg氯霉素,m/z321-152,信噪比≥100:12.6正、负离子采集切换速率≤20 ms2.7MRM扫描时间≤5 ms,一个采集通道可MRM定量数≥502.8扫描速率:?5000amu/秒2.9动态范围:?4X1062.10质量精度:≤0.1 amu2.11离子源:大气压离子源是双正交设计,而且离子源和质谱间有隔断阀,锥孔有N2保护气,可容忍不挥发性的缓冲盐。

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QSOP 0006-4100 CPage 1 of 6PI CONFIDENTIAL - MATTEL, INC. PROPRIETARY INFORMATIONTITLE CROCKING TESTQUALITY AND SAFETY NUMBER 0006-4100 REVISION C DATE 07/25/07 OPERATING PROCEDUREAUTHOR D. Taylor REVISED BY B. Brockway 1. SCOPE1.1. Products and Components CoveredFabric items.1.2. ExemptionsYarnSimulated hairThread, string, rope and similar materialsSolid white fabric1.3. Definitions: (Words defined are italicized and bolded once per section)Crocking: Color transfer from fabric due to rubbingDesized : Fabric with sizing and other finishing chemicals removedFabric : All flat-surface and raised-fiber textile materials yarn, ribbons, thread, string,rope and other similar materials. Vinyl, urethane, or similar materials used as fabriccomponents, including fabric items backed by these materials.Simulated Hair : Monofilament fiber used to simulate hair, usually Kanekalon,modacrylic, saran, or nylon, and typically rooted or stitched to a pliable substrate.Warp : The series of yarns extended lengthwise in a loom. These yarns are crossed bythe “weft” yarns, also referred to as fabric grain.QSOP 0006-4100 CPage 2 of 6PI CONFIDENTIAL - MATTEL, INC. PROPRIETARY INFORMATION 2. PERFORMANCE REQUIREMENTS 2.1. PRODUCTS FOR CHILDREN UNDER 3 or with high expected abrasion, such aschildren’s clothing, infant bedding, guitar straps, or diaper bags:Average CrockingScoreEvaluation for Dry Crocking Evaluation for Wet Crocking 4 - 5Accept Accept 3 Reject Accept 0 - 2.5Reject Reject 2.2. PRODUCTS FOR CHILDREN 3 OR OLDER:Average CrockingScoreEvaluation for Dry Crocking Evaluation for Wet Crocking 4 - 5Accept Not Applicable 3 - 3.5Perform wet crocking Accept 1.5 - 2.5Reject Accept 0 - 1 Reject Reject2.3. PRODUCTS FOR USE IN WATER:Average CrockingScoreEvaluation for Wet Crocking 4 - 5Accept 0 - 3.5 Reject3. TEST METHODS3.1. Test EnvironmentIlluminate the test surface with 538 lux (50 foot candles) or more. The light should hitthe surfaces at approximately 45° and the viewing direction approximately perpendicularto the surfaces.3.2. Equipment3.2.1. American Association of Textile Chemists and Colorists (AATCC) CROCKMETER, Model CM-1.13.2.2. Crock meter Test Cloth, cut 5 cm2. square (2 in2), desized, bleached and with nooptical brightener or finishing material.23.2.3. Evaluation easel, approx. 24 x 19 cm (.5 x 7.5 in) smooth, angled plywoodattached to a same size base.3.2.4. Any white evaluation cloth.3.2.5. AATCC Chromatic Transference Scale.33.2.6. Distilled or deionized water.3.3. General Test Requirements3.3.1. Crock five samples per test and average the score for each 5-sample test.3.4. Procedure3.4.1. PRODUCTS FOR CHILDREN UNDER 3 or with high expected abrasion, such aschildren’s clothing, infant bedding, or diaper bags.3.4.1.1. Perform both dry and wet crocking test and evaluate per §2.1 table.3.4.2. PRODUCTS FOR CHILDREN 3 OR OLDER3.4.2.1. Perform dry crocking test and evaluate per §2.2 table. Products thathave an average crocking score of 3 - 3.5 proceed with wet crockingtest.3.4.3. PRODUCTS FOR USE IN WATER:3.4.3.1. Perform wet crocking test and evaluate per §2.3 table.3.4.4. Dry Crocking Test3.4.4.1. Cut fabric samples to minimum size 51 x 127 mm. (2 x 5 in). Wheneverpossible; cut the long dimension of the sample crosswise (neitherparallel nor perpendicular to the grain) to the fabric grain (warp).Include the maximum number of colors, as is possible, in each sample1 Available from Atlas Electric Devices Co. 4114 North Ravenswood Avenue, Chicago, Illinois 60613, (312) 327-4520.2 Available from TestFabrics, Inc., P.O. Box 420, Middlesex, New Jersey 08846.3 Available from American Association of Textile Chemists and Colorists, P.O. Box 12215, Research Triangle Park, North Carolina 27709. QSOP 0006-4100 C Page 3 of 6PI CONFIDENTIAL - MATTEL, INC. PROPRIETARY INFORMATION3.4.4.2. For fabrics <2 in. wide, e.g. webbing, ribbons, and straps, may be laidside by side tested the width is ≥ the width of the finger dowel.Note: for fabric, webbing, printed labels and straps from which a 2x5 in.sample cannot be extracted, the uncut material shall be tested.3.4.4.3. Place test fabric with the colored surface facing up on the crock meter,flat on the sandpaper with its long dimension in the direction of rubbing.3.4.4.3.1. Perform crocking test on both sides of a fabric when both areprinted with color, but are not the same.3.4.4.4. Place holder over specimen to prevent slipping.3.4.4.5. Mount crock meter test cloth, threads parallel to the direction of rubbing,over the end of the finger projecting downward from the weighted slidingarm. Hold the test square in place with spiral wire clip. Position the clipwith loops upward (if the loops point downward they can drag againstthe test specimen).3.4.4.6. Lower the finger onto the test specimen. Crank the meter handle 10complete turns at one turn per second to slide the finger back and forth20 times. Be sure the finger does not contact the specimen holder.Adjust as necessary.3.4.4.7. Remove the crock meter test cloth square and evaluate. .Fabricspecimens, e.g. napped or brushed, may deposit loose fibers onto thetest fabric during the crocking process. Gently press cellophane tapeagainst the white test fabric to remove loose fibers before evaluating thecircular stain.3.4.5. Wet Crocking Test3.4.5.1. Thoroughly wet crock meter test cloth in distilled or deionized waterimmediately before performing the test. Prepare only one square at atime.3.4.5.2. Blot between two white paper towels to remove excess water.3.4.5.3. Perform test per Dry Crocking (§ 3.4.1).3.4.5.4. Remove the crock meter test cloth and air dry before evaluating..Fabric specimens, e.g. napped or brushed, may deposit loose fibersonto the test fabric during the crocking process. Gently presscellophane tape against the white test fabric to remove loose fibersbefore evaluating the circular stain.3.4.6. Crocking Samples Evaluation3.4.6.1. Evaluate color transfer per the AATCC Chromatic Transference Scale.QSOP 0006-4100 C Page 4 of 6PI CONFIDENTIAL - MATTEL, INC. PROPRIETARY INFORMATIONQSOP 0006-4100 CPage 5 of 6PI CONFIDENTIAL - MATTEL, INC. PROPRIETARY INFORMATION 3.4.6.2. Back the test squares with three layers of white test cloth whileevaluating.3.4.6.3. Rating dry and wet crocking fastness: 3.4.6.4. Place the material behind the scale. The colored portion (the colortransferred from the test fabric to the crock meter test cloth) must bevisible through one of the circular holes in the vertical column closest toit in shade. Move material up or down so that, if possible, it is betweenthe two closest shades.3.4.6.5. Determine ratings by comparing the numbered rows on the chart,interpolating when the sample color depth is between two rows. Choosethe shade that approximates the color transfer on the test fabrics."Grade 5" indicates the least color transfer and "Grade 1" the greatestcolor transfer.3.4.6.6. Average the results and round to the nearest 0.5.4. HISTORY4.1. SignificanceTo minimize fabric color transfer to the child’s mouth, mucous membranes or skin, or to other toy parts, clothing or furniture.This test method is familiar to fabric vendors as it is a standard in the textile industry. The evaluation criteria have been set for Mattel products based on complaints and problems encountered with color transfer. Although yarn, simulated hair , thread, string, and other similar materials are exempted, the AATCC method does evaluate these items if required.4.2. Reason for RevisionSection Revision CImplementation Date: All Reviewed and affirmed. Converted to SI editorial3.4.4.7 & 3.4.5.4 Rewritten to clarify that the procedure to removeexcess fibers prior to evaluation pertains to thewhite test cloth after the crocking process. Itdoes not apply to the test specimen (product).editorialQSOP 0006-4100 CPage 6 of 6PI CONFIDENTIAL - MATTEL, INC. PROPRIETARY INFORMATIONSection Revision B Implementation Date:3.4.1, 3.4.2 & 3.4.3 Clarifies when dry crocking and wet crocking tests are required based upon productcategory.Immediate3.4.4.1 Add a statement for fabric, webbing, printed labels and straps from which a 2x5 inchsample cannot be extracted, the uncut materialshall be tested.3.4.4.2 Clarifies that crocking test is required on both sides of a fabric whose sides are not identical.4.3. Referenced DocumentsAATCC Test Method 8-2001 Colorfastness to Crocking: AATCC Crock meter Method (found in any AATCC Technical Manual published 1989 and forward).。

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