国际化妆品重金属微生物标准(魅惑美妆)
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
（眼部口唇类）及化妆品法案
出口化妆品安全项目重点检测监控一览表
禁用物质"锑"
出口化妆品安全项目重点检测监控一览表
岁以下用）或每毫升化妆品
中）
准,参照我国
化妆品卫生规
范（2007年
版）
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
理法规及检测
方法与指南，
07年12月欧盟
通报禁用物质
"锑"
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表。
小心美白化妆品里的重金属
如对您有帮助，可购买打赏，谢谢小心美白化妆品里的重金属
导语：以适当的小苏打等纯碱调和适量的护肤品，几分钟至十几分钟后，如果呈现灰黑色，就可以初步判定其含有汞。
变色越深，汞或某种汞化合物的含量越高。
肌肤被金属伤了？怎么伤的？就是因为你每天使用了含有某种金属的化妆品。
如果选择得不正确，就可能直接引起金属中毒，那么，怎么减少这种情况的发生几率呢？
警惕化妆品中的3类重金属
测试：
如果你的肌肤符合下面几种状况，就可能是激素或者重金属残留过多了。
1.曾经用过药膏或者特效护肤品治痘，用过抗过敏或美白化妆品。
用后觉得皮肤状态有很大改善，于是连续用了几个月以上。
2.停用去痘或美白产品后皮肤很不舒服，用其他产品后会突然出现红肿、痒和过敏等现象。
3.肌肤暗淡没有光泽，暗黄，甚至变灰变黑，皮肤变薄，出现明显的红血丝，肌肤容易过敏。
既然重金罹对肌肤有害，为什么还在化妆品中添加此成分呢？
化妆品中含有的某些金属是为达到某些特定的功效而刻意添加的。
如添加汞可以起到美白的效果，因为汞化合物会破坏表皮层的酵素活动，使黑色素无法形成。
铅的氧化物具有一定的遮盖作用，也可用于美白。
另外，有些是由于生产原料成分不纯，将不该有的金属成分残留在化妆品中。
而如果长期使用添加了汞、铅等的化妆品，会对人体造成很大的伤害。
因此，允许它们在化妆品中存在，但要在一定的范围之内。
生活中的小知识分享，对您有帮助可购买打赏。
欧盟、美国、日本等国家化妆品重金属、微生物标准
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
及化妆品法案
（眼部口唇类）
出口化妆品安全项目重点检测监控一览表
禁用物质"锑"
出口化妆品安全项目重点检测监控一览表
岁以下用）或每毫升化妆品
中）
准,参照我国
化妆品卫生规
范（2007年
版）
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
理法规及检测
方法与指南，
07年12月欧盟
通报禁用物质
"锑"
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表。
德国更新了化妆品中重金属杂质限值要求
所列 使用情 形 ） ，但 未规 定重金 属的杂 质限值 ．而是参
考了 Ｂ Ｇ Ａ发 布 的 限 值 要 求 （ 该要求 于 １ ９ ８ ５年 由德 国联 邦健康办公 室 （ Ｂ Ｇ Ａ）发 布 ） 。 ２ ０ １ ６年 １ ２月 ，德 国联 邦 消 费 者 保 护 和 食 品 安 全 局
及 电话 ：
年一次 申报 中向俄勒 冈卫生局 申请 豁免 （ 第一个 截止 日
可能是 ２ ０ ２ ２年 １ 月 １日） 。 如 果 制 造 商 申请 豁 免 ，制 造 商 需 证 明 ：
・
７ ． 其他任何相关信息 。
《 无 毒 儿 童 法 案 》实 施 分 为 三个 阶段 ： 第 １阶 段 ：法 案 Ｓ Ｂ ４ ７ ８要 求 俄 勒 冈卫 生 局 在 ２ ０ １ ６ 年 １ 月 １日前 建 立 生 产 商 必 须 申报 的儿 童 健 康 高 度 关 注
可 溶 性 镍 的限 值 依 旧是 １ ０ ｐ ｐ ｍ。
美国 Ｆ ＤＡ 发 布 一份 化 妆 品 中 铅跟 值 的 建议 指 南草 案
铅不 能作 为成分故意添加到化妆 品中 ．但 因其是一 妆 品 （ 如 口红 、唇 彩 、唇 线 ）和 外 部 使 用 化妆 品 （ 如 眼
种 天 然 重 金 属 ，故 常会 出 现 在 空 气 、水 和 土壤 中 ， 因此 在 化 妆 品成 品 中很 可 能 会 发 现 极 低 水 平 的 微 量 铅 。２ ０ １ ６ 年 ｌ ２月 ２ ３ 日 ，美 国 Ｆ Ｄ Ａ 公 布 了 一 份 关 于 唇 部 化 妆 品
影 、腮 红 、洗发 水和身 体乳 ） 。草 案征集 意见截止 日期
为 ２ ０ １ ７年 ２月 ２ １日 ，之 后 Ｆ Ｄ Ａ 将 会 准 备 指 南 最 终 版 本 。 该 指 南 很 可 能 有 助 于缓 解 消 费者 的担 忧 。 目前 ，出 口到美 国 的化 妆 品 中铅 的 限 值 是 参 考 加 州
化妆品中重金属的危害及检测技术
化妆品中重金属的危害及检测技术化妆品是现代人日常生活中不可或缺的一部分。
不过，在一些廉价化妆品中，人们可能会接触到重金属成分，例如铅、汞和铬等，这些物质常常会对人的健康造成严重危害。
如果大量接触这些重金属，会引起不同程度的中毒症状，包括皮肤病、神经系统病变、肝肾功能不良等，有时候还会出现生殖系统异常和癌症等重大威胁。
化妆品中的重金属主要来自两个方面：一是化妆品原材料中的污染，二是生产过程中的残留。
首先，化妆品原材料中的铅、汞、铬等重金属，是在土壤、水源或大气污染物的存在下形成的。
在化妆品原材料采集过程中，这些重金属与其它成分混合在一起，无法从成分上进行区分和过滤，因此有可能被化妆品厂商使用。
此外，一些海外化妆品可能会在生产过程中，添加了含铅化合物的色素，以便减少生产成本。
其次，在化妆品生产过程中，重金属主要来自化妆品生产原材料和设备中的残留物。
例如，生产过程中常用的铜制设备，会释放少量的铜离子，如果不及时清理，铜离子会被其他化学物质吸附，污染化妆品。
对于消费者来说，选择合格的化妆品能够有效地降低接触到化学成分的风险。
除了选择知名品牌的化妆品外，我们还应使用市场上专门针对重金属检测的化妆品。
市场上的大型化妆品品牌一般会通过专业机构对化妆品进行检测，以确保它们不含有危险成分。
对于一些便宜、未知品牌的产品，我们可以通过一些简单的方法进行检测。
第一种方法是通过化学实验室对它们的成分进行分析。
这种方法比较简单，只需要将化妆品样品交给专业的化学实验室，他们便会用专门的设备进行分析。
不过，这种检测方法比较复杂，可能要花费较长时间进行，而且费用比较高。
第二种检测方法是比较简单和普遍的方法，只需要使用一些简单的工具即可完成。
我们可以在早晨涂抹一些化妆品在手臂上，然后再用一张镀银质量较大的纸将手臂包住，这个过程大约需要10-15分钟。
如果纸张表面有黑点，那么化妆品中就可能含有铅或其他重金属。
综上所述，化妆品中含有重金属的问题应引起我们的重视。
行业标准培训化妆品系列之4：化妆品中微生物和重金属的解读
送检注意事项
答疑时间
THANKS
-THE END-
行业标准培训化妆品系列之4：
化妆品中微生物和重金属的解读 SGS-化妆品及日化产品部 主讲： 2018.07.29
第一部分 微生物和重金属 污染的危害 第二部分 各国法规要求 第三部分
• 1、微生物污染的危害 • 2、重金属污染的危害 • 1、中国 2、欧盟 3、美国 4、加拿大 5、日本 • 1、微生物测试 • 2、重金属测试
限量标准
≤ 1000 CFU/g 或 ml； ≤ 100 CFU/g 或 ml (眼部用、粘膜用、3岁以下儿童 用）
梭菌 /g
耐胆汁酸革兰氏阴性菌/g 铜绿假单胞菌 /g 白色假丝酵母菌/g
不得检出
第二部分＞2、各国法规要求-欧盟
德国健康署 BgA 检测项目
铅
限量标准
≤ 20 mg / kg
汞 砷 锑 镉 镍(可溶出)
第三部分＞2、送检注意事项 重金属
不接受混样测试 样品量：≥ 30 g 或 ml 测试周期：5工作日
第三部分总结 送检注意事项
微生物：包装完好无破损 重金属：不接受混样测试
第一部分 微生物和重金属 污染的危害 第二部分 各国法规要求 第三部分
• 1、微生物污染的危害 • 2、重金属污染的危害 • 1、中国 2、欧盟 3、美国 4、加拿大 5、日本 • 1、微生物测试 • 2、重金属测试
孕妇或哺乳期妇女使用铅超标的化妆品, 铅会通 过胎盘和乳汁进入胎儿和婴儿体内,其智力会受到 影响.
第一部分＞2、重金属污染的危害
砷可以通过呼吸道、皮肤、消化道进入体内. 砷可以造成神经系统、心血管系统、消化系统、 皮肤等组织器官的损坏. 国际癌症研究中心确认，无机砷是人类皮肤及肺 的致癌物.
化妆品中重金属含量的测定(精)
TheDetermination of Heavy Metals inCosmetics化妆品中重金属含量的测定学生姓名赵红学号 054131233专业食品科学与工程班级 2005－C指导教师杨同舟张寒冰学部食品与环境工程学部答辩日期 2009年5月24日The determination of heavy metals inCosmeticsAbstractCosmetics impose on the surface of the body, play a role of clean, maintenance, landscaping and removal the bad smell. However, in the course of the production of cosmetics , the raw materials or intermediate inputs can be mixed with a number of restricted substances, in order to understand and master its limit value of the quality of the material, that is to do an analysis of physical and chemical indicators. In this paper, trace elements of arsenic and lead are determined by microwave digestion / inductively coupled plasma mass spectrometry in the cosmetics, the method has the advantages a short time, less consumption of reagents, loss of a small element, accurate measurement, Trace elements of mercury was determined by direct determination of mercury analyzer, the method is simple, sensitive, safe, fast, time-saving.The results are as follows:Hong Kong Monetary olary Cosmetics Co., Ltd. produce Xue Yan lasting whitening liquid foundation, Hong Kong Monetary olary Cosmetics Co., Ltd. produce Xue Yan Whitening Moisturizer，Shenzhen Green Xin Daily Cosmetics Co., Ltd. produce eight glasses of water nutrition moisturizing cream, Johnson & Joh Co.,、、、；、、、；、、、；Keywords；；关键词：化妆品 ; 重金属 ; 含量微波消解/电感耦合等离子质谱仪ContentsABSTRACT IN ENGLISH IAbstract in ChineseChapter 1 Introduction1.1 The purpose and significance of detection in this paper1.2 Common detection methods of cosmetics1.3 The hazards of heavy metals in cosmetics1.3.1 The hazards of mercury and its compounds 41.3.2 The hazards of arsenic and its compounds 51.3.3 The hazards of lead and its compounds 5Chapter 2 Materials and Methods2.1 Experimental materials2.2 Instruments and reagents2.3 Methods and procedures2.3.1 Sample pre-treatment 82.3.2 The determination of lead in cosmetics2.3.3 The determination of arsenic in cosmetics2.3.4 The determination of mercury in cosmeticsChapter 3 Results and Analysis3.1 The results and analysis of lead content in four kind of cosmetics3.2 The results and analysis of mercury content in four kind of cosmetics3.3 The results and analysis of arsenic content in four kind of cosmeticsConclusionsReferencesAcknowledgementsChapter 1 Introduction1.1 The purpose and significance of this paperWith the development of our society, cosmetics have become people daily life an indispensable element, in order to ensure that there is no harmful because of the use of cosmetics to consumers, many countries have formulated laws and regulations to manage cosmetics. raw materials, finished products of cosmetics to carry out a strict requirement. China's legal system and supervision of the Ministry of Health Division of Health has also formulated a "Hygienic Standard for Cosmetics", provides raw materials and cosmetic hygiene requirements of the final product. Countries implement health monitoring system. Health administrative departments of the State Council in charge of the national health supervision of cosmetic products, local people's governments above the county level health administrative departments in charge of this area of the health supervision of cosmetic products [1].Recent years, China's sustained economic development and people's consumption level's a significant increase in skin-care beauty of daily life has become an indispensable necessity, the function of cosmetics is now gradually modified by the simple beauty to the functional aspects extension, there are many types of cosmetics for special purposes. various brands of sunscreen, speckle reducing, wrinkle reduction phytosome, tender skin whitening and other cosmetic products in the domestic market has emerged.Access to the rapid development of cosmetic industry, the sales increase, the adverse reactions caused by cosmetics from time to time, consumers greatly enhance the safety awareness, hair dye allergy, freckle whitening products are often reported the content of heavy metals are exceeded, in particular in cosmetics banned substances were detected shocked the world, these problems reflect the safety of cosmetic products , due to theexistence of these problems, consumers should have a more objective understanding of scienceLead, mercury, arsenic is highly toxic accumulation of harmful elements, belonging to banned substances in cosmetics , Them is not permitted to add man-made, but in the course of the production of a number of cosmetics use raw materials itself contains a small amount of lead, mercury, arsenic, in order to achieve the purpose of antibacterial, antimicrobial, and whitening, result in a significant increase of heavy metals in cosmetics, so the national standard for lead, mercury, arsenic and other toxic substances have made clearly regulate, cosmetics norms of the National Health will review the provisions of health projects [2], "Hygienic Standards for Cosmetics" is a national mandatory standards, toxic and harmful elements of its provisions made. Toxic and harmful elements: standards set forth in the mercury , arsenic and lead in the cream cosmeticslimited.mercury ≤ 1mg/kg [3], arsenic (arsenic in total ≤ 10mg/kg [4], lead (lead in total ≤ 40mg/kg [5], The three kinds of heavy metal elements which comes mainly from the impact of human activities affected the environment, including soil pollution, river pollution and the introduction of raw materials pollution, lead, arsenic and mercury are harmful to human health [6], so that their content in cosmetics should be lower. Under the existing standard test of these projects has become a necessity of life, increasing sales volume, product brands, increasing the number of varieties. Cosmetics safety and health are closely related to people’s health , because of heavy metals in the special purpose of being used for cosmetics, but their harm to the human body is well known ,some of the material has a strong toxicity, mutagenicity, carcinogenicity, teratogenicity, what is more on the skin and mucous membrane may cause obvious damage, the heavy metal contentin cosmetics is one of the indicators will be detected[7].1.2 Common detection methods of cosmeticsCosmetics chemical standard test method provides test cosmetics are mainly high-performance liquid chromatography flame atomic absorption spectrometry, atomic fluorescence wet digestion and microwave digestion ICP-MS (inductively coupledplasma mass spectrometry, ICP-MS . [8]High Performance Liquid Chromatography (HPLC for short also known as high-pressure or high-speed liquid chromatography, high performance liquid chromatography separation or modern column chromatography to liquid as the mobile phase, using high-pressure fluid system, is color spectrum of an important branch of law. It is made of high-pressure pump will have a different polarity, the ratio of a single solvent or a mixture of different solvents, such as the mobile phase buffer with a fixed phase pumped into the column, the injection valve into the sample by the mobile phase with into the column in the column after the separation of the components were, in order to enter the detector test in order to achieve the analysis of samples. This method has become achemistry,biochemistry, medicine, industry, agriculture, environmental protection, inspection and seizure law in important areas such as the separation and analysis technology, analytical chemistry, biochemistry and environmental chemistry of the essential tools the hands of workers.Atomic absorption spectrophotometry, it is a test element from the hollow cathode lamp to emit a certain intensity and spectral characteristics of a certain wavelength of light, when it contains a test element through the ground state of the flame atomic vapor when some of the characteristics of the light spectrum is absorbed, and not absorption of light by the monochromator, the photoelectric detector exposure was detected, according to the characteristics of light absorption spectrum of the extent, it will test measured like elements in the test.Wet digestion atomic fluorescence spectrometry ，it is that high-pressure sealed using PTFE digestion Couplers can sample digestion products will be transferred to digest a good sample of 10mL bottle volume, deionized water volume 10mL, shaken. 1.0mL injection cold vapor atomic fluorescence in the detector response to the bottle, adding 0.2mL10% SnCl2, goods Couplers solution SnCl2 trace mercury has been reduced to mercury vapor, mercury vapor by argon gas into the fluorescence chamber, resulting in fluorescence. Determination of this method time is short digestion, the volatile loss ofmercury-free, less interference, lower detection limit for (100ng / L, recovery rate of95.7% -98.0%, good reproducibility, relative standard deviation of 2.6%.Microwave Digestion Inductively Coupled Plasma Mass Spectrometry,It is nitric acid and hydrogen peroxide pretreatment solution of cosmetics, the role of the electric field in the microwave the next, so that high-speed molecular friction and collisions, microwave energy to thermal energy. Conditions in the heating, due to acid oxidation and increase in activity, making cosmetics in a relatively short time period , so cosmetics lead, arsenic, mercury ion in the state will exist in the test solution [9].Microwave digestion is a highly effective method of sample handling, it has a fast decomposition of samples with good accuracy and precision, high sensitivity, elements not easily measured, as well as blank and low losses, currently at home and abroad, has been widely used in cosmetics , pharmaceuticals, plastic products such as pre-treatment samples. The method of cosmetic products of lead, arsenic treatment of samples with good results, and a resolution to be detected in a variety of elements in cosmetics, the digestion method is simple, time short, less reagent consumption, high accuracy measurements of the characteristics of an ideal sample preparation is one of the ways, lead, arsenic determination by carrier gas to the sample directly into apparatus, does not require any preconcentration, separation step, direct determination of high sensitivity, small interference.Inductively coupled plasma mass spectrometry is based on inductively coupled plasma (ICP ionization source for mass spectrometry analysis. It has high sensitivity, simple lines, linear dynamic range, can be multi-element detection , At the same time, It is a potential multi-element and isotope ratio analysis, has been widely used in environmental, metallurgical, oil, , medical, semiconductor, and other fields of nuclear materials analysis.ICP-MS from the power source is inductively coupled plasma (ICP, the main is a three-tier, composed of quartz torch casing pipe, tube top around the torch has load coils, the sample from the carrier gas into the plasma torch flame will occurrence of evaporation, decomposition, excitation and ionization, auxiliary gas used to maintain the plasma.Tangent direction of cooling air to the introduction of outer tube, resulting in a spiral flow to the load coil outside the tube wall to be cooled. The most common way is to use sampling or right-angle type concentric pneumatic nebulizer generated aerosols, taken off the set in the carrier gas is injected into flame torch, the sample injection volume of about 1ml/min, by peristaltic pump into the fog of devices. At about 10mm above the load coil, the torch flame temperature of about 8000K, in such a high temperature, the ionization energy of the elements below 7eV fully ionized, the ionization energy below the ionization degree of the elements 10.5ev greater than 20%. As the most important element in ionization energy is lower than 10.5eV, therefore have a very high sensitivity [10].1.3The hazards of heavy metals in cosmeticsIn modern society, the use of lipstick, skin care, sunscreen, whitening beauty cream, hair dye and other cosmetics is more and more , sustainable use of cosmetics for nearly decades. A significant portion of the above cosmetics (including some of the world's leading brands contain different levels of heavy metals . These have been detected or have not been detected . the harmful ingredients, the body will absorb some or all of them , at last deposition in the blood or organ cells of the human body, they will be a bomb hidden in the body, may endanger the physical health [ 11].Let us understand the risks of heavy metals:1.3.1 The hazards of mercury and its compoundsMercury and its compounds were banned in cosmetic, Them exist as impurities the limit is less than 1mg/kg. However, In view of sulphide of mercury (ethyl mercury thio sodium salicylate with the purpose of good inhibitory effect, allowing for eye make-up and eye make-up remover products, HgS pigment is generally added to the red lipstick, color cosmetics such as rouge, mercuric chloride used in cosmetics with the purpose of white, delicate, mercury ions can interfere with human skin in the process of tyrosine into melanin, are generally added in thewhitening, whitening, speckle reducing cosmetics, low prices of these substances, so HgS, mercuric chloride and even the use of modern cosmetics maker [13]. Mercury and its compounds can pass through the skin barrier into the body all the organs and tissues, mainly the most damage to the kidneys, followed by the liver and spleen, destruction of enzyme system activity, so that protein coagulation, tissue necrosis, with marked gonadal toxicity, embryo drug and the role of cell genetics. Chronic toxicity of mercury and its compounds as the main clinical manifestations: fatigue, weakness, drowsiness, apathy, emotional instability, headache, dizziness, tremor, as well as hemoglobin and red blood cell, WBC reduction ,liver damage and so on, in addition to sensory peripheral receded, concentric narrowing the field of vision, hearing impairment and the Masonic movement disorders and so on[12].1.3.2 The hazards of arsenic and its compoundsArsenic and its compounds in components of cosmetics for the prohibited substances , they are widespread in nature, cosmetic raw material and cosmetics production process, also vulnerable to arsenic contamination, so as the existence of impurities, arsenic in cosmetics for the limits is less than 10mg/kg (arsenic in total[13]. Arsenic and its compounds are considered carcinogens, long-term use cosmetics with high arsenic can cause dermatitis, skin pigmentation, eventually leading to skin cancer. Arsenic and its compounds as the main clinical manifestations poisoning peripheral neuritis symptoms such as pain in the limbs, difficulty walking, muscle atrophy, brittle hair easy to fall off, skin pigment a high degree of calm, the palm of your hand a high degree of foot plantar keratosis skin, repeat-like hyperplasia, chapped, ulcers enduring, you can change skin of skin cancer and may die from complications. If cosmetics added excessive arsenic poisoning after use, then if the absorption, arsenic can lead to changes in the nervous system, at the same time there are some changes in peripheral nerves, such as limbs rigid body weakness, pain and other symptoms, There may be changes skin on the black, pigments calm.1.3.3 The hazards of lead and its compoundsLead and its compounds in components of cosmetics for the prohibited substances , as the impurity element content in cosmetics should not exceed 40mg/kg (lead in total . Lead in cosmetics can increase the skin's white , it is added to whitening, whitening cosmetics. All the biological effect of lead on both toxic. Lead and its compounds absorbed through the skin and harm to human health, mainly affecting the nervous system, kidneys, gastrointestinal tract, reproductive function, cardiovascular, immune and endocrine systems, particularly affect fetal health. The main clinical manifestations central nervous system function as a result of disorder arising from neurasthenia syndrome. Acute or subacute encephalopathy. Ataxia. The loss of appetite , metallic taste in the mouth, gingival lead line, abdominal cramps, nausea, vomiting, diarrhea. Hematopoietic system in the low hemoglobin, normal red blood cell-cell or small cell anemia, red blood cell stippling appears, the network erythrocytosis. Other diseases are toxic hepatitis, hepatomegaly , jaundice, and kidney damage have also resulted in oliguria , anuria , hemoglobinuria , causing nephritis or renal atrophy, can also cause myocardial injury, congestive heart failure appear [14].Chapter 2 Materials and Methods2.1 Experimental materialsLasting whitening liquid foundation marketXue Yan whitening moisturizer marketEight glasses of water nutrition moisturizing cream marketJohnson & Johnson baby nourishing moisturizing cream market2.2 Instruments and reagentsUltrasonic cleaner data KQ-500DE-type Ultrasonic Instrument Co., Ltd. Kunshan CityShenzhen TF-80 Fume Hood Laboratory Equipment Co., Ltd. US-GhaliMARS-X microwave digestion apparatus CEU U.S. companiesDMA-80 mercury analyzer LabTech Ltd.Inductively coupled plasma mass spectrometer ELAN9000 U.S. ICP-MARKS-MS CorporationStandard Stock solution of arsenic concentration 1000μg/ml , media concentration of 10% HCL National Steel Iron Test Center & Steel Research Institute GSB G62028-90 (3302The use of arsenic standard solution: use 1mL pipet draw reserve arsenic standard solution (1000μg/ml in 100mL bottle volume. With 3% nitric acid solution diluted to calibration, mixing, the solution concentration of10μg/ml , 10μg/ml again draw arsenic standard solution 1ml to 100ml bottle volume, with 3% nitric acid solution diluted to the concentration of mixing, solution concentration of 100ng/ml, absorb arsenic 10ml100ng/mL solution volume to 50ml, this solution concentration of20ng/mL, back-up.Standard Stock solution of arsenic concentration 1000μg/ml media concentration of 10% HNO3 National Steel Iron Testing Center & Steel Research Institute GSB G62071-90 (8201The use of lead standard solution: use 1mL pipet draw reserve lead standard solution (1000μg/ml in 100mL bottle volume. With 3% nitric acid solution diluted to calibration, mixing, the solution concentration of10μg/ml , 10μg/ml again draw lead standard solution 1ml to 100ml bottle volume, with 3% nitric acid solution diluted to the concentration of mixing, solution concentration of 100ng/ml, absorb lead 10ml100ng/mL solution volume to 50ml, this solution concentration of 20ng/mL, back-up.2.3 Methods and procedures2.3.1 Sample pre-treatmentAccuracy check 0.500g sample of the four samples with electronic balance, each sample in two in the polyethylene digestive tract, and then a blank check for the control nitrification tube experiments, with the pipette gun in 10 the digestive tract by adding accurately 5ml 70% of nitric acid (pure grade gifted , and digestive tract can digest add to digestion in the microwave digestion instrument 1h 15min , until the completion of digestion and after natural cooling to room temperature remove the digestive tract, digestion in the mouth of the bottle up under the Fume Hood open the digestive tract, the digestive tract of the four samples and a blank tube into the cone-shaped 100ml bottles, with a small amount of deionized water and the tube side wall washing 2-3 times washing liquid will be poured into the cone-shaped bottle , and then tapered Fume Hood five bottles will be placed on the heating plate heated to high temperatures, the sample bottle until steaming to nearly dry, about 1ml around , the cone-shaped bottle is removed from the heating plate cooling to room temperature, then add 25ml 1% of nitric aciddissolved .Fume Hood will be in the digestive tract in the remaining four samples and a blank tube into bottle volume in 200ml , with a small amount of deionized water and pipe wall plug washing 2-3 times, will be poured into the washing liquid bottle volume in deionized water final volume of the sample bottle volume, shake, stand, filter, if the sample appears turbid phenomenon may be a bad digestion, it would take a further 100ml conical check four 200ml bottles and bottle volume filter corresponding sample container until the solution clarified, so as not to plug the equipment. Drawing standard curve, the two standard solutions that accurately bottle volume take 1ml to 100ml bottle volume in deionized water volume, this bottle volume number A (10 ppm, and then remove the accurate solution 1ml in A to another 100ml capacity bottle, deionized water volume, this bottle volume number B (100ppb, then remove accurate 20ml solution in B to another50ml in deionized water volume, this bottle volume numbered C (40ppb, then accurate remove the solution 10ml in B to another 100ml bottle volume in deionized water volume, this bottle volume number D (10ppb, then plasma mass spectrometry standard solution drawn from low - concentration to high concentration standard curve. Plasma mass spectrometry measurements of samples of various heavy metals.2.3.2 the determination of lead in cosmetics(1 working conditionsPower: 1kwAtomization gas flow rate: 0.9L/minLens voltage: 6.2VArgon: 0.4Mpa(2 The standard curveTest requirements and equipment in accordance with the provisions of the bestconditions for equipment set up and adjust the best working state apparatus, rendering the standard curve.(3 sampleIn the selection of the best conditions, the determination of blank solution and sample solution of lead content, the computer automatically calculated from the curve of the corresponding concentration2.3.3 Determination of arsenic in cosmetics(1 working conditionsPower: 1kwAtomization gas flow rate: 0.9L/minLens voltage: 6.2VArgon: 0.4Mpa(2 The standard curveTest requirements and equipment in accordance with the provisions of the best conditions for equipment set up and adjust the best working state apparatus, rendering thestandard curve.(3 sampleIn the selection of the best conditions, the determination of blank solution and sample solution in the arsenic content, the computer automatically calculated from the curve ofthe corresponding concentration.2.3.4 Determination of mercury in cosmeticsThis experiment tested mercury use mercury analyzer in directmeasurement, put the boat in mercury analyze to 800 moderately high-temperature perturbation bake furnace firing 10-20min, then cooling, accuracy check 0.200g the four samples with the boat in mercuryanalyzer with the boat can be measured the mercury content of samples.Chapter 3 Results and Analysis3.1 the results and analysis of lead content in four kind of cosmetics Table 3-1 Lead content in four kind of cosmeticssamples Lead mg / kgLasting whitening liquid foundation Whitening moisturizerNutrition moisturizing cream Baby moisturizing cream moisture 1.244 0.042 0.046 0.339Note: A－Lasting whitening liquid foundationB－Whitening moisturizerC－Nutrition moisturizing creamD－Baby moisturizing cream moistureFigure 3-1 Lead content in four kind of cosmeticsLead in cosmetics can increase the skin's white , it is added to whitening, whitening cosmetics. Lead and its compounds absorbed through the skin and harm to human health, mainly affecting the nervous system, kidneys, gastrointestinal tract, reproductive function, cardiovascular , particularly affect fetal health , We can see from the table, whitening liquidfoundation with a high level of lead. According to the standard set forth in the lead element of the limits in cosmetics: Lead (Pb in total ≤40mg/kg , we can see the lead content of four kinds of cosmetics are not exceeded the national standard , consumers can assured use .3.2 the results and analysis of mercury content in four kind of cosmeticsTable 3-2 Mercury content in four kind of cosmeticssamples Mercury mg / kgLasting whitening liquid foundation Whitening moisturizerNutrition moisturizing cream Baby moisturizing cream moisture 0．1013 0．0974 0．0625 0．0193Note: A－Lasting whitening liquid foundationB－Whitening moisturizerC－Nutrition moisturizing creamD－Baby moisturizing cream moistureFigure 3-2 Mercury content in four kind of cosmeticsThe mercury ion of cosmetics can be replacement with anion tyrosinase enzyme, lead to the loss of enzyme activity, so that can not generate melanin to the role of rapid whitening beauty cream [15], therefore, mercury whitening in a short time, from table we can see that the market cosmetics, whitening liquid foundation with a high level of mercury. Provided according to the standard element s of mercury in cosmetics limit: ≤ 1mg/kg, we can see none of the four cosmetics is exceeded.3.3 the results and analysis of arsenic content in four kind ofcosmeticsTable 3-3 Arsenic content in four kind of cosmeticssamples Arsenic mg / kg Lasting whitening liquid foundationWhitening moisturizer Nutrition moisturizing cream Baby moisturizing cream moisture 0．345 0．037 0．1270．036Note: A－Lasting whitening liquid foundationB－Whitening moisturizerC－Nutrition moisturizing creamD－Baby moisturizing cream moistureFigure 3-3 Arsenic content in four kind of cosmeticsLong-term use cosmetics with high arsenic can cause skin pigmentation , eventually leading to skin cancer . From the table, we can see that the market cosmetics , the same brand of cosmetics in the efficacy of different heavy metal content are very different, different brands of the same efficacy of the cosmetic heavy metal content are also very different, from the table we can see that the market cosmetics whitening liquid foundation with a high level of arsenic , heavy metals mercury in four kinds of cosmetics limited: arsenic (arsenic in total ≤ 10mg/kg , we can see heavy metals arsenic in cosmetics are not exceeded .ConclusionsMicrowave digestion with inductively coupled plasma mass spectrometry determination trace elements the contend of lead , arsenic in cosmetics is feasible and the method is simple, sensitive, reproducible, test results show that the market cosmetics the lead , arsenic concentration do not exceed the national standard., the microwave digestion method of heavy metals in cosmetics is the same digestion solution can be measured a variety of heavy metal elements at the same time, with simple and fast, precision and accuracy, and wide linear range, as well as save reagents, reduction environmental pollution and so on. determination of trace element content of mercury use mercury analyzer direct determination is possible, the method is simple, sensitive, safe, fast, time-saving and so on., lead content in the four types of cosmetics is whitening lasting liquid foundation 1.244ppm, baby moisturizing cream moisture 0.339ppm, moisturizing cream nutrition 0.046ppm, whitening moisturizer 0.042 ppm, mercury content in the four types of cosmetics is whitening lasting liquid foundation 0.1013ppm, whitening moisturizer 0.0974ppm, nutritional moisturizing cream 0.0625ppm, baby moisturizing cream moisture0.0193ppm ,arsenic content in the four types of cosmetics is whitening lasting liquid foundation 0.345ppm, nutritional moisturizing cream 0.127ppm, whitening moisturizer 0.037ppm, baby moisturizing cream moisture 0.036ppm. the experimental results show that the heavy metals content in four cosmetics are standards and can be assured use.References[1] 化妆品卫生规范、中华人民共和国卫生部、2002[2] 中华人民共和国国家标准、GB7916-87[3] GB 7917-1987化妆品卫生化学标准检验力法——汞[S]、中华人民共和国国家标准汇编、北京、中国标准出版社、1995:141-143。
各国化妆品重金属标准
*
*
*
*
150.0
*
*
*
*
美國
of the U.S. Code of Federal Regulations (CFR). To learn more about FDA-approved color additives, see Color Additives.
10
20.0(色素原
3.0
料)
歐盟
10.0
2.0
*
1.0
口腔:0.1 其他:3
口腔:0.2 其他:1.0
*
*
*
*
*
*
*
口腔:0.5 其他:5
*
*
*
*
*
*
墨西哥
*
*
*
*
*
*
*
*
*
*
*
*
沙烏地 阿拉伯
眼:0 / 嘴:1 眼:0 / 嘴:0.5 眼:0 / 嘴:0.1 眼:0 / 嘴:0.2
其它:10
其它:3
其它:3
其它:3
*
*
*
眼:2 / 嘴:0.5 其它:5
*
*
*
*
*
*
*
*
*
*
*
禁用(容許 1000 ppm)
未禁用
* 禁用 禁用 禁用 未禁用 未禁用 未禁用 未禁用 未禁用 未禁用 未禁用 未禁用
*
韓國
20.0
5.0(洗潤髮) 10(其他)
50.0
1.0
*
*
*
*
*
*
*
*
*
中國
40.0
欧盟、美国、日本等国家化妆品重金属、微生物标准
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
（眼部口唇类）及化妆品法案
出口化妆品安全项目重点检测监控一览表
禁用物质"锑"
出口化妆品安全项目重点检测监控一览表
准,参照我国化妆品卫生规范（2007年版）
或每毫升化妆品中）
岁以下用）
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
理法规及检测
方法与指南，
07年12月欧盟
通报禁用物质
"锑"
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表
剂
出口化妆品安全项目重点检测监控一览表
出口化妆品安全项目重点检测监控一览表。
科颜氏、欧莱雅等检出重金属铅,一叶子pH值超出其执行标准
科颜氏、欧莱雅等检出重金属铅，一叶子pH值超出其执行标准作者：阳佳来源：《消费者报道》2018年第04期用泥敷脸是一种渊源已久的清洁护肤方式。
直到现在，有条件的人还会直接飞往传说中的泥疗圣地死海，让这片富含盐分的湖底泥均匀地铺在肌肤上，以满足嫩滑、美白、修护的肌肤需求。
然而不能绕开的话题是，所谓的“泥膏”，卫生程度如何？会不会有铅、汞等重金属的残留？泥膜对敏感肌肤是否友好？2018年3月，《消费者报道》向权威第三方检测机构送检了11款市场热销的清洁泥膜产品，从重金属（铅、汞）、微生物（菌落总数）、防腐剂（甲醛、对羟基苯甲酸丙酯、对羟基苯甲酸丁酯）、pH值等四个方面，测试其安全性能。
结果显示，科颜氏、欧莱雅、比度克、膜法世家4款泥膜检出微量铅，但含量值未超出国标。
pH值方面，悦木之源、贝佳斯、茵芙莎、一叶子、科颜氏5款泥膜pH值偏高，或对皮肤产生刺激。
微生物方面，所有受检产品在开封时、开封后15天两个时间点菌落总数值均既然是清洁泥膜，自然少不了“泥”。
当前市面上的泥膜产品中，多数泥膜的基质为高岭土、膨润土、天然泥（如海泥、河泥、矿泥、火山泥）等。
此外，豆类（绿豆、黄豆等）研磨而成的粉末也常被当做基质使用。
以使用最广泛的高岭土和膨润土为例。
高岭土又称中国粘土，学名来自江西景德镇的高岭村，是几千年来制瓷的上佳原料。
质纯的高岭土洁白细腻，比表面积大，吸附性能良好；膨润土则最早在美国怀俄明州被发现，主要成分为蒙脱石，其矿物内部有大量空洞和较大的内表面积，同样有着极强的物理吸附能力。
相比起淀粉质衍生物、豆类粉末等，高岭土、膨润土均采自大自然，这意味着更天然，但也越可能出现重金属残留。
化妆品配方师甄认为：“采自大自然的原料可能存在铅、汞等金属超标的情况，但在原料生产过程中，会被清除掉。
那些铅超标的膨润土，是不能作为原料使用的。
”在《化妆品安全技术规范》（下称《规范》）中对于铅、汞均有限值要求，其规定化妆品中铅含量低于10 mg/kg，汞的含量低于1mg/kg。
化妆品行业质量检测标准
化妆品行业质量检测标准绪论化妆品作为人们日常生活中不可或缺的产品之一，其质量安全一直备受关注。
为了保障消费者的权益，并确保化妆品的质量符合相关标准，各国纷纷制定了化妆品行业的质量检测标准。
本文将对化妆品行业的质量检测标准进行论述。
一、产品成分分析检测标准1. 成分确认：对于化妆品中的各种成分进行确认，确保其符合国家或地区相关的法规法律要求，并评估其对人体的安全性。
2. 成分含量检测：对化妆品中活性成分、防腐剂、色素等含量进行检测，并确保其符合国家标准。
3. 有害物质检测：对潜在的有害物质如重金属、铅和汞等进行检测，并确保其含量在国家标准规定的范围内。
二、微生物检测标准1. 细菌总数及霉菌和酵母菌检测：对化妆品中的微生物进行检测，确保产品不受细菌、霉菌和酵母菌的污染。
2. 大肠菌群检测：对含有水分的化妆品进行大肠菌群的检测，确保其不含有大肠菌群和其他肠道细菌，防止对人体健康产生潜在风险。
三、物理性质检测标准1. 外观和气味检测：对化妆品外观、颜色和气味进行检测，确保其符合产品规格要求。
2. 稳定性测试：对化妆品进行各种环境下的稳定性测试，如温度、湿度、光照等因素，确保产品在正常使用过程中不会发生质量变化。
四、功能性能检测标准1. 防晒性能检测：对防晒类化妆品的SPF值进行测试，确保其防晒效果符合标准要求。
2. 保湿效果检测：对保湿类化妆品的保湿效果进行测试，确保其达到产品宣称的保湿效果。
3. 抗衰老效果检测：对抗衰老类化妆品的抗氧化性能进行测试，确保其具有抗衰老的效果，并符合产品标准规定。
五、安全性能检测标准1. 皮肤刺激性测试：对化妆品进行皮肤刺激性测试，确保其对皮肤无刺激性或致敏性。
2. 眼刺激性测试：对化妆品进行眼刺激性测试，确保其对眼部无刺激性。
3. 致敏原测试：对化妆品中的致敏原进行测试，确保其不含有对人体可能产生过敏反应的成分。
六、包装标识检测标准1. 标签标识检测：对化妆品标签和包装进行检测，确保其符合国家标准，并清晰地标示产品的成分、用途和使用方法等信息。